US20050034559A1 - Sinterable metal powder mixture for the production of sintered components - Google Patents

Sinterable metal powder mixture for the production of sintered components Download PDF

Info

Publication number
US20050034559A1
US20050034559A1 US10/903,551 US90355104A US2005034559A1 US 20050034559 A1 US20050034559 A1 US 20050034559A1 US 90355104 A US90355104 A US 90355104A US 2005034559 A1 US2005034559 A1 US 2005034559A1
Authority
US
United States
Prior art keywords
weight percent
powder composition
powder
sinterable
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/903,551
Inventor
Rene Lindenau
Klaus Dollmeier
Volker Arnhold
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GKN Sinter Metals GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7713260&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20050034559(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Assigned to GKN SINTER METALS GMBH reassignment GKN SINTER METALS GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ARNHOLD, VOLKER, DOLLMEIER, KLAUS, LINDENAU, RENE
Publication of US20050034559A1 publication Critical patent/US20050034559A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/0408Light metal alloys
    • C22C1/0416Aluminium-based alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/09Mixtures of metallic powders
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02Compacting only
    • B22F2003/026Mold wall lubrication or article surface lubrication
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps

Definitions

  • the invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components. More particularly, the invention relates to sinterable powder compositions, sintered components, and methods for use in automobile manufacture.
  • aluminum is a preferred material, particularly in the aerospace industry and the automobile industry. Components made of aluminum or aluminum-containing materials are considerably lighter in comparison with the usual components made for example of cast iron. An increase in efficiency and also a reduction in fuel consumption and an improvement in exhaust gas values in automobiles are to be attained by the reduction of weight.
  • a disadvantage for the powder metallurgical production of components using aluminum is the tendency of aluminum and its alloys to become coated with a very stable metallic oxide. In particular, the specific surface is hereby increased. The diffusion of the particles necessary for sintering is hindered by the oxide layers on the aluminum-containing material used. Furthermore, components made of aluminum-containing materials, in comparison with those made of steel or cast iron, have reduced strength values, particularly low hardness. Moreover, the oxide layers on the aluminum-containing starting material prevent the mutual cold welding of the particles in the usual pressing process.
  • the present invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components.
  • Sinterable powder compositions are composed of an aluminum-based powder, and a first metal powder comprising molybdenum and/or tungsten.
  • the aluminum based powder is composed of aluminum and magnesium, silicon, copper, zinc, titanium, tin, manganese, nickel, or combinations thereof.
  • sinterable powder compositions are composed of 60-98.5 wt. % with respect to the total amount of the powder composition, preferably 75-92 wt. %, of an aluminum-based powder of metals and/or their alloys, comprising aluminum and possibly with contents of at least one of the following metals: 0.2-30 wt.
  • the sinterable powder composition may also include a second group of metals and/or their alloys, consisting of Cu, Sn, Zn, Li and/or Mg.
  • the ratio of the amount of the first group of metals and/or their alloys to that of the second group in the powder composition is preferably in a range of 1:8 to 15:1 parts by weight, preferably in a range of 2:1 to 6:1 parts by weight.
  • the aluminum-based powder further contains, besides aluminum, 0.2-15 wt. % Mg, 0.2-16 wt. % Si, 0.2-10 wt. % Cu, and/or 0.2-15 wt. % Zn, respectively with respect to the total amount of aluminum-based powder.
  • the aluminum-based powder preferably contains, a second group of metals and/of their alloys including Cu, Zn and/or Sn.
  • the sinterable powder compositions may also include lubricants.
  • lubricants are included in an amount of 0.2-5 wt. %, preferably 1-3 wt. %, based on the total amount of the powder composition.
  • Such lubricants can be, for example, MoS 2 , WS 2 , BN, MnS as well as graphite and/or other carbon modifications such as coke, polarized graphite, and the like.
  • the sinterable powder composition can furthermore contain other binders and/or lubricants.
  • binders and/or lubricants are preferably used in an amount in a range of 0.01-12 wt. %, preferably in a range of 0.5-5 wt. %, more preferably in a range of 0.6-1.8 wt. %, respectively with respect to the total amount of the powder composition.
  • Sintered components are composed of the sinterable powder composition.
  • a tensile strength of at least 140 N/mm 2 , measured according to DIN EN 10002-1. More preferably the tensile strength is more than 200 N/mm 2 , yet more preferably more than 300 N/mm 2 .
  • the components sintered according to the invention have an elasticity modulus of at least 70 N/mm 2 , measured according to DIN EN 10002-1, and more preferably is greater than 80 kN/mm 2 .
  • sintered components according to certain preferred embodiments of the present invention have a hardness (HB 2.5 mm/62.5 kg) of at least 100, measured according to DIN EN 24498-1.
  • the hardness is furthermore preferably greater than 110, more preferably greater than 125.
  • the sintered components of the present invention preferably include a gearwheel; a pump wheel, in particular an oil pump wheel; a connecting rod; and/or a rotor set.
  • Methods of making sintered components, including sintered composites and composite bonded parts, from a powder composition include steps wherein the powder composition is charged into a first mold; the powder composition is pressed into a green compact; the green compact is at least partially post-compressed; and the post-compressed green compact is sintered.
  • the green compact is dewaxed before compression. Still further, it is particularly advantageous for the sintering process to be performed under nitrogen with a dew point below ⁇ 45° C., preferably below ⁇ 50° C.
  • the present invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components.
  • Sinterable powder compositions are composed of an aluminum-based powder, and a first metal powder comprising molybdenum and/or tungsten.
  • the aluminum based powder is composed of aluminum and magnesium, silicon, copper, zinc, titanium, tin, manganese, nickel, or combinations thereof.
  • sinterable powder compositions are composed of 60-98.5 wt. % with respect to the total amount of the powder composition, preferably 75-92 wt. %, of an aluminum-based powder of metals and/or their alloys, comprising aluminum and possibly with contents of at least one of the following metals: 0.2-30 wt.
  • a metallic powder chosen from a first group of metals and/or their alloys, consisting of Mo and/or W.
  • the first group of metals and/or their alloys consisting of Mo and/or W By means of the addition of the first group of metals and/or their alloys consisting of Mo and/or W, powder-metallurgical components having a very high hardness can be produced with this alloy composition.
  • the values for the hardness of the components produced with a powder chosen from the first group of metals and/or their alloys, in comparison with those without addition of this first group of metals and/or their alloys, are increased by 5-35%, preferably 10-25%.
  • the diffusion of the individual particles during the sintering process is also improved, so that components with higher strength values and higher hardnesses are obtained.
  • the sinterable powder composition furthermore advantageously includes a second group of metals and/or their alloys, consisting of Cu, Sn, Zn, Li and/or Mg.
  • a second group of metals and/or their alloys consisting of Cu, Sn, Zn, Li and/or Mg.
  • the second group of metals and/or their alloys transform into an at least partially liquid state at the sintering temperature whereby the binding of the first group, and/or the alloying of the first group to the aluminum-based powder, is improved.
  • the ratio of the amount of the first group of metals and/or their alloys to that of the second group in the powder composition is preferably in a range of 1:8 to 15:1 parts by weight.
  • the ratio preferably lies in a range of 2:1 to 6:1 parts by weight.
  • the aluminum-based powder has, besides Al, 0.2-15 wt. % Mg, 0.2-16 wt. % Si, 0.2-10 wt. % Cu, and/or 0.2-15 wt. % Zn, respectively with respect to the total amount of Al-based powder.
  • the second group of metals and/of their alloys preferably has Cu, Zn and/or Sn.
  • the sinterable powder composition includes a lubricant in an amount of 0.2-5 wt. % based on the total amount of the powder composition.
  • lubricants there can be provided on the one hand self-lubricating means such as, for example, MoS 2 , WS 2 , BN, MnS as well as graphite and/or other carbon modifications such as coke, polarized graphite, and the like.
  • 1-3 wt. % of lubricant is added to the sinterable powder composition.
  • the sinterable powder composition can furthermore contain binders and/or lubricants. These are preferably chosen from a group comprising polyvinyl acetate, waxes, in particular amide waxes such as ethylene-bisstearoylamide, shellac, polyalkylene oxides and/or polyglycols. Polyalkylene oxides and/or polyalkylene glycols are preferably used as polymers and/or copolymers with average molecular weights in a range of 100-500,000 g/mol, preferably 1,800-3,500 g/mol, more preferably 3,000-6,500 g/mol. The media are preferably used in an amount in a range of 0.01-12 wt.
  • the binder and/or lubricant also facilitate the removal from the press mold of the components made from the sinterable powder composition.
  • the powder composition can be produced by mixing the individual components with conventional devices such as tumble mixers, both when hot (hot mixing) and also at room temperature (cold mixing); hot mixing is preferred.
  • tumble mixers both when hot (hot mixing) and also at room temperature (cold mixing); hot mixing is preferred.
  • Sintered components are composed of the sinterable powder composition. Sintered components preferably have strength values and hardnesses which clearly exceed those alloys which are produced by conventional methods.
  • the sintered components according to the invention preferably have a tensile strength of at least 140 N/mm 2 , measured according to DIN EN 10002- 1. More preferably the tensile strength is more than 200 N/mm 2 , yet more preferably more than 300 N/mm 2 .
  • the components sintered according to the invention have an elasticity modulus of at least 70 N/mm 2 , measured according to DIN EN 10002- 1, and more preferably is greater than 80 kN/mm 2 .
  • the sintered components according to the invention have a hardness (HB 2.5 mm/62.5 kg) of at least 100, measured according to DIN EN 24498-1.
  • the hardness is furthermore preferably greater than 110, more preferably greater than 125.
  • the sintered component is formed as a gearwheel, pump wheel, particularly an oil pump wheel, and/or a connecting rod and/or a rotor set.
  • sintered components in the sense of the present invention these are understood to be components which are produced completely from a sinterable material; on the other hand, these are hereby understood to also be composite parts, where the base member of such a composite part can, for example, be produced from an aluminum-containing powder composition and the member further connected to the base member from a further material, for example iron or cast steel, sintered or solid, or of solid cast aluminum.
