EP1841529A1 - Catalyst for purifying exhaust gases and exhaust-gas purification controller using the same - Google Patents

Catalyst for purifying exhaust gases and exhaust-gas purification controller using the same

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Publication number
EP1841529A1
EP1841529A1 EP06701445A EP06701445A EP1841529A1 EP 1841529 A1 EP1841529 A1 EP 1841529A1 EP 06701445 A EP06701445 A EP 06701445A EP 06701445 A EP06701445 A EP 06701445A EP 1841529 A1 EP1841529 A1 EP 1841529A1
Authority
EP
European Patent Office
Prior art keywords
catalyst
exhaust
area
catalytic
respect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06701445A
Other languages
German (de)
English (en)
French (fr)
Inventor
Hiromasa c/o TOYOTA JIDOSHA KABUSHIKI KAISHA SUZUKI
Takahiko c/o TOYOTA JIDOSHA KABUSHIKI KAISHA FUJIWARA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Publication of EP1841529A1 publication Critical patent/EP1841529A1/en
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • F01N11/007—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring oxygen or air concentration downstream of the exhaust apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1025—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/40—Mixed oxides
    • B01D2255/407—Zr-Ce mixed oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F01N2370/02—Selection of materials for exhaust purification used in catalytic reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2510/00—Surface coverings
    • F01N2510/06—Surface coverings for exhaust purification, e.g. catalytic reaction
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/10—Carbon or carbon oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/12—Hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14—Nitrogen oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/40—Engine management systems

Definitions

  • the present invention relates to a catalyst for purifying exhaust gases , such as a three-way catalyst for purifying HC, CO and NO x in exhaust gases, and an exhaust-gas purification controller using the same .
  • a catalyst for purifying exhaust gases catalyst which is good in terms of the HC purifying performance in low-temperature regions , such as at the time of starting engine, and an exhaust-gas purification controller using the same, exhaust-gas purification controller which can control the combustion of internal combustion engine optimally and can accordingly demonstrate high NO x purifying performance .
  • the three-way catalyst comprises a porous support, such as alumina, and a noble metal, such as Pt, loaded on the porous support, and can purify CO, HC and NO x efficiently at around the theoretical air-fuel ratio .
  • Pt and Pd contribute to the oxidation purification of CO and HC mainly
  • Rh contributes to the reduction purification of NO x mainly
  • at the same Rh acts to inhibit the sintering of Pt or Pd. Therefore, it has been understood that , by using Pt or Pd with Rh combinedly, it is possible to suppress the drawback that the activity of Pt or Pd has been lowered by the decrease of active sites in Pt or Pd resulting from the sintering of Pt or Pd, and that it is accordingly- possible to improve the heat resistance of Pt or Pd.
  • the noble metal loaded on the three-way catalyst does not effect the catalytic reaction at temperatures lower than the activation temperature . Accordingly, there has been a drawback that the emission of HC is abundant, because the three-way catalyst does not function sufficiently in exhaust gases whose temperature falls in low-temperature region, such as at the time of starting engine . Moreover, the following fact is another cause of the drawback. That is , the air-fuel ratio has often become fuel-rich atmospheres so that the HC content is abundant when an engine is cold started.
  • Japanese ⁇ nexamined Patent Publication (KOKAI ) No . 8-332 , 350 proposes a catalyst in which Pd and Rh are loaded on the exhaust-gas flow upstream side and Pt and Rh are loaded on the downstream side with respect to Pd and Rh.
  • This catalyst is good in terms of the HC purifying performance in low-temperature region and the durability at high temperatures, because Pd is loaded in a higher concentration on the upstream side .
  • this catalyst demonstrates high NO x purifying performance, because the upstream-side reaction enhances the activity of the downstream-side Pt .
  • the NO x purifying performance of catalyst is lower when Pd and Rh coexist than when Pt and Rh coexist .
  • the alloying of Pd with Rh is more likely to develop than the alloying of Pt with Rh . Accordingly, there is a drawback that the alloying has lowered the characteristics of Rh. In addition, since Rh is extremely scarce as resource, it has been desired to make use of Rh efficiently and at the same time to enhance the durability of Rh by suppressing the degradation .
