EP1345195B1 - Etiquette pour l' occultation des informations - Google Patents

Etiquette pour l' occultation des informations Download PDF

Info

Publication number
EP1345195B1
EP1345195B1 EP03003978A EP03003978A EP1345195B1 EP 1345195 B1 EP1345195 B1 EP 1345195B1 EP 03003978 A EP03003978 A EP 03003978A EP 03003978 A EP03003978 A EP 03003978A EP 1345195 B1 EP1345195 B1 EP 1345195B1
Authority
EP
European Patent Office
Prior art keywords
label
backing layer
layer
additive
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
EP03003978A
Other languages
German (de)
English (en)
Other versions
EP1345195A2 (fr
EP1345195A3 (fr
Inventor
Malte Krone
Arne Koops
Sven Reiter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tesa SE
Original Assignee
Tesa SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10217120A external-priority patent/DE10217120A1/de
Application filed by Tesa SE filed Critical Tesa SE
Publication of EP1345195A2 publication Critical patent/EP1345195A2/fr
Publication of EP1345195A3 publication Critical patent/EP1345195A3/fr
Application granted granted Critical
Publication of EP1345195B1 publication Critical patent/EP1345195B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions

Definitions

  • the invention relates to a label for concealing information from a carrier layer, in particular lacquer layer, very particularly from thermosetting lacquer for laser marking, wherein on the lower side of the carrier layer, an adhesive layer is present, as well as the use thereof.
  • the labels serve to provide information, the information being generated by printing or inscription by means of a laser on the label.
  • application fields come into focus, in which information is not transmitted through the label, but where - on the contrary - information to be covered by the label, either right from the beginning of the bond or later, so that the information is first accessible and only after manipulation of the label disappears or is covered.
  • Disposable packaging for drinks will in future also be subject to the deposit system.
  • the customer Upon return of the packaging (mainly plastic bottles) the customer will receive the corresponding deposit. To simplify the return, this can be done in appropriately designed apparatus.
  • DE G 81 30 861 discloses a multilayer label of a thin and a thick self-supporting, opaque pigmented paint layer. Both layers consist of an electron beam-hardened solvent-free applied paint, wherein the layer thicknesses are different.
  • the labeling of the label takes place in that with the aid of a laser, the upper thinner lacquer layer is burned away, so that the lower thicker lacquer layer is visible, the lower layer preferably has a contrasting color to the former.
  • This lettering is a type of engraving, which eliminates the manipulation possibilities as with traditional printing with inks and inks.
  • the label is set by the raw materials used and the manufacturing process so brittle that removal of the same from the adhesive substrates is almost always possible only with destruction.
  • a laser film as from the DE G 81 30 861 is known and obtainable, for example, as tesa 6930® from the company tesa, because of its very brittle product structure good conditions to document possible manipulation attempts and thus to thwart.
  • the laser-printed label can only be removed at a very high cost and under certain conditions in a non-destructive way from its original bonding substrate.
  • a laser-writable multi-layer label material is shown which is composed of a first layer, a second layer differing optically from the first layer, the first layer being removable by laser radiation in accordance with a desired typeface or print image to visualize the surface of the second layer.
  • a transparent plastic film forming a carrier layer is furthermore arranged.
  • the DE 44 21 865 A1 shows a Ein harshlaseretikett from a carrier layer made of plastic, which contains an additive that shows a color change under laser irradiation.
  • the carrier layer is coated on one side with a self-adhesive, which is optionally covered with a release paper or a release film.
  • a security film which has a carrier layer in which an identification medium is contained.
  • the diffusion properties of this identification medium can be specifically selectively and locally changed. If the security film labeled in this way is adhered to a workpiece, the identification medium diffuses toward the substrate surface, where it causes a detectable reaction. In this case, this diffusion or reaction takes place only in those areas of the substrate surface in which the diffusion capability was triggered or not obstructed by the inscription process.
  • the security film allows a clear labeling and identification of the workpiece.
  • the security film is labeled by means of a non-contact method.
  • the labeling of the security film - and thus the change of the diffusion properties of the identification medium - can be done in particular by means of electromagnetic radiation.
  • Particularly advantageous for labeling the security film is the use of a laser, by means of which both a temperature-sensitive and a light-sensitive labeling can take place (the term "light” in this case, the entire laser-accessible range of the electromagnetic spectrum comprises).
  • Lasers have the additional advantage of allowing high-contrast labels with any choice of pattern, allowing rapid changes in the pattern of the label, and being process reliable in the factory environment.
  • a special blade tool can be placed under the label at a shallow angle. By careful cutting movements, it is possible to raise an edge, creating a so-called grip. In this way one creates an attack point, which simplifies a detachment.
  • An additional safety aspect is in the DE 199 04 823 A1 disclosed.
  • a method for producing a film is described in which initially a support carrier film is embossed by means of an embossing tool, wherein the embossing tool has holographic structures. Subsequently, a film is produced on the embossed support carrier film, so that at least one hologram appears on the film.
  • a laser label of at least one layer of plastic is known, which is coated on one side with a self-adhesive, which is optionally covered with a release paper or a release film; Between plastic and self-adhesive, a printing ink is printed.
  • the plastic layer can be transparent.
  • the object of the invention is to provide a way to specifically mask information by means of a label, so that, for example, after labeling the label with a laser, the previously (machine) readable content below the label no longer be evaluated.
  • a detachment of the label should only be possible by destroying it.
  • the invention should meet the aspect of improved security against counterfeiting.
  • the logo may be printed or embossed on the backing layer.
  • the carrier layer preferably has a thickness of 10 to 200 .mu.m, in particular from 50 to 100 .mu.m.
  • Suitable carrier layers consist of plastics such as polyesters, poly (meth) acrylates, polycarbonates and polyolefins, as well as of radiation-curable systems such as unsaturated polyesters, epoxy, polyester and urethane acrylates, as are also used for UV printing inks, in particular those of base polymers according to US Pat DE G 81 30 816 namely, aliphatic urethane acrylate oligomers.
  • the additive may be a pigment, in particular copper hydroxide phosphate or iriodine, a pearlescent pigment based on basic lead carbonate or mica, and be used in addition to the additive titanium dioxide. Furthermore, the additive may be a thermochromic dye.
  • Suitable additives are, in particular, metal salts, in particular copper hydroxide phosphate or else iriodine, a pearlescent pigment, such as is commercially available from Merck. These additives are added to the base polymers (such as in DE G 81 30 861 described) in particular of the order of a few parts per thousand to a maximum of 10 wt .-%, preferably in amounts of 0.1 to 10 wt .-%, in particular from 0.5 to 5 wt .-% based on the total weight of the carrier layer admixed , After production of sheet material by known methods such as extrusion, casting, coating, etc., optionally with subsequent radiation-chemical crosslinking, such films are coated with the adhesive layer.
  • a cover with siliconized release paper then gives the typical structure for starting material from which labels can be made.
  • the carrier layer consists of a lacquer, in particular of a cured lacquer, preferably a radiation-cured lacquer, particularly preferably of an electron beam-cured polyurethane acrylate lacquer.
  • the paint is a brittle paint. The brittleness of the paint is a cause that the label can not be peeled off after bonding because of lack of flexibility of the carrier, but splinters when attempting to detach.
  • the carrier layer consists of a polybutylene terephthalate.
  • paints In principle, four types of paint can be used, provided that their stability is sufficient, for example, acid-curing alkyd melamine resins, addition-curing polyurethanes, free-radical curing styrofoam and the like.
  • radiation-curing paints are particularly advantageous, since they cure very quickly without lengthy evaporation of solvents or the action of heat.
  • paints are for example by A. Vrancken (Farbe und Lack 83,3 (1977) 171 ).
  • the paint layer contains an additional additive of at least 5% by weight, preferably 7% by weight, which is fluorescent or phosphorescent or which is suitable for magnetic or electrical labeling.
  • a falsification by subsequent manipulation is particularly excluded by the fact that the conductivity measurement Vietnamese.Nur from edge to edge of the labels, but can be done between any points. So that a conductivity can be detected here, the complete lacquer layer must be consistently three-dimensionally conductive, which can only be ensured within the framework of the original production process.
  • Such a laser-inscribable label can be produced by adding electrically conductive substances to the formulation of the lacquer layer; This can be done in addition to the previous pigments or at least partially in replacement of the existing pigments in order to maintain the good processing properties of the paint pastes.
  • electrically conductive metallic, organic, polymeric and inorganic substances are suitable as conductive additives, the use of metals being preferred.
  • the own color of the conductive additive has to be considered for the selection.
  • Conductive carbon black is also suitable, but gives a clear black coloration of the carrier layer.
  • a minimum limit concentration of additive should be ensured, so that sufficient particles are present in the lacquer layer to touch and have contact with each other. If this limit concentration is undershot, a conductive path from A to B is no longer ensured in the three-dimensional structure of the base layer. Preference is therefore given to using metallic particles, preference being given to fibers having a high length to cross-sectional ratio, since in this case it is possible to ensure three-dimensional conductivity at lower concentrations than with spherical particles; In addition, the color change of the lacquer layer with the fibers is smaller.
  • the metals used are preferably cost-benefit considerations copper, iron, aluminum and steel and their alloys, but also expensive, highly conductive metals such as silver, gold are suitable.
  • the fiber dimensions are 0.1 to 50 mm in length and cross sections of 1 to 100 .mu.m, wherein preferably metal fibers with a diameter of 2 to 20 microns at a cross-sectional to length ratio of about 1: 100 to 1: 1000 are used.
  • Such fibers are incorporated homogeneously with 0.5 to 25 wt .-%, preferably with 2 to 10 wt .-% in the known recipe and according to DE G 81 30 861 coated and cured.
  • the additives which can be added to the carrier layer may be fine color pigments or else preferably visible particles of the order of 0.1 to 5 mm.
  • finely ground color pigments When using finely ground color pigments, a slight color change of the lettering is produced, with the visible particles a characteristic color mosaic.
  • daylight fluorescent colors the "fingerprint" can be recognized without any aids, which is often undesirable. Preference is therefore given to using color pigments or particles which do not absorb in the region of visible light and are therefore invisible under normal circumstances - it is only when the label is illuminated with a lamp of suitable wavelength that the color pigments are excited and light up in a characteristic way.
  • UV-active systems In addition to color pigments excited by IR radiation, mainly UV-active systems are used. Also suitable in principle are phosphors which are produced by electron beams, X-rays and the like. are excited as well as thermochromic pigments reversibly change in temperature change.
  • the color pigments When selecting the color pigments, care must be taken that they are sufficiently stable for the production process of the labels (film production, adhesive coating) and do not change irreversibly in the process conditions (optionally thermal drying, electron beam or UV curing, etc.). It is advantageous for continuous use of the labels that these usually sensitive phosphors are embedded in a polymer matrix. Further measures against mechanical abrasion and protection against direct oxygen and water contact are not necessary.
  • the same luminescent (phosphorescent) or fluorescent color pigments can be used as are used for the color pigments present in the paint.
  • These color pigments are only or predominantly excited by UV radiation and emit in the visible region of the spectrum (for an overview see, for example Ullmann's Encyclopedia of Industrial Chemistry, 4th edition, 1979, Verlag Chemie ).
  • IR-active luminescent pigments are also known.
  • UV fluorescence systems are xanthenes, coumarins, naphthalimides, etc., some of which are under the generic term “organic phosphors” or “optical brighteners” in the literature. The addition of a few percent of the relevant phosphors is sufficient.
  • formulations with RADGLO® pigments from Radiant Color N.V./Holland or Lumilux® CDPigmente from Riedel-de-Haen can be used.
  • inorganic phosphors are suitable.
  • photoluminescent substances, especially with the emission of light in the yellow range metal sulfides and oxides, usually in combination with suitable activators, have proved favorable. These are available, for example, under the trade name Lumilux® N or as luminescent pigments improved in terms of stability, luminosity and persistence under the trade name LumiNova® from Nemoto / Japan.
  • dyes / pigments listed in the formulation of the lacquer layer or the color in amounts of 0.1 to 50 wt .-%, preferably with 1 to 25 wt .-%, most preferably 7 wt .-%, incorporated.
  • the pre-label material is available for customer-specific use.
  • the label After stamping / laser cutting the desired label geometries and the final inscription by laser beam with lettering, barcodes, logos, etc., the label is in its final form.
  • the label When incorporating, for example, luminescent color pigments into the color layer of the logo, the label has a characteristic afterglow after appropriate stimulation of the luminescent pigments, which allows easy and rapid identification as original label. Apart from the special light source and, if necessary, a screen against disturbing ambient light, no further complex equipment is necessary - after the test the label remains unchanged.
  • Such labels which contain phosphors which emit only in the visible wavelength range in the color of the logo, are also suitable for precisely fitting production (printing, stamping, application, etc.). Instead of separately applied printing or control markings can during processing In particular, after labeling and cutting the labels by laser beam of unpunched roll material, in a downstream control unit at a defined location of the label, the excitation and emission with suitable equipment as a tax stamp for further processing steps or for the production of the next label be used.
  • Customer-specific "fingerprints" of the labels can be realized by printing different logos. Especially regular lines and line patterns create characteristic patterns of luminous dots and are also particularly material and cost saving. After punching or laser cutting of the label and the application on the adhesive substrates a pattern with respect to colors and geometries can be identified by selecting a suitable illumination source at the edge of the label.
  • the label which consists of a lacquer layer, obtainable in that on a printed or embossed support carrier film, the lacquer layer is preferably applied solvent-free and then cured.
  • a hologram can be applied to the lacquer layer.
  • the lacquer layer is self-supporting and opaque pigmented and if the lacquer layer is electron beam hardened.
  • the support carrier film is a plastic film, in particular of polyester.
  • the printing of the support carrier film takes place in particular by the flexographic printing process, because the UV flexographic printing process has a very high degree of freedom with regard to the design of geometries and can provide good print quality, especially for web-like materials from paper to film at the lowest possible price.
  • the UV flexographic printing process has a very high degree of freedom with regard to the design of geometries and can provide good print quality, especially for web-like materials from paper to film at the lowest possible price.
  • a cliché provided with the logos and fonts is wetted with printing ink and transferred to a plastic film.
  • the ink can then be cured by physical activation (thermal, radiation chemistry) on the film.
  • the color should undergo a high adhesion to the film substrate; this is indispensable for further processing.
  • a pressure anchorage must be checked before further processing. For this one uses the cross-hatch test (DIN EN ISO 2409). The pressure should reach at least one rating of Gt 02 in the crosshatch test.
  • the corona treatment can be selected, which can be used inline printing.
  • the surface tension should be set to> 50 mN / m. This can be measured with standard test inks.
  • the UV curing should have a percentage power setting between 50% and 100% in order to ensure sufficient flexibility of the printing for the further processing processes.
  • the print should have a height of 0.1 ⁇ m to 15 ⁇ m. Preferably, a height of 1 to 5 microns to choose. Also, the pressure impression and - impression can be varied by the course of the pressure points.
  • the other conventional printing methods can be used, which are known as high-pressure process. These include book and screen printing.
  • the backing film can be printed with a variety of designs, such as company logos or advertising.
  • the printing of the support carrier film produces a negative impression on the visible surface of the first lacquer layer of the label according to the invention.
  • the impression of the printed support carrier foil in the first lacquer layer is present as a depression of 0.1 to 15 ⁇ m, preferably of 1 to 5 ⁇ m.
  • the production of the label according to the invention can furthermore be carried out on an embossed support carrier film, for example likewise on a polyester film of preferably 25 to 100 .mu.m thickness, in particular 50 .mu.m.
  • the backing film can be provided with a variety of designs, such as company logos or advertising.
  • the embossing of the support carrier film produces a negative impression on the visible surface of the first lacquer layer of the label according to the invention.
  • the embossing of the support carrier film can be made, for example, with a embossing plate (available from Gerhardt) in different thicknesses or depths.
  • the embossing depth depends on the set embossing pressure, which acts on the magnetic cylinder used in the embossing process and the type of counterpressure cylinder.
  • a jacket of the impression cylinder (for example, with tesaprint ® or with a polyester film) causes a strong embossing.
  • the embossing tool used can have holographic structures, so that the structure is formed on the lacquer layer and results in at least one hologram.
  • the side of the embossing tool facing the material to be stamped is thus shaped in such a way that a structure is produced which contains a diffraction grating or a holographic image.
  • the hologram is formed in the paint layer itself, a harmful multi-layer structure is not given, and the diffraction grating thus produced has the same durability and chargeability as the paint layer itself.
  • the support carrier film consists of a duroplastic or thermoplastic material which is permanently embossed, in particular of polyester or polyamide.
  • the lacquer layer is applied to the support carrier film and cured by the action of a high-energy electron beam (150 to 500 kV) under effectively oxygen-free conditions. Then the coating with the adhesive and then, if desired, the cover with the backing paper. Thereafter, the polyester film is peeled off, so that the free surface of the first, upper layer comes to light. Depending on the shape of the surface of the polyester film, this is glossy, smooth, matt or embossed.
  • the pressure-sensitive adhesive is, for example, a pressure-sensitive adhesive, as used in US Pat DE 15 69 898 C is disclosed. The content of the entire disclosure of this document is thus part of this invention.
  • an acrylate adhesive is applied with 25 to 35 g / m 2 mass.
  • the inventively designed adhesive layer Due to the inventively designed adhesive layer, there is no impairment of the label. The physical and chemical resistance are not changed. From the application point of view, the label does not suffer any loss of inscribability with a laser, readability of the information.
  • the label can be used to hide information, namely, when the label above an information that is located on a body, glued and lasered to hide the information, so that the information is no longer due to the resulting color change of the label is evaluable. It should be emphasized that this preserves the security feature of the label in the form of the logo, possibly also in the form of images or text, after emaciation, although it is not necessarily readable without auxiliary means.
  • Disposable beverage cans may be beverage cans (for example, coke, beer, etc.), disposable glass bottles with paper labels, disposable plastic bottles with paper labels, plastic-backed beverage containers, or direct-printed glass or plastic bottles.
  • FIG. 1 illustrated construction of the label according to the invention is a first PU-acrylate layer on a layer of an adhesive 2, in particular a pressure-sensitive adhesive, which is covered with a release paper 3.
  • an adhesive 2 in particular a pressure-sensitive adhesive
  • a release paper 3 When labeling with a laser, a single photon hits a pigment whose color changes, the formerly transparent layer 1 turns black.
  • a layer 12 is introduced in the form of a logo, which contains a UV radiation-responsive additive. Without damage or inactivation of the cast UV feature, a label of the label 11 can be made.
  • the layer 12 is translucent (transmissive) to the Nd-YAG laser beam at 1.06 ⁇ m so that the label 11 beneath the UV logo undergoes the normal color change process.
  • the area 13 represents the area marked by inscription, which completely obscures the background due to the color change that has taken place.
  • the following example is intended to disclose a particularly advantageous label made using a printed backing sheet such that imprints (positive or negative) result on the label surface resulting in a further high safety factor.
  • the backing sheet to be printed in this case a polyester film (Hostaphan RN 75®) from Mitsubishi, is treated before printing by corona treatment to the desired surface tension.
  • a corona station VETAPHON-Corona-Plus DK - E-Treater ET 2 - with an output of 0.2 to 2.0 kW can be used.
  • Advantageous for further processing is the adjustment of the surface tension to> 50 mN / m.
  • the pretreated polyester film is printed at a machine speed of 30 m / min via a flexographic printing station.
  • the well-defined ink transfer to the flexographic printing plate is achieved by means of a corresponding anilox roller in the negative doctor blade method. It then takes place the color transfer from the cliché to the film substrate in a color height of 3 to 4 microns.
  • the application of paint on the film substrate is cured by powerful UV radiation tubes. For this purpose, a UV station UV UV station GEW with a radiator output of 110 W / cm and a wavelength of 365 nm is used.
  • the backing film is now ready for further processing.
  • the polyester film is peeled off so that the provided with the impressions and otherwise mirror-smooth surface of the product comes to light.
  • a mixture which consists of a paint from SICPA, namely Sicura Flex 3600076, the 5 wt .-% Lumipaste 806205 are also mixed by the company SICPA.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Claims (18)

  1. Etiquette (11) pour le masquage d'informations, constituée d'au moins
    a) une couche de support (1) transparente, qui contient
    b) un additif présentant un changement de couleur sous irradiation laser, et qui d'un côté est revêtue
    c) d'une matière autoadhésive (2),
    caractérisée en ce que
    d) un logo (12) qui est constitué à base d'une encre comportant un pigment luminescent est placé sur la surface de la couche de support (1) qui est opposée à la surface comportant la matière autoadhésive (2).
  2. Etiquette (11) selon la revendication 1, caractérisée en ce que la couche de support (1) est constituée d'une matière plastique.
  3. Etiquette (11) selon la revendication 1 ou 2, caractérisée en ce que la couche de support (1) est constituée d'une laque.
  4. Etiquette (11) selon la revendication 3, caractérisée en ce que la couche de support (1) est constituée d'une laque durcie.
  5. Etiquette (11) selon la revendication 3 ou 4, caractérisée en ce que la couche de support (1) est constituée d'une laque durcie par irradiation.
  6. Etiquette (11) selon au moins l'une des revendications 3 à 5, caractérisée en ce que la couche de support (1) est constituée d'une laque cassante.
  7. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que la couche de support est constituée d'une laque polyuréthanne-acrylate durcie par irradiation avec un faisceau d'électrons.
  8. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que l'additif est un pigment, un pigment nacré à base de carbonate de plomb basique ou de mica avec du dioxyde de titane et/ou un colorant thermochrome.
  9. Etiquette (11) selon la revendication 8, caractérisée en ce que le pigment est de l'hydroxyphosphate de cuivre.
  10. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que l'additif est utilisé en quantités de 0,1 à 10 % en poids, par rapport au poids total de la couche de support (1).
  11. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que l'additif est utilisé en quantités de 0,5 à 5 % en poids, par rapport au poids total de la couche de support (1).
  12. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que le pigment est utilisé en plus de l'additif dioxyde de titane.
  13. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que la couche de support (1) a une épaisseur de 10 à 200 µm, en particulier de 50 à 100 µm.
  14. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que la couche de support (1) a une épaisseur de 50 à 100 µm.
  15. Etiquette (11) selon au moins l'une des revendications précédentes, caractérisée en ce que la matière autoadhésive est recouverte d'un papier de séparation (3) ou d'un film de séparation (3).
  16. Utilisation d'une étiquette (11) selon au moins l'une des revendications précédentes, pour le masquage d'informations.
  17. Utilisation d'une étiquette (11) selon au moins l'une des revendications précédentes, dans laquelle l'étiquette (11) est collée au-dessus d'une information qui se trouve sur un corps, et est exposée à un laser pour le masquage de l'information, de sorte qu'en raison du changement de couleur résultant de l'étiquette (11), l'information n'est plus exploitable.
  18. Utilisation d'une étiquette (11) selon au moins l'une des revendications précédentes, sur des emballages, un code-barre se trouvant au-dessous de l'étiquette (11).
EP03003978A 2002-03-14 2003-02-22 Etiquette pour l' occultation des informations Expired - Fee Related EP1345195B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10211744 2002-03-14
DE10211744 2002-03-14
DE10217120A DE10217120A1 (de) 2002-03-14 2002-04-17 Etikett zur Verdeckung von Informationen
DE10217120 2002-04-17

Publications (3)

Publication Number Publication Date
EP1345195A2 EP1345195A2 (fr) 2003-09-17
EP1345195A3 EP1345195A3 (fr) 2007-07-11
EP1345195B1 true EP1345195B1 (fr) 2008-05-28

Family

ID=27766701

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03003978A Expired - Fee Related EP1345195B1 (fr) 2002-03-14 2003-02-22 Etiquette pour l' occultation des informations

Country Status (4)

Country Link
US (1) US20040026921A1 (fr)
EP (1) EP1345195B1 (fr)
JP (1) JP2004029726A (fr)
DE (1) DE50309905D1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2325829A1 (fr) 2009-11-18 2011-05-25 KPSS Kao Professional Salon Services GmbH Étiquette, emballage, utilisation d'une étiquette adhésive et procédé de fourniture d'un échantillon de test

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19909723C5 (de) * 1999-03-05 2004-04-15 Daimlerchrysler Ag Sicherheits - Klebefolie als Identifizierungsträger
DE10139653A1 (de) * 2001-08-11 2003-02-20 Tesa Ag Etikett mit erhöhter Fälschungssicherheit
US20040232242A1 (en) * 2003-04-18 2004-11-25 Charles Bolta Language insensitive marking system using photo luminescent printing of bar coded emergency information
BRPI0415205A (pt) * 2003-10-09 2006-12-05 Securency Pty Ltd documento de segurança com material convertedor
US20050156318A1 (en) * 2004-01-15 2005-07-21 Douglas Joel S. Security marking and security mark
DE202004009980U1 (de) 2004-06-25 2005-11-03 Weidmüller Interface GmbH & Co. KG Markiervorrichtung
US7021549B2 (en) * 2004-06-30 2006-04-04 Illinois Tool Works, Inc. Laser markable variable data heat transfer label and marking system
DE102004038774A1 (de) * 2004-08-09 2006-02-23 Tesa Ag Laserfilm aus einer zumindest einschichtigen Trägerschicht aus einer transparenten Folie, die einseitig mit einer Selbstklebemasse beschichtet ist
DE102005061125A1 (de) * 2005-12-19 2007-06-21 Tesa Ag Etikett
KR100785432B1 (ko) * 2006-07-26 2007-12-13 율촌화학 주식회사 라벨 및 그 제조 방법
DE102006034809A1 (de) * 2006-07-27 2008-01-31 Bizerba Gmbh & Co. Kg Indikator zur Kennzeichnung von Waren
JP2008090063A (ja) * 2006-10-03 2008-04-17 Three M Innovative Properties Co レーザーマーキングラベル及びラベル付き物品
DE102007014083A1 (de) * 2007-03-21 2008-09-25 Dade Behring Marburg Gmbh Verfahren zur Verhinderung des mehrfachen Gebrauchs von Einmalartikeln in Analysegeräten
JP2009034905A (ja) * 2007-08-01 2009-02-19 Nitto Denko Corp レーザーマーキングラベル
KR101053298B1 (ko) * 2008-05-16 2011-08-01 율촌화학 주식회사 라벨 및 그 제조 방법
US9477152B2 (en) * 2012-09-27 2016-10-25 E I Du Pont De Nemours And Company Printing form precursor having indicia and a method for preparing a printing form from the precursor
DE102012218033B4 (de) * 2012-10-02 2019-02-21 Tesa Se Versiegelungsetikett und ein Herstellungsverfahren dafür
WO2014059253A1 (fr) * 2012-10-11 2014-04-17 The Procter & Gamble Company Contenant moulé à revêtement vernis structuré
GB201222961D0 (en) * 2012-12-19 2013-01-30 Innovia Films Ltd Label
EP2746043A1 (fr) * 2012-12-20 2014-06-25 3M Innovative Properties Company Matériau stratifié à double fonctionnalité
CN106575369B (zh) * 2014-07-31 2019-09-13 3M创新有限公司 柔性基底上的rfid标签
CN113247434A (zh) * 2021-05-24 2021-08-13 李峰 隐形标签、产品包装和产品表面粘贴物
CN113554935B (zh) * 2021-06-17 2023-08-22 南京邮电大学 一种光响应型激光防伪标签、制备方法及其应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8130861U1 (de) * 1981-10-22 Beiersdorf Ag, 2000 Hamburg Mehrschichtiges Etikett
AT274180B (de) * 1965-05-19 1969-09-10 Beiersdorf Ag Verfahren zur Herstellung von lösungsmittel- und wärmebeständigen Selbstklebebändern oder -folien
FR2580233B1 (fr) * 1985-04-12 1988-11-25 Rhone Alpes Projets Plast Procede pour rendre une matiere plastique sensible au rayon laser et permettre son marquage au laser et article obtenu notamment pour le marquage des animaux
US5127675A (en) * 1986-11-17 1992-07-07 Moss James W Method for marking an article for identification and description and a label device therefor
DE4421865A1 (de) * 1994-06-22 1996-01-04 Beiersdorf Ag Einschichtlaseretikett
DE19509505C1 (de) * 1995-03-16 1996-01-25 Beiersdorf Ag Mehrschichtiges Etikett
DE19531332C2 (de) * 1995-08-25 1998-07-16 Beiersdorf Ag Verwendung von Etiketten zur Kennzeichnung von Gummiteilen, insbesondere Reifen
DE19642040C1 (de) * 1996-10-11 1998-01-15 Schreiner Etiketten Mit einem Laserstrahl beschriftbare Folie
DE19746998B4 (de) * 1997-10-24 2008-06-05 Tesa Ag Laseretiketten und ihre Verwendung
DE19747000C2 (de) * 1997-10-24 2003-10-30 Tesa Ag Laseretiketten und ihre Verwendung
DE10132848C1 (de) * 2001-07-06 2003-01-30 Sulo Umwelttechnik Gmbh & Co Kg Kennzeichnungssystem
DE10139653A1 (de) * 2001-08-11 2003-02-20 Tesa Ag Etikett mit erhöhter Fälschungssicherheit
US20040247832A1 (en) * 2001-11-26 2004-12-09 Arne Koops Label with improved anti-forgery security

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2325829A1 (fr) 2009-11-18 2011-05-25 KPSS Kao Professional Salon Services GmbH Étiquette, emballage, utilisation d'une étiquette adhésive et procédé de fourniture d'un échantillon de test
WO2011061149A1 (fr) 2009-11-18 2011-05-26 Kpss-Kao Professional Salon Service Gmbh Etiquette, emballage, utilisation d'une étiquette adhésive et procédé d'obtention d'un échantillon d'essai

Also Published As

Publication number Publication date
JP2004029726A (ja) 2004-01-29
EP1345195A2 (fr) 2003-09-17
US20040026921A1 (en) 2004-02-12
DE50309905D1 (de) 2008-07-10
EP1345195A3 (fr) 2007-07-11

Similar Documents

Publication Publication Date Title
EP1345195B1 (fr) Etiquette pour l' occultation des informations
EP1283511B1 (fr) Etiquette avec protection contre la falsification ameliorée
EP0911787B1 (fr) Etiquettes à laser et leur application
EP1966338A1 (fr) Etiquette a securite elevee contre la falsification
EP1818893B1 (fr) Etiquette auto-adhésive, méthode de fabrication et son utilisation
CN101076453B (zh) 具有与视角有关特性的安全元件
EP0911786B1 (fr) Etiquettes à laser et leur application
EP0695237B1 (fr) Feuille a marquer a chaud
EP1451791B1 (fr) Etiquette a securite amelioree contre la falsification
DE102007034636A1 (de) Lasersensitives Etikett mit einer Trägerschicht aus Polyolefin
DE10048665B4 (de) Verfahren zur Herstellung eines Etiketts mit erhöhter Fälschungssicherheit
EP0732678A1 (fr) Etiquette multicouche
EP2296911A2 (fr) Procédé de fabrication d'un produit de sécurité et/ou de valeur présentant un motif aléatoire et une chaîne de caractères d'identification corrélée
DE102008034022A1 (de) Verfahren zur Herstellung eines Sicherheits- und/oder Wertprodukts mit Teilbereichen mit unterschiedlicher Lumineszenzemission
WO2007071545A1 (fr) Etiquette
WO2007071547A1 (fr) Etiquette a securite elevee contre la falsification
DE10217120A1 (de) Etikett zur Verdeckung von Informationen
EP1565323B1 (fr) Elements de securite presentant des proprietes activables par apport d'energie
DE10227084A1 (de) Verfahren zur Herstellung einer Großrolle Etikettenmaterial sowie Verfahren zur Herstellung von Etiketten aus der Großrolle
DE202006013892U1 (de) Haftverbund

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: TESA AG

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO

17P Request for examination filed

Effective date: 20070502

17Q First examination report despatched

Effective date: 20070831

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT SE SI SK TR

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

RBV Designated contracting states (corrected)

Designated state(s): DE ES FR GB IT

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE ES FR GB IT

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REF Corresponds to:

Ref document number: 50309905

Country of ref document: DE

Date of ref document: 20080710

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080908

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20090303

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080528

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20090222

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20091030

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090222

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090302

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20100228

Year of fee payment: 8

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 50309905

Country of ref document: DE

Effective date: 20110901

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110901