EP1468126A1 - Sphärogusslegierung - Google Patents
SphärogusslegierungInfo
- Publication number
- EP1468126A1 EP1468126A1 EP02792934A EP02792934A EP1468126A1 EP 1468126 A1 EP1468126 A1 EP 1468126A1 EP 02792934 A EP02792934 A EP 02792934A EP 02792934 A EP02792934 A EP 02792934A EP 1468126 A1 EP1468126 A1 EP 1468126A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- iron alloy
- content
- ductile iron
- elasticity
- alloy according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title description 10
- 229910002804 graphite Inorganic materials 0.000 title description 10
- 239000010439 graphite Substances 0.000 title description 10
- 229910000640 Fe alloy Inorganic materials 0.000 title 1
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 30
- 239000000956 alloy Substances 0.000 claims abstract description 30
- 229910001141 Ductile iron Inorganic materials 0.000 claims abstract description 16
- 229910001018 Cast iron Inorganic materials 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 8
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
- 230000005496 eutectics Effects 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000011733 molybdenum Substances 0.000 claims abstract 2
- 229910001562 pearlite Inorganic materials 0.000 claims description 7
- 239000000470 constituent Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/04—Cast-iron alloys containing spheroidal graphite
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/10—Cast-iron alloys containing aluminium or silicon
Definitions
- the invention relates to a spheroidal cast iron alloy for cast iron products with a high modulus of elasticity, the spheroidal cast iron alloy containing at least the elements C, Si, Mn, Cu, Mg, S and as admixtures Ni and / or Mo as non-iron components.
- Ductile iron alloys are used in motor vehicle construction for the production of cast parts which must have a high resistance to torsional moments, for example the crankshaft, as part of the engine in the
- the castings often have a very complex geometry with many areas that are subjected to different loads and therefore have different wall thicknesses. This requires a casting technique that is suitable for parts with highly differentiated geometries.
- the castings also often have to be post-treated.
- the aftertreatment can be a heat treatment and / or a machining treatment.
- An important property that is desired for such cast parts is an elastic modulus that is as high as possible. Alloys with a modulus of elasticity of up to approx. 160 GPa are currently usually used.
- a steel alloy is usually used for parts with the highest possible modulus of elasticity and the parts are then machined by forging. However, this manufacturing method is expensive.
- WO 99/19525 discloses a nodular cast iron alloy which can be used for shafts and disks of a disc brake.
- the alloy contains in percent by weight 1.5 to 4.5% C, 1.5 to 4.5% Si and at least 1.0 to 6.5% Mo, and possibly Ni and Cu, the sum (% Mo +% Ni +% Cu) not exceeding 6.5%, and as Balance iron and the usual impurities.
- the alloy is characterized by good resistance to high temperatures and abrasion.
- WO 96/38596 discloses a spheroidal cast iron alloy with a high modulus of elasticity.
- the alloy contains in percent by weight: 3.0 to 3.8% C, 2.0 to 2.6% Si, 0.2 to 0.6% manganese, less than 0.02% P, less than 0.03% S, 0.03 to 0.06% magnesium, 0.8 to 1.2% Ni, 0.8 to 1.2% Cu, 0.4 to 1.0% Mo and the rest Fe.
- Ductile iron alloys with high pearlite and graphite contents are known. With these known alloys, the modulus of elasticity is too low for certain applications. If the graphite content is kept low, the matrix portion becomes larger and the modulus of elasticity higher. There is more mixed crystal than graphite. ,
- the alloy is composed of percentages by weight: C ⁇ 2.9%, Si 3.8 to 4.3%, Cu 0.5 to 1.0%, Ni and / or Mo 0 to 4%, Mn 0.1 to 0.8%, Mg 0.03 to 0.07% and S at most 0.015%, whereby the mixture proportions C and Si are very close to the eutectic.
- the pearlite content in the structure of the cast iron products is reduced and that the alloy comes very close to the eutectic. This is achieved in that the pearlite content is less than 50 to 70%.
- the cutting properties are improved by the lower percentage of pearlite.
- the core idea of the invention is to provide a spheroidal cast iron alloy which is particularly suitable for crankshafts in internal combustion engines.
- the higher modulus of elasticity considerably reduces the risk of breakage, even in the case of a one-piece shaft with a geometry with alternately relatively small and large cross sections, and the life of the shaft is considerably extended.
- the rigidity of the crankshaft is also increased. As a result, the crankshaft runs more smoothly. Better smoothness also means that the vibrations that act on the bearings of the crankshaft are significantly reduced. As a result, the bearings and the shaft achieve a significantly longer service life.