  • the composite part can also, for example, have a sintered layer of an aluminum-containing powder composition only on the end face or its surface, in contrast to which the base member is, for example, of steel or cast iron, sintered or solid.
  • the sintered components can be sized and/or heat hardened.
  • the present invention also relates to methods for producing sintered composites, and also composite bonded parts, from a powder composition according to the invention:
  • the advantageous result is attained that the oxide layers present on the surface of the material used are mechanically broken, so that a better cold welding between the individual material particles is attained in the pressing process. Furthermore by this means the diffusion of the individual material particles during the sintering process proper is also improved. Components with increased strength values and in particular higher hardness can hereby be attained.
  • the pressing process taking place in the second and third steps of the method according to the invention can take place both at elevated temperatures, particularly with addition of the abovementioned media, particularly polyethylene glycol (hot pressing); however also at room temperature (cold pressing), and likewise by vibrational compression.
  • vibrational compression is to be understood here a method in which a vibration is at least intermittently superimposed on the pressing process; the vibration can for example be introduced via at least one of the press plungers.
  • a combination of the abovementioned press methods is also possible.
  • Sinterable materials are in particular powder or powder compositions, particular metal powder and/or ceramic powder, for example of steels such as chromium-nickel steel, bronzes, nickel-base alloys such as Hastelloy, Inconel, metal oxides, metal nitrides, metal suicides and the like, and in particular aluminum-containing powders or powder compositions, the powder compositions can also contain high-melting components, such as for example platinum or the like.
  • the powder used and its particle size are dependent on the respective intended use.
  • Preferred iron-containing powders are the alloys 316, 304 L, Inconel 600, Monel and Hastalloy B, X and C.
  • the sinterable material can be partially or completely of short fibers or fibers, preferably fibers with diameters between about 0.1 and 250 ⁇ m and a length of a few ⁇ m up to millimeter size and up to 50 mm, e.g. bonded metal fibers.
  • the sinterable material is applied to the base member, for example by conventional methods; it can also be provided, for example, to spray on the material in powder form (wet powder spraying, WPS). It is necessary to prepare a suspension of the sinterable material for this purpose.
  • the suspension necessary for this purpose preferably includes solvents, binders, stabilizers and/or dispersing agents.
  • Particularly preferred solvents are chosen from a group comprising water, methanol, ethanol, isopropanol, terpenes, C2-C5 alkenes, toluene, trichloroethylene, diethyl ether and/or C1-C6 aldehydes and/or ketones.
  • Preferred solvents are those evaporable at temperatures below 100° C.
  • the amount of the solvent used lies in a range of about 40 through 70 wt. % with respect to the sinterable powder composition used, preferably in a range of about 50-65 wt. %.
  • the post-compression (which may also be termed intermediate compression) taking place in the third step can be performed by means of the usual and known method for pressing a green compact.
  • the green compact pressed in the second step can be again introduced into a conventional mold and at least partially post-compressed in this by corresponding press plunger.
  • the post-compression tools can be completely or partially of conical design, so that particularly high compressions can be attained at given predetermined places of the green compact.
  • the green compact is dewaxed in a further step before the third step.
  • the dewaxing preferably takes place under nitrogen, hydrogen, air and/or compositions of the said gases, particularly also with a specific supply of air. Furthermore this dewaxing can take place with endogenous and/or exogenous gas, however also in vacuum.
  • the dewaxing can preferably be performed by means of applied microwaves and/or ultrasound, or else with only microwaves to control the temperature.
  • the dewaxing can also be performed with solvents such as alcohol and the like, or by supercritical carbon dioxide with or without the effect of temperature, microwaves or ultrasound or combinations of the said methods.
  • a density can be attained which lies about 2 to about 40% above that before post-compression, preferably 5-30%, more preferably 15-25%.
  • green compacts with an initial density of 2.1-2.5 g/cm3, preferably 2.2-2.4 g/cm3, more preferably 2.25-2.38 g/cm3, measured according to DIN ISO 2738, are compressed.
  • a mold in which the possibly dewaxed green compact is introduced is sprayed with a lubricant before introduction of the green compact.
  • the dewaxed green compact can also be soaked in lubricant.
  • the sintering process it is particularly advantageous for the sintering process to be performed under nitrogen with a dew point below ⁇ 45° C., preferably below ⁇ 50° C.
  • the sintering preferably takes place under pure nitrogen.
  • the sintering can also be performed under air, compositions of nitrogen and hydrogen with or without specific air supply, endogenous gas or exogenous gas, or in vacuum; sintering can take place by superposed microwaves or else with microwaves for temperature control.
  • a heat treatment particularly a homogenizing annealing, which may possibly be necessary, can follow the sintering step, preferably directly.
  • the heat treatment can be performed in dependence on the chemical composition of the obtained component.
  • the sintered component can be quenched from the sintering or homogenizing annealing temperature, preferably in water or else by means of a steep gas cooling.
  • an additional surface compression in general an introduction of internal pressure stresses in the surface region, is possible by sandblasting or shot peening.
  • a sizing may be performed before or after the homogenizing annealing. The sizing is performed at room temperature or an elevated temperature, up to the forging temperature, also with the use of pressures up to 900 N/mm2. If necessary, sizing can be performed even above the solids line, it then being possible also to remove the component directly from the sintering heat.
  • the sizing and/or forging tools used for sizing can be wholly or partially of conical shape, whereby particularly high compressions can be attained at given regions of the component.
  • the temperature of the sizing and/or forging tools can differ according to the component to be processed, and can possibly be kept in the isothermal range.
  • a surface compression or application of internal pressures to the component is also possible before or after sizing.
  • coatings may be applied to the sintered component.
  • Processes are here preferred with which the components are hard coated and/or anodized, for example, thermal spray processes such as plasma spraying, flame spraying, or else physical and/or chemical processes such as PVD, CVD and the like.
  • coatings may also be applied in purely chemical ways such as for example by lubricant lacquers which may contain Teflon, or nanocomposite materials, can be applied.
  • the surface of the composites can be modified by a coating according to the hardness, roughness and coefficient of friction in a predetermined manner according to the use purpose.
  • An aluminum-based powder of the composition Al 4 Cu1Mg 0.5 Si (corresponds to the designation AC2014 of a conventional aluminum alloy, the basic powder having 4 wt. % Cu, 1 wt. % Mg, 0.5 wt. % Si and 94.5 wt. % Al, with respect to the total amount of powder) of the Company ECKA Granulate GmbH & Co. KG, Velden, Germany, with the company designation ECKA Alumix 123 (92.5% Al), and 1.5 wt. % of an amide wax as binder, of the Hoechst Company with designation Mikrowachs C, were mixed with molybdenum or tungsten powder according to the following Table 1. Mixing took place in a tumble mixer by addition of the molybdenum or tungsten powder to the already present Al-based powder at room temperature during 5 minutes.
  • the aluminum-based powder had a grain size distribution between 45 and 200 ⁇ m, the average particle diameter D 50 being 75-200 ⁇ m.
  • the admixed molybdenum or tungsten powder was from the Company H.C. Starck Gmbh. & Co. KG, Goslar, Germany and had an average particle diameter D 50 of 25 ⁇ m with a grain size distribution in a range of 5-50 ⁇ m.
  • the powder composition was then placed in a die mold and pressed under a pressure of about 175 N/mm 2 (calculated for a wheel end surface of 20 cm 2 ) for about 0.2-0.5 sec at room temperature to a green compact in the form of a pump wheel.
  • the density of the green compact was about 2.15-2.38 g/cm 3 .
  • the thus produced green compact was then dewaxed for about 30 min at about 430° C., and was then sintered at a sintering temperature of 610° C. under a pure nitrogen atmosphere with a dew point of ⁇ 50° C. in a belt furnace set to a speed of 3.4 m/h for 30 min.
  • the green compacts were on Al 2 0 3 plates.
  • a homogenizing annealing was then performed for 1.5 hours at a temperature of 515° C.
  • the sintered pump wheel was then shock cooled by quenching with water with a temperature of about 40° C. for 10 sec.
  • the above trial under numeral 1 was repeated, a copper powder however being admixed, sold by the Company Eckhart Granules under the trademark ECKA KUPFER CH-S.
  • the ad composition took place such that the molybdenum powder or the tungsten powder was first with the copper powder in a tumble mixer at room temperature for 5 min and this was then mixed with the Al-based powder in a tumble mixer.
  • the copper powder had an average particle diameter D 50 of about 5-50 ⁇ m.
  • the copper powder was produced electrolytically; the individual particles had a dendritic form.
  • the green compact was dewaxed at 410° C. for 10 min under a nitrogen atmosphere and then placed in a die mold identical to the first mold and sprayed with the lubricant GLEITMO 300, sold by Fuchs Lubritech GmbH, Weilerbach, Germany, and was post-compressed at a pressure of 760 N/mm 2 for about 0.2-0.5 sec at room temperature, such that the density of the post-compressed green compact was about 2.8-2.9 g/cm 3 and thus about 19-23% greater than that of the non-post-compressed pump wheels and thus having 95% of the theoretical density.
  • the green compacts thus produced were sintered as described hereinabove, sized to a theoretical density of 97-98% at a pressure of 810 N/mm 2 , however at room temperature, and hardened.
  • the mixing ratio of molybdenum or tungsten powder to the copper powder was 5:1 parts by weight.
  • the mixing ratios and the physical values determined are shown in Table 2.
  • sintered components particularly based on an Al-based powder, which not only have excellent strength values, but also in particular have high hardness.
  • Such articles can hereby advantageously be used at strongly stressed places, particularly in the motor or else in gears.
  • sintered components can be more favorably and quickly produced by the possible omission of sizing and of hardening by hot storage.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

