EP1537271A2 - Formulation pour le rincage des textiles - Google Patents
Formulation pour le rincage des textilesInfo
- Publication number
- EP1537271A2 EP1537271A2 EP03769587A EP03769587A EP1537271A2 EP 1537271 A2 EP1537271 A2 EP 1537271A2 EP 03769587 A EP03769587 A EP 03769587A EP 03769587 A EP03769587 A EP 03769587A EP 1537271 A2 EP1537271 A2 EP 1537271A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- medium
- cationic
- mav
- active material
- rinsing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 135
- 238000009472 formulation Methods 0.000 title claims abstract description 121
- 239000004753 textile Substances 0.000 title claims abstract description 26
- 239000000835 fiber Substances 0.000 claims abstract description 22
- 239000007787 solid Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 229920000620 organic polymer Polymers 0.000 claims abstract description 9
- 239000002609 medium Substances 0.000 claims description 210
- 125000002091 cationic group Chemical group 0.000 claims description 105
- 239000011149 active material Substances 0.000 claims description 100
- -1 polydimethylsiloxane Polymers 0.000 claims description 67
- 125000000129 anionic group Chemical group 0.000 claims description 61
- 239000003795 chemical substances by application Substances 0.000 claims description 61
- 125000004432 carbon atom Chemical group C* 0.000 claims description 53
- 229920001282 polysaccharide Polymers 0.000 claims description 48
- 239000005017 polysaccharide Substances 0.000 claims description 48
- 229920000642 polymer Polymers 0.000 claims description 44
- 239000006185 dispersion Substances 0.000 claims description 41
- 239000000178 monomer Substances 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 230000007935 neutral effect Effects 0.000 claims description 27
- 239000003093 cationic surfactant Substances 0.000 claims description 24
- 229920001577 copolymer Polymers 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- 125000001424 substituent group Chemical group 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 238000006467 substitution reaction Methods 0.000 claims description 9
- 239000001993 wax Substances 0.000 claims description 9
- 239000004480 active ingredient Substances 0.000 claims description 8
- 238000010409 ironing Methods 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 125000003386 piperidinyl group Chemical group 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 235000013772 propylene glycol Nutrition 0.000 claims description 5
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 238000005299 abrasion Methods 0.000 claims description 4
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Substances OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 229920002310 Welan gum Polymers 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 150000003626 triacylglycerols Chemical class 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- AEEOFKKBJXCQIB-UHFFFAOYSA-N (1-carboxy-5-hydroxypentan-2-yl)-(3-hydroxypropyl)-dimethylazanium;chloride Chemical compound [Cl-].OCCC[N+](C)(C)C(CCCO)CC(O)=O AEEOFKKBJXCQIB-UHFFFAOYSA-N 0.000 claims description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims description 2
- SINIRESCLUKQMF-UHFFFAOYSA-N 3-[3-hydroxypropyl(dimethyl)azaniumyl]propanoate Chemical compound OCCC[N+](C)(C)CCC([O-])=O SINIRESCLUKQMF-UHFFFAOYSA-N 0.000 claims description 2
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- 229920000926 Galactomannan Polymers 0.000 claims description 2
- 229920002148 Gellan gum Polymers 0.000 claims description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 239000007844 bleaching agent Substances 0.000 claims description 2
- 150000005690 diesters Chemical class 0.000 claims description 2
- 239000002612 dispersion medium Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 230000001050 lubricating effect Effects 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920000193 polymethacrylate Polymers 0.000 claims description 2
- 239000001957 sucroglyceride Substances 0.000 claims description 2
- 235000010964 sucroglyceride Nutrition 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 150000004804 polysaccharides Chemical class 0.000 claims 15
- 125000001483 monosaccharide substituent group Chemical group 0.000 claims 6
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims 4
- OVBHZZFKQLQZCD-UHFFFAOYSA-N 2-carboxyethyl-(3-hydroxypropyl)-dimethylazanium;chloride Chemical compound [Cl-].OCCC[N+](C)(C)CCC(O)=O OVBHZZFKQLQZCD-UHFFFAOYSA-N 0.000 claims 1
- ZDVCCKMWQAEPIH-UHFFFAOYSA-N C[N+](C)(CCCO)C(CCCO)CC([O-])=O Chemical compound C[N+](C)(CCCO)C(CCCO)CC([O-])=O ZDVCCKMWQAEPIH-UHFFFAOYSA-N 0.000 claims 1
- 229920001586 anionic polysaccharide Polymers 0.000 claims 1
- 150000004836 anionic polysaccharides Chemical class 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 239000000216 gellan gum Substances 0.000 claims 1
- 235000010492 gellan gum Nutrition 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 abstract description 2
- 239000011368 organic material Substances 0.000 abstract description 2
- 150000004676 glycans Chemical class 0.000 description 33
- 150000003254 radicals Chemical class 0.000 description 22
- 238000005406 washing Methods 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000000839 emulsion Substances 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- 239000002243 precursor Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 238000010907 mechanical stirring Methods 0.000 description 8
- 244000303965 Cyamopsis psoralioides Species 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 7
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 6
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 6
- 150000002772 monosaccharides Chemical group 0.000 description 6
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 5
- 150000007942 carboxylates Chemical group 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Chemical group O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 4
- WQZGKKKJIJFFOK-DHVFOXMCSA-N L-galactose Chemical compound OC[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-DHVFOXMCSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- PNNNRSAQSRJVSB-BXKVDMCESA-N aldehydo-L-rhamnose Chemical compound C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O PNNNRSAQSRJVSB-BXKVDMCESA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000003373 anti-fouling effect Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- AEMOLEFTQBMNLQ-UHFFFAOYSA-N beta-D-galactopyranuronic acid Chemical group OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 150000002402 hexoses Chemical group 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000005375 organosiloxane group Chemical group 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 3
- SHZGCJCMOBCMKK-PQMKYFCFSA-N L-Fucose Natural products C[C@H]1O[C@H](O)[C@@H](O)[C@@H](O)[C@@H]1O SHZGCJCMOBCMKK-PQMKYFCFSA-N 0.000 description 3
- SHZGCJCMOBCMKK-DHVFOXMCSA-N L-fucopyranose Chemical group C[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-DHVFOXMCSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- AEMOLEFTQBMNLQ-DTEWXJGMSA-N D-Galacturonic acid Chemical group O[C@@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-DTEWXJGMSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- IAJILQKETJEXLJ-RSJOWCBRSA-N aldehydo-D-galacturonic acid Chemical group O=C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-RSJOWCBRSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- AEMOLEFTQBMNLQ-WAXACMCWSA-N alpha-D-glucuronic acid Chemical group O[C@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-WAXACMCWSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000005228 aryl sulfonate group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- AEMOLEFTQBMNLQ-YBSDWZGDSA-N d-mannuronic acid Chemical group O[C@@H]1O[C@@H](C(O)=O)[C@H](O)[C@@H](O)[C@H]1O AEMOLEFTQBMNLQ-YBSDWZGDSA-N 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 229930182830 galactose Natural products 0.000 description 2
- 229960003082 galactose Drugs 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 125000003010 ionic group Chemical group 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 150000002972 pentoses Chemical class 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- 238000010606 normalization Methods 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 102220206201 rs1057524801 Human genes 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GLFDLEXFOHUASB-UHFFFAOYSA-N trimethyl(tetradecyl)azanium Chemical compound CCCCCCCCCCCCCC[N+](C)(C)C GLFDLEXFOHUASB-UHFFFAOYSA-N 0.000 description 1
- VZTGWJFIMGVKSN-UHFFFAOYSA-O trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium Chemical compound CC(=C)C(=O)NCCC[N+](C)(C)C VZTGWJFIMGVKSN-UHFFFAOYSA-O 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3734—Cyclic silicones
Definitions
- the subject of the present invention is an improved formulation intended for rinsing articles of textile fibers, comprising a hydrophobic active material made of a particulate, liquid or solid organic or organosilicon material.
