EP2129488A1 - Article abrasif et procédé de fabrication et d'utilisation de celui-ci - Google Patents

Article abrasif et procédé de fabrication et d'utilisation de celui-ci

Info

Publication number
EP2129488A1
EP2129488A1 EP08730687A EP08730687A EP2129488A1 EP 2129488 A1 EP2129488 A1 EP 2129488A1 EP 08730687 A EP08730687 A EP 08730687A EP 08730687 A EP08730687 A EP 08730687A EP 2129488 A1 EP2129488 A1 EP 2129488A1
Authority
EP
European Patent Office
Prior art keywords
filter medium
nonwoven filter
abrasive
abrasive article
article according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08730687A
Other languages
German (de)
English (en)
Other versions
EP2129488B1 (fr
Inventor
Edward J. Woo
Thomas W. Rambosek
Seyed A. Angadjivand
Mary B. Donovan
Rufus C. Jr. Sanders
Yeun-Jong Chou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of EP2129488A1 publication Critical patent/EP2129488A1/fr
Application granted granted Critical
Publication of EP2129488B1 publication Critical patent/EP2129488B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B55/00Safety devices for grinding or polishing machines; Accessories fitted to grinding or polishing machines for keeping tools or parts of the machine in good working condition
    • B24B55/06Dust extraction equipment on grinding or polishing machines
    • B24B55/10Dust extraction equipment on grinding or polishing machines specially designed for portable grinding machines, e.g. hand-guided
    • B24B55/102Dust extraction equipment on grinding or polishing machines specially designed for portable grinding machines, e.g. hand-guided with rotating tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/02Backings, e.g. foils, webs, mesh fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D9/00Wheels or drums supporting in exchangeable arrangement a layer of flexible abrasive material, e.g. sandpaper
    • B24D9/08Circular back-plates for carrying flexible material

Definitions

  • Abrasive articles are used in industry for abrading, grinding, and polishing applications. They may be obtained in a variety of converted forms, such as belts, discs, sheets, and the like, in many different sizes.
  • a back-up pad is used to mount or attach the abrasive article to the abrading tool.
  • One type of back-up pad has dust collection holes connected by a series of grooves.
  • the dust collection holes are typically connected to a vacuum source to help control particles such as, for example, swarf (as used herein, the term “swarf refers loose material such as dust and debris generated during abrading processes) build-up on the abrading surface of the abrasive article. Removing swarf from the abrading surface is known to improve the performance of the abrasive article.
  • swarf loose material such as dust and debris generated during abrading processes
  • Some abrasive tools have integral vacuum systems with dust collection means.
  • dust is collected in a complex collection system through a hose connected to the abrasive tools. Dust collection systems, however, are not always available for the abrasive tool operator. Further, the use of dust collection systems requiring hoses may be cumbersome and may interfere with the operator's manipulation of the abrasive tool.
  • the present invention provides an abrasive article comprising: a porous abrasive member comprising: an abrasive layer proximate and affixed to a first surface of a substrate, the abrasive layer comprising a plurality of abrasive particles affixed to the first surface of the substrate by at least one binder, wherein the abrasive layer has an outer abrasive surface, wherein the substrate has a second surface opposite the first surface of the substrate, and wherein a plurality of openings extend from the outer abrasive surface to the second surface of the substrate; a first nonwoven filter medium having a first surface and a second surface opposite the first surface, wherein the first surface of the first nonwoven filter medium is proximate and affixed to the second surface of the substrate, wherein the first nonwoven filter medium comprises a plurality of fibers; and a second nonwoven filter medium having a first surface and a second surface opposite the first surface, wherein the first
  • the present invention provides a method of making an abrasive article, the method comprising: providing a porous abrasive member comprising: an abrasive layer proximate and affixed to a first surface of a substrate, the abrasive layer comprising a plurality of abrasive particles affixed to the first surface of the substrate by at least one binder, wherein the abrasive layer has an outer abrasive surface, wherein the substrate has a second surface opposite the first surface of the substrate, and wherein a plurality of openings extend from the outer abrasive surface to the second surface of the substrate; providing a first nonwoven filter medium, the first nonwoven filter medium having a first surface and a second surface opposite the first surface, wherein the first nonwoven filter medium comprises a plurality of fibers, and wherein the first surface of the first nonwoven filter medium is proximate the second surface of the substrate; providing a second nonwoven filter medium, the second nonwoven filter medium, the second
  • the present invention provides an abrasive article comprising: a porous abrasive member comprising: an abrasive layer proximate and affixed to a first surface of a substrate, the abrasive layer comprising a plurality of abrasive particles affixed to the first surface of the substrate by at least one binder, wherein the abrasive layer has an outer abrasive surface, wherein the substrate has a second surface opposite the first surface of the substrate, and wherein a plurality of openings extend from the outer abrasive surface to the second surface of the substrate; a first nonwoven filter medium having a first surface and a second surface opposite the first surface, wherein the first surface of the first nonwoven filter medium is proximate and affixed to the second surface of the substrate, wherein the first nonwoven filter medium comprises a plurality of fibers, and wherein the first nonwoven filter medium has a thickness of from 1 to 25 millimeters and a bulk
  • the present invention provides a method of making an abrasive article, the method comprising: providing a porous abrasive member comprising: an abrasive layer proximate and affixed to a first surface of a substrate, the abrasive layer comprising a plurality of abrasive particles affixed to the first surface of the substrate by at least one binder, wherein the abrasive layer has an outer abrasive surface, wherein the substrate has a second surface opposite the first surface of the substrate, and wherein a plurality of openings extend from the outer abrasive surface to the second surface of the substrate; providing a first nonwoven filter medium having a first surface and a second surface opposite the first surface, wherein the first surface of the first nonwoven filter medium is proximate the second surface of the substrate, wherein the first nonwoven filter medium comprises a plurality of fibers, and wherein the second nonwoven filter medium has a thickness of from 0.5 to 15 millimeters
  • the porous abrasive member comprises an apertured coated abrasive. In certain embodiments, the porous abrasive member comprises a screen abrasive. In certain embodiments, the first nonwoven filter medium and the second nonwoven filter medium are affixed to one another by needletacking or a stitch bond. In certain embodiments, the porous abrasive member is affixed to the first nonwoven filter medium by an adhesive. In certain embodiments, the first nonwoven filter medium is affixed to the second nonwoven filter medium by an adhesive.
  • At least one of the first nonwoven filter medium or the second nonwoven filter medium comprise synthetic fibers selected from the group consisting of polypropylene fibers, polyester fibers, nylon fibers, and mixtures thereof.
  • the substrate is selected from the group consisting of metal foil, paper, fabric, and plastic film.
  • at least one of the first nonwoven filter medium or the second nonwoven filter medium comprises a blown micro fiber web.
  • at least one of the first nonwoven filter medium or the second nonwoven filter medium comprises an electret charge.
  • the second surface of the substrate and the first surface of the first nonwoven filter medium are coextensive, and the second surface of the first nonwoven filter medium and the first surface of the second nonwoven filter medium are coextensive.
  • at least one of the first or second nonwoven filter medium has a peripheral edge that is sealed along a major portion thereof.
  • the abrasive article comprises an abrasive disc.
  • a porous attachment layer is affixed to the second surface of the second nonwoven filter medium.
  • the porous attachment layer comprises a loop portion or a hook portion of a two-part mechanical engagement system.
  • the first nonwoven filter medium, the second nonwoven filter medium, and the porous attachment layer are affixed to one another by needletacking or a stitch bond.
  • Abrasive articles according to the present invention are useful, for example, for abrading a surface of a workpiece by a method comprising contacting the surface with the abrasive article, and relatively moving the abrasive article and the surface to mechanically modify the surface.
  • abrasive articles according to the present invention are particularly suitable for use in those abrading applications generating appreciable amounts of particles (e.g., swarf), and in at least some embodiments, may effectively trap at least 40, 50 (i.e., a majority), 60, 70, 80, or even more than 90 percent of particles generated in such abrading applications, for example, if used in combination with a tool having a vacuum source.
