EP1632732B1 - Air conditioner - Google Patents
Air conditioner Download PDFInfo
- Publication number
- EP1632732B1 EP1632732B1 EP04745455A EP04745455A EP1632732B1 EP 1632732 B1 EP1632732 B1 EP 1632732B1 EP 04745455 A EP04745455 A EP 04745455A EP 04745455 A EP04745455 A EP 04745455A EP 1632732 B1 EP1632732 B1 EP 1632732B1
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- EP
- European Patent Office
- Prior art keywords
- refrigerant
- pressure
- utilization
- heat source
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003507 refrigerant Substances 0.000 claims abstract description 279
- 239000007788 liquid Substances 0.000 claims abstract description 62
- 238000011176 pooling Methods 0.000 claims abstract description 8
- 230000006835 compression Effects 0.000 claims abstract description 6
- 238000007906 compression Methods 0.000 claims abstract description 6
- 230000007246 mechanism Effects 0.000 claims description 20
- 230000001105 regulatory effect Effects 0.000 claims description 11
- 238000001816 cooling Methods 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 14
- 239000002994 raw material Substances 0.000 description 11
- 230000008859 change Effects 0.000 description 9
- 238000004378 air conditioning Methods 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B13/00—Compression machines, plants or systems, with reversible cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/40—Fluid line arrangements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B43/00—Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
- F25B43/006—Accumulators
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/023—Compression machines, plants or systems with reversible cycle not otherwise provided for using multiple indoor units
- F25B2313/0233—Compression machines, plants or systems with reversible cycle not otherwise provided for using multiple indoor units in parallel arrangements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/027—Compression machines, plants or systems with reversible cycle not otherwise provided for characterised by the reversing means
- F25B2313/02741—Compression machines, plants or systems with reversible cycle not otherwise provided for characterised by the reversing means using one four-way valve
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/031—Sensor arrangements
- F25B2313/0313—Pressure sensors near the outdoor heat exchanger
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/031—Sensor arrangements
- F25B2313/0314—Temperature sensors near the indoor heat exchanger
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
- F25B2313/031—Sensor arrangements
- F25B2313/0315—Temperature sensors near the outdoor heat exchanger
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/01—Geometry problems, e.g. for reducing size
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/21—Reduction of parts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2600/00—Control issues
- F25B2600/25—Control of valves
- F25B2600/2513—Expansion valves
Definitions
- the present invention relates to an air conditioner, and more particularly relates to an air conditioner comprising a plurality of utilization units.
- the operating load fluctuates greatly, and attendant therewith the amount of refrigerant circulating in a refrigerant circuit fluctuates, thereby causing a fluctuation in the surplus refrigerant inside the refrigerant circuit.
- This surplus refrigerant is sometimes pooled as a liquid refrigerant in an accumulator connected on the inlet side of a compressor.
- R407C is a non-azeotropic refrigerant
- making the surplus refrigerant pool in the accumulator unfortunately causes a compositional change in the refrigerant during the evaporation process in the refrigerating cycle process, i.e., during the refrigerant evaporation process (during cooling operation) in a utilization side heat exchanger of a utilization unit, and during the refrigerant evaporation process (during heating operation) in a heat source side heat exchanger of a heat source unit, resulting in a rich state of the low boiling point component R32 in the gas phase inside the accumulator, and a rich state of the high boiling point component R134a in the liquid phase inside the accumulator. Consequently, the R32-rich refrigerant is sucked into the compressor and circulates inside the refrigerant circuit, and there is a risk that the overall air conditioner will not achieve the performance expected of R407C.
- an air conditioner wherein the surplus refrigerant is made to pool in a receiver connected to the refrigerant pipe, wherein a high-pressure liquid refrigerant flows, and to suppress a compositional change in the refrigerant attendant with the evaporation process (e.g., refer to JP-A-2001-183020 ).
- an air conditioner comprising a vapor compression type refrigerant circuit comprising a high pressure section constituted by the connection of a compressor that compresses low pressure gas refrigerant and discharges high pressure gas refrigerant, a heat source side heat exchanger capable of functioning as an evaporator or a condenser, a plurality of utilization side heat exchangers mutually connected in parallel each capable of functioning as a condenser or as an evaporator, and a switching mechanism capable of switching between a state, wherein the gas side of the heat source side heat exchanger is connected to the discharge side of the compressor, the inlet side of the compressor is connected to the gas side of the utilization side heat exchangers and low pressure gas refrigerant is sucked into the compressor and a state, wherein the gas side of the heat source side heat exchanger is connected to the inlet side of said compressor the discharge side of the compressor is connected to the gas side of the utilization side heat exchangers and high pressure gas ref
- a receiver is connected to the refrigerant pipe, wherein a high-pressure liquid refrigerant flows, instead of the accumulator as in the air conditioner that uses the latter R407C mentioned above, then it is preferable in that the constitution as well as operation and control of the refrigerant circuit are not as complicated as the former.
- the maximum value of the working pressure of the refrigerant flowing inside the refrigerant circuit is higher than the case wherein R407C is used (in contrast with the standard working pressure, a high pressure of approximately 1 MPa is often used, and shall be the maximum working pressure hereinbelow); consequently, the compressive strength of the parts constituting the refrigerant circuit must be increased.
- the size of the parts that constitute the refrigerant circuit in an air conditioner of a building and the like is larger than a relatively compact air conditioner like a room air conditioner, if the maximum working pressure of the refrigerant circuit portion wherein a high-pressure refrigerant flows (hereinbelow, referred to as the high pressure unit) increases, then the compressive strength of the parts that constitute the refrigerant circuit must consequently be increased, which strongly tends to increase cost. Consequently, to increase the compressive strength of the receiver in an air conditioner comprising a receiver that is one of the parts constituting the abovementioned high pressure unit, the wall thickness must be increased, which increases the cost.
- the high pressure unit the maximum working pressure of the refrigerant circuit portion wherein a high-pressure refrigerant flows
- the air conditioner of the invention comprises a plurality of utilization units, comprising a vapor compression type refrigerant circuit and an accumulator.
- the refrigerant circuit comprises a high pressure unit constituted by the connection of parts capable of flowing a high-pressure refrigerant at a maximum working pressure of 3.3 MPa or higher; and a low pressure unit constituted by the connection of parts capable of flowing only a low-pressure refrigerant at a maximum working pressure of less than 3.3 MPa.
- the accumulator is one of the parts constituting the low pressure unit and is capable of pooling refrigerant that circulates inside the refrigerant circuit as a liquid refrigerant.
- the refrigerant that flows through the low pressure unit and the high pressure unit is a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant.
- the standard working pressure of the high pressure unit is approximately 2.0 MPa. Consequently, if R407C is used as the working refrigerant, then it is often the case in an air conditioner that the maximum working pressure of the high pressure unit is set to 3.0 - 3.3 MPa, which is a pressure approximately 1 MPa higher than the standard working pressure of 2.0 MPa. Consequently, in the air conditioner that uses R407C as the working refrigerant, it is preferable that the parts constituting the high pressure unit have a compressive strength that can withstand 3.3 MPa.
- the parts constituting the high pressure unit must have a compressive strength that can withstand a pressure of 3.3 MPa or higher because the maximum working pressure of the high pressure unit exceeds 3.3 MPa.
- a raw material of the thick wall that satisfies the maximum working pressure condition is normally selected and fabricated from among standard products, such as JIS standard products. Consequently, by using a refrigerant having saturation pressure characteristics higher than R407C, the wall thickness unfortunately increases substantially, and the cost of the parts constituting the refrigerant circuit unfortunately increase unnecessarily.
- a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant is used as the refrigerant having saturation pressure characteristics higher than R407C, and an accumulator, capable of pooling the surplus refrigerant, which increases and decreases due to the fluctuations of the operating load of the plurality of utilization units, is installed in the low pressure unit having a maximum working pressure of less than 3.3 MPa; consequently, a receiver is no longer needed in the high pressure unit, and parts, such as the bypass pipe for preventing a compositional change in the refrigerant such as the case wherein a non-azeotropic refrigerant is used, are no longer necessary.
- the air conditioner according to the invention further comprises a compressor, a heat source side heat exchanger, expansion mechanisms, a plurality of utilization side heat exchangers, a switching mechanism, and an accumulator.
- the compressor compresses low-pressure gas refrigerant and discharges high-pressure gas refrigerant.
- the heat source side heat exchanger is capable of functioning as an evaporator or a condenser.
- the plurality of utilization side heat exchangers are mutually connected in parallel, and each is capable of functioning as a condenser or an evaporator.
- the expansion mechanisms are connected between the utilization side heat exchangers and the heat source side heat exchanger.
- the switching mechanism is capable of switching between a state wherein the gas side of the heat source side heat exchanger is connected to the discharge side of the compressor, the inlet side of the compressor is connected to the gas side of the utilization side heat exchangers, and low-pressure gas refrigerant is sucked into the compressor, and a state wherein the gas side of the heat source side heat exchanger is connected to the inlet side of the compressor, the discharge side of the compressor is connected to the gas side of the utilization side heat exchangers, and high-pressure gas refrigerant flows to the utilization side heat exchangers.
- the accumulator is connected between the switching mechanism and the inlet side of the compressor, and is capable of pooling low-pressure refrigerant as a liquid refrigerant.
- the low pressure unit which includes the accumulator and is constituted by the connection of the switching mechanism and the inlet side of the compressor, can flow only low-pressure refrigerant at a maximum working pressure of less than 3.3 MPa.
- the high pressure unit which is a part that excludes the low pressure unit and is constituted by the connection of the compressor, the heat source side heat exchanger, the plurality of utilization side heat exchangers, and the switching mechanism, can flow high-pressure refrigerant at a maximum working pressure of 3.3 MPa or higher.
- the refrigerant that flows through the low pressure unit and the high pressure unit is a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant having saturation pressure characteristics higher than R407C.
- the standard working pressure of the high pressure unit is approximately 2.0 MPa. Consequently, if R407C is used as the working refrigerant, then it is often the case in an air conditioner that the maximum working pressure of the high pressure unit is set to 3.0 - 3.3 MPa, which is a pressure approximately 1 MPa higher than the standard working pressure of 2.0 MPa. Consequently, in the air conditioner that uses R407C as the working refrigerant, it is preferable that the parts constituting the high pressure unit have a compressive strength that can withstand 3.3 MPa.
- the parts constituting the high pressure unit must have a compressive strength that can withstand a pressure of 3.3 MPa or higher because the maximum working pressure of the high pressure unit exceeds 3.3 MPa.
- a raw material of the thick wall that satisfies the maximum working pressure condition is normally selected and fabricated from among standard products, such as JIS standard products. Consequently, by using a refrigerant having saturation pressure characteristics higher than R407C, the wall thickness unfortunately increases substantially, and the cost of the parts constituting the refrigerant circuit unfortunately increases unnecessarily.
- a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant is used as the refrigerant having saturation pressure characteristics higher than R407C, and an accumulator, capable of pooling the surplus refrigerant, which increases and decreases due to the fluctuations of the operating load of the plurality of utilization side heat exchangers, is installed in the low pressure unit having a maximum working pressure of less than 3.3 MPa; consequently, a receiver is no longer needed in the high pressure unit, and parts, such as the bypass pipe for preventing a compositional change in the refrigerant such as the case wherein a non-azeotropic refrigerant is used, are no longer necessary.
- the air conditioner according to the invention further comprises a heat source side temperature detector, utilization side temperature detectors, and a high pressure pressure detector.
- the heat source side temperature detector detects a refrigerant temperature on the liquid side of the heat source side heat exchanger.
- a utilization side temperature detector detects a refrigerant temperature on the liquid side of each of the utilization side heat exchangers.
- the high pressure pressure detector detects a refrigerant pressure on the discharge side of the compressor.
- the opening of the expansion mechanism is regulated so that the liquid refrigerant on the liquid side of the heat source side heat exchanger reaches a prescribed subcooled state when the heat source side heat exchanger functions as a condenser
- the opening of each expansion mechanism is regulated so that the liquid refrigerant on the liquid side of the each utilization side heat exchanger reaches a prescribed subcooled state when the utilization side heat exchanger functions as the condenser.
- the surplus refrigerant which increases and decreases according to the operating load, can be reliably pooled in the accumulator by setting the condensed refrigerant to a prescribed subcooled state when the heat source side heat exchanger functions as the condenser during cooling operation.
- the surplus refrigerant which increases and decreases according to the operating load, can be reliably pooled in the accumulator by setting the condensed refrigerant to a prescribed subcooled state, even when the utilization side heat exchanger functions as the condenser during heating operation.
- the air conditioner according to an embodiment of the invention is the air conditioner as recited above, wherein the refrigerant that flows through the low pressure unit and the high pressure unit includes R32.
- the air conditioning capacity can be improved because a refrigerant is used that includes R32, which has a high heat transport performance.
- the refrigerant that flows through the low pressure unit and the high pressure unit is R410A.
- the air conditioning capacity can be improved more than when using R407C because R410A is used.
- FIG. 1 is a schematic view of the refrigerant circuit of an air conditioner 1 according to one embodiment of the present invention.
- the air conditioner 1 is, for example, an apparatus used in the cooling and heating of a building and the like, and comprises a heat source unit 2, a plurality of utilization units 5 (two units in the present embodiment) connected in parallel thereto, and a liquid refrigerant connecting pipe 6 and a gas refrigerant connecting pipe 7 for connecting the heat source unit 2 and the utilization units 5.
- the air conditioner 1 uses R410A (50 wt% of R32 and 50 wt% of R125), which is a pseudo azeotropic refrigerant having saturation pressure characteristics higher than R407C, as the working refrigerant.
- R410A includes more R32, which has high heat transport performance, than does R407C, which improves the air conditioning capacity of the air conditioner 1.
- Each utilization unit 5 principally comprises a utilization side expansion valve 51, a utilization side heat exchanger 52, and a pipe connecting them.
- the utilization side expansion valve 51 is an electric expansion valve connected on the liquid side of the utilization side heat exchanger 52 in order to regulate the refrigerant pressure, regulate the refrigerant flow, and the like.
- the utilization side heat exchanger 52 is a heat exchanger that functions as a refrigerant evaporator during cooling operation to cool the indoor air, and functions as a refrigerant condenser during heating operation to heat the indoor air.
- the utilization side heat exchanger 52 is provided with a utilization side temperature detector 53 that detects the refrigerant temperature.
- the utilization side temperature detector 53 is a thermistor disposed on the liquid side of the utilization side heat exchanger 52.
- the heat source unit 2 principally comprises a compressor 21, a four-way switching valve 22, a heat source side heat exchanger 23, a heat source side expansion valve 24, an accumulator 25, a liquid side gate valve 26, a gas side gate valve 27, and pipes that connect them.
- the compressor 21 is a variable capacity compressor that compresses low-pressure gas refrigerant and discharges high-pressure gas refrigerant.
- a high pressure pressure detector 28 comprising a pressure sensor that detects the pressure of the high-pressure gas refrigerant is provided on the discharge side of the compressor 21.
- the four-way switching valve 22 is a valve that switches the direction of the flow of the refrigerant when switching between cooling operation and heating operation; during cooling operation, the discharge side of the compressor 21 and the gas side of the heat source side heat exchanger 23 can be connected, and the inlet side of the compressor 21 (specifically, the accumulator 25) and the gas refrigerant connecting pipe 7 side can be connected (refer to the solid line of the four-way switching valve 22 in FIG. 1 ); and during heating operation, the discharge side of the compressor 21 and the gas refrigerant connecting pipe 7 side can be connected, and the inlet side of the compressor 21 and the gas side of the heat source side heat exchanger 23 can be connected (refer to the broken line of the four-way switching valve 22 in FIG. 1 ).
- the heat source side heat exchanger 23 is a heat exchanger that functions as a refrigerant condenser during cooling operation with the outdoor air or water as the heat source, and functions as a refrigerant evaporator during heating operation with the outdoor air or water as the heat source.
- the heat source side heat exchanger 23 is provided with a heat source side temperature detector 29 that detects the refrigerant temperature.
- the heat source side temperature detector 29 is a thermistor disposed on the liquid side of the heat source side heat exchanger 23.
- the heat source side expansion valve 24 is connected on the liquid side of the heat source side heat exchanger 23 and, in the present embodiment, is an electric expansion valve for regulating the refrigerant flow between the heat source side heat exchanger 23 and the utilization side heat exchanger 52, and the like.
- the accumulator 25 is connected between the four-way switching valve 22 and the compressor 21, and is a vessel for pooling the low-pressure refrigerant and the surplus refrigerant sucked into the compressor 21.
- the liquid side gate valve 26 and the gas side gate valve 27 are respectively connected to the liquid refrigerant connecting pipe 6 and the gas refrigerant connecting pipe 7.
- the liquid refrigerant connecting pipe 6 is connected between the liquid side of the utilization side heat exchanger 52 of each utilization unit 5 and the liquid side of the heat source side heat exchanger 23 of the heat source unit 2.
- the gas refrigerant connecting pipe 7 is connected between the gas side of the utilization side heat exchanger 52 of each utilization unit 5 and the four-way switching valve 22 of the heat source unit 2.
- the refrigerant circuit wherein are successively connected the utilization side expansion valves 51, the utilization side heat exchangers 52, the compressor 21, the four-way switching valve 22, the heat source side heat exchanger 23, the heat source side expansion valve 24, the accumulator 25, the liquid side gate valve 26, and the gas side gate valve 27, as explained above, constitutes a refrigerant circuit 10 of the air conditioner 1.
- FIG. 2 is a Mollier diagram that depicts the refrigerating cycle of the air conditioner 1.
- the four-way switching valve 22 is in the state depicted by the solid line in FIG. 1 , i.e., the discharge side of the compressor 21 and the gas side of the heat source side heat exchanger 23 are connected, and the inlet side of the compressor 21 and the gas side of the utilization side heat exchangers 52 are connected.
- the liquid side gate valve 26 and the gas side gate valve 27 are opened, and the utilization side expansion valves 51 are fully opened.
- the heat source side expansion valve 24 is in a state wherein the opening can be regulated by the subcooling control based on the high pressure pressure detector 28 and the heat source side temperature detector 29.
- a degree of subcooling of the high-pressure liquid refrigerant is calculated based on the temperature differential between a saturation temperature corresponding to a pressure value of the high-pressure gas refrigerant detected by the high pressure pressure detector 28 and a temperature value of the high-pressure liquid refrigerant detected by the heat source side temperature detector 29, and the opening of the heat source side expansion valve 24 can be regulated so that the degree of subcooling reaches a prescribed value.
- the high-pressure gas refrigerant is sent to the heat source side heat exchanger 23 via the four-way switching valve 22, is heat exchanged with the outdoor air or water that forms the heat source, is condensed, and is cooled to a temperature Tc (approximately 45° C) slightly lower than the saturation temperature Tsat (approximately 50° C) at pressure Pd (refer to the point C in FIG. 2 ).
- Tc approximately 45° C
- Tsat approximately 50° C
- the high pressure liquid refrigerant subcooling temperature ⁇ Tc in the point C state i.e., Tsat - Tc
- ⁇ Tc approximately 5° C
- the state change is maintained as in the refrigerating cycle depicted in FIG. 2 and the surplus refrigerant pools in the accumulator 25, even if the operating load of each utilization unit 5 fluctuates, changing the amount of refrigerant circulating.
- R410A which is one of the pseudo azeotropic refrigerants, is used as the working refrigerant in the present embodiment, the refrigerant composition of the low-pressure gas refrigerant sucked into the compressor 21 and the refrigerant composition of the liquid refrigerant that pooled in the accumulator 25 are maintained at a constant level by the vapor-liquid separation inside the accumulator 25.
- the four-way switching valve 22 is in the state indicated by the broken line in FIG. 1 , i.e., the discharge side of the compressor 21 is connected to the gas side of the utilization side heat exchangers 52, and the inlet side of the compressor 21 is connected to the gas side of the heat source side heat exchanger 23.
- the liquid side gate valve 26 and the gas side gate valve 27 are opened, and the heat source side expansion valve 24 is in a full-open state.
- Each utilization side expansion valve 51 is in a state wherein the valve opening can be regulated by the subcooling control based on the high pressure pressure detector 28 and the respective utilization side temperature detector 53.
- the degree of subcooling of the high-pressure liquid refrigerant is calculated based on the temperature differential between the saturation temperature corresponding to the pressure value of the high-pressure gas refrigerant detected by the high pressure pressure detector 28 and the temperature value of the high-pressure liquid refrigerant detected by the respective utilization side temperature detector 53, and the opening of the respective utilization side expansion valve 51 can be regulated so that the degree of subcooling reaches a prescribed value.
- the compressor 21 If the compressor 21 is activated in this refrigerant circuit 10 state, the low-pressure gas refrigerant is sucked into and compressed by the compressor 21, becomes a high-pressure gas refrigerant, and is then sent to the each utilization unit 5 via the four-way switching valve 22, the gas side gate valve 27, and the gas refrigerant connecting pipe 7. Furthermore, the high-pressure gas refrigerant sent to each utilization unit 5 is heat exchanged with the indoor air and condensed in the utilization side heat exchanger 52, and is cooled to a temperature slightly lower than the saturation temperature of the high-pressure gas refrigerant.
- the degree of subcooling of the high-pressure liquid refrigerant in the point C state is maintained at a constant level by the subcooling control based on the respective utilization side expansion valve 51.
- the pressure of this condensed liquid refrigerant is reduced in accordance with the opening of the respective utilization side expansion valve 51, becomes a low-pressure vapor-liquid two-phase refrigerant, and is sent to the heat source unit 2 via the liquid refrigerant connecting pipe 6 and the liquid side gate valve 26.
- the vapor-liquid two-phase refrigerant sent to the heat source unit 2 passes through the heat source side expansion valve 24, its heat is exchanged with the outdoor air or water, which forms the heat source, by the heat source side heat exchanger 23, is then evaporated, once again becomes a low-pressure gas refrigerant, and flows into the accumulator 25 via the four-way switching valve 22. Furthermore, the low-pressure gas refrigerant that flowed into the accumulator 25 once again is sucked into the compressor 21.
- the refrigerant flows during heating operation in a direction the opposite of the flow during cooling operation; in addition, although there is a point of difference in that subcooling control is performed by the utilization side expansion valve 51, the refrigerant state change is the same as the refrigerating cycle state change as shown in FIG. 2 .
- the refrigerant circuit 10 comprises a high pressure unit 10a, which is a refrigerant circuit part wherein high-pressure refrigerant flows, and a low pressure unit 10b, which is a refrigerant circuit part wherein only low-pressure refrigerant flows.
- the low pressure unit 10b is a part that includes the accumulator 25 and wherein the four-way switching valve 22 and the inlet side of the compressor 21 are connected; and the high pressure unit 10a is the part of the refrigerant circuit 10 that does not include the low pressure unit 10b.
- the parts that constitute the high pressure unit 10a (specifically, the compressor 21, the four-way switching valve 22, the heat source side heat exchanger 23, the heat source side expansion valve 24, the liquid side gate valve 26, the gas side gate valve 27, the utilization side expansion valves 51, and the utilization side heat exchangers 52) and the piping are designed taking into consideration a margin of approximately 1 MPa with respect to the standard working pressure (approximately 3.0 MPa) of the abovementioned high-pressure refrigerant so that high-pressure refrigerant can flow at the maximum working pressure (approximately 4 MPa).
- the parts that constitute the low pressure unit 10b (specifically, the accumulator 25) and the piping are designed taking into consideration a margin of approximately 1 MPa with respect to the standard working pressure (approximately 0.9 MPa) of the abovementioned low-pressure refrigerant, so that low-pressure refrigerant can flow at the maximum working pressure (approximately 2 MPa).
- the air conditioner 1 of the present embodiment has the following features.
- R410A is used as the refrigerant having saturation pressure characteristics higher than R407C; and an accumulator 25, capable of pooling surplus refrigerant that increases and decreases due to fluctuations in the operating load of the plurality of utilization units 5, is installed in the low pressure unit 10b, which has a maximum working pressure of less than 3.3 MPa.
- schedule 20 raw material can be used up to a working pressure of 3.3 MPa
- schedule 30 raw material can be used up to 4.3 MPa.
- schedule 20 raw material can be selected because it has sufficient compressive strength.
- the maximum working pressure of the receiver is approximately 4.0 MPa (the maximum working pressure of the high pressure unit 10a)
- schedule 20 raw material cannot be used; moreover, schedule 30 raw material must be selected regardless of the fact that the approximately 7.4 mm wall thickness is sufficient based on calculations.
- the maximum working pressure of the high pressure unit is 3.0 - 3.3 MPa if R407C is used as the working refrigerant of the air conditioner, it is possible to use schedule 20 raw material; however, in a case wherein a refrigerant is used, as in the present embodiment, having saturation pressure characteristics higher than R407C, such as R410A, the use of the receiver as the vessel that pools the surplus refrigerant results in a substantial increase in wall thickness, which unfortunately increases the cost of the parts that constitute the refrigerant circuit unnecessarily.
- R410A is a pseudo azeotropic refrigerant
- parts such as the bypass pipe are no longer necessary to prevent compositional changes in the refrigerant, such as in the case wherein a non-azeotropic refrigerant like R407C is used, even if using the accumulator 25 as the vessel that pools the surplus refrigerant, and it is therefore possible to prevent an increase in the cost of the parts that constitute the refrigerant circuit.
- the degree of subcooling based on the high-pressure liquid refrigerant is calculated during cooling operation in the air conditioner 1 based on the temperature differential between the pressure value of the high-pressure gas refrigerant detected by the high pressure pressure detector 28 and the temperature value of the high-pressure liquid refrigerant detected by the heat source side temperature detector 29, and the opening of the heat source side expansion valve 24 can be regulated so that the degree of subcooling reaches a prescribed value; consequently, the surplus refrigerant, which increases and decreases according to the operating load, can be reliably pooled in the accumulator 25.
- the degree of subcooling based on the high-pressure liquid refrigerant during heating operation is calculated based on the temperature differential between the pressure value of the high-pressure gas refrigerant detected by the high pressure pressure detector 28 and the temperature value of the high-pressure liquid refrigerant detected by the utilization side temperature detector 53, and the opening of the utilization side expansion valve 51 can be regulated so that the degree of subcooling reaches a prescribed value; consequently, the surplus refrigerant, which increases and decreases according to the operating load, can be reliably pooled in the accumulator 25.
