EP2118973B1 - Spark plug and insulator composed of high-purity aluminium oxide ceramic - Google Patents
Spark plug and insulator composed of high-purity aluminium oxide ceramic Download PDFInfo
- Publication number
- EP2118973B1 EP2118973B1 EP07856717A EP07856717A EP2118973B1 EP 2118973 B1 EP2118973 B1 EP 2118973B1 EP 07856717 A EP07856717 A EP 07856717A EP 07856717 A EP07856717 A EP 07856717A EP 2118973 B1 EP2118973 B1 EP 2118973B1
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- EP
- European Patent Office
- Prior art keywords
- insulator
- spark plug
- weight
- aluminium oxide
- sintering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012212 insulator Substances 0.000 title claims abstract description 52
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000000919 ceramic Substances 0.000 title claims abstract 3
- 238000005245 sintering Methods 0.000 claims abstract description 24
- 239000011521 glass Substances 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 11
- 239000012071 phase Substances 0.000 claims abstract description 11
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 239000007790 solid phase Substances 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 description 14
- 239000007791 liquid phase Substances 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 6
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- 239000011148 porous material Substances 0.000 description 5
- 238000010304 firing Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 210000002023 somite Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T13/00—Sparking plugs
- H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
- H01T13/38—Selection of materials for insulation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T21/00—Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs
- H01T21/02—Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs of sparking plugs
Definitions
- the invention is based on a spark plug with the features specified in the preamble of claim 1.
- a spark plug is from the EP 0 954 074 B1 known.
- Advanced gasoline engines require more space in the cylinder head for intake valves and exhaust valves, and this is one reason why spark plugs with smaller diameters than before are required today.
- Lighter spark plugs need a slimmer insulator. This in turn requires higher demands on the mechanical strength and electrical insulation, namely the dielectric strength, of the existing in the spark plug insulator, which usually consists of an alumina ceramic.
- the JP-A 63-190753 discloses an alumina ceramic insulator made by mixing 95% by weight of alumina powder having an average particle size of 0.1 ⁇ m to 0.5 ⁇ m with yttria, magnesia and lanthana, liquid phase pressing and sintering.
- the yttria, magnesium oxide and lanthanum oxide together make up 5% by weight of the mixture and serve as a sintering aid by leading to a liquid phase during sintering, the melting point of which is far below the melting point of the aluminum oxide.
- the liquid phase spreads at the boundaries of the alumina particles and is said to inhibit their growth in the sintering process so that the sintered insulator still has a very finely divided structure.
- the preserved by the sintering aids fine structure leads to the disclosure of JP-A 63-190753 extending the aluminum oxide particles extending along the boundaries of the sintering aids enriched paths over which electrical charges would move when voltage breakdown, and thus leads to an increase in the dielectric strength of the insulator.
- an adverse effect on the electrical breakdown strength the fine pores, which are particularly numerous in the finely structured sintered insulator and the number increases with increasing content of alumina in the insulator, because at the same time the proportion of sintering aids, by the formation of a liquid phase the pores could close, decreasing.
- This insulator is prepared by mixing alumina powder having an average particle size of not more than 1 .mu.m with 0.3 to 5 wt .-% of a sintering aid, pressed and sintered at a temperature between 1450 ° C and 1700 ° C in the liquid phase.
- the sintering aid is selected so as not to interfere with the growth of the alumina powder particles during sintering. The sintering process takes place until at least half of the aluminum oxide has grown to particles with a size of 20 microns or more.
- the sintering aid forms a liquid phase during sintering, which is to favor a small pore volume.
- the present invention aims to further improve the dielectric strength of the insulator in spark plugs both at room temperature and, in particular, at the high temperatures which occur when the gasoline engine is in operation.
- the spark plug according to the invention has an insulator containing 0.01 wt .-% to 1 wt .-% magnesium oxide, at most 0.3 wt .-% natural and / or caused by the manufacturing process impurities and the balance alumina and is formed by solid phase sintering , so that it is largely free of glass phases.
- the insulator of the new spark plug contains 0.03 wt% to 0.15 wt%.