  • particles e.g., swarf
  • air resistance refers to resistance of air passing through the thickness dimension of a nonwoven web or abrasive article, and, when used for comparison purposes, all air resistance values are to be measured under like conditions;
  • nonwoven filter medium refers to a material, having internal void space and formed substantially of a plurality of entangled and/or bonded fibers, produced by a process other than weaving or knitting;
  • thickness as applied to a nonwoven filter medium refers to the thickness of the nonwoven web as measured according to ASTM D5736-95 (Reapproved 2001) "Standard Test Method for Thickness of Highloft Nonwoven Fabrics" using a pressure plate force of 0.002 pound per square inch (13.8 Pa).
  • Fig. IA is a perspective view of an exemplary abrasive article according to one embodiment of the present invention, partially cut away to reveal the layers forming the article;
  • Fig. IB is a schematic cross-sectional view of the abrasive article shown in Fig. IA;
  • Fig. 2A is a top view of an exemplary porous abrasive member useful in abrasive articles according to the present invention
  • Fig. 2B is a cross-sectional view of the porous abrasive member shown in Fig. 2A;
  • Fig. 3 is a top view of an exemplary porous abrasive member useful in abrasive articles according to the present invention, partially cut away to reveal the components forming the abrasive layer;
  • Fig. 4 is a scale top view showing an exemplary perforation pattern 400 for a 5- inch diameter coated abrasive disc.
  • Fig. IA shows a perspective view of an exemplary abrasive article 102 (shown as an abrasive disc) with a partial cutaway.
  • the abrasive article 102 has a porous abrasive member 104, a first nonwoven filter medium 120, a second nonwoven filter medium 140, and an optional porous attachment layer 146.
  • the porous abrasive member 104 comprises a plurality of openings that allow the flow of particles (e.g., swarf generated during an abrading process) through the porous abrasive member 104. Particles are then captured by the filter medium within the abrasive article.
  • Optional seal 105 seals the peripheral edge 106 (shown in Fig. IB) of first and second nonwoven filter medium 120, 140, respectively, thereby preventing lateral escape of particles not retained by the abrasive article 102.
  • Fig. IB shows a schematic cross-sectional view of the abrasive article 102 shown in Fig. IA.
  • the abrasive article 102 comprises multiple layers.
  • the first nonwoven filter medium 120 comprises a first surface 122 and a second surface 124 opposite the first surface 122.
  • the second nonwoven filter medium 140 comprises a first surface 142 and a second surface 144 opposite the first surface 142.
  • the first surface 122 of the first nonwoven filter medium 120 is proximate the porous abrasive member 104.
  • the second surface 124 of the first nonwoven filter medium 120 is proximate the first surface 142 of the second nonwoven filter medium 140.
  • a porous attachment layer 146 is proximate the second surface 144 of the second nonwoven filter medium 140.
  • the porous abrasive member and various filter medium layers of the abrasive article are affixed to one another in a manner that does not prevent the flow of particles from one layer to the next, although some partial or minor obstruction(s) to particle flow may be present.
  • the porous abrasive member and various filter medium layers of the abrasive article are affixed to one another in a manner that does not substantially inhibit the flow of particles from one layer to the next.
  • the level of particle flow through the abrasive article may be restricted, at least in part, by the introduction of an adhesive between the porous abrasive member and the first nonwoven filter medium, or the first nonwoven filter medium and the second nonwoven filter medium.
  • the level of restriction may be minimized by applying the adhesive between layers in a discontinuous fashion such as for example, as discrete adhesive areas (e.g., atomized spray or starved extrusion die) or distinct adhesive lines (e.g., hot melt swirl-spray or patterned roll coater).
  • discrete adhesive areas e.g., atomized spray or starved extrusion die
  • distinct adhesive lines e.g., hot melt swirl-spray or patterned roll coater
  • Fig. 2A shows a top view of an exemplary coated abrasive material used to form the porous abrasive member.
  • Fig. 2B shows a cross-sectional view of a section of the porous abrasive member shown in Fig. 2A.
  • the porous abrasive member 204 comprises a substrate 206 having a first surface 208 and a second surface 210, a make coat 214, a plurality of abrasive particles 212, and a size coat 215.
  • the porous abrasive member 204 comprises a plurality of apertures 216 (not shown in Fig. 2B).
  • FIG. 3 shows a top view of an exemplary screen abrasive material used to form the porous abrasive member.
  • Fig. 3 includes a partial cutaway to reveal the components forming the abrasive layer.
  • the porous abrasive member 304 comprises an open mesh substrate 306, a make coat 314, a plurality of abrasive particles 312, and a size coat 315.
  • the porous abrasive member 304 comprises a plurality of openings 316 that extend through the porous abrasive member.
  • the openings 316 are formed by openings 318 in the open mesh substrate 306.
  • the open mesh substrate may be made from any porous material including, for example, perforated films, nonwovens, or woven or knitted fabrics.
  • the open mesh substrate 306 is a perforated film.
  • the film for the substrate may be made from metal, paper, or plastic, including molded thermoplastic materials and molded thermoset materials.
  • the open mesh substrate comprises perforated or slit and stretched sheet materials.
  • the open mesh substrate comprises fiberglass, nylon, polyester, polypropylene, or aluminum.
  • the openings 318 in the open mesh substrate 306 may be generally square shaped as shown in Fig. 3.
  • the shape of the openings may be other geometric shapes including, for example, a rectangular shape, a circular shape, an oval shape, a triangular shape, a parallelogram shape, a polygon shape, or a combination of these shapes.
  • the openings 318 in the open mesh substrate 306 may be uniformly sized and positioned as shown in Fig. 3.
  • the openings may be placed non-uniformly by, for example, using a random opening placement pattern, varying the size or shape of the openings, or any combination of random placement, random shapes, and random sizes.
  • a screen abrasive with a woven or knitted substrate may be used to form the porous abrasive member.
  • a woven substrate typically comprises a plurality of generally parallel warp elements that extend in a first direction and a plurality of generally parallel weft elements that extend in a second direction.
  • the weft elements and warp elements of the open mesh substrate intersect to form a plurality of openings.
  • the second direction may be perpendicular to the first direction to form square shaped openings in the woven open mesh substrate.
  • the first and second directions intersect to form a diamond pattern.
  • the shape of the openings may be other geometric shapes including, for example, a rectangular shape, a circular shape, an oval shape, a triangular shape, a parallelogram shape, a polygon shape, or a combination of these shapes.
  • the warp and weft elements are yarns that are woven together in a one -over-one weave.
  • the warp and weft elements may be combined in any manner known to those in the art including, for example, weaving, stitch-bonding, or adhesive bonding.
  • the warp and weft elements may be fibers, filaments, threads, yarns or a combination thereof.
  • the warp and weft elements may be made from a variety of materials known to those skilled in the art including, for example, synthetic fibers, natural fibers, glass fibers, and metal.
  • the warp and weft elements comprise monofilaments of thermoplastic material or metal wire.
  • the woven open mesh substrate comprises nylon, polyester, or polypropylene.
  • the porous abrasive member may comprise openings having different open areas.
  • the "open area" of an opening in the porous abrasive member refers to the area of the opening as measured over the thickness of the porous abrasive member (i.e., the area bounded by the perimeter of material forming the opening through which a three-dimensional object could pass).
  • Useful porous abrasive members typically have an average open area of at least about 0.5 square millimeters per opening. In some embodiments, the porous abrasive member has an average open area of at least about one square millimeter per opening. In yet further embodiments, the porous abrasive member has an average open area of at least about 1.5 square millimeters per opening.
  • the porous abrasive member whether woven, perforated or otherwise, comprises a total open area that affects the amount of air that may pass through the porous abrasive member as well as the effective area and performance of the abrasive layer.
  • the "total open area" of the porous abrasive member refers to the cumulative open areas of the openings as measured over the area formed by the perimeter of the porous abrasive member.
  • Porous abrasive members have a total open area of at least about 0.01 square centimeters per square centimeter of the abrasive layer (i.e., 1 percent open area).
  • the porous abrasive member has a total open area of at least about 0.03 square centimeters per square centimeter of the abrasive layer (i.e., 3 percent open area). In yet further embodiments, the porous abrasive member has a total open area of at least about 0.05 square centimeters per square centimeter of the abrasive layer (i.e., 5 percent open area).