- US-A-4,818,242 describes an aqueous rinse aid for ironing, comprising a cationic silicone oil dispersed in water, a fatty acid and polyamine condensate, and a cationic film-forming agent.
- Patent US-A-4,923,622 proposes rinsing compositions comprising an emulsifiable concentrate containing cationic surfactants and an oil capable of exhibiting librifying properties with respect to the textiles to be treated, such as mineral oils and vegetable oils containing 8 with 22 carbon atoms, fatty acid esters.
- the Applicant has found that the addition, in a formulation comprising particles of insoluble organic or organosilicon hydrophobic active material, intended for rinsing articles of textile fibers, of a small amount of a suitably chosen soluble carrier agent of said active material , made it possible to significantly improve the deposition of particles on the surface of said articles, and thus to bring to said articles significant benefits, such as lubrication benefits, softness to the touch, anti-creasing properties and / or helps with ironing and / or antifouling, abrasion resistance.
- a first object of the invention consists of a formulation (F), intended to be used during a rinsing operation (R) of articles made of textile fibers (S) using an aqueous medium or hydroalcoholic (MR), said formulation (F)
- TAC cationic surfactant
- the formulation according to the invention is intended to be used both for carrying out a rinsing operation in a washing machine and for a rinsing operation by hand. This operation is usually carried out at a pH which can range from 5.5 to
- the rinse formulation is implemented on the last rinse.
- a dispersion of particles is considered to be stable, if no sedimentation, phase separation or evolution of turbidity is observed over time. This dispersion is destabilized when the particles aggregate together.
- the active material (A) is considered to be destabilized in the rinsing medium (MR) comprising the vector agent (V), when the size of the objects of the dispersion is at least twice that of the of the same objects in the absence of a vector agent (V).
- the active material (A) is made of an organic or organosilicon material, liquid or solid, in particulate form, insoluble in the medium (MAV), present in the medium (MAV) with a total cationic charge or zero, remains insoluble in the rinsing medium (MR).
- the material constituting the active material (A) is considered to be insoluble when less than 15%, preferably less than 10% of its weight, is soluble in the medium (MAV) and the rinsing medium (MR) .
- Said material constituting the active material (A) is in liquid or particulate solid form.
- it is in the form of an oil or a fusible solid (a wax for example).
- Said particles can have an average diameter ranging from 10 nm to
- 200 ⁇ m preferably from 10nm to 5 ⁇ m and more preferably from 10nm to
- the diameter of said particles can be determined in a well known manner by light scattering, by laser diffraction or by microscopic technique.
- the materials which can constitute the active material (A) mention may be made in particular of those having a lubricating action, capable of bringing lubrication properties to textile fiber articles, which can result in the provision of benefits such as softness, anti-crease, ironing aid, abrasion resistance, anti-fouling ...
- said material constituting active material (A) is an organosilicon material.
- Said polyorganosiloxane preferably has a dynamic viscosity measured at 25 ° C. and at a shear rate of 0.01 Hz for a stress of
- R are identical or different and represent an alkyl hydrocarbon radical, linear or branched, having from 1 to 4 carbon atoms, aryl, phenyl in particular;
- X are identical or different and represent a hydroxyl group, an alkoxy radical, linear or branched, having from 1 to 12 carbon atoms, an OCOR 1 function, where R 'represents an alkyl group containing from 1 to 12 atoms carbon, preferably 1 carbon atom;
- said polyorganosiloxane is at least substantially linear, and most preferably linear.
- ⁇ - ⁇ bis (hydroxy) polydimethylsiloxane oils ⁇ - ⁇ bis (trimethyl) polydimethylsiloxane oils
- cyclic polydimethylsiloxanes polymethylphenylsiloxanes.
- R are identical or different and represent a monovalent alkyl hydrocarbon radical, linear or branched, having from 1 to 4 carbon atoms, aryl, phenyl in particular;
- the symbols X are identical or different and represent a hydroxyl group, an alkoxy radical, linear or branched, having from 1 to 12 carbon atoms, an OCOR 'function, where R' represents an alkyl group containing from 1 to 12 atoms carbon, preferably 1 carbon atom;
- the symbols B are identical or different and represent an aliphatic and / or aromatic and / or cyclic hydrocarbon radical containing up to 30 carbon atoms, optionally interrupted by one or more heteroatoms of oxygen and / or nitrogen and / or sulfur, optionally carrying one or more ether, ester, thiol, hydroxyl, optionally quaternized amine, carboxylate functions, the symbol B being bonded to silicon preferably via an Si-C- bond;
- - c is equal to 1 or 2 - a + b + c is equal to 1, 2 or 3
- Organosiloxane units present alongside those of formula (II), are preferably nonionic and of formula (I) above.
- Organosiloxane units having one or more strong anionic functions, of the sulfonate or phosphonate type, may also be present, when the units of formula (II) are cationic or potentially cationic in the medium (MAV). They are however present in a limited number, so that said polyorganosiloxane presents in the medium (AVM) an overall cationic charge or zero.
- substituents corresponding to the symbol (B) in the formula (II) above there may be mentioned
- n is equal to 2 or 3
- m and p each go from 0 to 30 and R' represents an alkyl residue containing 1 with 12 carbon atoms, preferably e 1 to 4 carbon atoms.