  • the three-way catalyst oxidizes HC and CO and reduces NO x to purify them in exhaust-gas atmospheres at around the stoichiometric point . Accordingly, it is essential to control the air-fuel ratio of engine so that the exhaust-gas atmospheres are at around the stoichiometric point . It is possible to carry out such a control by detecting a physical quantity, such as the oxygen concentration in exhaust gases emitted from engine, which relates to the catalyst-inlet gas atmosphere, and carrying out the feed back control of the air-fuel ratio (A/F) of engine depending on the physical quantity.
  • a physical quantity such as the oxygen concentration in exhaust gases emitted from engine
  • a first sensor for detecting a physical quantity, which relates to the three-way catalyst-inlet gas atmospheres, and a second sensor for detecting a physical quantity, which relates to the three-way catalyst-outlet gas atmospheres have been disposed in an exhaust system of engine conventionally.
  • the output difference between the first and second sensors has been judged to change the fuel inj ection volume .
  • the catalyst has a catalytic loading layer, which comprises : a coexistence area onwhich Rh and Pt are loadedover an areaextending from the exhaust-gas inlet-end surface of a support substrate to a location of 4/10 or less of the overall length of the support substrate; and an Rh area which is formed from the coexistence area to the exhaust-gas flow downstream side, and on which Rh is loaded uniformly in the exhaust-gas flow direction.
  • Rh suppresses the sintering of Pt in the coexistence area . Accordingly, the activity of Pt is inhibited from lowering. Moreover, even if Pt is alloyed with Rh in the coexistence area to degrade the characteristics of Rh, Rh, which is loaded on the Rh area, shows the characteristics fully, and additionally the length of the coexistence area is 4/10 or less of the overall length of the support substrate . Consequently, it is possible to make use of Rh efficiently.
  • the present invention has been developed in view of the aforementioned circumstances . It is therefore an obj ect of the present invention to control the air-fuel ratio of internal combustion engine optimally by inhibiting the unnecessary fluctuation of the sudden output change-over point of the second sensor, unnecessary fluctuation which results from H 2 generated in the Rh area of the novel catalyst .
  • a catalyst according to the present invention for purifying exhaust gases achieves the aforementioned obj ect, and comprises : a support substrate having an exhaust-gas flow passage; and a catalytic loading layer formed on a surface of the exhaust-gas flow passage, and composed of a porous oxide support and a catalytic ingredient, the catalytic loading layer comprising: an Rh area on which rhodium is loaded as the catalytic ingredient; and an oxidizing area which is formed on an exhaust-gas flow downstreamside with respect to the Rh area, andonwhich a catalytic ingredient exhibiting an oxidizing activity at least is loaded.
  • the catalytic loading layer can desirably further comprise a coexistence area, which is formed on an exhaust-gas flow upstream side with respect to the Rh area, and on which rhodium and platinum are loaded as the catalytic ingredient .
  • the support substrate canhave apredeterminedoverall length;
  • the coexistence area of the catalytic loading layer can have a length which is 4/10 times or less as short as the predetermined overall length of the support substrate; and the coexistence area can comprise rhodium and platinum in a proportion of Pt with respect to Rh falling in a range of 10 ⁇ Pt/Rh ⁇ 60 byweight ratio .
  • the porous support can preferably include ceria at least .
  • An exhaust-gas purification controller achieves the aforementioned object, and comprises : the present catalyst, and disposed in an exhaust channel of an internal combustion engine; a first sensor disposed on an exhaust-gas flow upstream side with respect to the present catalyst, and detecting a physical quantity relating to a catalyst-inlet gas atmosphere; a second sensor disposed on an exhaust-gas flow downstream side with respect to the present catalyst, and detecting a physical quantity relating to a catalyst-outlet gas atmosphere; and a control device for receiving detection signals , which are output from the first sensor and the second sensor, and controlling an air-fuel ratio of the internal combustion engine .
