EP1463858A2 - Verfahren zur behandlung von cellulosischen formkörpern - Google Patents
Verfahren zur behandlung von cellulosischen formkörpernInfo
- Publication number
- EP1463858A2 EP1463858A2 EP02796479A EP02796479A EP1463858A2 EP 1463858 A2 EP1463858 A2 EP 1463858A2 EP 02796479 A EP02796479 A EP 02796479A EP 02796479 A EP02796479 A EP 02796479A EP 1463858 A2 EP1463858 A2 EP 1463858A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- cyclodextrin
- textile auxiliary
- hydroxy
- cellulosic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Definitions
- the invention relates to a ner process for the treatment of cellulosic molded articles which are produced from a solution of the cellulose in an aqueous tertiary amine oxide, in particular fibers and structures which contain these fibers, in which ner process the foam articles are brought into contact with a textile auxiliary in order to To give moldings improved properties.
- molded body in particular also includes sponges.
- a ner process for producing a solvent-spun cellulose fiber has prevailed until industrial implementation.
- a tertiary amine oxide in particular ⁇ -methylmorpholine- ⁇ -oxide ( ⁇ MMO)
- ⁇ MMO ⁇ -methylmorpholine- ⁇ -oxide
- Such a ner driving is e.g. described in US Pat. No. 4,246,221 and delivers fibers which are distinguished by high strength, a high modulus of elasticity and by a high loop strength.
- WO 99/19555 describes a ner process for the treatment of solvent-spun. Fibers in which the fibers are brought into contact with 2,4-dichloro-6-hydroxy-1.3.5-triazine or with a salt thereof. The fibers produced in this way are characterized by better resistance to fibrillation.
- No. 5,728,823 discloses cyclodextrin derivatives, including the sodium salt of 2-chloro-4-hydroxy-1.3.5-triazinylcyclodextrin. US 5,728,823 also describes Membranes, foils, textiles or leather to which a cyclodextrin derivative is bound. Textiles treated with cyclodextrin derivatives are suitable, for example, for absorbing unpleasant odors.
- WO 01/48025 describes cyclodextrins which are covalently bound to a polysaccharide by means of a wetting agent.
- cellulosic moldings which are prepared from a solution of the cellulose in an aqueous tertiary amine oxide can be treated with a textile auxiliary which comprises a cyclodextrin and / or a cyclodextrin derivative, thereby producing products with improved properties.
- the shaped bodies are preferably fibers in a never-dried state.
- the fibers can be treated in a never-dried state in a post-treatment stage of a continuously operating production plant.
- cyclodextrins can include active ingredients which are then released, for example, over a longer period of time.
- the treatment with the textile auxiliary is preferably carried out in an alkaline environment.
- the textile auxiliary also preferably comprises a crosslinking agent.
- Particularly preferred wetting agent is 2,4-dichloro-6-hydroxy-1,3,5-triazine or a salt thereof.
- a cyclodextrin derivative e.g. the sodium salt of 2-chloro-4-hydroxy-1.3.5-triazinylcyclodextrin, are prepared in order to subsequently apply this derivative to the material to be treated.
- the fibers to be treated can be added with the cyclodextrin and a wetting agent, in particular 2,4-dichloro-6-hydroxy-1.3.5-triazine, without having to prepare a nerbinding from these two substances beforehand and get good results.
- the textile auxiliary comprises 2-chloro-4-hydroxy-1.3.5-triazinyl-cyclodextrin (MCT-CD) or a salt thereof.
- the invention also relates to a solvent-spun cellulosic fiber which can be obtained by the process according to the invention, and to fiber structures which contain these fibers.
- Solvent-spun fibers with a titer of 1.3 dtex produced according to the process described in WO 93/19230 were treated in the never-dried state as follows:
- the fibers were washed at a liquor ratio of 1:10 with a solution containing 20 g / 1 sodium salt of 2,4-dichloro-6-hydroxy-1,3.5-triazine, 16 g / 1 NaOH and 100 g / 1 of a cyclodextrin ( CAVAMAX W7, manufacturer Wacker-Chemie) impregnated for 5 minutes at room temperature.
- the fibers were then squeezed to a moisture content of 100% -110% using a squeeze mechanism and heat-treated for 5 minutes with saturated steam (100%) at 100 ° C., washed out and dried.
- the content of active cyclodextrin in the fibers thus produced was determined photometrically (552 nm) using the decolorization of a phenolphthalein solution and was 2.33% by weight.
- the degree of fibrillation on the fibers was determined on the basis of the wet scrub resistance (test method according to WO 99/19555) of the individual fibers. According to this test method, the sample treated according to the invention has an average value of 210 revolutions. In comparison, an untreated fiber shows a wet abrasion value of only 40-60 revolutions. - - -
- Example 2 The procedure was as in Example 1, with the treatment solution 20 g / 1 sodium salt of 2,4-dichloro-6-hydroxy-1.3.5-triazine, 16 g / 1 NaOH, 30 g / 1 soda and 50 g / 1 one Cyclodextrins (CAVAMAX W7, manufacturer Wacker-Chemie) contained.
- the active cyclodextrin content in the fibers thus obtained was 1.65% by weight, the wet abrasion value was 470 revolutions.
- Example 2 The procedure was as in Example 1, with the treatment solution 30 g / 1 soda and 100 g / 1 2-chloro-4-hydroxy-1.3.5-triazinyl-cyclodextrin (MCT-CD; CAVASOL W7 MCT, manufacturer Wacker- Chemistry) contained.