  • the porous abrasive member has a total open area that is less than about 0.95 square centimeters per square centimeter of the abrasive layer (i.e., 95 percent open area). In some embodiments, the porous abrasive member has a total open area that is less than about 0.9 square centimeters per square centimeter of the abrasive layer (i.e., 90 percent open area). In yet further embodiments, the porous abrasive member has a total open area that is less than about 0.80 square centimeters per square centimeter of the abrasive layer (i.e., 80 percent open area).
  • the porous abrasive member whether a perforated coated abrasive, a coated screen abrasive, a nonwoven abrasive, or otherwise, comprises a plurality of abrasive particles and at least one binder.
  • the abrasive layer comprises a make coat, a size coat, a supersize coat, or a combination thereof.
  • the abrasive layer is provided, at least in part, by curing a slurry coat comprising abrasive particles in a binder precursor.
  • a make layer of a coated abrasive is prepared by coating at least a portion of a substrate (e.g., a treated or untreated backing, open mesh, or nonwoven fiber web) with a make layer precursor comprising a first binder precursor.
  • a substrate e.g., a treated or untreated backing, open mesh, or nonwoven fiber web
  • the substrate may have one or more treatments (e.g., a backsize, presize, saturant, or subsize) thereon.
  • Suitable substrates are widely known in the abrasive arts and may consist of, for example, metal foil, paper, fabric (e.g., knits, nonwovens, or wovens (including open scrims and tightly woven fabrics), woven mesh (e.g., scrim), plastic film (e.g., including thermoplastic materials such as polyester, polyethylene, and polypropylene), and combinations thereof.
  • the substrate does not have a laminate structure.
  • the substrate is preferably relatively thin and flexible.
  • the substrate may have a thickness of less than 1 millimeter, less than 0.5 millimeter, or even less than 0.1 millimeter.
  • the perforations, holes, or other porous features extending through the thickness of the substrate have a substantially uniform cross-section throughout their length.
  • Abrasive particles are then at least partially embedded (e.g., by electrostatic or drop coating) to the make layer precursor comprising a first binder precursor, and the make layer precursor is at least partially cured.
  • Electrostatic coating of the abrasive particles typically provides erectly oriented abrasive particles.
  • the term "erectly oriented" refers to a characteristic in which the longer dimensions of a majority of the abrasive particles are oriented substantially perpendicular (i.e., between 60 and 120 degrees) to the substrate. Other techniques for erectly orienting abrasive particles may also be used.
  • the size layer is prepared by coating at least a portion of the make layer and abrasive particles with a size layer precursor comprising a second binder precursor (which may be the same as, or different from, the first binder precursor), and at least partially curing the size layer precursor.
  • a supersize is applied to at least a portion of the size layer. If present, the supersize layer typically includes grinding aids and/or anti-loading materials.
  • a binder is formed by curing (e.g., by thermal means, or by using electromagnetic or particulate radiation) a binder precursor.
  • binder precursors suitable for use in make, size, supersize, and slurry coats are well known in the abrasive art and include, for example, free-radically polymerizable monomer and/or oligomer, epoxy resins, acrylic resins, urethane resins, phenolic resins, urea-formaldehyde resins, melamine-formaldehyde resins, aminoplast resins, cyanate resins, or combinations thereof.
  • binder precursors include thermally curable resins and radiation curable resins, which may be cured, for example, thermally and/or by exposure to radiation.
  • catalysts, initiators, and/or curatives may be used in combination with binder precursors, typically in an effective amount.
  • Suitable abrasive particles for the coated abrasives include, for example, any known abrasive particles or materials commonly used in abrasive articles.
  • abrasive particles for coated abrasives include, for example, fused aluminum oxide, heat treated aluminum oxide, white fused aluminum oxide, black silicon carbide, green silicon carbide, titanium diboride, boron carbide, tungsten carbide, titanium carbide, diamond, cubic boron nitride, garnet, fused alumina zirconia, sol gel abrasive particles, silica, iron oxide, chromia, ceria, zirconia, titania, silicates, metal carbonates (such as calcium carbonate (e.g., chalk, calcite, marl, travertine, marble and limestone), calcium magnesium carbonate, sodium carbonate, magnesium carbonate), silica (e.g., quartz, glass beads, glass bubbles and glass fibers) silicates (e.g., talc, clays, (montmorillonite) feldspar, mica, calcium silicate, calcium metasilicate, sodium aluminosilicate, sodium silicate) metal
  • the abrasive particles may also be agglomerates or composites that include additional components, such as, for example, a binder. Criteria used in selecting abrasive particles used for a particular abrading application typically include: abrading life, rate of cut, substrate surface finish, grinding efficiency, and product cost.
  • Coated abrasive members may further comprise optional additives such as abrasive particle surface modification additives, coupling agents, plasticizers, fillers, expanding agents, fibers, antistatic agents, initiators, suspending agents, photosensitizers, lubricants, wetting agents, surfactants, pigments, dyes, UV stabilizers, and suspending agents.
  • additives such as abrasive particle surface modification additives, coupling agents, plasticizers, fillers, expanding agents, fibers, antistatic agents, initiators, suspending agents, photosensitizers, lubricants, wetting agents, surfactants, pigments, dyes, UV stabilizers, and suspending agents.
  • Additives may also be incorporated into the binder, applied as a separate coating, held within the pores of the agglomerate, or combinations of the above.
  • the abrasive member may be perforated, for example, by mechanical perforation (e.g., die punching), laser perforation, any other suitable technique. Any pattern of perforations may be used.
  • Perforations may be, for example, round or oblong, straight, arcuate, or some complex shape. There should be sufficient porosity of the porous abrasive member to allow particles (e.g., swarf) to flow from the outer abrasive surface to the first and second filter medium at a rate comparable to that at which they are generated.
  • particles e.g., swarf
  • Examples of commercially available apertured coated abrasive articles suitable for use as a porous abrasive member include material available under the trade designation "NORTON MULTI-AIR", from Saint-Gobain Abrasives GmbH, Wesseling, Germany, and coated abrasive discs available under the trade designation "CLEAN SANDING DISC” from 3M Company, Saint Paul. Minnesota.
  • the first and/or second nonwoven filter media have an average thickness in a range of at least 0.5, 1, or even at least 5 millimeters up to 10 or 15 millimeters. In other embodiments, the first nonwoven filter medium may have a thickness of up to 20, or even 30 millimeters, or more. In some embodiments, the first nonwoven filter medium has an average thickness that is less than about 20 millimeters. In some embodiments, the first and/or second nonwoven filter media have a bulk density of from 0.04 to 0.5 grams per cubic centimeter (g/cm 3 ). For example, the first filter medium may have a bulk density of from 0.75 to 0.4 g/cm 3 , or from 1 to 0.3 g/cm 3 .
  • the first filter medium is thicker and optionally less dense than the second filter medium. In other embodiments, the second filter medium is thicker and optionally less dense than the first filter medium.
  • the first and/or second filter medium of the abrasive article may be electrostatically charged. Electrostatic charging enhances the filter media's ability to remove particulate matter from a fluid stream by increasing the attraction between particles and the surface of the filter medium. Non-impinging particles passing close to fibers of the filter media are more readily pulled from the fluid stream, and impinging particles are adhered more strongly. Passive electrostatic charging is provided by an electret, which is a dielectric material that exhibits a semi-permanent or permanent electrical charge.
  • Electret chargeable polymeric materials include nonpolar polymers such as polytetrafluoroethylene (PTFE) and polypropylene.
  • any of which may be used to charge the filtration medium of the abrasive article including corona discharge, heating and cooling the material in the presence of a charged field, contact electrification, spraying the web with charged particles, and impinging a surface with water jets or water droplet streams.
  • the chargeability of the surface may be enhanced by the use of blended materials. Examples of charging methods are disclosed in U.S. Pat. Nos.
  • Each of the first and/or second nonwoven filter media comprise a plurality of fibers.
  • the first and/or second nonwoven filter media comprise materials having a fiber size that is less than about 100 microns in diameter, and sometimes less than about 50 microns, and sometimes less than about 1 micron in diameter.
  • the first and/or second nonwoven filter media may be made from a wide variety of organic polymeric materials, including mixtures and blends.
  • Suitable filter medium includes a wide range of materials commercially available. They include polyolefms, such as polypropylene, linear low density polyethylene, poly-1-butene, poly(4-methyl-l- pentene), polytetrafluoroethylene, polychlorotrifluoroethylene; or polyvinyl chloride; aromatic polyarenes, such as polystyrene; polycarbonates; polyesters; and combinations thereof (including blends or copolymers).
  • materials include polyolefms free of branched alkyl radicals and copolymers thereof.
  • materials include thermoplastic fiber formers (e.g., polyolefms such as polyethylene, polypropylene, copolymers thereof, etc.).
  • suitable materials include: thermoplastic polymers such as polylactic acid (PLA); non-thermoplastic fibers such as cellulose, rayon, acrylic, and modified acrylic (halogen modified acrylic); polyamide or polyimide fibers such as those available under the trade designations "NOMEX” and "KEVLAR” from E.I. du Pont de Nemours & Co., Wilmington, Delaware; and fiber blends of different polymers.
  • the nonwoven filter media may be formed in a web by conventional nonwoven techniques including, for example, melt blown, spunbond, carding, air laying (dry laying), or wet laying techniques.
  • melt blown nonwoven filter media include bimodal blown microfiber media, for example, as described in U.S. Pat. Appln. No. 11/461136 to Brandner et al., filed July 31, 2006.
  • the nonwoven filter medium may have a gradient density, for example, as prepared by contacting a thermoformable nonwoven web with a hot can.
  • the fibers or webs may be charged by known methods, including, for example, by use of corona discharge electrodes or high-intensity electric fields. The fibers may be charged during fiber formation, prior to or while forming the fibers into the filter web or subsequent to forming the filter web. The fibers forming the second filter medium may even be charged subsequent to being joined to the first nonwoven filter medium.
  • the second nonwoven filter medium may comprise fibers coated with a polymer binder or adhesive, including pressure sensitive adhesives.
  • the porous attachment layer allows air to pass through.
  • the porous attachment layer may comprise a layer of adhesive, a fabric, a sheet material, a molded body, or a combination thereof.
  • the sheet material may comprise, for example, a loop portion or a hook portion of a two-part mechanical engagement system.
  • the porous attachment layer may comprise a layer of pressure sensitive adhesive with an optional release liner to protect it during handling.
  • the porous attachment layer comprises a nonwoven, woven, or knitted loop material.
  • the loop material may be used to affix the abrasive article to a back-up pad having a complementary mating component.
  • Suitable materials for a loop porous attachment layer include both woven and nonwoven materials.
  • Woven and knit porous attachment layer materials may have loop- forming filaments or yarns included in their fabric structure to form upstanding loops for engaging hooks.
  • Nonwoven loop attachment interface materials may have loops formed by the interlocking fibers. In some nonwoven loop attachment interface materials, the loops are formed by stitching a yarn through the nonwoven web to form upstanding loops.
  • Useful nonwovens suitable for use as a loop porous attachment layer include, for example, airlaids, spunbonds, spunlaces, bonded melt blown webs, and bonded carded webs.
  • the nonwoven materials may be bonded in a variety of ways known to those skilled in the art including, for example, needle-punching, stitchbonding, hydroentangling, chemical bonding, thermal bonding, and combinations thereof.
  • the woven or nonwoven materials used may be made from natural fibers (e.g., wood or cotton fibers), synthetic fibers (e.g., polyester or polypropylene fibers) or combinations of natural and synthetic fibers.
  • the porous attachment layer comprises nylon, polyester or polypropylene.
  • a loop porous attachment layer having an open structure that does not significantly interfere with the flow of air through it is selected.
  • the porous attachment layer material is selected, at least in part, based on the porosity of the material.
  • the porous attachment layer comprises a hook material.
  • the material used to form the hook material useful in the abrasive article may be made in one of many different ways known to those skilled in the art.
  • Several suitable processes for making hook material useful in making porous attachment layers include, for example, methods described in U.S. Pat. Nos. 5,058,247 (Thomas et al); 4,894,060 (Nestegard); 5,679,302 (Miller et al.); and 6,579,161 (Chesley et al.).
  • the hook material may be a porous material such as, for example the polymer netting material reported in U.S. Pat. Appln. Publ. No. 2004/0170801 (Seth et al.).
  • the hook material may be apertured to allow air to pass through. Apertures may be formed in the hook material using any methods known to those skilled in the art. For example, the apertures may be cut from a sheet of hook material using, for example, a die, laser, or other perforating instruments known to those skilled in the art. In other embodiments, the hook material may be formed with apertures.
  • the porous attachment layer of the abrasive article is affixed to the filter medium in a manner that does not prevent the flow of air from the filter medium.
  • the porous attachment layer of the abrasive article is affixed to the filter medium in a manner that does not substantially inhibit the flow of air from the filter medium.
  • the level of air flow through the porous attachment layer may be restricted, at least in part, by the introduction of an adhesive between a porous attachment layer comprising a sheet material and the filter medium.
  • the level of restriction may be minimized by applying the adhesive between the sheet material of the porous attachment layer and the filter medium in a discontinuous fashion such as, for example, discrete adhesive areas (e.g., atomized spray or starved extrusion die) or distinct adhesive lines (e.g., hot melt swirl-spray or patterned roll coater).
  • discrete adhesive areas e.g., atomized spray or starved extrusion die
  • distinct adhesive lines e.g., hot melt swirl-spray or patterned roll coater
  • Exemplary useful adhesives include both pressure sensitive and non-pressure sensitive adhesives.
  • Pressure sensitive adhesives are normally tacky at room temperature and may be adhered to a surface by application of, at most, light finger pressure, while non-pressure sensitive adhesives include solvent, heat, or radiation activated adhesive systems.
  • useful adhesives include those based on general compositions of polyacrylate; polyvinyl ether; diene-containing rubbers such as natural rubber, polyisoprene, and polyisobutylene; polychloroprene; butyl rubber; butadiene-acrylonitrile polymers; thermoplastic elastomers; block copolymers such as styrene-isoprene and styrene-isoprene-styrene block copolymers, ethylene -propylene-diene polymers, and styrene-butadiene polymers; poly(alpha olefins); amorphous polyolefms; silicone; ethylene-containing copolymers such as poly(ethylene-co-vinyl acetate), poly(ethylene-co- ethyl acrylate), and poly(ethylene-co-ethyl methacrylate); polyurethanes; polyamides; polyesters; epoxies;
  • the various layers in the abrasive article may be held together using any suitable form of attachment such as, for example, glue, pressure sensitive adhesive, hot-melt adhesive, spray adhesive, thermal bonding, needletacking, stitch bonding, and ultrasonic bonding.
  • the layers are adhered to one another by applying a spray adhesive such as, for example, "3M BRAND SUPER 77 ADHESIVE", available from 3M Company, St. Paul, Minnesota, to one side of the porous abrasive.
  • a hot-melt adhesive is applied to one side of a layer using either a hot-melt spray gun or an extruder with a comb-type shim.
  • a preformed adhesive mesh is placed between the layers to be joined.
  • a seal may be applied to the peripheral edge of the abrasive article, typically to at least a majority (if not all) of the peripheral edge, to reduce or prevent lateral escape of particles not retained by the abrasive article.
  • seals include welds, tape, latex coatings, caulks, and sealants (e.g., latex or silicone).
  • Abrasive articles according to the present invention are generally useful for collecting particles during abrading processes, and in some cases, are capable of retaining large amounts of particles at high rates of delivery.
  • the abrasive articles are suitable for use with any devices adapted for use with such articles. Examples include random orbital, dual action, and disc sanders, with or without vacuum applied to the porous attachment layer and/or second nonwoven filter medium of the abrasive article.
  • the multiple filter components may function such that a given component (e.g., the first nonwoven filter medium) may be aided by a secondary component (e.g., the second nonwoven filter medium) that may address the failure mode of the first component and compensate, keeping overall efficiency high and extending performance to a level that aligns with the performance of the abrasive it is used with.
  • a given component e.g., the first nonwoven filter medium
  • a secondary component e.g., the second nonwoven filter medium
  • At least a portion of an abrasive article (e.g., representative of the perforated area) according to the present invention (in an unused state) exhibits a pressure drop according to the Pressure Drop Measurement Test (hereinbelow) in a range of from 0.2 to 20 millimeters of water.
