EP2286008A1 - Herstellungsverfahren für hochfeste polyethylenfaser und dadurch hergestellte hochfeste polyethylenfaser - Google Patents
Herstellungsverfahren für hochfeste polyethylenfaser und dadurch hergestellte hochfeste polyethylenfaserInfo
- Publication number
- EP2286008A1 EP2286008A1 EP08753618A EP08753618A EP2286008A1 EP 2286008 A1 EP2286008 A1 EP 2286008A1 EP 08753618 A EP08753618 A EP 08753618A EP 08753618 A EP08753618 A EP 08753618A EP 2286008 A1 EP2286008 A1 EP 2286008A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solvent
- fiber
- gel
- tenacity
- organic compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 98
- -1 polyethylene Polymers 0.000 title claims abstract description 50
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 49
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 49
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000009987 spinning Methods 0.000 claims abstract description 15
- 239000012855 volatile organic compound Substances 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 239000007791 liquid phase Substances 0.000 claims abstract description 7
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000012071 phase Substances 0.000 claims abstract description 5
- 238000009835 boiling Methods 0.000 claims description 6
- 229920006240 drawn fiber Polymers 0.000 claims description 6
- 239000000126 substance Substances 0.000 abstract description 8
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 16
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 16
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000001891 gel spinning Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 208000018747 cerebellar ataxia with neuropathy and bilateral vestibular areflexia syndrome Diseases 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229960004132 diethyl ether Drugs 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/06—Washing or drying
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
Definitions
- the present invention relates to a method of manufacturing high-tenacity polyethylene fiber and high-tenacity polyethylene fiber manufactured thereby, and more particularly, to a method of manufacturing high-tenacity polyethylene fiber, which is capable of realizing high-tenacity polyethylene fiber having superior mechanical properties, including high tenacity and high elongation and excellent chemical resistance, and to high-tenacity polyethylene fiber manufactured thereby.
- Background Art
- high-tenacity polyethylene fiber has been widely used in various fields, thanks to its superior mechanical properties, including high tenacity and high elongation, and superior chemical properties, including high chemical resistance.
- the preparation of such high-tenacity polyethylene fiber includes an ultra-high drawing method, a solid state extrusion method, a zone drawing method, or a gel spinning method.
- a gel spinning method which makes mass production possible.
- the gel spinning method is conducted in a manner of mixing ultra- high-molecular- weight polyethylene with a first solvent which is nonvolatile, thus obtaining a gel solution, spinning the gel solution in a cooling bath, thus forming gel fiber, removing the first solvent, which is nonvolatile, from the gel fiber using a second solvent, which is volatile, and drawing the gel fiber.
- the conventional volatile solvent is problematic in that it cannot completely extract the nonvolatile solvent for dissolving the high-tenacity polyethylene fiber and cannot be reused either, because it is difficult to separate from the nonvolatile solvent.
- the fiber manufactured through the above method has creep properties and stress internally generated in the course of solidification and drawing, and thus may crack, and as well, does not have sufficient tenacity in the state in which the first solvent is not completely removed therefrom. Disclosure of Invention
- the present invention has been made keeping in mind the above problems occurring in the related art, and provides a method of manufacturing high- tenacity polyethylene fiber having superior mechanical properties including high tenacity and high elongation and excellent chemical resistance using ultra- high-molecular- weight polyethylene having a molecular weight ranging from hundreds of thousands to millions of mol.
- the present invention provides a method of manufacturing high-tenacity polyethylene fiber, which is capable of completely removing a first solvent, which is nonvolatile, and eliminating creep properties and stress from the fiber.
- the present invention provides high-tenacity polyethylene fiber, manufactured through the above method.
- a method of manufacturing high-tenacity polyethylene fiber may comprise mixing polyethylene, having a molecular weight average molecular weight ranging from 200,000 to 5,000,000, with a first solvent, which is a nonvolatile organic compound, thus obtaining a gel solution having an intrinsic viscosity of 17-23 dl/g; spinning the gel solution using a die, thus forming gel fiber; immersing the gel fiber in a second solvent, which is a liquid-phase volatile organic compound, at a high temperature close to the volatile point of the second solvent, and cooling it; and jetting the second solvent, which is a gas-phase volatile organic compound, to the cooled gel fiber, thus extracting the first solvent and drawing the gel fiber at a draw ratio of 30: 1-50: 1.
- high-tenacity polyethylene fiber may be manufactured through the above method.
- the method of manufacturing high-tenacity polyethylene fiber enables the manufacture of high-tenacity polyethylene fiber having superior mechanical properties, including high tenacity and high elongation and excellent chemical resistance.
- Such high-tenacity polyethylene fiber can be widely used in various fields such as bulletproof clothes, safety gloves, medical purposes, various ropes, helmets, and skis.
- a first solvent can be completely removed from gel fiber, and simultaneously, creep properties and stress can be eliminated.
- the term 'ultra high molecular weight 1 indicates a weight average molecular weight of 200,000 or more, and the term 'high tenacity 1 indicates a tenacity of 30 g/d or more, unless otherwise specified.
- the term 'total draw ratio' indicates a value obtained by dividing the maximum speed of any roller, selected from among rollers from an early godet roller to a later winding roller, by the speed of the early godet roller.
- the method of paring high- tenacity polyethylene fiber includes mixing polyethylene, having a molecular weight average molecular weight ranging from 200,000 to 5,000,000, with a first solvent which is a nonvolatile organic compound, thus obtaining a gel solution having an intrinsic viscosity of 17 ⁇ 23 dl/g (Sl), spinning the gel solution using a die, thus forming gel fiber (S2), immersing the gel fiber in a second solvent, which is a liquid- phase volatile organic compound at a high temperature close to a volatile point thereof, and cooling it (S3), and jetting the second solvent, which is a gas -phase volatile organic compound, to the cooled gel fiber, thus extracting the first solvent and drawing the gel fiber at a draw ratio of 30: 1-50: 1.
- the ultra-high-molecular- weight polyethylene is a polyethylene homopolymer composed exclusively of ethylene as a repeating unit, or a polyethylene copolymer resulting from copolymerization of ethylene, substantially constituting a repeating unit with 5 mol% or less of a monomer copolymerizable with the above ethylene, such as alkene.
- the ultra-high-molecular- weight polyethylene has a weight average molecular weight of 200,000 or more, and preferably from 200,000 to 5,000,000. If the weight average molecular weight thereof falls below the above range, the number of terminal groups of polymer chains is increased, and such groups act as defects of finished polyethylene fiber, thus making it difficult to realize high tenacity. Hence, the use of polyethylene having a weight average molecular weight within the above range is preferable.
- the polyethylene has a ratio (Mw/Mn) of weight average molecular weight to number average molecular weight of 10 or less, and preferably 5-8. When the molecular weight distribution is narrow, as above, polyethylene fiber having superior tenacity can be manufactured.
- the first solvent includes a nonvolatile organic compound, in particular, a hydrocarbon-based organic compound having a boiling point of 35O 0 C or higher, and preferably from 35O 0 C to 500 0 C under atmospheric pressure.
- the first solvent having such properties is responsible for dissolving the ultra-high-molecular- weight polyethylene, and can be easily extracted by the second solvent in the subsequent extraction process. Moreover, the first solvent can be reused, with ease of handling due to no danger of fire.
- the first solvent include aromatic hydrocarbons, such as xylene, toluene, or fluorene; aromatic chlorinated hydrocarbons, such as trichlorobenzene; decalin; tetralin; paraffin; petroleum mineral oil; and mineral oil.
- the ultra-high-molecular-weight polyethylene is used in an amount of 5 ⁇ 20 parts by weight based on 100 parts by weight of the first solvent. If the amount of ultra-high-molecular- weight polyethylene is less than the above lower limit, the properties of finished polyethylene fiber, including tenacity and elongation, may be deteriorated. Conversely, if the amount of ultra- high-molecular- weight polyethylene is greater than the above upper limit, the solubility may be decreased.
- the ultra-high-molecular- weight polyethylene is preferably used within the above range in terms of the properties of finished high- tenacity polyethylene fiber and the solubility of ultra-high-molecular- weight polyethylene.
- the ultra-high-molecular- weight polyethylene is preferably dissolved at
- the gel solution of ultra-high-molecular- weight polyethylene thus prepared has an intrinsic viscosity of 17-23 dl/g.
- the intrinsic viscosity of the gel solution is within the above range, it has high crystallinity, and is thus efficiently drawn. Also, high tenacity and elongation may be ensured.
- the formation of the gel fiber may be conducted by spinning the gel solution through a plurality of spinning nozzles formed in the die using an extruder.
- the spinning temperature is set to 12O 0 C or higher, and preferably to 120 ⁇ 210°C.
- the spinning pressure is set to 5 kPa or less, and preferably to 1.5 kPa or less. More specifically, the temperature of the extruder is maintained at 160- 18O 0 C, and the temperature of the die is maintained at 190-210 0 C.
- the die has a ratio (L/D) of length to diameter ranging from 25: 1 to 60: 1.
- the gel solution passing through the spinning nozzles of the die may be maintained at an optimal intrinsic viscosity, thus resulting in polyethylene fiber having high tenacity and elongation.
- the gel fiber exiting from the spinning nozzles of the die is immersed in the second solvent, which is a liquid-phase volatile organic compound, and is then cooled (S3).
- the gel fiber exiting from the spinning nozzles is passed through the air gap defined between the die head and the surface of the second solvent before being immersed in the second solvent.
- the air gap is preferably 2-10 mm long. Further, air, preferably an inert gas such as N , is blown into the air gap at a rate of 1 m/min, in order to prevent oxidation.
- the second solvent includes a volatile organic compound which does not change the gel structure of polyethylene and is harmless to the human body, and preferably a liquid-phase volatile organic compound having a boiling point of 60 ⁇ 80°C under atmospheric pressure.
- a volatile organic compound which does not change the gel structure of polyethylene and is harmless to the human body
- a liquid-phase volatile organic compound having a boiling point of 60 ⁇ 80°C under atmospheric pressure.
- the second solvent examples include alcohols such as ethanol, ethers such as diethylether, ketones, such as acetone, cyclohexanone, and 2-methylpentanone, alkanes such as ethane and n-hexane, haloalkanes, such as dichloromethane and trichlorotrifluoroethane, and mixtures thereof.
- the second solvent has a high temperature close to the volatile point thereof, and preferably the temperature thereof is set at ⁇ 1O 0 C of the volatile point of the second solvent.
- the gel fiber is immersed in the second solvent at a high temperature and is then cooled, such that the gel fiber is slowly cooled in the range from the core portion to the outer portion, consequently preventing the generation of stress and creep properties.
- the second solvent which is a gas-phase volatile organic compound, is jetted to the cooled gel fiber, thus extracting the first solvent and drawing the gel fiber (S4).
- the extraction of the first solvent using the second solvent is conducted by jetting the second solvent when passing the cooled gel fiber through a roller, in order to draw the fiber.
- the drawing process is preferably conducted at a total draw ratio of 30: 1-50: 1.
- the drawing process may be performed through a single step, but is preferably carried out through two or more steps to prevent the generation of yarn breakage in the drawing process and to realize uniform drawing. More preferably, the drawing process is conducted in three or more steps.
- the drawing process includes primarily drawing the fiber while jetting the second solvent at a high temperature (volatile point of second solvent + 50 ⁇ 80°C) greatly exceeding the volatile point thereof, secondarily drawing the primarily drawn fiber while jetting the second solvent at an intermediate temperature (volatile point of second solvent + 20 ⁇ 50°C) slightly exceeding the volatile point thereof, and tertiarily drawing the secondarily drawn fiber at a low temperature (volatile point of second solvent + 5 ⁇ 20°C).
- the primary drawing process is conducted by jetting the second solvent at a high temperature greatly exceeding the volatile point of the second solvent when passing the fiber through a first roller.
- the temperature of the second solvent is set to 120- 15O 0 C.
- the jetting speed of the second solvent is preferably 10-20 times as fast as the drawing speed. In the case where the jetting speed falls outside of the above range and is much faster than the drawing speed, fiber may be damaged. Conversely, when the jetting speed is too slow, annealing effects are exhibited only for a short distance.
- the temperature of the roller is very high, and is preferably set to 120 ⁇ 150°C. As such, it is preferred that the draw ratio be 70% or more of the total draw ratio.
- the secondary drawing is conducted by jetting the second solvent at an intermediate temperature slightly exceeding the volatile point of the second solvent when passing the fiber through a second roller.
- the jetting speed of the second solvent is preferably 20-40 times as fast as the spinning speed.
- the roller has an intermediate temperature, which is set to 100 ⁇ 130°C.
- the draw ratio is 20% or less of the total draw ratio.
- the secondarily drawn gel fiber is passed through a third roller (at a low temperature) without jetting, thereby realizing tertiary drawing.
- the temperature of the roller is low, and is specifically set to
- the second solvent at a high temperature greatly exceeding the volatile point thereof, is jetted to the fiber at a speed 5-10 times as fast as the drawing speed, thus facilitating the connection of ethylene molecules broken due to annealing.
- the high-tenacity polyethylene fiber thus manufactured has superior mechanical properties, including high tenacity and elongation, and excellent chemical resistance. Specifically, tenacity of 30 g/d or more and high elongation of 3% or more are realized.
- high-tenacity polyethylene fiber is provided.
- the high-tenacity polyethylene fiber has high mechanical properties and chemical resistance, and thus can be used in various fields such as cables, canvases, bulletproof clothes, safety gloves, medical purposes, various ropes, helmets, skis, sports and automobile products, and construction materials.
- the gel solution thus obtained was spun through spinning nozzles of a die having a ratio of L/D of 25:1 using an extruder at 170 + 1O 0 C, immersed in trichlorotriflu- oroethane, as a second solvent, at 70 ⁇ 1O 0 C, and then cooled, thus forming gel fiber.
- the air gap defined between the die and the second solvent was set to 3 mm, into which N gas was then blown.
- Example 1 with the exception that the total draw ratio was set to 40: 1 through three steps of drawing. [70] ⁇ Example 3>
- High-tenacity polyethylene fiber was manufactured in the same manner as in
- Example 1 with the exception that the total draw ratio was set to 50: 1 through three steps of drawing.
- the polyethylene fiber of Example 1 was measured for tenacity and elongation through the following methods.
- the tensile properties were measured under conditions of a tensile speed of 300 mm/ min, a sample length of 250 mm, 2O 0 C and 65% RH, using an Instron material test system, and the denier of the sample was measured using a denier creel and was used to calculate tenacity.
- all of the polyethylene fibers of Examples 1 to 3 could be confirmed to have tenacity of 30 g/d or more and high elongation of 3% or more.
- the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020080027103A KR100959867B1 (ko) | 2008-03-24 | 2008-03-24 | 초고강도 폴리에틸렌 섬유의 제조방법 및 이로부터 제조된초고강도 폴리에틸렌 섬유 |
PCT/KR2008/002823 WO2009119940A1 (en) | 2008-03-24 | 2008-05-21 | Manufacturing method of high tenacity polyethylene fiber and high tenacity polyethylene fiber prepared thereby |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2286008A1 true EP2286008A1 (de) | 2011-02-23 |
EP2286008A4 EP2286008A4 (de) | 2012-06-20 |
Family
ID=41114105
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08753618A Withdrawn EP2286008A4 (de) | 2008-03-24 | 2008-05-21 | Herstellungsverfahren für hochfeste polyethylenfaser und dadurch hergestellte hochfeste polyethylenfaser |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2286008A4 (de) |
KR (1) | KR100959867B1 (de) |
WO (1) | WO2009119940A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5370390B2 (ja) * | 2011-02-14 | 2013-12-18 | Jnc株式会社 | ポリオレフィン系帯電防止繊維およびそれからなる不織布 |
EP3564415A1 (de) * | 2013-10-29 | 2019-11-06 | Braskem S.A. | System und verfahren zur dosierung einer polymermischung mit einem ersten lösungsmittel |
KR101917164B1 (ko) | 2013-10-30 | 2018-11-09 | 에스케이이노베이션 주식회사 | 열전도성 폴리머의 제조방법 |
KR101466692B1 (ko) | 2013-12-02 | 2014-12-01 | 동양제강 주식회사 | 용제 추출 장치 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL9301979A (nl) * | 1993-07-08 | 1995-02-01 | Ind Tech Res Inst | Nieuw oplosmiddelensysteem ter bereiding van polyethyleenvezels met een hoge treksterkte en een hoge modulus middels gelspinnen en uitrekken in meerdere fasen. |
US20070154707A1 (en) * | 2004-01-01 | 2007-07-05 | Simmelink Joseph A P | Process for making high-performance polyethylene multifilament yarn |
WO2008024732A2 (en) * | 2006-08-23 | 2008-02-28 | Honeywell International Inc. | Process for the preparation of uhmw multi-filament poly(alpha-olefin) yarns |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU549453B2 (en) * | 1981-04-30 | 1986-01-30 | Allied Corporation | High tenacity, high modulus, cyrstalline thermoplastic fibres |
US4455273A (en) * | 1982-09-30 | 1984-06-19 | Allied Corporation | Producing modified high performance polyolefin fiber |
JPH0410783A (ja) * | 1990-04-27 | 1992-01-14 | Hitachi Ltd | ビデオカメラ装置 |
KR100266997B1 (ko) * | 1993-08-27 | 2000-09-15 | 차이뚜안파옌 꿍예찌슈옌찌 우위완 | 고 강도 및 고 모듈러스 폴리에틸렌 섬유의 제조 방법 |
KR20060106058A (ko) * | 2005-04-06 | 2006-10-12 | 동양제강 주식회사 | 초고강도 폴리에틸렌섬유의 제조방법 |
-
2008
- 2008-03-24 KR KR1020080027103A patent/KR100959867B1/ko not_active IP Right Cessation
- 2008-05-21 EP EP08753618A patent/EP2286008A4/de not_active Withdrawn
- 2008-05-21 WO PCT/KR2008/002823 patent/WO2009119940A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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NL9301979A (nl) * | 1993-07-08 | 1995-02-01 | Ind Tech Res Inst | Nieuw oplosmiddelensysteem ter bereiding van polyethyleenvezels met een hoge treksterkte en een hoge modulus middels gelspinnen en uitrekken in meerdere fasen. |
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Also Published As
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WO2009119940A1 (en) | 2009-10-01 |
EP2286008A4 (de) | 2012-06-20 |
KR100959867B1 (ko) | 2010-05-27 |
KR20090101766A (ko) | 2009-09-29 |
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