- MCT-CD 2-chloro-4-hydroxy-1.3.5-triazinyl-cyclodextrin
- the active MCT-CD content in the fibers thus obtained was 1.89% by weight.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0201201A AT413988B (de) | 2001-12-20 | 2001-12-20 | Verfahren zur behandlung von cellulosischen formkörpern |
AT20122001 | 2001-12-20 | ||
PCT/AT2002/000362 WO2003054283A2 (de) | 2001-12-20 | 2002-12-19 | Verfahren zur behandlung von cellulosischen formkörpern |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1463858A2 true EP1463858A2 (de) | 2004-10-06 |
EP1463858B1 EP1463858B1 (de) | 2010-10-06 |
Family
ID=3689615
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02796479A Expired - Lifetime EP1463858B1 (de) | 2001-12-20 | 2002-12-19 | Verfahren zur behandlung von cellulosischen formkörpern |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1463858B1 (de) |
JP (1) | JP2005535790A (de) |
KR (1) | KR100910989B1 (de) |
CN (1) | CN1311123C (de) |
AT (2) | AT413988B (de) |
AU (1) | AU2002361375A1 (de) |
DE (1) | DE50214703D1 (de) |
TW (1) | TWI273148B (de) |
WO (1) | WO2003054283A2 (de) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100415980C (zh) * | 2006-09-21 | 2008-09-03 | 浙江理工大学 | 一种环糊精-酞菁双重模拟酶功能纤维的制备方法 |
CN100392172C (zh) * | 2006-09-21 | 2008-06-04 | 浙江理工大学 | 环糊精聚合物模拟酶功能纤维的制备方法 |
CN100392173C (zh) * | 2006-09-21 | 2008-06-04 | 浙江理工大学 | 环糊精模拟酶功能纤维的制备方法 |
CN100398741C (zh) * | 2006-09-21 | 2008-07-02 | 浙江理工大学 | 一种环糊精-酞菁双重模拟酶功能纤维的制造方法 |
CN101220557B (zh) * | 2007-12-06 | 2010-06-02 | 浙江理工大学 | 一种模拟酶催化纤维的制备方法 |
AT506334B1 (de) * | 2008-01-22 | 2010-12-15 | Chemiefaser Lenzing Ag | Verfahren zur behandlung cellulosischer formkörper |
AT509289B1 (de) * | 2009-12-28 | 2014-06-15 | Chemiefaser Lenzing Ag | Funktionalisierter cellulosischer formkörper und verfahren zu seiner herstellung |
JP4832573B2 (ja) * | 2010-02-27 | 2011-12-07 | 慶一郎 金久 | 繊維構造物の抗ウィルス・制菌加工法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5102564A (en) * | 1989-04-12 | 1992-04-07 | The Procter & Gamble Company | Treatment of fabric with perfume/cyclodextrin complexes |
US5534165A (en) * | 1994-08-12 | 1996-07-09 | The Procter & Gamble Company | Fabric treating composition containing beta-cyclodextrin and essentially free of perfume |
DE4429229A1 (de) * | 1994-08-18 | 1996-02-22 | Consortium Elektrochem Ind | Cyclodextrinderivate mit mindestens einem stickstoffhaltigen Heterozyklus, ihre Herstellung und Verwendung |
DE19520967A1 (de) * | 1995-06-08 | 1996-12-12 | Consortium Elektrochem Ind | Textiles Material oder Leder, welches mit Cyclodextrinderivaten mit mindestens einem stickstoffhaltigen Heterozyklus ausgerüstet ist |
EP0946209A2 (de) * | 1996-12-17 | 1999-10-06 | The Procter & Gamble Company | Absorbierende artikel mit einem geruchskontrollesystem |
AT2256U1 (de) * | 1997-10-15 | 1998-07-27 | Chemiefaser Lenzing Ag | Verfahren zur behandlung von cellulosischen formkörpern |
-
2001
- 2001-12-20 AT AT0201201A patent/AT413988B/de not_active IP Right Cessation
-
2002
- 2002-12-16 TW TW091136278A patent/TWI273148B/zh not_active IP Right Cessation
- 2002-12-19 AU AU2002361375A patent/AU2002361375A1/en not_active Abandoned
- 2002-12-19 JP JP2003554976A patent/JP2005535790A/ja active Pending
- 2002-12-19 AT AT02796479T patent/ATE483848T1/de not_active IP Right Cessation
- 2002-12-19 EP EP02796479A patent/EP1463858B1/de not_active Expired - Lifetime
- 2002-12-19 CN CNB028253175A patent/CN1311123C/zh not_active Expired - Fee Related
- 2002-12-19 KR KR1020047009441A patent/KR100910989B1/ko active IP Right Grant
- 2002-12-19 WO PCT/AT2002/000362 patent/WO2003054283A2/de active Application Filing
- 2002-12-19 DE DE50214703T patent/DE50214703D1/de not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO03054283A2 * |
Also Published As
Publication number | Publication date |
---|---|
KR100910989B1 (ko) | 2009-08-05 |
AU2002361375A8 (en) | 2003-07-09 |
JP2005535790A (ja) | 2005-11-24 |
TW200301325A (en) | 2003-07-01 |
ATA20122001A (de) | 2005-11-15 |
KR20040070238A (ko) | 2004-08-06 |
TWI273148B (en) | 2007-02-11 |
CN1604979A (zh) | 2005-04-06 |
CN1311123C (zh) | 2007-04-18 |
WO2003054283A3 (de) | 2004-08-05 |
EP1463858B1 (de) | 2010-10-06 |
AU2002361375A1 (en) | 2003-07-09 |
WO2003054283A2 (de) | 2003-07-03 |
AT413988B (de) | 2006-08-15 |
DE50214703D1 (de) | 2010-11-18 |
ATE483848T1 (de) | 2010-10-15 |
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