EP1738662B1 - Gant avec fonctions de protection du type ABC - Google Patents

Gant avec fonctions de protection du type ABC Download PDF

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Publication number
EP1738662B1
EP1738662B1 EP06012024A EP06012024A EP1738662B1 EP 1738662 B1 EP1738662 B1 EP 1738662B1 EP 06012024 A EP06012024 A EP 06012024A EP 06012024 A EP06012024 A EP 06012024A EP 1738662 B1 EP1738662 B1 EP 1738662B1
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EP
European Patent Office
Prior art keywords
glove
section
activated carbon
range
fingers
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EP06012024A
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German (de)
English (en)
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EP1738662A1 (fr
Inventor
Marianne Hofmann
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Bluecher GmbH
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Bluecher GmbH
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    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/015—Protective gloves
    • A41D19/01576—Protective gloves made of a patchwork of different materials

Definitions

  • the present invention relates to a glove having a protective function against toxins and / or pollutants, the glove having two interconnected glove sections constructed of different materials.
  • non-breathable rubber gloves were used Although they are impermeable to chemical toxins, but have the serious disadvantage that they have low comfort due to the virtually nonexistent breathability, which is particularly disadvantageous for longer periods of use or under heavy physical stress.
  • breathable protective gloves are known from the prior art, as for example in the going back to the applicant itself US 6 301 715 B1 or belonging to the same patent family WO 01/82728 A1 and DE 201 21 518 U1 are described.
  • the glove described there is particularly suitable for pilots of fighter aircraft, since it has an increased tactility with simultaneous protective effect against chemical toxins.
  • This glove has an active carbon-based adsorption layer formed over the entire glove surface for adsorbing chemical poisonous and warfare agents. While this glove has high breathability, the glove is not optimized for protection against extremely high levels of noxious or toxic contaminants, such as those found when toxic substances are in liquid form. Thus, in this glove is not always guaranteed that under extreme situations - for example, when in contact with liquid contaminants highly contaminated objects - the passage of harmful or toxic substances can be completely prevented.
  • a breathable protective glove having - comparable to the aforementioned documents - an adsorbing layer extending over the entire glove surface, for example based on activated carbon, but the protective glove has an additional barrier layer which extends equally over the entire glove surface.
  • the intended barrier layer is arranged between an adsorption layer and an outer carrier layer based on a textile or leather material.
  • DE202004001939 U1 relates to a glove having an inner palm of a liquid-tight, breathable material and a Hanschuhschreiben, the Hanschuhschreiben is formed at least in a layer of a liquid-tight, breathable material. It is therefore the object of the present invention to provide a glove which at least partially avoids or at least mitigates the previously described disadvantages of the prior art.
  • a glove is to be provided, which has a good breathability with simultaneously high protective function against poison or pollutants.
  • this is to be achieved that concentrated poison or pollutants, such as those present in highly concentrated liquids, aerosols and the like, can not come into contact with the hand or the skin of the hand. This is to be avoided in particular that such toxic substances can come into contact with the palm or the gripping surface of the hand when touching or when gripping and / or holding, for example, contaminated objects or surfaces in contact,
  • the present invention proposes a glove for covering a palm, a palm and fingers, in particular a breathable protective glove (z, B, military protective glove, ABC protective glove or work glove with ABC protection function) with protective function against poison and / or pollutants, according to claim 1 before.
  • a breathable protective glove z, B, military protective glove, ABC protective glove or work glove with ABC protection function
  • the subject matter of the present invention is thus a glove which covers at least one inside of the hand, one outside of the hand and the fingers of a wearer, for example a soldier, industrial worker, decontamination specialist, etc., the glove having a protective function against toxic and / or harmful substances.
  • the glove of the invention has two interconnected glove sections, which are constructed of different materials.
  • a special feature of the glove according to the invention is the fact that the first glove portion is formed of a polymer-based material that is at least substantially impermeable to chemical poison or warfare agents or their passage at least delayed and at least substantially gas and water impermeable and in the generally also impermeable to water vapor. Due to this special embodiment of the first glove section, which preferably the gripping surface of the hand,
  • the first glove portion is capable of effectively preventing highly concentrated, such as liquid poison, from the hand. This results in an effective protection for the wearer of the glove according to the invention, even if the wearer gets in direct contact with highly concentrated or liquid pollutant sources.
  • the glove according to the invention is characterized in that the second glove portion is formed from a textile surface filter material which prevents the passage of poison or pollutants or at least delayed and at least substantially gas and water vapor permeable.