- Magnesium oxide Even small additions of magnesium oxide reduce the crystal growth of the alumina during solid-phase sintering. From a content of 0.03 wt .-%, this effect becomes technically significant. At a content of more than 0.15% by weight of magnesium oxide, this effect is no longer significantly increased.
- the insulator contains only natural and / or process-related impurities.
- the invention dispenses with the addition of any sintering aids such as sodium oxide, yttrium oxide, lanthanum oxide, silica, barium oxide, boron oxide and the like, which at temperatures at which alumina can be sintered in solid phase, would form a liquid phase, from which after solidification Glass phase would.
- Any minimal glass phases which may be detectable in an insulator according to the invention, can therefore only from the natural and / or process-related impurities present in the alumina come. In this sense, the statement in claim 1 is understood that the insulator should be largely free of glass phases.
- the insulator of the spark plug according to the invention preferably contains more than 99.7% by weight of aluminum oxide. In this case, glass phases caused by the remaining impurities can no longer appreciably affect the electrical breakdown strength of the insulator.
- a density of at least 3.85 g cm -3 is preferred.
- a high density can be achieved if one starts from a very fine alumina powder, which preferably has an average particle size of less than 1 micron, if the insulator blanks sufficiently compacted before sintering, in particular by isostatic pressing, and if the sintering temperature and the sintering time is coordinated so that an insulator is obtained in which 90 wt .-% of the alumina having particle sizes of less than 5 microns, even better, with particle sizes of less than 3 microns.
- the temperature for the solid phase sintering is a temperature in the range of 1,600 ° C to 1,700 ° C, well below the melting temperature of alumina, which is above 2,000 °.
- FIG. 1 shows in a partially sectioned side view of the typical structure of a spark plug according to the invention, which has a center electrode 1 and in its extension a firing pin 2, which are at a distance behind each other in an insulator 4 according to the invention, namely in a longitudinal channel, in which they by a electrically conductive glass phase 3 are interconnected.
- the insulator 4 is inserted in a metallic body 5, in which it is fixed by crimping and electric diving.
- a ground electrode 6 is mounted, which is bent towards the center electrode 1 and this opposite to form a discharge gap with a defined distance.
- the insulator consists z. B. from 99.8 wt .-% alumina, about 0.1 wt .-% magnesium oxide and the balance of natural and / or process-related impurities. It is formed by solid-phase sintering and contains no glass-containing secondary phase that can be detected by X-ray analysis.
- the insulator according to the invention can be mounted in a known manner in the body 5 of the spark plug, so that existing manufacturing facilities and methods for mounting the insulator 4 as well as the center electrode 1 and the firing pin 2 can be used.
- the required ceramic-metal compound is effected by means of an electrically conductive composite glass.
- the electrically conductive glass mass 3 ensures the electrical connection between the center electrode 1 and the firing pin 2 and moreover has the task of introducing the center electrode 1 into the isolator 4 in a pressure-tight manner.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Spark Plugs (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
Description
Die Erfindung geht von einer Zündkerze mit den im Oberbegriff des Anspruchs 1 angegebenen Merkmalen aus. Eine solche Zündkerze ist aus der
Fortschrittliche Ottomotoren benötigen im Zylinderkopf mehr Platz für Einlassventile und Auslassventile und das ist eine Ursache dafür, dass heute Zündkerzen mit kleinerem Durchmesser als früher gefordert werden. Schlankere Zündkerzen benötigen einen schlankeren Isolator. Das wiederum bedingt höhere Anforderungen an die mechanische Festigkeit und die elektrische Isolationsfähigkeit, namentlich die elektrische Durchschlagsfestigkeit, des in der Zündkerze vorhandenen Isolators, welcher üblicherweise aus einer Aluminiumoxid-Keramik besteht.Advanced gasoline engines require more space in the cylinder head for intake valves and exhaust valves, and this is one reason why spark plugs with smaller diameters than before are required today. Lighter spark plugs need a slimmer insulator. This in turn requires higher demands on the mechanical strength and electrical insulation, namely the dielectric strength, of the existing in the spark plug insulator, which usually consists of an alumina ceramic.
Die
Um dieser Schwierigkeit zu entgehen offenbart die
Nach der Offenbarung der
Zum Vergleich wurde in der
Die vorliegende Erfindung bezweckt eine weitere Verbesserung der elektrischen Durchschlagsfestigkeit des Isolators in Zündkerzen sowohl bei Raumtemperatur als auch insbesondere bei den hohen Temperaturen, welche bei betriebswarmem Ottomotor auftreten.The present invention aims to further improve the dielectric strength of the insulator in spark plugs both at room temperature and, in particular, at the high temperatures which occur when the gasoline engine is in operation.
Diese Aufgabe wird gelöst durch eine Zündkerze mit den im Patentanspruch 1 angegebenen Merkmalen. Vorteilhafte Weiterbildungen der Erfindung sind Gegenstand der Unteransprüche.This object is achieved by a spark plug having the features specified in
Die erfindungsgemäße Zündkerze hat einen Isolator, der 0,01 Gew.-% bis 1 Gew.-% Magnesiumoxid, höchstens 0,3 Gew.-% natürliche und/oder durch den Herstellungsprozess bedingte Verunreinigungen und zum Rest Aluminiumoxid enthält und durch Festphasensintern gebildet ist, so dass er weitestgehend frei von Glasphasen ist.The spark plug according to the invention has an insulator containing 0.01 wt .-% to 1 wt .-% magnesium oxide, at most 0.3 wt .-% natural and / or caused by the manufacturing process impurities and the balance alumina and is formed by solid phase sintering , so that it is largely free of glass phases.
Überraschenderweise hat es sich gezeigt, dass Zündkerzen mit einem solchen Isolator gegenüber dem Stand der Technik wesentliche Vorteile haben:
- Die Spannungsfestigkeit des Isolators ist höher als im Stand der Technik. Bei Zimmertemperatur wurden Durchbruchsspannungen von 50 kV/mm und mehr gemessen. Das erlaubt die Herstellung von Zündkerzen, deren Isolator nur noch eine Wandstärke von 0,8 mm und damit eine Durchbruchsspannung von 40 kV und mehr hat.
- Die hohe Spannungsfestigkeit bleibt bei den Arbeitstemperaturen bis 900° C, welche bei betriebswarmem Ottomotor auftreten, erhalten.
- Die Isolatoren zeigen eine erhöhte mechanische Festigkeit, insbesondere eine erhöhte Biegefestigkeit und Biegewechselfestigkeit.
- Die Isolatoren haben gegenüber den Isolatoren in herkömmlichen Zündkerzen eine um bis zu 15 % höhere Wärmeleitfähigkeit. Das macht es möglich, den Isolatorfuß der Zündkerze, das ist der in den Zylinder des Ottomotors ragende Abschnitt des Isolators, zu verlängern, ohne den Wärmewert zu erhöhen. Der Vorteil einer solchen Isolatorfußverlängerung ist eine Erhöhung des elektrischen Nebenschlusswiderstandes der Zündkerze und dadurch eine deutliche Verbesserung der Zündfähigkeit bei Kaltstarts und bei Wiederholstarts.
- Der Isolator der erfindungsgemäßen Zündkerze zeigt eine höhere chemische Beständigkeit und trägt somit zu einer Erhöhung der Lebensdauer der Zündkerze bei.
- Die erhöhte Spannungsfestigkeit ermöglicht dünnere Isolatoren und damit schlankere Zündkerzen. Schlankere Zündkerzen erlauben engere Einschraubgewinde, z. B. Gewinde der Größe M12 und M10, und schaffen dadurch im Zylinderkopf mehr Platz für Einlassventile und Auslassventile des Motors.
- The dielectric strength of the insulator is higher than in the prior art. At room temperature, breakdown voltages of 50 kV / mm and more were measured. This allows the production of spark plugs whose insulator only has a wall thickness of 0.8 mm and thus a breakdown voltage of 40 kV and more.
- The high dielectric strength remains at working temperatures up to 900 ° C, which occur when the gasoline engine is warm.
- The insulators show increased mechanical strength, in particular increased flexural strength and fatigue strength.
- The insulators have compared to the insulators in conventional spark plugs by up to 15% higher thermal conductivity. This makes it possible to extend the insulator root of the spark plug, that is, the portion of the insulator projecting into the cylinder of the gasoline engine, without increasing the calorific value. The advantage of such an insulator foot extension is an increase in the electrical shunt resistance of the spark plug and thereby a significant improvement in ignitability during cold starts and at repeat starts.
- The insulator of the spark plug according to the invention shows a higher chemical resistance and thus contributes to an increase in the life of the spark plug.
- The increased dielectric strength allows thinner insulators and thus slimmer spark plugs. Slimmer spark plugs allow tighter screw-in thread, z. B. M12 and M10 threads, thereby providing more space in the cylinder head for intake and exhaust valves of the engine.
Vorzugsweise enthält der Isolator der neuen Zündkerze 0,03 Gew.-% bis 0,15 Gew.-%. Magnesiumoxid. Bereits geringe Zugaben von Magnesiumoxid vermindern das Kristallwachstum des Aluminiumoxids beim Festphasensintern. Ab einem Gehalt von 0,03 Gew.-% wird dieser Effekt technisch bedeutsam. Bei einem Gehalt von mehr als 0,15 Gew.-% Magnesiumoxid wird diese Wirkung nicht mehr signifikant erhöht.Preferably, the insulator of the new spark plug contains 0.03 wt% to 0.15 wt%. Magnesium oxide. Even small additions of magnesium oxide reduce the crystal growth of the alumina during solid-phase sintering. From a content of 0.03 wt .-%, this effect becomes technically significant. At a content of more than 0.15% by weight of magnesium oxide, this effect is no longer significantly increased.
Außer Aluminiumoxid und Magnesiumoxid enthält der Isolator nur noch natürliche und/oder prozessbedingte Verunreinigungen. Insbesondere verzichtet die Erfindung auf das Zusetzen irgendwelcher Sinterhilfsmittel wie Natriumoxid, Yttriumoxid, Lanthanoxid, Siliziumoxid, Bariumoxid, Boroxid und dergleichen, welche bei Temperaturen, bei welchen Aluminiumoxid in fester Phase gesintert werden kann, eine flüssige Phase bilden würden, aus welcher nach dem Erstarren eine Glasphase würde. Etwaige minimale Glasphasen, welche in einem erfindungsgemäßen Isolator nachweisbar sein mögen, können deshalb nur von den im Aluminiumoxid vorhandenen natürlichen und/oder prozessbedingten Verunreinigungen stammen. In diesem Sinne wird die Angabe im Patentanspruch 1 verstanden, dass der Isolator weitestgehend frei von Glasphasen sein soll.Except for aluminum oxide and magnesium oxide, the insulator contains only natural and / or process-related impurities. In particular, the invention dispenses with the addition of any sintering aids such as sodium oxide, yttrium oxide, lanthanum oxide, silica, barium oxide, boron oxide and the like, which at temperatures at which alumina can be sintered in solid phase, would form a liquid phase, from which after solidification Glass phase would. Any minimal glass phases, which may be detectable in an insulator according to the invention, can therefore only from the natural and / or process-related impurities present in the alumina come. In this sense, the statement in
Vorzugsweise enthält der Isolator der erfindungsgemäßen Zündkerze mehr als 99,7 Gew.-% Aluminiumoxid. In diesem Fall werden von den verbliebenen Verunreinigungen verursachte Glasphasen die elektrische Durchschlagsfestigkeit des Isolators nicht mehr spürbar beeinträchtigten können.The insulator of the spark plug according to the invention preferably contains more than 99.7% by weight of aluminum oxide. In this case, glass phases caused by the remaining impurities can no longer appreciably affect the electrical breakdown strength of the insulator.
Für den Isolator einer erfindungsgemäßen Zündkerze wird eine Dichte von mindestens 3,85g cm-3 bevorzugt. Eine solche hohe Dichte lässt sich erreichen, wenn man von einem sehr feinen Aluminiumoxidpulver ausgeht, welches vorzugsweise eine mittlere Teilchengröße von weniger als 1 µm aufweist, wenn man die Isolatorrohlinge vor dem Sintern hinreichend verdichtet, insbesondere durch isostatisches Pressen, und wenn man die Sintertemperatur und die Sinterdauer so aufeinander abstimmt, dass ein Isolator erhalten wird, in welchem 90 Gew.-% des Aluminiumoxids mit Teilchengrößen von kleiner als 5 µm, noch besser mit Teilchengrößen von kleiner als 3 µm vorliegen. Als Temperatur für das Festphasensintern eignet sich eine Temperatur im Bereich von 1.600° C bis 1.700° C, also deutlich unterhalb der Schmelztemperatur von Aluminiumoxid, welche oberhalb von 2.000° liegt.For the insulator of a spark plug according to the invention, a density of at least 3.85 g cm -3 is preferred. Such a high density can be achieved if one starts from a very fine alumina powder, which preferably has an average particle size of less than 1 micron, if the insulator blanks sufficiently compacted before sintering, in particular by isostatic pressing, and if the sintering temperature and the sintering time is coordinated so that an insulator is obtained in which 90 wt .-% of the alumina having particle sizes of less than 5 microns, even better, with particle sizes of less than 3 microns. The temperature for the solid phase sintering is a temperature in the range of 1,600 ° C to 1,700 ° C, well below the melting temperature of alumina, which is above 2,000 °.
Der Isolator besteht z. B. aus 99,8 Gew.-% Aluminiumoxid, ca. 0,1 Gew.-% Magnesiumoxid und zum Rest aus natürlichen und/oder prozessbedingten Verunreinigungen. Er ist durch Festphasensintern gebildet und enthält keine röntgenographisch nachweisbare glashaltige Sekundärphase.The insulator consists z. B. from 99.8 wt .-% alumina, about 0.1 wt .-% magnesium oxide and the balance of natural and / or process-related impurities. It is formed by solid-phase sintering and contains no glass-containing secondary phase that can be detected by X-ray analysis.
Der erfindungsgemäße Isolator lässt sich in bekannter Art und Weise in den Körper 5 der Zündkerze montieren, so dass vorhandene Fertigungseinrichtungen und Verfahren für die Montage des Isolators 4 ebenso wie der Mittelelektrode 1 und des Zündstiftes 2 verwendet werden können. Die erforderliche Keramik-Metallverbindung wird mittels eines elektrisch leitenden Kompositglases bewirkt. Die elektrisch leitende Glasmasse 3 stellt den elektrischen Anschluss zwischen der Mittelelektrode 1 und dem Zündstift 2 sicher und hat darüber hinaus die Aufgabe, die Mittelelektrode 1 druckdicht in den Isolator 4 einzubringen.The insulator according to the invention can be mounted in a known manner in the
- 1.1.
- Mittelelektrodecenter electrode
- 2.Second
- Zündstiftfiring pin
- 3.Third
- Glasphaseglass phase
- 4.4th
- Isolatorinsulator
- 5.5th
- Körperbody
- 6.6th
- Masseelektrodeground electrode
Claims (7)
- Spark plug for Otto-cycle engines having a metallic spark plug body (5), a central electrode (1), a ceramic insulator (4), which is arranged between the central electrode (1) and the body (5) and is based on aluminium oxide, and at least one ground electrode (6), characterized in that the insulator (4) contains 0.01 % by weight to 1 % by weight of magnesium oxide, a maximum of 0.3 % by weight of natural impurities and/or impurities resulting from the production process, the rest being aluminium oxide, and which is formed by solid-phase sintering so that it is very largely free from glass phases.
- The spark plug as defined in Claim 1, characterized in that the content of magnesium oxide is 0.03 % by weight to 0.15 % by weight.
- The spark plug as defined in Claim 1 or Claim 2, characterized in that the insulator (4) contains more than 99.7 % by weight of aluminium oxide.
- The spark plug as defined in any of the preceding claims, characterized in that the insulator (4) has a density of at least 3.85g cm-3.
- The spark plug as defined in any of Claims 1 to 3, characterized in that the insulator (4) has a density of 3.90g cm-3 +- 0.02g cm-3.
- The spark plug as defined in any of the preceding claims, characterized in that 90 % by weight of the aluminium oxide present in the insulator (4) have crystallite sizes of less than 5 µm (mean diameter).
- The spark plug as defined in Claim 6, characterized in that 90 % by weight of the aluminium oxide present in the insulator (4) have crystallite sizes of less than 3 µm.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006061907A DE102006061907A1 (en) | 2006-12-20 | 2006-12-20 | Spark plug with an insulator made of high-purity alumina ceramic |
PCT/EP2007/010974 WO2008074438A1 (en) | 2006-12-20 | 2007-12-13 | Spark plug and insulator composed of high-purity aluminium oxide ceramic |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2118973A1 EP2118973A1 (en) | 2009-11-18 |
EP2118973B1 true EP2118973B1 (en) | 2010-05-12 |
Family
ID=39147500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07856717A Active EP2118973B1 (en) | 2006-12-20 | 2007-12-13 | Spark plug and insulator composed of high-purity aluminium oxide ceramic |
Country Status (7)
Country | Link |
---|---|
US (1) | US20100007260A1 (en) |
EP (1) | EP2118973B1 (en) |
JP (1) | JP2010514114A (en) |
KR (1) | KR20090098972A (en) |
AT (1) | ATE467930T1 (en) |
DE (2) | DE102006061907A1 (en) |
WO (1) | WO2008074438A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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US11870221B2 (en) | 2021-09-30 | 2024-01-09 | Federal-Mogul Ignition Llc | Spark plug and methods of manufacturing same |
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JP2000007425A (en) * | 1998-06-29 | 2000-01-11 | Sumitomo Chem Co Ltd | High strength alumina substrate and its production |
JP2000095557A (en) * | 1998-07-23 | 2000-04-04 | Ngk Spark Plug Co Ltd | Alumina-base insulator for spark plug, its production and spark plug using the same |
JP4530380B2 (en) * | 1999-11-29 | 2010-08-25 | 日本特殊陶業株式会社 | Spark plug insulator and spark plug including the same |
DE10036008A1 (en) * | 2000-07-25 | 2002-02-07 | Bosch Gmbh Robert | Spark plug for an internal combustion engine and method for producing a spark plug |
JP4578025B2 (en) * | 2001-07-06 | 2010-11-10 | 日本特殊陶業株式会社 | Spark plug |
DE10132888A1 (en) * | 2001-07-06 | 2003-01-30 | Bosch Gmbh Robert | Alumina product, especially for use as a spark plug insulator |
US7598661B2 (en) * | 2006-06-23 | 2009-10-06 | Federal-Mogul World Wide, Inc | Spark plug |
-
2006
- 2006-12-20 DE DE102006061907A patent/DE102006061907A1/en not_active Withdrawn
-
2007
- 2007-12-13 EP EP07856717A patent/EP2118973B1/en active Active
- 2007-12-13 WO PCT/EP2007/010974 patent/WO2008074438A1/en active Application Filing
- 2007-12-13 DE DE502007003810T patent/DE502007003810D1/en active Active
- 2007-12-13 US US12/448,116 patent/US20100007260A1/en not_active Abandoned
- 2007-12-13 KR KR1020097013565A patent/KR20090098972A/en not_active Application Discontinuation
- 2007-12-13 JP JP2009541853A patent/JP2010514114A/en active Pending
- 2007-12-13 AT AT07856717T patent/ATE467930T1/en active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11870221B2 (en) | 2021-09-30 | 2024-01-09 | Federal-Mogul Ignition Llc | Spark plug and methods of manufacturing same |
Also Published As
Publication number | Publication date |
---|---|
WO2008074438A1 (en) | 2008-06-26 |
ATE467930T1 (en) | 2010-05-15 |
DE102006061907A1 (en) | 2008-06-26 |
EP2118973A1 (en) | 2009-11-18 |
US20100007260A1 (en) | 2010-01-14 |
JP2010514114A (en) | 2010-04-30 |
DE502007003810D1 (en) | 2010-06-24 |
KR20090098972A (en) | 2009-09-18 |
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