- the C content is decisive for the modulus of elasticity of the crankshaft.
- GJS spheroidal graphite iron
- the structure consists of 60-70% pearlite, 30 to 40% ferrite.
- the total graphite content is 10%.
- the graphite formation is greater than 90% V and VI (according to DIN EN ISO 945) with a size of 6 to 7.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Shafts, Cranks, Connecting Bars, And Related Bearings (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Carbon And Carbon Compounds (AREA)
- Valve Housings (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10201218A DE10201218A1 (de) | 2002-01-14 | 2002-01-14 | Sphärogusslegierung |
DE10201218 | 2002-01-14 | ||
PCT/EP2002/013895 WO2003057937A1 (de) | 2002-01-14 | 2002-12-07 | Sphärogusslegierung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1468126A1 true EP1468126A1 (de) | 2004-10-20 |
EP1468126B1 EP1468126B1 (de) | 2005-11-09 |
Family
ID=7712142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02792934A Expired - Lifetime EP1468126B1 (de) | 2002-01-14 | 2002-12-07 | Sphärogusslegierung |
Country Status (9)
Country | Link |
---|---|
US (1) | US6939414B2 (de) |
EP (1) | EP1468126B1 (de) |
JP (1) | JP4326959B2 (de) |
CN (1) | CN100340689C (de) |
AT (1) | ATE309396T1 (de) |
AU (1) | AU2002358642A1 (de) |
DE (2) | DE10201218A1 (de) |
ES (1) | ES2248629T3 (de) |
WO (1) | WO2003057937A1 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10344073A1 (de) * | 2003-09-23 | 2005-04-28 | Daimler Chrysler Ag | Kurbelwelle mit kombiniertem Antriebszahnrad sowie Verfahren zu ihrer Herstellung und deren Verwendung |
EP1566454A1 (de) * | 2004-02-10 | 2005-08-24 | Magna Drivetrain AG & Co KG | Verfahren zur Herstellung eines Werkstückes aus sphäroguss und nach diesem hergestelltes Werkstück |
SE531107C2 (sv) * | 2006-12-16 | 2008-12-23 | Indexator Ab | Metod |
JP4561778B2 (ja) * | 2007-06-04 | 2010-10-13 | 株式会社日立製作所 | エレベーター用非常止め装置 |
US7846381B2 (en) * | 2008-01-29 | 2010-12-07 | Aarrowcast, Inc. | Ferritic ductile cast iron alloys having high carbon content, high silicon content, low nickel content and formed without annealing |
JP4825886B2 (ja) | 2009-02-27 | 2011-11-30 | トヨタ自動車株式会社 | フェライト系球状黒鉛鋳鉄 |
CN101893033B (zh) * | 2009-05-19 | 2012-08-22 | 天润曲轴股份有限公司 | 一种球铁合金曲轴 |
DE202011105648U1 (de) * | 2011-09-13 | 2011-10-13 | Robert Bosch Gmbh | Drehmomentbelastetes Maschinenbauteil |
EP2785882B1 (de) * | 2011-11-30 | 2016-01-20 | Federal-Mogul Corporation | Verschleissfestes graugusseisen mit hohem modulus für kolbenringanwendungen |
CN104032205B (zh) * | 2014-06-11 | 2016-03-23 | 温州中普知识产权有限公司 | 球墨铸铁合金 |
JP6313154B2 (ja) * | 2014-07-28 | 2018-04-18 | 株式会社リケン | 鋳鉄及びブレーキ部品 |
CN104561797A (zh) * | 2014-12-31 | 2015-04-29 | 铜陵市经纬流体科技有限公司 | 一种易焊接珠光体软密封闸阀阀体及其制备方法 |
CN104561836A (zh) * | 2014-12-31 | 2015-04-29 | 铜陵市经纬流体科技有限公司 | 一种强度和耐蚀性良好的软密封闸阀阀体及其制备方法 |
CN105525193A (zh) * | 2015-12-18 | 2016-04-27 | 张淑芬 | 用于曲轴的新型铸铁合金材料 |
CN105401068A (zh) * | 2015-12-18 | 2016-03-16 | 张淑芬 | 用于曲轴的铸铁合金材料 |
CN105506446A (zh) * | 2015-12-18 | 2016-04-20 | 张淑芬 | 铸造领域用的铸铁合金材料 |