  • the invention ensures that - due to the gas and water vapor permeable, d. H. breathable training of the second glove section - the glove according to the invention also has a total high comfort, so that it is also suitable for prolonged use, for example, under physical stress or at high temperatures.
  • the present invention relates to a glove with protective function against poison and / or pollutants, wherein the glove comprises two interconnected glove sections, wherein the glove sections are each formed by at least one piece of material, wherein the pieces of material of the two glove sections each consist of different materials
  • the first glove portion is formed from at least a first piece of material, wherein the first piece of material of at least one at least substantially gas impermeable and impermeable to water and impermeable to water, the passage of toxic and / or pollutants at least retarding or against chemical poison and / or warfare agents, at least substantially impermeable polymeric material.
  • the second glove section it is formed from at least one second piece of material, wherein the second piece of material consists of at least one at least substantially gas-permeable and water vapor permeable, ie breathable textile surface filter material, wherein the textile Surface filter material is designed such that it prevents the passage of toxins and / or pollutants or at least delayed.
  • the glove has an excellent protective function against highly concentrated pollutants, in particular in liquid form, while the second glove section - in addition to a good protective effect against toxins or pollutants - a high breathability and thus ensures a high level of comfort of the glove according to the invention.
  • the peculiarity of the glove according to the present invention must therefore be seen in particular in the fact that the glove according to the present invention, two differently shaped glove sections with each specially adapted to the requirement profile or tailored protection properties - very high protection potential with respect to the gripping or Hand surface on the one hand and high breathability with respect to the less vulnerable back of the hand on the other - -, so that overall an optimal protection performance on the one hand and a high wearing comfort, in particular an excellent breathability, on the other hand is achieved.
  • the terms “inside of the hand” and “inside of the fingers” are understood to mean the regions of the hand or fingers which to a certain extent form the gripping surface of the hand, while the terms “back of the hand” and “back of the fingers” the areas of the hand are understood, which lie opposite the inner side of the hand or the inner sides of the fingers and thus do not contribute to the formation of the gripping surface.
  • longitudinal sides of the fingers refers to the sides extending in the longitudinal direction of the fingers, which are arranged between the insides of the fingers and the backs of the fingers, that is to say the areas between the fingers.
  • free ends of the fingers refers to the finger portions formed by the fingertip and the immediately adjacent finger portions.
  • the term "glove” is preferably understood to mean such a glove which serves for the at least substantially complete covering of a palm, a palm and fingers.
  • the glove preferably has the shape of a hand with five fingers.
  • this embodiment of the glove according to the invention is not limiting; Similarly, it is inventively possible to design the glove, for example in the form of a so-called mitten. Similarly, it is possible according to the invention that in each case two fingers (for example index and middle fingers on the one hand and ring finger and small finger on the other hand) are accommodated in each case in a finger holder or sheath.
  • front side synonymously also referred to as “inside” refers to the glove of the invention, which at least substantially cover the palm of the hand and the insides of the fingers when wearing the glove extend over these.
  • back synonymously also referred to as “outside” - of the glove according to the invention to be understood such that it relates to the areas of the glove which cover the back of the hand at least substantially in the wearing state or extend at least substantially over this.
  • inside refers to the side or layer of the glove sections which, in the wearing state of the glove according to the invention, faces the wearer or is in contact with the wearer or the hand, whereby further (covering) Layers can be provided.
  • outside refers to the side or layer of the glove sections which, in the wearing state of the glove, faces away from the wearer or is in contact with the surroundings, further (cover) layers covering the side or the cover Layer can cover.
  • front end of the glove according to the invention relates to the area of the glove, which covers in the wearing state, in particular the fingers and the metacarpus or hand area, while the term “rear end” refers to the area which in the wearing state the wrist and covering the area of the forearm that joins the wrist.
  • the term "toxins and / or pollutants” means those substances which have toxic properties and which can lead to health or serious physical damage when taken up by the skin or with this in Contact advised.
  • chemical warfare agents such. B, the blistering Lost (yellow cross) and the neurotoxin sarin, mentioned.
  • the toxic or pollutants also include radioactive, biological and chemical substances with toxic potential (eg ABC agents), but also toxic substances, such as those found in industrial production plants, or substances which, for example, arise uncontrollably during fires and environmental disasters.
  • the poison or pollutants can be in solid, liquid and / or gaseous form, eg. As an aerosol or the like.
  • Fig. 1A to 3B show a erfindunin glove 1 for covering a hand inside, a hand outside and fingers with protective function against toxins and / or pollutants.
