EP1463858B1 - Verfahren zur behandlung von cellulosischen formkörpern - Google Patents
Verfahren zur behandlung von cellulosischen formkörpern Download PDFInfo
- Publication number
- EP1463858B1 EP1463858B1 EP02796479A EP02796479A EP1463858B1 EP 1463858 B1 EP1463858 B1 EP 1463858B1 EP 02796479 A EP02796479 A EP 02796479A EP 02796479 A EP02796479 A EP 02796479A EP 1463858 B1 EP1463858 B1 EP 1463858B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cyclodextrin
- fibers
- process according
- moulded bodies
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 21
- 239000000835 fiber Substances 0.000 claims description 26
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 14
- 229920000858 Cyclodextrin Polymers 0.000 claims description 12
- 239000004753 textile Substances 0.000 claims description 11
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 229940097362 cyclodextrins Drugs 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 229920000433 Lyocell Polymers 0.000 description 2
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 2
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 2
- 206010061592 cardiac fibrillation Diseases 0.000 description 2
- 230000002600 fibrillogenic effect Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 150000004676 glycans Chemical group 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Definitions
- the invention relates to a process for the treatment of cellulosic molded articles, which are prepared from a solution of cellulose in an aqueous tertiary amine oxide, in particular fibers and structures containing these fibers, in which process the shaped bodies are brought into contact with a textile auxiliary in order to Give moldings improved properties.
- shaped body includes sponges in particular.
- the solvent used is a tertiary amine oxide, in particular N-methylmorpholine-N-oxide (NMMO).
- NMMO N-methylmorpholine-N-oxide
- the WO 99/19555 describes a process for treating solvent-spun fibers in which the fibers are contacted with 2,4-dichloro-6-hydroxy-1,3,5-triazine or with a salt thereof.
- the fibers thus produced are characterized by a better resistance to fibrillation.
- the WO 01/48025 describes cyclodextrins which are covalently bound to a polysaccharide by means of a crosslinking agent.
- cellulosic molded articles prepared from a solution of the cellulose in an aqueous tertiary amine oxide can be treated with a textile auxiliary comprising a cyclodextrin and / or a cyclodextrin derivative to give products having improved properties.
- the moldings are preferably fibers in never-dried state.
- the fibers can be treated in a never-dried state in a post-treatment stage of a continuous processing plant.
- cyclodextrins may include drugs that are then released, for example, over a longer period of time.
- the treatment with the textile auxiliaries is preferably carried out in an alkaline medium.
- the textile auxiliary additionally comprises a crosslinking agent.
- a crosslinking agent particularly preference is given to using 2,4-dichloro-6-hydroxy-1,3,5-triazine or a salt thereof as crosslinking agent.
- the textile auxiliary comprises 2-chloro-4-hydroxy-1,3,5-triazinyl-cyclodextrin (MCT-CD) or a salt thereof.
- the invention also relates to a solvent-spun cellulosic fiber obtainable by the process according to the invention and to fiber structures which contain these fibers.
- the fibers were mixed at a liquor ratio of 1:10 with a solution containing 20 g / l sodium salt of 2,4-dichloro-6-hydroxy-1,3,5-triazine, 16 g / l NaOH and 100 g / l of a cyclodextrin ( CAVAMAX W7, manufacturer Wacker-Chemie) for 5 minutes at room temperature impregnated.
- the fibers were then squeezed to a moisture content of 100% -110% by means of a squeezer and heat treated for 5 minutes with saturated steam (100%) at 100 ° C, washed and dried.
- the content of active cyclodextrin in the fibers thus produced was determined photometrically (552 nm) on the basis of the decolorization of a phenolphthalein solution and was 2.33% by weight.
- the degree of fibrillation was determined by wet scrub resistance (test method according to WO 99/19555 ) of the individual fibers. According to this test method, a value of 210 revolutions results on average for the sample treated according to the invention. An untreated fiber, in comparison, exhibits a wet rub of only 40-60 turns.
- Example 2 The procedure was as in Example 1, wherein the treatment solution 20 g / l sodium salt of 2,4-dichloro-6-hydroxy-1,3,5-triazine, 16 g / l NaOH, 30 g / l of soda and 50 g / l of a Cyclodextrins (CAVAMAX W7, manufacturer Fa. Wacker-Chemie) contained.
- CAVAMAX W7 Cyclodextrins
- the content of active cyclodextrin in the fibers thus obtained was 1.65 wt.%, The wet abrasion value was 470 revolutions.