  • at least a portion of an abrasive article according to the present invention (in an unused state) may exhibits a pressure drop according to the Pressure Drop Measurement Test in a range of from 1 to 15 millimeters of water, or even 4 to 10 millimeters of water.
  • the Pressure Drop Measurement Test is performed as follows: Pressure drop across the thickness of an abrasive article is determined using a filter testing apparatus comprising a pair of equal inside diameter cylinders mounted in series, such that, the length of the cylinders is in the vertical direction, and such that air flows through the cylinders with a face velocity of 5.2 centimeters per second. A pressure transducer is mounted to each cylinder to measure the pressure within the cylinders. The adjacent ends of the top and bottom cylinders are sealed upon the abrasive article.
  • the abrasive article being tested is tightly clamped, so as to prevent sideways leakage, between the cylinders with the outer abrasive surface of the abrasive article being perpendicular to the direction of, and facing, the air flow.
  • the difference in air pressure between the first and second cylinders is recorded as the pressure drop of the abrasive article.
  • ALEX PLUS manufactured by DAP Products, Inc., Baltimore, Maryland; around the peripheral edge (abutting the circumference) of the disc.
  • the caulk was forced into the edge of the filter medium via a spatula.
  • the caulk was allowed to dry at least 8 hours. FMl, sealed in this manner was designated as FM3.
  • a sheet of abrasive material 1, AMI was laminated to similar sized sheet of a dual-sided transfer tape having the trade designation "3M 964 13 MIL TRANSFER TAPE" available from the 3M Company, by the following procedure. One side of the tape's liner was removed and the side of a sheet of AMI opposite the outer abrasive surface was hand-laminated to the exposed, tacky pressure sensitive adhesive of the tape.
  • the laminated abrasive was laser perforated according to pattern 400 shown in Fig. 4. Laser perforated and cut 5 -inch diameter discs of this layered construction were designated as AM2.
  • a pressure-sensitive adhesive commercially available under the trade designation "SUPER 77 SPRAY ADHESIVE" from 3M Company, was applied to the non-loop side of an approximately 6-inch (15.2-cm) square sheet of ATI and allowed to dry for approximately 30 seconds at 25 degrees Celsius.
  • the dry weight of adhesive was about 12 milligrams per square centimeter (mg/cm 2 ).
  • the circular surface of the filter medium FMl, FM2, or FM3, or abrasive material AM5 or AM6 was laminated to the adhesive coated surface of ATI.
  • the excess material of ATI protruding from the edge of the construction was removed by cutting with a scissors, creating a circular, substantially coextensive, multi-layer construction.
  • Procedure 4 Attachment of Filter Medium to AM2
  • the liner of the transfer tape of AM2 was removed exposing the tacky, pressure sensitive adhesive of the tape.
  • the appropriate circular disc of filter medium, FMl or FM3 was aligned with and hand laminated to the adhesive, such that, the layer of AM2 and the layer of filter medium were substantially coextensive.
  • FMl and FM3 had previously been laminated to a disc of FM2, as reported below.
  • the exposed circular surface of FMl or FM3, i.e., the side opposite the surface attached to FM2 was laminated to AM2.
  • AM2 is attached to the FM4/FM5 needle tacked filter medium
  • AM2 is attached to the exposed circular surface of FM4, forming a substantially coextensive layers.
  • a pressure-sensitive adhesive commercially available under the trade designation
  • FM4 was formed from a 90/10, by weight, blend of FIBl and FIB2.
  • the basis weight of the blend was about 155 grains/24 square inch. (648 g/m 2 ), with a thickness of about 5 inches (12 cm).
  • An air laid web former, trade designation "RANDO WEBBER", available from Rando Machine Corporation, Ard, New York was employed using conventional conditions to form FM4 from the indicated fiber blend..
  • FM4 Upon exit from the Rando Webber in Procedure 6, FM4 was positioned above FM5 and the two layers were attached to one another by passing them through a needle tacker, trade designation "AUTOMATEX", available from STP Impianti Spa, Milan, Italy, at a speed of 1.52 m/minute.
  • the needle tacker rate was 185 strokes/minute, with a penetration from above of 15 mm, and a punch density of 8.4 punches/cm 2 .
  • Needles were type F20 9-37-9K 15X20x2.5, available from Foster Needle Co., Manitowoc, Wisconsin.
  • the final basis weight for the needle tacked FM5/FM6 filter medium was about 855 g/m 2 with a thickness of about 5.2 mm.
  • the combined nonwoven structure was passed through a convection oven for a period of 2 minutes at 129 degrees Celsius, where FIBl bonded the entire structure together. The finished structure was allowed to cool to 25 degrees Celsius.
  • the components e.g., porous abrasive member, filter medium, and porous attachment layer
  • the processing sequence in which the layers are combined together to form the multi-layer abrasive disc is often not of particular concern, as long as the desired final construction is obtained.
  • a 5.0-inch (12.7-cm) diameter abrasive disc was weighed and then attached to a 40-hole, 5.0-inch (12.7-cm) diameter by 3/8-inch (0.95-cm) thick foam back up pad, available under the trade designation "3M HOOKIT BACKUP PAD, #20206" from 3M Company.
  • the backup pad and disc assembly was then mounted onto a 5-inch (12.7-cm) diameter, medium finishing, dual-action orbital sander, model 21033, obtained from Dynabrade Corp., Clarence, New York.
  • the abrasive face of the disc was manually brought into contact with a pre-weighed, 18 inches by 30 inches (46 cm by 76 cm) gel- coated fiberglass reinforced plastic panel, obtained from White Bear Boat Works, White Bear Lake, Minnesota.
  • the sander was run at 90 psi (620 kPa) air line pressure and a down force of 10 pounds force (44 N) for 2 cycles of 75 seconds each. An angle of zero degrees to the surface of the workpiece was used.
  • Each cycle consisted of 24 overlapping transverse passes, for a combined 504 inches (12.8 meters) total length, at a tool speed of 6.7 inches per second (17 cm per second) across the panel surface resulting in an evenly sanded area of test panel.
  • test panel was cleaned by blowing compressed air across the top of the sanded panel to remove visible dust.
  • the disc was removed from the back up pad and both the panel and disc were weighed.
  • the abrasive was remounted on the back up pad and the 75 -second sanding cycle was repeated using the same test panel.
  • the test panel was again cleaned by blowing compressed air across the top of the sanded panel to remove visible dust.
  • the abrasive disc was removed from the back-up pad and both the panel and abrasive disc were weighed. Reported data is after the 2 nd sanding cycle, cumulative sanding time of 150 seconds. The following measurements were made for each sample tested by this method and reported as an average of two test samples per example in Tables 1 and Table 2 as indicated:
  • a 5.0-inch (12.7-cm) abrasive filter disc was weighed, attached to the back up pad and the disc/pad assembly was then mounted to the orbital sander as described in Sanding Test Method 1.
  • the abrasive face of the disc was manually brought into contact with a pre-weighed, 18 inches by 30 inches (45.7 cm by 76.2 cm) gel-coated fiberglass reinforced plastic panel obtained from White Bear Boat Works, White Bear Lake, Minnesota.
  • the sander was run at 90 psi (620 kPa) air line pressure for 6 cycles of 25 seconds each. An angle of zero degrees to the surface of the workpiece was used. After the first 3 cycles, the test panel was cleaned by blowing compressed air across the top of the sanded panel to remove visible dust.
  • the disc was removed from the back up pad and both the panel and disc were weighed.
  • the abrasive was remounted on the back up pad and the final 3 sanding cycles were conducted using the same test panel.
  • the test panel was again cleaned by blowing compressed air across the top of the sanded panel to remove visible dust.
  • the abrasive disc was removed from the back up pad and both the panel and abrasive disc were weighed. Reported data is after the 6 th sanding cycle, cumulative sanding time of 150 seconds.
  • Retain weight, in grams, of particles collected in the sample disc; and "DE %”: Ratio of the Retain/Cut multiplied by 100.
  • the resulting surface roughness of the abraded test panels was determined by using a surface finish testing device available under the trade designation "PERTHOMETER MODEL M4P-130589" from Mahr Corporation, Cincinnati, Ohio. Surface finish values were measured at three abraded sections of the test panel after each completed 150-second sanding test. The Rz (also known as Rtm), which is the mean of the maximum peak-to- valley values, was recorded for each measurement. Modified Pressure Drop Measurement Test
  • Sanding Test 1 was used as the abrading procedure corresponding to the data generated in Table 1.
  • Sanding Test 2 was used as the abrading procedure corresponding to the data generated in Table 2.
  • Modified Pressure Drop Test measurements were not made on all examples. Modified Pressure Drop Test for certain Examples reported in Tables 1 and 2 are reported in Table 3 along with data associated with additional comparative examples.
  • Examples Ib, 2b, 3b, 4b and Comparative Example A2 were all run using the same gel-coated fiberglass reinforced plastic panel.
  • Examples 6, 7 and Comparative Example A3 were all run using the same gel-coated fiberglass reinforced plastic panel, yet a different panel from the previous examples and comparative example.
  • Example 5 and Comparative Example A4 were run on yet another panel. Variability in the panel can lead to variability in the measured cut.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Filtering Materials (AREA)
EP08730687A 2007-03-20 2008-02-26 Article abrasif et procédé de fabrication et d'utilisation de celui-ci Not-in-force EP2129488B1 (fr)

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Families Citing this family (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8513147B2 (en) 2003-06-19 2013-08-20 Eastman Chemical Company Nonwovens produced from multicomponent fibers
US7892993B2 (en) 2003-06-19 2011-02-22 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US20040260034A1 (en) 2003-06-19 2004-12-23 Haile William Alston Water-dispersible fibers and fibrous articles
US8382016B2 (en) * 2009-02-25 2013-02-26 Thiele Kaolin Company Nano particle mineral pigment
US20140234639A1 (en) * 2013-02-21 2014-08-21 Prakash B Malla Self binding nano particle mineral pigment
US8512519B2 (en) 2009-04-24 2013-08-20 Eastman Chemical Company Sulfopolyesters for paper strength and process
US20120258652A1 (en) * 2009-11-12 2012-10-11 Koehnle Gregory A Rotary buffing pad
WO2011088376A2 (fr) * 2010-01-15 2011-07-21 Perry Equipment Corporation Eléments filtres discoïdes pour production de gaz
CN101972567A (zh) * 2010-08-17 2011-02-16 江苏旭日冶金环保设备厂 一种复合滤料的生产方法
CN101954223A (zh) * 2010-08-17 2011-01-26 江苏旭日冶金环保设备厂 复合滤料的生产方法
ITCR20100033A1 (it) * 2010-10-05 2012-04-06 Paolo Corazzi Fibre Srl Procedimento per ottenere un disco abrasivo microforato
EP2625002B1 (fr) * 2010-10-06 2018-06-13 Saint-Gobain Abrasives, Inc. Composite non-tissé abrasif comprenant des particules abrasives de diamant
US9273417B2 (en) 2010-10-21 2016-03-01 Eastman Chemical Company Wet-Laid process to produce a bound nonwoven article
EP2640553B1 (fr) * 2010-11-18 2019-04-17 3M Innovative Properties Company Roue abrasive enroulée et son procédé de fabrication
US8652230B2 (en) * 2010-12-08 2014-02-18 E I Du Pont De Nemours And Company Media for hot gas filtration
US20120220207A1 (en) * 2011-02-24 2012-08-30 Dean Daniel R Substrate preparation tool system and method
JP5845796B2 (ja) * 2011-02-25 2016-01-20 株式会社リコー 乾式クリーニング装置
CN102233540B (zh) * 2011-04-12 2013-05-29 安泰科技股份有限公司 一种珩磨条及其制造方法
US8986409B2 (en) 2011-06-30 2015-03-24 Saint-Gobain Ceramics & Plastics, Inc. Abrasive articles including abrasive particles of silicon nitride
BR112014007089A2 (pt) 2011-09-26 2017-03-28 Saint-Gobain Ceram & Plastics Inc artigos abrasivos incluindo materiais de partículas abrasivas, abrasivos revestidos usando os materiais de partículas abrasivas e os métodos de formação
JP6033886B2 (ja) 2011-12-30 2016-11-30 サン−ゴバン セラミックス アンド プラスティクス,インコーポレイティド 成形研磨粒子および同粒子を形成する方法
JP5903502B2 (ja) 2011-12-30 2016-04-13 サン−ゴバン セラミックス アンド プラスティクス,インコーポレイティド 成形研磨粒子を備える粒子材料
RU2602581C2 (ru) 2012-01-10 2016-11-20 Сэнт - Гобэйн Керамикс Энд Пластик,Инк. Абразивные частицы, имеющие сложные формы, и способы их формования
US8840696B2 (en) 2012-01-10 2014-09-23 Saint-Gobain Ceramics & Plastics, Inc. Abrasive particles having particular shapes and methods of forming such particles
KR102204989B1 (ko) * 2012-01-12 2021-01-20 예일 유니버시티 E3 유비퀴틴 리가아제에 의한 표적 단백질 및 다른 폴리펩티드의 증진된 분해를 위한 화합물 및 방법
US8840757B2 (en) 2012-01-31 2014-09-23 Eastman Chemical Company Processes to produce short cut microfibers
DE102012201337A1 (de) * 2012-01-31 2013-08-01 Robert Bosch Gmbh Schleifscheibe
WO2013131009A1 (fr) * 2012-03-02 2013-09-06 Saint-Gobain Abrasives, Inc. Meules abrasives et des procédés de fabrication et d'utilisation correspondants
KR101813466B1 (ko) 2012-05-23 2017-12-29 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 형상화 연마입자들 및 이의 형성방법
KR20150023034A (ko) 2012-06-29 2015-03-04 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 특정 형상을 가지는 연마입자들 및 이러한 입자들 형성방법
KR101736085B1 (ko) 2012-10-15 2017-05-16 생-고뱅 어브레이시브즈, 인코포레이티드 특정한 형태들을 가진 연마 입자들 및 이러한 입자들을 형성하는 방법들
US9423234B2 (en) 2012-11-05 2016-08-23 The Regents Of The University Of California Mechanical phenotyping of single cells: high throughput quantitative detection and sorting
CN103084992B (zh) * 2012-11-13 2015-06-17 谢泽 基于针织布或机织布与塑料薄膜复合作基材的工业砂带
CN103084988B (zh) * 2012-11-13 2015-05-27 谢泽 一种基于针织布与机织布复合作基材的工业砂带
CN103111955A (zh) * 2012-11-13 2013-05-22 谢泽 一种基于纸与塑料薄膜复合作基材的工业砂带
CN103084993B (zh) * 2012-11-13 2015-04-01 谢泽 一种基于麻短切纤维的工业用砂带
CN103111959B (zh) * 2012-11-13 2015-05-27 谢泽 一种基于针织布或机织布与麻布复合作基材的工业砂带
US9074119B2 (en) 2012-12-31 2015-07-07 Saint-Gobain Ceramics & Plastics, Inc. Particulate materials and methods of forming same
MX2015013831A (es) 2013-03-29 2016-03-01 Saint Gobain Abrasives Inc Particulas abrasivas con formas particulares y metodos para elaborar las particulas.
US9303357B2 (en) 2013-04-19 2016-04-05 Eastman Chemical Company Paper and nonwoven articles comprising synthetic microfiber binders
TWI589404B (zh) * 2013-06-28 2017-07-01 聖高拜磨料有限公司 基於向日葵圖案之經塗佈的研磨製品
TW201502263A (zh) 2013-06-28 2015-01-16 Saint Gobain Ceramics 包含成形研磨粒子之研磨物品
GB201311891D0 (en) 2013-07-03 2013-08-14 Glaxosmithkline Ip Dev Ltd Novel compound
GB201311888D0 (en) 2013-07-03 2013-08-14 Glaxosmithkline Ip Dev Ltd Novel compounds
US20150059804A1 (en) * 2013-08-28 2015-03-05 Renee BERGEZ Cleaning implement
JP2016538149A (ja) 2013-09-30 2016-12-08 サン−ゴバン セラミックス アンド プラスティクス,インコーポレイティド 形状化研磨粒子及び形状化研磨粒子を形成する方法
US9605126B2 (en) 2013-12-17 2017-03-28 Eastman Chemical Company Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion
US9598802B2 (en) 2013-12-17 2017-03-21 Eastman Chemical Company Ultrafiltration process for producing a sulfopolyester concentrate
WO2015094938A1 (fr) 2013-12-19 2015-06-25 3M Innovative Properties Company Articles stratifiés pour élimination de microbes et filtration à faible chute de pression, procédés de fabrication et procédés d'utilisation associés
WO2015102992A1 (fr) 2013-12-31 2015-07-09 Saint-Gobain Abrasives, Inc. Article abrasif comprenant des particules abrasives façonnées
US9771507B2 (en) 2014-01-31 2017-09-26 Saint-Gobain Ceramics & Plastics, Inc. Shaped abrasive particle including dopant material and method of forming same
EP3105010B1 (fr) 2014-02-14 2021-04-28 3M Innovative Properties Company Article abrasif et procédé pour son utilisation
CN106457522B (zh) 2014-04-14 2020-03-24 圣戈本陶瓷及塑料股份有限公司 包括成形磨粒的研磨制品
CA2945493C (fr) 2014-04-14 2020-08-04 Saint-Gobain Ceramics & Plastics, Inc. Article abrasif comprenant des particules abrasives mises en forme
US9902045B2 (en) 2014-05-30 2018-02-27 Saint-Gobain Abrasives, Inc. Method of using an abrasive article including shaped abrasive particles
BR112017011433A2 (pt) 2014-12-01 2018-04-03 3M Innovative Properties Company roda abrasiva não tecida com uma camada de barreira à umidade
US9914864B2 (en) 2014-12-23 2018-03-13 Saint-Gobain Ceramics & Plastics, Inc. Shaped abrasive particles and method of forming same
US9707529B2 (en) 2014-12-23 2017-07-18 Saint-Gobain Ceramics & Plastics, Inc. Composite shaped abrasive particles and method of forming same
US9676981B2 (en) 2014-12-24 2017-06-13 Saint-Gobain Ceramics & Plastics, Inc. Shaped abrasive particle fractions and method of forming same
TWI634200B (zh) 2015-03-31 2018-09-01 聖高拜磨料有限公司 固定磨料物品及其形成方法
WO2016161157A1 (fr) 2015-03-31 2016-10-06 Saint-Gobain Abrasives, Inc. Articles abrasifs fixes et procédés pour les former
WO2016167967A1 (fr) * 2015-04-14 2016-10-20 3M Innovative Properties Company Article abrasif non tissé et procédé de fabrication de ce dernier
CA3118239A1 (fr) 2015-06-11 2016-12-15 Saint-Gobain Ceramics & Plastics, Inc. Article abrasif comprenant des particules abrasives profilees
RU2018120330A (ru) 2015-11-02 2019-12-04 Йейл Юниверсити Химерные соединения, осуществляющие нацеливание для протеолиза, и способы их получения и применения
KR102313436B1 (ko) 2016-05-10 2021-10-19 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 연마 입자들 및 그 형성 방법
SI3455321T1 (sl) 2016-05-10 2022-10-28 Saint-Gobain Ceramics & Plastics, Inc. Metode oblikovanja abrazivnih delcev
EP3275594A1 (fr) * 2016-07-29 2018-01-31 Guido Valentini Unité de plaque de support
US11230653B2 (en) 2016-09-29 2022-01-25 Saint-Gobain Abrasives, Inc. Fixed abrasive articles and methods of forming same
US10563105B2 (en) 2017-01-31 2020-02-18 Saint-Gobain Ceramics & Plastics, Inc. Abrasive article including shaped abrasive particles
US10759024B2 (en) 2017-01-31 2020-09-01 Saint-Gobain Ceramics & Plastics, Inc. Abrasive article including shaped abrasive particles
US10865148B2 (en) 2017-06-21 2020-12-15 Saint-Gobain Ceramics & Plastics, Inc. Particulate materials and methods of forming same
EP3651934A1 (fr) * 2017-07-14 2020-05-20 3M Innovative Properties Company Article abrasif comprenant un matériau de solubilisation dans l'eau anionique et son procédé de fabrication
DE102017122141A1 (de) * 2017-09-25 2019-03-28 Jakob Löwer Inh. von Schumann GmbH & Co. KG Vorrichtung zur Erzeugung eines undefinierten Finishes auf einer Oberfläche eines metallenen Werkstückes im Durchlaufverfahren
SG11202009728RA (en) * 2018-03-30 2020-10-29 Saint Gobain Abrasives Inc Abrasive article including a coating
CN109759939A (zh) * 2019-03-11 2019-05-17 谢泽 一种抛磨一体轮
WO2021133901A1 (fr) 2019-12-27 2021-07-01 Saint-Gobain Ceramics & Plastics, Inc. Articles abrasifs et leurs procédés de formation
CN111451950B (zh) * 2020-04-15 2021-11-02 浙江工业大学 摇臂送料式研磨盘制备装置

Family Cites Families (82)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2123581A (en) * 1936-08-15 1938-07-12 Norton Co Flexible coated abrasive product
US2740239A (en) * 1953-07-02 1956-04-03 Bay State Abrasive Products Co Flexible abrasive products
US2810650A (en) * 1955-03-04 1957-10-22 Monsanto Chemicals Refrigeration of doughs and batters including as a leavening component dicalcium phosphate dihydrate
US2984052A (en) * 1959-08-12 1961-05-16 Norton Co Coated abrasives
US3426486A (en) * 1964-11-16 1969-02-11 Landis Tool Co Abrasive disc
US3420007A (en) * 1966-07-11 1969-01-07 Wallace Murray Corp Abrasive tool
US3861892A (en) * 1973-02-08 1975-01-21 Norton Co Coated abrasive material and manner of manufacture
NL160303C (nl) * 1974-03-25 1979-10-15 Verto Nv Werkwijze voor het vervaardigen van een vezelfilter.
GB1466545A (en) * 1974-03-26 1977-03-09 Nederman B Abrasive disc
NL181632C (nl) * 1976-12-23 1987-10-01 Minnesota Mining & Mfg Electreetfilter en werkwijze voor het vervaardigen daarvan.
US4215682A (en) * 1978-02-06 1980-08-05 Minnesota Mining And Manufacturing Company Melt-blown fibrous electrets
US4287685A (en) * 1978-12-08 1981-09-08 Miksa Marton Pad assembly for vacuum rotary sander
US4282011A (en) * 1980-05-30 1981-08-04 Dan River Incorporated Woven fabrics containing glass fibers and abrasive belts made from same
US4374888A (en) * 1981-09-25 1983-02-22 Kimberly-Clark Corporation Nonwoven laminate for recreation fabric
JPS60168511A (ja) * 1984-02-10 1985-09-02 Japan Vilene Co Ltd エレクトレツトフイルタの製造方法
US4609581A (en) * 1985-04-15 1986-09-02 Minnesota Mining And Manufacturing Company Coated abrasive sheet material with loop attachment means
US4629473A (en) * 1985-06-26 1986-12-16 Norton Company Resilient abrasive polishing product
US4725487A (en) * 1986-03-28 1988-02-16 Norton Company Flexible coated abrasive and fabric therefor
US4714644A (en) * 1986-12-30 1987-12-22 Minnesota Mining And Manufacturing Company Sanding pad
US4894060A (en) * 1988-01-11 1990-01-16 Minnesota Mining And Manufacturing Company Disposable diaper with improved hook fastener portion
US5254194A (en) * 1988-05-13 1993-10-19 Minnesota Mining And Manufacturing Company Coated abrasive sheet material with loop material for attachment incorporated therein
JP2672329B2 (ja) * 1988-05-13 1997-11-05 東レ株式会社 エレクトレット材料
US5058247A (en) * 1989-01-31 1991-10-22 The Procter & Gamble Company Mechanical fastening prong
US5036627A (en) * 1989-06-28 1991-08-06 David Walters Dustless sanding device
US5007206A (en) * 1989-10-05 1991-04-16 Paterson Patrick J Dustless drywall sander
DE8912060U1 (fr) * 1989-10-10 1991-02-07 Norddeutsche Schleifmittel-Industrie Christiansen & Co (Gmbh & Co), 2000 Hamburg, De
US5131924A (en) * 1990-02-02 1992-07-21 Wiand Ronald C Abrasive sheet and method
US5679302A (en) * 1990-09-21 1997-10-21 Minnesota Mining And Manufacturing Company Method for making a mushroom-type hook strip for a mechanical fastener
US5306545A (en) * 1991-12-11 1994-04-26 Mitsui Petrochemical Industries, Ltd. Melt-blown non-woven fabric and laminated non-woven fabric material using the same
US5316812A (en) * 1991-12-20 1994-05-31 Minnesota Mining And Manufacturing Company Coated abrasive backing
GB2267680A (en) * 1992-06-02 1993-12-15 Kimberly Clark Ltd Absorbent,abrasive composite non-woven web
US5344688A (en) * 1992-08-19 1994-09-06 Minnesota Mining And Manufacturing Company Coated abrasive article and a method of making same
AU669420B2 (en) * 1993-03-26 1996-06-06 Minnesota Mining And Manufacturing Company Oily mist resistant electret filter media
EP0619165A1 (fr) * 1993-04-07 1994-10-12 Minnesota Mining And Manufacturing Company Article abrasif
EP0714463B1 (fr) * 1993-08-17 1999-03-10 Minnesota Mining And Manufacturing Company Procede de charge d'un filtre a electret
US5458532A (en) * 1994-01-12 1995-10-17 Cannone; Salvatore L. Undulating edged pad holder for rotary floor polishers
TW317223U (en) * 1994-01-13 1997-10-01 Minnesota Mining & Mfg Abrasive article
US5607345A (en) * 1994-01-13 1997-03-04 Minnesota Mining And Manufacturing Company Abrading apparatus
FI96585C (sv) * 1994-09-06 1996-07-25 Kwh Mirka Ab Oy Slipprodukt
US5674122A (en) * 1994-10-27 1997-10-07 Minnesota Mining And Manufacturing Company Abrasive articles and methods for their manufacture
US5578343A (en) * 1995-06-07 1996-11-26 Norton Company Mesh-backed abrasive products
US5908598A (en) * 1995-08-14 1999-06-01 Minnesota Mining And Manufacturing Company Fibrous webs having enhanced electret properties
US5807161A (en) * 1996-03-15 1998-09-15 Minnesota Mining And Manufacturing Company Reversible back-up pad
CA2192880C (fr) * 1996-12-13 2005-02-22 Brian H. Parrott Dispositifs de poncage et elements similaires pour l'enlevement de materiau
US6077601A (en) * 1998-05-01 2000-06-20 3M Innovative Properties Company Coated abrasive article
US5989112A (en) * 1998-05-11 1999-11-23 Norton Company Universal abrasive disc
US6074292A (en) * 1998-06-05 2000-06-13 Gilday; Mark Byron Compounding, glazing, or polishing pad with vacuum action
DE19843266A1 (de) * 1998-09-21 2000-03-23 Martin Wiemann Gitterleinen-Schleifmaterial und Schleifverfahren
US6139308A (en) * 1998-10-28 2000-10-31 3M Innovative Properties Company Uniform meltblown fibrous web and methods and apparatus for manufacturing
US6910823B2 (en) * 1998-11-09 2005-06-28 The Procter & Gamble Company Cleaning composition, pad, wipe, implement, and system and method of use thereof
JP3526226B2 (ja) * 1998-11-11 2004-05-10 キヤノン株式会社 シート処理装置及びこれを備える画像形成装置
US6302930B1 (en) * 1999-01-15 2001-10-16 3M Innovative Properties Company Durable nonwoven abrasive product
US6203418B1 (en) * 1999-03-05 2001-03-20 Doyle D. Hendrickson Precision taxidermy and field-use micro cutting system
RU2153839C1 (ru) * 1999-09-08 2000-08-10 Открытое акционерное общество "Научно-исследовательский институт нетканых материалов" Обтирочная салфетка
US6713413B2 (en) * 2000-01-03 2004-03-30 Freudenberg Nonwovens Limited Partnership Nonwoven buffing or polishing material having increased strength and dimensional stability
DE10012243A1 (de) * 2000-03-14 2001-09-20 Bosch Gmbh Robert Elektrohandschleifmaschine, insbesondere Exzenterschleifer
US6575821B2 (en) * 2000-08-01 2003-06-10 Joest Peter Abrasive belt for a belt grinding machine
EP1332194B1 (fr) * 2000-10-06 2007-01-03 3M Innovative Properties Company Particules d'agregat de ceramique
US20020090901A1 (en) * 2000-11-03 2002-07-11 3M Innovative Properties Company Flexible abrasive product and method of making and using the same
FR2820666B1 (fr) * 2001-02-14 2003-04-11 Arjo Wiggins Sa Support autoagrippant pour un produit abrasif applique et procede de fabrication dudit produit abrasif l'incorporant
US7108594B2 (en) * 2001-03-16 2006-09-19 Saint-Gobain Abrasives Technology Company Perforated sanding disc
US20040180618A1 (en) * 2001-09-03 2004-09-16 Kazuo Suzuki Sheet-form abrasive with dimples or perforations
US7291369B2 (en) * 2001-10-03 2007-11-06 3M Innovative Properties Company Multi-layer articles including a fluoroelastomer layer and a barrier layer and method of making the same
US20040209561A1 (en) * 2001-11-13 2004-10-21 Kazuo Suzuki Abrasive material
US6613113B2 (en) * 2001-12-28 2003-09-02 3M Innovative Properties Company Abrasive product and method of making the same
US6723142B2 (en) * 2002-06-05 2004-04-20 Tepco Ltd. Preformed abrasive articles and method for the manufacture of same
RU2222417C1 (ru) * 2002-10-16 2004-01-27 Чернов Олег Анатольевич Универсальная плоскошлифовальная машина
US20040098923A1 (en) * 2002-11-25 2004-05-27 3M Innovative Properties Company Nonwoven abrasive articles and methods for making and using the same
US6860912B2 (en) * 2003-02-04 2005-03-01 Webb Manufacturing Corporation Abrasive filament, abrasive articles incorporating abrasive filament and method of making abrasive filaments and abrasive articles
US20040166788A1 (en) * 2003-02-20 2004-08-26 George Travis Sanding disc
US7048984B2 (en) * 2003-02-28 2006-05-23 3M Innovative Properties Company Net structure and method of making
FI114902B (sv) * 2003-10-06 2005-01-31 Kwh Mirka Ab Oy Slipprodukt
US20060019579A1 (en) * 2004-07-26 2006-01-26 Braunschweig Ehrich J Non-loading abrasive article
EP1838497B1 (fr) * 2004-12-30 2016-07-13 3M Innovative Properties Company Article abrasif et procedes de fabrication
FI121653B (sv) * 2005-06-13 2011-02-28 Kwh Mirka Ab Oy Flexibel slipprodukt och förfarande för tillverkning av densamma
US7258705B2 (en) * 2005-08-05 2007-08-21 3M Innovative Properties Company Abrasive article and methods of making same
US7252694B2 (en) * 2005-08-05 2007-08-07 3M Innovative Properties Company Abrasive article and methods of making same
US7244170B2 (en) * 2005-09-16 2007-07-17 3M Innovative Properties Co. Abrasive article and methods of making same
US7393269B2 (en) * 2005-09-16 2008-07-01 3M Innovative Properties Company Abrasive filter assembly and methods of making same
US7390244B2 (en) * 2005-09-16 2008-06-24 3M Innovative Properties Company Abrasive article mounting assembly and methods of making same
US7338355B2 (en) * 2006-06-13 2008-03-04 3M Innovative Properties Company Abrasive article and methods of making and using the same
US7452265B2 (en) * 2006-12-21 2008-11-18 3M Innovative Properties Company Abrasive article and methods of making same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008115663A1 *

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CN101636243B (zh) 2011-12-28
EP2129488B1 (fr) 2011-06-29
US20080233850A1 (en) 2008-09-25
RU2452613C2 (ru) 2012-06-10
JP5238726B2 (ja) 2013-07-17
JP2010522091A (ja) 2010-07-01
ATE514523T1 (de) 2011-07-15
WO2008115663A1 (fr) 2008-09-25
BRPI0808973A2 (pt) 2014-08-26
CN101636243A (zh) 2010-01-27
RU2009134880A (ru) 2011-04-27

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