EP1620216B1 - Matiere a mouler, piece moulee et procede de fabrication de pieces moulees pour un moule - Google Patents
Matiere a mouler, piece moulee et procede de fabrication de pieces moulees pour un moule Download PDFInfo
- Publication number
- EP1620216B1 EP1620216B1 EP04731830A EP04731830A EP1620216B1 EP 1620216 B1 EP1620216 B1 EP 1620216B1 EP 04731830 A EP04731830 A EP 04731830A EP 04731830 A EP04731830 A EP 04731830A EP 1620216 B1 EP1620216 B1 EP 1620216B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mould
- casting
- solidification
- mould material
- produced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005266 casting Methods 0.000 title claims abstract description 56
- 238000000465 moulding Methods 0.000 title claims abstract description 48
- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 239000004576 sand Substances 0.000 claims abstract description 17
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 16
- 239000011230 binding agent Substances 0.000 claims abstract description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000155 melt Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004411 aluminium Substances 0.000 claims abstract 2
- 238000007711 solidification Methods 0.000 claims description 21
- 230000008023 solidification Effects 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 229910052609 olivine Inorganic materials 0.000 claims description 9
- 239000010450 olivine Substances 0.000 claims description 9
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229910052863 mullite Inorganic materials 0.000 claims description 4
- 238000005299 abrasion Methods 0.000 claims description 2
- 239000011796 hollow space material Substances 0.000 claims 1
- 238000005058 metal casting Methods 0.000 claims 1
- 235000011121 sodium hydroxide Nutrition 0.000 claims 1
- MBDHLQKZIVIDEY-UHFFFAOYSA-N Olivin Natural products COc1cc(C=C(C)/C(=O)c2c(O)cc(O)cc2O)ccc1O MBDHLQKZIVIDEY-UHFFFAOYSA-N 0.000 abstract 1
- PIHTXGRVQBTVRE-KFYAXVMHSA-N olivin Chemical compound OC1=CC(O)=C2C(O)=C(C(=O)[C@H]([C@H]([C@H](OC)C(=O)[C@@H](O)[C@@H](C)O)C3)O)C3=CC2=C1 PIHTXGRVQBTVRE-KFYAXVMHSA-N 0.000 abstract 1
- 239000012778 molding material Substances 0.000 description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 239000006004 Quartz sand Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/18—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
- B22C1/186—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents contaming ammonium or metal silicates, silica sols
- B22C1/188—Alkali metal silicates
Definitions
- the invention relates to a molding material for the production of moldings for casting molds for casting molten metals, in particular light metal melts, such as cast aluminum melts. Moreover, the invention relates to moldings produced from such a molding material. Finally, the invention provides a method with which molded parts can be produced from molded materials according to the invention.
- quartz sand is usually used as a raw material of molded materials from which moldings, such as casting cores, are produced for casting molds. This sand is placed in advance in a mixer and mixed with a binder. The molding material obtained by this mixture is then injected into the mold cavity defining the shape of the molding to be produced. Subsequently, the solidification of the molding takes place in the mold. If an organic binder, for example synthetic resin-based binder, is used, a chemical reaction in the molding material injected into the molding tool is brought about.
- an organic binder for example synthetic resin-based binder
- an inorganic for example, water-glass-based binder
- heat is usually added to the molding material contained in the mold in order to bring about the solidification of the molded part to be produced by evaporation of the water contained in the molding material.
- quartz sand as a raw material for the production of moldings has proven itself in many ways, especially in the field of casting of light metal materials.
- quartz sand can be obtained inexpensively and is characterized by a simple processability and a good quality in the image of the mold elements of each mold part to be produced.
- JP-A-06 063683 discloses the use of Chromitsend, so a quartz-free sand, as a base form stoFP for moldings of Gie ⁇ formen.
- the object of the invention was to provide a molding material, which allows the cost-effective production of mold parts, in particular casting cores.
- low cost manufacturable molded parts and a method should be specified, which makes it possible to produce such moldings.
- this object is achieved in that such a molding material from a base material produced on the basis of olivine sand and a mixed with the molding base, based on Water glass produced inorganic binder is made.
- Olivine sand is a widespread mineral that is available in large quantities at low cost.
- molding materials which are produced according to the invention on the basis of a wholly or at least predominantly quartz-free olivine sands base material, even when properly bonded with a water glass binder from the finished casting.
- the remaining sand retention on the casting is reduced to a minimum. In this way, even when using Moldings made of novel moldings containing a water glass binder can be guaranteed to give sanding adherence-free castings.
- the molding material produced on the basis of quartz-free olivine sand according to the invention creates the prerequisite for cost-effective production of castings.
- the outlay for sand removal is reduced compared with that which is obtained in the cleaning of cast parts which have been cast using molded parts produced from conventional, quartz-containing molding materials.
- the molding material used according to the invention can consist entirely of quartz-free olivine sand.
- One of the requirements of practice particularly well fulfilling molding composition is characterized in that it contains 1.5 to 3.0 wt .-% water glass.
- To improve the sand life of the molding material of the invention may contain 0.3 to 0.5 wt .-% sodium hydroxide solution.
- a molded part according to the invention for casting molds which is in particular a casting core, is produced from a molding material according to the invention.
- the advantageous effects achieved by using a molding material system based on the mixture of quartz-free sands and an inorganic water glass binder in the casting of light metal melts are independent of the process by which the respective molded parts, in particular casting cores, have been produced.
- moldings which are produced by mixing quartz-free sands according to the invention, in particular olivine sand precursors, with an inorganic binder can reliably produce molded parts which not only have a particularly high strength and image fidelity, but moreover have the property of to disintegrate without adhesion during the production of the castings. Decay promoting additives in the binder system are no longer required. Therefore, in the application of the invention, environmental stresses and hazards to the operator are avoided by escaping gases whose formation and unwanted spread can be minimized in conventional manufacturing only with great technical effort.
- the temperature of the molding box in the first stage of solidification should be 150 ° C to 200 ° C.
- the complete curing of the molding then adjusts safely when the exposure time of the microwave heating in the second phase of solidification is 2 - 5 minutes.
- the respective exposure time can be adjusted taking into account the complexity of the shaping so that at the end of the microwave treatment sufficient for the casting process final strength and dryness of the molding is guaranteed.
- a molding material has subsequently been produced by mixing the molding material with a waterglass binder.
- a proportion of sodium hydroxide solution has been added to the molding base to improve its durability.
- the mold base material thus composed contained 2.5% by weight of waterglass binder, 0.3% by weight of sodium hydroxide solution and the remainder the molding base material of the above-described composition.
- This molding material has been placed in the cavity of a preheated molding box which images the finished casting core. Due to the excellent flowability of the molding material while difficult-shaped, small-part mold elements of the cavity have been filled safely. This secure mold filling has also been supported by the fact that the mold box has already been subjected to negative pressure during the filling process. The negative pressure was 0.3 bar.
- the temperature of the mold box was 180 ° C when filling the molding material. At this temperature, after completion of the filling operation in the molding box, the molding material has been held for 30 seconds with still effective negative pressure. At this time formed in the area of the inner walls of the Mold box adjacent areas of the molding material, a solid outer shell. In this way, at the end of the completed in the mold box first stage of solidification, a molding was available, the strength was sufficient to be able to safely transport it in a microwave oven can.
- the molded article In the microwave oven, the molded article has been microwave heated for 3 minutes until it has reached a final strength sufficient for the casting insert.
- the casting core thus produced has then been placed in a casting mold, in which subsequently the melt produced from the aluminum casting alloy has been cast to the cylinder head to be produced.
- the casting core is automatically disintegrated into many small fragments due to the temperature influence of the casting heat and its due to the solidification of the casting mechanical stress, which could be easily removed after complete solidification of the casting.
Claims (11)
- Matière de moulage pour pièces de moulage de moules de coulage pour le coulage de masse fondue de métal, en particulier, de masse fondue de métaux légers, comme de la masse fondue d'aluminium, constituée d'un composant de base de moulage élaboré à partir de sable sans quartz et un liant inorganique élaboré à partir de silicate soluble et mélangé avec le composant de base de moulage, caractérisée en ce que le sable sans quartz est olivine.
- Matière de moulage, conformément à la revendication 1, caractérisée en ce que le composant de base de moulage contient une partie de mullite synthétique.
- Matière de moulage, conformément à l'une quelconque des revendications antérieures, caractérisée en ce que le silicate soluble offre un module de 3,3 - 2.
- Matière de moulage, conformément à l'une quelconque des revendications antérieures, caractérisée en ce qu'elle contient entre 1,5 et 3,0 de poids en % de silicate soluble.
- Matière de moulage, conformément à l'une quelconque des revendications antérieures, caractérisée en ce qu'elle contient entre 0,3 et 0,5 du poids en % d'hydroxyde sodique liquide.
- Pièce de moulage pour des moules de coulage, en particulier pour des noyaux de coulage, constituée d'une matière de moulage composée, conformément à l'une quelconque des revendications antérieures.
- Procédé pour l'élaboration d'une pièce de moulage pour des moules de coulage, en particulier, pour l'élaboration de noyaux de coulage, en incluant les phases de travail suivantes :- Elaboration d'une matière de moulage fournie, conformément à l'une quelconque des revendications 1 à 6,- Conditionnement de la matière de moulage dans une cavité représentée par la pièce de moulage d'une boîte de moulage trempée,- Solidification de la matière de moulage en deux phases,- Comme conséquence de celle-ci, lors de la première phase de solidification, la matière de moulage sera maintenue dans la boîte de moulage trempée, jusqu'à la création d'une couche de bord de la pièce de moulage résistante à l'usure; et- Une fois ceci réalisé, par la suite, la pièce de moulage sera extraite de la boîte de moulage et celle-ci terminera son durcissement sous l'effet d'une radiation de micro-ondes.
- Procédé, conformément à la revendication 7, caractérisé en ce que la matière de moulage, pendant la première phase de la solidification, est maintenue sous pression.
- Procédé, conformément à l'une quelconque des revendications 7 ou 8, caractérisé en ce que la température de la boîte de moulage, dans la première phase de la solidification, est de 150 - 200° C.
- Procédé, conformément à l'une quelconque des revendications 7 à 9, caractérisé en ce que la première phase de solidification a une durée de 10 à 50 secondes.
- Procédé, conformément à l'une quelconque des revendications 7 à 10, caractérisé en ce que la période l'action de la radiation de micro-ondes, dans la deuxième phase de solidification, a une durée de 2 à 5 minutes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL04731830T PL1620216T3 (pl) | 2003-05-09 | 2004-05-08 | Tworzywo do formowania, element formowany i sposób wytwarzania elementów formowanych stosowanych w formie odlewniczej |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10321106A DE10321106A1 (de) | 2003-05-09 | 2003-05-09 | Formstoff, Formteil und Verfahren zur Herstellung von Formteilen für eine Gießform |
PCT/EP2004/004936 WO2004098811A1 (fr) | 2003-05-09 | 2004-05-08 | Matiere a mouler, piece moulee et procede de fabrication de pieces moulees pour un moule |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1620216A1 EP1620216A1 (fr) | 2006-02-01 |
EP1620216B1 true EP1620216B1 (fr) | 2006-06-21 |
Family
ID=33426732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04731830A Expired - Lifetime EP1620216B1 (fr) | 2003-05-09 | 2004-05-08 | Matiere a mouler, piece moulee et procede de fabrication de pieces moulees pour un moule |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1620216B1 (fr) |
AT (1) | ATE330733T1 (fr) |
AU (1) | AU2004235962A1 (fr) |
DE (2) | DE10321106A1 (fr) |
ES (1) | ES2267068T3 (fr) |
MX (1) | MXPA05011996A (fr) |
PL (1) | PL1620216T3 (fr) |
WO (1) | WO2004098811A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014221994A1 (de) * | 2014-10-29 | 2016-05-04 | Bayerische Motoren Werke Aktiengesellschaft | Herstellen und Bearbeiten von Gussteilen |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2163328A1 (fr) | 2008-09-05 | 2010-03-17 | Minelco GmbH | Sable de noyau ou de moule revêtu par et/ou mélangés avec des silicates de potassium ayant une teneur en eau comprise entre environ 0,25 poids -% jusqu'à environ 0,9 poids -% |
CN105658352B (zh) | 2013-10-19 | 2018-04-20 | 皮克德国有限公司 | 制造用于生产铸造件的失芯或模制件方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2322667A (en) * | 1942-07-31 | 1943-06-22 | Westinghouse Electric & Mfg Co | Mold and mold composition |
GB1042659A (en) * | 1964-10-29 | 1966-09-14 | Thaelmann Schwermaschbau Veb | Method of making foundry moulds |
JPS58107250A (ja) * | 1981-12-21 | 1983-06-25 | Komatsu Ltd | マイクロ波加熱硬化鋳型用中子の製造方法 |
DE3841473A1 (de) * | 1988-12-09 | 1990-06-13 | Heinze Gerald | Formsand fuer giessereizwecke |
JPH0663683A (ja) * | 1992-08-18 | 1994-03-08 | Mitsubishi Heavy Ind Ltd | 鋳型の製造方法 |
JP2918180B2 (ja) * | 1994-10-13 | 1999-07-12 | ゲオルグ フィッチャー ディサ アクツイエセルスカプ | 鋳型および中子製造のための破砕されたかつグレード化された鉱石、好ましくは磁鉄鉱鉱石の使用 |
EP1043094B1 (fr) * | 1999-04-09 | 2008-12-24 | SHERA-Werkstofftechnologie GmbH & Co.KG | Procédé de fabrication de pièces coulée |
JP3204653B2 (ja) * | 1999-11-08 | 2001-09-04 | ファー・アー・ヴェー アルミニウム アクチェンゲゼルシャフト | 鋳造中子製造用水ガラス基バインダー |
WO2003024642A1 (fr) * | 2001-09-14 | 2003-03-27 | Hydro Aluminium Deutschland Gmbh | Procede de realisation de pieces moulees, sable de coulee, et son utilisation pour la mise en oeuvre du procede |
-
2003
- 2003-05-09 DE DE10321106A patent/DE10321106A1/de not_active Ceased
-
2004
- 2004-05-08 DE DE502004000846T patent/DE502004000846D1/de not_active Expired - Fee Related
- 2004-05-08 PL PL04731830T patent/PL1620216T3/pl unknown
- 2004-05-08 WO PCT/EP2004/004936 patent/WO2004098811A1/fr active IP Right Grant
- 2004-05-08 AU AU2004235962A patent/AU2004235962A1/en not_active Abandoned
- 2004-05-08 ES ES04731830T patent/ES2267068T3/es not_active Expired - Lifetime
- 2004-05-08 AT AT04731830T patent/ATE330733T1/de not_active IP Right Cessation
- 2004-05-08 MX MXPA05011996A patent/MXPA05011996A/es unknown
- 2004-05-08 EP EP04731830A patent/EP1620216B1/fr not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014221994A1 (de) * | 2014-10-29 | 2016-05-04 | Bayerische Motoren Werke Aktiengesellschaft | Herstellen und Bearbeiten von Gussteilen |
DE102014221994B4 (de) | 2014-10-29 | 2023-03-30 | Bayerische Motoren Werke Aktiengesellschaft | Herstellen und Bearbeiten von Gussteilen |
Also Published As
Publication number | Publication date |
---|---|
DE10321106A1 (de) | 2004-12-23 |
WO2004098811A1 (fr) | 2004-11-18 |
ES2267068T3 (es) | 2007-03-01 |
AU2004235962A1 (en) | 2004-11-18 |
MXPA05011996A (es) | 2006-02-02 |
ATE330733T1 (de) | 2006-07-15 |
EP1620216A1 (fr) | 2006-02-01 |
PL1620216T3 (pl) | 2006-11-30 |
DE502004000846D1 (de) | 2006-08-03 |
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