- Example 2 The procedure was as in Example 1, the treatment solution containing 30 g / l of sodium carbonate and 100 g / l of 2-chloro-4-hydroxy-1,3,5-triazinylcyclodextrin (MCT-CD; CAVASOL W7 MCT, manufacturer Wacker-Chemie). Chemistry).
- the content of active MCT-CD in the fibers thus obtained was 1.89 wt%.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0201201A AT413988B (de) | 2001-12-20 | 2001-12-20 | Verfahren zur behandlung von cellulosischen formkörpern |
AT20122001 | 2001-12-20 | ||
PCT/AT2002/000362 WO2003054283A2 (de) | 2001-12-20 | 2002-12-19 | Verfahren zur behandlung von cellulosischen formkörpern |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1463858A2 EP1463858A2 (de) | 2004-10-06 |
EP1463858B1 true EP1463858B1 (de) | 2010-10-06 |
Family
ID=3689615
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02796479A Expired - Lifetime EP1463858B1 (de) | 2001-12-20 | 2002-12-19 | Verfahren zur behandlung von cellulosischen formkörpern |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1463858B1 (ko) |
JP (1) | JP2005535790A (ko) |
KR (1) | KR100910989B1 (ko) |
CN (1) | CN1311123C (ko) |
AT (2) | AT413988B (ko) |
AU (1) | AU2002361375A1 (ko) |
DE (1) | DE50214703D1 (ko) |
TW (1) | TWI273148B (ko) |
WO (1) | WO2003054283A2 (ko) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100415980C (zh) * | 2006-09-21 | 2008-09-03 | 浙江理工大学 | 一种环糊精-酞菁双重模拟酶功能纤维的制备方法 |
CN100392172C (zh) * | 2006-09-21 | 2008-06-04 | 浙江理工大学 | 环糊精聚合物模拟酶功能纤维的制备方法 |
CN100392173C (zh) * | 2006-09-21 | 2008-06-04 | 浙江理工大学 | 环糊精模拟酶功能纤维的制备方法 |
CN100398741C (zh) * | 2006-09-21 | 2008-07-02 | 浙江理工大学 | 一种环糊精-酞菁双重模拟酶功能纤维的制造方法 |
CN101220557B (zh) * | 2007-12-06 | 2010-06-02 | 浙江理工大学 | 一种模拟酶催化纤维的制备方法 |
AT506334B1 (de) * | 2008-01-22 | 2010-12-15 | Chemiefaser Lenzing Ag | Verfahren zur behandlung cellulosischer formkörper |
AT509289B1 (de) * | 2009-12-28 | 2014-06-15 | Chemiefaser Lenzing Ag | Funktionalisierter cellulosischer formkörper und verfahren zu seiner herstellung |
JP4832573B2 (ja) * | 2010-02-27 | 2011-12-07 | 慶一郎 金久 | 繊維構造物の抗ウィルス・制菌加工法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5102564A (en) * | 1989-04-12 | 1992-04-07 | The Procter & Gamble Company | Treatment of fabric with perfume/cyclodextrin complexes |
US5534165A (en) * | 1994-08-12 | 1996-07-09 | The Procter & Gamble Company | Fabric treating composition containing beta-cyclodextrin and essentially free of perfume |
DE4429229A1 (de) * | 1994-08-18 | 1996-02-22 | Consortium Elektrochem Ind | Cyclodextrinderivate mit mindestens einem stickstoffhaltigen Heterozyklus, ihre Herstellung und Verwendung |
DE19520967A1 (de) * | 1995-06-08 | 1996-12-12 | Consortium Elektrochem Ind | Textiles Material oder Leder, welches mit Cyclodextrinderivaten mit mindestens einem stickstoffhaltigen Heterozyklus ausgerüstet ist |
EP0946209A2 (en) * | 1996-12-17 | 1999-10-06 | The Procter & Gamble Company | Absorbent articles with odor control system |
AT2256U1 (de) * | 1997-10-15 | 1998-07-27 | Chemiefaser Lenzing Ag | Verfahren zur behandlung von cellulosischen formkörpern |
-
2001
- 2001-12-20 AT AT0201201A patent/AT413988B/de not_active IP Right Cessation
-
2002
- 2002-12-16 TW TW091136278A patent/TWI273148B/zh not_active IP Right Cessation
- 2002-12-19 AU AU2002361375A patent/AU2002361375A1/en not_active Abandoned
- 2002-12-19 JP JP2003554976A patent/JP2005535790A/ja active Pending
- 2002-12-19 AT AT02796479T patent/ATE483848T1/de not_active IP Right Cessation
- 2002-12-19 EP EP02796479A patent/EP1463858B1/de not_active Expired - Lifetime
- 2002-12-19 CN CNB028253175A patent/CN1311123C/zh not_active Expired - Fee Related
- 2002-12-19 KR KR1020047009441A patent/KR100910989B1/ko active IP Right Grant
- 2002-12-19 WO PCT/AT2002/000362 patent/WO2003054283A2/de active Application Filing
- 2002-12-19 DE DE50214703T patent/DE50214703D1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR100910989B1 (ko) | 2009-08-05 |
AU2002361375A8 (en) | 2003-07-09 |
JP2005535790A (ja) | 2005-11-24 |
TW200301325A (en) | 2003-07-01 |
ATA20122001A (de) | 2005-11-15 |
EP1463858A2 (de) | 2004-10-06 |
KR20040070238A (ko) | 2004-08-06 |
TWI273148B (en) | 2007-02-11 |
CN1604979A (zh) | 2005-04-06 |
CN1311123C (zh) | 2007-04-18 |
WO2003054283A3 (de) | 2004-08-05 |