  • glove 1 according to the invention has two glove sections 2, 3 connected to one another, which are constructed from different materials.
  • the first glove section 2 is formed from a polymer-based material which is at least substantially impermeable to chemical poisoning agents and / or warfare agents or whose passage is at least retarded and at least substantially gas and water impermeable and generally also impermeable to water vapor.
  • the second glove section 3 is formed from a textile surface filter material which prevents the passage of poison and / or pollutants or at least delayed and at least substantially gas and / or water vapor permeable.
  • the Fig. 1A . 2A and 3A show the invention preferred principle that the first glove portion 2 of the glove 1 is designed according to the invention such that it covers the hand inside and the inside of the fingers at least substantially completely in the wearing state of the glove 1.
  • the first glove portion 2 of the glove 1 according to the invention is arranged at the front end of the glove 1, and particularly preferably at the Front or inside of the glove according to the invention 1. More precisely, the first glove portion 2 extends in the wearing state at least substantially completely over the palm of your hand or, the inner sides of the fingers.
  • this is not mandatory, and it is equally possible to cover only certain areas of the palm and the inner surface of the fingers, such as those of the index finger and the thumb, with the first glove portion 2.
  • the first glove section 2 in the wearing state of the glove 1 covers the free ends of the fingers over the entire circumference of the finger.
  • the first glove portion 2 can extend, so to speak, fully over the fingertips of the fingers or enclose them, so that, as it were, a covering of the fingertips takes place in the manner of a thimble.
  • the covering of the fingertips by the first glove section 2 in the wearing state of the glove 1 results in the fact that even the particularly exposed and thus endangered fingertips are effectively protected against highly concentrated, in particular liquid, toxic and pollutants.
  • the first glove section 2 in the wearing state of the glove 1 covers the fingers for more than half, in particular more than two thirds, particularly preferably more than three quarters, of the finger circumference. It should be ensured - as mentioned above - that the inner surfaces of the fingers are equally covered by the first glove section 2. Furthermore, it can be provided according to a further aspect of this embodiment that the first glove portion 2, the long sides of the fingers at least substantially completely covered, as well as the Fig. 1B can be seen.
  • the covering of the side surfaces of the fingers with the first glove portion 2 leads to the advantage that these areas, which - are arranged in the immediate vicinity of the actual gripping surface of the hand, similar to the fingertips, equally against highly concentrated or, liquid poison or Pollutants are protected. For example, when touching a contaminated object with the Palm inside there is also a certain risk that the long sides of the fingers can come into contact with the poison or pollutants.
  • the second glove portion 3 is formed such that the backs of the fingers are covered in the wearing state of the glove 1 of the second glove portion 3.
  • the second glove portion 3 may, so to speak, extend from the front end to the rear end of the back of the glove 1 according to the invention, preferably up to the fingertips covered by the first glove portion 2.
  • the first glove section 2 at least substantially completely covers the fingers in the wearing state of the glove 1, as in the second embodiment according to FIG Fig. 2A or the third embodiment according to Fig. 3A can be seen.
  • the first glove portion 2 in the wearing state of the glove 1 forms at least a part of the back of the hand.
  • the first glove section 2 covers at least one region of the back of the hand which is adjacent to the fingers.
  • the first glove section 2 extends, so to speak, completely over the palm of the hand, the fingers and can also (cf. Fig. 3B ) over the knuckles of the back of the hand or over the entire back of the hand.
  • the second glove section 3 can be designed in such a way that the second glove section 3 covers the back of the hand or at least part of the back of the hand in the wearing state of the glove 1 (FIG. Fig. 2B ),
  • the second glove portion 3 extends from the rear end of the glove 1 according to the invention to the knuckles. If the second glove section 3 only partially covers the back of the hand in the wearing state of the glove 1, then that is second glove portion 3 arranged such that it preferably covers at least one not adjacent to the fingers portion of the back of the hand.
  • the glove 1 according to the invention - while having a high protection against poison or warfare agents - overall has a very high wearing comfort.
  • the protective effect is not significantly impaired, as well as the second glove section 3 due to its design as textile surface filter material prevents the passage of poison or pollutants or at least delayed, so that even for the less vulnerable area of the hand, especially the back of the hand, an effective Protection against toxic or pollutants is present, especially if they are present in lower concentrations or gaseous.
  • the glove of the invention also has a shaft for the wrist or for the subsequent wrist section of the forearm.
  • the shaft may be formed, for example, as a cuff, which can be placed on other items of clothing, such as a jacket, so that thereby a contamination-safe transition between glove 1 and the rest of the garment is created.
  • the shaft is located at the rear end of the glove 1 according to the invention and, as it were, forms the opening for inserting the hand into the glove 1 according to the invention.
  • the shaft is formed only by the second glove portion 3, as the Fig. 1A to 3B can be removed.
  • the shaft is at least partially formed by the first glove section 2.
  • the first glove portion 2 should cover the inner surface of the wrist or the forearm portion in the wearing state of the glove 1 and thus effectively form the inside of the shaft.
  • the shank may be modified by means known per se to those skilled in the art: For example, a zipper fastened in addition to the shank can be provided, which in the closed state can reduce the shank diameter that this rests more closely on the wrist or the forearm, whereby the carrying security is increased.
  • the corresponding glove section section 2, 3 should also be formed continuously below the zipper in order not to reduce the protective action against toxic or pollutants. Furthermore, it may be provided that, for example, in the region of the wrist and / or at the rear end of the shaft - for example, and in a non-limiting way - an elastic means, in particular a rubber or the like, is provided to reduce the diameter at this point, so that the glove 1 according to the invention rests against these areas particularly close to the wrist or on the forearm.
  • an elastic means in particular a rubber or the like
  • the glove 1 according to the invention is characterized in that the first glove portion 2 and / or the second glove portion 3 can each be integrally formed, so that the glove 1 according to the invention preferably consists only of two pieces of material. This leads to a simple structure and thus to a significant cost reduction in terms of production. In addition, there is the advantage that the glove 1 according to the invention has only a few potential break-through points, such as can be created, for example, by sewing pieces of material.
  • the pieces of material are connected via connections 4 with each other.
  • the first glove portion 2 and the second glove portion 3 may be sewn, glued, welded and the like in a non-restrictive manner, and plural kinds of connection may be simultaneously realized in the joint 4 (for example, sewing and welding). It is crucial that the compounds 4 is formed at least substantially sealing.
  • the material of the first glove section 2 is essentially free of pores or free of interruptions or continuously formed. Because of these properties, it is ensured that the first glove section 2 is at least substantially impermeable to chemical poisoning or warfare agents or at least retards their passage and at least substantially impermeable to gas and water, and at least is also generally impermeable to water vapor, so that there is a high protective effect with respect to highly concentrated poison or pollutants, in particular if they occur in liquid form. In other words, the first glove section 2 acts as a kind of barrier layer for poison or pollutants since they can not penetrate the first glove section 2 or the material of the first glove section 2.
  • the material of the first glove section 2 may comprise or consist of at least one rubber, d, h, a natural or synthetic rubber, in particular a modified rubber.
  • the material of the first glove section 2 comprises butyl rubber or consists thereof.
  • chloroprene rubbers such as neoprenes, or fluororubbers.
  • fluoroelastomers such as Viton ® , is possible.
  • the first glove section 2 eg rubber on the one hand and fluoroelastomers on the other
  • this preferably taking place in a layered construction ie the individual layers form a contiguous one Composite, wherein each layer may comprise a different polymer from the adjacent layer.
  • the material of the first glove section 2 is multilayered, in particular at least two-layered, preferably at least three-layered ("sandwich construction" or "sandwich construction"), wherein in a preferred embodiment at least one layer has an optionally modified one Rubber, in particular an optionally modified butyl rubber, contains or consists thereof and at least one other layer, which is preferably arranged adjacent to the rubber-containing layer, a fluoroelastomer, such as Viton ® , contains or consists thereof.
  • a fluoroelastomer such as Viton ®
  • the first glove section 2 may preferably additionally have a textile fabric on the inside, in particular a woven fabric, knitted fabric, knit fabric, scrim, nonwoven fabric or nonwoven fabric. If necessary, the textile fabric can also be attached on the outside. It can serve both to increase the wearing comfort, in particular if it is attached on the inside, as well as contribute to an additional reinforcement of the first glove section 2.
  • the first glove section 2 preferably to be exposed on the inside to a material improving the wear comfort, such as polyamide or viscose.
  • a material improving the wear comfort such as polyamide or viscose. This can be done, for example, in the context of flocking.
  • the exposure to the aforementioned materials leads to an increase in wearing comfort, since on the one hand the feel or the feeling of wear is improved and on the other hand, the applied material preferably can absorb body sweat.
  • the second glove section 3 or the textile surface filter material of the second glove section 3 may have a textile fabric or any textile material which is permeable to air or breathable or permeable to water vapor.
  • Non-limiting examples are woven, knitted, knitted, laid, nonwoven fabrics, nonwovens, nonwovens.
  • a reversibly extensible or an elastic textile fabric for example in order to improve the fit of the glove 1 according to the invention.
  • Elastic textile fabrics are known to those skilled in the art.
  • the textile fabric can be stretched or stretched to at least 5%, in particular to at least 10%, preferably to at least 20%, in at least one direction.
  • the textile fabric may have a basis weight of 25 to 500 g / m 2 , in particular 50 to 300 g / m 2 , preferably 75 to 250 g / m 2 .
  • the skilled person is always able to adapt the corresponding basis weights to the respective requirements.
  • this or this adsorbent absorbing a chemical poisons, in particular based on activated carbon may preferably comprise in the form of activated carbon particles and / or activated carbon fibers.
  • the adsorbent is preferably attached to the textile fabric, in particular as defined above, in particular by means of gluing.
  • the attachment or fixation of poison or pollutants absorbent adsorbent preferably on the textile fabric takes place in a manner known to those skilled in the art, for example by continuous or preferably discontinuous application of an adhesive to the fabric, then the poison or pollutants adsorbing material on the fabric by means of the adhesive is fixed.
  • Usable adhesives are known to those skilled in the art as such; For example, thickened plastic dispersions, hot melt adhesives or reactive adhesives, such as in particular polyurethane-based one- or two-component systems, such.
  • thickened plastic dispersions hot melt adhesives or reactive adhesives, such as in particular polyurethane-based one- or two-component systems, such.
  • masked prepolymer diisocyanates which crosslink via di- or polyfunctional amines or alcohols are used.
  • Advantageously according to the invention are those adhesives which are breathable in the cured state, z, B, polyurethane-based adhesives.
  • a discontinuous, in particular a punctiform adhesive application is preferred.
  • the textile fabric is advantageously applied discontinuously or punctiform in a regular or irregular pattern or grid with the adsorbent adsorbing poisonous or pollutant. Due to the dot-like application of the adhesive, the softness, flexibility, and air permeability of the fabric are obtained to a high degree.
  • at least 50%, in particular at least 60%, preferably at least 70%, of the textile fabric is exposed to the adsorbent adsorbing the toxic or pollutant.
  • the amount of adhesive used should advantageously be selected such that at least 50%, in particular at least 60%, preferably at least 70%, of the adsorbent adsorbent adsorbent is freely accessible to the adsorbing toxins and pollutants, d. H. is not completely pressed into the adhesive or sinks.
  • the adsorbent adsorbing poison and / or pollutants is arranged on the side of the second glove section 3 facing away from the wearer in the wearing state of the glove 1.
  • the flat textile structure of the second glove section 3 is preferably arranged on the inside. According to the invention, however, it is equally possible that the adsorbent adsorbing toxic and / or pollutant substances is arranged on the side of the second glove section 3 facing the wearer in the wearing state of the glove 1.
  • the activated carbon preferably used as adsorbent adsorbing poison or pollutants, it may consist, for example, of discrete activated carbon particles, preferably in granular form ("granular carbon") or spherical form ("spherical carbon").
  • the average diameter of the activated carbon particles is preferably less than 1.0 mm, in particular less than 0.8 mm, preferably less than 0.6 mm, but is generally at least 0.1 mm.
  • the activated carbon particles are advantageously in an amount of 5 to 500 g / m 2 , in particular 10 to 400 g / m 2 , preferably 20 to 300 g / m 2 , preferably 25 to 250 g / m 2 , particularly preferably 50 to 150 g / m 2 , most preferably 50 to 100 g / m 2 , applied to the carrier material or the textile fabric (loading amount).
  • Suitable activated carbon particles in particular have an internal surface area (BET) of at least 800 m 2 / g, in particular of at least 900 m 2 / g, preferably of at least 1000 m 2 / g, preferably in the range of 800 to 2500 m 2 / g.
  • Grain especially ball carbon
  • the bursting pressure for a single particle of activated carbon is at least 5 Newton, especially at least 10 Newton, and may reach up to 20 Newton.
  • the second glove section 3 or the textile fabric of the second glove section 3 may be provided or acted upon by activated carbon fibers, in particular in the form of an activated carbon fiber sheet.
  • activated carbon fiber sheetings may, for example, have a weight per unit area of 10 to 300 g / m 2 , in particular 20 to 200 g / m 2 , preferably 30 to 150 g / m 2 .
  • the activated carbon fiber sheet can be, for example, an activated carbon fiber fabric, knitted fabric, fabric or composite, in particular based on carbonized and activated cellulose or a carbonized and activated acrylonitrile.
  • the second glove portion 3 may consist essentially of the poison or Pollutant adsorbing material, in particular from the activated carbon fibers, preferably in the form of the aforementioned textile activated carbon fiber sheets exist.
  • activated carbon particles have the advantage of higher adsorption capacity, while activated carbon fibers have better adsorption kinetics.
  • Suitable catalysts according to the invention are, for example, enzymes and / or metals, preferably copper, silver, cadmium, platinum, palladium, rhodium, zinc and / or mercury, in particular their ions and / or salts.
  • the amount of catalyst can vary widely; In general, it is 0.05 to 12 wt .-%, preferably 1 to 10 wt .-%, particularly preferably 2 to 8 wt .-%, based on the weight of the adsorbent.
  • the additional use of a catalyst leads to a discharge of the activated carbon, so that it does not exhaust too quickly.
  • the good wearing properties of the glove 1 according to the invention are additionally improved when using a poison or adsorbent adsorbent based on activated carbon by the Puffung of the activated carbon, because the activated carbon as a moisture or water storage or buffer (eg., For hand perspiration) is used ,
  • activated carbon particles in grain form (“grain carbon”) or spherical shape (“ball carbon”) for example, up to about 250 g / m 2 or more z.
  • the adsorbent adsorbing the chemical poisons is covered on the outside with another textile sheet material, in particular with a woven, knitted, knitted, laid, nonwoven or nonwoven fabric, in order to protect the adsorbent from external influences.
  • another textile sheet material in particular with a woven, knitted, knitted, laid, nonwoven or nonwoven fabric, in order to protect the adsorbent from external influences.
  • the second glove section has 3 or the textile surface filter material of the second glove section 3 has a so-called sandwich structure.
  • the air permeability of the second glove section 3 should, measured according to DIN 53887, be more than 200 l / m 2 per second, preferably more than 300 l / m 2 per second, preferably more than 400 l / m 2 per second, more preferably more than 600 l / m 2 per second, very particularly preferably more than 800 l / m 2 per second.
  • a high air permeability is particularly advantageous insofar as this ensures a high wearing comfort.
  • the water vapor permeability of the second glove section 3 or the textile fabric of the second glove section 3 results in a high wearing comfort with respect to the entire glove 1 according to the invention.
  • the second glove section 3 of the glove 1 according to the invention can have a water vapor permeability at 25 ° C.
  • the second glove section 3 or the textile fabric of the second glove section 3 may also have a water vapor transmission resistance R 1 under steady-state conditions - measured according to DIN EN 31 092: 1993 of February 1994 ("Textiles - physiological effects, measurement of heat and water vapor transmission resistance under steady-state conditions (sweating guardedhotplate test) "or according to the same international standard ISO 11 092 - at 35 ° C of at most 20 (m 2 ⁇ Pascal) / watt, in particular at most 15 (m 2 Pascal) / Watt, preferably at most 10 (m 2 ⁇ Pascal) / watt, more preferably at most 5 (m 2 ⁇ Pascal) / watt.
  • the second glove section 3 Due to the specific design of the second glove section 3, an excellent protection against toxins and pollutants is thus made possible, since the second glove section 3 in particular prevents or at least delays the passage of gaseous toxins or pollutants, so that the glove according to the invention 1 as a whole has excellent protective properties against the aforementioned toxic substances.
  • connection element in particular a preferably elastic termination collar.
  • the connecting element can be designed equally and in a non-restrictive manner as a tear or Velcro closure, whereby an effective and secure connection can be achieved with other articles of clothing, such as jackets, shirts and the like.
  • the glove 1 according to the invention can thus be an integral part of, for example, a (full-body) protective suit.
  • the preparation of the glove according to the invention can be carried out in a conventional manner. This is the one concerned with the manufacture of gloves Professional well known, so that in this regard requires no further comments.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Gloves (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Claims (12)

  1. Gant (1) destiné à couvrir le côté intérieur de la main, le côté extérieur de la main et les doigts et à assurer une fonction de protection vis-à-vis de substances toxiques et/ou nocives, le gant (1) présentant deux parties (2, 3) de gant reliées l'une à l'autre et constituées de matériaux différents,
    la première partie de gant (2) étant formée d'un matériau à base de polymère au moins essentiellement imperméable vis-à-vis de substances toxiques et/ou d'agents chimiques ou au moins ralentissant leur traversée et étant au moins essentiellement imperméable aux gaz et à l'eau,
    la deuxième partie de gant (3) étant formée d'un matériau textile filtrant plat qui empêche ou au moins ralentit le passage de substances toxiques et/ou nocives et qui est perméable à l'air et perméable à la vapeur d'eau, la deuxième partie de gant (3) présentant un adsorbant à base de charbon actif qui adsorbe les substances toxiques et/ou nocives.
  2. Gant selon la revendication 1, caractérisé en ce que lorsque le gant (1) est porté, la première partie de gant (2) recouvre le côté intérieur de la main et le côté intérieur des doigts, en ce que lorsque le gant (1) est porté, la première partie de gant (2) recouvre les extrémités libres des doigts sur toute la périphérie des doigts et/ou en ce que lorsque le gant (1) est porté, la première partie de gant (2) recouvre la surface intérieure des doigts, de préférence plus de la moitié, en particulier plus des deux tiers et de façon particulièrement préférable plus des trois quarts de la périphérie des doigts et/ou recouvre au moins essentiellement complètement le côté longitudinal des doigts.
  3. Gant selon les revendications 1 et/ou 2, caractérisé en ce que lorsque le gant (1) est porté, la première partie de gant (2) recouvre au moins essentiellement complètement les doigts et/ou en ce que lorsque le gant (1) est porté, la deuxième partie de gant (3) recouvre le côté dorsal des doigts.
  4. Gant selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que lorsque le gant (1) est porté, la première partie de gant (2) recouvre au moins une partie du dos de la main, en particulier au moins la partie du dos de la main voisine des doigts, et/ou en ce que lorsque le gant (1) est porté, la deuxième partie de gant (3) recouvre le dos de la main ou au moins une partie du dos de la main, en particulier au moins la partie du dos de la main non voisine des doigts.
  5. Gant selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que le gant présente une manche pour l'articulation du poignet et/ou la partie de l'avant-bras qui se raccorde à l'articulation du poignet, la manche étant en particulier formée uniquement par la deuxième partie de gant (3) ou la manche étant en particulier formée au moins en partie par la première partie de gant (2) et en particulier lorsque le gant (1) est porté, la première partie de gant (2) recouvrant la surface intérieure de l'articulation du poignet et/ou de la partie de l'avant-bras.
  6. Gant selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que la première partie de gant (2) et/ou la deuxième partie de gant (3) sont chacune réalisée d'une seule pièce, en ce que la première partie de gant (2) et la deuxième partie de gant (3) sont cousues, collées et/ou soudées l'une à l'autre et/ou en ce que la première partie de gant (2) et la deuxième partie de gant (3) sont reliées l'une à l'autre de manière hermétique.
  7. Gant selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que le matériau de la première partie de gant (2) est au moins essentiellement exempt de pores et de perforations et/ou a une configuration continue, en ce que le matériau de la première partie de gant (2) présente au moins un caoutchouc, en particulier un caoutchouc naturel et/ou un caoutchouc synthétique, de préférence un caoutchouc modifié, de préférence du caoutchouc butyle et/ou un élastomère fluoré, ou en est constitué, et/ou en ce que le matériau de la première partie de gant (2) a une structure en plusieurs couches, en particulier en au moins deux couches et de préférence en au moins trois couches, les couches voisines comprenant en particulier, chacune des polymères différents, et/ou au moins une couche contenant en particulier un caoutchouc éventuellement modifié, en particulier un caoutchouc butyle éventuellement modifié ou en est constituée, et au moins une autre couche disposée de préférence au voisinage de la couche contenant du caoutchouc, contenant un élastomère fluoré ou en étant constituée.
  8. Gant selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que la première partie de gant (2) présente de préférence sur son côté intérieur un produit textile plat, en particulier un tissu, un tricot, une couche, un composite textile, un feutre ou un non tissé, en ce qu'un matériau améliorant le confort de pose, par exemple le polyamide et/ou la viscose, est appliqué sur le côté intérieur de la première partie de gant (2) et/ou en ce que la deuxième partie de gant (3) présente un produit textile plat, en particulier un tissu, un tricot, une couche, un composite textile, un feutre ou un non tissé, le produit textile plat présentant en particulier un poids par unité de surface de 25 à 500 g/m2, en particulier de 50 à 300 g/m2 et de préférence de 75 à 250 g/m2.
