EP2242866A1 - Système de couches calorifuges et son procédé de fabrication - Google Patents

Système de couches calorifuges et son procédé de fabrication

Info

Publication number
EP2242866A1
EP2242866A1 EP09708297A EP09708297A EP2242866A1 EP 2242866 A1 EP2242866 A1 EP 2242866A1 EP 09708297 A EP09708297 A EP 09708297A EP 09708297 A EP09708297 A EP 09708297A EP 2242866 A1 EP2242866 A1 EP 2242866A1
Authority
EP
European Patent Office
Prior art keywords
layer
aps
sps
thermal barrier
barrier coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09708297A
Other languages
German (de)
English (en)
Inventor
Alexandra Stuke
Holger Kassner
Robert Vassen
Detlef STÖVER
Josè-Luis MARQUÈS-LOPEZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Forschungszentrum Juelich GmbH
Original Assignee
Forschungszentrum Juelich GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Forschungszentrum Juelich GmbH filed Critical Forschungszentrum Juelich GmbH
Publication of EP2242866A1 publication Critical patent/EP2242866A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/36Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including layers graded in composition or physical properties
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C23C4/11Oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134Plasma spraying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249981Plural void-containing components

Definitions

  • the turbine inlet temperature of about 1230 0 C to about 1350 0 C is necessary.
  • This goal can be achieved by using ceramic thermal barrier coatings in addition to the use of improved base materials and effective cooling methods.
  • the permissible surface temperature can be increased by a few 100 K by the thermal insulating effect of the ceramic thermal barrier layer while maintaining the same cooling conditions depending on the thickness of the thermal barrier coating.
  • the greater thermal load often leads to a shortened life of the thermal layer system.
  • thermal conductivity of thermal barrier coatings can be achieved by using ceramic materials with a correspondingly small intrinsic
  • Thermal conductivity can be reliably achieved.
  • thermal barrier coatings in the form of duplex structures are used.
  • the first layer consists of a metallic layer, which has the task of protecting the underlying substrate (component) from corrosion and oxidation.
  • this layer usually serves as a primer layer for the actual thermal barrier coating, as the second layer of the duplex structure.
  • This second layer which performs the actual function of thermal insulation, is often a ceramic layer.
  • These typically consist of yttria-stabilized zirconia (YSZ) or other oxide ceramics.
  • YSZ yttria-stabilized zirconia
  • Newer thermal barrier coating systems sometimes also have multilayer coating systems of various ceramics.
  • suspension solution evaporates abruptly and the small solid particles are aggregated into partially or completely molten droplets, accelerated and impacted on the substrate in order to form a layer there.
  • the suspension plasma spraying can be used for coatings of both ceramic and metallic materials, wherein in each case very fine, dense spherical particles are used.
  • thermal barrier coatings are determined by the thermal conductivity of the material of the thermal barrier coating and by the layer thickness. Under the insulating effect of thermal barrier coatings is understood here the temperature drop across the thermal barrier coating. The layer thickness is limited due to mechanical properties to be fulfilled and can not be made arbitrarily large. These two parameters represent a principal barrier for all thermal barrier coating systems.
  • the APS layer can be used in particular as a mechanically and erosively stable layer and the SPS layer in particular for improving the reflectivity and reducing the thermal conductivity.
  • the advantages of the individual layers can be optimally combined, thus enabling applications that can not be fulfilled by the single-layer systems.
  • the solids content of the powder in the suspension was 10% by weight (Example 1) and 20% by weight (Example 2).
  • the suspension pressure was 2 bar and was operated at an air pressure of 0.5 bar.
  • the layer thickness of the SPS layer was varied between 60 and 150 ⁇ m.
  • the thermal conductivity of this layer was only 0.58 W / mK, the layer having a porosity of about 29%.
  • FIGS. 4a to 4c Shown in FIGS. 4a to 4c are photographs of the layer systems according to the invention.
  • the microstructures in the transverse section of the two double layers are shown in FIGS. 4a and 4b.
  • the layer thickness of the SPS layer is 60 or 150 ⁇ m and for the APS layer 270 or 200 ⁇ m.
  • the SPS layer is interspersed with significantly finer pores and cracks are visible, which in particular pass vertically through the layer. Within the APS layer significantly coarser pores are represented.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Ceramic Engineering (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

La présente invention concerne un procédé de fabrication d'un système de couches sur un composant. Selon le procédé, au moins au moins une couche est déposée sur le composant par pulvérisation plasma atmosphérique (APS) et au moins une autre couche est déposée sur le composant par pulvérisation plasma en suspension (SPS). De manière avantageuse, on dépose en particulier les couches dans l'ordre suivant APS + SPS ou APS + SPS + APS ou également APS + SPS + couche d'érosion. Ces séries de couches ainsi appliquées ont ordinairement pour effet la création d'une première couche poreuse ainsi que d'une seconde couche poreuse disposée sur la première, la porosité et la réflectivité de la seconde couche étant supérieures à celle de la première couche. L'augmentation de la réflectivité de la couche, en particulier dans la gamme de longueurs d'ondes d'infrarouges visibles (VIS) et proches (NIR), produit de manière avantageuse une contrainte thermique plus faible du matériau de substrat, étant donné que seule une part plus faible de rayonnement thermique pénètre à travers la couche calorifuge céramique et entraîne ainsi un réchauffement moindre du substrat (composant).
EP09708297A 2008-02-06 2009-01-29 Système de couches calorifuges et son procédé de fabrication Withdrawn EP2242866A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200810007870 DE102008007870A1 (de) 2008-02-06 2008-02-06 Wärmedämmschichtsystem sowie Verfahren zu seiner Herstellung
PCT/DE2009/000120 WO2009097834A1 (fr) 2008-02-06 2009-01-29 Système de couches calorifuges et son procédé de fabrication

Publications (1)

Publication Number Publication Date
EP2242866A1 true EP2242866A1 (fr) 2010-10-27

Family

ID=40568290

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09708297A Withdrawn EP2242866A1 (fr) 2008-02-06 2009-01-29 Système de couches calorifuges et son procédé de fabrication

Country Status (4)

Country Link
US (1) US20110244216A1 (fr)
EP (1) EP2242866A1 (fr)
DE (1) DE102008007870A1 (fr)
WO (1) WO2009097834A1 (fr)

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EP2450465A1 (fr) * 2010-11-09 2012-05-09 Siemens Aktiengesellschaft Système de couche poreux doté d'une couche intérieure poreuse
DE102011103731A1 (de) * 2011-05-31 2012-12-06 Man Diesel & Turbo Se Verfahren zum Aufbringen einer Schutzschicht, mit einer Schutzschicht beschichtetes Bauteil und Gasturbine mit einem solchen Bauteil
US20130260132A1 (en) * 2012-04-02 2013-10-03 United Technologies Corporation Hybrid thermal barrier coating
US9052111B2 (en) 2012-06-22 2015-06-09 United Technologies Corporation Turbine engine combustor wall with non-uniform distribution of effusion apertures
US9556505B2 (en) 2012-08-31 2017-01-31 General Electric Company Thermal barrier coating systems and methods of making and using the same
US11047033B2 (en) * 2012-09-05 2021-06-29 Raytheon Technologies Corporation Thermal barrier coating for gas turbine engine components
DE102012218198A1 (de) 2012-10-05 2014-04-10 Lufthansa Technik Ag Wärmedämmschicht, Gasturbinenbauteil und Verfahren zur Beschichtung eines Gasturbinenbauteils
WO2014126633A2 (fr) * 2012-12-26 2014-08-21 United Technologies Corporation Revêtement de barrière thermique résistant à l'éclatement
EP2971240B1 (fr) * 2013-03-14 2018-11-21 United Technologies Corporation Revêtement de barrière thermique hybride et son procédé de fabrication
DE102013217627A1 (de) * 2013-09-04 2015-03-05 MTU Aero Engines AG Wärmedämmschichtsystem mit Korrosions- und Erosionsschutz
EP2865781A1 (fr) * 2013-10-22 2015-04-29 Siemens Aktiengesellschaft Couche céramique à deux couches dotée de microstructures différentes
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US20150147524A1 (en) * 2013-11-26 2015-05-28 Christopher A. Petorak Modified thermal barrier composite coatings
DE102014208216A1 (de) * 2014-04-30 2015-11-05 Siemens Aktiengesellschaft CMAS resistente keramische Schicht durch Nanoporosität
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FR3057580A1 (fr) 2016-10-18 2018-04-20 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede de revetement d'une surface d'un substrat solide par une couche comprenant un compose ceramique, et substrat revetu ainsi obtenu
US20190017177A1 (en) 2017-07-17 2019-01-17 Rolls-Royce Corporation Thermal barrier coatings for components in high-temperature mechanical systems
US10822951B2 (en) * 2017-07-21 2020-11-03 Raytheon Technologies Corporation Suspension plasma spray abradable coating for cantilever stator
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Also Published As

Publication number Publication date
WO2009097834A1 (fr) 2009-08-13
US20110244216A1 (en) 2011-10-06
DE102008007870A1 (de) 2009-08-13

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