  • the present catalyst comprises the oxidizing area, which is disposed on a downstream side with respect to the Rh area, H 2 , which is generated in the Rh area, is oxidized in the oxidizing area . Accordingly, it is possible to inhibit the sudden output change-over point of the second sensor from fluctuating . Consequently, the present exhaust-gas purification controller can minimize the error in the output values from the second sensor remarkably. Therefore, not only the present exhaust-gas purification controller can have the present catalyst exhibit an improved NO x conversion, but also it can upgrade the accuracy of air-fuel control greatly . Moreover, the present exhaust-gas purification controller exhibits enhanced accuracy for grasping the degradation degree of catalyst .
  • the present catalyst comprises the coexistence area with Pt and Rh loaded, coexistence area which is formed on an exhaust-gas flow upstream side being more likely to become high temperatures than an exhaust-gas flow downstream side, Rh inhibits the sintering of Pt in the coexistence area so that the activity of Pt is prevented from lowering. Moreover, even if Pt is alloyed with Rh to lower the characteristics of Rh, Rh, which is loaded on the Rh area, shows the characteristics fully.
  • Fig .1 is a perspective diagram for illustrating a catalyst of Example No . 1 according to the present invention .
  • Fig . 2 is a cross-sectional diagram for illustrating the catalyst of Example No . 1 according to the present invention .
  • Fig .3 is a block diagram for illustrating an exhaust-gas purification controller of Example No . 1 according to the present invention .
  • Fig .4 is a flowchart for illustrating how the exhaust-gas purification controller of Example No . 1 according to the present invention carries out controlling the combustion of engine .
  • Fig.5 is a time chart for illustrating the relationships between the A/F value and the output value from a second sensor when the air-fuel ratio is switched from fuel-lean atmosphere to fuel-rich atmosphere .
  • the present catalyst comprises the oxidizing area which is further formed on a downstream side with respect to the Rh area, in addition to the Rh area . Therefore, even if fuel-rich-atmosphere exhaust gases flow into the present catalyst to facilitate the steam reforming reaction in the Rh area so that H 2 is generated, the resulting H 2 is oxidized in the oxidizing area, and accordingly hardly contacts with the second sensor . As a result, not only it is possible to inhibit the sudden output change-over point of the second sensor from fluctuating, but also it is possible to improve the detection accuracy of the second sensor .
  • the NO x conversion of the present catalyst upgrades as well as the air-fuel control accuracy of the present exhaust-gas purification controller enhances .
  • the accuracy of the present exhaust-gas purification controller for grasping the degradation degree of catalyst improves as well .
  • the Rh area of the catalytic loading layer can preferably comprise Rh in a loading amount of from 0.05 to 5 g with respect to 1-L volume of the support substrate .
  • the loading amount of Rh is less than the lower limit of the range, the resulting Rh area exhibits insufficient purifying performance .
  • the loading amount of Rh is more than the upper limit of the range, the effect of Rh addition has saturated so that it is impossible to utilize Rh effectively.
  • the loading density of Rh in the Rh region can differ from the loading density of Rh in the coexistence area . However, from the viewpoint of production, it is convenient to control the loading density of Rh in the Rh region identical with the loading density of Rh in the coexistence area .
  • the forming range of the oxidizing area is not limited in particular, as far as the oxidizing area is formed on an exhaust-gas flow downstream side with respect to the Rh area . However, it is desirable to form the oxidizing area over the entire exhaust-gas flow downstream side of the catalytic loading layer with respect to the Rh area .
  • a catalytic ingredient which exhibits an oxidizing activity at least, is loaded.
  • the other noble metals, or transition metals other than noble metals can be loaded on the oxidizing area in such a loading amount that does not impair the oxidizing activity of the catalytic ingredient .
  • the oxidizing area of the catalytic loading layer can preferably comprise the catalytic ingredient in a loading amount of from 0.05 to 100 g, further preferably from 1 to 40 g with respect to 1-L volume of the support substrate .
  • the present catalyst can desirably further comprise a coexistence area, which is disposed on an exhaust-gas flow upstream side with respect to the Rh area and on which Rh and Pt are loaded.