- the air conditioner of the abovementioned embodiment uses a refrigerant circuit capable of cooling and heating operation; however, the present invention is not limited thereto, and may be applied to an air conditioner having a refrigerant circuit dedicated for cooling or for heating that does not use a 4-way switching valve.
- R410A which is one type of pseudo azeotropic refrigerant
- R410B R32: 45 wt%, R125: 55 wt%
- a single refrigerant like R32 and other pseudo azeotropic refrigerants or azeotropic refrigerants.
- the use of the present invention enables, in an air conditioner comprising a plurality of utilization units, the prevention of a cost increase in the parts constituting the refrigerant circuit, even if the maximum working pressure of the refrigerant circuit increases, by the use of a refrigerant having saturation pressure characteristics higher than R407C.
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Abstract
Description
- The present invention relates to an air conditioner, and more particularly relates to an air conditioner comprising a plurality of utilization units.
- From the standpoint of environment preservation, the working refrigerant in air conditioners used in the air conditioning of buildings and the like is being changed over from R22 to R407C of HFC refrigerants.
- Insofar as such an air conditioner used in the air conditioning of a building and the like is provided with a plurality of utilization units, the operating load fluctuates greatly, and attendant therewith the amount of refrigerant circulating in a refrigerant circuit fluctuates, thereby causing a fluctuation in the surplus refrigerant inside the refrigerant circuit. This surplus refrigerant is sometimes pooled as a liquid refrigerant in an accumulator connected on the inlet side of a compressor.
- However, because R407C is a non-azeotropic refrigerant, making the surplus refrigerant pool in the accumulator unfortunately causes a compositional change in the refrigerant during the evaporation process in the refrigerating cycle process, i.e., during the refrigerant evaporation process (during cooling operation) in a utilization side heat exchanger of a utilization unit, and during the refrigerant evaporation process (during heating operation) in a heat source side heat exchanger of a heat source unit, resulting in a rich state of the low boiling point component R32 in the gas phase inside the accumulator, and a rich state of the high boiling point component R134a in the liquid phase inside the accumulator. Consequently, the R32-rich refrigerant is sucked into the compressor and circulates inside the refrigerant circuit, and there is a risk that the overall air conditioner will not achieve the performance expected of R407C.
- In contrast, it is known to suppress a compositional change in the refrigerant by connecting the accumulator and a refrigerant pipe, wherein a high-pressure liquid refrigerant flows, with a bypass pipe, and also to detect the composition of the refrigerant and optimally control operation in accordance with compositional change (e.g., refer to
JP-A-8-35725 JP-A-10-220880 JP-A-10-332211 JP-A-11-173698 JP-A-2001-183020 EP-A-0 848 214 A2 comprising a vapor compression type refrigerant circuit comprising a high pressure section constituted by the connection of a compressor that compresses low pressure gas refrigerant and discharges high pressure gas refrigerant, a heat source side heat exchanger capable of functioning as an evaporator or a condenser, a plurality of utilization side heat exchangers mutually connected in parallel each capable of functioning as a condenser or as an evaporator, and a switching mechanism capable of switching between a state, wherein the gas side of the heat source side heat exchanger is connected to the discharge side of the compressor, the inlet side of the compressor is connected to the gas side of the utilization side heat exchangers and low pressure gas refrigerant is sucked into the compressor and a state, wherein the gas side of the heat source side heat exchanger is connected to the inlet side of said compressor the discharge side of the compressor is connected to the gas side of the utilization side heat exchangers and high pressure gas refrigerant flows to said utilization side heat exchangers, a low pressure unit constituted by the connection of said switching mechanism and an inlet side of said compressor and an accumulator connected between said switching mechanism and the inlet side of the compressor, wherein the refrigerant that flows through the vapor compression type refrigerant circuit is a refrigerant having saturation pressure characteristics higher than R407C. Further, said air conditioner comprises utilization side expansion mechanisms each connected to a utilization side heat exchanger. - There is a problem in that, if the accumulator and the refrigerant pipe, wherein a high-pressure liquid refrigerant flows, are connected by a bypass pipe as in an air conditioner that uses the former R407C mentioned above, then the constitution as well as operation and control of the refrigerant circuit become complicated.
- On one hand, if a receiver is connected to the refrigerant pipe, wherein a high-pressure liquid refrigerant flows, instead of the accumulator as in the air conditioner that uses the latter R407C mentioned above, then it is preferable in that the constitution as well as operation and control of the refrigerant circuit are not as complicated as the former.
- However, even in the field of air conditioners used in the air conditioning of buildings and the like, those that use a refrigerant having saturation pressure characteristics higher than R407C (e.g., R410A and HC refrigerants) have recently begun to be developed or commercialized in order to improve air conditioning capacity and make the equipment more compact. However, in cases where a refrigerant is used having saturation pressure characteristics higher than R407C, the maximum value of the working pressure of the refrigerant flowing inside the refrigerant circuit is higher than the case wherein R407C is used (in contrast with the standard working pressure, a high pressure of approximately 1 MPa is often used, and shall be the maximum working pressure hereinbelow); consequently, the compressive strength of the parts constituting the refrigerant circuit must be increased. In particular, because the size of the parts that constitute the refrigerant circuit in an air conditioner of a building and the like is larger than a relatively compact air conditioner like a room air conditioner, if the maximum working pressure of the refrigerant circuit portion wherein a high-pressure refrigerant flows (hereinbelow, referred to as the high pressure unit) increases, then the compressive strength of the parts that constitute the refrigerant circuit must consequently be increased, which strongly tends to increase cost. Consequently, to increase the compressive strength of the receiver in an air conditioner comprising a receiver that is one of the parts constituting the abovementioned high pressure unit, the wall thickness must be increased, which increases the cost.
- It is an object of the present invention to suppress an increase in the cost of the parts that constitute the refrigerant circuit in an air conditioner comprising a plurality of utilization units, even if the maximum working pressure of the refrigerant circuit increases, by using a refrigerant having saturation pressure characteristics higher than R407C.
- This object is solved by the features of claim 1. Embodiments of the invention are named in the dependent claims.
- The air conditioner of the invention comprises a plurality of utilization units, comprising a vapor compression type refrigerant circuit and an accumulator. The refrigerant circuit comprises a high pressure unit constituted by the connection of parts capable of flowing a high-pressure refrigerant at a maximum working pressure of 3.3 MPa or higher; and a low pressure unit constituted by the connection of parts capable of flowing only a low-pressure refrigerant at a maximum working pressure of less than 3.3 MPa. The accumulator is one of the parts constituting the low pressure unit and is capable of pooling refrigerant that circulates inside the refrigerant circuit as a liquid refrigerant. Further, the refrigerant that flows through the low pressure unit and the high pressure unit is a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant.
- If using R407C as the working refrigerant of the air conditioner, then the standard working pressure of the high pressure unit is approximately 2.0 MPa. Consequently, if R407C is used as the working refrigerant, then it is often the case in an air conditioner that the maximum working pressure of the high pressure unit is set to 3.0 - 3.3 MPa, which is a pressure approximately 1 MPa higher than the standard working pressure of 2.0 MPa. Consequently, in the air conditioner that uses R407C as the working refrigerant, it is preferable that the parts constituting the high pressure unit have a compressive strength that can withstand 3.3 MPa.
- However, if using a refrigerant having saturation pressure characteristics higher than R407C, then the parts constituting the high pressure unit must have a compressive strength that can withstand a pressure of 3.3 MPa or higher because the maximum working pressure of the high pressure unit exceeds 3.3 MPa. Particularly for vessels and piping and the like, instead of manufacturing and fabricating a raw material having an optimal wall thickness computed from the maximum working pressure of the high pressure unit, a raw material of the thick wall that satisfies the maximum working pressure condition is normally selected and fabricated from among standard products, such as JIS standard products. Consequently, by using a refrigerant having saturation pressure characteristics higher than R407C, the wall thickness unfortunately increases substantially, and the cost of the parts constituting the refrigerant circuit unfortunately increase unnecessarily.
- To prevent such an unnecessary cost increase in the air conditioner according to the present invention, a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant is used as the refrigerant having saturation pressure characteristics higher than R407C, and an accumulator, capable of pooling the surplus refrigerant, which increases and decreases due to the fluctuations of the operating load of the plurality of utilization units, is installed in the low pressure unit having a maximum working pressure of less than 3.3 MPa; consequently, a receiver is no longer needed in the high pressure unit, and parts, such as the bypass pipe for preventing a compositional change in the refrigerant such as the case wherein a non-azeotropic refrigerant is used, are no longer necessary.