AU2002361375A1 (en) | 2003-07-09 |
WO2003054283A2 (de) | 2003-07-03 |
AT413988B (de) | 2006-08-15 |
DE50214703D1 (de) | 2010-11-18 |
ATE483848T1 (de) | 2010-10-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AT403296B (de) | Verfahren zur herstellung eines celluloseformkörpers | |
EP3011085B1 (de) | Polysaccharidfaser und verfahren zu ihrer herstellung | |
EP0943027B1 (de) | Verfahren zur behandlung von cellulosischen formkörpern | |
EP2329074B1 (de) | Verfahren zur behandlung cellulosischer formkörper | |
AT402932B (de) | Celluloseschwamm und verfahren zu dessen herstellung | |
AT507758A1 (de) | Yarn and threads from blends of fibres and articles therefrom | |
EP1537261B1 (de) | Verfahren zur herstellung cellulosischer formkorper | |
EP1463858B1 (de) | Verfahren zur behandlung von cellulosischen formkörpern | |
EP0796358B1 (de) | Cellulosefaser | |
EP0726974A1 (de) | Verfahren zur herstellung cellulosischer formkörper | |
WO2005118923A1 (de) | Verfahren zur herstellung von cellulosischen formkörpern | |
DE102007014272A1 (de) | Verfahren zur Flammschutzausrüstung von Baumwolle | |
WO2012107362A1 (de) | Verfahren zur verformung von cellulosecarbamat und produkte, die nach diesem verfahren hergestellt werden | |
AT402828B (de) | Modifizierte viskosefasern, verfahren zu ihrer herstellung und ihre verwendung | |
EP1440190B1 (de) | Verfahren zur behandlung von lösungsmittelgesponnenen cellulosischen fasern | |
EP0901533B1 (de) | Verfahren zur herstellung eines verfestigten faserverbundes | |
WO1998055673A1 (de) | Regenerierter cellulosischer formkörper | |
EP0783602B1 (de) | Cellulosefaser | |
AT507051B1 (de) | Cellulosefaser und verfahren zu ihrer herstellung | |
DE102005027349A1 (de) | Verfahren und Vorrichtung zum Nachbehandeln venetzter Cellulose-Fasern mit einer Bisulfitverbindung | |
DE10048681B4 (de) | Verfahren zur Modifizierung der Anfärbbarkeit und der Erhöhung des Naßmoduls von Celluloseformkörpern | |
US20050121832A1 (en) | Process for the treatment of cellulosic moulded bodies | |
DE19501290A1 (de) | Formkörper aus regenerierter Cellulose | |
CH351364A (de) | Verfahren zur Herstellung von Gebilden aus modifizierter Viskose |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20040607 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: LENZING AKTIENGESELLSCHAFT |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: D06M 101/06 20060101ALI20100408BHEP Ipc: D06M 15/03 20060101ALI20100408BHEP Ipc: D06M 13/358 20060101AFI20100408BHEP |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REF | Corresponds to: |
Ref document number: 50214703 Country of ref document: DE Date of ref document: 20101118 Kind code of ref document: P |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: VDEP Effective date: 20101006 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110106 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110207 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
BERE | Be: lapsed |
Owner name: LENZING A.G. Effective date: 20101231 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110107 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110117 Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101231 Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20110831 |
|
26N | No opposition filed |
Effective date: 20110707 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20110106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101231 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101231 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101231 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110103 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 50214703 Country of ref document: DE Effective date: 20110707 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 50214703 Country of ref document: DE Effective date: 20110701 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110106 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110701 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101219 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 483848 Country of ref document: AT Kind code of ref document: T Effective date: 20101219 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101219 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |