EP1818893B1 - Etiquette auto-adhésive, méthode de fabrication et son utilisation - Google Patents

Etiquette auto-adhésive, méthode de fabrication et son utilisation Download PDF

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Publication number
EP1818893B1
EP1818893B1 EP07108135A EP07108135A EP1818893B1 EP 1818893 B1 EP1818893 B1 EP 1818893B1 EP 07108135 A EP07108135 A EP 07108135A EP 07108135 A EP07108135 A EP 07108135A EP 1818893 B1 EP1818893 B1 EP 1818893B1
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EP
European Patent Office
Prior art keywords
printing
adhesive
print substrate
web
self
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP07108135A
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German (de)
English (en)
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EP1818893A1 (fr
Inventor
Thomas Scheubner
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CCL Label AG
Original Assignee
Tesa SE
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Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y10S428/915—Fraud or tamper detecting
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/916—Fraud or tamper detecting
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1476—Release layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1486—Ornamental, decorative, pattern, or indicia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers

Definitions

  • the invention relates to self-adhesive finished labels, processes for the preparation of these and their use.
  • Labels usually consist of several layers, for example a printing material on which a self-adhesive coating is applied, as well as a carrier material.
  • the carrier material is usually provided with a release layer of silicone. It has the task to carry the actual label during manufacture and protect its adhesive layer from contamination, so that it can undergo processing processes such as printing, punching, cutting, perforating, etc.
  • the siliconized material serves as a punching pad.
  • support materials are release papers or different release films to choose from.
  • a common carrier material for self-adhesive labels are calendered kraft papers.
  • coated papers are also used.
  • plastic-coated paper is also used.
  • special products such as self-copying carrier papers are available.
  • Plastic films are chosen primarily as a carrier material, if the later application makes special demands. If a self-adhesive label, for example, imitate the appearance of a direct-printed container (no-label look), adhesive composite manufacturers often recommend siliconized films that are highly transparent and extremely smooth.
  • silicone paper As a basis for silicone paper can serve pulp that is bleached either conventional or chlorine-free. Release papers are available in different colors. They are used in different basis weights and strengths. The palette ranges from very thin papers to cardboard thickness materials.
  • release liners are also tear resistance, punching resistance, tensile strength, dimensional stability, etc. They must be tailored to the requirements imposed by processing processes and the manual or automatic dispensing of the labels.
  • the separation behavior can be influenced by the type of silicone coating and is thus adjustable to different purposes. This plays an important role especially in the further processing of self-adhesive labels with automatic dispensers. A trouble-free and quick donating makes the self-adhesive label economically superior.
  • a special form among the self-adhesive labels are the so-called carrierless systems. They do not require any siliconized release papers or foils. In this label form is considered a particular advantage that no carrier material is obtained as waste after application. Due to the lack of a carrier, however, the selection in the labels is limited to rectangular shapes, since the punching without a carrier is not possible. The cutting of the self-adhesive label takes place only in the labeling.
  • Self-adhesive labels are used in a wide range of applications and meet an extraordinarily wide range of different requirements. This is made possible by a selection of materials used in the label industry diverse is like in hardly any other industry. For processing therefore also means of production are necessary, which are similarly versatile in their possibilities. This explains why all processes available in practice are used for label production. A key role in this context is the printing of self-adhesive labels.
  • the following overview of the various printing technologies with a description of the respective basic principle makes it easier to understand which possibilities are available in conventional printing processes such as letterpress, flexographic, offset, screen or gravure printing as well as in non-impact printing techniques or digital processes.
  • Book printing can be seen as the classic method of duplication in print. It was already used in the Middle Ages - as the name implies - mainly for the production of books.
  • a printing form also called a printing substrate, which consists of printing and non-printing parts.
  • the printing plate is often referred to as a cliché.
  • photopolymer printing plates have almost completely replaced the etched or electroformed clichés of the past. Because the raised areas of the cliché represent the printing surfaces, the letterpress printing is one of the high-pressure methods.
  • the coloring of the printed parts is done via an inking unit, which consists of a series of rollers. They create a thin film of color and thus color the raised areas of the cliché. From the printing form there is a direct transfer of color under a certain contact pressure on the substrate.
  • Another high-pressure process is flexographic printing.
  • a difference to the book printing consists in the printing form, which is much more elastic. As a result, a smaller contact pressure is required to transfer the motif directly from the printing plate to the substrate. This is an important reason for the wide range of materials that can be printed using the flexographic printing process.
  • the processes differ by the colors, which have a rather viscous consistency in letterpress printing, while flexographic inks are much thinner.
  • the inking units have a correspondingly simple structure.
  • the coloring of the Flexoklischees is done via anilox rollers. They have recesses in the roll surface, which transport a defined amount of color. They are filled either by a dipping roller, which rotates in a paint tray, or by a paint chamber, which is employed by the anilox roller.
  • a special feature of the flexographic printing process is the printing with radiation-curing inks. While solvent-based or water-based inks dry physically, in UV flexographic printing, polymerization of the inks or lacquers is achieved through exposure to UV rays. The curing reaction takes place in fractions of a second. This reduces process-typical phenomena of flexographic printing, which arise from the elastic printing form, such as pinch edges or high dot gain.
  • Offset printing is one of the planographic printing processes. Printing and non-printing surfaces are almost on one level.
  • the separation of the printing and non-printing surfaces is based on the principle that fat and water repel each other.
  • the printing areas of a metallic offset printing plate are prepared so that they are hydrophobic (water repellent) and thus accept the greasy printing ink. The remaining areas remain hydrophilic (water-friendly).
  • the offset plate is supplied with both water and color. For coloring an inking unit, which is very similar to a letterpress press. The wetting of the plate surface with water is done with the help of a dampening unit.