  • a coexistence area which is disposed on an exhaust-gas flow upstream side with respect to the Rh area and on which Rh and Pt are loaded.
  • low-temperature exhaust gases which are produced when starting an engine, first pass the coexistence area after they collide with the exhaust-gas inlet-end surface of the present catalyst in such a state that they have not yet turned into laminar flow . Accordingly, the heat of the exhaust gases increases the temperature of the present catalyst quickly so that Pt with good ignitability, which is loaded on the coexistence area, reaches the activation temperature in a short period of time relatively. Then, the reaction heat further increases the temperature of the present catalyst so that the temperature increment is facilitated as well on the exhaust-gas flow downstream side of the present catalyst . Consequently, the present catalyst demonstrates improved purifying performance for HC and NO x .
  • the coexistence area can preferably have a length, which is 4/10 times or less , further preferably from 0/10 to 4/10 times furthermore preferably from 2/10 to 4 /10 times, as short as the overall length of the support substrate .
  • a length which is 4/10 times or less , further preferably from 0/10 to 4/10 times furthermore preferably from 2/10 to 4 /10 times, as short as the overall length of the support substrate .
  • the coexistence area is formed to have a length, which is more than 4/10 times as short as the overall length of the support substrate, the proportion of Rh alloying with Pt increases so that the resulting catalyst has shown insufficient purifying performance for HC and NO x .
  • the coexistence area can be formed continuously from the exhaust-gas inlet-end surface of thepresent catalyst .
  • catalytic ingredients such as noble metals , which are loaded in a range of 5 mm from the exhaust-gas inlet-end surface of catalyst, contribute to catalytic reactions in lesser degrees relatively. Consequently, it is advisable to dispose the coexistence area by 5 mm or more on an exhaust-gas flow downstream side with respect to the exhaust-gas inlet-end surface of the present catalyst .
  • the oxidizing area when the coexistence area is formed to have a length, which is 4/10 times or less as short as the overall length of the support substrate, can desirably have a length, which is 1/5 time or less, further desirably from 1/10 to 1/5 time, as short as the overall length the support substrate : and the balance can desirably be assigned to the Rh area .
  • the Rh area has a length, which is more than 4/10 times as short as the overall length of the support substrate, the resulting catalyst has showed lowered purifying performance for NO x . Since it is sufficient for the oxidizing area to have a function of oxidizing H 2 , it is satisfactory that the oxidizing area has a length, which is 1/5 time or less as short as the overall of length of the support substrate .
  • the coexistence area can preferably comprise Rh and Pt in a proportion of Pt with respect to Rh falling in a range of
  • the proportion of Pt with respect to Rh can fall in a range of 15 ⁇ Pt/Rh ⁇ 50 by weight ratio .
  • the proportion of Pt with respect to Rh is smaller than the lower limit of the preferable range, the resulting catalyst exhibits lowered ignitability so that it has shown degraded HC purifying performance at low temperatures .
  • the proportion of Pt with respect to Rh is larger than the upper limit of the preferable range, the sintering of Pt is likely to occur at high temperatures .
  • the coexistence area can preferably comprise Pt in a loading amount of from 0.5 to 40 g, further preferably from 5 to 40 g, furthermore preferably from 10 to 40 g, with respect to 1-L volume of the support substrate .
  • the loading amount of Pt is less than the lower limit of the preferable range, the resulting catalyst is poor in terms of the ignitability at low temperatures so that it has shown insufficient purifying performance for HC and NO x .
  • the loading amount of Pt is more than the upper limit of the preferable range, not only the effect of Pt addition has saturated but also the sintering of Pt is likely to occur at high temperatures .
  • the coexistence area can comprise Rh in such a loading amount that can inhibit loaded Pt from sintering .
  • the coexistence area can preferably comprise Rh in a loading amount of from 0.05 to 5 g, further preferably from 0.1 to 5 g, with respect to 1-L volume of the support substrate .
  • the loading amount of Rh is less than the lower limit of the preferable range, the sintering of Pt is likely to occur at high temperatures .
  • the other noblemetals orbasemetals can be loaded on the coexistence area in such a loading amount that does not impair the advantages resulting from the coexistence area .
  • the present catalyst can be formed as pellet shapes , honeycomb shapes, and foam shapes .
  • the support substrate can be made of heat-resistant ceramic, such as cordierite, or metallic foil .
  • the catalytic loading layer which is composed of the porous oxide support and catalytic ingredient, is formed.
  • the porous oxide support it is possible to use a single species or a plurality of species which are selected from the group consisting of AI2O3, SiC>2, Zr ⁇ 2, Ce ⁇ 2 and TiO 2 . Moreover, it is possible to use composite oxides which are composed of a plurality of the simple oxides . Among such composite oxides, it is preferable use composite oxides including Ce ⁇ 2 . That is, it is possible to inhibit the exhaust-gas atmospheres from fluctuating by means of the oxygen absorbing-and-releasing ability of CeO 2 .
  • the porous oxide support is composed of a Ce ⁇ 2 ⁇ Zr ⁇ 2 composite oxide
  • the porous oxide support made of Ce ⁇ 2 ⁇ Zr ⁇ 2 and with Pt loaded exhibits more upgraded oxygen absorbing-and-releasing ability than CeU 2 with Pt loaded does .
  • the porous oxide support made of CeO 2 -Zr ⁇ 2 and with Rh loaded shows more enhanced hydrogen generating ability as well as NO x purifying performance than Ce ⁇ 2 with Rh loaded does .
  • the porous oxide support of the catalytic loading layer can preferably have a uniform composition over the entire length of the support substrate in view of production process .
  • the porous oxide support can be composed of AI 2 O 3 in the coexistence area and oxidizing area; and can be composed of a Ce ⁇ 2-ZrC>2 composite oxide in the Rh area . If such is the case, since the characteristics of catalytic ingredients furthermore enhance in all of the three areas , the present catalyst shows much better purifying performance .
  • the present exhaust-gas purification controller comprises the present catalyst, a first sensor, a second sensor, and a control device .
  • the present catalyst is disposed in an exhaust channel of an internal combustion engine .
  • the first sensor is disposed on an exhaust-gas flow upstream side with respect to the catalyst , and detects a physical quantity relating to a catalyst-inlet gas atmosphere .
  • the second sensor is disposed on an exhaust-gas flow downstream side with respect to the catalyst, and detects a physical quantity relating to a catalyst-outlet gas atmosphere .
  • the control device is for receiving detection signals, which are output from the first sensor and the second sensor, and controlling an air-fuel ratio of the internal combustion engine .
  • the first and second sensors it is possible to use A/F sensors, oxygen sensors , and the like, which have been used conventionally.
  • the control device it is possible to use engine control units (hereinafter abbreviated to as ⁇ ⁇ CU") .
  • the sudden output change-over point might be fluctuatedby H 2 .
  • the control subj ects, which the control device carries out, can be the same as those of the conventional ones .
  • the present catalyst it is possible to prevent the sudden output change-over point of the second sensor from fluctuating in fuel-rich-atmosphere exhaust gases, which are produced by combusting fuel-rich air-fuel mixtures . As a result, it is possible to carry out the air-fuel ratio control with high accuracy.
  • Fig . 1 and Fig . 2 illustrate a catalyst according to Example No .1 of the present invention for purifying exhaust gases .
  • the catalyst comprises a cylinder-shaped honeycomb substrate 1, and a catalytic loading layer 2.
  • the honeycomb substrate 1 comprises a large number of square-shaped cells, and has an overall length of 130 mm (Li) .
  • the catalytic loading layer 1 is formed on the surface of the cells .
  • a coexistence area 20 is formed by a length of 20 mm (L 2 ) from the exhaust-gas inlet-end surface of the catalyst to an exhaust-gas flow downstream side; an Rh area 21 is formed by a length of 100 mm from the coexistence area 20 to an exhaust-gas flow downstream side; and an oxidizing area 22 is formed by a length of 10 mm (L 3 ) from the Rh area 21 to the exhaust-gas outlet-end surface of the catalyst .
  • a CeO 2 -ZrO 2 solid solution powder 120 parts by weight of a CeO 2 -ZrO 2 solid solution powder, 80 parts by weight of an activated alumina powder, and an alumina binder were mixed with a predetermined amount of water .
  • the alumina binder was composed of alumina hydrate in an amount of 3 parts by weight, and 40% aluminum nitrate aqueous solution in an amount of 44 parts by weight . The resulting mixture was milled to prepare a slurry.
  • honeycomb substrate 1 was made of cordierite; and had a volume of 1.1 L, cells in a quantity of 600 cells/inch 2 , an average cellular wall thickness of 75 ⁇ m, an overall length of 130 mm, and a diameter of 103 mm. Thereafter, the excessive slurry was blown off with air . After drying the honeycomb substrate 1 at 120 0 C, the honeycomb substrate 1 was calcined at 650 0 C for 3 hours . Thus , a coating layer was formed on the entire cellular surfaces of the honeycomb substrate 1. Note that the coating layer was formed in an amount of 210 g with respect to 1-L volume of the honeycomb substrate 1.
  • the entire coating layer was immersed into an RhCl 3 aqueous solution having a predetermined concentration (that is , the honeycomb substrate 1 was immersed into it over the entire overall length) to load Rh by means of adsorption .
  • the honeycomb substrate 1 was calcined at 500 °C for 1 hour .
  • Rh was loaded on the coating layer .
  • Rh was loaded in an amount of 0.4 g with respect to 1-L volume of the honeycomb substrate 1.
  • the coating layer was impregnated with a Pt (NO2) 2 (NH 3 ) 2 aqueous solution having a predetermined concentration by a length of 20 mm from the exhaust-gas inlet-end surface of the honeycomb substrate 1 to an exhaust-gas flow downstream side thereof . After drying the honeycomb substrate
  • the honeycomb substrate 1 was calcined at 650 °C for 3 hours to load Pt on the coating layer .
  • the coexistence area 20 was formed. Note that Pt was loaded on the coexistence area 20 in an amount of 10 g with respect to 1-L volume of the honeycomb substrate 1.
  • the coating layer was impregnated with a Pt (NO 2 ) 2 (NH 3 ) 2 aqueous solution having a predetermined concentration by a length of 10 mm from the exhaust-gas outlet-end surface of the honeycomb substrate 1 to an exhaust-gas flow upstream side thereof .
  • the honeycomb substrate 1 was calcined at 650 °C for 3 hours to load Pt on the coating layer .
  • the oxidizing area 22 was formed. Note that Pt was loaded on the oxidizing area 22 in an amount of 5 g with respect to 1-L volume of the honeycomb substrate 1.
  • Example No .1 prepared as described above was installed to an exhaust system of an automobile immediately below the 2.4-L displacement engine to make an exhaust-gas purification controller illustrated in Fig . 3.
  • the exhaust-gas purification controller comprises an engine 3, a catalytic converter 30 , a catalyst 31 , a first sensor 32 , a second sensor 33 , and a control device 4.
  • the catalytic converter 30 is placed in the exhaust pipe of the engine 3.
  • the catalyst 31 is installed within the catalytic converter 30.
  • the first sensor 32 comprises an A/F sensor, which is placed between the engine 3 and the catalytic converter 30 and detects the A/F equivalent value of inlet exhaust gases to the catalyst 31.
  • the second sensor 33 comprises an oxygen sensor, which is placed on an exhaust-gas flow downstream side with respect to the catalytic converter 30 and detects an oxygen gas concentration in outlet exhaust gases from the catalyst 31.
  • the controller device 4 controls the air-fuel ratio of the engine 3 based on the input values .
  • Fig . 4 illustrates how the control device 4 carries out the control subj ects .
  • the first sensor 32 first detects the catalyst-inlet gas atmosphere at step 100.
  • the control device 4 j udges the deviation of the detected catalyst-inlet gas atmosphere from the stoichiometric A/F ratio .
  • control device 4 j When the control device 4 j udges that the A/F ratio falls in a range of 14.6 ⁇ 0.05, the stoichiometric atmosphere, the control device 4 does not do anything and returns the programmed control process to step 100. On the other hand, when the control device 4 judges that the A/F ratio deviates from 14.6, the theoretical stoichiometric value, by more than ⁇ 0.05 , the control device 4 j udges whether the catalyst-inlet gas atmosphere derives from fuel-lean atmosphere or not at step 102.
  • control device 4 judges that the catalyst-inlet gas atmosphere derives from fuel-lean atmosphere, the control device 4 controls the fuel inj ection volume so as to make the A/F ratio fall in a range of 14.6 ⁇ 0.05 at step 103. Then, the control device 4 returns the programmed control process to step 100. On the contrary, when the catalyst-inlet gas atmosphere does not derive from fuel-lean atmosphere, the control device 4 j udges that the catalyst-inlet gas atmosphere derives from fuel-rich atmosphere . Then, the control device 4 has the second sensor 33 detect the oxygen concentration of the catalyst-outlet gas atmosphere at step 104.
  • the control device 4 judges whether the catalyst-outlet gas atmosphere derives from fuel-rich atmosphere or not .
  • the control device 4 controls the fuel inj ection volume so as to make the A/F ratio fall in a range of 14.6 ⁇ 0.05 at step 103. Thereafter, the control device 4 returns the programmed control process to step 100.
  • the control device 4 refers to records, such as the accumulated service time and thermal history of the catalyst 31 , to judge whether the catalyst 31 has been degraded or not based on a map, which is stored separately, at step 106.
  • control device 4 When the control device 4 does not judge that the catalyst 31 has been degraded, the control device 4 returns the programmed control process to step 104 to have the second sensor 33 re-detect the oxygen concentration of the catalyst-outlet gas atmosphere . Onthe otherhand, when the control device 4 j udges that the catalyst 31 has been degraded, the control device 4 displays a replacement symbol to call the driver' s attention to the replacement of the catalyst 31. Moreover, at step 103 , the control device 4 controls the fuel inj ection volume so as to make the A/F ratio fall in a range of 14.6 ⁇ 0.05. Thereafter, the control device 4 returns the programmed control process to step 100.
  • Example No . 1 Using the above-described exhaust-gas purification controller of Example No . 1 , the catalyst of Example No . 1 was first subj ected to a degradation treatment at an inlet gas temperature of 950 °C (or a catalyst bed temperature of 1, 000 °C) for 100 hours . After completing the degradation treatment, the engine 3 was operated under the following conditions : a revolving speed of 1 , 600 rpm; and an exhaust-gas flow rate of 10 g/second. Meanwhile, the output values of the second sensor 33 were measured with time after the target value of the engine 3 ' s A/F ratio, which the control device 4 j udged according to the detected value of the first sensor 32 , was switched from 14.8 to 14.4.
  • Fig .5 illustrates the result of measuring the output values of the second sensor 33 with time .
  • Example No . 2 a catalyst of Example No . 2 was prepared in the same manner as set forth in Example No . 1. Moreover, the output values of the second sensor 33 and the NO x emission under a steady driving condition were measured in the same manner as described in Example No . 1.
  • Fig . 5 illustrates the result of measuring the second sensor 33 ' s output values, and Table 1 below summarizes the result of measuring the NO x emission .
  • Ahoneycomb substrate 1 was prepared . Note that a coating layer was formed on the honeycomb substrate 1 in the same manner as Example No . 1. Then, the entire coating layer was immersed into an RhCl 3 aqueous solution having a predetermined concentration (that is , the honeycomb substrate 1 was immersed into it over the entire overall length) to load Rh by means of adsorption . After drying the honeycomb substrate 1 at 120 0 C, the honeycomb substrate 1 was calcined at 500 °C for 1 hour . Thus, Rh was loaded on the coating layer . Note that Rh was loaded in an amount of 0.4 g with respect to 1-L volume of the honeycomb substrate 1.
  • the coating layer was impregnated with a Pt (NO2 ) 2 (NH 3 ) 2 aqueous solution having a predetermined concentration by the overall length of the honeycomb substrate 1.
  • a Pt (NO2 ) 2 (NH 3 ) 2 aqueous solution having a predetermined concentration by the overall length of the honeycomb substrate 1.
  • the honeycomb substrate 1 was calgined at 650 0 C for 3 hours to load Pt on the coating layer .
  • Pt was loaded on the coating layer in an amount of 1.5 g with respect to 1-L volume of the honeycomb substrate 1.
  • Example Nos . 1 and 2 the second sensor 33 exhibited the sudden output change-over point, which shifted by lesser shift magnitude than that the second sensor 33 did in the Conventional Example . Additionally, the sudden output change-over point shifted more on a longer elapsed-time side . Therefore, in Example Nos . 1 and 2, it was possible to secure an ample time until the control device 4 judged that catalyst-outlet exhaust-gas atmosphere derived from a fuel-rich air-fuel mixture . As a result, Example Nos .1 and 2 could upgrade the NO x purifying performance . Moreover, from Table 1 above, it is appreciated that the Comparative Example exhibited the poorer NO x emission than Example Nos . 1 and 2 did . It is apparent that the disadvantage resulted fromthe fact that the sudden output change-over point of the second sensor 33 shifted more on a shorter elapsed-time side in the Comparative Example .
  • the present catalyst, and the present exhaust-gas purification controller using the same can be applied to the purification of exhaust gases emitted form internal combustion engines , in particular to the purification of HC in low-temperature regions , such as at the time of starting engine, and the purification of NO x .

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  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
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  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Catalysts (AREA)
EP06701445A 2005-01-31 2006-01-19 Catalyst for purifying exhaust gases and exhaust-gas purification controller using the same Withdrawn EP1841529A1 (en)

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JP2005024285A JP4506487B2 (ja) 2005-01-31 2005-01-31 排ガス浄化用触媒及びそれを用いた排ガス浄化制御装置
PCT/JP2006/301177 WO2006080369A1 (en) 2005-01-31 2006-01-19 Catalyst for purifying exhaust gases and exhaust-gas purification controller using the same

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US7870724B2 (en) 2004-11-09 2011-01-18 Ford Global Technologies, Llc Lean NOx trap with PGM zoned axially
JP4760625B2 (ja) 2006-09-06 2011-08-31 マツダ株式会社 排ガス浄化用触媒装置
US7718150B2 (en) 2007-04-17 2010-05-18 Ford Global Technologies, Llc Reverse platinum group metal zoned lean NOx trap system and method of use
JP4978781B2 (ja) 2007-05-18 2012-07-18 トヨタ自動車株式会社 Ｓ吸蔵触媒及び排ガス浄化装置
JP5096200B2 (ja) * 2008-03-19 2012-12-12 株式会社キャタラー 排ガス浄化用触媒
DE102011100017A1 (de) * 2011-04-29 2012-10-31 Süd-Chemie AG Verfahren zur Herstellung gezonter Katalysatoren
US11154842B2 (en) 2016-03-09 2021-10-26 Cataler Corporation Exhaust gas purification underfloor catalyst and catalyst system
EP3702032A4 (en) * 2017-10-27 2021-06-02 Cataler Corporation EXHAUST GAS PURGE DEVICE USING A BASE METAL MATERIAL AND METHOD OF MANUFACTURING THE EXHAUST GAS PURGE DEVICE
JP7245613B2 (ja) * 2018-07-05 2023-03-24 株式会社キャタラー 排ガス浄化触媒装置

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JPS62125856A (ja) * 1985-11-27 1987-06-08 Toyota Motor Corp 排気ガス浄化用モノリス触媒
JPS6384635A (ja) * 1986-09-26 1988-04-15 Nissan Motor Co Ltd 排気ガス浄化用触媒
AU604083B2 (en) * 1987-01-20 1990-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalyst for purifying exhaust gas and method for production thereof
JP3327054B2 (ja) * 1995-06-07 2002-09-24 トヨタ自動車株式会社 排ガス浄化用触媒
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KR20070095988A (ko) 2007-10-01
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