The present invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components. Sinterable powder compositions are composed of an aluminum-based powder, and a first metal powder comprising molybdenum and/or tungsten. The aluminum based powder is composed of aluminum and magnesium, silicon, copper, zinc, titanium, tin, manganese, nickel, or combinations thereof. In another embodiment, the sinterable powder composition includes a second metal powder comprising copper, tin, zinc, lithium, magnesium, or combination thereof. The sinterable powder compositions may be used for the production of sintered components, including composite components, having not only sufficient strength values but also with high hardness.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a continuation of International Application No. PCT/EP02/12088 filed Oct. 30, 2002, which claims priority to German Application No. 102 03 285.8 filed Jan. 29, 2002, each of which is hereby incorporated by reference in its entirety.
  • FIELD OF THE INVENTION
  • The invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components. More particularly, the invention relates to sinterable powder compositions, sintered components, and methods for use in automobile manufacture.
  • BACKGROUND OF THE INVENTION
  • Because of its special properties, aluminum is a preferred material, particularly in the aerospace industry and the automobile industry. Components made of aluminum or aluminum-containing materials are considerably lighter in comparison with the usual components made for example of cast iron. An increase in efficiency and also a reduction in fuel consumption and an improvement in exhaust gas values in automobiles are to be attained by the reduction of weight.
  • In the course of the desirable weight reduction of automobiles, there exists an increasing need for aluminum in the automobile field. Thus in engine and gear construction, the previous steel or cast iron was replaced piece by piece with those of aluminum or with the use of aluminum. However, problems arise when steel or cast iron parts are combined with aluminum parts because of the differing physical behavior of the materials. Problems arise when combining different materials due to the differences of the materials physical properties, such as for example, thermal expansion coefficients, thermal conductivity, elastic properties, etc.
  • Since, many engine, clutch and gear components are produced by powder metallurgy, there is great interest in producing powder compositions and in methods by which aluminum components can be produced by powder metallurgy. A disadvantage for the powder metallurgical production of components using aluminum is the tendency of aluminum and its alloys to become coated with a very stable metallic oxide. In particular, the specific surface is hereby increased. The diffusion of the particles necessary for sintering is hindered by the oxide layers on the aluminum-containing material used. Furthermore, components made of aluminum-containing materials, in comparison with those made of steel or cast iron, have reduced strength values, particularly low hardness. Moreover, the oxide layers on the aluminum-containing starting material prevent the mutual cold welding of the particles in the usual pressing process.
  • There therefore exists a need for sinterable powder compositions with good processability by powder metallurgy and from which components can be produced with good strength values and high hardness. There furthermore exists a need for powder-metallurgical methods for processing such aluminum-containing sinterable powder compositions.
  • SUMMARY OF THE INVENTION
  • The present invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components. Sinterable powder compositions are composed of an aluminum-based powder, and a first metal powder comprising molybdenum and/or tungsten. The aluminum based powder is composed of aluminum and magnesium, silicon, copper, zinc, titanium, tin, manganese, nickel, or combinations thereof. In a preferred embodiment, sinterable powder compositions are composed of 60-98.5 wt. % with respect to the total amount of the powder composition, preferably 75-92 wt. %, of an aluminum-based powder of metals and/or their alloys, comprising aluminum and possibly with contents of at least one of the following metals: 0.2-30 wt. % Mg, 0.2-40 wt. % Si, 0.2-15 wt. % Cu, 0.2-15 wt. % Zn, 0.2-15 wt. % Ti, 0.2-10 wt. % Sn, 0.2-5 wt. % Mn, 0.2-10 wt. % Ni and/or less than 1 wt. % of As, Sb, Co, Be, Pb and/or B, the weight percent fractions being respectively based on the total amount of aluminum-based powder; and 0.8-40 wt. %, based on the total amount of the powder composition, preferably 8-15 wt. %, of a metallic powder, chosen from a first group of metals and/or their alloys, consisting of Mo and/or W. The sinterable powder composition may also include a second group of metals and/or their alloys, consisting of Cu, Sn, Zn, Li and/or Mg. The ratio of the amount of the first group of metals and/or their alloys to that of the second group in the powder composition is preferably in a range of 1:8 to 15:1 parts by weight, preferably in a range of 2:1 to 6:1 parts by weight.
  • In another embodiment, the aluminum-based powder further contains, besides aluminum, 0.2-15 wt. % Mg, 0.2-16 wt. % Si, 0.2-10 wt. % Cu, and/or 0.2-15 wt. % Zn, respectively with respect to the total amount of aluminum-based powder. Furthermore, the aluminum-based powder preferably contains, a second group of metals and/of their alloys including Cu, Zn and/or Sn.
  • The sinterable powder compositions may also include lubricants. Preferably lubricants are included in an amount of 0.2-5 wt. %, preferably 1-3 wt. %, based on the total amount of the powder composition. Such lubricants can be, for example, MoS2, WS2, BN, MnS as well as graphite and/or other carbon modifications such as coke, polarized graphite, and the like. The sinterable powder composition can furthermore contain other binders and/or lubricants. These are preferably chosen from a group comprising polyvinyl acetate, waxes, in particular amide waxes such as ethylene-bisstearoylamide, shellac, polyalkylene oxides and/or polyglycols. These binders and/or lubricants are preferably used in an amount in a range of 0.01-12 wt. %, preferably in a range of 0.5-5 wt. %, more preferably in a range of 0.6-1.8 wt. %, respectively with respect to the total amount of the powder composition.
  • Sintered components are composed of the sinterable powder composition. According to the certain preferred embodiments of the present invention preferably have a tensile strength of at least 140 N/mm2, measured according to DIN EN 10002-1. More preferably the tensile strength is more than 200 N/mm2, yet more preferably more than 300 N/mm2. Advantageously, the components sintered according to the invention have an elasticity modulus of at least 70 N/mm2, measured according to DIN EN 10002-1, and more preferably is greater than 80 kN/mm2.
  • Further, sintered components according to certain preferred embodiments of the present invention have a hardness (HB 2.5 mm/62.5 kg) of at least 100, measured according to DIN EN 24498-1. The hardness is furthermore preferably greater than 110, more preferably greater than 125. The sintered components of the present invention preferably include a gearwheel; a pump wheel, in particular an oil pump wheel; a connecting rod; and/or a rotor set.
  • Methods of making sintered components, including sintered composites and composite bonded parts, from a powder composition include steps wherein the powder composition is charged into a first mold; the powder composition is pressed into a green compact; the green compact is at least partially post-compressed; and the post-compressed green compact is sintered. In a preferred embodiment of the method according to the invention, the green compact is dewaxed before compression. Still further, it is particularly advantageous for the sintering process to be performed under nitrogen with a dew point below −45° C., preferably below −50° C.
  • DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
  • The present invention relates to sinterable powder compositions, sintered components produced therefrom, and methods for prepared such components. Sinterable powder compositions are composed of an aluminum-based powder, and a first metal powder comprising molybdenum and/or tungsten. The aluminum based powder is composed of aluminum and magnesium, silicon, copper, zinc, titanium, tin, manganese, nickel, or combinations thereof. In a preferred embodiment, sinterable powder compositions are composed of 60-98.5 wt. % with respect to the total amount of the powder composition, preferably 75-92 wt. %, of an aluminum-based powder of metals and/or their alloys, comprising aluminum and possibly with contents of at least one of the following metals: 0.2-30 wt. % Mg, 0.2-40 wt. % Si, 0.2-15 wt. % Cu, 0.2-15 wt. % Zn, 0.2-15 wt. % Ti, 0.2-10 wt. % Sn, 0.2-5 wt. % Mn, 0.2-10 wt. % Ni and/or less than 1 wt. % of As, Sb, Co, Be, Pb and/or B, the weight percent fractions being respectively based on the total amount of aluminum-based powder; and 0.8-40 wt. %, based on the total amount of the powder composition, preferably 8-15 wt. %, of a metallic powder, chosen from a first group of metals and/or their alloys, consisting of Mo and/or W.
  • By means of the addition of the first group of metals and/or their alloys consisting of Mo and/or W, powder-metallurgical components having a very high hardness can be produced with this alloy composition. The values for the hardness of the components produced with a powder chosen from the first group of metals and/or their alloys, in comparison with those without addition of this first group of metals and/or their alloys, are increased by 5-35%, preferably 10-25%. Without being limited by theory, it is believed that by the addition of the first group of metals and/or their alloys to an aluminum-based powder, the cold welding of the particles to one another brought about by the pressing process, particularly the post-compression, is improved. Hereby, finally, the diffusion of the individual particles during the sintering process is also improved, so that components with higher strength values and higher hardnesses are obtained.
  • The sinterable powder composition furthermore advantageously includes a second group of metals and/or their alloys, consisting of Cu, Sn, Zn, Li and/or Mg. Without being limited by theory, it is believed that the addition of the second group of metals and/or their alloys presumably has the effect that during the pressing process, in particular during the post-compression, an alloy and/or intermetallic phase is formed with the aluminum-based powder. Hereby the formation of oxide layers on the surface of the aluminum-based powder used is prevented. Additionally it is believed that at least partially in the sintering process, the second group of metals and/or their alloys transform into an at least partially liquid state at the sintering temperature whereby the binding of the first group, and/or the alloying of the first group to the aluminum-based powder, is improved.
  • The ratio of the amount of the first group of metals and/or their alloys to that of the second group in the powder composition is preferably in a range of 1:8 to 15:1 parts by weight. The ratio preferably lies in a range of 2:1 to 6:1 parts by weight. With such mixing ratios, it is believed that maximum binding of the metals and/or alloys of the first group to the aluminum-based powders is attained. Components with high hardness can hereby be obtained with the powder composition.
  • In a further advantageous embodiment of the invention, the aluminum-based powder has, besides Al, 0.2-15 wt. % Mg, 0.2-16 wt. % Si, 0.2-10 wt. % Cu, and/or 0.2-15 wt. % Zn, respectively with respect to the total amount of Al-based powder. Furthermore, the second group of metals and/of their alloys preferably has Cu, Zn and/or Sn.
  • Preferably the sinterable powder composition includes a lubricant in an amount of 0.2-5 wt. % based on the total amount of the powder composition. As lubricants there can be provided on the one hand self-lubricating means such as, for example, MoS2, WS2, BN, MnS as well as graphite and/or other carbon modifications such as coke, polarized graphite, and the like. Preferably 1-3 wt. % of lubricant is added to the sinterable powder composition. By the use of the said lubricant, self-lubricating properties are believed to be conferred on the components produced from the sinterable powder composition.
  • The sinterable powder composition can furthermore contain binders and/or lubricants. These are preferably chosen from a group comprising polyvinyl acetate, waxes, in particular amide waxes such as ethylene-bisstearoylamide, shellac, polyalkylene oxides and/or polyglycols. Polyalkylene oxides and/or polyalkylene glycols are preferably used as polymers and/or copolymers with average molecular weights in a range of 100-500,000 g/mol, preferably 1,800-3,500 g/mol, more preferably 3,000-6,500 g/mol. The media are preferably used in an amount in a range of 0.01-12 wt. %, preferably in a range of 0.5-5 wt. %, more preferably in a range of 0.6-1.8 wt. %, respectively with respect to the total amount of the powder composition. The binder and/or lubricant also facilitate the removal from the press mold of the components made from the sinterable powder composition.
  • The powder composition can be produced by mixing the individual components with conventional devices such as tumble mixers, both when hot (hot mixing) and also at room temperature (cold mixing); hot mixing is preferred.
  • Sintered components are composed of the sinterable powder composition. Sintered components preferably have strength values and hardnesses which clearly exceed those alloys which are produced by conventional methods. The sintered components according to the invention preferably have a tensile strength of at least 140 N/mm2, measured according to DIN EN 10002- 1. More preferably the tensile strength is more than 200 N/mm2, yet more preferably more than 300 N/mm2. Advantageously, the components sintered according to the invention have an elasticity modulus of at least 70 N/mm2, measured according to DIN EN 10002- 1, and more preferably is greater than 80 kN/mm2.
  • In a further preferred embodiment, the sintered components according to the invention have a hardness (HB 2.5 mm/62.5 kg) of at least 100, measured according to DIN EN 24498-1. The hardness is furthermore preferably greater than 110, more preferably greater than 125.
  • In a further advantageous embodiment, the sintered component is formed as a gearwheel, pump wheel, particularly an oil pump wheel, and/or a connecting rod and/or a rotor set.
  • By sintered components in the sense of the present invention these are understood to be components which are produced completely from a sinterable material; on the other hand, these are hereby understood to also be composite parts, where the base member of such a composite part can, for example, be produced from an aluminum-containing powder composition and the member further connected to the base member from a further material, for example iron or cast steel, sintered or solid, or of solid cast aluminum. On the other hand, the composite part can also, for example, have a sintered layer of an aluminum-containing powder composition only on the end face or its surface, in contrast to which the base member is, for example, of steel or cast iron, sintered or solid. The sintered components can be sized and/or heat hardened.
  • The present invention also relates to methods for producing sintered composites, and also composite bonded parts, from a powder composition according to the invention:
      • in a first step, the powder composition is charged into a first mold;
      • in a second step, the powder composition is pressed into a green compact;
      • in a third step, the green compact is at least partially post-compressed; and
      • in a fourth step, the post-compressed green compact is sintered.
  • These methods have the great advantage that by means of the high density attained in the third step before the sintering itself, components can be produced which on the one hand have outstanding strength values, and on the other hand also have markedly high density and hardness. In particular, by means of the post-compression performed by the method according to the invention, the usual after-treatment steps following the sintering step, such as sizing and/or hardening by hot storage can be considerably shortened, or else possibly the usual reheating or else the sizing can be omitted. By this shortening of the whole process, a productivity increase and thereby an economic advantage is attained.
  • By the post-compression in the third step of the method according to the invention, the advantageous result is attained that the oxide layers present on the surface of the material used are mechanically broken, so that a better cold welding between the individual material particles is attained in the pressing process. Furthermore by this means the diffusion of the individual material particles during the sintering process proper is also improved. Components with increased strength values and in particular higher hardness can hereby be attained.
  • The pressing process taking place in the second and third steps of the method according to the invention can take place both at elevated temperatures, particularly with addition of the abovementioned media, particularly polyethylene glycol (hot pressing); however also at room temperature (cold pressing), and likewise by vibrational compression. By “vibrational compression” is to be understood here a method in which a vibration is at least intermittently superimposed on the pressing process; the vibration can for example be introduced via at least one of the press plungers. A combination of the abovementioned press methods is also possible. Sinterable materials are in particular powder or powder compositions, particular metal powder and/or ceramic powder, for example of steels such as chromium-nickel steel, bronzes, nickel-base alloys such as Hastelloy, Inconel, metal oxides, metal nitrides, metal suicides and the like, and in particular aluminum-containing powders or powder compositions, the powder compositions can also contain high-melting components, such as for example platinum or the like. The powder used and its particle size are dependent on the respective intended use. Preferred iron-containing powders are the alloys 316, 304 L, Inconel 600, Monel and Hastalloy B, X and C. Furthermore, the sinterable material can be partially or completely of short fibers or fibers, preferably fibers with diameters between about 0.1 and 250 μm and a length of a few μm up to millimeter size and up to 50 mm, e.g. bonded metal fibers.
