Classifications

• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C1/00—Making non-ferrous alloys
  • C22C1/04—Making non-ferrous alloys by powder metallurgy
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C1/00—Making non-ferrous alloys
  • C22C1/04—Making non-ferrous alloys by powder metallurgy
  • C22C1/0408—Light metal alloys
  • C22C1/0416—Aluminium-based alloys
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
  • B22F1/09—Mixtures of metallic powders
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
  • B22F3/02—Compacting only
  • B22F2003/026—Mold wall lubrication or article surface lubrication
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
  • B22F2998/10—Processes characterised by the sequence of their steps

Definitions

• the invention relates to a sinterable powder mixture for the production of sintered components, in particular for automobile construction, based on an AI powder, and to sintered components produced therefrom, and a method for producing such components.
• aluminum is a preferred material, especially in the aerospace and automotive industries. Components made from aluminum or materials containing aluminum are considerably lighter than conventional components, for example made from cast iron. By reducing the weight, an increase in efficiency as well as a reduction in fuel consumption and an improvement in exhaust gas values can be achieved in automobiles, for example.
• a disadvantage of the powder-metallurgical production of components using aluminum is, in particular, that aluminum and its alloys tend to be coated with an extremely stable metal oxide when in contact with air. This in particular increases the specific surface area.
• the diffusion of the particles of the powder material used for sintering is hindered by the oxide skins located on the aluminum-containing material used.
• components made from aluminum-containing materials have reduced strength values, in particular low hardness, compared to those made from steel or cast iron.
• the oxide skins located on the aluminum-containing starting material hinder the cold welding of the particles to one another in the usual pressing process.
• the object of the present invention is therefore to provide a powder mixture and components produced therefrom and corresponding methods which do not have the aforementioned disadvantages.
• a sinterable powder mixture for producing sintered components, in particular for automobile construction comprising 60 to 98.5% by weight, based on the total amount of the powder mixture, preferably 75 to 92% by weight, of an Al-based powder made of metals and / or their alloys, comprising AI, 0.2 to 30% by weight of Mg, 0.2 to 40% by weight of Si, 0.2 to 15% by weight of Cu, 0.2 to 15% by weight of Zn, 0.2 to 15 %
• Ti 0.2 to 10% by weight Sn, 0.2 to 5% by weight Mn, 0.2 to 10% by weight Ni and / or less than 1% by weight of As, Sb, Co, Be, Pb and / or B, wherein the percentages by weight are in each case based on the total amount of Al base powder, and 0.8 to 40% by weight, based on the total amount of the powder mixture, preferably 8 to 15% by weight, of a metal powder selected from a first group of metals and / or their alloys consist
• first group of metals and / or their alloys consisting of Mo, W, Cr, V, Zr and / or Y
• components that have a very high hardness can be produced with this powder mixture using powder metallurgy.
• the hardness values for components made with a powder selected from the first group of metals and / or their alloys are 5 to 35% compared to those without addition of this first group of metals and / or their alloys. , preferably 10 to 25%, increased.
• the addition of the first group of metals and / or their alloys to an Al base powder improves, in particular, the cold welding of the particles to one another caused by the pressing process, in particular the post-compression. This ultimately also improves the diffusion of the individual particles during the individual sintering process, as a result of which components with higher strength values and higher hardness are obtained.
• the sinterable powder mixture further comprises a second group of metals and / or their alloys consisting of Cu, Sn, Zn, Li and / or Mg.
• the addition of the aforementioned second group of metals and / or their alloys presumably has the effect that in particular an alloy and / or intermetallic phase is formed with the Al base powder during the pressing process, in particular during the post-compression. As a result, the formation of oxide skins on the surface of the used Al base powder hindered.
• the second group of metals and / or their alloys changes into an at least partially liquid state at the sintering temperature, as a result of which the connection of the first group of metals and / or their alloys to the aluminum base powder in particular is improved.
• the ratio of the amount of the first group of metals and / or their alloys to that of the second group in the powder mixture is preferably in a range from 1: 8 to 15: 1 parts by weight.
• the ratio is preferably in a range from 2: 1 to 6: 1 parts by weight.
• the Al base powder has, in addition to Al, 0.2-15% by weight of Mg, 0.2 to 16% by weight of Si, 0.2 to 10% by weight of Cu and / or 0.2 to 15% by weight Zn, based in each case on the total amount of the Al base powder.
• the second group of metals and / or their alloys preferably has Cu, Zn and / or Sn.
• the sinterable powder mixture preferably comprises lubricants in an amount of 0.2 to 5% by weight, based on the total amount of the powder mixture.
• Self-lubricating agents such as MoS 2 , WS 2 , BN, MnS and graphite and / or other carbon modifications such as coke, polarized graphite or the like can be provided as lubricants on the one hand.
• Preferably 1 to 3% by weight of lubricant is added to the sinterable powder mixture.
• the components made from the sinterable powder mixture can be imparted with self-lubricating properties.
• the sinterable powder mixture can further comprise binders and / or lubricants.
• polyvinyl acetates preferably selected from a group comprising polyvinyl acetates, waxes, in particular amide waxes such as ethylene bisstearoylamide, shellac, polyalkylene oxides and / or polyglycols.
• Polyalkylene oxides and / or glycols are preferably used as polymers and / or copolymers with average molecular weights in a range from 100 to 500,000 g / mol, preferably 1,000 to 3,500 g / mol, further preferably 3,000 to 6,500 g / mol.
• the agents are preferably used in an amount in a range from about 0.01 to 12% by weight, preferably in a range from 0.5 to 5% by weight, still more preferably 0.6 to 1.8% by weight, in each case based on the Total amount of powder mixture used.
• the binders and / or lubricants also make it easier to remove the components made from the sinterable powder mixture from the mold.
• the powder mixture can be prepared by mixing the individual constituents with conventional apparatus such as tumble mixers both in the warm (hot mixing) and at room temperature (cold mixing), with warm mixing being preferred.
• the present invention relates to a sintered component which is at least partially manufactured according to the method according to the invention.
• Such sintered components according to the invention have strength values and hardnesses which are significantly higher than those which were produced using conventional methods.
• the sintered components according to the invention preferably have a tensile strength of at least
• the sintered components according to the invention advantageously have a modulus of elasticity of at least 70 kN / mm 2 , measured in accordance with DIN EN 10002-1, which is more preferably greater than 80 kN / mm 2 .
• the sintered components according to the invention have a hardness (HB 2.5 / 62.5 kg) of at least 100, measured in accordance with DIN EN 24498-1. The hardness is more preferably greater than 110, more preferably greater than 125.
• the sintered component is designed as a toothed wheel, pump wheel, in particular 01 pump wheel, and / or connecting rod and / or rotor set.
• Sintered components in the sense of the present invention are understood to mean components which have been produced entirely from a sinterable material; on the other hand, this also includes composite parts, wherein the base body of such a composite part can be made, for example, of an aluminum-containing powder mixture and the base body connected body made of a further material, for example iron or cast steel, sintered or solid, or made of solid cast aluminum.
• the composite part can also have, for example, only a sintered layer made of an aluminum-containing powder mixture on the end faces or its surface, whereas the base body is made of, for example, steel or cast iron, sintered or solid.
• the sintered components can be calibrated and / or hardened in the heat.
• the present invention relates to a method for producing sintered components, including composite parts, from a powder mixture according to the invention, wherein
• the powder mixture is entered into a first form
• the powder mixture is pressed into a green body
• the green compact is at least partially post-compacted; and - In a fourth step, the green compact is compacted.
• the process according to the invention has the great advantage that, due to the high density achieved in the third step before the actual sintering, components can be produced which on the one hand have excellent strength values and on the other hand also have extremely high densities and hardnesses.
• the post-compaction which followed the sintering step such as calibration and / or curing by aging in the heat, can be considerably shortened by the post-compression carried out according to the method according to the invention, or the customary post-firing or the calibration can optionally be omitted. This shortening of the overall process leads to an increase in productivity and thus an economic advantage.
• the subsequent densification in the third step of the method according to the invention advantageously has the effect that the oxide layers present on the surface of the material used are mechanically broken up, as a result of which better cold welding during the pressing process between the individual material particles is achieved. Furthermore, this also improves the diffusion during the actual sintering process of the individual material particles. In this way, components with increased strength values and in particular higher hardness can be obtained.
• the pressing process carried out in the second and third step of the process according to the invention can take place both at elevated temperature, in particular with the addition of the abovementioned agents, in particular polyethylene glycols (hot pressing), but also at room temperature (cold pressing), and also by means of vibration compression.
• Vibration compaction is understood here to mean a method in which, during the pressing process, an oscillation at least temporarily overlaps the pressing process, the vibration, for example, over at least one NEN ram can be initiated.
• Sinterable materials are in particular powders or powder mixtures, in particular metal powder and / or ceramic powder, for example made of steels such as chromium-nickel steel, bronzes, nickel-based alloys such as Hastalloy, Inconel, metal oxides, nitrides, suicides or the like, and in particular aluminum-containing powders or powder mixtures, where the powder mixtures can also contain high-melting components, such as platinum or the like.
• the powder used and its particle size depend on the respective application.
• Preferred iron-containing powders are the alloys 316 L, 304 L, Inconel 600, Inconel 625, Monel and Hastalloy B, X and C.
• the sinterable material can be wholly or partly made of short fibers or fibers, preferably fibers with diameters between about 0.1 and 250 ⁇ m and a length of a few ⁇ m up to millimeter size, up to 50 mm such as metal fiber fleece.
• the sinterable material is applied to the base body in the first step of the method according to the invention, for example, using conventional methods
• WPS dry powder spraying
• Particularly preferred solvents are selected from a group comprising water, methanol, ethanol, isopropanol, terpenes, C 2 -C 5 -alkenes, toluene, trichlorethylene, diethyl ether and / or Ci-Cg aldehydes and / or ketones. Solvents which can be evaporated at temperatures below 100 ° C. are preferred. The amount of solvent used is in the range of about 40 to 70% by weight, based on the sinterable powder mixture used, preferably in a range from about 50 to 65% by weight.
• the post-compaction which takes place in the third step can be carried out by methods which are customary and known for pressing a green compact.
• the green compact pressed in the second step can be reinserted into a customary die form and at least partially compressed in it by means of corresponding press punches.
• the post-compression tools can preferably be designed to be wholly or partially conical, so that particularly high densities can be achieved at certain predetermined locations of the green compact.
• the green body is dewaxed in a further step before the third step.
• the dewaxing is preferably carried out under nitrogen, hydrogen, air and / or mixtures of the gases mentioned, in particular also with more targeted ones
• Dewaxing can also be carried out with endogas and / or exogas, but also in a vacuum. Dewaxing can preferably be carried out by superimposed microwaves and / or ultrasound, or only by microwaves for temperature control. Finally, the dewaxing can also be carried out using solvents such as alcohol or the like or supercritical carbon dioxide with or without the action of temperature, microwaves or ultrasound or a combination of the aforementioned methods.
• a density is achieved which is about 2 to about 40% above that before the post-compression, preferably 5 to 30%, more preferably 15 to 25%.
• green compacts with an initial density are preferably range from 2.1 to 2.5 g / cm 3 , preferably 2.2 to 2.4 g / cm 3 , more preferably 2.25 to 2.38 g / cm 3 , measured according to DIN ISO 2738, pressed.
• a mold, into which the possibly dewaxed green body is introduced is advantageously sprayed with a lubricant before the green body is introduced.
• the dewaxed green body can also be soaked in lubricant.
• the sintering process is carried out in the fourth step under nitrogen with a dew point less than -40 ° C., preferably less than -50 ° C.
• the sintering is preferably carried out under pure nitrogen.
• the sintering can also be carried out under air, hydrogen, mixtures of nitrogen and hydrogen with or without a targeted air supply, endogas, exogas or in a vacuum, the sintering being carried out by superimposed microwaves or via microwaves Temperature control can take place.
• An optionally necessary heat treatment in particular a homogenization annealing, can preferably be connected directly to the sintering step.
• the heat treatment can be carried out depending on the chemical composition of the component obtained.
• the sintered component can also be quenched, starting from the sintering or homogenizing annealing temperature, preferably in water or by means of gas-shredded cooling.
• a calibration can also be carried out before or after the homogenization annealing.
• the calibration is carried out at room temperature or elevated temperature up to the forging temperature, even below Application of pressures up to 900 N / mm 2 . If necessary, the calibration can even be carried out above the solidus line, in which case the component can also be removed directly from the sintering heat.
• the calibration and / or forging tools used for calibration can be wholly or partially conical, as a result of which particularly high densities can be achieved in certain areas of the components.
• the temperature of the calibration and / or forging tools can differ depending on the component to be machined and, if necessary, can be kept in the isothermal range. Surface compression or the introduction of residual compressive stresses into the surface is also possible before or after heat treatment or calibration.
• coatings can be applied to the sintered component.
• methods with which the components are hard-coated and / or anodized such as thermal spraying methods such as plasma spraying, flame spraying or physical and / or chemical methods such as PVD, CVD or the like.
• coatings can also be produced in a purely chemical way, for example by means of sliding lacquers, which may contain Teflon, or nanocomposite materials.
• a coating can be used to modify the surface of the components in terms of hardness, roughness and the coefficient of friction, precisely tailored to the application.
• Al base powder of the composition Al4CulMg0.5Si (corresponds to the designation AC2014 of a conventional aluminum alloy, the base powder being 4% by weight Cu, 1% by weight Mg, 0.5% by weight Si and 94.5% by weight AI, based on the Total amount of pulse ver) from ECKA Granulate GmbH & Co. KG, Velden, Germany, with the company name ECKA Alumix 123 (92.5% by weight of AI), with 1.5% by weight of an amide wax as a binder from Hoechst with the Micro wax C was mixed with molybdenum or tungsten powder according to Table 1 below. The mixing was carried out in a tumble mixer by adding the molybdenum or tungsten powder to the aluminum base powder provided at room temperature over 5 minutes.
• the Al base powder had a particle size distribution between 45 and 200 ⁇ m, the mean particle diameter D 50 being 75 to 95 ⁇ m.
• the blended molybdenum or tungsten powder was obtained from HC Starck GmbH & Co. KG, Goslar, Germany, and had an average particle diameter D 50 of 25 ⁇ m with a particle size distribution in a range from about 5 to 50 ⁇ m on.
• the powder mixture was then placed in a die mold and pressed under a pressure of about 175 N / mm 2 (calculated for a wheel face of 20 cm 2 ) for about 0.2-0.5 sec at room temperature to form a green compact in the form of a pump wheel.
• the density of the green compacts was approximately 2.35 to 2.38 g / cm 3 .
• the green body thus produced was then dewaxed for about 30 minutes at about 430 ° C. and then at a sintering temperature of 610 ° C. under a pure nitrogen atmosphere with a dew point of ⁇ 50 ° C. in a belt furnace, which had a speed of 3.4 m / h was set, sintered for 30 min.
• the green compacts were on Al 2 0 3 plates. Homogenization annealing was then carried out for 1.5 h at a temperature of 515 ° C. The sintered pump wheel was then shock-cooled by quenching with water at a temperature of about 40 ° C. for 10 seconds.
• the tests mentioned under number 1 were repeated, but with the addition of a copper powder, which is sold by Eckart Granules under the Ecka Kupfer CH-S brand.
• the admixture was carried out in such a way that the molybdenum or tungsten powder was first mixed with the copper powder in a tumble mixer at room temperature for 5 minutes and this was then mixed in with the tumbler mixer to the Al base powder over 5 minutes.
• the copper powder had an average particle diameter D 50 of 25 ⁇ m and a particle size distribution in a range from about 5 to about 50 ⁇ m.
• the copper powder was produced electrolytically, the individual particles were dendritic
• the green compact was dewaxed under a nitrogen atmosphere for 30 min at about 430 ° C and then in a matrix form identical to the first mold, which was coated with the lubricant GLEITMO 300, Fuchs Lubritech GmbH, Weilerbach, Germany was sprayed, at a pressure of 760 N / mm 2 for about 0.2-0.5 sec at room temperature in such a way that the density of the post-compacted green body at about 2.8-2.9 g / cm 3 and thus around about 19-23% above that of the non-re-compressed impeller green body and thus about 95% of the theoretical density.
• the green compacts produced were then sintered as described above, calibrated to a theoretical density of 97-98% at a pressure of 810 N / mm 2 , but at room temperature, and cured.
• the mixing ratio between see molybdenum or tungsten powder to the copper powder was 5: 1 parts by weight. Table 2 shows the mixing ratios and the physical values determined.
• the physical properties are positively influenced by post-compression.
• a further increase in the hardness of the pump wheels produced can be achieved.
• the present invention makes it possible to produce sintered components, in particular based on an Al powder, which not only have excellent strength values, but in particular have a high hardness.
• components of this type can advantageously be subjected to high stress Places, especially in the engine or transmission.
• components sintered can be produced more cheaply and quickly.

Landscapes

• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Mechanical Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Powder Metallurgy (AREA)

Applications Claiming Priority (3)

Publications (2)

Family

ID=7713260

Family Applications (1)

Country Status (11)

Cited By (1)

Families Citing this family (35)

Family Cites Families (11)

• 2002
  • 2002-01-29 DE DE10203285A patent/DE10203285C1/de not_active Expired - Fee Related
  • 2002-10-30 EP EP02806652A patent/EP1470261B1/fr not_active Revoked
  • 2002-10-30 MX MXPA04007248A patent/MXPA04007248A/es active IP Right Grant
  • 2002-10-30 BR BR0215554-0A patent/BR0215554A/pt not_active Application Discontinuation
  • 2002-10-30 WO PCT/EP2002/012088 patent/WO2003064710A1/fr not_active Application Discontinuation
  • 2002-10-30 ES ES02806652T patent/ES2244838T3/es not_active Expired - Lifetime
  • 2002-10-30 JP JP2003564298A patent/JP2005516118A/ja active Pending
  • 2002-10-30 DE DE50203794T patent/DE50203794D1/de not_active Revoked
  • 2002-10-30 KR KR1020047010480A patent/KR100696312B1/ko not_active IP Right Cessation
  • 2002-10-30 AT AT02806652T patent/ATE300626T1/de not_active IP Right Cessation
  • 2002-10-30 CN CNA028277031A patent/CN1617940A/zh active Pending
• 2004
  • 2004-07-29 US US10/903,551 patent/US20050034559A1/en not_active Abandoned

Non-Patent Citations (1)

Also Published As

Similar Documents

Legal Events