EP1587658A2 - Procede permettant de fabriquer des panneaux de portiere - Google Patents

Procede permettant de fabriquer des panneaux de portiere

Info

Publication number
EP1587658A2
EP1587658A2 EP04702160A EP04702160A EP1587658A2 EP 1587658 A2 EP1587658 A2 EP 1587658A2 EP 04702160 A EP04702160 A EP 04702160A EP 04702160 A EP04702160 A EP 04702160A EP 1587658 A2 EP1587658 A2 EP 1587658A2
Authority
EP
European Patent Office
Prior art keywords
energy
absorbing component
foam
substrate
absorbing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04702160A
Other languages
German (de)
English (en)
Inventor
Myron J. Maurer
Steve J. Rogers
Martin H. Tusim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of EP1587658A2 publication Critical patent/EP1587658A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/04—Padded linings for the vehicle interior ; Energy absorbing structures associated with padded or non-padded linings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/18—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/34—Feeding the material to the mould or the compression means
    • B29C2043/3433—Feeding the material to the mould or the compression means using dispensing heads, e.g. extruders, placed over or apart from the moulds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/26—Scrap or recycled material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3005—Body finishings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3005—Body finishings
    • B29L2031/3014—Door linings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/04—Padded linings for the vehicle interior ; Energy absorbing structures associated with padded or non-padded linings
    • B60R2021/0414—Padded linings for the vehicle interior ; Energy absorbing structures associated with padded or non-padded linings using energy absorbing ribs

Definitions

  • This invention relates to methods of making composite panels containing an energy absorbing component.
  • many automotive parts include a passive energy absorbing countermeasure. Examples of such standards in the United States include Federal Motor Vehicle Safety (FMVSS) 201U— Occupant Head Impact Protection, FMVSS 208— Occupant Knee Impact Protection and FMVSS 214 — Occupant Side Impact Protection.
  • FMVSS Federal Motor Vehicle Safety
  • the energy absorbing countermeasure absorbs energy upon impact during a collision, thereby reducing injury to vehicle occupants and often reducing damage to the vehicle or other property.
  • automotive parts are pillars, door trim panels, knee bolsters and fascia, among others.
  • these parts include, in addition to the energy-absorbing countermeasure layer, a relatively rigid substrate material that provides overall shape and structural support. Sometimes, the part will also include a show surface such as a polymeric skin. In addition to providing personal injury protection, these parts are designed to meet various other functional and aesthetic needs. Thus the parts are often complex in design and construction.
  • these parts are increasingly made from a structural plastic material such as a thermoplastic olefin (TPO) or polypropylene (PP), although in some cases other polymers and thermoset materials can be used.
  • TPO thermoplastic olefin
  • PP polypropylene
  • the energy-absorbing countermeasure is typically a polyurethane foam, expanded polypropylene bead foam, or a structural thermoplastic component such as a ribbed cartridge.
  • a common process for making the parts is to mold the substrate material into the required shape.
  • the energy absorbing countermeasure is produced and shaped separately, usually in multiple foam expansion and secondary tooling steps (as in a steam chest mold), and is affixed to the substrate material using a hot melt or other form of an adhesive.
  • the vinyl sheet may be a thin foam laminate.
  • a soft foam having a specified density may be affixed to the plastic sheet using an adhesive prior to injecting the foamable composition, in order to provide localized cushioning for an interior arm rest for a vehicle door.
  • a process whereby they can be produced simply at low cost is desired.
  • This invention is a method of making a shaped part having an integrated energy-absorbing component, comprising (a) positioning a previously-formed thermoplastic energy-absorbing component into a mold; (b) introducing a molten thermoplastic substrate polymer into the mold, and (c) molding the substrate polymer in the mold under conditions sufficient to form said thermoplastic polymer into a shaped substrate and to adhere the thermoplastic energy-absorbing component to said substrate while substantially retaining the structure of the thermoplastic energy-absorbing component.
  • This process provides a simplified and inexpensive method of making shaped parts that include an energy-absorbing component. In this method, the substrate is molded and affixed to the energy-absorbing component in a single operation. This eliminates the need to adhere separately formed components together.
  • this invention in certain aspects allows for substantial reduction or even elimination of secondary tooling of the energy-absorbing component.
  • the thermoplastic energy-absorbing component can be shaped within the mold at the same time the substrate polymer is molded. For that reason, it is not necessary to tool the energy-absorbing component into its final shape prior to forming the part. All that is necessary is that the energy-absorbing component be cut into appropriate dimensions for insertion into the mold. This greatly simplifies the preparation of the energy- absorbing component of the part.
  • Figures 1 and LA are cross-sectional schematics of an embodiment of the method of the invention.
  • Figure 2 is a cross-sectional view of an embodiment of a composite part made in accordance with the invention.
  • Figure 3 is an isometric view of an embodiment of an energy- absorbing component for use in the invention.
  • shaped composite parts having an integral energy- absorbing component are prepared.
  • the composite part contains at least two components: (1) a shaped thermoplastic substrate and (2) a thermoplastic energy- absorbing component.
  • the substrate is adhered to the thermoplastic energy- absorbing component without an intervening adhesive.
  • the composite part is formed in a suitable mold assembly.
  • the mold assembly typically will consist of two mold halves. One half (typically the so-called “male” or “core” half) will have a mold surface shaped to form one surface of the composite part. The other half (typically the “female” half) will similarly have a shaped mold surface that is shaped to form the other surface (typically a “show” surface) of the composite part.
  • the mold will also be adapted to hold a previously-formed thermoplastic energy-absorbing component, as described more below, into a desired position so that the energy-absorbing component is positioned and oriented in a desirable way in the finished composite part.
  • a suitable mold assembly is shown in Figures 1 and 1A.
  • mold assembly 10 is shown in an open position.
  • Mold half 1 has a shaped mold surface 6 that defines the shape of one surface of the composite part to be molded.
  • a previously-formed thermoplastic energy-absorbing component 3 (as shown, a polymer foam) is positioned within mold half 1. Molten thermoplastic substrate polymer 4 is injected into the mold over energy-absorbing component 3 and into mold half 1.
  • the mold assembly also includes mold half 2 having a shaped mold surface 7. Shaped mold surface 7 defines the exterior shape of the composite part that is to be formed.
  • Mold halves 1 and 2 move in the relative (to each other) directions indicated by arrows 13 and 14, respectively, to bring the filled mold assembly 10 into a closed position. Of course, one of the mold halves may be kept in a fixed position.
  • substrate polymer 4 has been shaped by the mold into a desired configuration to form shaped substrate 20.
  • Substrate 20 becomes adhered to energy-absorbing component 3, thereby forming a composite part.
  • No separate adhesive is required to adhere substrate 20 to energy-absorbing component 3.
  • substrate polymer 4 wets out the surface of energy- absorbing component 3 so that good adhesion is formed when the substrate polymer 4 hardens into substrate 20.
  • the embodiment shown in Figures 1 and LA includes various optional features.
  • energy-absorbing component 3 does not conform to the shape of surface 6 of mold half 1.
  • the energy-absorbing component itself may be shaped somewhat during the molding process, particularly in cases where the energy-absorbing component is a foam.
  • Figure 1A where the surface of energy-absorbing component 3 is shaped during the molding process to conform to the shape of interior surface 6 of mold half 1. It is often helpful to pre-heat the energy-absorbing component 3 prior to forming the composite part. This allows the energy-absorbing component to become more pliable and therefore more easily shaped in the mold. Preheating is of course performed such that the ability of the energy-absorbing component to absorb energy is not destroyed.
  • In-mold shaping of the energy-absorbing component represents a preferred manner of forming composite parts in which the energy- absorbing component must assume, a complex shape.
  • the in-mold shaping eliminates complex secondary toohng of the energy-absorbing component prior to forming the part. It is only necessary to cut the energy-absorbing component into the approximate dimensions that will be needed in the composite part.
  • Complex shaping is then achieved in the molding process. This allows regularly-shaped pieces of the energy- absorbing component (i.e., those having simple and preferably uniform cross- sections) to be used as starting materials in the molding process.
  • the energy-absorbing component forms an exterior surface of the shaped part, it is possible that it will not be shaped sufficiently during the molding process to conform to the surface of the mold. Resulting voids can be filled with the structural polymer during the molding process.
  • Another optional feature shown in Figures 1 and 1A is the use of previously-formed skin 5. Skins may be provided for many purposes, but are most often used for aesthetic reasons. As shown in Figures 1 and 1A, skiri 5 is placed into mold half 2 in contact with interior surface 7, and drawn into the mold such that it assumes approximately the three-dimensional features of interior mold surface 7. In this embodiment, skin 5 is separated from energy-absorbing component 3 by structural member 20 in the finished part. However, if desired, a skin can be placed on either or both sides of the composite part.
  • a skin can be placed in mold half 1 in contact with interior surface 6, to form a skin on the other side of the part, in contact with a surface of energy- absorbing component 3.
  • This can be instead of or in addition to skin 5 as shown in Figures 1 and 1A.
  • Molding conditions are selected to accomplish several things.
  • the substrate polymers must of course fill the empty portion of the mold cavity and be shaped into the desired configuration.
  • substantially preserved it is meant that the energy-absorbing component retains at least 50%, more preferably at least about 75%, more preferably at least about 85% of its original ability to absorb energy upon impact in at least one direction.
  • the energy- absorbing component is a foam, it retains at least 50%, more preferably at least about 75%, more preferably at least about 85% of its original volume in the composite part as it is demolded.
  • Cell collapse and/or compression may occur at the interface of the energy-absorbing component and the structural member (shown at 23 in Figures 1A and 2), at places where the energy-absorbing component contacts the surface of the mold cavity, and in areas where the energy- absorbing component is shaped during the molding process (such as areas 21 and 22 in Figures 1A and 2).
  • the mold assembly may or may not be heated. If the mold assembly is heated, either the mold temperature is kept below that temperature at which the energy-absorbing component will significantly distort or collapse (in the case of a foam), or else mold residence times are kept short enough that such distortion and/or collapse does not occur before the composite part is demolded and cooled. In all instances, before demolding the composite part, the mold is brought to a temperature below the hardening temperature of the structural polymer, so that the polymer hardens within the mold and can be demolded without significant distortion.
  • Clamp pressures are similarly chosen with the foregoing needs in mind. Clamp pressures are sufficient to shape the thermoplastic polymer into the desired shape while substantially preserving the ability of the energy-absorbing component to absorb energy.
  • the mold When a skin is applied, the mold is conveniently equipped with a vacuum assist to draw the skin against the corresponding internal surface of the mold.
  • the skin is preferably heated to an elevated temperature below its melting temperature to soften it and therefore enable it to more easily conform to the surface of the mold.
  • the process of the invention is readily adapted to being used in conjunction with various conventional molding processes, with minimal modification being needed other than to design the mold cavity to accommodate the energy-absorbing component.
  • Various extrusion, injection molding, injection compression, vacuum thermoforming, and compression molding techniques can be used, together with the corresponding equipment.
  • Low pressure melt compression molding techniques are particularly suitable.
  • the mold may be oriented vertically, such as in some injection compression molding processes.
  • the energy-absorbing component (1) is a thermoplastic; (2) is previously- formed (i.e., fabricated in a separate step prior to introduction into the mold to make the shaped part, and (3) contains gas-filled voids which provide at least a portion of its ability to absorb energy.
  • the energy-absorbing component advantageously has a compressive strength, in at least one direction, of no greater than about 150 psi (pounds per square inch) (1034 kPa) at 25% strain, more preferably no greater than about 125 psi (861 kPa) at 25% strain, even more preferably no greater than 100 psi (689 Pa) at 25% strain, and most preferably no greater than about 50 psi (345 kPa) at 25% strain, and at least about 10 psi (69 kPa) at 25% strain, as measured in accordance with ASTM D3575-93 (Suffix D).
  • a compressive strength in at least one direction, of no greater than about 150 psi (pounds per square inch) (1034 kPa) at 25% strain, more preferably no greater than about 125 psi (861 kPa) at 25% strain, even more preferably no greater than 100 psi (689 Pa) at 25% strain, and most preferably no greater than about 50 psi (3
  • the energy-absorbing component may be more or less isotropic, in that the compressive strength may be substantially the same in all directions (isotropic), or may have a significantly higher compressive strength in one direction than in other directions (anisotropic).
  • Anisotropic energy-absorbing components may have a compressive strength in one direction that is from 1.25, preferably from about 1.5, more preferably from about 2 to about 10 times the compressive strength in one or more other directions.
  • an aniostropic energy-absorbing component it is preferably oriented in the composite part in such a manner that the direction of maximum compressive strength is approximately aligned with the direction along which a cushioning effect is desired (i.e., that in which an impact is expected).
  • the direction of maximum strength of the energy absorbing component and the direction in which impact is expected should differ by less than 45°, preferably less than 30° and especially less than 15°.
  • Two suitable types of energy-absorbing components are polymer foams and modular energy- absorbing assemblies as described below.
  • Foam used as the energy-absorbing component is preferably substantially closed-celled, having a closed cell content of at least about 50%, more preferably of at least about 70%, even more preferably at least about 80% and most preferably at least about 85%.
  • Suitable foam energy-absorbing components desirably have a density of less than 20 pounds per cubic foot (320 kg/m 3 ), preferably from about 0.5 per cubic foot (pcf) (8 kg/m 3 ), more preferably from 1.0 pcf (16 kg/m 3 ), especially from 1.25 pcf (20 kg/m 3 ), most preferably from 1.5 pcf (24 kg/m 3 ), preferably to 12 pcf (192 kg/m 3 ), more preferably to 10 pounds per cubic foot (160 kg/m 3 ), and most preferably to 8 pounds per cubic foot (128 kg/m 3 ), prior to the insertion into the mold for forming the composite part.
  • foam energy-absorbing components may be made in an extrusion process such as is described, for example, in U. S. Patent Nos. 4,694,027 5,348,795; 5,527,573 and 5,567,742 to Park (all incorporated herein by reference), by a coalesced strand process as described in US 6,213,540 to Tusim et al. (also incorporated by reference), or via a bead-foam process, an example of which is described in US Patent No. 4,866,098 to Tusim (incorporated herein by reference).
  • extruded foam including coalesced strand foam types
  • expanded polypropylene bead foam are preferred foam types of energy-absorbing component.
  • the foam may be cut to a size and shape that approximates its final shape in the composite part and fits into the mold.
  • anisotropic foams of particular interest are coalesced strand foams of the type described in US Patent No. 6,213,540 to Tusim et al and US Patent No. 4,824,720, both incorporated herein by reference. These coalesced strand foams tend to be highly anisotropic, with the highest compressive strengths generally being observed in the extrusion direction.
  • those thermoplastic foams may be prepared by the extrusion foaming of a molten thermoplastic composition utilizing a die including a multiplicity of orifices.
  • the orifices are arranged such that contact between adjacent streams of the molten extrudate occurs during the foaming process and the contacting surfaces adhere to one another well enough to result in a unitary structure that does not strain delaminate under stresses encountered in preparing, shaping, and forming the foam product.
  • the coalesced strand foam may be a coextrudate comprising strands of two or more different densities:
  • the coalesced strand foam may include missing strands or designed voids, i.e., exhibit a profile or cross section transverse to the extrusion direction which is discontinuous.
  • Bead foams included foams prepared by heating blowing agent- impregnated thermoplastic beads such that they expand and adhere to form a foam structure.
  • the thermoplastic may be polystyrene, a polystyrene copolymer, such as a. styrene/polyphenylene oxide copolymer (commercially available as NorylTM, from GE Plastics. A commercial grade of a styrene/polyphenylene oxide bead foam copolymer is available as GECETTM from Huntsman Chemicals.
  • the thermoplastic may also be a polyolefm, such as a lightly crosslinked polyethylene.
  • Yet another suitable foam energy-absorbing component is a composite foam structure comprising a first segment of an extruded, preferably anisotropic thermoplastic foam (such as described above) and a second segment shaped foam of a part comprising an isotropic foam wherein the first foa segment and second, isotropic foam part intersect along at least one common surface.
  • the first foam segment is an anisotropic foam that comprises a plurality of extruded strands of foam which are fused together wherein all of the strands of the foam are oriented in the same direction.
  • the second foam segment is preferably a bead foam.
  • Such composite foam structures are described, for example, in WO 04/003064, which is incorporated herein by reference.
  • Alternative energy-absorbing components include a modular energy absorbing assembly comprising a base having a plurality of separated recesses, and an overlay which covers the openings to the recesses.
  • the recesses each have a floor and walls extending from the base to the floor to form, together with the overlay, a plurality of gas-filled enclosed spaces. The walls are deformable such that the recesses are at least partially compressed during energy absorption.
  • Suitable base components of such a modular energy absorbing assembly are described in U. S. Patent No. 6,247,745 to Carroll III et al., incorporated herein by reference.
  • the overlay is typically a thermoplastic sheet or film that is adhered to the base through a twin sheet thermoforming, blow molding or melt adhesion process. An embodiment of such a modular energy- absorbing assembly is shown in
  • modular energy-absorbing assembly 30 includes base 31 having a plurality of recesses 32.
  • Recesses 32 each include a floor 34 and walls 33.
  • Recesses 32 are each open to the (as shown) bottom of base 31.
  • Overlay 35 is adhered to the bottom of base 31, covering the openings of each of recesses 32 to form a gas-filled enclosed space defined by each recess 32.
  • the walls of adjacent recesses 32 can be connected by support members 36 to provide increased stability and rigidity.
  • modular energy-absorbing assembly 30 is oriented in the shaped part such that floors 34 are substantially perpendicular to the expected direction of impact, and the walls 33 are inclined at an angle of from about 0 to about 45 degrees from such expected direction of impact.
  • a second overlay similar to overlay 35 may be positioned at the top (in the orientation shown in Fig. 3) of the modular energy-absorbing assembly, such second overlay being affixed (directly or indirectly) to the floors of the recesses.
  • energy-absorbing, gas-filled enclosed spaces are defined by base 31, the second overlay, and the exterior walls 33 of recesses 32.
  • thermoplastic polymer Both the energy-absorbing component and the substrate are made from a thermoplastic polymer.
  • Suitable thermoplastics include polyolefins such as low density polyethylene (LLDE), high density polyethylene (HDPE), so-called “substantially linear” polyethylene, polypropylene, and co-polymers of ethylene or propylene and one or more copolymerizable monoethylenically unsaturated monomers.
  • polyethylenes examples include low density polyethylene homopolymers and substantially linear ethylenic polymers having a melt flow ratio, I10/I2, greater than or equal to about 5.63, a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn ⁇ (I ⁇ o/l2)-4.63, and a critical shear rate at onset of surface melt fracture of at least 50% greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I2 and Mw/Mn.
  • substantially linear ethylenic polymers as set forth above are described in U.S. Patent Nos. 5,340,840 and 5,272,236, which are hereby incorporated by reference.
  • Preferred polyolefins other than the polyethylenes include polypropylene homopolymers and copolymers of polypropylene that are comprised of at least about 50% polymerized propylene by weight.
  • Other suitable polyolefins include branched polypropylene homopolymers and branched copolymers of polypropylene.
  • copolymers examples include copolymers of ethylene and acrylic acid, methylacrylic acid or C ⁇ -4 alkyl esters; ethylene vinyl- acetate copolymers; ethylene/carbon monoxide copolymers; copolymers of ethylene and an alpha-olefin having ultra low molecular weight (i.e., densities less than 0.92 g/cc); and blends of two or more of the above resins.
  • Suitable polypropylene polymers are described in U. S. Patent Nos. 4,916,198 and 5,554,668.
  • Commercially available polypropylenes that are useful include INSPIRETM C702-20 and C703-35U polypropylene resins, available from The Dow Chemical Company.
  • TPO thermoplastic polyolefin
  • suitable TPOs include those described in US Patent No. 5,861,463 to Sehanobish et al., incorporated herein by reference.
  • TPOs are blends of polypropylene polymer, a modifier, and optionally fillers and other compounding ingredients.
  • TPOs are multiphase polymer blends where the polypropylene polymer forms a continuous matrix phase and the modifier and fillers are the dispersed components.
  • the polypropylene matrix imparts tensile strength and chemical resistance to the TPO while the modifier imparts flexibility and impact resistance.
  • the TPO may contain a compatibilizer to compatibilize the polypropylene polymer and modifier phases, such as an ethylene-propylene copolymer as described in US Patent No.' 6,245,856 to Kaufman et al.
  • the polypropylene polymer phase of the TPO preferably has a relatively high melt flow rate (MFR), such as from about 20 to 100, with a MFR of 35 to 70 being preferred.
  • MFR melt flow rate
  • the polypropylene polymer component will typically comprise 50 to 88 weight percent of the TPO with a polypropylene content of 65 to 75 weight percent being preferred.
  • the modifier will typically have a melting point lower than that of the polypropylene polymer, and preferably has a melting point below about 125°C.
  • the modifier is suitably an ethylene-propylene copolymer, ethylene-propylene-diene terpolymer, other ethylene-alpha olefin copolymers such as ethylene-butene and ethylene-octene copolymers.
  • suitable ethylene type resin modifiers include medium density polyethylene (MDPE), high density polyethylene (HDPE) (for example, those made using Ziegler catalysts as in U.S. Pat. No. 4,076,698), ethylene/ester copolymers, ethylene/vinyl acetate copolymers, copolymers of ethylene and ethylenically unsaturated carboxylic acids, homopolymers and copolymers of ⁇ -ethylenics, etc.
  • MDPE medium density polyethylene
  • HDPE high density polyethylene
  • ethylene/ester copolymers ethylene/vinyl acetate copolymers
  • the polyethylene type resin modifiers are comprised primarily of ethylene monomeric units, and more preferably are comprised of at least 80% ethylene monomeric units by weight.
  • preferred polyethylene type resin modifiers include low density polyethylene homopolymers and substantially linear ethylenic polymers having a melt flow ratio, I10/I2, greater than or equal to about 5.63, a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn ⁇ (I ⁇ o/l2)-4.63, and a critical shear rate at onset of surface melt fracture of at least 50% greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I2 and Mw/Mn.
  • polyethylene type resin modifiers are homogeneously branched substantially linear ethylene/ ⁇ -olefin interpolymers having a density from about 0.89 g/cc to about 0.92 g/cc, a molecular weight distribution (M w /M n ) from about 1.8 to about 2.8, a melt index (I2) from about 0.001 grams/10 minutes to about 10 grams/10 minutes, no high density fraction, a single melting peak as measured using differential scanning colorimetry, a critical shear stress at onset of gross melt fracture greater than 4 X 10 6 dynes/cm 2 , and a slope of strain hardening coefficient from 1.3 to 2.3.
  • thermoplastic used as the substrate polymer or in the energy-absorbing component may also be an alkenyl aromatic polymer, such as polystyrene or copolymer of styrene and a copolymerizable monomer.
  • alkenyl aromatic polymer such as polystyrene or copolymer of styrene and a copolymerizable monomer.
  • suitable thermoplastics include polyesters, polyamides, polyvinylchloride, polyvinylidene chloride and polycarbonates.
  • the energy-absorbing component and the substrate be of the same material, or else be made of polymers that are classified as the same for recychng purposes. This allows scrap from both the substrate and the energy-absorbing components to be recycled together, thus eliminating the need to disassemble the shaped part and segregate the different materials. Similarly, defective parts can be recycled easily without separating them into their constituent components. The shaped panel is recycled easily at the end. of its useful life, as it is unnecessary to delaminate. the various components in order to segregate them for separate recychng.
  • the energy-absorbing component and the substrate polymer are each the same and are each polypropylene or TPO.
  • the substrate, the energy- absorbing component, or both may contain various additives such as fillers, reinforcing agents, colorants, antioxidants, preservatives, flame retardants, slip agents, lubricants, mold release agents, and the like.
  • the substrate is typically relatively stiff (due to polymer selection, density, thickness and/or design) compared with the energy-absorbing component and thus provides rigidity to the composite part.
  • the substrate polymer may contain a blowing agent that generates a gas under the conditions of the molding process. This can help the substrate polymer to completely fill the mold and reduce overall part weight somewhat. In such cases, the molded substrate will have a reduced bulk density, compared to that of the unfbamed substrate polymer, and will usually be somewhat cellular.
  • the density of the substrate is preferably at least 10, more preferably at least 25, even more preferably at least about 35 pounds per cubic foot, and in any case is higher than that of any foam that is used as the energy-absorbing component.
  • the optional skin can be any of a wide variety of materials, such as leather, carpeting, synthetic leather, a vinyl sheet or foam-backed vinyl (such as described in US 5,571,355 and 6,213,540, for example).
  • the skin material most preferably is a film and/or sheet of the same polymer as the energy-absorbing component (or one classified the same as for recychng purposes), the substrate, or, most preferably, both.
  • a most preferred skin material is a TPO or polypropylene sheet, especially a slush molded TPO or polypropylene sheet.
  • composite part 25 comprises energy absorbing component 3, substrate 20 and optional skin 5.
  • the energy absorbing component 3 is affixed directly to substrate 20 along interface 23, without any intervening adhesive layer.
  • substrate 20 is affixed directly to skin 5 along interface 26, again without intervening adhesive layer.
  • Skin 5 has an exposed surface 24 that in many embodiments will be the exposed (show) surface of the part.
  • energy absorbing component 3 has been shaped during the molding process, forming regions 21 and 22 where the energy absorbing component has been densified somewhat in the molding process.
  • a thermoplastic energy-absorbing component preferably will have a thickness (greatest distance in the shortest dimension) of at least 5 millimeters, preferably at least about 10 milhmeters, even more preferably at least about 13 millimeters, to about 200 mil meters, especially to about 150 mil meters.
  • the thickness of the substrate will depend largely on the form and function of the composite part. Most typically, the function of the substrate will be to provide a rigid layer through which the composite can be attached to the vehicle, and through which other parts can be assembled, and in some cases to provide a smooth backing for a show layer.
  • Any skin that may be present is typically from about 1 mm to as much as 50 mm in thickness, but skin thickness usually will not exceed about 5 mm.
  • the part may contain multiple sections of energy-absorbing component, which may be contiguous or separated.
  • the substrate may consist of multiple segments that also can be contiguous or separated.
  • An example of this is a sandwich structure, in which substrate sections are molded on either side of the energy-absorbing component.
  • the substrate may wholly or partially encapsulate the energy-absorbing component.
  • a skin can be provided on either or both sides of the part, and in particular may be applied directly over all or a portion of the energy-absorbing component. To achieve good adhesion, it is usually necessary to employ a heated mold so as to soften the surface of the energy-absorbing component and/or the skin to cause one or both of them to become tacky and adhere to the other. Alternatively, the skin can be pre-heated before being inserted into the mold, until it becomes slightly tacky.
  • a reinforcing layer can be incorporated into the substrate, for example by laying a reinforcing material into the mold prior to injecting the structural polymer.
  • a suitable method of incorporating a reinforcing mat is described in US
  • the foam may also incorporate a reinforcing material, if desired.
  • carpet can be vacuum-drawn into the mold and used in place of a skin to form a carpet-covered part.
  • Wood or synthetic wood, leather or synthetic leather or other show surfaces can be applied using the process, by appropriately inserting the materials into the mold prior to molding.
  • the parts will often contain specialized features to meet performance and/or assembly requirements for their particular applications.
  • the parts may be formed with bolsters; cut-outs for features such as door handles, audio speakers, controls, air bags and the like; various fasteners for attachment to a vehicle or other vehicular parts; additional features such as arm rests; and the like.
  • These features can be incorporated into the part through appropriate mold design, including these components into the molding process (as described, for example, in US 5,397,409 and 5,171,419, for example) or by post-molding assembly.
  • Shaped composite parts for automotive applications preferably satisfy one or more of Federal Motor Vehicle Safety (FMVSS) 201U— Occupant Head ' lmpact Protection, FMVSS 208— -Occupant Knee Impact Protection and FMVSS 214— Occupant Side Impact Protection standards.
  • FMVSS Federal Motor Vehicle Safety

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Selon l'invention, pour fabriquer des parties structurelles composites, telles que des parties amortisseuses d'automobile, on insère un composant amortisseur thermoplastique dans un moule, on injecte un substrat polymère dans le moule et on moule le composant amortisseur et le substrat polymère pour former un composite dans lequel le substrat polymère est fixé au composant amortisseur sans utiliser d'adhésif intermédiaire. La structure du composant amortisseur est sensiblement conservée. Les parties sont fabriquées sans outillage de mousse secondaire et peuvent, par conséquent, être produites à bas prix. Dans des modes de réalisation préférés, le substrat polymère et le composant amortisseur sont constitués du même matériau polymère ou de différents matériaux polymères qui ont la même classification à des fins de recyclage. Il est ainsi possible de recycler les parties mises au rebut, usées et endommagées, sans qu'il soit nécessaire de séparer leurs parties constituantes.
EP04702160A 2003-01-17 2004-01-14 Procede permettant de fabriquer des panneaux de portiere Withdrawn EP1587658A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US44105103P 2003-01-17 2003-01-17
US441051P 2003-01-17
PCT/US2004/000845 WO2004067304A2 (fr) 2003-01-17 2004-01-14 Procede permettant de fabriquer des panneaux de portiere

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EP1587658A2 true EP1587658A2 (fr) 2005-10-26

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WO (1) WO2004067304A2 (fr)

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US7043815B2 (en) 2002-01-25 2006-05-16 L & L Products, Inc. Method for applying flowable materials
GB0402221D0 (en) 2004-02-02 2004-03-03 L & L Products Inc Improvements in or relating to composite materials
GB201207481D0 (en) 2012-04-26 2012-06-13 Zephyros Inc Applying flowable materials to synthetic substrates
IT201600132402A1 (it) * 2016-12-29 2018-06-29 Aipol S P A Metodo di formatura di un semilavorato composito con cuoio o pelle e relativo semilavorato

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GB2216081A (en) * 1988-03-31 1989-10-04 Kasai Kogyo Kk Automotive accoustic insulation panel assemblies
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JPH0732384A (ja) 1993-04-26 1995-02-03 Atoma Internatl Inc 総合ボルスタを有するドアパネルの製造方法
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WO2004067304A3 (fr) 2004-11-18

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