  • If it is desired to produce composite parts which for example are to consist of a sintered layer of the sinterable material on the end face of a member consisting of steel or cast iron, in a first step of the method according to the invention the sinterable material is applied to the base member, for example by conventional methods; it can also be provided, for example, to spray on the material in powder form (wet powder spraying, WPS). It is necessary to prepare a suspension of the sinterable material for this purpose. The suspension necessary for this purpose preferably includes solvents, binders, stabilizers and/or dispersing agents. Particularly preferred solvents are chosen from a group comprising water, methanol, ethanol, isopropanol, terpenes, C2-C5 alkenes, toluene, trichloroethylene, diethyl ether and/or C1-C6 aldehydes and/or ketones. Preferred solvents are those evaporable at temperatures below 100° C. The amount of the solvent used lies in a range of about 40 through 70 wt. % with respect to the sinterable powder composition used, preferably in a range of about 50-65 wt. %.
  • The post-compression (which may also be termed intermediate compression) taking place in the third step can be performed by means of the usual and known method for pressing a green compact. Thus for example the green compact pressed in the second step can be again introduced into a conventional mold and at least partially post-compressed in this by corresponding press plunger. The post-compression tools can be completely or partially of conical design, so that particularly high compressions can be attained at given predetermined places of the green compact.
  • In a preferred embodiment of the method according to the invention, the green compact is dewaxed in a further step before the third step. The dewaxing preferably takes place under nitrogen, hydrogen, air and/or compositions of the said gases, particularly also with a specific supply of air. Furthermore this dewaxing can take place with endogenous and/or exogenous gas, however also in vacuum. The dewaxing can preferably be performed by means of applied microwaves and/or ultrasound, or else with only microwaves to control the temperature. Finally, the dewaxing can also be performed with solvents such as alcohol and the like, or by supercritical carbon dioxide with or without the effect of temperature, microwaves or ultrasound or combinations of the said methods.
  • Advantageously, with the method according to the invention, with the post-compression performed in the third step, a density can be attained which lies about 2 to about 40% above that before post-compression, preferably 5-30%, more preferably 15-25%.
  • Preferably in the second step of the method according to the invention, green compacts with an initial density of 2.1-2.5 g/cm3, preferably 2.2-2.4 g/cm3, more preferably 2.25-2.38 g/cm3, measured according to DIN ISO 2738, are compressed.
  • In a further embodiment of the method according to the invention, advantageously a mold in which the possibly dewaxed green compact is introduced is sprayed with a lubricant before introduction of the green compact. The dewaxed green compact can also be soaked in lubricant. Furthermore it is particularly advantageous for the sintering process to be performed under nitrogen with a dew point below −45° C., preferably below −50° C. Here the sintering preferably takes place under pure nitrogen. Furthermore the sintering can also be performed under air, compositions of nitrogen and hydrogen with or without specific air supply, endogenous gas or exogenous gas, or in vacuum; sintering can take place by superposed microwaves or else with microwaves for temperature control.
  • A heat treatment, particularly a homogenizing annealing, which may possibly be necessary, can follow the sintering step, preferably directly. Here the heat treatment can be performed in dependence on the chemical composition of the obtained component. Alternatively or additionally to the heat treatment, the sintered component can be quenched from the sintering or homogenizing annealing temperature, preferably in water or else by means of a steep gas cooling.
  • Before or after sintering, an additional surface compression, in general an introduction of internal pressure stresses in the surface region, is possible by sandblasting or shot peening. Likewise, a sizing may be performed before or after the homogenizing annealing. The sizing is performed at room temperature or an elevated temperature, up to the forging temperature, also with the use of pressures up to 900 N/mm2. If necessary, sizing can be performed even above the solids line, it then being possible also to remove the component directly from the sintering heat.
  • The sizing and/or forging tools used for sizing can be wholly or partially of conical shape, whereby particularly high compressions can be attained at given regions of the component. The temperature of the sizing and/or forging tools can differ according to the component to be processed, and can possibly be kept in the isothermal range. A surface compression or application of internal pressures to the component is also possible before or after sizing.
  • Finally, coatings may be applied to the sintered component. Processes are here preferred with which the components are hard coated and/or anodized, for example, thermal spray processes such as plasma spraying, flame spraying, or else physical and/or chemical processes such as PVD, CVD and the like. However, coatings may also be applied in purely chemical ways such as for example by lubricant lacquers which may contain Teflon, or nanocomposite materials, can be applied. The surface of the composites can be modified by a coating according to the hardness, roughness and coefficient of friction in a predetermined manner according to the use purpose.
  • This and further advantages of the invention are explained using the following examples. It will be appreciated by one skilled in the art that the descriptions given herein are for exemplary purposes only and is not intended in any way to limit the scope of the invention.
  • EXAMPLE 1
  • An aluminum-based powder of the composition Al4Cu1Mg0.5Si (corresponds to the designation AC2014 of a conventional aluminum alloy, the basic powder having 4 wt. % Cu, 1 wt. % Mg, 0.5 wt. % Si and 94.5 wt. % Al, with respect to the total amount of powder) of the Company ECKA Granulate GmbH & Co. KG, Velden, Germany, with the company designation ECKA Alumix 123 (92.5% Al), and 1.5 wt. % of an amide wax as binder, of the Hoechst Company with designation Mikrowachs C, were mixed with molybdenum or tungsten powder according to the following Table 1. Mixing took place in a tumble mixer by addition of the molybdenum or tungsten powder to the already present Al-based powder at room temperature during 5 minutes.
  • The aluminum-based powder had a grain size distribution between 45 and 200 μm, the average particle diameter D50 being 75-200 μm. The admixed molybdenum or tungsten powder was from the Company H.C. Starck Gmbh. & Co. KG, Goslar, Germany and had an average particle diameter D50 of 25 μm with a grain size distribution in a range of 5-50 μm.
  • The powder composition was then placed in a die mold and pressed under a pressure of about 175 N/mm2 (calculated for a wheel end surface of 20 cm2) for about 0.2-0.5 sec at room temperature to a green compact in the form of a pump wheel. The density of the green compact was about 2.15-2.38 g/cm3. The thus produced green compact was then dewaxed for about 30 min at about 430° C., and was then sintered at a sintering temperature of 610° C. under a pure nitrogen atmosphere with a dew point of −50° C. in a belt furnace set to a speed of 3.4 m/h for 30 min. Here the green compacts were on Al203 plates. A homogenizing annealing was then performed for 1.5 hours at a temperature of 515° C. The sintered pump wheel was then shock cooled by quenching with water with a temperature of about 40° C. for 10 sec.
  • A sizing was then performed to a theoretical density of 97-98% using a pressure of about 810 N/mm2 at 200° C. After the sizing, yet another hardening if the sintered pump wheels was carried out with heating at 160° C. for 16 h. Then tensile strength Rm, elasticity modulus, and extension according to DIN EN 10002-1 were determined on standardized samples. Furthermore the hardness according to DIN EN 24498-1 (Brinell hardness) was determined with a hardened steel ball as the penetrating member with a diameter of 2.5 mm? and with a load of 62.5 kg. The values determined are reproduced in Table 1.
    TABLE 1
    Rm* Elast. Hardness
    N/ modulus A** HB 2.5 mm/
    Material mm2 kN/mm2 % 62.5 kg
    Al4Cu1Mg0.5Si + 8 wt. % Mo 205 87 0.01 122
    Al4Cu1Mg0.5Si + 14 wt. % Mo 152 104 0.01 148
    Al4Cu1Mg0.5Si + 8 wt. % W 144 74 0.01 105
    Al4Cu1Mg0.5Si + 14 wt. % W 135 74 0.01 102

    Rm* = Tensile strength

    A** = Extension

    Elast. = elasticity
  • EXAMPLE 2
  • The above trial under numeral 1 was repeated, a copper powder however being admixed, sold by the Company Eckhart Granules under the trademark ECKA KUPFER CH-S. The ad composition took place such that the molybdenum powder or the tungsten powder was first with the copper powder in a tumble mixer at room temperature for 5 min and this was then mixed with the Al-based powder in a tumble mixer. The copper powder had an average particle diameter D50 of about 5-50 μm. The copper powder was produced electrolytically; the individual particles had a dendritic form.
  • Different compositions were produced, these being described under numeral 1, and were sintered to give pump wheels, with and without post-compression. For the post-compression, the green compact was dewaxed at 410° C. for 10 min under a nitrogen atmosphere and then placed in a die mold identical to the first mold and sprayed with the lubricant GLEITMO 300, sold by Fuchs Lubritech GmbH, Weilerbach, Germany, and was post-compressed at a pressure of 760 N/mm2 for about 0.2-0.5 sec at room temperature, such that the density of the post-compressed green compact was about 2.8-2.9 g/cm3 and thus about 19-23% greater than that of the non-post-compressed pump wheels and thus having 95% of the theoretical density.
  • The green compacts thus produced were sintered as described hereinabove, sized to a theoretical density of 97-98% at a pressure of 810 N/mm2, however at room temperature, and hardened. The mixing ratio of molybdenum or tungsten powder to the copper powder was 5:1 parts by weight. The mixing ratios and the physical values determined are shown in Table 2.
    TABLE 2
    Post-
    Com- Elast. Hardness
    pression Rm* Modulus A** HB
    No. Material Yes No N/mm2 kN/mm2 % 2.5 mm/62.5 kg
    2a Al4Cu1Mg0.5Si + x 226 88 0.03 138
     8 wt. % (80 wt. %
    Mo + 20 wt. % Cu)
    2a′ Al4Cu1Mg0.5Si + x 253 89 0.01 146
     8 wt. % (80 wt. %
    Mo + 30 wt. % Cu)
    2b Al4Cu1Mg0.5Si + x 206 93 0.01 142
    10 wt. % (80 wt. %
    Mo + 20 wt. % Cu)
    2b′ Al4Cu1Mg0.5Si + x 227 94 0.03 150
    10 wt. % (80 wt. %
    Mo + 20 wt. % Cu)
    2c Al4Cu1Mg0.5Si + x 187 96 0.01 159
    12 wt. % (80 wt. %
    Mo + 20 wt. % Cu)
    2c′ Al4Cu1Mg0.5Si + x 193 100 0.01 164
    12 wt. % (80 wt. %
    Mo + 30 wt. % Cu)
    2d Al4Cu1Mg0.5Si + x 178 101 0.01 159
    14 wt. % (80 wt. %
    Mo + 20 wt. % Cu)
    2d′ Al4Cu1Mg0.5Si + x 191 107 0.01 179
    14 wt. % (80 wt. %
    Mo + 20 wt. % Cu)
    2e Al4Cu1Mg0.5Si + x 155 75 0.03 110
     8 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2e′ Al4Cu1Mg0.5Si + x 237 79 0.04 122
     8 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2f Al4Cu1Mg0.5Si + x 173 74 0.05 107
    10 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2f′ Al4Cu1Mg0.5Si + x 243 81 0.03 121
    10 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2g Al4Cu1Mg0.5Si + x 147 73 0.05 107
    12 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2g′ Al4Cu1Mg0.5Si + x 233 86 0.04 121
    12 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2h Al4Cu1Mg0.5Si + x 146 76 0.05 107
    14 wt. % (80 wt. %
    W + 20 wt. % Cu)
    2h′ Al4Cu1Mg0.5Si + x 213 84 0.03 130
    14 wt. % (80 wt. %
    W + 20 wt. % Cu)

    Rm* = Tensile strength

    A** = Extension
  • As can be seen from Table 2, the physical properties are affected positively by a post-compression. In particular, a further increase of the hardness of the produced pump wheels can be attained.
  • It is possible with the present invention to produce sintered components, particularly based on an Al-based powder, which not only have excellent strength values, but also in particular have high hardness. Such articles can hereby advantageously be used at strongly stressed places, particularly in the motor or else in gears. In addition, sintered components can be more favorably and quickly produced by the possible omission of sizing and of hardening by hot storage.

Claims (23)

1. A sinterable powder composition for the production of sintered components comprising:
(a) at least 60 weight percent of an aluminum-based powder, based on the weight of the sinterable powder composition, comprising:
aluminum, and
from 0.2 to 30 weight percent magnesium, from 0.2 to 40 weight percent silicon, from 0.2 to 15 weight percent copper, from 0.2 to 15 weight percent zinc, from 0.2 to 15 weight percent titanium, from 0.2 to 10 weight percent tin, from 0.2 to 5 weight percent manganese, from 0.2 to 10 weight percent nickel, or combinations thereof based on the weight of the aluminum based powder; and
(b) from 0.8 to 40 weight percent of a first metal powder comprising molybdenum, tungsten or combinations thereof, based on the weight of the sinterable powder composition.
2. The sinterable powder composition of claim 1 wherein the aluminum based powder further comprises up to 1 weight percent of arsenic, antimony, cobalt, beryllium, lead, boron, or combinations thereof, based on the weight of the aluminum-based powder.
3. The sinterable powder composition of claim 1, wherein the aluminum based powder is composed of:
aluminum, and
from 0.2 to 15 weight percent magnesium, from 0.2 to 16 weight percent silicon, from 0.2 to 10 weight percent copper, from 0.2 to 15 weight percent zinc, or combinations thereof, based on the weight of the aluminum-based powder.
4. The sinterable powder composition of claim 1, wherein the first metal powder is a prealloy.
5. The sinterable powder composition of claim 1, further comprising a second metal powder comprising copper, tin, zinc, lithium, magnesium, or combination thereof.
6. The sinterable powder composition of claim 5, wherein the second metal powder is a prealloy.
7. The sinterable powder composition of claim 5, wherein the ratio of the weight percent of the first metal powder to the weight percent of the second metal powder is from 1:8 to 15:1.
8. The sinterable powder composition of claim 5, wherein the ratio of the weight percent of the first metal powder to the weight percent of the second metal powder is from 2:1 to 6:1.
9. The sinterable powder composition of claim 5, wherein the second metal powder is composed of copper, tin, zinc, or combination thereof.
10. The sinterable powder composition according to claim 1, further comprising from 0.2 to 5 weight percent of at least one lubricant, based on the weight of the sinterable powder composition.
11. The sinterable powder composition of claim 10, wherein the at least one lubricant is MoS2, WS2, BN, MnS, or carbon.
12. The sinterable powder composition of claim 1, further comprising polyvinyl acetate, an amide wax, or combinations thereof.
13. The sinterable powder composition of claim 12, wherein the amide wax comprises polyvinyl acetate, ethylene-bisstearoylamide, shellac, polyalkylene oxide, polyalkylene polyglycol, or combinations thereof.
14. A sintered component comprising the sinterable powder composition of claim 1.
15. The sintered component of claim 14, wherein the sintered component has a tensile strength of at least 140 N/mm2.
16. Sintered component of claim 14, wherein the sintered component has an elasticity modulus of at least 70 kN/mm2.
17. Sintered component of claim 15, wherein the sintered component has an elasticity modulus of at least 70 kN/mm2.
18. Sintered component of claim 14, wherein the sintered component has a hardness of at least 100, at 2.5 mm and 62.5 kg.
19. A method of preparing sintered components comprising:
(a) providing the sinterable powder composition of claim 1;
(b) filling a mold with the sinterable powder composition;
(c) pressing the sinterable powder composition to form a green compact;
(d) at least partially post-compressing said green compact; and
(e) sintering the post-compressed green compact.
20. The method of claim 19, further comprising the step of dewaxing the green compact before partially post-compressing the green compact.
21. The method of claim 19, wherein the density of the partially post-compacted green compact is from 2% to 60% greater than the density before partial post-compaction.
22. The method of claims 19, further comprising the step of applying a lubricant to said mold.
23. The method of claim 19, wherein said sintering is performed under nitrogen with a dew point below at least −45° C.
US10/903,551 2002-01-29 2004-07-29 Sinterable metal powder mixture for the production of sintered components Abandoned US20050034559A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10203285.8 2002-01-29
DE10203285A DE10203285C1 (en) 2002-01-29 2002-01-29 Sinterable powder mixture for the production of sintered components
PCT/EP2002/012088 WO2003064710A1 (en) 2002-01-29 2002-10-30 Sinterable metal powder mixture for the production of sintered components

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/012088 Continuation WO2003064710A1 (en) 2002-01-29 2002-10-30 Sinterable metal powder mixture for the production of sintered components

Publications (1)

Publication Number Publication Date
US20050034559A1 true US20050034559A1 (en) 2005-02-17

Family

ID=7713260

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/903,551 Abandoned US20050034559A1 (en) 2002-01-29 2004-07-29 Sinterable metal powder mixture for the production of sintered components

Country Status (11)

Country Link
US (1) US20050034559A1 (en)
EP (1) EP1470261B1 (en)
JP (1) JP2005516118A (en)
KR (1) KR100696312B1 (en)
CN (1) CN1617940A (en)
AT (1) ATE300626T1 (en)
BR (1) BR0215554A (en)
DE (2) DE10203285C1 (en)
ES (1) ES2244838T3 (en)
MX (1) MXPA04007248A (en)
WO (1) WO2003064710A1 (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050079085A1 (en) * 2003-10-02 2005-04-14 Junichi Ichikawa Manufacturing method of sinter forged aluminum parts with high strength
US20080283021A1 (en) * 2004-12-10 2008-11-20 Kurt Maier Connecting Rod for an Internal Combustion Engine and Method for Coating Its Slide Bearing Surfaces
US20090042057A1 (en) * 2007-08-10 2009-02-12 Springfield Munitions Company, Llc Metal composite article and method of manufacturing
CN103372646A (en) * 2012-04-12 2013-10-30 会田工程技术有限公司 High-density molding device and high-density molding method for mixed powder
FR2997325A1 (en) * 2012-10-25 2014-05-02 Peugeot Citroen Automobiles Sa Manufacturing e.g. spacers in motor vehicle comprises selecting powder from powders of aluminum particles, compressing powder for producing preform, sintering preform, quenching continuous material, and hardening material
CN105081328A (en) * 2015-08-05 2015-11-25 苏州好洁清洁器具有限公司 Manufacturing method for high-strength aluminum alloy pipe
EP2842666A4 (en) * 2012-04-23 2016-01-13 Aida Eng Ltd Device for high-density molding and method for high-density molding of mixed powder
WO2019241097A1 (en) * 2018-06-11 2019-12-19 Chapman John Eric Hybrid washer
US10870148B2 (en) * 2010-12-15 2020-12-22 Gkn Sinter Metals, Llc Aluminum alloy powder metal with transition elements
US11213887B2 (en) * 2018-07-02 2022-01-04 Schlumberger Technology Corporation Ultra hard electrically-responsive and environmentally resistant metals for oilfield services
US11273489B2 (en) * 2014-04-11 2022-03-15 Gkn Sinter Metals, Llc Aluminum alloy powder formulations with silicon additions for mechanical property improvements
US11752550B2 (en) * 2018-01-10 2023-09-12 Gkn Sinter Metals, Llc Method for improving fatigue strength on sized aluminum powder metal components

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005027049A1 (en) * 2005-06-10 2006-12-14 Gkn Sinter Metals Gmbh Resilient gearing
WO2012082621A1 (en) 2010-12-13 2012-06-21 Gkn Sinter Metals, Llc Aluminum alloy powder metal with high thermal conductivity
US9038802B2 (en) 2012-07-30 2015-05-26 Gm Global Technology Operations, Llc Clutch backing plate for bearing support
CN103537689A (en) * 2013-10-11 2014-01-29 芜湖市鸿坤汽车零部件有限公司 Powder metallurgy alloy gear and manufacturing method thereof
CN103537694A (en) * 2013-10-11 2014-01-29 芜湖市鸿坤汽车零部件有限公司 Powder metallurgy chain wheel and preparing method of powder metallurgy chain wheel
CN103537698A (en) * 2013-10-11 2014-01-29 芜湖市鸿坤汽车零部件有限公司 Powder metallurgy automotive synchronizer gear hub and manufacturing method thereof
CN103537691A (en) * 2013-10-11 2014-01-29 芜湖市鸿坤汽车零部件有限公司 Iron-based powder metallurgy alloy and manufacturing method thereof
CN104120367A (en) * 2014-06-26 2014-10-29 芜湖市鸿坤汽车零部件有限公司 High-hardness flange prepared by employing powder metallurgy and preparation method thereof
CN104878262B (en) * 2015-05-18 2017-01-18 广东省材料与加工研究所 High-strength aluminum alloy and preparation method thereof
CN105345006A (en) * 2015-06-11 2016-02-24 西北稀有金属材料研究院 Direct-heating type hot-pressing equipment suitable for producing large-size beryllium materials
US9915007B2 (en) 2015-06-29 2018-03-13 GM Global Technology Operations LLC Electro ceramic coated aluminum transmission components
CN105154699A (en) * 2015-08-31 2015-12-16 苏州莱特复合材料有限公司 Preparation method of high temperature-resistant aluminium alloy material
CN105443828A (en) * 2015-12-29 2016-03-30 常熟市虞菱机械有限责任公司 Pipeline flow regulating valve easy to control
CN105543594A (en) * 2015-12-29 2016-05-04 常熟市虞菱机械有限责任公司 Manufacturing method of easily-controlled pipeline flow control valve
CN107245608A (en) * 2017-06-09 2017-10-13 太仓东旭精密机械有限公司 A kind of bicycle use aluminium alloy
CN107287474A (en) * 2017-06-20 2017-10-24 陈雨琴 Superpower wear-resistant alloy material
CN108672702A (en) * 2018-05-21 2018-10-19 宁波市奇强精密冲件有限公司 Damper knuckle support
CN108531784B (en) * 2018-05-24 2020-08-11 河北工业大学 Method for preparing aluminum-titanium-magnesium ternary intermetallic compound powder by mechanical alloying
AT521546B1 (en) * 2018-08-10 2020-07-15 Miba Sinter Austria Gmbh Process for making a connection between two metallic components
CN109022935A (en) * 2018-09-12 2018-12-18 张家港市五湖新材料技术开发有限公司 A kind of preparation method of aluminium nickel-titanium alloy material
CN109630547B (en) * 2018-12-13 2020-05-22 武汉东顺汽车配件有限公司 Automobile antifriction bush
CN109554636A (en) * 2018-12-29 2019-04-02 安徽鑫铂铝业股份有限公司 A kind of high-performance color sorter slipway aluminum profile
CN112251650A (en) * 2020-09-30 2021-01-22 福建祥鑫股份有限公司 Aluminum alloy and preparation method thereof
CN114293048B (en) * 2021-12-28 2022-08-02 哈尔滨工业大学 High-density and component-controllable high-silicon aluminum alloy material and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2287251A (en) * 1939-07-07 1942-06-23 Jones William David Manufacture of nonporous metal articles
US4177069A (en) * 1977-04-09 1979-12-04 Showa Denko K.K. Process for manufacturing sintered compacts of aluminum-base alloys
US4460541A (en) * 1980-01-16 1984-07-17 Reynolds Metals Company Aluminum powder metallurgy
US5061323A (en) * 1990-10-15 1991-10-29 The United States Of America As Represented By The Secretary Of The Navy Composition and method for producing an aluminum alloy resistant to environmentally-assisted cracking
US5232659A (en) * 1992-06-29 1993-08-03 Brown Sanford W Method for alloying lithium with powdered aluminum
US5304343A (en) * 1989-12-29 1994-04-19 Showa Denko K.K. Aluminum-alloy powder, sintered aluminum-alloy, and method for producing the sintered aluminum-alloy
US5902943A (en) * 1995-05-02 1999-05-11 The University Of Queensland Aluminium alloy powder blends and sintered aluminium alloys
US5972523A (en) * 1996-12-09 1999-10-26 The Chinese University Of Hong Kong Aluminum metal matrix composite materials reinforced by intermetallic compounds and alumina whiskers

