EP2123833A1 - Dispositif de distribution de substances actives liquides - Google Patents

Dispositif de distribution de substances actives liquides Download PDF

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Publication number
EP2123833A1
EP2123833A1 EP09008188A EP09008188A EP2123833A1 EP 2123833 A1 EP2123833 A1 EP 2123833A1 EP 09008188 A EP09008188 A EP 09008188A EP 09008188 A EP09008188 A EP 09008188A EP 2123833 A1 EP2123833 A1 EP 2123833A1
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EP
European Patent Office
Prior art keywords
active substance
dispensing device
phase
reservoir
active
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09008188A
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German (de)
English (en)
Other versions
EP2123833B1 (fr
Inventor
Ralph Butter-Jentsch
Roland Menke
Hans-Georg MÜHLHAUSEN
Frank Pessel
Detlef Lehmann
Ltuz Gräßer
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Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority claimed from EP01996653.0A external-priority patent/EP1334243B1/fr
Publication of EP2123833A1 publication Critical patent/EP2123833A1/fr
Application granted granted Critical
Publication of EP2123833B1 publication Critical patent/EP2123833B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E03D9/032—Devices connected to or dispensing into the bowl

Definitions

  • the invention relates to a delivery device for delivering active substance fluids into the rinsing liquid in a toilet bowl having the features of the preamble of claim 1.
  • active ingredient fluid means flowable, that is liquid to viscous, possibly gelatinous or pasty or granular or otherwise pourable active substance preparations with cleansing, disinfecting, deodorizing, bleaching and the like. Effect (especially described in the non-prepublished DE 199 30 362 A1 , as well as in the EP 0 775 741 A1 and the EP 0 960 984 A2 ).
  • Dispensers of the type in question are known under the keyword “toilet bowl” in different versions.
  • dispensing devices for a single active substance fluid are known.
  • the drug fluid is there in a fixed in a holder or interchangeably inserted reservoir with a mounted on the holder reservoir bottom outlet opening arranged.
  • a first known dispensing device for a single active substance fluid the active substance fluid is added via an actuating element (eg made of an open-cell foam) which can be impregnated therewith and acted upon by the irrigation fluid (EP 785 315 A1 ).
  • an actuating element eg made of an open-cell foam
  • the outlet opening of the reservoir after expulsion of a closure member of the reservoir of a holder fixedly arranged on the sealing member is largely closed, so that only a flow path with a small cross-section for leakage of the active ingredient fluid is available.
  • the device works by utilizing the capillary action of the open cell foam.
  • a similar construction is also known with a distribution ribbed plate.
  • Another delivery device for a single drug fluid ( DE 299 02 066 U1 ) realized on the reservoir a valve-like working sealing element, which normally assumes a positive closed closed position in which the outlet opening is closed. This happens under the effect of the weight of a valve ball acting as a sealing element.
  • This sealing element can be adjusted against the biasing force in the outlet opening a little releasing release position.
  • Each chamber has a dispenser with a dispensing tube, which exits with its one free end over the bottom of the container into the environment and at its other free end fluid leading surrounded by a cover.
  • the two chambers of the container can be filled via slit-like passages of a cover part of overflowing rinse water, which then exits in the manner of a siphon or headwaters on the delivery tubes with entrainment of the respective active ingredient in the toilet bowl.
  • the separation of the chambers in the container has the advantage that different media can be used, which would otherwise be detrimentally influenced in their desired effect in a common storage in only one chamber. The consistency of the media may vary in the different chambers.
  • a two-chamber dispenser for the same or different, gel-like drug fluids ( WO 92/20876 A1 ), in which the outlet openings are designed as bottom-side perforations in the storage containers and are permanently open. Due to the viscosity and surface tension of the gel, this normally can not escape by itself under gravitational force. Only by overflowing rinsing liquid, which enters the outlet openings from below and which slightly dissolves the outlet openings near gel, subsets of the active substance fluids can be discharged.
  • the teaching is based on the problem of optimizing the known, previously explained dispensing device for dispensing active fluid from at least two separate reservoir with respect to the control option for the delivery of the drug fluids.
  • an embodiment of the dispensing device according to the invention according to claim 16 is particularly useful.
