EP2220708A1 - Plaque bipolaire et procédé de réalisation d'une couche de protection sur une plaque bipolaire - Google Patents

Plaque bipolaire et procédé de réalisation d'une couche de protection sur une plaque bipolaire

Info

Publication number
EP2220708A1
EP2220708A1 EP07856759A EP07856759A EP2220708A1 EP 2220708 A1 EP2220708 A1 EP 2220708A1 EP 07856759 A EP07856759 A EP 07856759A EP 07856759 A EP07856759 A EP 07856759A EP 2220708 A1 EP2220708 A1 EP 2220708A1
Authority
EP
European Patent Office
Prior art keywords
protective layer
bipolar plate
cations
layer
oxide system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07856759A
Other languages
German (de)
English (en)
Inventor
Thomas Kiefer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ElringKlinger AG
Original Assignee
ElringKlinger AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ElringKlinger AG filed Critical ElringKlinger AG
Publication of EP2220708A1 publication Critical patent/EP2220708A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0223—Composites
    • H01M8/0228—Composites in the form of layered or coated products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0215—Glass; Ceramic materials
    • H01M8/0217—Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites
    • H01M8/0219—Chromium complex oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a bipolar plate for a fuel cell unit, wherein the bipolar plate comprises a carrier layer and a protective layer, wherein the protective layer comprises a minimum binary oxide system with at least two different types of metal cations.
  • bipolar plates also referred to as interconnectors
  • bipolar plate must meet the following requirements:
  • Distribution of the media (fuel gas and / or oxidant).
  • chromium oxide is formed on the surface of a chromium oxide-forming stainless steel. Under the operating conditions of a fuel cell, volatile chromium compounds are formed from this chromium oxide. This "chromium vaporization" causes poisoning of the cathode, in particular during long-term operation of the fuel cell unit, as a result of which the current efficiency is drastically reduced.
  • a protective layer is produced by a sintering process of a wet-chemically applied oxide layer (Mn f5 C ⁇ i # 5 O 4 ) under a reducing atmosphere.
  • a paste containing a binder and oxides of nominal composition Mni / 5 C ⁇ i, 5 O 4 is applied to a steel material.
  • the sintering takes place in two separate temperature treatment steps. In the first temperature cycle, the lattice structure of the protective layer is weakened by a reduction of the oxygen partial pressure, whereby a better sintering behavior occurs. In a separate, subsequent temperature treatment step, the lattice structure is fully oxidized again, ie the missing oxygen is re-incorporated into the lattice.
  • the resulting microstructure of the protective layer has numerous pores and cracks.
  • the protective layer thus produced therefore, has no sustainable chromium retention ability.
  • the physical material properties of the protective layer in particular its electrical conductivity and the thermal expansion behavior, are not optimally adapted to the requirements of a bipolar plate for a fuel cell unit.
  • the present invention has for its object to provide a bipolar plate of the type mentioned, the protective layer reliably reduces a chromium evaporation in long-term operation and also meets the other requirements for a bipolar plate.
  • This object is achieved in a bipolar plate having the features of the preamble of claim 1 according to the invention in that one type of metal cations of the oxide system of the protective layer is iron.
  • the addition of iron improves the microstructure of the protective layer (in particular with regard to the reduction of cracks and pores).
  • the iron thus has a positive effect on the sintering behavior of the protective layer.
  • the improved microstructure of the protective layer is an indication of greater freedom from defects of the protective layer. Since the chromium diffusion is based inter alia on lattice defects, a defect-free protective layer ensures lasting chrome retention.
  • the addition of iron also reduces the coefficient of thermal expansion of the protective layer and thus adapts it better to the thermal expansion coefficient of the other components of the fuel cell unit. This results in lower mechanical stresses during a temperature cycle (heating to operating temperature and cooling) of the fuel cell stack.
  • the oxide system of the protective layer has a spinel structure.
  • the oxide system has at least one type of metal cation whose oxide is more unstable than chromium oxide (whose stability limit in the Ellingham diagram is therefore higher than the stability limit of chromium oxide). Furthermore, it is favorable if the oxide system has at least one type of metal cation whose oxide is more stable than chromium oxide (whose stability limit in the Ellingham diagram is therefore lower than the stability limit of chromium oxide).
  • the oxide system of the protective layer is an at least ternary oxide system with at least three different types of metal cations.
  • one type of metal cations of the oxide system of the protective layer Mn is provided.
  • the oxide system comprises Mn, Co and Fe cations.
  • the oxide system has approximately the composition MnCo 2 - ⁇ Fe x O 4 , where 0 ⁇ x ⁇ 1.
  • the oxide system with the approximate composition MnC ⁇ i , 9 Fe 0, 10 4 proved to be particularly favorable.
  • the oxide system of the protective layer comprises Mn, Cu and Fe cations.
  • the composition of the protective layer of the bipolar plate is preferably selected so that the thermal expansion coefficient ⁇ of the protective layer of about 10-10 "6 K” 1 to about 20-10 “6 K” 1, preferably from about 11.5 to 10 "6 K “1 to about 13.5-10 “ 6K "1 .
  • Such a thermal expansion coefficient is particularly well adapted to the thermal expansion behavior of the other components of the bipolar plate and the fuel cell unit.
  • the specific electrical conductivity ⁇ of the protective layer is preferably from about 0.01 S / cm to about 200 S / cm.
  • the bipolar plate according to the invention is particularly suitable for use in a high-temperature fuel cell, in particular a SOFC (solid oxide fuel cell), with an operating temperature of, for example, at least 600 ° C.
  • a SOFC solid oxide fuel cell
  • the present invention further relates to a method for producing a protective layer on a bipolar plate for a fuel cell unit.
  • the invention has the further object of providing such a method, whereby a protective layer is produced, which has a good chromium retention capability even in long-term operation and also meets the other requirements to be placed on a bipolar plate.
  • the sintering temperature (usually up to 900 ° C-1100 ° C) can be lowered (in the range of about 750 ° C to about 800 ° C).
  • the sintering time (usually 10 hours) can be shortened (for example, at most about 3 hours).
  • manufacturing costs can be saved and corrosive previous damage, in particular by the growth of a Cr 2 O 3 layer at elevated temperature and an associated lower electrical conductivity can be reduced.
  • the reducing atmosphere is preferably chosen so that at least one of the metal oxides of the oxide system of the protective layer becomes unstable, so that the associated metal cations have a higher reactivity, while the reducing atmosphere is simultaneously selected such that unwanted elements from the base material of the bipolar plate (especially chromium) are oxidic.
  • the oxidic form means a higher chemical stability and thus a lower reactivity.
  • the temperature and the oxygen partial pressure are selected such that the temperature determined by the sintering temperature and the sintering oxygen partial pressure defined state point in the Ellingham diagram is above the stability limit of chromium oxide but below the stability limit of at least one metal oxide whose metal cation is contained in the protective layer precursor.
  • the carrier layer is not cooled with the starting material between raising the temperature to sintering temperature and increasing the partial pressure of oxygen.
  • the protective layer can be produced in a single temperature cycle, with no intervening cooling to room temperature, which has a positive effect on the manufacturing costs and the microstructure of the protective layer.
  • the starting material is applied wet-chemically to the carrier layer.
  • the starting material can for example be sprayed onto the carrier layer or applied by screen printing on the carrier layer.
  • Fig. 1 is an Ellingham diagram showing the stability limits of
  • Figure 2 is a photomicrograph of a section through a Crofer22 APU substrate and a protective layer of the composition which has been sintered in a reducing atmosphere at a sintering temperature of 800 ° C. for 3 hours;
  • FIG. 3 shows a schematic section corresponding to FIG. 2 through a bipolar plate with a protective layer and an intermediate layer arranged between the protective layer and a base material of the bipolar plate.
  • a carrier layer made of a ferritic chromium-forming stainless steel is provided, for example made from the stainless steel Crofer22 APU, which has the following composition: 22.2% by weight Cr; 0.46 weight percent Mn; 0.06 wt% Ti; 0.07 weight percent La; 0.002 weight percent C; 0.02 weight percent Al; 0.03 weight percent Si; 0.004 weight percent N; 0.02 weight percent Ni; Rest iron.
  • a suspension is sprayed onto this carrier layer in a wet spraying process which has the following composition: 1 part by weight of a ceramic powder; 1.5 parts by weight of ethanol; 0.04 parts by weight of a dispersing agent (for example Dolapix ET85); 0.1 parts by weight of a binder (for example, polyvinyl acetate, PVAC).
  • a dispersing agent for example Dolapix ET85
  • a binder for example, polyvinyl acetate, PVAC
  • the ceramic powder for the suspension is prepared as follows: First, an amount of three different metal oxides, for example Mn 2 O 3 , Co 3 O 4 and Fe 2 O 3 , is weighed out so that the numerical ratio of the respective metal cations (eg Mn, Co, Fe) is the numerical ratio in the desired composition of the protective layer to be produced (eg 1: 1.9: 0.1 in the composition MnC ⁇ i, 9 Feo, i0 4 ).
  • Mn, Co, Fe the numerical ratio in the desired composition of the protective layer to be produced
  • the weighed metal oxide powders are filled into a polyethylene bottle along with ethanol and ZrO 2 milling balls (approximately 3 mm in average diameter).
  • the weight ratio of powder: ethanol: grinding balls is approximately 1: 2: 3.
  • the polyethylene bottle is sealed and turned on a roll bar for 48 hours.
  • the rotational speed of the bottle is 250 rpm, for example.
  • the ZrO 2 milling balls are removed from the mixture, and the ceramic powder is dried. Subsequently, the ceramic powder is calcined at a temperature of 900 0 C with a holding time of six hours. The powder is heated at a heating rate of 3 K / min and cooled after the holding time unregulated (natural cooling).
  • the ceramic powder thus obtained is blended with ethanol, dispersant and binder to the suspension of the above composition.
  • the suspension obtained in this way is sprayed onto the carrier layer by a spray nozzle in a wet spraying process.
  • the diameter of the nozzle opening, with which the suspension is atomized to about 0.5 mm.
  • the injection pressure with which the suspension is conveyed to the nozzle is, for example, 0.3 bar.
  • the spraying distance of the nozzle to the carrier layer (substrate) is for example 15 cm.
  • the nozzle is moved over the carrier layer at a speed of 230 mm / s.
  • the layer of protective layer precursor is cured in two to four coating cycles, i. by spraying each surface area of the carrier layer two to four times, applied to the carrier layer.
  • a screen printing method may also be used to apply the ceramic powder to the carrier layer.
  • a paste is prepared which contains, for example, 50% by weight of the ceramic powder, 47% by weight of terpineol and 3% by weight of ethylcellulose.
  • the ceramic powder is produced in the same way as described above in connection with the wet spraying process.
  • the ingredients of the paste are homogenized in a roller mill.
  • the paste is applied from the protective layer precursor material to the carrier layer of the bipolar plate by means of a screen printing machine known per se to a person skilled in the art.
  • the carrier layer with the layer of the protective layer precursor applied is first sintered in a subsequent temperature treatment under reduced oxygen partial pressure.
  • the carrier layer with the protective layer precursor disposed thereon is introduced into a sintering furnace.
  • the oxygen partial pressure is lowered in the sintering furnace, for example, by rinsing by means of a mixture of an inert gas (for example argon) and for example 4 mole percent hydrogen, which has been previously moistened at a temperature of 25 ° C, so that the gas mixture has a water content of about 3 weight percent having.
  • the furnace is heated, so that the carrier layer with the starting material arranged thereon to a sintering temperature of at least about 750 0 C, preferably in the range of about 750 0 C to 800 0 C heated becomes.
  • the carrier layer with the precursor material arranged thereon is held in a first sintering phase during a sintering time of, for example, about 3 hours, whereby the layer of the protective layer precursor material is sintered.
  • the lowering of the oxygen partial pressure causes a decomposition of the original spinel structure of the sintering additives, whereby the reactivity is increased and the associated compression process of the protective layer is accelerated.
  • the temperature is changed to an atmospheric oxygen partial pressure in order to restore the desired and chemically stable spinel structure of the protective layer in a second sintering phase.
  • the temperature of the protective layer or the protective layer Vormaterials between the sintering process at reduced oxygen partial pressure and the increase of the oxygen partial pressure to an atmospheric oxygen partial pressure is not lowered to a temperature below 750 0 C.
  • the lowered oxygen partial pressure during the sintering process is about 10 "18 , for example.
  • the sintering temperature through line 100 and the reduced oxygen partial pressure during the first sintering phase are indicated by line 102.
  • the intersection 104 of the lines 100 and 102 characterizes the conditions in the first sintering phase.
  • This intersection point 104 is below the stability limit 106 of cobalt in the Ellingham diagram, but above the stability limit 108 of iron, above the stability limit 110 of chromium and above the stability limit 112 of manganese.
  • the oxides of iron, chromium and manganese are stable, while the oxides of cobalt are unstable.
  • the cobalt cations therefore show a higher reactivity and thus a higher sintering activity under these conditions, whereas unwanted elements of the steel of the carrier layer, in particular chromium, are present in an oxidic form.
  • the oxidic form means a higher chemical stability and thus a lower reactivity.
  • the sintering temperature which is usually up to 900 0 C - 1,100 0 C, reduced to about 750 0 C to 800 0 C and the sintering time , which is usually 10 hours, be shortened to about 3 hours.
  • costs can be saved in the production of the bipolar plate and corrosive preliminary damage (degradation) of the carrier layer and the protective layer, in particular excessive growth of a chromium oxide layer between the carrier layer and the protective layer at elevated sintering temperature can be reduced.
  • the bipolar plate obtained from the carrier layer 116, the protective layer 118 having the composition, obtained after completion of the second sintering phase (under atmospheric oxygen partial pressure), designated as a whole by 114 MnC ⁇ i , 9 Feo, i0 4 and an intermediate layer 120 formed between the carrier layer 116 and the protective layer 118, which contains cobalt manganese iron chromate, are shown in FIG. 3 in a purely schematic longitudinal section and in FIG. 2 in a real, shown microscopic longitudinal section.
  • the presence of iron cations in the starting material of the protective layer 118 improves the microstructure of the protective layer 118; In particular, the protective layer 118 has only a few cracks and pores.
  • the iron cations thus have a positive effect on the sintering behavior.
  • the improved microstructure of the protective layer 118 is an indication of a high freedom of defect of the protective layer. Since the chromium diffusion is based, inter alia, on the presence of lattice defects, a sustainable retention of chromium in the carrier layer 116 and the intermediate layer 120 is ensured by a protective layer 118 which is as defect-free as possible.
  • thermal expansion coefficient ⁇ of the prepared in the manner described above, protective layer 118 is from about 10-10 "6 K” 1 to about 20 10 "6 K '1.
  • the specific electrical conductivity ⁇ of the protective layer 118 is from about 0.01 S / cm to about 200 S / cm.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)

Abstract

L'invention concerne une plaque bipolaire pour un bloc de piles à combustible, la plaque bipolaire comprenant une couche de support (116) et une couche de protection (118), la couche de protection comprenant un système oxyde au moins binaire possédant au moins deux différents types de cations métalliques. Le but de l'invention est d'obtenir une couche de protection réduisant de manière fiable l'évaporation du chrome même lors d'une utilisation de longue durée, tout en répondant aux autres exigences auxquelles une plaque bipolaire doit satisfaire. A cet effet, un type de cations métalliques du système oxyde de la couche de protection est Fe.
EP07856759A 2007-12-14 2007-12-14 Plaque bipolaire et procédé de réalisation d'une couche de protection sur une plaque bipolaire Withdrawn EP2220708A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2007/011021 WO2009076977A1 (fr) 2007-12-14 2007-12-14 Plaque bipolaire et procédé de réalisation d'une couche de protection sur une plaque bipolaire

Publications (1)

Publication Number Publication Date
EP2220708A1 true EP2220708A1 (fr) 2010-08-25

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EP07856759A Withdrawn EP2220708A1 (fr) 2007-12-14 2007-12-14 Plaque bipolaire et procédé de réalisation d'une couche de protection sur une plaque bipolaire

Country Status (3)

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US (1) US20090155667A1 (fr)
EP (1) EP2220708A1 (fr)
WO (1) WO2009076977A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2491608B1 (fr) * 2009-10-22 2014-04-16 Electricité de France Interconnecteur pour pile à combustible et électrolyseur à électrolyte solide fonctionnant à haute température
DK2676318T3 (en) 2011-02-15 2016-06-27 Plansee Se A layered structure as well as its use for forming a ceramic layered structure between an interconnector and a cathode by a high temperature fuel cell.
JP2013118178A (ja) * 2011-10-31 2013-06-13 Osaka Gas Co Ltd 固体酸化物形燃料電池
JP2013118177A (ja) * 2011-10-31 2013-06-13 Osaka Gas Co Ltd 固体酸化物形燃料電池
WO2014031622A1 (fr) * 2012-08-21 2014-02-27 Bloom Energy Corporation Systèmes et procédés de suppression d'empoisonnement au chrome dans des piles à combustible
JP6268209B2 (ja) * 2016-02-26 2018-01-24 日本特殊陶業株式会社 燃料電池発電単位および燃料電池スタック

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPN173595A0 (en) 1995-03-15 1995-04-06 Ceramic Fuel Cells Limited Fuel cell interconnect device
DE102005015755A1 (de) 2005-04-06 2006-10-12 Forschungszentrum Jülich GmbH Verfahren zur Herstellung einer Chromverdampfungsschutzschicht für chromoxidbildende Metallsubstrate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
KIEFER T ET AL: "Electrical conductivity and thermal expansion coefficientes of spinels in the series MnCo2-xFexO4 for application as a protective layer in SOFC", SOLID STATE ELECTROCHEMISTRY : PROCEEDINGS OF THE 26TH RISÖ INTERNATIONAL SYMPOSIUM ON MATERIALS SCIENCE, 4 - 8 SEPTEMBER 2005, RISÖ NATIONAL LABORATORY, ROSKILDE, DENMARK, ROSKILDE, DENMARK : RISÖ NATIONAL LABORATORY, DK, 4 September 2005 (2005-09-04), pages 261 - 266, XP008149469, ISBN: 87-550-3455-1 *

Also Published As

Publication number Publication date
US20090155667A1 (en) 2009-06-18
WO2009076977A1 (fr) 2009-06-25

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