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU491717A1 (en) * 1973-10-29 1975-11-15
JPS6386831A (en) * 1986-09-29 1988-04-18 Alum Funmatsu Yakin Gijutsu Kenkyu Kumiai Manufacture of working stock of aluminum-base sintered alloy
JPH0625782A (en) * 1991-04-12 1994-02-01 Hitachi Ltd High ductility aluminum sintered alloy and its manufacture as well as its application

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2287251A (en) * 1939-07-07 1942-06-23 Jones William David Manufacture of nonporous metal articles
US4177069A (en) * 1977-04-09 1979-12-04 Showa Denko K.K. Process for manufacturing sintered compacts of aluminum-base alloys
US4460541A (en) * 1980-01-16 1984-07-17 Reynolds Metals Company Aluminum powder metallurgy
US5304343A (en) * 1989-12-29 1994-04-19 Showa Denko K.K. Aluminum-alloy powder, sintered aluminum-alloy, and method for producing the sintered aluminum-alloy
US5061323A (en) * 1990-10-15 1991-10-29 The United States Of America As Represented By The Secretary Of The Navy Composition and method for producing an aluminum alloy resistant to environmentally-assisted cracking
US5232659A (en) * 1992-06-29 1993-08-03 Brown Sanford W Method for alloying lithium with powdered aluminum
US5902943A (en) * 1995-05-02 1999-05-11 The University Of Queensland Aluminium alloy powder blends and sintered aluminium alloys
US5972523A (en) * 1996-12-09 1999-10-26 The Chinese University Of Hong Kong Aluminum metal matrix composite materials reinforced by intermetallic compounds and alumina whiskers

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050079085A1 (en) * 2003-10-02 2005-04-14 Junichi Ichikawa Manufacturing method of sinter forged aluminum parts with high strength
US7651659B2 (en) * 2003-10-02 2010-01-26 Hitachi Powdered Metals Co., Ltd. Manufacturing method of sinter forged aluminum parts with high strength
US20080283021A1 (en) * 2004-12-10 2008-11-20 Kurt Maier Connecting Rod for an Internal Combustion Engine and Method for Coating Its Slide Bearing Surfaces
US7743746B2 (en) 2004-12-10 2010-06-29 Mahle International Gmbh Coating for connecting rods and bearings in an internal combustion engine
US20090042057A1 (en) * 2007-08-10 2009-02-12 Springfield Munitions Company, Llc Metal composite article and method of manufacturing
US10870148B2 (en) * 2010-12-15 2020-12-22 Gkn Sinter Metals, Llc Aluminum alloy powder metal with transition elements
EP2837443A4 (en) * 2012-04-12 2016-01-13 Aida Eng Ltd High-density molding device and high-density molding method for mixed powder
CN103372646A (en) * 2012-04-12 2013-10-30 会田工程技术有限公司 High-density molding device and high-density molding method for mixed powder
EP2842666A4 (en) * 2012-04-23 2016-01-13 Aida Eng Ltd Device for high-density molding and method for high-density molding of mixed powder
FR2997325A1 (en) * 2012-10-25 2014-05-02 Peugeot Citroen Automobiles Sa Manufacturing e.g. spacers in motor vehicle comprises selecting powder from powders of aluminum particles, compressing powder for producing preform, sintering preform, quenching continuous material, and hardening material
US11273489B2 (en) * 2014-04-11 2022-03-15 Gkn Sinter Metals, Llc Aluminum alloy powder formulations with silicon additions for mechanical property improvements
CN105081328A (en) * 2015-08-05 2015-11-25 苏州好洁清洁器具有限公司 Manufacturing method for high-strength aluminum alloy pipe
US11752550B2 (en) * 2018-01-10 2023-09-12 Gkn Sinter Metals, Llc Method for improving fatigue strength on sized aluminum powder metal components
WO2019241097A1 (en) * 2018-06-11 2019-12-19 Chapman John Eric Hybrid washer
US11867222B2 (en) 2018-06-11 2024-01-09 John Eric Chapman Hybrid washer
US11213887B2 (en) * 2018-07-02 2022-01-04 Schlumberger Technology Corporation Ultra hard electrically-responsive and environmentally resistant metals for oilfield services

Also Published As

Publication number Publication date
ES2244838T3 (en) 2005-12-16
BR0215554A (en) 2004-12-21
DE10203285C1 (en) 2003-08-07
KR20040066937A (en) 2004-07-27
DE50203794D1 (en) 2005-09-01
EP1470261B1 (en) 2005-07-27
CN1617940A (en) 2005-05-18
WO2003064710A1 (en) 2003-08-07
EP1470261A1 (en) 2004-10-27
MXPA04007248A (en) 2004-10-29
JP2005516118A (en) 2005-06-02
ATE300626T1 (en) 2005-08-15
KR100696312B1 (en) 2007-03-19

Similar Documents

Publication Publication Date Title
US20050034559A1 (en) Sinterable metal powder mixture for the production of sintered components
US20050036899A1 (en) Method for producing sintered components from a sinterable material
KR100187616B1 (en) Sintered friction material composite copper alloy powder used therefor and manufacturing method thereof
US4135922A (en) Metal article and powder alloy and method for producing metal article from aluminum base powder alloy containing silicon and manganese
US6117204A (en) Sintered titanium alloy material and process for producing the same
EP0577436B1 (en) Nitrogen-combined aluminum sintered alloys and method of producing the same
JP2002504188A (en) Manufacturing method for high density high carbon sintered metal powder steel parts
JP2006063400A (en) Aluminum-based composite material
JP2546660B2 (en) Method for producing ceramics dispersion strengthened aluminum alloy
JPH0120215B2 (en)
EP0202886B1 (en) Canless method for hot working gas atomized powders
US6485540B1 (en) Method for producing powder metal materials
US5613184A (en) Aluminium alloys
US6296682B1 (en) Iron-based powder blend for use in powder metallurgy
JP4008597B2 (en) Aluminum-based composite material and manufacturing method thereof
JPH0578708A (en) Production of aluminum-based grain composite alloy
JP3336949B2 (en) Synchronizer ring made of iron-based sintered alloy
JP3413031B2 (en) Composite material for railway vehicle brake discs
JPH0533013A (en) Production of highly accurate aluminum alloy sliding parts
JPH08193236A (en) Aluminum alloy with high toughness and wear resistance and its production
JP2605866B2 (en) Manufacturing method of composite compound dispersion type Cu-Zn-A (1) sintered alloy with excellent wear resistance
JP3346286B2 (en) Synchronizer ring made of iron-based sintered alloy
JP2003096533A (en) Iron-base powder mixture for warm compaction, iron-base powder mixture for warm die lubrication compaction, and method for manufacturing iron-base sintered compact using them
JP2001262201A (en) Al SERIES POWDERY MIXTURE, GRANULATED BODY, PREFORM AND SINTERED BODY
JPS6335706B2 (en)

Legal Events

Date Code Title Description
AS Assignment

Owner name: GKN SINTER METALS GMBH, GERMANY

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LINDENAU, RENE;DOLLMEIER, KLAUS;ARNHOLD, VOLKER;REEL/FRAME:015309/0917

Effective date: 20040920

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION