EP2282303A2 - Etiquette multicouche - Google Patents

Etiquette multicouche Download PDF

Info

Publication number
EP2282303A2
EP2282303A2 EP20100171546 EP10171546A EP2282303A2 EP 2282303 A2 EP2282303 A2 EP 2282303A2 EP 20100171546 EP20100171546 EP 20100171546 EP 10171546 A EP10171546 A EP 10171546A EP 2282303 A2 EP2282303 A2 EP 2282303A2
Authority
EP
European Patent Office
Prior art keywords
layer
label
printing layer
adhesive
printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20100171546
Other languages
German (de)
English (en)
Other versions
EP2282303A3 (fr
EP2282303B1 (fr
Inventor
André Galle
Thomas Scheubner
Jakob Knechtli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CCL Label AG
Original Assignee
Tesa SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tesa SE filed Critical Tesa SE
Priority to PL10171546T priority Critical patent/PL2282303T3/pl
Publication of EP2282303A2 publication Critical patent/EP2282303A2/fr
Publication of EP2282303A3 publication Critical patent/EP2282303A3/fr
Application granted granted Critical
Publication of EP2282303B1 publication Critical patent/EP2282303B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F3/0288—Labels or tickets consisting of more than one part, e.g. with address of sender or other reference on separate section to main label; Multi-copy labels
    • G09F3/0289—Pull- or fold-out labels
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/023—Adhesive
    • G09F2003/0241—Repositionable or pressure sensitive adhesive
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0257—Multilayer

Definitions

  • the invention relates to a multilayer label having a splittable layer.
  • Information labels are, as the name suggests, information, mostly in the printing process. To apply these labels on a substrate, they have a pressure-sensitive adhesive layer, which fixes the label after the dispensing process.
  • An optimized variant of a label is characterized by the fact that the carrier of the label is printed on top and bottom side. To get to the information on the bottom, the label must be separable. For this purpose, the label is designed such that the carrier can be removed from the adhesive.
  • the disadvantage is that an open adhesive remains on the ground, which tends to foul or adhere to the undesirable things.
  • a laminating adhesive is applied for this purpose between adhesive and carrier. Subsequently, the laminating adhesive is cured (for example, by UV light or thermal), so that the laminating adhesive after irreversible curing no longer has pressure-sensitive adhesive properties.
  • the bond between the carrier and laminating adhesive is preferably designed so that the carrier is removable from the laminating adhesive. Then he stays Laminating adhesive without adhesive properties on the adhesive, the disadvantages described do not occur.
  • the carrier is printed on the top and bottom sides. Both layers are brought together and a compound is formed between two of the print layers. When separating the label, this splits between the print layers, so that the adhesive is still covered.
  • VID labels which are used as a security label and indicate unauthorized opening of packages or the like.
  • the deformations during the cleavage process mean that the layers can not be brought over one another after separation, so that even after re-gluing the lettering or the like remain recognizable and thus the unauthorized opening is signaled.
  • the usually single-layer labels are constructed in such a way that certain portions of the label base are equipped with a primer and others are not.
  • a paint separates on removal of a bonded label from the film side and remains on the adhesive.
  • the object of the present invention is to provide a label which is easy to open, which provides a lot of surface for printing and which leaves no free adhesive surface after opening.
  • the first and / or the second printing layer are applied to the carrier, more preferably both printing layers simultaneously.
  • a protective lacquer layer is present between the support or the second printing layer and the gap-capable printing layer.
  • the weakest link within the label is represented by the splittable print layer. Between all layers of the label, the bond is stronger than the cohesion within the splittable print layer.
  • the individual layers are also designed in such a way that no cohesive fracture can be observed in them.
  • the bond strength with which the label can be adhered to the substrate is also higher than the cohesion in the splittable layer, so that the entire label does not peel off from the substrate during the opening attempt of the bonded label, but the label is actually in the splittable printing layer splits.
  • the bond strength with which the label can be adhered to the substrate is also higher than the cohesion in the splittable layer, so that the entire label does not peel off from the substrate during the opening attempt of the bonded label, but the label is actually in the splittable printing layer splits.
  • use cases are conceivable where it is possible to dispense with a column of the label, that is, the removal has higher priority.
  • the first, second and third print layers carry the information that is to be disseminated through the label. They can also consist of several individual layers, which are printed one after the other and which can have different colors. The pressure can be next to or to each other.
  • the first, second and third printed layers are partially applied.
  • the protective lacquer layer serves to protect the second print layer.
  • the Klebemassenabdeck für serves to tap the adhesive side facing the label side of the adhesive layer, since this is covered by the imprint of the layer.
  • the cleavable printing layer, the adhesive compound covering layer and, if appropriate, the protective lacquer layer are applied over the entire surface of the support.
  • the third printing layer may be printed on the cleavable printing layer, preferably it is printed on the adhesive layer, so that the Klebemassenabdeck harsh protects the third printed layer.
  • the pressure-sensitive adhesive is applied to the Klebemassenabdeck für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für adstand für abdeck
  • the label is a Klebemassen arthritis stiffening on the Klebemassenabdeck für adabdeck für adabdeck
  • optionally the third printing layer optionally the third printing layer.
  • This adhesive mass-free projecting region on the adhesive mass covering layer and optionally on the third printing layer can serve as a handle if - after the separation of the label - also the Klebemassenabdeck harsh including the third printing layer should be removed from the substrate.
  • the bond between the adhesive compound covering layer and optionally the third printing layer and the PSA is stronger than the adhesive force with which the label is glued to the substrate.
  • a non-adhesive strip can be produced on the PSA layer by partially rendering the adhesive in the region inactivated (for example by irradiation, powdering or partial neutralization).
  • a low tack streak can also be achieved by using two different adhesives within the adhesive layer.
  • a removable adhesive having low bond strength is used in the area in which the grip is to be formed.
  • a second handle may be provided on the carrier layer.
  • an area on the underside of the substrate in this area is not coated or the bond to the underlying layer is weakened. the. This area then serves as a handle for grasping and peeling off the wearer.
  • This grip can also be formed in that an additional, preferably uncoated surface is formed on the carrier.
  • the cleavable printing layer, the Klebemassenabdeck harsh and the third printing layer are partially applied so that PSA is in contact at least in an edge region of the label with the overlying the cleavable printing layer.
  • the splittable layer When the label is opened, the splittable layer, while no cohesive failure is observed in the adhesive layer, does not split even in the region in which the adhesive with the layer above the cleavable printing layer is in Contact stands. This area rather forms a hinge, over which the label can be opened and closed.
  • this adhesive tape is 5 mm wide in the edge region of the label.
  • the hinge preferably lies opposite the adhesive-mass-free area forming a grip and / or the grip formed on the support.
  • a second recess is additionally present in the cleavable printing layer, in the adhesive mass covering layer and in the third printing layer so that the pressure-sensitive adhesive is in contact with the layer located above the cleavable printing layer in a second area.
  • This recess may be cylindrical (for example, with an oval base), in particular circular cylindrical and should have a small area compared to the total area of the label.
  • This recess is in relation to the described strip of adhesive, which forms the hinge, as close as possible to the opposite edge of the label, because this area allows a reversible bonding of the opened label, so that a previously opened label can be closed again at this point and a "fluttering" and kinking of the label can be prevented.
  • the label is additionally provided with an additional and variable printing by means of a further printing method, such as, for example, an inkjet printing (preferred), a laser marking or a thermal transfer printing.
  • a further printing method such as, for example, an inkjet printing (preferred), a laser marking or a thermal transfer printing.
  • it is alphabetic, numeric or alphanumeric codes, logistics codes, EAN codes, bar codes, etc., to use the inventive label for competitions, pricing, logistics purposes, etc. can.
  • This printing is integrated in particular in the second or particularly preferred in the third printing layer, so that it is not immediately visible, but only after the label has been opened.
  • the printing can also be applied to the second or third printing layer.
  • the labels according to the invention may be circular, for example with a diameter of 30 mm, oval, polygonal or rectangular and square, the latter moreover also having rounded corners.
  • the outer shape of the labels can be varied almost unrestrictedly adapted to the respective application.
  • films in particular monoaxially and biaxially oriented films based on polyolefins, then films based on stretched polyethylene or stretched copolymers containing ethylene and / or polypropylene units, optionally also PVC films, PET films, films Base of vinyl polymers, polyamides, polyesters, polyacetals, polycarbonates
  • Biaxially oriented polypropylene is characterized by its very high tensile strength and low elongation.
  • Preferred for the production of the labels according to the invention are biaxially oriented films based on polypropylene.
  • the thicknesses of the biaxially oriented films based on polypropylene are preferably between 20 and 100 ⁇ m, in particular between 25 and 75 ⁇ m, very particularly between 30 and 65 ⁇ m.
  • Biaxially oriented films based on polypropylene can be produced by blown film extrusion or by means of conventional flat film systems. Biaxially stretched films are produced in one or more layers. In the case of multilayer films, the thickness and composition of the different layers may be the same, but also different thicknesses and compositions are known.
  • Suitable for the labels according to the invention are monolayer, biaxially or monoaxially stretched films or multilayer, biaxial or monoaxial films based on polypropylene, which have a sufficiently strong bond between the layers, since delamination of the layers during use is disadvantageous.
  • Films based on rigid PVC are used for the production of labels as well as films based on soft PVC.
  • films based on rigid PVC can be used.
  • the thicknesses of the films are preferably between 20 and 100 ⁇ m, in particular between 25 and 65 ⁇ m, very particularly between 30 and 60 ⁇ m.
  • Polyester-based films for example polyethylene terephthalate, are also known and can also be used to make the labels of the invention.
  • the thicknesses of the films based on PET are between 20 and 100 ⁇ m, in particular between 25 and 65 ⁇ m, very particularly between 30 and 60 ⁇ m.
  • the films used are preferably nontransparent. They can be dyed, foamed or unfoamed in any way.
  • the film can be a BOPP film from EXXON which is 60 ZH 247 with a thickness of 60 ⁇ m, white and foamed.
  • the support and also the adhesive layer can be transparent, in such a way that each layer preferably has a transmission of greater than 60%, in particular a transmission greater than 90% at a wavelength of 350 to 1150 nm.
  • the labels according to the invention may contain, as adhesives, a pressure-sensitive adhesive based on natural rubber, PUR, acrylates or styrene-isoprene-styrene block copolymers.
  • a pressure sensitive adhesive is a viscoelastic composition that remains permanently tacky and tacky at room temperature in a dry state. The bonding takes place by light pressure immediately on almost all substrates.
  • Suitable masses are for example in the " Handbook of pressure-sensitive adhesive technology, second edition, edited by Donatas Satas, Van Nostrand Reinhold, New York, 1989 described.
  • the self-adhesive composition used is in particular a commercially available pressure-sensitive adhesive composition based on PUR, acrylate or rubber, preferably a UV-crosslinkable hot-melt pressure-sensitive adhesive mixed with additives and resins.
  • the Adhesive Novarad RC 21151 from Novamelt is an example.
  • an acrylate hot melt base which has a K value of at least 20, in particular greater than 30, obtainable by concentrating a solution of such a composition into a system which can be processed as a hotmelt.
  • benzoin derivatives may be copolymerized, such as benzoin acrylate or benzoin methacrylate, acrylic acid or methacrylic acid ester. Such benzoin derivatives are in the EP 0 578 151 A1 described.
  • the adhesive on Acrylathotmeltbasis can also be chemically crosslinked.
  • An adhesive which is suitable is a low molecular weight acrylate hot melt pressure-sensitive adhesive, such as that marketed under the name acResin UV or Acronal®, in particular Acronal DS 3458, by BASF.
  • This adhesive with a low K value obtains its application-oriented properties through a final radiation-induced crosslinking.
  • the adhesive application is preferably between 5.0 and 50.0 g / m 2 , more preferably between 10.0 and 30.0 g / m 2 and particularly preferably between 15.0 and 25.0 g / m 2 .
  • the latter corresponds to a thickness between 15 and 25 microns.
  • the application of the adhesive takes place in the curtain coating process.
  • the release film used may be a PET film which is siliconized on one or both sides, preferably with a thickness of 30 .mu.m, for example the silicone film Silphan S30 M74F from Siliconature.
  • the individual print layers and the protective lacquer layer can be applied in any printing process such as (UV) flexo, offset or screen printing.
  • the first, second and third printing layers can also consist of several successive printed layers.
  • Each individual layer preferably has a thickness of between 1 and 2 .mu.m, so that the maximum total thickness of the respective print layer-if several layers are printed on one another-results from the addition of the thicknesses of the layers forming the print layer.
  • UV-curing flexographic printing inks are preferably selected for the three printing layers, for example from the Flint series UFZXXXXX from Flint Group Switzerland AG.
  • "XXXXX” encrypts the color, for example, UFZ50082 (cyan), UFZ30082 (magenta), UFZ10082 (yellow), UFZ80082 (black).
  • colorants in the UV-curing flexographic printing inks find organic pigments (selected in the fastness to requirements), basic dyes (mainly for commercial printing), gold bronze (brass) and silver bronzes (aluminum), pearlescent pigments, titanium dioxide, carbon blacks, Zapon dyes ® (metal complex dyes ) Use.
  • the binders used are cellulose derivatives such as cellulose nitrate, ethylcellulose, ethylhydroxyethylcellulose or cellulose acetopropionate or vinyl polymers such as polyvinyl butyrals, PVC copolymers, polyacrylates and methacrylates, styrene / maleic acid copolymers or polyamide resins or polyesters or polyurethanes, or ketone resins or maleate resins or shellac.
  • cellulose derivatives such as cellulose nitrate, ethylcellulose, ethylhydroxyethylcellulose or cellulose acetopropionate or vinyl polymers such as polyvinyl butyrals, PVC copolymers, polyacrylates and methacrylates, styrene / maleic acid copolymers or polyamide resins or polyesters or polyurethanes, or ketone resins or maleate resins or shellac.
  • alcohols such as ethanol, propan-2-ol, propan-1-ol are glycol ethers such as methoxypropanol, ethoxypropanol, propylene glycol, dipropylene glycol monomethyl ether, esters such as ethyl acetate, isopropyl acetate, propyl acetate, methoxy and ethoxypropyl acetate, ketones for special cases such as butane-2 -on, 4-methylpentan-2-one, acetone, cyclohexanone or aliphatic hydrocarbons such as gasolines, mostly used in conjunction with cosolvent polyamide resins.
  • glycol ethers such as methoxypropanol, ethoxypropanol, propylene glycol, dipropylene glycol monomethyl ether
  • esters such as ethyl acetate, isopropyl acetate, propyl acetate, methoxy and ethoxypropyl acetate
  • additives are used, for example plasticizers, waxes (polyethylene and polypropylene waxes), lubricants (silicones, fatty acid amides), wetting agents or dispersants.
  • plasticizers for example waxes, waxes (polyethylene and polypropylene waxes), lubricants (silicones, fatty acid amides), wetting agents or dispersants.
  • lubricants silicones, fatty acid amides
  • wetting agents or dispersants wetting agents or dispersants.
  • fungicides and bactericides are also used.
  • the first print layer reflects the customer's design wishes.
  • the first print layer forms the image that the customer sees when looking at the label.
  • the imprint or the reproduction of the design can be implemented in a printing press in many ways.
  • the second print layer is - as the third print layer - visible only after separation of the label.
  • All three layers are preferably made by the same process using the same printing inks (optionally with different hue).
  • the printing can be done, for example, in gravure printing using solvent inks or offset printing process using appropriate offset inks.
  • paint suppliers include companies such as Sun Chemical, Siegwerk or Stehlin + Hostag.
  • the flexographic printing process using UV-curable ink systems of the UV ink series "Flexocure Sigma" of the Flint Group is applied.
  • the ink application per ink is determined by the scoop volume of the anilox roller used and is between nominally 3.0 and 12.0 cm 3 of ink per m 2 of substrate.
  • anilox rollers with a nominal scoop volume between 3.0 and 8.0 cm 3 / m 2 are preferably used.
  • Still further preferred screen rollers have a cell volume between 4.0 and 5.0 cm 3 / m 2.
  • the protective lacquer layer can also be a UV-curing flexo color such as those from the Flint series UFZXXXXX the company Flint Group Switzerland AG be selected, for example UFZ00061 (transparent white).
  • the effective ink application is here preferably between 1.0 and 4.0 cm 3 / m 2 , more preferably between 2.0 and 3.0 cm 3 / m 2 .
  • the printed on the basis of the design specification partly not fully printed second printing layer with a uniformly homogeneous, full-surface and preferably transparent protective lacquer layer can be overprinted.
  • a uniformly homogeneous, full-surface and preferably transparent protective lacquer layer can be overprinted.
  • the essential feature of the label is based on the use of a splittable ink with "separating" properties. Radical or cationic UV-based silicone-based ink systems are used.
  • This layer is also transparent according to an advantageous embodiment.
  • a water-based mixture consisting of an aqueous flexo ink such as Flint SOP00090, which is additionally blended with a thickener (for example HAW00104 from Flint Group Switzerland AG) and a fluorescent raw material (for example SQH00100 from Flint Group Switzerland AG).
  • a thickener for example HAW00104 from Flint Group Switzerland AG
  • a fluorescent raw material for example SQH00100 from Flint Group Switzerland AG.
  • the order of the water-based mixture also takes place in the flexographic printing process with a preferred, effective ink application between 1.0 and 8.0 cm 3 / m 2 and a particularly preferred order volume between 3.0 and 4.0 cm 3 / m 2 .
  • the release coating mixture should be constantly stirred during processing.
  • the drying of the aqueous release coating is carried out thermally at drying temperatures between 40 to 100 ° C, preferably 60 to 80 ° C.
  • All of the raw materials used for the release coating are preferably from the company Flint Group Switzerland AG.
  • the mixture consists of 80.0 to 98.0% by weight of a UV-curing flexographic ink such as "SOP00090", 1.0 to 8.0% by weight of a thickener such as, for example “ HAW00104 "and 1.0 to 12.0 wt .-% of a fluorescent additive such as” SOH00100 ", more preferably from 90.0 to 95.0 wt .-% of the flexographic ink, 2.0 to 4.0 wt. -% of the thickener and 3.0 to 6.0 wt .-% of the fluorescent additive.
  • a UV-curing flexographic ink such as "SOP00090”
  • a thickener such as, for example " HAW00104 "and 1.0 to 12.0 wt .-% of a fluorescent additive such as” SOH00100 ", more preferably from 90.0 to 95.0 wt .-% of the flexographic ink, 2.0 to 4.0 wt. -% of the thickener and 3.0 to
  • a thickener like "HAW00104" increases the viscosity of the aqueous paint system.
  • aqueous ink systems also tend to coalesce on carefully physically pretreated (polyolefin) films, that is, the paint is repelled from some areas of the film and coalesces in other areas.
  • so-called "pinholes” form on the printing substrate after the application of the printing ink; the ink is not present in a homogeneous, coherent film.
  • the color is restless" (mottling).
  • a fluorescent raw material such as "SQH00100” is added to the release lacquer mixture.
  • the machine operator has the ability to control using a black light lamp, the accuracy of fit of the release coating and readjust if necessary.
  • the Klebemassenabdeck harsh serves for perfect neutralization of the adhesive after separation of the label.
  • the label separates at the splittable printing layer, that is, a part of the splittable printing layer remains at the upper part of the label, a part at the lower part. Since the third printing layer is usually applied partially and the splittable printing layer optionally separates so that it remains only partially at the bottom of the label, there is a risk that the adhesive layer is not completely covered and thus at least partially still sticky, which is more likely is undesirable.
  • a printing ink for particularly high paint application is used as neutralization printing.
  • the paint is applied by screen printing.
  • RSS screens plate thickness 66 microns, mesh 290 mesh / inch, 21% open mesh area, mesh size 40 microns, ink layer thickness 10 microns, resolution line width 150 microns
  • HM sieves plate thickness 57 ⁇ m, mesh size 275 mesh / inch, open screen area 21%, mesh size 40 ⁇ m, ink layer thickness 7 ⁇ m, resolution line width 130 ⁇ m
  • this UV flexo ink In order to be able to process this UV flexo ink by screen printing, the mixing of the ink with 0.5 to 3.0 wt .-%, particularly preferably 1.0 to 2.0 wt .-% of a silicone-based leveling agent such as the raw material "UAS00100" of the Flint Group Switzerland AG necessary.
  • a silicone-based leveling agent such as the raw material "UAS00100" of the Flint Group Switzerland AG
  • the accurate printing of the label is also of crucial importance when printing the adhesive compound covering layer.
  • the color is additionally 0.5 to 3.0 wt .-%, particularly preferably 1.0 to 2.0 wt .-% with a UV Blended suitable fluorescent raw material such as "UAA00105" of Flint Group Switzerland AG.
  • IR-active luminescent pigments are also known.
  • systems with UV fluorescence are xanthenes, coumarins, naphthalimides, etc., which are sometimes referred to in the literature under the generic term “organic phosphors” or “optical brighteners”. The addition of a few percent of the relevant phosphors is sufficient.
  • formulations with RADGLO® pigments from Radiant Color N.V./Holland or Lumilux® CD pigments from Riedel-de-Haen can be used.
  • inorganic phosphors are suitable.
  • photoluminescent substances, especially with the emission of light in the yellow range metal sulfides and oxides, usually in combination with suitable activators, have proved favorable. These are available, for example, under the trade name Lumilux® N or as luminescent pigments improved in terms of stability, luminosity and persistence under the trade name LumiNova® from Nemoto / Japan.
  • thermochromic pigments which reversibly change color when the temperature changes.
  • electrically conductive colors is possible.
  • the color pigments care must be taken that they are sufficiently stable for the production process of the label (for example adhesive coating) and do not change irreversibly in the process conditions (optionally thermal drying, electron beam or UV curing).
  • the label according to the invention combines many advantages.
  • the label offers the novel possibility of providing the customer with a label in which up to three pages can be provided with an individual text or the like, despite a single-layer carrier material.
  • the special product structure enables the two sides of the carrier material (substrate) to be printed with customized information. It is advantageous and novel that additional information can be applied between the splittable layer and the adhesive in the form of the third layer.
  • the substrate to which the label is adhered acts as a carrier for the adhesive remaining thereon with the additional information.
  • the label consists of only one carrier layer, preferably a film layer, an adhesive layer and various print layers, the material thickness is significantly thinner compared to the conventional labels. This advantage makes it much easier and trouble-free to process the label material with the classic labeling machines.
  • the label applied to the substrate can be removed without residue and without pressure-sensitive adhesive properties.
  • the carrier is usually placed in a reversible composite with a self-adhesive material. This results in a relatively stiff and possibly difficult to process material.
  • the new label consists of only one carrier layer (usually white, foamed BOPP film) on which the adhesive is directly and reversibly applied.
  • the label can be optimally used on cardboard or foil packaging.
  • the multilayer label 10 has a carrier 2, the upper side of which is printed with a first print layer 1.
  • the first print layer 1 consists of a total of three-ply imprint 11, 12, 13, wherein each layer 11, 12, 13 is partially applied, partially also one above the other, and has a different color. According to the illustrated embodiment, the first printing layer 1 gives a three-color image.
  • a second print layer 3 which is also partially printed, further information that is accessible to the customer after separating the label 10. Since the second printing layer 2 consists of only one layer, the imprint is monochrome.
  • the carrier 2 or the second printing layer 3 are covered with a protective lacquer layer 4 applied over the entire surface.
  • cleavable printing layer 5 is applied over the entire surface, wherein the force to induce the cohesive failure within the cleavable printing layer 5 is smaller than the forces with which the cleavable printing layer 5 is connected to the overlying and the underlying layer 4 and 7 , This force is also smaller than any force associated with each of two superposed layers within the label.
  • a third printing layer 6 is provided, which is also partially printed. This information is accessible to the customer only after separation of the label 10. Since the third printing layer 6 also consists of only one layer, the imprint is again monochrome.
  • the third printing layer 6 is printed onto the layer of adhesive layer 8, so that the third printing layer 6 is protected by the overlying adhesive layer covering layer 7.
  • the adhesive masking layer 7 is applied over the entire surface of the label 10. Furthermore, the adhesive compound covering layer 7 completely covers the adhesive layer 8 as well as the third printing layer 6, which in turn is covered with a release film layer 9, which is removed for bonding the label 10 to the substrate or substrate.
  • the PSA layer 8 is not applied over the entire surface, but instead on the adhesive compound cover layer 7 such that in an edge region of the label 10 there is a stick-free strip 14 on the adhesive-mass covering layer 7.
  • This adhesive mass-free projecting region 14 on the Klebemassenabdeck Mrs 7 can serve as a handle if - after the separation of the label 10 - and the Klebemassenabdeck harshness
  • FIG. 2 shows the multilayer label 10 according to FIG. 1 after the separation.
  • the splittable printing layer 5 has split into two layers 5a, 5b, which cover the protective lacquer layer 4 as well as the third printed layer 6 and the adhesive mass covering layer 7.
  • both the second printing layer 3 and the third printing layer 6 become legible for the customer.
  • FIG. 3 shows the multilayer label 10 in another preferred embodiment in the lateral section.
  • the structure of the label 10 corresponds to that of the FIG. 1 is known.
  • the cleavable printing layer 5, the adhesive compound covering layer 7 and the third printing layer 6 are absent in an edge region of the label 10, namely the adhesive mass-free region 14, so that the PSA layer 8 in this edge region of the label 10 with the layer above the cleavable printing layer 5 4 is in contact.
  • the hinge can be separated.
  • FIG. 5 shows the multilayer label 10 in another preferred embodiment in the lateral section.
  • the structure of the label 10 corresponds to that of the FIG. 3 is known.
  • an additional second recess 82 is present, so that the pressure-sensitive adhesive 8 in a second region 82 with the above the splittable Print layer 5 lying layer 4 is in contact.
  • This recess 82 is circular cylindrical.
  • the recess 82 is located in the vicinity of the opposite edge of the label 10, ie in the vicinity of the adhesive mass-free region 14 with respect to the described strip 81 adhesive which forms the hinge.
  • this area 82 allows a reversible bonding of the opened label 10 by the label 10 is folded back so that the region 82 with the protective lacquer layer 4 or the upper layer 5a of the fissile pressure layer 5 comes into contact and exerts an adhesive effect.
  • the area 82 has a small area compared to the total area of the label 10.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Laminated Bodies (AREA)
EP10171546.4A 2009-08-04 2010-08-02 Etiquette multicouche Not-in-force EP2282303B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10171546T PL2282303T3 (pl) 2009-08-04 2010-08-02 Etykieta wielowarstwowa

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102009035931A DE102009035931A1 (de) 2009-08-04 2009-08-04 Mehrschichtiges Etikett

Publications (3)

Publication Number Publication Date
EP2282303A2 true EP2282303A2 (fr) 2011-02-09
EP2282303A3 EP2282303A3 (fr) 2012-07-25
EP2282303B1 EP2282303B1 (fr) 2015-09-30

Family

ID=43127176

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10171546.4A Not-in-force EP2282303B1 (fr) 2009-08-04 2010-08-02 Etiquette multicouche

Country Status (4)

Country Link
EP (1) EP2282303B1 (fr)
DE (1) DE102009035931A1 (fr)
ES (1) ES2558139T3 (fr)
PL (1) PL2282303T3 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2653304B1 (fr) * 2012-04-16 2018-08-15 Linhardt GmbH & Co. KG Matériau laminé pour l'équipement de produits
US10377117B2 (en) 2013-09-25 2019-08-13 Avery Dennison Corporation Tamper evident security labels
WO2020219029A1 (fr) * 2019-04-23 2020-10-29 Bemis Company, Inc. Procédé de production de stratifiés exempts d'adhésif
CN113487960A (zh) * 2021-05-26 2021-10-08 丝艾工业科技(海安)有限公司 一种易清理的防伪标签
EP4202889A1 (fr) * 2021-12-23 2023-06-28 SCRIBOS GmbH Étiquette d'étanchéité, procédé de fabrication d'une étiquette d'étanchéité et utilisation

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011120830A1 (de) 2011-12-13 2013-06-13 Baumer Hhs Gmbh Verfahren zur Herstellung eines Haftklebeprodukts mit unterschiedlichen Hafteigenschaften
DE102021134470A1 (de) 2021-12-23 2023-06-29 Scribos Gmbh Versiegelungsetikett, Verfahren zur Herstellung eines Versiegelungsetiketts sowie Verwendung

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0578151A1 (fr) 1992-07-08 1994-01-12 Beiersdorf Aktiengesellschaft Adhésifs thermofusibles sensibles à la pression pour des produits médicaux
DE4313008C1 (de) 1993-04-21 1994-11-10 Beiersdorf Ag Selbstklebemasse auf Acrylathotmelt-Basis, Verfahren zu deren Herstellung und deren Verwendung
DE19912711A1 (de) 1999-03-20 2000-09-21 Hoernlein Reinhard Gmbh Magnettür, insbesondere für Möbel
DE19912710A1 (de) 1999-03-20 2000-09-28 Wella Ag Kunststoffflasche mit einer aufprellbaren, wieder lösbaren Verschlußkappe
DE19912709A1 (de) 1999-03-20 2000-10-05 Koenig & Bauer Ag Übergabetrommel mit schwenkbaren Trommelkappen
DE10022002A1 (de) 1999-12-29 2001-07-12 Beiersdorf Ag Sicherheitsklebeband zum Nachweis des unbefugten Öffnens einer Verpackung

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19832990B4 (de) * 1998-07-22 2006-04-20 Schreiner Etiketten Und Selbstklebetechnik Gmbh & Co. Etikett und Verfahren zum Verdecken von Informationen
US6416857B1 (en) * 2000-10-25 2002-07-09 3M Innovative Properties Company Tamper indicating device
DE10245430A1 (de) * 2002-09-27 2004-04-08 Tesa Ag Originalitätssiegel
DE10316310B4 (de) * 2003-04-08 2005-08-04 Witte Plusprint Druckmedien Gmbh Aufkleber, insbesondere Warnaufkleber
DE102005016261A1 (de) * 2005-04-08 2006-10-12 Schreiner Group Gmbh & Co. Kg Transponderetikett
DE202007000228U1 (de) * 2007-01-08 2007-03-15 Trautwein Security Gmbh & Co Etikett, Siegel, Klebeband o.dgl.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0578151A1 (fr) 1992-07-08 1994-01-12 Beiersdorf Aktiengesellschaft Adhésifs thermofusibles sensibles à la pression pour des produits médicaux
DE4313008C1 (de) 1993-04-21 1994-11-10 Beiersdorf Ag Selbstklebemasse auf Acrylathotmelt-Basis, Verfahren zu deren Herstellung und deren Verwendung
DE19912711A1 (de) 1999-03-20 2000-09-21 Hoernlein Reinhard Gmbh Magnettür, insbesondere für Möbel
DE19912710A1 (de) 1999-03-20 2000-09-28 Wella Ag Kunststoffflasche mit einer aufprellbaren, wieder lösbaren Verschlußkappe
DE19912709A1 (de) 1999-03-20 2000-10-05 Koenig & Bauer Ag Übergabetrommel mit schwenkbaren Trommelkappen
DE10022002A1 (de) 1999-12-29 2001-07-12 Beiersdorf Ag Sicherheitsklebeband zum Nachweis des unbefugten Öffnens einer Verpackung

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2653304B1 (fr) * 2012-04-16 2018-08-15 Linhardt GmbH & Co. KG Matériau laminé pour l'équipement de produits
US10377117B2 (en) 2013-09-25 2019-08-13 Avery Dennison Corporation Tamper evident security labels
US10968368B2 (en) 2013-09-25 2021-04-06 Avery Dennison Corporation Tamper evident security labels
WO2020219029A1 (fr) * 2019-04-23 2020-10-29 Bemis Company, Inc. Procédé de production de stratifiés exempts d'adhésif
CN113487960A (zh) * 2021-05-26 2021-10-08 丝艾工业科技(海安)有限公司 一种易清理的防伪标签
CN113487960B (zh) * 2021-05-26 2023-10-27 丝艾工业科技(海安)有限公司 一种易清理的防伪标签
EP4202889A1 (fr) * 2021-12-23 2023-06-28 SCRIBOS GmbH Étiquette d'étanchéité, procédé de fabrication d'une étiquette d'étanchéité et utilisation

Also Published As

Publication number Publication date
EP2282303A3 (fr) 2012-07-25
DE102009035931A1 (de) 2011-02-10
PL2282303T3 (pl) 2016-04-29
EP2282303B1 (fr) 2015-09-30
ES2558139T3 (es) 2016-02-02

Similar Documents

Publication Publication Date Title
EP2282303B1 (fr) Etiquette multicouche
DE69632867T2 (de) Wasseraktivierbare polymere und bildübertragungstechnik
EP1818893B1 (fr) Etiquette auto-adhésive, méthode de fabrication et son utilisation
EP1113058B1 (fr) Ruban adhésif inviolable pour emballage
EP1297090B1 (fr) Bande adhesive de securite permettant de detecter l'ouverture non autorisee d'un emballage
DE1671531B1 (de) Abziehbild fuer Kunststoffbehaelter
DE19963709A1 (de) Sicherheitsklebeband zum Nachweis des unbefugten Öffnens einer Verpackung
EP1297089A1 (fr) Bande adhesive de securite destinee a deceler l'ouverture non autorisee d'un emballage
EP3743480B1 (fr) Film de séparation imprimé et muni d'un revêtement
DE60005494T2 (de) Etikettmehrschichtenverbund
EP1296306A2 (fr) Utilisation d'une bande adhesive de securité pour révéler l'ouverture non-authorisée d'un emballage postal
EP1666554B1 (fr) Bande de sécurité pour détecter l'ouverture non autorisée d'emballage
WO2009065630A1 (fr) Feuille pouvant être imprimée par laser
EP3106561A1 (fr) Étiquette de securite avec verification de la manipulation
EP1297087B1 (fr) Bande adhesive de securite destinee a deceler l'ouverture non autorisee d'un emballage
DE10245430A1 (de) Originalitätssiegel
EP1926791A1 (fr) Ruban auto-adhesif
EP1520690B1 (fr) pellicule d'adhesion
DE102006031189B4 (de) Verfahren zur Herstellung von selbstklebenden Folienprodukten wie Aufklebern, Aufklebeetiketten, selbstklebenden Sicherheitskennzeichnungen, selbstklebenden Folien und dergleichen
DE102008057456A1 (de) Sicherheitsetikett
DE4327995C2 (de) Verfahren zur Aufbringung einer variierbaren Kennzeichnung auf ein Substrat
DE10140491A1 (de) Selbstklebendes Sicherheitsetikett
EP3726507B1 (fr) Feuille de scellement
EP4202889A1 (fr) Étiquette d'étanchéité, procédé de fabrication d'une étiquette d'étanchéité et utilisation
DE102010002481B4 (de) Originalitätssiegel

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME RS

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

RIC1 Information provided on ipc code assigned before grant

Ipc: G09F 3/10 20060101ALI20120614BHEP

Ipc: G09F 3/02 20060101AFI20120614BHEP

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME RS

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: BANDFIX AG

17P Request for examination filed

Effective date: 20130121

17Q First examination report despatched

Effective date: 20140410

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20150423

RIN1 Information on inventor provided before grant (corrected)

Inventor name: KNECHTLI, JAKOB

Inventor name: GALLE, ANDRE

Inventor name: SCHEUBNER, THOMAS

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: CCL LABEL AG

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 752831

Country of ref document: AT

Kind code of ref document: T

Effective date: 20151015

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502010010372

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: FREI PATENTANWALTSBUERO AG, CH

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20151230

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20151231

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2558139

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20160202

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160130

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160201

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502010010372

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

26N No opposition filed

Effective date: 20160701

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20160819

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20160825

Year of fee payment: 7

Ref country code: GB

Payment date: 20160819

Year of fee payment: 7

Ref country code: DE

Payment date: 20160822

Year of fee payment: 7

Ref country code: CH

Payment date: 20160802

Year of fee payment: 7

Ref country code: IE

Payment date: 20160823

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20160727

Year of fee payment: 7

Ref country code: AT

Payment date: 20160822

Year of fee payment: 7

Ref country code: FR

Payment date: 20160822

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160831

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20160810

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160802

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502010010372

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20170901

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 752831

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170802

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20170802

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20180430

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20100802

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170802

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170901

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170802

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170802

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180301

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170802

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20181029

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170802

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170803