- Thereby, by using a refrigerant having saturation pressure characteristics higher than R407C, it is possible to prevent an increase in the cost of the parts that constitute the refrigerant circuit, even if the maximum working pressure of the refrigerant circuit increases.
- The air conditioner according to the invention further comprises a compressor, a heat source side heat exchanger, expansion mechanisms, a plurality of utilization side heat exchangers, a switching mechanism, and an accumulator. The compressor compresses low-pressure gas refrigerant and discharges high-pressure gas refrigerant. The heat source side heat exchanger is capable of functioning as an evaporator or a condenser. The plurality of utilization side heat exchangers are mutually connected in parallel, and each is capable of functioning as a condenser or an evaporator. The expansion mechanisms are connected between the utilization side heat exchangers and the heat source side heat exchanger. The switching mechanism is capable of switching between a state wherein the gas side of the heat source side heat exchanger is connected to the discharge side of the compressor, the inlet side of the compressor is connected to the gas side of the utilization side heat exchangers, and low-pressure gas refrigerant is sucked into the compressor, and a state wherein the gas side of the heat source side heat exchanger is connected to the inlet side of the compressor, the discharge side of the compressor is connected to the gas side of the utilization side heat exchangers, and high-pressure gas refrigerant flows to the utilization side heat exchangers. The accumulator is connected between the switching mechanism and the inlet side of the compressor, and is capable of pooling low-pressure refrigerant as a liquid refrigerant. The low pressure unit, which includes the accumulator and is constituted by the connection of the switching mechanism and the inlet side of the compressor, can flow only low-pressure refrigerant at a maximum working pressure of less than 3.3 MPa. The high pressure unit, which is a part that excludes the low pressure unit and is constituted by the connection of the compressor, the heat source side heat exchanger, the plurality of utilization side heat exchangers, and the switching mechanism, can flow high-pressure refrigerant at a maximum working pressure of 3.3 MPa or higher. Further, the refrigerant that flows through the low pressure unit and the high pressure unit is a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant having saturation pressure characteristics higher than R407C.
- If using R407C as the working refrigerant of the air conditioner, then the standard working pressure of the high pressure unit is approximately 2.0 MPa. Consequently, if R407C is used as the working refrigerant, then it is often the case in an air conditioner that the maximum working pressure of the high pressure unit is set to 3.0 - 3.3 MPa, which is a pressure approximately 1 MPa higher than the standard working pressure of 2.0 MPa. Consequently, in the air conditioner that uses R407C as the working refrigerant, it is preferable that the parts constituting the high pressure unit have a compressive strength that can withstand 3.3 MPa.
- However, if using a refrigerant having saturation pressure characteristics higher than R407C, then the parts constituting the high pressure unit must have a compressive strength that can withstand a pressure of 3.3 MPa or higher because the maximum working pressure of the high pressure unit exceeds 3.3 MPa. Particularly for vessels and piping and the like, instead of manufacturing and fabricating a raw material having an optimal wall thickness computed from the maximum working pressure of the high pressure unit, a raw material of the thick wall that satisfies the maximum working pressure condition is normally selected and fabricated from among standard products, such as JIS standard products. Consequently, by using a refrigerant having saturation pressure characteristics higher than R407C, the wall thickness unfortunately increases substantially, and the cost of the parts constituting the refrigerant circuit unfortunately increases unnecessarily.
- To prevent such an unnecessary cost increase in the air conditioner according to the present invention, a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant is used as the refrigerant having saturation pressure characteristics higher than R407C, and an accumulator, capable of pooling the surplus refrigerant, which increases and decreases due to the fluctuations of the operating load of the plurality of utilization side heat exchangers, is installed in the low pressure unit having a maximum working pressure of less than 3.3 MPa; consequently, a receiver is no longer needed in the high pressure unit, and parts, such as the bypass pipe for preventing a compositional change in the refrigerant such as the case wherein a non-azeotropic refrigerant is used, are no longer necessary.
- Thereby, by using a refrigerant having saturation pressure characteristics higher than R407C, it is possible to prevent an increase in the cost of the parts that constitute the refrigerant circuit, even if the maximum working pressure of the refrigerant circuit increases.
- The air conditioner according to the invention further comprises a heat source side temperature detector, utilization side temperature detectors, and a high pressure pressure detector. The heat source side temperature detector detects a refrigerant temperature on the liquid side of the heat source side heat exchanger. A utilization side temperature detector detects a refrigerant temperature on the liquid side of each of the utilization side heat exchangers. The high pressure pressure detector detects a refrigerant pressure on the discharge side of the compressor. Furthermore, based on the values of the refrigerant temperature and the refrigerant pressure detected by the heat source side temperature detector, the utilization side temperature detectors, and the high pressure pressure detector, the opening of the expansion mechanism is regulated so that the liquid refrigerant on the liquid side of the heat source side heat exchanger reaches a prescribed subcooled state when the heat source side heat exchanger functions as a condenser, and the opening of each expansion mechanism is regulated so that the liquid refrigerant on the liquid side of the each utilization side heat exchanger reaches a prescribed subcooled state when the utilization side heat exchanger functions as the condenser.
- In the present air conditioner, the surplus refrigerant, which increases and decreases according to the operating load, can be reliably pooled in the accumulator by setting the condensed refrigerant to a prescribed subcooled state when the heat source side heat exchanger functions as the condenser during cooling operation. In addition, the surplus refrigerant, which increases and decreases according to the operating load, can be reliably pooled in the accumulator by setting the condensed refrigerant to a prescribed subcooled state, even when the utilization side heat exchanger functions as the condenser during heating operation.
- The air conditioner according to an embodiment of the invention is the air conditioner as recited above, wherein the refrigerant that flows through the low pressure unit and the high pressure unit includes R32.
- In the present air conditioner, the air conditioning capacity can be improved because a refrigerant is used that includes R32, which has a high heat transport performance.
- In an air conditioner according to an alternative embodiment of the invention the refrigerant that flows through the low pressure unit and the high pressure unit is R410A.
- In the present air conditioner, the air conditioning capacity can be improved more than when using R407C because R410A is used.
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FIG. 1 is a schematic view of the refrigerant circuit of the air conditioner of one embodiment according to the present invention. -
FIG. 2 is a Mollier diagram that depicts the refrigerating cycle of the air conditioner. -
FIG. 3 is a chart that depicts the relationship between the working pressure and the wall thickness. - The following explains an embodiment of the air conditioner according to the present invention, referencing the drawings.
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FIG. 1 is a schematic view of the refrigerant circuit of an air conditioner 1 according to one embodiment of the present invention. - The air conditioner 1 is, for example, an apparatus used in the cooling and heating of a building and the like, and comprises a heat source unit 2, a plurality of utilization units 5 (two units in the present embodiment) connected in parallel thereto, and a liquid
refrigerant connecting pipe 6 and a gasrefrigerant connecting pipe 7 for connecting the heat source unit 2 and theutilization units 5. - In the present embodiment, the air conditioner 1 uses R410A (50 wt% of R32 and 50 wt% of R125), which is a pseudo azeotropic refrigerant having saturation pressure characteristics higher than R407C, as the working refrigerant. R410A includes more R32, which has high heat transport performance, than does R407C, which improves the air conditioning capacity of the air conditioner 1.
- Each
utilization unit 5 principally comprises a utilization side expansion valve 51, a utilization side heat exchanger 52, and a pipe connecting them. - In the present embodiment, the utilization side expansion valve 51 is an electric expansion valve connected on the liquid side of the utilization side heat exchanger 52 in order to regulate the refrigerant pressure, regulate the refrigerant flow, and the like.