  • a proper adjustment of the color-water balance gives a sharp separation of the printing and non-printing surfaces. This allows a pinpoint print image and is especially important for raster gradients or very fine elements.
  • In the waterless offset printing is dispensed with the dampening of the plates.
  • In order to prevent coloring of the non-printing parts on the offset plate they are coated with a color-repellent silicone layer, which is removed in the development of the plates in the places that will later color.
  • the printing parts are slightly lower in waterless offset printing. In practice, it is thus possible to achieve a very high color density and, at the same time, to print a very sharp and sharp-edged dot.
  • Screen printing subsumes the processes of flat screen printing and rotary screen printing.
  • Screen printing owes its name to the principle of the process, which is to press paint through a fine mesh screen onto the material to be printed.
  • a printing form is a mesh fabric made of metal, textile or plastic threads.
  • the fabric stitches are sealed with a copyable coating. After appropriate exposure, this layer is washed out at the unexposed areas.
  • the ink is pressed onto the substrate with the aid of a squeegee through these open stitches.
  • a major advantage of screen printing is the high layer thickness in which the paint can be applied. This opens up the use of a wide range of special colors or special lacquers in screen printing.
  • screen printing is used in two different process variants. The differences arise from the structure of the printing form.
  • flat screen printing it is formed by a frame that is covered with a fabric.
  • the label web is fed under the flat screen for printing, stopped and printed. Subsequently, the web is transported on to a printed image, so that the next printing process can take place.
  • a stainless steel mesh is used, which is formed into a hollow cylinder. In the interior of this cylinder, the ink supply and the squeegee are arranged. Due to the rotative structure, a continuous printing process is possible with this method.
  • DE G 81 30 861 describes a multi-layer label in which a different colored cover layer is removed by the laser beam and thus allows the color contrast to the next layer labels of high quality and readability.
  • This lettering is a type of engraving, which eliminates the manipulation possibilities as with traditional printing with inks and inks.
  • the label film is set by the raw materials used and the manufacturing process so brittle that a removal of the glued labels from the adhesive substrates is only possible with destruction.
  • JP 08/328474 A1 describes a textile clothing label, which is printed on the upper side with a transparent, fluorescent color, woven design and print should be approximately congruent.
  • a similar superficial printing with UV-active, photochromatic colors is in WO 88/01288 A1 described; however, to protect the chemicals of this paint layer, an additional protective layer against oxygen and water is necessary.
  • FR 2,734,655 A1 In the case of checks, security marking is achieved by partially printing under an IR-transmissive layer which is invisible in the visible wavelength range, but is machine-readable / -identifiable with special IR light.
  • labels are produced in such a way that they are printed directly on the substrate (paper or film, for example 60 ⁇ m PP or 100 ⁇ m PE) (frontal printing).
  • a raw film for example, a 60 micron PP film
  • the coating is done with adhesive
  • the carrier is laminated and the labels are punched.
  • the printing is on these labels on the side facing the adhesive.
  • labels are represented on the market with a so-called intermediate pressure.
  • a 30 ⁇ m laminating film is printed in mirror image, laminated together in a suitable laminating station with a correspondingly thin (for example 30 ⁇ m PP) self-adhesive material, and then the composite is punched.
  • This type of label is usually made in a single operation. With this method one can achieve an excellent silver print (usually gravure).
  • the entire printing on the inner side of the laminating film (liner pressure).
  • the print is not plastic, it shows no relief effect, which is desired for certain applications. It is thus only the laminating foil printed on the inside page, without any additional printing on the top of the label.
  • EP 0 404 402 A2 is a label of a carrier layer, which is coated on one side with a self-adhesive, known, wherein on the support layer on the one hand, on the side which is oriented to the adhesive, a printing ink is printed so that between the carrier layer and adhesive, a printing ink is present, and on the other hand, on the side opposite the adhesive-finished surface, another printing ink is printed, so that there is another printing ink on the upper side of the carrier layer.
  • the DE 26 13 131 A discloses a license plate or label in the form of a badge consisting of a film adherable to a base, provided with a color coding representing a seal, the foil being made of transparent material and provided with the color coding on its adhesive side such that a part of the applied color coding is in intimate connection with the film, while the remaining color coding part is intimately connected to an adhesive layer applied to the film.
  • the US 4,557,505 A describes an adhesive tape with a carrier that is printed on both sides. One side of the printed carrier is covered with two layers of paint. Finally, an adhesive is applied to the outer of the two layers.
  • the object of the present invention is firstly to provide a self-adhesive label in which the printing material or a printing material layer has printing on both sides, ie in particular counter printed elements (in intermediate printing or reverse printing) are combined with elements which are produced by frontal printing.
  • the object of the invention to provide methods for producing such self-adhesive labels.
  • the self-adhesive composition is one based on acrylate hotmelt, which has a K value of at least 20.
  • a second printing material layer is present below the adhesive, on the underside of which a self-adhesive composition is coated, which is optionally covered with a release paper or a release film.
  • the second substrate layer is the actual The substrate of the basic label and the first substrate layer the laminating film.
  • the upper adhesive coating represents the laminating adhesive of the label. It is preferred if, following the printing on the underside of the printing material or the first printing material layer (counter printed elements), the lamination takes place.
  • the printing ink is printed on the upper side of the printing substrate or the first printing material layer in frontal printing after the lamination has taken place.
  • the printing inks for counter printed elements are metallic (silver, gold, etc.).
  • a raised pressure frontal pressure
  • a pressure with a transparent relief lacquer for example from Sicpa, 78- 3-021
  • a conventional transparent screen printing ink for example from Sicpa, 78- 3-021
  • the relief character of a hot foil stamping can be simulated, creating an effect that is very similar to a hot foil stamping.
