EP2093204B1 - Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels - Google Patents
Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels Download PDFInfo
- Publication number
- EP2093204B1 EP2093204B1 EP09001162A EP09001162A EP2093204B1 EP 2093204 B1 EP2093204 B1 EP 2093204B1 EP 09001162 A EP09001162 A EP 09001162A EP 09001162 A EP09001162 A EP 09001162A EP 2093204 B1 EP2093204 B1 EP 2093204B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixture
- smoke
- dicarboxylic acids
- acid
- fog
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 14
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000779 smoke Substances 0.000 claims abstract description 10
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims abstract description 6
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims abstract description 6
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 5
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 231100000252 nontoxic Toxicity 0.000 claims abstract description 3
- 230000003000 nontoxic effect Effects 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- -1 aromatic dicarboxylic acids Chemical class 0.000 claims description 8
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920001290 polyvinyl ester Polymers 0.000 claims description 3
- 229920001289 polyvinyl ether Polymers 0.000 claims description 3
- 239000011736 potassium bicarbonate Substances 0.000 claims description 3
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 3
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 abstract description 7
- 239000003638 chemical reducing agent Substances 0.000 abstract description 3
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000003595 mist Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000004156 Azodicarbonamide Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 2
- 235000019399 azodicarbonamide Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 241000475481 Nebula Species 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/006—Stabilisers (e.g. thermal stabilisers)
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/04—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being an inorganic nitrogen-oxygen salt
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/12—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
- C06B33/14—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds at least one being an inorganic nitrogen-oxygen salt
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D3/00—Generation of smoke or mist (chemical part)
Definitions
- the invention relates to a pyrotechnic mist set for generating a camouflage mist according to the preamble of patent claim 1.
- the mist set is a mixture of a light metal powder, preferably magnesium powder as a metallic reducing agent, potassium nitrate or a mixture of potassium nitrate and potassium perchlorate as the main oxidizing agent, at least one carbonate, for example calcium carbonate, potassium bicarbonate, sodium bicarbonate, potassium carbonate or sodium carbonate as a further auxiliary oxidant and nitrogen-releasing Substances as Abbrandmoderatoren and potassium chloride as sublimiertravelen and / or common salt as evaporable non-toxic, mist-forming substance.
- nitrogen-releasing substances preferably azodicarbonamide, oxamide or dicyandiamide are used.
- the mixture of said substances are preferably pressed into a sleeve, at the end of which a priming mixture is provided.
- the igniter mixture consists essentially of the same components as the fog set, but with the exception of Abbrandmoderatoren, but has a modified quantitative composition, as this is explained in detail in said patent.
- This known pyrotechnic fog set has proven excellent. However, it has been found that this mixture is susceptible to corrosion for very long periods of storage.
- the metal in the mist set reacts with water that is present in the mist set as residual moisture or originates from the ambient moisture, whereby hydrogen is formed.
- the liberated hydrogen reduces the nitrate in the mist set to gaseous ammonia.
- pyrotechnic fog sets containing as fog-forming substance dicarboxylic acids, eg. Sebacic acid, adipic acid, terephthalic acid, etc. These acids are present in the pyrotechnic fog composition at a level of from about 15 to 68 percent by weight, usually at a level of between about 30 and about 50 percent by weight; see. for example US-H227, US-H233, US 5,522,320 or US 5,154,782 , The dicarboxylic acids are usually mixed with potassium perchlorate etc. as the oxidizing agent.
- dicarboxylic acids eg. Sebacic acid, adipic acid, terephthalic acid, etc.
- the dicarboxylic acids are usually mixed with potassium perchlorate etc. as the oxidizing agent.
- the invention has for its object to improve the known fog set according to the preamble of claim 1 so that it is optimally functional even after a long storage time.
- aromatic dicarboxylic acids used are preferably phthalic acid or terephthalic acid or a mixture of these substances.
- the abovementioned aliphatic and / or aromatic dicarboxylic acids chemically stabilize the mixture of the pyrotechnic mist composition in such a way that no ammonia forms and the mixture of the mist set can be stored for a long time without impairing its functionality.
- Pyrotechnic fog sets of the type in question are usually pressed into a sleeve and covered with a primer mixture, which ignites the fog set when it is used pyrotechnic.
- a binder may be added to the mixture of the fog set selected from the group of halogen-free thermoplastics.
- the binder is, for example, a polyvinyl acetate, polyvinyl alcohol, polyvinyl butyral, polyvinyl ester or polyvinyl ether.
- the mixture for a pyrotechnic mist set according to the invention preferably contains proportionately: Magnesium powder (Mg) as a reducing agent 10-25% Potassium nitrate (KNO 3 ) 20-36% Potassium perchlorate (KClO 4 ) 0-15% wherein potassium nitrate and / or potassium perchlorate serve as the main oxidizing agent, at least one carbonate, such as calcium carbonate (CaCO 3 ), potassium bicarbonate (KHCO 3 ), sodium bicarbonate (NaHCO 3 ), potassium carbonate (K 2 CO 3 ) and / or sodium carbonate (Na 2 CO 3 ) in a proportion of 12-30% wherein said carbonates serve as further oxidizing agents, Potassium chloride (KCl) and / or Common salt (NaCl) as fog-forming substances 20-50% aliphatic and / or aromatic dicarboxylic acids as stabilizers 0.1-5%.
- Mg Magnesium powder
- azodicarbonamide, oxamide and / or dicyandiamide are preferably used in a proportion of 5-20%.
- a binder from the group of halogen-free thermoplastics may also be used, wherein the binder is preferably polyvinyl acetate, polyvinyl alcohol, polyvinyl butyral, polyvinyl esters or polyvinyl ethers.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Pest Control & Pesticides (AREA)
- Botany (AREA)
- Life Sciences & Earth Sciences (AREA)
- Plant Pathology (AREA)
- Combustion & Propulsion (AREA)
- Air Bags (AREA)
- Fireproofing Substances (AREA)
- Medicinal Preparation (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL09001162T PL2093204T3 (pl) | 2008-02-25 | 2009-01-28 | Pirotechniczny zestaw mgłotwórczy do wytwarzania maskującej mgły |
| SI200930046T SI2093204T1 (sl) | 2008-02-25 | 2009-01-28 | Komplet za pirotehniäśno meglo za proizvajanje meglene zavese |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008010942A DE102008010942B4 (de) | 2008-02-25 | 2008-02-25 | Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2093204A1 EP2093204A1 (de) | 2009-08-26 |
| EP2093204B1 true EP2093204B1 (de) | 2011-05-04 |
Family
ID=40740010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09001162A Active EP2093204B1 (de) | 2008-02-25 | 2009-01-28 | Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9034126B2 (es) |
| EP (1) | EP2093204B1 (es) |
| KR (1) | KR20090091671A (es) |
| AT (1) | ATE508102T1 (es) |
| CA (1) | CA2652175A1 (es) |
| DE (2) | DE102008010942B4 (es) |
| ES (1) | ES2362473T3 (es) |
| PL (1) | PL2093204T3 (es) |
| SI (1) | SI2093204T1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008010942B4 (de) | 2008-02-25 | 2012-09-27 | Rheinmetall Waffe Munition Gmbh | Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels |
| DE102009049003A1 (de) | 2009-10-09 | 2011-06-16 | Rheinmetall Waffe Munition Gmbh | Kunststoffgebundene pyrotechnische Mischung zur Erzeugung von Alkalimetallchlorid- bzw. Erdalkalimetallchlorid-Aerosolen als Tarnnebel |
| RU2460711C1 (ru) * | 2011-03-29 | 2012-09-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВПО "КНИТУ") | Пиротехнический состав цветного огня |
| FR3018277B1 (fr) * | 2014-03-07 | 2016-04-15 | Etienne Lacroix Tous Artifices S A | Composition fumigene incapacitante comprenant de la resine d'oleum capsicum microencapsulee |
| US10519074B2 (en) | 2016-09-20 | 2019-12-31 | Goodrich Corporation | Obscurant emission systems and methods |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USH233H (en) * | 1986-08-29 | 1987-03-03 | The United States Of America As Represented By The Secretary Of The Army | Smoke producing composition |
| USH227H (en) * | 1986-08-29 | 1987-03-03 | The United States Of America As Represented By The Secretary Of The Army | Colored smoke-producing composition |
| US4841865A (en) * | 1987-06-17 | 1989-06-27 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Smoke composition and method of making same |
| DE3728380C1 (de) | 1987-08-26 | 1988-11-24 | Nico Pyrotechnik | Pyrotechnische Mischung zur Erzeugung eines Tarnnebels und Anzuendmischung hierfuer |
| US5154782A (en) * | 1991-08-15 | 1992-10-13 | Thiokol Corporation | Obscuring and nontoxic smoke compositions |
| US5522320A (en) | 1993-07-12 | 1996-06-04 | Thiokol Corporation | Low-toxicity obscuring smoke formulation |
| JP2001002488A (ja) * | 1999-06-17 | 2001-01-09 | Daicel Chem Ind Ltd | プリテンショナー用ガス発生剤組成物 |
| DE10064285C1 (de) * | 2000-12-22 | 2002-10-17 | Nigu Chemie Gmbh | Gasgeneratortreibstoff-Zusammensetzung und deren Verwendung |
| US6558487B1 (en) * | 2001-07-24 | 2003-05-06 | The United States Of America As Represented By The Secretary Of The Army | Smoke generating compositions and methods of making the same |
| US7407598B2 (en) * | 2004-04-30 | 2008-08-05 | Goodrich Corporation | Flame suppressant aerosol generant |
| US7670446B2 (en) * | 2004-11-30 | 2010-03-02 | The United States Of America As Represented By The Secretary Of The Navy | Wet processing and loading of percussion primers based on metastable nanoenergetic composites |
| DE102008010942B4 (de) | 2008-02-25 | 2012-09-27 | Rheinmetall Waffe Munition Gmbh | Pyrotechnischer Nebelsatz zum Erzeugen eines Tarnnebels |
-
2008
- 2008-02-25 DE DE102008010942A patent/DE102008010942B4/de not_active Expired - Fee Related
-
2009
- 2009-01-28 SI SI200930046T patent/SI2093204T1/sl unknown
- 2009-01-28 ES ES09001162T patent/ES2362473T3/es active Active
- 2009-01-28 PL PL09001162T patent/PL2093204T3/pl unknown
- 2009-01-28 AT AT09001162T patent/ATE508102T1/de active
- 2009-01-28 DE DE502009000610T patent/DE502009000610D1/de active Active
- 2009-01-28 EP EP09001162A patent/EP2093204B1/de active Active
- 2009-02-02 CA CA002652175A patent/CA2652175A1/en not_active Abandoned
- 2009-02-18 US US12/378,672 patent/US9034126B2/en active Active
- 2009-02-25 KR KR1020090015592A patent/KR20090091671A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US9034126B2 (en) | 2015-05-19 |
| PL2093204T3 (pl) | 2011-07-29 |
| DE502009000610D1 (de) | 2011-06-16 |
| KR20090091671A (ko) | 2009-08-28 |
| SI2093204T1 (sl) | 2011-08-31 |
| DE102008010942B4 (de) | 2012-09-27 |
| EP2093204A1 (de) | 2009-08-26 |
| CA2652175A1 (en) | 2009-08-25 |
| ES2362473T3 (es) | 2011-07-06 |
| DE102008010942A1 (de) | 2009-08-27 |
| ATE508102T1 (de) | 2011-05-15 |
| US20090211672A1 (en) | 2009-08-27 |
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