WO2024180392A1 (en) | 2023-02-27 | 2024-09-06 | C.R.F. Società Consortile Per Azioni | Internal combustion engine with variable intake valve actuation and engine control method |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL85806B1 (de) | 1973-04-27 | 1976-04-30 | Politechnika Slaska Im Wincentego Pstrowskiego Te Gliwice Polen | |
DE2428822A1 (de) * | 1974-06-14 | 1976-01-02 | Goetzewerke | Sphaerogusseisenlegierung mit erhoehter verschleissbestaendigkeit |
US4040875A (en) * | 1975-04-03 | 1977-08-09 | Noble Charles H | Ductile cast iron articles |
DE3147461C2 (de) * | 1981-12-01 | 1983-10-13 | Goetze Ag, 5093 Burscheid | Verschleißfeste Gußeisenlegierung hoher Festigkeit mit sphärolithischer Graphitausscheidung, ihr Herstellungsverfahren und ihre Verwendung |
FR2522291A1 (fr) * | 1982-03-01 | 1983-09-02 | Pont A Mousson | Tube centrifuge en fonte a graphite spheroidal et son procede de fabrication |
SU1285045A1 (ru) | 1984-06-11 | 1987-01-23 | Камский политехнический институт | Антифрикционный чугун |
DE3639658A1 (de) * | 1986-11-20 | 1988-06-01 | Horst Dipl Phys Dr Muehlberger | Verfahren zur herstellung von gussstuecken aus gusseisen mit kugelgraphit |
JPS63166928A (ja) * | 1986-12-26 | 1988-07-11 | Kurimoto Iron Works Ltd | 強靭ベイナイト球状黒鉛鋳鉄の製造方法 |
JP2620695B2 (ja) | 1987-10-21 | 1997-06-18 | マツダ株式会社 | 高強度を有する鉄系鋳物 |
CN1043754A (zh) * | 1988-12-21 | 1990-07-11 | 机械制造工艺科学生产联合公司 | 球墨铸铁 |
SU1752819A1 (ru) | 1990-10-26 | 1992-08-07 | Брянский технологический институт | Антифрикционный чугун |
CN1017473B (zh) * | 1991-04-20 | 1992-07-15 | 吉林大学 | 双球腔实用标准黑体 |
CN1068599A (zh) * | 1991-06-28 | 1993-02-03 | 招远县黄金机械总厂 | 一种耐磨球墨铸铁 |
DE19629970C1 (de) * | 1996-07-25 | 1998-03-12 | Ae Goetze Gmbh | Gußeisenlegierung für die Herstellung von Kolbenringen von Verbrennungskraftmaschinen |
JPH10195587A (ja) | 1996-12-26 | 1998-07-28 | Toyota Central Res & Dev Lab Inc | 中温延性に優れた球状黒鉛鋳鉄、エキゾーストマニホールド、およびその製造方法 |
-
2002
- 2002-01-14 DE DE10201218A patent/DE10201218A1/de not_active Withdrawn
- 2002-12-07 DE DE50204908T patent/DE50204908D1/de not_active Expired - Lifetime
- 2002-12-07 EP EP02792934A patent/EP1468126B1/de not_active Expired - Lifetime
- 2002-12-07 CN CNB02806464XA patent/CN100340689C/zh not_active Expired - Fee Related
- 2002-12-07 ES ES02792934T patent/ES2248629T3/es not_active Expired - Lifetime
- 2002-12-07 AT AT02792934T patent/ATE309396T1/de active
- 2002-12-07 JP JP2003558227A patent/JP4326959B2/ja not_active Expired - Fee Related
- 2002-12-07 AU AU2002358642A patent/AU2002358642A1/en not_active Abandoned
- 2002-12-07 WO PCT/EP2002/013895 patent/WO2003057937A1/de active IP Right Grant
- 2002-12-07 US US10/469,650 patent/US6939414B2/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO03057937A1 * |
Also Published As
Publication number | Publication date |
---|---|
US6939414B2 (en) | 2005-09-06 |
WO2003057937A1 (de) | 2003-07-17 |
JP4326959B2 (ja) | 2009-09-09 |
ATE309396T1 (de) | 2005-11-15 |
CN100340689C (zh) | 2007-10-03 |
ES2248629T3 (es) | 2006-03-16 |
DE50204908D1 (de) | 2005-12-15 |
EP1468126B1 (de) | 2005-11-09 |
US20040091382A1 (en) | 2004-05-13 |
DE10201218A1 (de) | 2003-07-24 |
AU2002358642A1 (en) | 2003-07-24 |
JP2005514519A (ja) | 2005-05-19 |
CN1496418A (zh) | 2004-05-12 |
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