- R 1 represents an alkylene group containing from 2 to 6 carbon atoms, optionally substituted or interrupted by one or more nitrogen or oxygen atoms,
- an amino alkyl group preferably primary, the alkyl group of which contains from 1 to 12 carbon atoms, preferably from 1 to 6 carbon atoms, optionally substituted and / or interrupted by at least one nitrogen atom and / or d oxygen, said amino group being optionally quaternized, for example by a hydrohalic acid or an alkyl or aryl halide.
- the polyorganosiloxanes carrying amino functions present in their chain, per 100 total silicon atoms, from 0.1 to
- R 4 is a divalent hydrocarbon radical chosen from:
- R 4 has the meaning indicated above
- R 5 and R 6 have the meanings indicated below and
- R 1 1 represents a divalent alkylene radical, linear or branched, having from 1 to 12 carbon atoms, one of the links valentials (that of R 1 1 ) being connected to the atom of -NR 10 -, the other (that of R 4 ) being connected to a atom of silicon;
- the radicals R 5 are identical or different, chosen from linear or branched alkyl radicals having 1 to 3 carbon atoms and the phenyl radical;
- radical R 6 represents a hydrogen radical or the radical R 5 or O.
- R ' 4 is chosen from a trivalent radical of formula:
- ⁇ co - or m represents a number from 2 to 20, and a trivalent radical of formula:
- said polyorganosiloxanes with an amino function are polyorganosiloxanes with a sterically hindered piperydinyl function, in particular those which can be prepared according to the process described in EP-A-659930.
- said polyorganosiloxane having a sterically hindered amino function is a linear, cyclic or three-dimensional polyorganosiloxane of formula (V):
- R 1 , R 2 and R 3 which are identical and / or different, represent a monovalent hydrocarbon radical chosen from linear or branched alkyl radicals having from 1 to 4 carbon atoms, linear or branched alkoxy radicals having from 1 to 4 carbon atoms, a phenyl radical and preferably a hydroxy radical, an ethoxy radical, a methoxy radical or a methyl radical;
- the number of rjSi units with a group B ranges from 1 to 5, preferably from 1 to 3;
- said polyorganosiloxane is linear.
- said material constituting active material (A) is an organic material.
- said material constituting active material (A) is an organic material.
- C1-C30 carboxylic acids or their mixtures such as vegetable oils (rapeseed, castor oil, sunflower oil, erucic rapeseed oil, linseed oil, etc.)
- sucroglycerides - C1-C30 alcoholesters of C1-C30 carboxylic or C 2 -C 30 dicarboxylic acids
- waxes comprising alkyl chains containing from 4 to 40 carbon atoms.
- the waxes there may be mentioned in particular:
- animal waxes (beeswax, lanolin, whale oil) “ vegetable waxes (carnauba, candellila, sugar cane wax, jojoba)
- hydrocarbon waxes comprising from 4 to 35 carbon atoms (mineral oils, paraffins, microcrystalline waxes) “ synthetic waxes such as polyolefins (polyethylene, polypropylene), sterone, carbowax.
- the active material (A) is placed in stable dispersion in the medium (MAV) using a surfactant (TAC).
- TAC surfactant
- Said surfactant can be a nonionic surfactant and / or a cationic surfactant when the material constituting the active material (A) is intrinsically cationic or intrinsically potentially cationic in the medium (MAV).
- Said surfactant (TAC) is a cationic surfactant or a mixture of cationic surfactant and nonionic surfactant when said material constituting the active material (A) is not charged or has a zero charge; the quantity of nonionic surfactant representing less than 70% of the weight of all the surfactants
- the mass ratio of polymer constituting the active material (A) / mass of surfactant (TAC) ranges from
- the cationic charges, generated by the possible cationic or potentially cationic functions of the active material (A) and by the cationic surfactant (s), on the surface of the active active material (A) dispersed in the medium (AVM), are such that the zeta potential of the active ingredient in dispersion in (MAV) is from 0 to +50 mV, preferably
- R, R and R similar or different, represent H or an alkyl group containing less than 4 carbon atoms, preferably 1 or 2 carbon atom (s), optionally substituted by one or more hydroxyl functions, or can form together with the nitrogen atom N + at least one aromatic or heterocyclic ring
- R represents a C8-C22, preferably C12-C22, alkyl or alkenyl group. an aryl or benzyl group, and
- X " is a solubilizing anion such as halide (for example chloride, bromide, iodide), sulfate or alkylsulfate (methylsulfate), carboxylate (acetate, propionate, benzoate), alkyl or arylsulfonate.
- halide for example chloride, bromide, iodide
- sulfate or alkylsulfate methylsulfate
- carboxylate acetate, propionate, benzoate
- alkyl or arylsulfonate alkyl or arylsulfonate.
- R and R represent H or an alkyl group containing less than 4 carbon atoms, preferably 1 or 2 carbon atom (s), optionally substituted by one or more hydroxyl functions, or may form together with the nitrogen atom N + a heterocyclic cycle
- R and R represent a C8-C22 alkyl or alkenyl group. preferably in C10-C22. an aryl or benzyl group, and .
- X " is an anion such as halide (for example chloride, bromide, iodide), sulfate or alkylsulfate (methylsulfate), carboxylate (acetate, propionate, benzoate), alkyl or arylsulfonate.
- dialkyldimethyl ammonium chlorides such as ditallow dimethyl ammonium chloride or methylsulfate, etc.
- alkylbenzyldimethylammonium chlorides alkylbenzyldimethylammonium chlorides.
- nonionic surfactants there may be mentioned polyoxyalkylenated derivatives such as
- the dispersion medium (AVM) of the active material (A) is an aqueous or hydroalcoholic polar medium.
- the alcohols which may be present can represent up to 70% of the volume of medium (MAV).
- the medium ( MAV) is water.
- the medium can be brought to the desired pH from 2 to 5 by addition of an acid, such as hydrochloric acid, citric acid, phosphoric acid, benzoic acid ...
- the rinse formulation (F) forming the subject of the invention comprises a carrier agent (V) capable of bringing the active material (A) to the surface of the textile fiber articles during the rinse operation.
- said vector agent (V) capable of bringing the active material (A) to the surface of the textile fiber articles during the rinse operation.
- • is capable of developing at the pH of the rinsing operation in the rinsing medium (MR) anionic charges in sufficient number to destabilize the active material (A) in the rinsing medium (MR).
- Said organic polymer constituting the vector agent (V) can be any polymer which is soluble or dispersible in an aqueous or hydroalcoholic medium with a pH between 2 and 8, comprising at least one unit which is neutral in the medium (MAV) and potentially anionic (HA) in the rinsing medium (MR).
- They can also comprise at least one cationic or potentially cationic unit (HC) in the medium (MAV) and / or at least one hydrophilic or hydrophobic nonionic unit.
- HC cationic or potentially cationic unit
- the term "dispersible” means that the vector agent (V) does not form a macroscopic precipitate in an aqueous or hydroalcoholic medium.
- the polymer constituting the carrier agent (V) is a copolymer comprising:
- the polymer constituting the carrier agent (V) may optionally contain anionic units (the first pKa of which is less than 3), but this in a very small amount, for example in an amount much less than 5% by weight relative to the 'all units.
- the relative amounts of the different units of the polymer constituting the carrier agent (V) are such that, in the medium (MAV), the overall charge of the polymer or copolymer is zero or cationic.
- the relative amounts of carrier agent polymer (V), cationic surfactant (TAC) and material constituting the active material (A), are such that during the rinsing operation, the number of anionic charges developed in the rinsing medium (MR) with the carrier agent polymer (V) is sufficient to destabilize the active material (A) in the rinsing medium (MR), in particular by electrostatic attraction with the surface charges of the active material (A ) in the middle (MR).
- the active material (A) is considered to be destabilized in the rinsing medium (MR) comprising the vector agent (V), when the turbidity of said medium reaches, in less than 5 minutes, a value at least 5 times greater than the turbidity that the same medium would have in the absence of carrier (V).
- the number of anionic charges developed in the rinsing medium (MR) by the carrier agent polymer (V) to destabilize the active material is preferably at least 1% relative to the number of cationic surface charges of the active material (A ) in the middle (MR). This number of anionic charges can range up to 200% relative to the number of cationic surface charges of the active material (A) in the medium (MR).
- polymers which can constitute the vector agent (V) mention may in particular be made of polymers derived from ethylenically unsaturated monomers, as well as native polysaccharides and substituted or modified polysaccharides, as well as mixtures of said polymers derived from ethylenically unsaturated monomers and said polysaccharides.
- polymer is used here to denote both a homopolymer and a copolymer.
- copolymer will be used when it is a polymer derived from at least two monomers of different type.
- a first example of a polymer which can constitute the vector agent (V), are the derived polymers:. at least one monoethylenically unsaturated ⁇ - ⁇ monomer, neutral in the medium (MAV) and potentially anionic (HA) in the rinsing medium (MR) and
- HC monoethylenically unsaturated, cationic or potentially cationic
- MAV medium
- (V) is a random, block or graft copolymer, derivative:
- HC monoethylenically unsaturated ⁇ - ⁇ hydrophilic monomer
- MAV medium
- hydrophilic or hydrophobic non-ionic monoethylenically unsaturated ⁇ - ⁇ monomer preferably hydrophilic.
- the average molar mass of said polymer or copolymer (V) derived from one or more monoethylenically unsaturated ⁇ - ⁇ monomers is greater than 5000 g / mol, generally on the order of 20,000 to 500,000 g / mol.
- monomers having at least one carboxylic function such as ⁇ - ⁇ ethylenically unsaturated carboxylic acids or the corresponding anhydrides, such as acrylic, methacrylic, maleic acids or anhydrides, fumaric acid, itaconic acid, N-methacroyl alanine, N- acryloylglycine and their water-soluble salts
- hydrophilic cationic or potentially cationic (HC) monoethylenically unsaturated ⁇ - ⁇ monomer in the medium there may be mentioned: • ammoniumacryloyl or acryloyloxy monomers such as trimethylammoniumpropylmethacrylate chloride, trimethylammoniumethylacrylamide chloride or methacrylamide, trimethylammoniumbutylacrylamide methylsulfate or methacrylamide, trimethylammoniumpropylmethacrylamide methylsulfate (MES), (3-methacrylamidopropyl) trimethylammonium chloride (MAPTAC), (3-acrylamidopropyl) trimethylammonium chloride, methyl chloride or methylethylchloride acryloyloxyethyl trimethylammonium chloride;
- ammoniumacryloyl or acryloyloxy monomers such as trimethylammoniumpropylmethacrylate chloride, trimethylammoniumethylacrylamide chloride or methacryl
- polyquaternary monomers such as dimethylaminopropylmethacrylamide chloride, N- (3-chloro-2-hydroxypropyl) trimethylammonium (DIQUAT) ...
- N, N (dialkylamino ⁇ alkyl) amides of monoethylenically unsaturated ⁇ - ⁇ carboxylic acids such as N, N-dimethylaminomethyl -acrylamide or -methacrylamide, 2 (N, N-dimethylamino) ethyl-acrylamide or -methacrylamide, 3 ( N, N-dimethylamino) propyl-acrylamide or
- monoethylenically unsaturated ⁇ - ⁇ aminoesters such as 2 (dimethyl amino) ethylmethacrylate (DMAM), 3 (dimethyl amino) propylmethacrylate, 2 (tertiobutylamino) ethyl methacrylate, 2 (dipentylamino) ethyl methacrylate,
- precursor monomers of amino functions such as N-vinyl formamide, N-vinyl acetamide, etc. which generate primary amine functions by simple acid or basic hydrolysis.
- monoethylenically unsaturated ⁇ - ⁇ monomers hydrophilic uncharged or non-ionizable. we can cite
- hydroxyalkyl esters of ⁇ - ⁇ ethylenically unsaturated acids such as hydroxyethyl and hydroxypropyl acrylates and methacrylates, glycerol monomethacrylate
- ⁇ - ⁇ ethylenically unsaturated amides such as acrylamide, N, N-dimethyl methacrylamide , N-methylolacrylamide ...
- the ethylenically unsaturated ⁇ - ⁇ monomers carrying a water-soluble polyoxyalkylenated segment of the polyethylene oxide type such as the polyethylene oxide ⁇ -methacrylates (BISOMER S20W, S10W, ... from LAPORTE) or ⁇ , ⁇ -dimethacrylates, the SIPOMER BEM de RHODIA
- hydrophobic nonionic monoethylenically unsaturated ⁇ - ⁇ monomers we can mention:
- vinylaromatic monomers such as styrene, vinyltoluene ...
- alkyl esters of monoethylenically unsaturated ⁇ - ⁇ acids such as methyl and ethyl acrylates and methacrylates, etc.
- monoethylenically unsaturated ⁇ - ⁇ nitriles such as acrylonitrile, etc.
- anionic hydrophilic monoethylenically unsaturated ⁇ - ⁇ monomer (the first pKa of which is less than 3)
- esters of ethylenically unsaturated phosphates such as the phosphates derived from hydroxyethyl methacrylate (Empicryl 6835 from RHODIA) and those derived from polyoxyalkylene methacrylates and their water-soluble salts
- phosphates derived from hydroxyethyl methacrylate Empicryl 6835 from RHODIA
- polyoxyalkylene methacrylates and their water-soluble salts As examples of polymers derived from ethylenically unsaturated monomers s constituents of the vector agent (V), we can mention:
- polyacrylic or polymethacrylic acids polyacrylates or polymethacrylates of alkali metals, preferably with a molar mass by weight of 100,000 to 1,000,000 g / mol • acrylic acid / DADMAC copolymers, with a molar ratio of 50/50 to 30/70 , preferably of molar mass by weight of 70,000 to 350,000 g / mol
- acrylic acid / MAPTAC copolymers with a molar ratio of 60/40 to 30/70, preferably with a molar mass by weight of 90,000 to 300,000 g / mol
- acrylic acid / MAPTAC / alkyl methacrylate terpolymers whose alkyl radical is linear in C -C 18 , terpolymers comprising from 0.005 to 10% by mass of alkyl methacrylate with an acid molar ratio acrylic / MAPTAC ranging from 60/40 to 30/70, and preferably having a molar mass by weight of 50,000 to 250,000 g / mol • acrylic acid / dimethylaminoethylmethacrylate (DMAEMA) copolymers, with molar ratio of 60/40 to 30 / 70, preferably of molar mass by weight of 50,000 to 300,000 g / mol
- DMAEMA dimethylaminoethylmethacrylate
- a second example of a polymer which can constitute the vector agent (V), are the potentially anionic native polysaccharides and the substituted or modified, potentially anionic or amphoteric polysaccharides.
- Potentially anionic native polysaccharides are formed from similar or different non-ionic monosaccharide units and monosaccharide neutral in the medium (AVM) and potentially anionic in the rinsing medium (MR). They can be linear or branched.
- said potentially anionic native polysaccharides are branched polysaccharides formed
- the hexose units (similar or different) of the main chain can be D-glucose, D- or L-galactose, D-mannose, D- or L- fucose, L-rhamnose ... units.
- the pentose and / or hexose units can be D-xylose ..., L- or D- units arabinose, D-glucose, D- or L-galactose, D-mannose, D- or L-fucose, L- rhamnose, D-glucuronic acid, D-galacturonic acid, D-mannuronic acid, D-mannose substituted by a group pyruvic, ...
- xanthan gums such as RHODOPOL® from RHODIA
- succinoglycans rhamsans
- gellan gums welan ...
- Their molar mass by weight can range from 2000 to 5,000,000, preferably from 10,000 to 5,000,000, most particularly from 10,000 to 4,000,000 g / mol.
- the molar mass by weight Mw of said polysaccharides can be measured by size exclusion chromatography.
- their native skeleton is formed of nonionic monosaccharide units and / or monosaccharide units neutral in the medium (AVM) and potentially anionic in the rinsing medium (MR) or different, said monosaccharide units being substituted or modified:
- Said substituted or modified polysaccharides may also contain at least one nonionic substituent or modifying group.
- • and of branches comprising at least one anhydropentose and / or anhydrohexose unit neutral in the medium (MAV) and possibly potentially anionic in the rinsing medium (MR), the anhydrohexoses and / or anhydropentoses units of said polysaccharide being substituted or modified by one or groups carrying at least one neutral charge in the medium (MAV) and potentially anionic in the medium (MR) and optionally at least one cationic or potentially cationic charge in the medium (MAV), the degree of substitution or modification DSi of the anhydrohexoses and / or anhydropentoses units by all of said groups carrying ionic or potentially ionic charges ranging from 0.01 to less than 3, preferably from 0.01 to 2.5, with a ratio of number of potentially anionic charges in the medium (MR) to the number of cationic or potentially cationic charges in the medium (MAV) ranging from 100/0 to 30/70, preferably from 1 00/0 to 50/50.
- the ratio of the number of potentially anionic charges in the medium (MR) to the number of cationic or potentially cationic charges in the medium (AVM) ranges from 99.5 / 0.5 to 30/70, preferably from 99.5 / 0.5 to 50/50.
- Said substituted or modified branched polysaccharide may also contain at least one nonionic substituent or modifying group.
- the molar mass by weight of said substituted or modified polysaccharides can range from 2000 to 5,000,000, preferably from 10,000 to 5,000,000 g / mol.
- the molar mass by weight Mw of said polysaccharides can be measured by size exclusion chromatography.
- the measurement is carried out in water at pH 9-10 containing 0.1 M of LiCl and 2/10000 of nitrate of sodium.
- the measurement is carried out in an aqueous solution of 0.1 M in formic acid containing 0.05 M of sodium nitrate and 10 ppm of polyallyldimethylamine chloride of high molar mass (PDADMA) in the case of polysaccharides whose DSi in ionic or potentially ionic function is less than 0.5.
- PDADMA polyallyldimethylamine chloride of high molar mass
- an aqueous solution of 0.025 M in hydrochloric acid is used.
- the molar mass by weight Mw is established in a known manner directly via the light scattering values.
- the degree of substitution or modification DSi corresponds to the average number of hydroxyl functions of the anhydrohexose and / or anhydropentose units substituted or modified by said ionic or potentially ionic group (s), per anhydrohexose and / or anhydropentose unit.
- Said ionic or potentially ionic groups are linked to the carbon atoms of the sugar skeleton either directly or via -O- bonds.
- the potentially anionic charges can be provided by substituent or modifying groups different from those carrying cationic or potentially cationic charges; said polymer is then an ampholyte polysaccharide.
- substituent or modifying group carries both a potentially anionic charge and a cationic or potentially cationic charge; said polysaccharide is then of betaine type.
- Said substituted or modified polysaccharide may also have at least one nonionic substituent or modifying group.
- Said nonionic groups are linked to the carbon atoms of the sugar skeleton either directly or via -O- bonds. The presence of such groups is expressed in number of moles of substitution MS, that is to say in average number of moles of precursor of said nonionic substituent having reacted by anhydrohexose and / or anhydropentose unit.
- the degree of substitution or modification by all of the ionic or ionizable and nonionic groups is less than 3 by definition . If said precursor is capable of forming new reactive hydroxyl groups (hydroxyalkylation precursor for example), the number of moles of substitution MS is theoretically not limited; it can for example go up to 6, preferably up to 2.
- R is a hydrogen atom or an alkyl radical containing from 1 to 4 carbon atoms x is an integer ranging from 0 to 5 y is an integer ranging from 0 to 5 M represents an alkali metal
- cationic or potentially cationic groups mention may be made of those containing one or more amino, ammonium, phosphonium, pyridinium, etc. functions. Mention may in particular be made of cationic or potentially cationic groups of formula
- R is a hydrogen atom or an alkyl radical containing from 1 to 4 carbon atoms
- x is an integer ranging from 0 to 5.
- y is an integer ranging from 0 to 5
- R ' is an alkylene radical containing from 1 to 12 carbon atoms, optionally carrying one or more OH substituents
- radicals R " similar or different, represent a hydrogen atom, an alkyl radical containing from 1 to 18 carbon atoms.
- radicals R" ' similar or different, represent an alkyl radical containing from 1 to 18 carbon atoms
- R "" is a linear, branched or cyclic alkylene radical containing from 1 to 6 carbon atoms
- A represents O or NH.
- Y is a heterocyclic aliphatic group comprising from 5 to 20 carbon atoms and a nitrogen heteroatom
- X- is a counterion, preferably halide (chloride, bromide, iodide in particular), as well as the N-alkylpyridinium-yl groups in which the alkyl radical contains from 1 to 18 carbon atoms, with a counterion, preferably halide (chloride, bromide, iodide in particular).
- cationic or potentially cationic groups there may be mentioned very particularly: - those of formula -NH 2
- R represents CH3 or H.
- R 1 represents
- a hydrogen atom an alkyl radical containing from 1 to 22 carbon atoms optionally interrupted by one or more oxygen and / or nitrogen heteroatoms, cycloalkyl, aryl, arylalkyl, containing from 6 to 12 carbon atoms .
- a radical - (CH2) y-COOR 2 a radical - (CH2) y -CN.
- a radical - (CH 2 ) y -CONHR 2 R 2 representing an alkyl, aryl or arylalkyl radical containing from 1 to 22 carbon atoms, and y is an integer ranging from 0 to 5 • -CO-NH-R1
- R 1 having the definition given above, linked to a carbon atom of the sugar skeleton via an —O— bond Mention may very particularly be made of the groups
- the hexose units (similar or different) of the main chain of the native skeleton can be D-glucose, D- or L-galactose, D- mannose, D- or L-fucose, L-rhamnose ...
- the pentose and / or hexose units can be units D- xylose ..., L- or D-arabinose, D-glucose, D- or L-galactose, D-mannose, D- or L-fucose, L-rhamnose, D-glucuronic acid, D-galacturonic acid, D-mannuronic acid.
- a native skeleton we may mention gaiactomannans, galactoglucomannans, xyloglucans, xanthan gums, scleroglucans, succinoglycans, rhamsans, welan gums ...
- the native skeleton is a galactomannan.
- Gaiactomannans are macromolecules comprising a main chain of D-mannopyranose units linked in position ⁇ (1-4) substituted by D-galactopyranose units in position ⁇ (1-6).
- guar carob
- tara gums we can mention guar, carob, tara gums.
- the native skeleton is a guar gum. Guar gums have a mannose / galactose ratio of 2.
- the substituted or modified polysaccharides used according to the invention can be obtained by functionalization of the native skeleton using precursors of ionic or potentially ionic and possibly nonionic groups.
- the dispersion of the active material (A) in the medium (MAV) comprising the vector agent (V) has a pH ranging from 3 to 5 and in particular of 4.5 to 5 when said polysaccharide is a substituted or modified guar.
- the amount of carrier agent (V) present in the formulation according to the invention ranges from 0.001 to 5 parts by weight, preferably from 0.01 to 4 parts, very particularly from 0 0.05 to 2 parts by weight per 100 parts by weight of active material (A).
- the formulation (F) according to the invention can be presented
- Formulation (F), in the form of a stable dispersion, can be obtained by
- the aqueous or hydroalcoholic formulation (F) comprises per 100 parts of its weight:
- TAC cationic surfactant
- carrier polymer (V) from 0.001 to 4, preferably from 0.01 to 1 parts by dry weight of carrier polymer (V).
- Said dispersion can have a dry extract of 0.021 to 90%, preferably 0.07 to 51% by weight.
- Formulation (F), in the form of a solid, can be obtained by
- TAC surfactant
- the evaporation / drying step can be carried out by any means known to those skilled in the art, in particular by lyophilization (that is to say freezing, then sublimation) or preferably by spray drying.
- Spray drying can be carried out in any known device, such as an atomization tower associating a spraying carried out by a nozzle or a turbine with a stream of hot air.
- the conditions of implementation depend on the type of atomizer used; these conditions are generally such that the temperature of the entire product during drying is at least 30 ° C and does not exceed 150 ° C.
- the evaporation / drying step can be facilitated by the presence, within the dispersion subjected to said step, of a protective agent, in particular by the presence of at least one water-soluble ose, oside or polyholoside or water-dispersible, preferably a dare.
- a protective agent in particular by the presence of at least one water-soluble ose, oside or polyholoside or water-dispersible, preferably a dare.
- the amount of protective agent can represent on the order of 10 to 50 parts by weight per 100 parts by weight of active material (A).
- aldoses such as glucose, mannose, galactose, ribose and ketoses such as fructose.
- the granules obtained can be ground to obtain a powder or compacted in a known manner to obtain tablets, for example.
- the formulation (F) can also comprise other usual constituents of the cationic rinse formulations. It can in particular comprise at least one cationic and / or non-ionic softening agent, such as acyclic quaternary ammonium compounds, alkoxylated polyamines, diamido quaternary ammonium salts, quaternary ammonium esters, imidazolium quaternary salts, primary, secondary amines or tertiary, alkoxylated amines, cyclic amines, nonionic sugar derivatives, ... mentioned in particular in WO 00/68352. Examples of some of these cationic softeners have already been mentioned above as a surfactant (TAC).
- TAC surfactant
- the softening agents may be present in an amount of 0.5 to 90%, preferably from 0.5 to 40%, depending on the concentration of said formulation (F).
- - water-soluble monovalent mineral salts such as sodium, potassium or ammonium chlorides, nitrates or sulphates (especially when the vector agent (V) is a polysaccharide), for example, from 0.01 to 2 moles per liter - dyes,
- the formulation (F) of the invention can be used to carry out a rinsing operation following a washing operation by hand or in a washing machine of articles made of textile fibers.
- Said articles can be made of natural and / or artificial fibers and / or synthetic fibers.
- Said formulation is particularly advantageous for rinsing cotton or cotton-based articles.
- This rinsing operation can be carried out at room temperature.
- This rinsing operation makes it possible to provide said articles, in addition to the conventional benefits of softness brought by the cationic and / or non-ionic softening agent (s), with anti wrinkle properties and / or ironing aid (“Ease of ironing”), antiabrasion, as well as anti-fouling (“soil release”) properties brought about by the deposition of the active material (A) on the surface of said articles, deposition favored by the presence the vector agent (V).
- a second object of the invention consists in a process for treating articles made of textile fibers, by bringing them into contact, during a rinsing operation in an aqueous or aqueous-alcoholic medium, with the rinsing formulation (F) such that described above, then recovery of said rinsed articles.
- a third object of the invention relates to a method for improving the properties of anti-creasing and / or of ironing aid and / or of anti-soiling and / or of resistance to abrasion of articles of textile fibers. , consisting in bringing into contact, during a rinsing operation in an aqueous or aqueous-alcoholic medium, said articles with the rinsing formulation (F) as described above, then in recovering said rinsed articles.
- the conditions used to carry out such a process have already been mentioned above.
- a fourth object of the invention consists in the use, in a formulation (F), intended to be used during a rinsing operation (R) of articles of textile fibers (S) using an aqueous or hydroalcoholic medium (MR), formulation (F) comprising at least one active material (A) made of at least one organic or organosilicon material, liquid or solid, in particulate form, and having: in the form of a stable dispersion, of pH 2 to 5, of said active material (A), in an aqueous or hydroalcoholic medium (MAV) or in solid form obtained by drying of said dispersion, the nature of the active material ( A) and aqueous or hydroalcoholic medium
- a fifth object of the invention consists of a method for improving the deposition of an active material (A) in at least one organic or organosilicon material, liquid or solid, in particulate form, on the surface of articles of textile fibers ( S), during a rinsing operation of said articles using an aqueous or hydroalcoholic medium (MR) obtained from a formulation (F) comprising said active material (A), formulation (F) is presenting: in the form of a stable dispersion, of pH 2 to 5, of said active material (A), in an aqueous or hydroalcoholic medium (MAV) or in solid form obtained by drying of said dispersion, the nature of the active material ( A) and aqueous or hydroalcoholic medium
- MR aqueous or hydroalcoholic medium
- Example 1 anti-crease and ironing aid effect
- a sunflower oil of the Lubrirob® type TOD18.80 (from Rhodia / Novance) is emulsified in water with a microfluidizer (4 bars, 3 cycles) when hot (50 ° C) in the presence of 3% by weight cationic surfactants (cetyltrimethylammonium bromide type).
- An emulsion (E) having a dry extract of 30% by weight of active material is obtained, an emulsion the size of which, measured by laser diffraction (Horiba granulometer) is 250 nm. This size is a mass average size of the size distribution of the emulsion.
- This emulsion (E) is used to make different formulations.
- the pH of the emulsion (E) is adjusted to 4.0 with a 1N hydrochloric acid solution.
- the pH of the emulsion (E) is adjusted to 4.0 with a 1N hydrochloric acid solution.
- the dispersion obtained is milky.
- aqueous solution containing 2.2% by weight of a 1: 1 molar copolymer (vector agent) of acrylic acid and of DADMAC (with a molar mass of 100,000 g / mol) is prepared, solution of which adjusted the pH to 4.0 with a 10% by weight hydrochloric acid solution.
- water is introduced whose pH has been adjusted to 4 ( about 100ml).
- the pH of the emulsion (E) at 30% by weight of active material is adjusted to 4.0 with a 1N hydrochloric acid solution.
- the dispersion obtained is milky.
- aqueous solution of a 1: 1 molar copolymer (carrier agent V) of acrylic acid and DADMAC (of molar mass of 100,000 g / mol) is also prepared, the solution of which has been adjusted. pH 4.0 with 10% hydrochloric acid solution by weight. 20ml of the active ingredient dispersion (A) are poured into 4ml respectively
- Formulations 2 and 3 are completed with 3.9 ml and 3.95 ml of water respectively, in order to maintain the concentration of active material (A) constant.
- Three beakers are prepared, each containing 200 ml of water at its natural pH of 7.2.
- the second batch is rinsed for 5 minutes with 15 liters of city water at 23 ° C. added with the 60 ml of FRI1 formulation, then wrung under the same conditions as the sample placed in reserve.
- the third batch is rinsed for 5 minutes with 15 liters of city water at 23 ° C. added with the 60 ml of FRII1 formulation, then wrung under the same conditions as the sample placed in reserve. During the rinsing cycle, the pH of the medium reaches 7.
- the articles After wringing, the articles are put to dry on a shelf.
- the standard deviation ⁇ of the gray level distribution is measured.
- ⁇ l corresponds to the standard deviation corresponding to the sample placed in reserve (rinsing without rinsing formulation).
- ⁇ 2 corresponds to the standard deviation obtained with the rinse formulation considered.
- ⁇ 3 corresponds to the standard deviation obtained on flat starting samples which have not undergone a washing, rinsing or spinning operation.
- WR (%) [( ⁇ l- ⁇ 2) / ⁇ l] f x 100 being a normalization factor, equal to 1 / [( ⁇ l- ⁇ 3) / ⁇ l]
- An emulsion comprising 30% by weight of silicone with hindered piperidinyl functions (Rhodorsil® 21645 from Rhodia) and 3% of nonionic surfactant of ethoxylated fatty alcohol type (Symperonic A7). 20 ml of the dispersion are poured under mechanical stirring into 1 ml of water, the pH of which has been adjusted to 4.5.
- An emulsion comprising 30% by weight of silicone with hindered piperidinyl functions (Rhodorsil® 21645 from Rhodia) and 3% of nonionic surfactant of ethoxylated fatty alcohol type (Symperonic A7).
- a 1% by weight solution of xanthan gum (Rhodopol® T from Rhodia) with a molar mass by weight of 4,000,000 g / mol is prepared in water of pH 4.5.
- the test is carried out in a Tergotometer laboratory apparatus, well known to formulators of detergent compositions.
- the device simulates the mechanical and thermal effects of washing machines of the American type with pulsator; thanks to the presence of 3 washing pots, it makes it possible to carry out series of simultaneous tests with appreciable time savings.
- the composition of the detergent used is as follows:
- test tubes measuring 10 x 10 cm, in flat woven cotton, are prewashed in a TERGOTOMETER for 20 minutes at 23 ° C, using the above washing formula; the water used has a hardness of 30 ° HT (diluted Contrexeville® mineral water); the amount of detergent used is 5g per 1 liter of water; the number of test tubes per jar is 6.
- tissue squares are then rinsed 3 times for 5 minutes (each time), including twice with cold water and the third time with cold water additive either 7ml of commercial FR rinse formula or 7.3ml of rinse formulas FRI2 or FRII2.
- the fabric squares are then wrung out, then dried on clothes lines.
- DMO dirty motor oil
- the fabrics are washed within 24 hours.
- the reflectance of the fabrics before and after washing is measured using the DR colorimeter.
- E in% 100 x (R3-R2) / (R1-R2)
- R1 representing the reflectance before washing of the soiled fabric (step (a))
- R2 representing the reflectance, before washing, of the soiled fabric (steps (a) and (b)
- R3 representing the reflectance, after washing, of the soiled fabric (steps (a), (b) and (c)
- the average of the% stain removal is calculated.
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Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US40916402P | 2002-09-09 | 2002-09-09 | |
US409164P | 2002-09-09 | ||
PCT/FR2003/002665 WO2004022839A2 (fr) | 2002-09-09 | 2003-09-08 | Formulation pour le rincage des textiles |
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EP1537271A2 true EP1537271A2 (fr) | 2005-06-08 |
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EP03769587A Withdrawn EP1537271A2 (fr) | 2002-09-09 | 2003-09-08 | Formulation pour le rincage des textiles |
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US (1) | US20050028293A1 (ja) |
EP (1) | EP1537271A2 (ja) |
JP (1) | JP2005538262A (ja) |
AU (1) | AU2003278279A1 (ja) |
BR (1) | BR0314149A (ja) |
WO (1) | WO2004022839A2 (ja) |
Families Citing this family (22)
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MX288034B (es) * | 2002-06-04 | 2011-07-04 | Procter & Gamble | Composiciones de champu acondicionador que contienen polimeros acondicionadores cationicos selectos. |
CN101031589B (zh) * | 2004-07-02 | 2010-05-26 | 罗迪亚公司 | 含有沉积控制剂的喷剂组合物 |
US7666963B2 (en) * | 2005-07-21 | 2010-02-23 | Akzo Nobel N.V. | Hybrid copolymers |
NO20073834L (no) | 2006-07-21 | 2008-01-22 | Akzo Nobel Chemicals Int Bv | Sulfonerte podede kopolymerer |
NO20073821L (no) * | 2006-07-21 | 2008-01-22 | Akzo Nobel Chemicals Int Bv | Podede kopolymerer med lav molekylvekt |
US20090053165A1 (en) * | 2007-08-20 | 2009-02-26 | Mark Anthony Brown | Method for Treating Damaged Hair |
US20090087398A1 (en) * | 2007-08-20 | 2009-04-02 | Mark Anthony Brown | Method for Treating Damaged Hair |
EP2252681B2 (en) | 2008-03-14 | 2022-11-02 | Unilever IP Holdings B.V. | Laundry treatment compositions |
US20100050346A1 (en) * | 2008-08-28 | 2010-03-04 | Corona Iii Alessandro | Compositions and methods for providing a benefit |
MX2011002151A (es) * | 2008-08-28 | 2011-03-29 | Procter & Gamble | Composiciones para el cuidado de las telas, proceso para elaborarlas y metodos de uso. |
CN102574961B (zh) | 2009-07-31 | 2015-09-23 | 阿克佐诺贝尔股份有限公司 | 混杂共聚物组合物 |
US8679366B2 (en) | 2011-08-05 | 2014-03-25 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale |
US8841246B2 (en) | 2011-08-05 | 2014-09-23 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
US8853144B2 (en) | 2011-08-05 | 2014-10-07 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage |
US8636918B2 (en) | 2011-08-05 | 2014-01-28 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale |
CA2845882A1 (en) | 2011-08-31 | 2013-03-07 | Akzo Nobel Chemicals International B.V. | Laundry detergent compositions comprising soil release agent |
BR112014008874A2 (pt) | 2011-11-04 | 2017-04-25 | Akzo Nobel Chemicals Int Bv | composição de copolímero híbrido de dendrito |
WO2013064648A1 (en) | 2011-11-04 | 2013-05-10 | Akzo Nobel Chemicals International B.V. | Graft dendrite copolymers, and methods for producing the same |
US20130118531A1 (en) * | 2011-11-11 | 2013-05-16 | The Procter & Gamble Company | Emulsions containing polymeric cationic emulsifiers, substance and process |
US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
US9441188B2 (en) | 2012-12-11 | 2016-09-13 | Colgate-Palmolive Company | Fabric conditioning composition |
US9365805B2 (en) | 2014-05-15 | 2016-06-14 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
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DE2724816A1 (de) * | 1976-06-04 | 1977-12-15 | Procter & Gamble Europ | Textil-behandlungsmittel |
DE3542725A1 (de) * | 1985-12-03 | 1987-06-04 | Hoffmann Staerkefabriken Ag | Waeschenachbehandlungsmittel |
EP0413416A3 (en) * | 1989-06-21 | 1991-09-04 | Colgate-Palmolive Company | Fiber conditioning compositions containing an aminosilicone |
FR2714289B1 (fr) * | 1993-12-27 | 1996-01-26 | Oreal | Composition cosmétique contenant un mélange de polymères conditionneurs. |
US5869442A (en) * | 1997-09-19 | 1999-02-09 | Isp Investments Inc. | Fabric softening compositions with dye transfer inhibitors for improved fabric appearance |
MXPA01010947A (es) * | 1999-04-27 | 2002-05-06 | Procter & Gamble | Composiciones de tratamiento que contienen polisacaridos. |
HUP0201411A3 (en) * | 1999-05-21 | 2004-03-01 | Unilever Nv | A method for stabilising the viscosity of fabric softening composition and the fabric softening composition |
PT1218478E (pt) * | 1999-10-05 | 2005-11-30 | Ciba Sc Holding Ag | Composicoes de amaciador de tecido |
US20050015888A1 (en) * | 1999-10-27 | 2005-01-27 | The Procter & Gamble Company | Wrinkle resistant composition |
GB9930435D0 (en) * | 1999-12-22 | 2000-02-16 | Unilever Plc | Fabric softening compositions |
US7026278B2 (en) * | 2000-06-22 | 2006-04-11 | The Procter & Gamble Company | Rinse-added fabric treatment composition, kit containing such, and method of use therefor |
GB0212157D0 (en) * | 2002-05-27 | 2002-07-03 | Unilever Plc | Fabric conditioning composition |
-
2003
- 2003-09-08 JP JP2004533581A patent/JP2005538262A/ja not_active Abandoned
- 2003-09-08 AU AU2003278279A patent/AU2003278279A1/en not_active Abandoned
- 2003-09-08 BR BR0314149-7A patent/BR0314149A/pt not_active IP Right Cessation
- 2003-09-08 EP EP03769587A patent/EP1537271A2/fr not_active Withdrawn
- 2003-09-08 WO PCT/FR2003/002665 patent/WO2004022839A2/fr not_active Application Discontinuation
- 2003-09-09 US US10/658,577 patent/US20050028293A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
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See references of WO2004022839A2 * |
Also Published As
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JP2005538262A (ja) | 2005-12-15 |
AU2003278279A1 (en) | 2004-03-29 |
US20050028293A1 (en) | 2005-02-10 |
WO2004022839A3 (fr) | 2004-05-06 |
WO2004022839A2 (fr) | 2004-03-18 |
AU2003278279A8 (en) | 2004-03-29 |
BR0314149A (pt) | 2005-07-12 |
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