  • the printing material or the first substrate layer films can be used as materials of the printing material or the first substrate layer films, in particular monoaxially and biaxially oriented films based on polyolefins, then films based on stretched polyethylene or stretched copolymers containing ethylene and / or polypropylene units, optionally also PVC Films, PET films, films based on vinyl polymers, polyamides, polyesters, polyacetals, polycarbonates
  • films based on stretched polyethylene or stretched copolymers containing ethylene and / or polypropylene units can be used as printing material according to the invention.
  • Monoaxially stretched polypropylene is characterized by its very high tensile strength and low elongation in the longitudinal direction.
  • Preferred for the preparation of Labels according to the invention are monoaxially stretched films based on polypropylene.
  • the thicknesses of the monoaxially stretched films based on polypropylene are preferably between 20 and 100 ⁇ m, in particular between 25 and 65 ⁇ m, very particularly between 30 and 60 ⁇ m.
  • Monoaxially oriented films are predominantly single-layered, but in principle it is also possible to produce multilayer monoaxially stretched films. Are known predominantly one, two and three-layer films, the number of layers can also be chosen larger.
  • the thicknesses of the biaxially oriented films based on polypropylene are in particular between 12 and 100 ⁇ m, in particular between 20 and 75 ⁇ m, very particularly between 30 and 60 ⁇ m.
  • Biaxially oriented films based on polypropylene can be produced by blown film extrusion or by means of conventional flat film systems. Biaxially stretched films are produced in one or more layers. In the case of multilayer films, the thickness and composition of the different layers may be the same, but also different thicknesses and compositions are known.
  • the labels of the invention are monolayer, biaxially or monoaxially stretched films and multilayer, biaxial or monoaxial polypropylene-based films which have a sufficiently strong bond between the layers, since delamination of the layers during use is disadvantageous.
  • Films based on rigid PVC are used for the production of labels as well as films based on soft PVC.
  • films are used based on rigid PVC.
  • the thicknesses of the films are preferably between 20 and 100 ⁇ m, in particular between 25 and 65 ⁇ m, very particularly between 30 and 60 ⁇ m.
  • Polyester-based films for example polyethylene terephthalate, are also known and can also be used to make the labels of the invention.
  • the thicknesses of the films based on PET are between 20 and 100 ⁇ m, in particular between 25 and 65 ⁇ m, very particularly between 30 and 60 ⁇ m.
  • the former are prepared from only a single monomer by, for example, polycondensation of an ⁇ -hydroxycarboxylic acid 1 or by ring-opening polymerization of cyclic esters (lactones) 2, for example
  • the latter is synthesized by polycondensation of two complementary monomers, for example a diol 3 and a dicarboxylic acid 4:
  • polyesters are obtained in the polycondensation of trihydric or polyhydric alcohols with polyfunctional carboxylic acids.
  • the polyesters are generally also the polycarbonates (carbonic acid polyester) counted.
  • PET polyethylene terephthalate
  • PBT polybutylene terephthalate
  • PCDT Poly (1,4-cyclohexanedimethylene terephthalate) s
  • any self-adhesive materials commonly used for producing self-adhesive labels can be used without exception.
  • This is known to be a printing material, which is coated with a self-adhesive composition, covered with a carrier, usually a release paper or a release film.
  • self-adhesive materials with a printing material based on PP having a thickness of 25 to 60 microns, more preferably those having a thickness of 30 to 40 microns.
  • a printing material based on PP having a thickness of 25 to 60 microns, more preferably those having a thickness of 30 to 40 microns.
  • any types of self-adhesive compositions which are offered for self-adhesive materials.
  • permanent, removable, frozen adhesives, self-adhesive compounds for no-label-look labels etc. are used.
  • UV-curing offset / flexo / book / screen printing inks or solvent-based gravure printing inks are offered for polyolefin film label materials, for example Flexocure® series for UV flexo printing from Akzo.
  • IR-active luminescent pigments are also known.
  • UV fluorescence systems are xanthenes, coumarins, naphthalimides, etc., which are sometimes referred to in the literature under the generic term 'organic phosphors' or 'optical brighteners'.
  • the addition of a few percent of the relevant phosphors is sufficient, and in particular the integration into a solid polymer matrix is favorable in terms of luminosity and stability.
  • formulations with RADGLO® pigments from Radiant Color NV / Holland or Lumilux® CD pigments from Riedel-de-Haen can be used.
  • inorganic phosphors are suitable.
  • photoluminescent substances, especially with the emission of light in the yellow range metal sulfides and oxides, usually in combination with suitable activators, have proved favorable. These are available, for example, under the trade name Lumilux® N or as luminescent pigments improved in terms of stability, luminosity and persistence under the trade name LumiNova® from Nemoto / Japan.
  • thermochromic pigments which are produced by electron beams, X-rays and the like. are excited as well as thermochromic pigments reversibly change in temperature change.
  • electrically conductive colors is possible.
  • the color pigments care must be taken that they are sufficiently stable for the further production process of the labels (for example adhesive coating) and that they are not irreversible in the process conditions (optionally thermal drying, electron beam or UV curing, etc.). change.
  • the security tag is protected from external access because the print is embedded, for example, between the label film and the adhesive layer. Subsequent manipulations are not to be feared, since a replacement is possible only with destruction.
  • Customer-specific "fingerprints" of the labels can be realized by printing different colors or patterns. Particularly regular line and line patterns create characteristic patterns of luminous dots on the edges of the labels and are also particularly cost-saving and material-saving. After punching or laser cutting of the label and the application on the adhesive substrates a pattern with respect to colors and geometries can be identified by selecting a suitable illumination source at the edge of the label.
  • Suitable adhesives for laminating are, for example, UV flexographic laminating adhesives, hotmelt laminating adhesives, pressure-sensitive adhesives, 2-component adhesives or the like.
  • UV laminating adhesives have proved to be advantageous.
  • the laminating adhesive UV 9402 from Akzo such a composite of the counterprinted first printing material web with the second printing material web, the self-adhesive material, can be produced.
  • the labels according to the invention are hotmelt laminating adhesives.
  • the hot melt laminating adhesive A2700 from Novamelt which is applied with a slot die, in particular one with a rotary rod.
  • hotmelt PSAs are outstandingly suitable for lamination during interlayer printing, as well as for self-adhesive coating in counter-pressure.
  • the labels according to the invention may contain, as a laminating adhesive, a self-adhesive composition based on natural rubber, PUR, acrylates or styrene-isoprene-styrene block copolymers.
  • an acrylate hotmelt base which has a K value of at least 20, in particular greater than 30, obtainable by concentrating a solution of such a composition into a system which can be processed as a hotmelt.
  • the concentration can take place in suitably equipped boilers or extruders, in particular in the concomitant degassing a vented extruder is preferred.
  • the solution of the composition may contain from 5 to 80% by weight, in particular from 30 to 70% by weight, of solvent.
  • solvents are preferably used, in particular low-boiling hydrocarbons, ketones, alcohols and / or esters.
  • single-screw, twin-screw or multi-screw extruders with one or in particular two or more degassing units are used.
  • benzoin derivatives may be copolymerized, such as benzoin acrylate or benzoin methacrylate, acrylic acid or methacrylic acid ester.
  • benzoin derivatives are in the EP 0 578 151 A1 described.
  • the adhesive on Acrylathotmelt-based can also be chemically crosslinked.
  • self-adhesive compositions of (meth) acrylic acid and esters thereof having 1 to 25 carbon atoms, maleic, fumaric and / or itaconic acid and / or their esters, substituted (meth) acrylamides, maleic anhydride and other vinyl compounds , used as vinyl esters, in particular vinyl acetate, vinyl alcohols and / or vinyl ethers.
  • the residual solvent content should be below 1% by weight.
  • An adhesive which is particularly suitable is a low molecular weight acrylate hot melt pressure-sensitive adhesive, such as that marketed under the name acResin UV or Acronal®, in particular Acronal DS 3458, by BASF.
  • This adhesive with a low K value obtains its application-oriented properties through a final radiation-induced crosslinking.
  • an adhesive may be used which consists of the group of natural rubbers or of the synthetic rubbers or of any blend of natural rubbers and / or synthetic rubbers, the natural rubber or the natural rubbers basically being made of all available qualities, such as Crepe, RSS.
  • the synthetic rubber or synthetic rubbers from the group of randomly copolymerized styrene-butadiene rubbers (SBR), the butadiene rubbers (BR), the synthetic,.
  • ADS, TSR or CV types Polyisoprenes (IR), the butyl rubbers (IIR), the halogenated butyl rubbers (XIIR), the acrylate rubbers (ACM), the ethylene-vinyl acetate copolymers (EVA) and the polyurethanes and / or their blends can be selected.
  • thermoplastic elastomers having a weight proportion of 10 to 50% by weight, based on the total elastomer content.
  • SIS styrene-isoprene-styrene
  • SBS styrene-butadiene-styrene
  • tackifying resins all previously known adhesive resins described in the literature can be used without exception. Mention may be made representative of the rosins, their disproportionated, hydrogenated, polymerized, esterified derivatives and salts, the aliphatic and aromatic hydrocarbon resins, terpene resins and terpene phenolic resins. Any combination of these and other resins can be used to adjust the properties of the resulting adhesive as desired. On the presentation of the knowledge in the " Handbook of Pressure Sensitive Adhesive Technology "by Donatas Satas (van Nostrand, 1989 ) is explicitly pointed out.
  • Hydrocarbon resin is a collective term for thermoplastic, colorless to intense brown colored polymers having a molecular weight of generally ⁇ 2000.
  • coal tar resins In petroleum, coal tar and terpene resins.
  • the most important coal tar resins are the coumarone-indene resins.
  • the hydrocarbon resins are obtained by polymerization of the unsaturated compounds which can be isolated from the raw materials.
  • hydrocarbon resins are also calculated by polymerization of monomers such as styrene or by polycondensation (certain formaldehyde resins) accessible polymers having a correspondingly low molecular weight.
  • Hydrocarbon resins are products with a softening range varying from ⁇ 0 ° C (at 20 ° C liquid hydrocarbon resins) to> 200 ° C in a wide range and a density of about 0.9 to 1.2 g / cm 3 .
  • Rosin resin is understood to mean a natural resin derived from the crude resin of conifers. There are three types of rosin: balsam resin as distillation residue of turpentine oil, root resin as extract of coniferous rootstocks and tall resin, the distillation residue of tall oil. The most important in terms of quantity is balsam resin.
  • Rosin is a brittle, transparent product of red to brown color. It is insoluble in water but soluble in many organic solvents such as (chlorinated) aliphatic and aromatic hydrocarbons, esters, ethers and ketones as well as in vegetable and mineral oils.
  • organic solvents such as (chlorinated) aliphatic and aromatic hydrocarbons, esters, ethers and ketones as well as in vegetable and mineral oils.
  • the softening point of rosin is in the range of about 70 to 80 ° C.
  • Rosin is a mixture of about 90% resin acids and 10% neutral substances (fatty acid esters, terpene alcohols and hydrocarbons).
  • the most important rosin resin acids are unsaturated carboxylic acids of the general formula C20H30O2, abietic, neoabietic, levopimaric, pimaric, isopimaric and palustric acids, in addition to hydrogenated and dehydrated abietic acid.
  • softener it is possible to use all known softening substances. These include, among others, the paraffinic and naphthenic oils, (functionalized) oligomers such as oligobutadienes, isoprenes, liquid nitrile rubbers, liquid terpene resins, vegetable and animal oils and fats, phthalates, functionalized acrylates.
  • paraffinic and naphthenic oils such as oligobutadienes, isoprenes, liquid nitrile rubbers, liquid terpene resins, vegetable and animal oils and fats, phthalates, functionalized acrylates.
  • thermally activatable chemical crosslinkers such as accelerated sulfur or sulfur donor systems, isocyanate systems, reactive melamine, formaldehyde and (optionally halogenated) phenol-formaldehyde or reactive phenolic or Diisocyanatvernetzungssysteme with the corresponding activators, epoxidized polyester - And acrylate resins and their combinations used.
  • the crosslinkers are preferably activated at temperatures above 50 ° C, in particular at temperatures of 100 ° C to 160 ° C, most preferably at temperatures of 110 ° C to 140 ° C.
  • the thermal excitation of the crosslinker can also be effected by IR radiation or high-energy alternating fields.
  • the label according to the invention has all possible uses. Particularly advantageous is the use of the label on packaging such as tubes, jars, cans or bottles made of glass, plastic or metal, in particular in the embodiment with silver print and relief varnish.
  • the label looks very attractive and has a very attractive effect on potential customers when placed on the packaging accordingly.
  • the label according to the invention can be produced very advantageously in particular by the following methods.
  • the invention is in no way restricted in an alternative method of preparation in the form of printing on both sides of the printing material or the first printing material web prior to lamination.
  • the composite is turned after lamination with the aid of a turning cross.
  • a two-sided corona pretreatment of the film surfaces is generally carried out.
  • the printing material web is provided in the printing units D1 to D (x), shown here in the printing units D1 to D3, with the desired imprint.
  • a self-adhesive mass is coated in the laminating station K. Subsequently, the carrier material and the printing material web are laminated together in such a way that the self-adhesive composition covers the pressure on the first carrier layer.
  • FIG. 2 An alternative manufacturing method is in FIG. 2 This represents the coating of the self-adhesive composition in the flexo process.
  • the turn of the laminated web is effected, so that the upper side of the printing material web in the printing units D (x + 1) to D (z), shown here in the printing units D4 to D8, can be printed.
  • An advantage of the method according to the invention is that the self-adhesive coating can take place at any position of the machine, ie at each of the printing units D1 to D (z), in the illustrated case D1 to D8, with a lamination on the printing unit D3.
  • K counterpressure
  • F frontal pressure
  • the pressure-sensitive adhesive in this case is coated indirectly, that is to say first on the support material, preferably a silicone film, this being not a limitation of this invention, since self-adhesive coating on the printed web prior to lamination to the support material is also feasible.
  • a roll with the second printing substrate a self-adhesive material, consisting of printing material, self-adhesive and carrier material handled.
  • a roll with the first printing material web is unrolled.
  • the first substrate web is in the printing units D1 to D (x), shown here in the printing units D1 to D3, provided with the desired imprint (pad pressure).
  • the second printing material web and the first printing material web are laminated together in the laminating station K in such a way that the adhesive covers the pressure on the first carrier layer.
  • FIG. 5 An alternative, very advantageous manufacturing method is in FIG. 5 This represents the coating of the self-adhesive composition in the hotmelt process.
  • the turn of the laminated web is effected, so that the upper side of the first printing material web in the printing units D (x + 1) to D (z), shown here in the printing units D4 to D8, can be printed.
  • the label web EB is rolled up.
  • An advantage of the method according to the invention is that the lamination can take place at any position of the machine, ie at each of the printing units D1 to D (z), in the illustrated case D1 to D8, with a lamination on the printing unit D3.
  • K counterpressure
  • F frontal pressure
  • the label according to the invention has elements which may be produced once by the frontal printing method and then further elements which are produced after the counter or interlayer printing.
  • the label combines the advantages of both printing process variants.
  • Certain printing inks are internal (interlayer printing or reverse printing), in combination with printing inks overhead (frontal printing).
  • interlayer pressure is used, for example, to achieve a good, inexpensive silver print, in frontal pressure to achieve a better relief effect (usually screen printing). It is also an advantage of the counter-pressure that the printing inks are protected against media (fillings, chemicals, etc.).
  • the adhesive is applied over the entire area by means of a slot die (for example Nordson BC 40, rotating rod principle) and UV-crosslinked.
  • a slot die for example Nordson BC 40, rotating rod principle
  • flexo-UV pressure-sensitive adhesives or dispersion / solvent pressure-sensitive adhesives may be used.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
  • Making Paper Articles (AREA)

Claims (12)

  1. Etiquette constituée par au moins une première couche transparente en matériau à imprimer (5), qui est revêtue sur une face par une masse autoadhésive (4) qui est le cas échéant revêtue par un papier de séparation (3) ou une feuille de séparation (3), où, sur la première couche en matériau à imprimer (5)
    d'une part, une encre d'imprimerie (12) est imprimée par contre-pression sur la face inférieure orientée vers la masse adhésive (4), de manière telle qu'une encre d'imprimerie (12) se trouve entre la couche en matériau à imprimer (5) et la masse adhésive (4), et
    d'autre part, sur la face supérieure opposée à la surface apprêtée de manière adhésive, une autre encre d'imprimerie (11) est imprimée en impression frontale, de manière telle qu'une autre encre d'imprimerie (11) se trouve sur la face supérieure de la couche en matériau à imprimer (5), caractérisée en ce que
    la masse autoadhésive (4) est à base d'une masse fondue à chaud à base d'acrylate, qui présente une valeur K d'au moins 20.
  2. Etiquette selon la revendication 1, caractérisée en ce qu'une deuxième couche en matériau à imprimer (1) se trouve sous la masse adhésive (4), sur la face inférieure de laquelle est revêtue une masse autoadhésive (2) qui est le cas échéant revêtue par un papier de séparation (3) ou une feuille de séparation (3).
  3. Etiquette selon au moins l'une quelconque des revendications précédentes, caractérisée en ce que l'encre d'imprimerie (12) sur la face inférieure de la première couche en matériau à imprimer (5) est une encre métallique, par exemple argentée.
  4. Etiquette selon au moins l'une quelconque des revendications précédentes, caractérisée en ce que, en plus de l'imprimerie (12), en particulier avec des encres métalliques, sur la face inférieure de la première couche en matériau à imprimer (5), une impression (11), en particulier une impression (11) avec une laque en relief transparente, est présente aux mêmes endroits sur la face supérieure.
  5. Utilisation d'une étiquette selon au moins l'une quelconque des revendications précédentes sur des emballages tels que des tubes, des casseroles, des boîtes ou des bouteilles en verre, en matériau synthétique ou en métal.
  6. Procédé pour la production d'étiquettes selon au moins l'une quelconque des revendications précédentes, dans lequel, dans un processus de travail, la bande en matériau à imprimer (5) peut être imprimée et ce du côté orienté vers la masse adhésive (4) et sur la face opposée et, dans le même processus de travail, une bande support revêtue de manière anti-adhésive est acheminée et une masse autoadhésive est appliquée sur une face d'une des deux bandes, généralement sur la couche de séparation de la bande support, de telle manière qu'un assemblage est réalisé entre le matériau à imprimer (5) et le support lors du contre-collage consécutif.
  7. Procédé selon la revendication 6, caractérisé en ce qu'on contrecolle, au lieu de la bande support, une deuxième couche en matériau à imprimer (1) sur la face inférieure de laquelle est revêtue une masse autoadhésive (2) qui est le cas échéant revêtue par un papier de séparation (3) ou une feuille de séparation (3).
  8. Procédé selon la revendication 6 ou 7, caractérisé en ce qu'on réalise le contrecollage après l'impression de la face inférieure du matériau à imprimer (5) ou selon le cas de la première couche en matériau à imprimer (5).
  9. Procédé selon au moins l'une quelconque des revendications précédentes 6 à 8, caractérisé en ce que l'encre d'imprimerie (11) est imprimée sur la face supérieure du matériau à imprimer (5) ou selon le cas de la première couche en matériau à imprimer (5) en impression frontale après que le contrecollage a eu lieu.
  10. Procédé selon au moins l'une quelconque des revendications précédentes 6 à 9, caractérisé en ce qu'on utilise pour le contrecollage un autoadhésif en masse fondue à chaud à base d'acrylate durcissant sous l'effet des UV, qui est appliqué avec une filière à fente large.
  11. Procédé pour la production d'une étiquette selon au moins l'une quelconque des revendications précédentes, caractérisé
    en ce qu'on déroule, sur une des deux poulies (A1, A2), un rouleau avec un matériau support, par exemple un papier de séparation,
    en ce qu'on déroule sur une autre poulie un rouleau avec la bande en matériau à imprimer (5),
    en ce que la bande en matériau à imprimer (5) est imprimée avec un nombre quelconque des postes d'impression à disposition (D1 à D(x)), au choix par impression offset, typo, flexo ou par sérigraphie, en particulier par un procédé par héliogravure,
    en ce que le matériau support est revêtu sur le côté revêtu de manière antiadhésive par une masse autoadhésive (4),
    en ce que le matériau support et la bande de matériau à imprimer (5) sont contrecollés de telle manière que la masse autoadhésive (4) recouvre l'impression (12) sur la bande en matériau à imprimer (5),
    en ce que la bande contrecollée est tournée dans la machine,
    en ce que la face supérieure de la bande en matériau à imprimer (5), en fonction des postes d'impression encore à disposition (D1 à D(x)), est imprimée au choix par impression offset, typo, flexo ou par héliogravure, en particulier par un procédé par sérigraphie,
    en ce qu'on réalise le cas échéant une découpe des différentes étiquettes,
    en ce qu'on réalise le cas échéant un enroulement de la bande d'étiquettes (BE).
  12. Procédé pour la production d'une étiquette selon au moins l'une quelconque des revendications précédentes, caractérisé
    en ce qu'on déroule sur une des deux poulies (A1, A2) un rouleau de matériau autoadhésif avec la deuxième bande de matériau à imprimer (1), sur laquelle se trouve une masse autoadhésive (2), qui est recouverte par un matériau support (3),
    en ce qu'on déroule sur une autre poulie (A1, A2) un rouleau avec la première bande en matériau à imprimer (5), en ce que la bande en matériau à imprimer (5) est à présent imprimée avec un nombre quelconque des postes d'impression à disposition (D1 à D(x)), au choix par impression offset, typo, flexo ou par sérigraphie, en particulier par un procédé par héliogravure,
    en ce que la deuxième bande de matériau à imprimer (1) et la première bande de matériau à imprimer (5) sont contrecollées de telle manière que la masse adhésive de contre-collage (4) recouvre l'impression sur la bande en matériau à imprimer (5),
    en ce que la bande contrecollée est tournée dans la machine,
    en ce que la face supérieure de la bande en matériau à imprimer (5), en fonction des postes d'impression encore à disposition (D1 à D(x)), est imprimée au choix par impression offset, typo, flexo ou par héliogravure, en particulier par un procédé par sérigraphie,
    en ce qu'on réalise le cas échéant une découpe des différentes étiquettes,
    en ce qu'on réalise le cas échéant un enroulement de la bande d'étiquettes (BE).
EP07108135A 2001-12-21 2002-11-21 Etiquette auto-adhésive, méthode de fabrication et son utilisation Revoked EP1818893B1 (fr)

Applications Claiming Priority (2)

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DE10163589A DE10163589A1 (de) 2001-12-21 2001-12-21 Selbstklebend ausgerüstete Etiketten, Verfahren zur Herstellung dieser sowie ihre Verwendung
EP20020025966 EP1321919B1 (fr) 2001-12-21 2002-11-21 Etiquette auto-adhesive, méthode de fabrication et son utilisation

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Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7484667B2 (en) * 2001-06-22 2009-02-03 Brevitex Etablissement Pour L'exploitation De Brevets Textiles Method and installation for producing patterned textile labels
WO2004078467A1 (fr) * 2003-03-03 2004-09-16 Iwata Label Co., Ltd. Etiquette collante, ainsi que son procede et son dispositif de fabrication
GB0308530D0 (en) * 2003-04-12 2003-05-21 Bastione Ltd Security arrangement
US8609212B2 (en) 2003-04-12 2013-12-17 Bastione Limited Security arrangement
DE102005036258A1 (de) * 2005-08-02 2007-02-08 Pierre Chappuis Dekorfolien und Verfahren zu deren Herstellung
US20070218263A1 (en) * 2006-03-17 2007-09-20 General Binding Corporation Thermal laminating film and method of manufacture
US20070252382A1 (en) * 2006-03-20 2007-11-01 Baum Robert E Laminated multi-ply in-mold label
JP4714622B2 (ja) * 2006-03-30 2011-06-29 富士フイルム株式会社 インクジェット記録媒体の後加工方法および後加工装置を有する装置
DE102006037627A1 (de) * 2006-08-10 2008-02-14 Tesa Ag Selbstklebemasse aus hydrierten Blockcopolymeren und daraus hergestellte Schutzfolie für glatte und raue Oberflächen
US20080143094A1 (en) * 2006-12-18 2008-06-19 Fmc Technologies, Inc. Two-sided label, label stock, and associated method of making same
FR2912153B1 (fr) * 2007-02-02 2009-04-17 Bostik S A Sa Composition adhesive pour etiquette auto-adhesive decollable
FR2918069B1 (fr) * 2007-06-29 2009-09-04 Bostik S A Sa Hmpsa pour etiquette auto-adhesive decollable
DE102008005564A1 (de) * 2008-01-22 2009-07-23 Tesa Ag Trägerfolie insbesondere für ein Klebeband und Verwendung derselben
US20100132881A1 (en) * 2008-11-26 2010-06-03 Gaughan Michael H Article with obverse and reverse side printing
DE102009037430A1 (de) 2009-08-13 2011-03-24 Frimo Group Gmbh Verfahren zur Kaschierung von zumindest einem Formteil
US9079681B1 (en) * 2009-08-14 2015-07-14 Nucoat, Inc. Methods and articles for image transfer
DE102011076552A1 (de) 2011-05-26 2012-11-29 Tesa Se Verfahren zum Verspenden von auf einem Trägerband vorhandenen Etiketten und Verfahren zur Herstellung von mit Etiketten ausgerüsteten Trägerbändern
DE102011105209A1 (de) 2011-06-17 2012-12-20 Lohmann Gmbh & Co Kg Reaktives Klebebandpolymerisat
DE202011104393U1 (de) 2011-06-29 2012-02-13 Lohmann Gmbh & Co. Kg Reaktives Klebebandpolymerisat
US20130122292A1 (en) * 2011-11-14 2013-05-16 Diana Carrdine Scotch® Tape or like Tear-line Indicator
DE102012200831A1 (de) 2012-01-20 2013-07-25 Bandfix Ag Rundumetikett zur Etikettierung eines Gebindes wie einer Getränkeverpackung
US10275969B2 (en) 2012-03-09 2019-04-30 United States Postal Service Method and system for item authentication and customization
EP3407263A1 (fr) 2012-03-09 2018-11-28 United States Postal Service Procédé de fabrication d'un label d'authentification
JP2014036250A (ja) * 2012-08-07 2014-02-24 Brother Ind Ltd 紙媒体及び読取装置
GB201222961D0 (en) * 2012-12-19 2013-01-30 Innovia Films Ltd Label
FR3030856B1 (fr) * 2014-12-19 2018-02-02 Arjobex Etiquette adhesive
CN104599590A (zh) * 2014-12-31 2015-05-06 广东天元印刷有限公司 一种不干胶印刷的亮银不干胶标签及其制备方法
US20160243653A1 (en) 2015-02-24 2016-08-25 Electronics For Imaging, Inc. Compensated laser cutting of labels
US10112378B2 (en) * 2016-05-24 2018-10-30 Chem Etch Manufacturing Inc. Method of manufacturing anti-theft labels
US10532586B1 (en) * 2018-06-14 2020-01-14 Christian Carter Noterman Metal photographic plate with carrier and method of use
AU2020349427A1 (en) * 2019-09-16 2022-03-31 Align Technology, Inc. Durable ornamental indicia carrier
CN114863791A (zh) * 2022-04-20 2022-08-05 中国科学技术大学 一种多重防伪标签及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0937761A1 (fr) * 1998-02-24 1999-08-25 Beiersdorf Aktiengesellschaft Ruban adhésif n'émettant pas de buée

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8130861U1 (de) 1981-10-22 Beiersdorf Ag, 2000 Hamburg Mehrschichtiges Etikett
US1752462A (en) * 1927-11-16 1930-04-01 Kingsport Press Inc Nontarnishing metallic ink
US3301728A (en) 1956-12-14 1967-01-31 Swartz William Process for making three dimensional display items
DE1569909A1 (de) * 1966-02-23 1969-08-14 Basf Ag Schmelzkleber
US3516904A (en) * 1966-04-07 1970-06-23 Diamond Int Corp Heat transfer decalcomania for application to plastic bottles made from a laminate of a polyamide adhesive,a printed layer,and a wax like heat release layer
DE2613131C2 (de) 1976-03-27 1984-05-17 Karl Dr. 2320 Plön Schröder Folienkennzeichen für Kraftfahrzeuge
US4233195A (en) * 1979-02-26 1980-11-11 Reynolds Metals Company Metallic printing inks and metallized papers printed therewith
US4521492A (en) * 1982-04-05 1985-06-04 Champion International Corporation Light refractive coated paperboard
US4557505A (en) 1984-01-05 1985-12-10 Minnesota Mining And Manufacturing Company Stress-opacifying tamper indicating tape
DE3534558A1 (de) * 1984-10-01 1986-04-17 Daimatsu Kagaku Kogyo Co. Ltd., Osaka Aufklebematerial zur verhinderung des wiederaufklebens
US5372669A (en) * 1985-02-05 1994-12-13 Avery Dennison Corporation Composite facestocks and liners
GB8620430D0 (en) 1986-08-22 1986-10-01 Plessey Co Plc Marking of articles
US4980222A (en) 1989-06-21 1990-12-25 Minnesota Mining And Manufacturing Company Tamper indicating tape
EP0453131A3 (en) 1990-04-12 1992-04-29 James River Corporation Security paper and method of manufacturing same
IT1248303B (it) * 1991-05-08 1995-01-05 Az Service S R L Macchina per il trattamento e l'erogazione di impasti cementizi, particolarmente per la realizzazione di intonaci
DE4222334A1 (de) 1992-07-08 1994-01-13 Beiersdorf Ag Schmelzhaftkleber für Medical-Produkte
DE4231800A1 (de) 1992-09-23 1994-03-24 Schreiner Etiketten Kennzeichnungsträger und Druckverfahren
DE4313008C1 (de) 1993-04-21 1994-11-10 Beiersdorf Ag Selbstklebemasse auf Acrylathotmelt-Basis, Verfahren zu deren Herstellung und deren Verwendung
JP3418746B2 (ja) 1993-10-05 2003-06-23 日立マクセル株式会社 インクリボン
US5661099A (en) * 1994-02-28 1997-08-26 Media Solutions, Inc. Self-wound direct thermal printed labels
DE9421868U1 (de) 1994-06-22 1997-02-13 Beiersdorf Ag Einschichtlaseretikett
DE4421865A1 (de) 1994-06-22 1996-01-04 Beiersdorf Ag Einschichtlaseretikett
JPH0854825A (ja) 1994-08-11 1996-02-27 Honda Motor Co Ltd ラベル
FR2730671B1 (fr) 1995-02-17 1997-04-04 Sibille Dalle Document imprimable comprenant des moyens revelateurs de falsification
FR2734655B1 (fr) 1995-05-23 1997-08-14 Seror Marc Allain Procede d'etablissement d'un document fiduciaire protege contre les falsifications, et document fiduciaire obtenu
JPH08328474A (ja) 1995-05-30 1996-12-13 Hideaki Nakai 多層の織ラベル
DE19703712A1 (de) * 1996-01-27 1997-11-13 Josef Teltenkoetter Druckerzeugnis, sowie Verfahren zum Bedrucken von Papieren oder Folien und Verwendung des Druckerzeugnisses als Etikett
JPH09237045A (ja) * 1996-02-29 1997-09-09 Lintec Corp ハーフ蒸着ラベル
DE19747000C2 (de) * 1997-10-24 2003-10-30 Tesa Ag Laseretiketten und ihre Verwendung
US6022440A (en) * 1997-12-08 2000-02-08 Imation Corp. Image transfer process for ink-jet generated images
US6099944A (en) * 1998-12-02 2000-08-08 Avery Dennison Corporation Heat-transfer label including a frosted ink design
US6432528B1 (en) * 1998-12-09 2002-08-13 3M Innovative Properties Company Variably printed tape and system for printing and applying tape onto surfaces
DE19913641C2 (de) * 1999-03-25 2001-05-03 Pachem Papier Chem Produktions Etikett
DE20020228U1 (de) * 2000-11-29 2001-01-25 Toepfer Kulmbach Gmbh Transparente Folie
US6756095B2 (en) * 2001-01-10 2004-06-29 Avery Dennison Corporation Heat-sealable laminate
DE10139653A1 (de) * 2001-08-11 2003-02-20 Tesa Ag Etikett mit erhöhter Fälschungssicherheit
US6773653B2 (en) * 2001-10-05 2004-08-10 Avery Dennison Corporation In-mold labeling method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0937761A1 (fr) * 1998-02-24 1999-08-25 Beiersdorf Aktiengesellschaft Ruban adhésif n'émettant pas de buée

Also Published As

Publication number Publication date
US7250191B2 (en) 2007-07-31
EP1321919A3 (fr) 2005-10-12
EP1321919B1 (fr) 2007-08-22
DE10163589A1 (de) 2003-08-07
EP1818893A1 (fr) 2007-08-15
ATE495518T1 (de) 2011-01-15
ATE371244T1 (de) 2007-09-15
DE50210748D1 (de) 2007-10-04
US20060263595A1 (en) 2006-11-23
DE50214865D1 (de) 2011-02-24
EP1321919A2 (fr) 2003-06-25
US20030148055A1 (en) 2003-08-07

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