EP2118973B1 - Bougie avec un isolant en céramique d'oxyde d'aluminium à haute pureté - Google Patents

Bougie avec un isolant en céramique d'oxyde d'aluminium à haute pureté Download PDF

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Publication number
EP2118973B1
EP2118973B1 EP07856717A EP07856717A EP2118973B1 EP 2118973 B1 EP2118973 B1 EP 2118973B1 EP 07856717 A EP07856717 A EP 07856717A EP 07856717 A EP07856717 A EP 07856717A EP 2118973 B1 EP2118973 B1 EP 2118973B1
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EP
European Patent Office
Prior art keywords
insulator
spark plug
weight
aluminium oxide
sintering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP07856717A
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German (de)
English (en)
Other versions
EP2118973A1 (fr
Inventor
Niessner Werner
Knoch Martin
Stetter Klaus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BorgWarner Ludwigsburg GmbH
Original Assignee
Beru AG
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Publication date
Application filed by Beru AG filed Critical Beru AG
Publication of EP2118973A1 publication Critical patent/EP2118973A1/fr
Application granted granted Critical
Publication of EP2118973B1 publication Critical patent/EP2118973B1/fr
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T13/00Sparking plugs
    • H01T13/20Sparking plugs characterised by features of the electrodes or insulation
    • H01T13/38Selection of materials for insulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T21/00Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs
    • H01T21/02Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs of sparking plugs

Definitions

  • the invention is based on a spark plug with the features specified in the preamble of claim 1.
  • a spark plug is from the EP 0 954 074 B1 known.
  • Advanced gasoline engines require more space in the cylinder head for intake valves and exhaust valves, and this is one reason why spark plugs with smaller diameters than before are required today.
  • Lighter spark plugs need a slimmer insulator. This in turn requires higher demands on the mechanical strength and electrical insulation, namely the dielectric strength, of the existing in the spark plug insulator, which usually consists of an alumina ceramic.
  • the JP-A 63-190753 discloses an alumina ceramic insulator made by mixing 95% by weight of alumina powder having an average particle size of 0.1 ⁇ m to 0.5 ⁇ m with yttria, magnesia and lanthana, liquid phase pressing and sintering.
  • the yttria, magnesium oxide and lanthanum oxide together make up 5% by weight of the mixture and serve as a sintering aid by leading to a liquid phase during sintering, the melting point of which is far below the melting point of the aluminum oxide.
  • the liquid phase spreads at the boundaries of the alumina particles and is said to inhibit their growth in the sintering process so that the sintered insulator still has a very finely divided structure.
  • the preserved by the sintering aids fine structure leads to the disclosure of JP-A 63-190753 extending the aluminum oxide particles extending along the boundaries of the sintering aids enriched paths over which electrical charges would move when voltage breakdown, and thus leads to an increase in the dielectric strength of the insulator.
  • an adverse effect on the electrical breakdown strength the fine pores, which are particularly numerous in the finely structured sintered insulator and the number increases with increasing content of alumina in the insulator, because at the same time the proportion of sintering aids, by the formation of a liquid phase the pores could close, decreasing.
  • This insulator is prepared by mixing alumina powder having an average particle size of not more than 1 .mu.m with 0.3 to 5 wt .-% of a sintering aid, pressed and sintered at a temperature between 1450 ° C and 1700 ° C in the liquid phase.
  • the sintering aid is selected so as not to interfere with the growth of the alumina powder particles during sintering. The sintering process takes place until at least half of the aluminum oxide has grown to particles with a size of 20 microns or more.
  • the sintering aid forms a liquid phase during sintering, which is to favor a small pore volume.
  • the present invention aims to further improve the dielectric strength of the insulator in spark plugs both at room temperature and, in particular, at the high temperatures which occur when the gasoline engine is in operation.
  • the spark plug according to the invention has an insulator containing 0.01 wt .-% to 1 wt .-% magnesium oxide, at most 0.3 wt .-% natural and / or caused by the manufacturing process impurities and the balance alumina and is formed by solid phase sintering , so that it is largely free of glass phases.
  • the insulator of the new spark plug contains 0.03 wt% to 0.15 wt%.
  • Magnesium oxide Even small additions of magnesium oxide reduce the crystal growth of the alumina during solid-phase sintering. From a content of 0.03 wt .-%, this effect becomes technically significant. At a content of more than 0.15% by weight of magnesium oxide, this effect is no longer significantly increased.
  • the insulator contains only natural and / or process-related impurities.
  • the invention dispenses with the addition of any sintering aids such as sodium oxide, yttrium oxide, lanthanum oxide, silica, barium oxide, boron oxide and the like, which at temperatures at which alumina can be sintered in solid phase, would form a liquid phase, from which after solidification Glass phase would.
  • Any minimal glass phases which may be detectable in an insulator according to the invention, can therefore only from the natural and / or process-related impurities present in the alumina come. In this sense, the statement in claim 1 is understood that the insulator should be largely free of glass phases.
  • the insulator of the spark plug according to the invention preferably contains more than 99.7% by weight of aluminum oxide. In this case, glass phases caused by the remaining impurities can no longer appreciably affect the electrical breakdown strength of the insulator.
  • a density of at least 3.85 g cm -3 is preferred.
  • a high density can be achieved if one starts from a very fine alumina powder, which preferably has an average particle size of less than 1 micron, if the insulator blanks sufficiently compacted before sintering, in particular by isostatic pressing, and if the sintering temperature and the sintering time is coordinated so that an insulator is obtained in which 90 wt .-% of the alumina having particle sizes of less than 5 microns, even better, with particle sizes of less than 3 microns.
  • the temperature for the solid phase sintering is a temperature in the range of 1,600 ° C to 1,700 ° C, well below the melting temperature of alumina, which is above 2,000 °.
  • FIG. 1 shows in a partially sectioned side view of the typical structure of a spark plug according to the invention, which has a center electrode 1 and in its extension a firing pin 2, which are at a distance behind each other in an insulator 4 according to the invention, namely in a longitudinal channel, in which they by a electrically conductive glass phase 3 are interconnected.
  • the insulator 4 is inserted in a metallic body 5, in which it is fixed by crimping and electric diving.
  • a ground electrode 6 is mounted, which is bent towards the center electrode 1 and this opposite to form a discharge gap with a defined distance.
  • the insulator consists z. B. from 99.8 wt .-% alumina, about 0.1 wt .-% magnesium oxide and the balance of natural and / or process-related impurities. It is formed by solid-phase sintering and contains no glass-containing secondary phase that can be detected by X-ray analysis.
  • the insulator according to the invention can be mounted in a known manner in the body 5 of the spark plug, so that existing manufacturing facilities and methods for mounting the insulator 4 as well as the center electrode 1 and the firing pin 2 can be used.
  • the required ceramic-metal compound is effected by means of an electrically conductive composite glass.
  • the electrically conductive glass mass 3 ensures the electrical connection between the center electrode 1 and the firing pin 2 and moreover has the task of introducing the center electrode 1 into the isolator 4 in a pressure-tight manner.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Spark Plugs (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Claims (7)

  1. Bougie d'allumage pour des moteurs à allumage par étincelle comprenant un corps métallique de bougie d'allumage (5), une électrode centrale (1), un isolateur en céramique (4) disposé entre l'électrode centrale (1) et le corps (5), à base d'oxyde d'aluminium, et comprenant au moins une électrode de masse (6), caractérisée en ce que l'isolateur (4) contient de l'oxyde de magnésium à concurrence de 0,01 % en poids à 1 % en poids, des impuretés naturelles et/ou liées aux processus à concurrence maximale de 0,3 % en poids, et pour le reste de l'oxyde d'aluminium, et est obtenu par frittage en phase solide, si bien qu'elle est très largement exempte de phases verre.
  2. Bougie d'allumage selon la revendication 1, caractérisée en ce que la teneur en oxyde de magnésium s'élève de 0,03 % en poids à 0,15 % en poids.
  3. Bougie d'allumage selon la revendication 1 ou 2, caractérisée en ce que l'isolateur (4) contient de l'oxyde d'aluminium à concurrence de plus de 99,7 % en poids.
  4. Bougie d'allumage selon l'une quelconque des revendications précédentes, caractérisée en ce que l'isolateur (4) présente une densité d'au moins 3,85 g/cm-3.
  5. Bougie d'allumage selon l'une quelconque des revendications 1 à 3, caractérisée en ce que l'isolateur (4) présente une densité de 3,90 ± 0,02 g/cm-3.
  6. Bougie d'allumage selon l'une quelconque des revendications précédentes, caractérisée en ce que, dans l'isolateur (4), sont présents 90 % en poids de l'oxyde d'aluminium avec des dimensions de cristallite inférieures à 5 µm (diamètre moyen).
  7. Bougie d'allumage selon la revendication 6, caractérisée en ce que, dans l'isolateur (4), sont présents 90 % en poids de l'oxyde d'aluminium avec des dimensions de cristallite inférieures à 3 µm.
EP07856717A 2006-12-20 2007-12-13 Bougie avec un isolant en céramique d'oxyde d'aluminium à haute pureté Active EP2118973B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006061907A DE102006061907A1 (de) 2006-12-20 2006-12-20 Zündkerze mit einem Isolator aus hochreiner Aluminiumoxid-Keramik
PCT/EP2007/010974 WO2008074438A1 (fr) 2006-12-20 2007-12-13 Bougie avec un isolant en céramique d'oxyde d'aluminium à haute pureté

Publications (2)

Publication Number Publication Date
EP2118973A1 EP2118973A1 (fr) 2009-11-18
EP2118973B1 true EP2118973B1 (fr) 2010-05-12

Family

ID=39147500

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07856717A Active EP2118973B1 (fr) 2006-12-20 2007-12-13 Bougie avec un isolant en céramique d'oxyde d'aluminium à haute pureté

Country Status (7)

Country Link
US (1) US20100007260A1 (fr)
EP (1) EP2118973B1 (fr)
JP (1) JP2010514114A (fr)
KR (1) KR20090098972A (fr)
AT (1) ATE467930T1 (fr)
DE (2) DE102006061907A1 (fr)
WO (1) WO2008074438A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11870221B2 (en) 2021-09-30 2024-01-09 Federal-Mogul Ignition Llc Spark plug and methods of manufacturing same

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6222384A (ja) * 1985-07-23 1987-01-30 日本特殊陶業株式会社 点火プラグ
DE3802233A1 (de) * 1987-01-22 1988-08-04 Jidosha Kiki Co Gluehkerze fuer einen dieselmotor
JPH0712969B2 (ja) 1987-01-30 1995-02-15 日本電装株式会社 アルミナ磁器および点火プラグ
JP2925425B2 (ja) * 1993-04-26 1999-07-28 日本特殊陶業株式会社 スパークプラグ用絶縁碍子
JP3036367B2 (ja) * 1994-08-19 2000-04-24 住友金属工業株式会社 アルミナ磁器組成物
CN1265522C (zh) * 1998-02-27 2006-07-19 日本特殊陶业株式会社 火花塞、用于火花塞的氧化铝基绝缘体及用于该绝缘体的生产方法
JP3859354B2 (ja) * 1998-04-30 2006-12-20 日本特殊陶業株式会社 スパークプラグ及びスパークプラグ用絶縁体及びその製造方法
JP2000007425A (ja) * 1998-06-29 2000-01-11 Sumitomo Chem Co Ltd 高強度アルミナ基板およびその製造方法
JP2000095557A (ja) * 1998-07-23 2000-04-04 Ngk Spark Plug Co Ltd スパ―クプラグ用アルミナ系絶縁体、その製造方法及びそれを用いたスパ―クプラグ
JP4530380B2 (ja) * 1999-11-29 2010-08-25 日本特殊陶業株式会社 スパークプラグ用絶縁体及びそれを備えるスパークプラグ
DE10036008A1 (de) * 2000-07-25 2002-02-07 Bosch Gmbh Robert Zündkerze für einen Verbrennungsmotor und Verfahren zur Herstellung einer Zündkerze
DE10132888A1 (de) * 2001-07-06 2003-01-30 Bosch Gmbh Robert Aluminiumoxidprodukt, insbesondere zur Verwendung als Zündkerzenisolator
JP4578025B2 (ja) * 2001-07-06 2010-11-10 日本特殊陶業株式会社 スパークプラグ
US7598661B2 (en) * 2006-06-23 2009-10-06 Federal-Mogul World Wide, Inc Spark plug

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11870221B2 (en) 2021-09-30 2024-01-09 Federal-Mogul Ignition Llc Spark plug and methods of manufacturing same

Also Published As

Publication number Publication date
KR20090098972A (ko) 2009-09-18
EP2118973A1 (fr) 2009-11-18
JP2010514114A (ja) 2010-04-30
DE102006061907A1 (de) 2008-06-26
ATE467930T1 (de) 2010-05-15
WO2008074438A1 (fr) 2008-06-26
DE502007003810D1 (de) 2010-06-24
US20100007260A1 (en) 2010-01-14

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