  • a positive closure of the outlet openings is useful in this design, in particular for the purpose of the defined dimensioning of the subsets and for the purpose of protecting the active ingredient fluids in the reservoirs with prolonged non-use.
  • Fig. 1 to Fig. 3 illustrated dispensing device serves to deliver at least two active fluids in the rinsing fluid, with which is rinsed in a toilet bowl.
  • drug fluid has already been defined in the general part of the description, it should be pointed out.
  • Such a dispensing device initially has a holder 1 which can be suspended at the edge of the toilet bowl and at least two storage containers 2, 3, which are provided in the holder 1 and are separated from each other, for one active substance fluid in each case.
  • the drug fluids may be matched, different, compatible or incompatible drug fluids.
  • Such active substance fluids are, for example, fragrance phases, in particular perfumed fragrance phases.
  • fragrance phases usually comprise at least one perfume, preferably perfume oil, at least one surfactant or an emulsifier and water and optionally further ingredients such as preservatives, thickeners, complexing agents, dyes, other surfactants or emulsifiers, stabilizers, Decalcifier etc.
  • bleaching phases in particular chlorine-containing bleaching phases, preferably bleaching phases based on hypochlorite, wherein the bleaching phases may contain, in addition to the actual bleaching agent and water, optionally further ingredients such as thickeners, surfactants or emulsifiers, neutralizing agents, dyes, fragrances, etc.
  • lime-dissolving active substance phases preferably acidic lime-dissolving active substance phases.
  • Such lime-solubilizing active ingredient phases may contain, in addition to the actual lime solubilizer - preferably this is an organic or inorganic acid - and water optionally further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
  • Such highly concentrated surfactant phases may also contain other conventional ingredients in addition to the surfactants.
  • active-ingredient fluids having an antibacterial and / or fungicidal and / or antiviral active phase, wherein the active-substance phase, in addition to the antibacterial and / or fungicidal and / or antiviral active and water, optionally further ingredients, such as, for example, surfactants or emulsifiers, thickeners, fragrances , Preservatives, etc. may contain.
  • the active substance fluids are enzyme-containing active substance phases.
  • enzyme (s) and water such enzyme-containing active substance phases may optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
  • the active substance fluids used according to the invention are absorbent, in particular odor-absorbing, active-substance phases. These may, in addition to the absorbent, in particular odor absorbent, and water optionally further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc. included.
  • the dispensing device offers the possibility of using combinations of different active substance fluids in the storage containers 2, 3, wherein according to a preferred embodiment one of the storage containers 2, 3 contains a fragrance phase, in particular as defined above.
  • active substance fluid combinations to be used are perfumed fragrance phase combined with chlorine bleach (together not storage-stable), perfumed fragrance phase with highly concentrated surfactant phase (foam booster), fragrance phase with limesolvent, acidic active phase, fragrance phase with antibacterial active ingredient phase, different acid systems, fragrance phase combined with enzyme-containing active substance phase, perfumed acid phase combined with water-coloring phase, fragrance phase with odor-absorbing phase, perfumed acid phase with active oxygen, perfumed acid phase with active substance phase, thickened with polyacrylate etc.
  • viscous to gel-like active substance fluids with viscosities in the range of a few thousand mPas, in particular 2000 up to 5000 mPas, preferably 2500 to 3500 mPas (measured with Rotovisko LVT, spindle 2, 6 rpm, 20 ° C).
  • each storage container 2, 3 has its own outlet opening 4, via which the respective active substance fluid can be dispensed into the rinsing liquid.
  • the outlet openings 4 of the reservoir 2, 3 are arranged so that only active fluid exits.
  • the delivery of a subset of the active substance fluid from each of the storage containers 2, 3 takes place in the rinsing liquid.
  • this is realized in that the outlet opening 4 of the respective storage container 2, 3 in the use position, as shown in FIG Fig. 2 , is arranged on the bottom side. Overflowing rinse water meets at most laterally on the reservoir 2, 3rd
  • the reservoir 2, 3 are mounted individually replaceable in the holder 1 or attachable.
  • An alternative is the storage container 2, 3 by means of an adapter or the like. to couple together and so coupled in the holder 1 to install.
  • a further alternative is to couple the storage containers 2, 3 directly to one another and to mount them directly coupled in the holder 1.
  • the reservoir 2, 3 in a common, one-piece housing form, for example, as a separate chambers in a contiguous housing, and then to attach to the holder 1.
  • one or the other variant will be chosen.
  • the illustrated embodiment shows the reservoir 2, 3 as exchangeable disposable containers, which will probably be more common in practice.
  • the illustrated and preferred embodiment shows the reservoir 2, 3 arranged on the holder 1 side by side. The same applies to an arrangement of the reservoir 2, 3 in a row.
  • the illustrated and preferred embodiment also shows that the reservoir 2.3, which are here individually interchangeable, in the holder 1 by plugging in from above (in the use position) are attachable.
  • the reservoir 2, 3 attach laterally on the holder 1 and then swing in the position of use about a pivot axis.
  • the storage container 2, 3 has a flexible wall portion or a total of a flexible wall and an application of the active substance contained therein by pressurizing the reservoir 2, 3 takes place. This pressurization can be exercised for example by a corresponding mechanism by the overflowing rinsing liquid.
  • the dispensing mechanisms known in principle for dispensing devices for a single active substance fluid of the prior art can be used.
  • a plate-like distribution element is provided which has an overflowed during rinsing of rinsing fluid Beaufschlagungs Scheme, the interior of the reservoir 2, 3 via the outlet opening 4, if necessary, with interposition of a free Flow of the drug fluid preventing arrangement, permanently communicating with the distribution element.
  • the plate-like distribution element is assigned to all storage containers 2, 3 together.
  • the illustrated and preferred embodiment shows a solution that operates with an actively closing sealing element.
  • an actively closing sealing element namely, the bottom side arranged outlet opening 4 of the reservoir 2, 3 closed by means of a sealing element 5.
  • the sealing element 5 is biased into the closing position closing the outlet opening 4 and adjustable against the biasing force in a release opening 4 a little releasing release position.
  • actuating element 6 which is temporarily such a force acted upon in such a way with each flushing by the rinsing liquid, that the sealing element 5 temporarily assumes the release position against the biasing force.
  • an actuation element 6 acts on an impingement process of flushing fluid applied to the actuation element 7, so that the flushing fluid impinges during the flushing process.
  • the actuator 6 is designed as a one-armed, at one end hinged to the holder 1 lever.
  • the sealing element 5 is arranged on the actuating element 6 at a certain distance from the loading area 7. Due to the one-armed design of the actuating element 6 forming lever ( Fig.
  • the sealing element 5 is arranged between the hinged to the holder 1 end of the actuating element 6 and the loading area 7.
  • the opening path of the sealing element 5 is thus comparatively low, the opening is as desired only with a very small gap.
  • this gap is opened asymmetrically with a corresponding design of the sealing element 5, namely, more strongly opening in the direction of the loading region 7, so that active substance fluid preferably exits in this direction.
  • This is the direction to the rinsing fluid with which the active fluid then mixes accordingly.
  • the active substance fluid can therefore run on the upper side of the actuating element 6 in the direction of the loading region 7 and already mixes with the overflowing rinsing fluid on this route.
  • the sealing element 5 is integrally formed on the actuating element 6. This is recommended in particular in the design of the actuating element 6 made of a plastic material, in particular of plastic spritzcalledem.
  • the holder 1 may be made of plastic, in particular of plastic, preferably plastic, preferably thermoplastic material in a particularly preferred manner. Overall, it can be provided that the actuating element 6 is integrally formed on the holder 1 and the biasing force is generated by the inherent elasticity of the confirmation element 6.
  • chlorine-containing bleaching phase (about 1% active chlorine)
  • fragrance phase combined with acidic, limescale active ingredient phase
  • FAEOS-Na C 12-14 + 2 EO 24.50%.
  • surfactant / emulsifier 1 2-propanediol 5.00% emulsifier Ethanol 96%, 1% MEK denatured 5.00% Co.
  • connection point 10 is star-shaped / conical designed as a kind Auf lakespitze.
  • connection points 10 are arranged adjacent to each other near the longitudinal edge and that the distribution element 6 'on the upper side of the connection points 10 and starting approximately to the opposite longitudinal edge reaching recesses 11, which serve to distribute the drug fluids in the rinsing liquid ,
  • the wells 11 can fulfill their function of distributing the active fluid in the rinsing liquid useful, it is recommended that the wells 11 grooved, preferably with a U-shaped, V-shaped, W-shaped or semicircular cross-section or as a series of punctiform depressions or are designed as spaces between rows of punctiform or stripe-shaped elevations. It can be provided that the recesses 11 widen or taper towards their ends.
  • the recesses 11 are groove-shaped, with these recesses 11 widening towards their ends.
  • the recesses 11 are arranged straight and / or parallel to each other, radially, curved, zigzag-shaped, wave-shaped or cascade-shaped. In the embodiment of 4 and FIG. 5 the recesses are straight and parallel to each other.
  • the depressions 11 originating from the various connection points 10 or not assigned thereto do not intersect or do not predominantly cross each other.
  • the active substance fluids of the various storage containers 2, 3 are premixed relatively quickly. This is helped by the fact that the outgoing from different connection points 10 recesses 11 are arranged crossing each other or at least partially converging. Otherwise, intersecting depressions 11 can also be used,
  • connection points 10 are connected near the longitudinal edge directly via at least one transverse recess 12 with each other. This results in a cross-mixing on a relatively wide recess 12 in the area under the storage containers 2, 3rd
  • the distribution element 6 'or in the alternative design variant of the actuating element 6, there are also various possibilities. It can initially be provided that the distribution element 6 'or the actuating element 6 in plan view is approximately rectangular, square, round, oval or elliptical. That in the 4 and 5 For example, shown distribution element 6 'is formed in plan view approximately rectangular.
  • the distribution element 6 'in section there are also various possibilities. One is not committed to a smooth flat shape.
  • the term "plate-like” may also include inclined and undulating shapes.
  • the distribution element 6 'or the actuating element 6 as a whole is of concave, convex, cross-section, curved, shell-shaped, cascade-shaped or funnel-shaped running is designed. This can also be realized per connection point 10, ie in sections.
  • the distribution element 6 primarily plastic and that a hygienically suitable plastic, such as polypropylene.
  • a sintered material in particular a sintered plastic, which due to its porosity may have an additional storage function and a mixing function and the function of foaming the rinsing fluid mixed with active substance fluid, could be recommended here.
  • Alternatives are, of course, other materials such as ceramic, glass, metal or, in a particularly essential variant also a suitably equipped wood.
  • the number of recesses 11 on the distribution element 6 'or the actuator 6 is between 2 and 100, preferably between 10 and 50. It should further be provided that the width of the recesses 11 at the surface is between 0.5 and 5.0 mm, preferably between 1.0 and 2.0 mm. Finally, it is recommended that the depth of the recesses 11 is between 0.2 mm and 4.0 mm, preferably between 0.5 mm and 2.0 mm.
  • the total area of the distribution element 6' or the actuating element 6 between 500 mm 2 and 8000 mm 2 , preferably between 2000 mm 2 and 4000 mm 2 .
  • the present patent application but also relates to a dispensing device, which, while taking into account the delivery of several, at least two drug fluids have been optimized, but can also be used as a dispensing device for a single drug fluid.
  • Fig. 25 shows in this respect a particularly suitably designed flushing plate, so a fixed distribution element 6 ', which is also carried out again plate-like, in this dispensing device two provided in the holder 1 reservoir 2, 3 are provided. But one can also imagine purely constructive as well that this arrangement can be realized even with only one reservoir 2.
  • the distribution element 6 on the top in one hand, a starting from a longitudinal edge 13 terminal portion 14 in which a connection point 10 for the outlet opening 4 of the reservoir 2; 3 is arranged, and on the other hand, from the terminal portion 14 substantially to the opposite longitudinal edge 15 reaching Beaufschlagungs Scheme 7 'is divided and that the surface in the connection area 14, except for technical reasons, technical connection or sealing reasons existing individual increases, depressions or breakthroughs, running smooth is. It has been found that the smooth upper surface of the distribution element 6 'with proper adjustment of the gap between the lower edge of the outlet opening 4 of the reservoir 2, 3 and the top of the distribution element 6', a sufficient distribution of the active substance fluid and a sufficient charge of the loading region 7 ' allowed. The experiments realized in the prior art with all imaginable formations in the connection area 14 have thus proved to be not necessarily necessary, if it adjusts other parameters of the overall arrangement appropriate.
  • connection area 14 is not everywhere a smooth surface, but a smooth surface with the exception of such elevations, depressions or breakthroughs, which are available for technical reasons, technical connection and sealing reasons. It is essential that the surface on which the active substance fluid is distributed, is a smooth surface, so has neither ribs nor grooves, nor is a porous plate.
  • the illustrated embodiment shows the plate-like distribution element 6 'for both reservoirs 2, 3 together. These are then in the connection area 14 adjacent spaced the connection points 10 for the outlet openings 4 of the reservoir 2, 3. Especially in the mixing of different active fluids, the constructive solution shown here for the distribution element 6 'has proven in practice to be useful.
  • Fig. 25 further shows that between the outer edge of the connection point 10 and the Beauftschungs Schemees 7 'is a wide strip of smooth surface of the terminal portion 14.
  • connection points 10 again embodied as a type of impact tip, as has already been described in the previously described embodiments:
  • FIG. 27 shows, the lower edge 17, the outlet opening 4 of the reservoir 2 as a spacer assembly with individual, slightly axially projecting spacers 16 'is executed, which sit in mounted reservoir 2 on the top of the distribution element 6' in the connection area 14. Since then the spacers 16 'have just moved to the lower edge 17 of the reservoir 2, 3.
  • FIG. 25 illustrated and preferred embodiment also shows that the distribution element 6 'in the loading region 7' starting from the edge of the terminal portion 14 and approximately to the opposite longitudinal edge 15 reaching recesses 11, which serve to distribute the active substance fluid or the drug fluids in the rinsing liquid.
  • recesses 11 which serve to distribute the active substance fluid or the drug fluids in the rinsing liquid.
  • the illustrated embodiment shows parallel recesses 11. These are known from the prior art for decades.
  • Fig. 26 shows a vertical section through a dispenser, the distribution element 6 'as in Fig. 25 has shown.
  • the holder 1 has a reservoir 2 or the reservoir 2, 3 receiving carrier 18, wherein the loading area 7 'facing front wall 19 at the transition from the terminal portion 14 extends to the loading area 7'.
  • the front wall 19 of the holder 1 serves to shield the reservoir 2, 3 against unwanted ingress of water. Consequently, it is recommended that the recesses 11 extend below the edge of the front wall 19 in order to form a gap as narrow as possible through which as little water as possible can enter.
  • Fig. 25 makes the position of the front wall 19 of the holder 1 with respect to the recesses 11 in the loading area 7 'of the distribution element 6' clearly.
  • Fig. 26 Further, it is clear that in the embodiment shown here, the carrier 18 is not an integral part of the holder 1, but is a separate insert part which is inserted into the holder 1.
  • the front wall 19 is formed here on the holder 1. If the carrier 19 is an integral part of the holder 1, the front wall 19 is naturally formed on the holder 18.
  • the illustrated embodiment can in Fig. 26 Incidentally, recognize that the top of the distribution element 6 'in the connection region 14 at the level of the lowest point of the recesses 11 in the loading region 7' extends. The active substance fluid can thus enter the recesses 11 on the face side. At the same time, the accessibility of water under the edge of the front wall 19 is restricted as much as possible.
  • Fig. 26 Moreover, further, that between the underside of the holder 1 and the surface of the distribution element 6 'in the connection region 14 in the free areas results in a considerable vertical distance.
  • Fig. 25 finally shows that, as already explained, the top of the distribution element 6 'in the connection area 14 for the active substance fluid is smooth, but otherwise may have individual increases for technical reasons, technical connection and sealing reasons.
  • Fig. 25 shows as from sealing-technical reasons existing increase that in the connection area 14 on the one longitudinal wheel 13 facing side of the connection point 10, in particular the spacers 16 on this page comprising a slightly upwardly projecting from the top protective edge 20 is formed.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Epidemiology (AREA)
  • Detergent Compositions (AREA)
  • Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
EP09008188A 2000-11-17 2001-11-09 Dispositif de distribution de substances actives liquides Expired - Lifetime EP2123833B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10057325 2000-11-17
DE10113036A DE10113036B4 (de) 2000-11-17 2001-03-17 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
DE20113329 2001-08-17
DE20116295 2001-10-04
EP01996653.0A EP1334243B1 (fr) 2000-11-17 2001-11-09 Dispositif de distribution servant a distribuer des liquides actifs

Related Parent Applications (3)

Application Number Title Priority Date Filing Date
EP01996653.0 Division 2001-11-09
EP01996653.0A Division EP1334243B1 (fr) 2000-11-17 2001-11-09 Dispositif de distribution servant a distribuer des liquides actifs
EP01996653.0A Division-Into EP1334243B1 (fr) 2000-11-17 2001-11-09 Dispositif de distribution servant a distribuer des liquides actifs

Publications (2)

Publication Number Publication Date
EP2123833A1 true EP2123833A1 (fr) 2009-11-25
EP2123833B1 EP2123833B1 (fr) 2011-03-09

Family

ID=26007712

Family Applications (4)

Application Number Title Priority Date Filing Date
EP01955364A Expired - Lifetime EP1334239B1 (fr) 2000-11-17 2001-07-21 Dispositif de distribution pour ajouter des fluides actifs a l'eau de la chasse dans une cuvette de w.c.
EP05022491A Withdrawn EP1614817A1 (fr) 2000-11-17 2001-07-21 Dispositif de distribution pour ajouter des fluides actifs à l'eau de la chasse dans une cuvette de w.c.
EP09008185A Expired - Lifetime EP2116656B1 (fr) 2000-11-17 2001-11-09 Dispositif de distribution de substances actives liquides
EP09008188A Expired - Lifetime EP2123833B1 (fr) 2000-11-17 2001-11-09 Dispositif de distribution de substances actives liquides

Family Applications Before (3)

Application Number Title Priority Date Filing Date
EP01955364A Expired - Lifetime EP1334239B1 (fr) 2000-11-17 2001-07-21 Dispositif de distribution pour ajouter des fluides actifs a l'eau de la chasse dans une cuvette de w.c.
EP05022491A Withdrawn EP1614817A1 (fr) 2000-11-17 2001-07-21 Dispositif de distribution pour ajouter des fluides actifs à l'eau de la chasse dans une cuvette de w.c.
EP09008185A Expired - Lifetime EP2116656B1 (fr) 2000-11-17 2001-11-09 Dispositif de distribution de substances actives liquides

Country Status (21)

Country Link
US (2) US20040068782A1 (fr)
EP (4) EP1334239B1 (fr)
JP (1) JP2004526075A (fr)
CN (1) CN1474901A (fr)
AR (1) AR031465A1 (fr)
AT (3) ATE315140T1 (fr)
AU (1) AU2001277547A1 (fr)
CR (1) CR6973A (fr)
CZ (4) CZ305483B6 (fr)
DE (4) DE10113036B4 (fr)
ES (3) ES2206080T3 (fr)
HU (1) HU228554B1 (fr)
PL (1) PL196974B1 (fr)
PT (2) PT2123833E (fr)
RO (1) RO120857B1 (fr)
RU (1) RU2266372C2 (fr)
SI (1) SI21141B (fr)
SK (1) SK5812003A3 (fr)
TR (1) TR200301652T3 (fr)
UA (1) UA74854C2 (fr)
WO (1) WO2002040791A1 (fr)

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PL361188A1 (en) 2004-09-20
ATE523640T1 (de) 2011-09-15
ATE315140T1 (de) 2006-02-15
CZ305484B6 (cs) 2015-10-21
HUP0301545A3 (en) 2006-03-28
HUP0301545A2 (en) 2006-01-30
CZ305483B6 (cs) 2015-10-21
DE10113036B4 (de) 2005-02-17
EP1334239A1 (fr) 2003-08-13
HU228554B1 (en) 2013-03-28
PT2116656E (pt) 2011-11-21
US20040068782A1 (en) 2004-04-15
EP2116656B1 (fr) 2011-09-07
CN1474901A (zh) 2004-02-11
CZ299957B6 (cs) 2009-01-07
DE50115818D1 (de) 2011-04-21
TR200301652T3 (tr) 2003-11-21
EP1334239B1 (fr) 2006-01-04
US20040107484A1 (en) 2004-06-10
RO120857B1 (ro) 2006-08-30
CZ305459B6 (cs) 2015-10-07
EP1614817A1 (fr) 2006-01-11
AR031465A1 (es) 2003-09-24
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SK5812003A3 (en) 2004-06-08
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ES2206080T1 (es) 2004-05-16
UA74854C2 (en) 2006-02-15
RU2266372C2 (ru) 2005-12-20
EP2123833B1 (fr) 2011-03-09
JP2004526075A (ja) 2004-08-26
SI21141A (sl) 2003-08-31
AU2001277547A1 (en) 2002-05-27
PT2123833E (pt) 2011-06-15
WO2002040791A1 (fr) 2002-05-23
ES2361806T3 (es) 2011-06-22
CR6973A (es) 2006-03-28
ES2370687T3 (es) 2011-12-21
EP2116656A1 (fr) 2009-11-11
CZ20031361A3 (cs) 2004-03-17
DE50108626D1 (de) 2006-03-30
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SI21141B (sl) 2007-02-28
PL196974B1 (pl) 2008-02-29

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