- In the present embodiment, the utilization side heat exchanger 52 is a heat exchanger that functions as a refrigerant evaporator during cooling operation to cool the indoor air, and functions as a refrigerant condenser during heating operation to heat the indoor air. In addition, the utilization side heat exchanger 52 is provided with a utilization
side temperature detector 53 that detects the refrigerant temperature. In the present embodiment, the utilizationside temperature detector 53 is a thermistor disposed on the liquid side of the utilization side heat exchanger 52. - The heat source unit 2 principally comprises a
compressor 21, a four-way switching valve 22, a heat sourceside heat exchanger 23, a heat sourceside expansion valve 24, anaccumulator 25, a liquidside gate valve 26, a gasside gate valve 27, and pipes that connect them. - In the present embodiment, the
compressor 21 is a variable capacity compressor that compresses low-pressure gas refrigerant and discharges high-pressure gas refrigerant. In addition, a highpressure pressure detector 28 comprising a pressure sensor that detects the pressure of the high-pressure gas refrigerant is provided on the discharge side of thecompressor 21. - The four-
way switching valve 22 is a valve that switches the direction of the flow of the refrigerant when switching between cooling operation and heating operation; during cooling operation, the discharge side of thecompressor 21 and the gas side of the heat sourceside heat exchanger 23 can be connected, and the inlet side of the compressor 21 (specifically, the accumulator 25) and the gasrefrigerant connecting pipe 7 side can be connected (refer to the solid line of the four-way switching valve 22 inFIG. 1 ); and during heating operation, the discharge side of thecompressor 21 and the gasrefrigerant connecting pipe 7 side can be connected, and the inlet side of thecompressor 21 and the gas side of the heat sourceside heat exchanger 23 can be connected (refer to the broken line of the four-way switching valve 22 inFIG. 1 ). - In the present embodiment, the heat source
side heat exchanger 23 is a heat exchanger that functions as a refrigerant condenser during cooling operation with the outdoor air or water as the heat source, and functions as a refrigerant evaporator during heating operation with the outdoor air or water as the heat source. In addition, the heat sourceside heat exchanger 23 is provided with a heat sourceside temperature detector 29 that detects the refrigerant temperature. In the present embodiment, the heat sourceside temperature detector 29 is a thermistor disposed on the liquid side of the heat sourceside heat exchanger 23. - The heat source
side expansion valve 24 is connected on the liquid side of the heat sourceside heat exchanger 23 and, in the present embodiment, is an electric expansion valve for regulating the refrigerant flow between the heat sourceside heat exchanger 23 and the utilization side heat exchanger 52, and the like. - The
accumulator 25 is connected between the four-way switching valve 22 and thecompressor 21, and is a vessel for pooling the low-pressure refrigerant and the surplus refrigerant sucked into thecompressor 21. - The liquid
side gate valve 26 and the gasside gate valve 27 are respectively connected to the liquidrefrigerant connecting pipe 6 and the gasrefrigerant connecting pipe 7. The liquidrefrigerant connecting pipe 6 is connected between the liquid side of the utilization side heat exchanger 52 of eachutilization unit 5 and the liquid side of the heat sourceside heat exchanger 23 of the heat source unit 2. The gasrefrigerant connecting pipe 7 is connected between the gas side of the utilization side heat exchanger 52 of eachutilization unit 5 and the four-way switching valve 22 of the heat source unit 2. - The refrigerant circuit wherein are successively connected the utilization side expansion valves 51, the utilization side heat exchangers 52, the
compressor 21, the four-way switching valve 22, the heat sourceside heat exchanger 23, the heat sourceside expansion valve 24, theaccumulator 25, the liquidside gate valve 26, and the gasside gate valve 27, as explained above, constitutes arefrigerant circuit 10 of the air conditioner 1. - The following explains the operation of the air conditioner 1 under standard working conditions, referencing
FIG. 1 andFIG. 2 . Herein,FIG. 2 is a Mollier diagram that depicts the refrigerating cycle of the air conditioner 1. - During cooling operation, the four-
way switching valve 22 is in the state depicted by the solid line inFIG. 1 , i.e., the discharge side of thecompressor 21 and the gas side of the heat sourceside heat exchanger 23 are connected, and the inlet side of thecompressor 21 and the gas side of the utilization side heat exchangers 52 are connected. In addition, the liquidside gate valve 26 and the gasside gate valve 27 are opened, and the utilization side expansion valves 51 are fully opened. The heat sourceside expansion valve 24 is in a state wherein the opening can be regulated by the subcooling control based on the highpressure pressure detector 28 and the heat sourceside temperature detector 29. More specifically, a degree of subcooling of the high-pressure liquid refrigerant is calculated based on the temperature differential between a saturation temperature corresponding to a pressure value of the high-pressure gas refrigerant detected by the highpressure pressure detector 28 and a temperature value of the high-pressure liquid refrigerant detected by the heat sourceside temperature detector 29, and the opening of the heat sourceside expansion valve 24 can be regulated so that the degree of subcooling reaches a prescribed value. - If the
compressor 21 activates in this state of therefrigerant circuit 10, then the low-pressure gas refrigerant (pressure Ps = approximately 0.9 MPa, and temperature Ts = approximately 15° C) is sucked into and compressed by thecompressor 21 to form the high-pressure gas refrigerant (pressure Pd = approximately 3.0 MPa, and temperature Td = approximately 70° C) (refer to the point A and the point B inFIG. 2 ). Subsequently, the high-pressure gas refrigerant is sent to the heat sourceside heat exchanger 23 via the four-way switching valve 22, is heat exchanged with the outdoor air or water that forms the heat source, is condensed, and is cooled to a temperature Tc (approximately 45° C) slightly lower than the saturation temperature Tsat (approximately 50° C) at pressure Pd (refer to the point C inFIG. 2 ). Herein, the high pressure liquid refrigerant subcooling temperature ΔTc in the point C state (i.e., Tsat - Tc) is maintained at a constant level (herein, ΔTc = approximately 5° C) by the subcooling control based on the heat sourceside expansion valve 24. - Furthermore, the pressure of this condensed liquid refrigerant is reduced in accordance with the opening of the heat source
side expansion valve 24, becomes a low-pressure vapor-liquid two-phase refrigerant (pressure Ps = approximately 0.9 MPa, temperature TD = approximately 3° C) (refer to point D inFIG. 2 ), and is sent to eachutilization unit 5 via the liquidside gate valve 26 and the liquidrefrigerant connecting pipe 6. - After the vapor-liquid two-phase refrigerant sent to each
utilization unit 5 passes through the utilization side expansion valve 51, its heat is exchanged with the indoor air by the utilization side heat exchanger 52, it evaporates, and then once again becomes a low-pressure gas refrigerant (pressure Ps = approximately 0.9 MPa, temperature Ts = approximately 15° C) (refer to point A inFIG. 2 ). This low-pressure gas refrigerant passes through the gasrefrigerant connecting pipe 7, the gasside gate valve 27, and the four-way switching valve 22, and flows into theaccumulator 25. Furthermore, the low-pressure gas refrigerant that flowed into theaccumulator 25 once again is sucked into thecompressor 21. - Furthermore, as explained above, because the high pressure liquid refrigerant subcooling temperature ΔTc is maintained at a constant level in the point C state by the subcooling control based on the heat source
side expansion valve 24, the state change is maintained as in the refrigerating cycle depicted inFIG. 2 and the surplus refrigerant pools in theaccumulator 25, even if the operating load of eachutilization unit 5 fluctuates, changing the amount of refrigerant circulating. - In addition, if low-pressure liquid refrigerant flows from the utilization side heat exchanger 52 along with the low-pressure gas refrigerant into the
accumulator 25, or if the surplus refrigerant pools in theaccumulator 25, then the low-pressure gas refrigerant and liquid refrigerant inside theaccumulator 25 undergo vapor-liquid separation, and only the low-pressure gas refrigerant is sucked into thecompressor 21. At this time, because R410A, which is one of the pseudo azeotropic refrigerants, is used as the working refrigerant in the present embodiment, the refrigerant composition of the low-pressure gas refrigerant sucked into thecompressor 21 and the refrigerant composition of the liquid refrigerant that pooled in theaccumulator 25 are maintained at a constant level by the vapor-liquid separation inside theaccumulator 25. - During heating operation, the four-
way switching valve 22 is in the state indicated by the broken line inFIG. 1 , i.e., the discharge side of thecompressor 21 is connected to the gas side of the utilization side heat exchangers 52, and the inlet side of thecompressor 21 is connected to the gas side of the heat sourceside heat exchanger 23. In addition, the liquidside gate valve 26 and the gasside gate valve 27 are opened, and the heat sourceside expansion valve 24 is in a full-open state. Each utilization side expansion valve 51 is in a state wherein the valve opening can be regulated by the subcooling control based on the highpressure pressure detector 28 and the respective utilizationside temperature detector 53. More specifically, the degree of subcooling of the high-pressure liquid refrigerant is calculated based on the temperature differential between the saturation temperature corresponding to the pressure value of the high-pressure gas refrigerant detected by the highpressure pressure detector 28 and the temperature value of the high-pressure liquid refrigerant detected by the respective utilizationside temperature detector 53, and the opening of the respective utilization side expansion valve 51 can be regulated so that the degree of subcooling reaches a prescribed value. - If the
compressor 21 is activated in thisrefrigerant circuit 10 state, the low-pressure gas refrigerant is sucked into and compressed by thecompressor 21, becomes a high-pressure gas refrigerant, and is then sent to the eachutilization unit 5 via the four-way switching valve 22, the gasside gate valve 27, and the gasrefrigerant connecting pipe 7. Furthermore, the high-pressure gas refrigerant sent to eachutilization unit 5 is heat exchanged with the indoor air and condensed in the utilization side heat exchanger 52, and is cooled to a temperature slightly lower than the saturation temperature of the high-pressure gas refrigerant. Herein, the degree of subcooling of the high-pressure liquid refrigerant in the point C state is maintained at a constant level by the subcooling control based on the respective utilization side expansion valve 51. The pressure of this condensed liquid refrigerant is reduced in accordance with the opening of the respective utilization side expansion valve 51, becomes a low-pressure vapor-liquid two-phase refrigerant, and is sent to the heat source unit 2 via the liquidrefrigerant connecting pipe 6 and the liquidside gate valve 26. Furthermore, after the vapor-liquid two-phase refrigerant sent to the heat source unit 2 passes through the heat sourceside expansion valve 24, its heat is exchanged with the outdoor air or water, which forms the heat source, by the heat sourceside heat exchanger 23, is then evaporated, once again becomes a low-pressure gas refrigerant, and flows into theaccumulator 25 via the four-way switching valve 22. Furthermore, the low-pressure gas refrigerant that flowed into theaccumulator 25 once again is sucked into thecompressor 21. - Thus, the refrigerant flows during heating operation in a direction the opposite of the flow during cooling operation; in addition, although there is a point of difference in that subcooling control is performed by the utilization side expansion valve 51, the refrigerant state change is the same as the refrigerating cycle state change as shown in
FIG. 2 . - As can be understood from the above explanation of the operation of the air conditioner 1 during cooling operation and during heating operation, the
refrigerant circuit 10 comprises ahigh pressure unit 10a, which is a refrigerant circuit part wherein high-pressure refrigerant flows, and alow pressure unit 10b, which is a refrigerant circuit part wherein only low-pressure refrigerant flows. Specifically, thelow pressure unit 10b is a part that includes theaccumulator 25 and wherein the four-way switching valve 22 and the inlet side of thecompressor 21 are connected; and thehigh pressure unit 10a is the part of therefrigerant circuit 10 that does not include thelow pressure unit 10b. - Herein, the parts that constitute the
high pressure unit 10a (specifically, thecompressor 21, the four-way switching valve 22, the heat sourceside heat exchanger 23, the heat sourceside expansion valve 24, the liquidside gate valve 26, the gasside gate valve 27, the utilization side expansion valves 51, and the utilization side heat exchangers 52) and the piping are designed taking into consideration a margin of approximately 1 MPa with respect to the standard working pressure (approximately 3.0 MPa) of the abovementioned high-pressure refrigerant so that high-pressure refrigerant can flow at the maximum working pressure (approximately 4 MPa). In addition, the parts that constitute thelow pressure unit 10b (specifically, the accumulator 25) and the piping are designed taking into consideration a margin of approximately 1 MPa with respect to the standard working pressure (approximately 0.9 MPa) of the abovementioned low-pressure refrigerant, so that low-pressure refrigerant can flow at the maximum working pressure (approximately 2 MPa). - The air conditioner 1 of the present embodiment has the following features.
- It is unnecessary in the air conditioner 1 of the present embodiment to provide the
high pressure unit 10a with a receiver because: R410A is used as the refrigerant having saturation pressure characteristics higher than R407C; and anaccumulator 25, capable of pooling surplus refrigerant that increases and decreases due to fluctuations in the operating load of the plurality ofutilization units 5, is installed in thelow pressure unit 10b, which has a maximum working pressure of less than 3.3 MPa. - Thereby, the use of a refrigerant in the air conditioner 1 having saturation pressure characteristics higher than R407C can prevent cost increases in the parts constituting the refrigerant circuit, even if the maximum working pressure of the refrigerant circuit increases.
- The effect of preventing a cost increase will be explained, for the case wherein the maximum working pressure of the refrigerant circuit increases due to the use of R410A as the working refrigerant, by comparing the case wherein the
accumulator 25 is provided in thelow pressure unit 10b as in the present embodiment with the case wherein thehigh pressure unit 10a is provided with a receiver (not shown) as in the conventional case. - For example, if fabrication and manufacture are performed using the JIS standard STPG 370E (carbon steel pipes for pressure service) as the raw material for the
accumulator 25, which is cylindrically shaped and has a nominal diameter of ten inches, and the receiver, then it is conceivable to select schedule 20 (thickness 6.4 mm) or schedule 30 (thickness 7.8 mm). Further, as shown by the chart inFIG. 3 depicting the relationship between the working pressure and the wall thickness,schedule 20 raw material can be used up to a working pressure of 3.3 MPa, andschedule 30 raw material can be used up to 4.3 MPa. - Herein, because the maximum working pressure of the
accumulator 25 is approximately 2.0 MPa (the maximum working pressure of thelow pressure unit 10b), even schedule 20 raw material can be selected because it has sufficient compressive strength. However, because the maximum working pressure of the receiver is approximately 4.0 MPa (the maximum working pressure of thehigh pressure unit 10a),schedule 20 raw material cannot be used; moreover,schedule 30 raw material must be selected regardless of the fact that the approximately 7.4 mm wall thickness is sufficient based on calculations. - Thus, because the maximum working pressure of the high pressure unit is 3.0 - 3.3 MPa if R407C is used as the working refrigerant of the air conditioner, it is possible to use
schedule 20 raw material; however, in a case wherein a refrigerant is used, as in the present embodiment, having saturation pressure characteristics higher than R407C, such as R410A, the use of the receiver as the vessel that pools the surplus refrigerant results in a substantial increase in wall thickness, which unfortunately increases the cost of the parts that constitute the refrigerant circuit unnecessarily. In other words, as above mentioned, in the case wherein a refrigerant is used, such as R410A, having saturation pressure characteristics higher than R407C, then an increase in the cost is prevented more if the accumulator is used instead of the receiver as the vessel that pools the surplus refrigerant. - In addition, because R410A is a pseudo azeotropic refrigerant, parts such as the bypass pipe are no longer necessary to prevent compositional changes in the refrigerant, such as in the case wherein a non-azeotropic refrigerant like R407C is used, even if using the
accumulator 25 as the vessel that pools the surplus refrigerant, and it is therefore possible to prevent an increase in the cost of the parts that constitute the refrigerant circuit. - Furthermore, the degree of subcooling based on the high-pressure liquid refrigerant is calculated during cooling operation in the air conditioner 1 based on the temperature differential between the pressure value of the high-pressure gas refrigerant detected by the high
pressure pressure detector 28 and the temperature value of the high-pressure liquid refrigerant detected by the heat sourceside temperature detector 29, and the opening of the heat sourceside expansion valve 24 can be regulated so that the degree of subcooling reaches a prescribed value; consequently, the surplus refrigerant, which increases and decreases according to the operating load, can be reliably pooled in theaccumulator 25. In addition, the degree of subcooling based on the high-pressure liquid refrigerant during heating operation is calculated based on the temperature differential between the pressure value of the high-pressure gas refrigerant detected by the highpressure pressure detector 28 and the temperature value of the high-pressure liquid refrigerant detected by the utilizationside temperature detector 53, and the opening of the utilization side expansion valve 51 can be regulated so that the degree of subcooling reaches a prescribed value; consequently, the surplus refrigerant, which increases and decreases according to the operating load, can be reliably pooled in theaccumulator 25. - The above explained an embodiment of the present invention based on the drawings, but the specific constitution is not limited to these embodiments, and it is understood that variations and modifications may be effected without departing from the spirit and scope of the invention.
- The air conditioner of the abovementioned embodiment uses a refrigerant circuit capable of cooling and heating operation; however, the present invention is not limited thereto, and may be applied to an air conditioner having a refrigerant circuit dedicated for cooling or for heating that does not use a 4-way switching valve.
- In the abovementioned embodiment, R410A, which is one type of pseudo azeotropic refrigerant, was used as the working refrigerant; however, the present invention is not limited thereto, and it is also acceptable to use a pseudo azeotropic refrigerant having a R32:R125 compositional ratio different than that of R410A, such as R410B (R32: 45 wt%, R125: 55 wt%), a single refrigerant like R32, and other pseudo azeotropic refrigerants or azeotropic refrigerants.
- The use of the present invention enables, in an air conditioner comprising a plurality of utilization units, the prevention of a cost increase in the parts constituting the refrigerant circuit, even if the maximum working pressure of the refrigerant circuit increases, by the use of a refrigerant having saturation pressure characteristics higher than R407C.
Claims (4)
- An air conditioner (1) comprising a plurality of utilization units (5), comprising:a vapor compression type refrigerant circuit (10) comprising: a high pressure unit (10a) constituted by the connection of a compressor (21) that compresses low-pressure gas refrigerant and discharges high-pressure gas refrigerant;a heat source side heat exchanger (23) capable of functioning as an evaporator or a condenser;a plurality of utilization side heat exchangers (52) mutually connected in parallel, each capable of functioning as a condenser or as an evaporator; anda switching mechanism (22) capable of switching between a state wherein the gas side of said heat source side heat exchanger is connected to the discharge side of said compressor, the inlet side of said compressor is connected to the gas side of said utilization side heat exchangers, and low-pressure gas refrigerant is sucked into the compressor, and a state wherein the gas side of said heat source side heat exchanger is connected to the inlet side of said compressor, the discharge side of said compressor is connected to the gas side of said utilization side heat exchangers, and high-pressure gas refrigerant flows to said utilization side heat exchanger, wherein the parts of the high pressure unit (10a) are capable of flowing a high-pressure refrigerant at a maximum working pressure of 3.3 MPa or higher;a low pressure unit (10b) constituted by the connection of said switching mechanism and the inlet side of said compressor and an accumulator (25) connected between said switching mechanism and the inlet side of said compressor, and capable of pooling refrigerant that circulates inside said refrigerant circuit as a liquid refrigerant, wherein the parts of the low pressure unit are capable of flowing only a low-pressure refrigerant at a maximum working pressure of less than 3.3 MPa; andwherein, the refrigerant that flows through the vapour compression type refrigerant circuit is a pseudo azeotropic refrigerant, an azeotropic refrigerant, or a single refrigerant having saturation pressure characteristics higher than R407C, wherein the air conditioner further comprisesa heat source side expansion mechanisms (24) connected between said utilization side heat exchangers and said heat source side heat exchanger and a utilization side expansion mechanism (51) each connected to a utilization heat exchanger; anda heat source side temperature detector (29) configured to detect a refrigerant temperature on the liquid side of said heat source side heat exchanger (23);a utilization side temperature detector (53) configured to detect a refrigerant temperature on the liquid side of each of said utilization side heat exchangers (52); anda high pressure pressure detector (28) configured to detect a refrigerant pressure on the discharge side of said compressor (21);wherein, based on the values of the refrigerant temperature and the refrigerant pressure detected by said heat source side temperature detector, said utilization side temperature detectors, and said high pressure pressure detector, the opening of said heat source side expansion mechanism (24) is regulated so that the liquid refrigerant on the liquid side of said heat source side heat exchanger reaches a prescribed subcooled state when said heat source side heat exchanger functions as a condenser, and the opening of each said utilization side expansion mechanisms (51) is regulated so that the liquid refrigerant on the liquid side of each said utilization side heat exchanger reaches a prescribed subcooled state when said utilization side heat exchanger functions as the condenser.
- The air conditioner (1) as recited in Claim 1, wherein the refrigerant that flows through said low pressure unit (10b) and said high pressure unit (10a) includes R32.
- The air conditioner (1) as recited in Claim 1, wherein the refrigerant that flows through said low pressure unit (10b) and said high pressure unit (10a) is R410A.
- The air conditioner (1) as recited in any one claim of claims 1 through 3, wherein the high pressure unit is not provided with a receiver.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003161934A JP2004361036A (en) | 2003-06-06 | 2003-06-06 | Air conditioning system |
PCT/JP2004/007490 WO2004109199A1 (en) | 2003-06-06 | 2004-05-31 | Air conditioner |
Publications (3)
Publication Number | Publication Date |
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EP1632732A1 EP1632732A1 (en) | 2006-03-08 |
EP1632732A4 EP1632732A4 (en) | 2006-07-26 |
EP1632732B1 true EP1632732B1 (en) | 2012-01-11 |
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ID=33508651
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Application Number | Title | Priority Date | Filing Date |
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EP04745455A Expired - Lifetime EP1632732B1 (en) | 2003-06-06 | 2004-05-31 | Air conditioner |
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US (1) | US20060000224A1 (en) |
EP (1) | EP1632732B1 (en) |
JP (1) | JP2004361036A (en) |
KR (1) | KR100605797B1 (en) |
CN (1) | CN100419344C (en) |
AT (1) | ATE541167T1 (en) |
AU (1) | AU2004245797B2 (en) |
ES (1) | ES2380331T3 (en) |
WO (1) | WO2004109199A1 (en) |
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JP4187020B2 (en) * | 2006-08-08 | 2008-11-26 | ダイキン工業株式会社 | Air conditioner and cleaning method thereof |
JP5138292B2 (en) * | 2007-07-04 | 2013-02-06 | 三菱重工業株式会社 | Air conditioner |
JP5213372B2 (en) * | 2007-07-09 | 2013-06-19 | 三菱電機株式会社 | Air conditioner |
US20170080773A1 (en) * | 2008-11-03 | 2017-03-23 | Arkema France | Vehicle Heating and/or Air Conditioning Method |
JP5315990B2 (en) * | 2008-12-29 | 2013-10-16 | ダイキン工業株式会社 | Air conditioning apparatus and control method thereof |
US9746223B2 (en) * | 2010-09-30 | 2017-08-29 | Mitsubishi Electric Corporation | Air-conditioning apparatus |
KR20120136854A (en) * | 2011-06-10 | 2012-12-20 | 삼성전자주식회사 | Water supply apparatus |
ES2796384T3 (en) * | 2011-10-04 | 2020-11-26 | Mitsubishi Electric Corp | Refrigeration cycle device |
JP6064412B2 (en) * | 2012-07-30 | 2017-01-25 | 株式会社富士通ゼネラル | Air conditioner |
JP2016102631A (en) * | 2014-11-28 | 2016-06-02 | パナソニックIpマネジメント株式会社 | Air conditioning device |
US11906207B2 (en) | 2017-12-18 | 2024-02-20 | Daikin Industries, Ltd. | Refrigeration apparatus |
US11549695B2 (en) | 2017-12-18 | 2023-01-10 | Daikin Industries, Ltd. | Heat exchange unit |
US11441802B2 (en) | 2017-12-18 | 2022-09-13 | Daikin Industries, Ltd. | Air conditioning apparatus |
US11506425B2 (en) | 2017-12-18 | 2022-11-22 | Daikin Industries, Ltd. | Refrigeration cycle apparatus |
US11493244B2 (en) | 2017-12-18 | 2022-11-08 | Daikin Industries, Ltd. | Air-conditioning unit |
US11549041B2 (en) | 2017-12-18 | 2023-01-10 | Daikin Industries, Ltd. | Composition containing refrigerant, use of said composition, refrigerator having said composition, and method for operating said refrigerator |
US11365335B2 (en) | 2017-12-18 | 2022-06-21 | Daikin Industries, Ltd. | Composition comprising refrigerant, use thereof, refrigerating machine having same, and method for operating said refrigerating machine |
US11441819B2 (en) | 2017-12-18 | 2022-09-13 | Daikin Industries, Ltd. | Refrigeration cycle apparatus |
WO2019123898A1 (en) * | 2017-12-18 | 2019-06-27 | ダイキン工業株式会社 | Refrigeration machine oil for refrigerant or refrigerant composition, method for using refrigeration machine oil, and use of refrigeration machine oil |
US11435118B2 (en) | 2017-12-18 | 2022-09-06 | Daikin Industries, Ltd. | Heat source unit and refrigeration cycle apparatus |
JP7269499B2 (en) | 2017-12-18 | 2023-05-09 | ダイキン工業株式会社 | refrigeration cycle equipment |
WO2019123782A1 (en) | 2017-12-18 | 2019-06-27 | ダイキン工業株式会社 | Composition comprising refrigerant, use thereof, refrigerating machine having same, and method for operating said refrigerating machine |
US11820933B2 (en) | 2017-12-18 | 2023-11-21 | Daikin Industries, Ltd. | Refrigeration cycle apparatus |
CN110953779B (en) * | 2019-12-20 | 2021-06-22 | 潍柴动力股份有限公司 | Method and device for controlling pressure of liquid storage tank of Rankine cycle system |
KR20230168821A (en) | 2022-06-08 | 2023-12-15 | 임종봉 | R410A gas insulated transformer |
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-
2003
- 2003-06-06 JP JP2003161934A patent/JP2004361036A/en active Pending
-
2004
- 2004-05-31 CN CNB200480001832XA patent/CN100419344C/en not_active Expired - Lifetime
- 2004-05-31 ES ES04745455T patent/ES2380331T3/en not_active Expired - Lifetime
- 2004-05-31 WO PCT/JP2004/007490 patent/WO2004109199A1/en active Application Filing
- 2004-05-31 EP EP04745455A patent/EP1632732B1/en not_active Expired - Lifetime
- 2004-05-31 KR KR1020057004897A patent/KR100605797B1/en active IP Right Grant
- 2004-05-31 AU AU2004245797A patent/AU2004245797B2/en not_active Expired
- 2004-05-31 AT AT04745455T patent/ATE541167T1/en active
- 2004-05-31 US US10/523,780 patent/US20060000224A1/en not_active Abandoned
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AU2004245797B2 (en) | 2006-06-29 |
KR100605797B1 (en) | 2006-08-01 |
KR20050044931A (en) | 2005-05-13 |
CN1723373A (en) | 2006-01-18 |
WO2004109199A1 (en) | 2004-12-16 |
CN100419344C (en) | 2008-09-17 |
ATE541167T1 (en) | 2012-01-15 |
EP1632732A1 (en) | 2006-03-08 |
JP2004361036A (en) | 2004-12-24 |
EP1632732A4 (en) | 2006-07-26 |
ES2380331T3 (en) | 2012-05-10 |
US20060000224A1 (en) | 2006-01-05 |
AU2004245797A1 (en) | 2004-12-16 |
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