  9. Gant selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que la deuxième partie de gant (3) comporte l'adsorbant à base de charbon actif qui adsorbe les substances toxiques et/ou nocives sous la forme de particules de charbon actif et/ou de fibres de charbon actif, l'adsorbant étant de préférence fixé sur le produit textile plat et en particulier par collage.
  10. Gant selon la revendication 9, caractérisé en ce que l'adsorbant qui adsorbe les substances toxiques et/ou nocives présente des particules séparées de charbon actif, de préférence sous forme de grains ("charbon en grains") ou sous forme de billes ("charbon en billes"), le diamètre moyen des particules de charbon actif étant en particulier < 1,0 mm, de préférence < 0,8 mm et mieux < 0,6 mm, en ce que le diamètre moyen des particules de charbon actif est d'au moins 0,1 mm, en ce que les particules de charbon actif sont prévues en quantité de 5 à 500 g/m2, en particulier de 10 à 400 g/m2, de préférence de 20 à 300 g/m2, mieux de 25 à 250 g/m2, de façon particulièrement préférable de 50 à 150 g/m2 et de façon tout particulièrement préférable de 50 à 100 g/m2, en ce que les particules de charbon actif présentent en particulier une surface intérieure (BET) d'au moins 800 m2/g, en particulier d'au moins 900 m2/g, mieux d'au moins 1 000 m2/g et de préférence dans la plage de 800 à 2 500 m2/g et/ou en ce que les particules de charbon actif présentent en particulier une pression d'éclatement de chaque particule de charbon actif, en particulier des grains de charbon actif ou des billes de charbon actif, d'au moins 5 Newton, en particulier d'au moins 10 Newton et/ou de jusque 20 Newton.
  11. Gant selon la revendication 9, caractérisé en ce que l'adsorbant qui adsorbe les substances toxiques et/ou les substances nocives comporte des fibres de charbon actif qui présentent en particulier la forme d'un produit plat de fibres de charbon actif, le produit plat de fibres de charbon actif présentant un poids par unité de surface de 10 à 300 g/m2, en particulier de 20 à 200 g/m2 et de préférence de 30 à 150 g/m2, et/ou en ce que le produit plat de fibres de charbon actif est un tissu, un tricot, une couche ou un matériau composite de charbon actif, en particulier à base de cellulose carbonisée et activée et/ou d'un acrylonitrile carbonisé et activé.
  12. Gant selon la revendication 9, caractérisé en ce que l'adsorbant qui adsorbe les substances toxiques et/ou nocives comporte des particules séparées et/ou des fibres séparées de charbon actif, l'adsorbant étant imprégné d'au moins un catalyseur, le catalyseur étant en particulier sélectionné parmi des enzymes et/ou des métaux, de préférence le cuivre, l'argent, le cadmium, le platine, le palladium, le rhodium, le zinc et/ou le mercure, en particulier leurs ions et/ou sels, et/ou en ce qu'en particulier la quantité de catalyseur est de 0,05 à 12 % en poids, de préférence de 1 à 10 % en poids, de façon particulièrement préférable de 2 à 8 % en poids par rapport au poids de l'adsorbant.
EP06012024A 2005-07-01 2006-06-12 Gant avec fonctions de protection du type ABC Active EP1738662B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005031235 2005-07-01
DE102005050730A DE102005050730A1 (de) 2005-07-01 2005-10-22 Handschuh mit verbesserter ABC-Schutzfunktion

Publications (2)

Publication Number Publication Date
EP1738662A1 EP1738662A1 (fr) 2007-01-03
EP1738662B1 true EP1738662B1 (fr) 2011-08-03

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EP06012024A Active EP1738662B1 (fr) 2005-07-01 2006-06-12 Gant avec fonctions de protection du type ABC

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US (1) US7802316B2 (fr)
EP (1) EP1738662B1 (fr)
JP (1) JP4671129B2 (fr)
AT (1) ATE518438T1 (fr)
DE (1) DE102005050730A1 (fr)

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US20080216218A1 (en) * 2007-03-05 2008-09-11 Mckinney Ronald James Chemically protective articles with separable adsorptive liner
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Also Published As

Publication number Publication date
JP2007009401A (ja) 2007-01-18
JP4671129B2 (ja) 2011-04-13
DE102005050730A1 (de) 2007-01-04
EP1738662A1 (fr) 2007-01-03
US7802316B2 (en) 2010-09-28
ATE518438T1 (de) 2011-08-15
US20070000017A1 (en) 2007-01-04

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