EP1459005B1 - Method of preparing aerogel-containing insulation article - Google Patents

Method of preparing aerogel-containing insulation article Download PDF

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Publication number
EP1459005B1
EP1459005B1 EP02798574A EP02798574A EP1459005B1 EP 1459005 B1 EP1459005 B1 EP 1459005B1 EP 02798574 A EP02798574 A EP 02798574A EP 02798574 A EP02798574 A EP 02798574A EP 1459005 B1 EP1459005 B1 EP 1459005B1
Authority
EP
European Patent Office
Prior art keywords
container
aerogel particles
air pressure
volume
sealed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
EP02798574A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1459005A1 (en
Inventor
Stephane F. Rouanet
David J. Spelman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cabot Corp
Original Assignee
Cabot Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cabot Corp filed Critical Cabot Corp
Priority to EP05020333A priority Critical patent/EP1614954B1/en
Publication of EP1459005A1 publication Critical patent/EP1459005A1/en
Application granted granted Critical
Publication of EP1459005B1 publication Critical patent/EP1459005B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00—Thermal insulation in general
    • F16L59/06—Arrangements using an air layer or vacuum
    • F16L59/065—Arrangements using an air layer or vacuum using vacuum
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00—Thermal insulation in general
    • F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
    • F16L59/026—Mattresses, mats, blankets or the like
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00—Thermal insulation in general
    • F16L59/06—Arrangements using an air layer or vacuum
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49826—Assembling or joining
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49826—Assembling or joining
    • Y10T29/49879—Spaced wall tube or receptacle
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23—Sheet including cover or casing
    • Y10T428/231—Filled with gas other than air; or under vacuum

Definitions

  • This invention pertains to a method of preparing an insulation article.
  • Insulation articles are used in a variety of applications to provide an insulation layer.
  • insulation articles typically in the form of panels, are used in refrigerators to provide the necessary insulation between the cold interior and the warmer exterior.
  • Insulation articles are formed in many ways, though, typically, insulation articles are formed by filling panels and other cavities with insulating materials, such as insulating fibers and powders. Such a preparation process, however, is often cumbersome and does not result in an insulation article with the most optimum thermal conductivity characteristics.
  • the invention provides a method of preparing an insulation article that minimizes the handling of the insulation material and maximizes the thermal conductivity characteristics of the resulting insulation article.
  • the inventive method of preparing an insulation article comprises providing a sealed first container comprising aerogel particles under a first air pressure that is less than atmospheric pressure.
  • the unrestrained volume of the aerogel particles at the first air pressure is less than the unrestrained volume of the aerogel particles under a second air pressure that is greater than the first air pressure.
  • the sealed first container then is placed within a second container, and the sealed first container is breached to equalize the air pressure between the first and second containers at the second air pressure and to increase the volume of the aerogel particles, thereby forming the insulation article.
  • the invention provides a method of preparing an insulation article.
  • the method of preparing the insulation article comprises providing a sealed first container and a second container.
  • the sealed first container comprises aerogel particles under a first air pressure that is less than atmospheric pressure.
  • the unrestrained volume of the aerogel particles at the first air pressure is less than the unrestrained volume of the aerogel particles under a second air pressure that is greater than the first air pressure.
  • the sealed first container then is placed within the second container that is at an air pressure greater than the air pressure present in the sealed first container.
  • the air pressure between the first and second containers is equalized at the second air pressure.
  • the volume of the aerogel particles accordingly increases to fill the second container, thereby forming the insulation article.
  • the first and second containers can be any suitable containers.
  • the first container must be capable of containing aerogel particles under an air pressure that is less than atmospheric pressure.
  • the first container must be capable of being breached so as to allow the volume of the aerogel particles to expand upon being exposed to the higher, equalized air pressure between the first and second containers.
  • the second container is larger than the first container so that the first container can be placed within the second container. While the second container need not be sealable, the second container desirably is sealable to retain the aerogel particles within the second container upon the breach of the sealed first container and the expansion of the volume of the aerogel particles upon being exposed to the higher, equalized air pressure between the first and second containers.
  • the first and second containers can be formed of any suitable material(s) and can be rigid or flexible. It is particularly desirable that the first container consist essentially of, preferably consist of, a film, e.g., a polyester or shrink-wrap film, that is of a relatively thin gauge so as to be easy to breach by puncture or by exposure to heat. It is similarly desirable that the second container comprise, preferably consist of, a film that is of a relatively thicker gauge or of a material that does not breach upon exposure to the same level of heat as would cause the breach of the first container and desirably is sealed by that same heat.
  • a film e.g., a polyester or shrink-wrap film
  • the aerogel can be any suitable aerogel.
  • a "gel” refers to a coherent, rigid, continuous three-dimensional network of colloidal particles. Gels are produced by the aggregation of colloidal particles (typically under acidic conditions when neutralizing salts are absent) to form a three dimensional gel microstructure. When a gel is dried ( i . e ., when liquid is removed from the pores) by means in which the coherent gel microstructure is preserved, such as by supercritical drying, a low-density gel or an "aerogel” is formed.
  • a suitable process for the production of an aerogel is described in U.S. Patent 3,122,520.
  • the aerogel preferably is a metal oxide aerogel, particularly a silica aerogel.
  • Aerogel particles have highly desirable properties such as, for example, optical transparency, extremely low density, and very low thermal conductivity. Accordingly, aerogel particles are advantageously used as an insulating material.
  • the aerogel particles can have any suitable diameter.
  • the diameter of substantially all of the aerogel particles is about 0.5 mm or more (e.g., about 1 mm or more). More preferably, the diameter of substantially all of the aerogel particles is about 5 mm or less (e.g., about 0.5 or 1 mm to about 5 mm).
  • the aerogel particles can have any suitable density, preferably about 0.05 g/cm 3 to about 0.15 g/cm 3 .
  • the aerogel particles also can have any suitable surface area, preferably at least about 200 m 2 /g.
  • the surface area described herein is calculated based on the amount of nitrogen adsorbed at five different relative pressures over the range 0.05 to 0.25 atm according to the Brunauer-Emmett-Teller (BET) model, referenced in Gregg, S.J., and Sing, K.S.W., "Adsorption, Surface Area and Porosity,” p. 285, Academic Press, New York (1991).
  • BET Brunauer-Emmett-Teller
  • the aerogel particles in the sealed first container are under a first air pressure that is less than atmospheric pressure, which generally can be regarded as about 100 kPa (but which varies depending on the altitude at which the sealed first container comprising the aerogel particles is prepared).
  • the air pressure in the first container i.e., the first air pressure, can be obtained in any suitable manner, e.g., by establishing at least a partial vacuum within the first container, which vacuum can be created using conventional equipment.
  • the air pressure within the first container desirably is about 50 kPa or less (e.g., about 10-50 kPa), preferably about 20 kPa or less (e.g., about 1-20 kPa), and more preferably about 10 kPa or less (e.g., about 1 kPa or less or even about 0.1 kPa or less).
  • the air pressure in the second container i.e., the second air pressure
  • the air pressure in the second container will be atmospheric pressure (e.g., about 100 kPa), although the air pressure in the second container can be different from atmospheric pressure, i.e., lower or higher than atmospheric pressure.
  • the unrestricted volume of the aerogel particles within the sealed first container at the first air pressure is less than the unrestricted volume of the aerogel particles under a second air pressure that is greater than the first air pressure.
  • the term "unrestrained” is meant to exclude the effect of any restraint by the container, so that the volume of the aerogel particles is considered based on the effect of the air pressure alone.
  • the aerogel particles in the first container typically will have an unrestrained volume that is less than the unrestrained volume at substantially atmospheric pressure, which usually will be the second air pressure to which the aerogel particles are subjected in the final product of the insulation article.
  • the unrestrained volume of the aerogel particles at the second air pressure can be less than, greater than, or substantially the same as the volume of the second container.
  • aerogel particles can underfill, overfill, or merely fill the second container.
  • the aerogel particles merely fill or overfill the second container, such that the unrestrained volume of the aerogel particles at the second air pressure is substantially the same as or, more preferably, greater than the volume of the second container.
  • the overfilling of the second container with the aerogel particles is preferred because of the improvement in the insulating characteristics of the resulting insulation article.
  • the unrestrained volume of the aerogel particles at the second air pressure preferably is about 10% or more (e.g., about 10-30%) greater than the volume of the first container.
  • Such an overfilling of the second container can be accomplished by ensuring that the unrestrained volume of the aerogel particles at the second air pressure is larger than the volume of the second container and then ensuring that the actual volume of the aerogel particles at the first air pressure can be made small enough by a reduction in air pressure in the first container and optionally restraint on the volume of the aerogel particles (e.g., by the first container itself) so that the sealed first container comprising the aerogel particles can fit within the second container.
  • the breaching of the sealed first container and the exposure of the aerogel particles therein to the second air pressure will cause the aerogel particles to expand and fill (desirably, overfill) the second container to its volume capacity.
  • the second container need not be sealed, but desirably is sealed to form the insulation article.
  • the second container can be sealed before, after, or while breaching the sealed first container. Since it is desirable to overfill the second container with the aerogel particles, the second container desirably is sealed before or while breaching the sealed first container.
  • the breaching of the sealed first container can be accomplished in any suitable manner. Suitable techniques for breaching the sealed first container include puncturing the sealed first container with a physical device and heating the sealed first container. The heating of the sealed first container to cause a breach is preferred, because such heating can take place while the sealed first container is present in a sealed second container (i.e., a second container that is sealed before the breaching of the sealed first container). Heat can be applied to the sealed first container to cause a breach of that container by any suitable technique, e.g., sonic or microwave energy. Indeed, the manner in which the second container is sealed can be the same manner in which the sealed first container is breached. Thus, for example, if the second container is amenable to heat sealing, then the heat used to seal the second container can be used to breach the sealed first container, desirably in the same procedural step.
  • the first and second containers can comprise other things in addition to the aerogel particles.
  • the first and/or second containers can contain thermally reflective layers to improve the insulating characteristics of the resulting insulation article in certain applications.
  • the first and/or second containers can contain opaque materials, such as carbon black, to improve the insulating characteristics of the resulting insulation article in certain applications.
  • the inventive insulation article can have any suitable properties, e.g., thermal conductivity, light transmission, and handling characteristics.
  • the insulation article desirably has a thermal conductivity at 2.5 °C and/or 12.5 °C of about 20 mw/mk or less (e.g., about 19 mw/mk or less, or even about 18 mw/mk or less).
  • the insulation article desirably has a light transmission/cm thickness of the insulation article of about 50% or more (e.g., about 70% or more, or even about 80% or more).
  • Other desirable characteristics of insulation articles are known to those of ordinary skill in the art, and the inventive insulation article can be tailored to possess such desirable characteristics to fit particular end-uses for the insulation article.
  • the volume of a sample of aerogel particles was measured at atmospheric pressure.
  • This same sample of aerogel particles then was subjected to various reduced air pressures by placing the aerogel particles in a sealed (i.e., air-tight) container and imparting an increasing vacuum to the container.
  • the volume of the aerogel particles was measured at these different reduced pressures and compared to the volume of the aerogel particles at atmospheric pressure.
  • the percentage reduction in the measured volume of the aerogel particles at these different reduced pressures was calculated, and the resulting data is set forth in Table 1 below.
  • this example demonstrates that the volume of aerogel particles can be reduced by exposure to reduced air pressure. Furthermore, this reduction in aerogel particle volume is reversible with an increase in air pressure.
  • This example demonstrates the effect of aerogel packing on the insulation characteristics of the aerogel particles in an insulation article.
  • a container was filled with aerogel particles (particularly, silica aerogel particles) such that the unrestrained volume of aerogel particles was the same as the volume of the container, i.e., the aerogel particles did not overfill the container such that the container restrained the volume of the aerogel particles.
  • An insulation article was thereby prepared, and the apparent thermal conductivity of the insulation article was measured at 2.5 °C and at 12.5 °C.
  • the container then was overfilled to different extents with aerogel particles, and the apparent thermal conductivity of each of the resulting insulation articles was measured at 2.5 °C and at 12.5 °C. The results of these measurements are set forth in Table 2 below. Effect of Aerogel Packing on Article Thermal Conductivity Unrestrained Vol.
  • the container can be overfilled with aerogel particles so as to obtain an optimum thermal conductivity.
  • the unrestrained volume of the aerogel particles is about 10% or more, especially about 10-30%, of the volume of the container, the resulting insulation article achieves an optimum thermal conductivity at both 2.5 C and 12.5 °C.
  • aerogel particles provide an excellent insulation material. Furthermore, this example demonstrates that the unrestrained volume of aerogel particles relative to the volume of the container comprising the aerogel particles can be adjusted so as to provide optimum insulation characteristics for the resulting insulation article.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)
  • Silicon Compounds (AREA)
  • Thermal Insulation (AREA)
EP02798574A 2001-12-21 2002-12-20 Method of preparing aerogel-containing insulation article Expired - Fee Related EP1459005B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05020333A EP1614954B1 (en) 2001-12-21 2002-12-20 Aerogel-containing insulation article

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US36773 2001-12-21
US10/036,773 US6598283B2 (en) 2001-12-21 2001-12-21 Method of preparing aerogel-containing insulation article
PCT/US2002/041147 WO2003056230A1 (en) 2001-12-21 2002-12-20 Method of preparing aerogel-containing insulation article

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP05020333A Division EP1614954B1 (en) 2001-12-21 2002-12-20 Aerogel-containing insulation article

Publications (2)

Publication Number Publication Date
EP1459005A1 EP1459005A1 (en) 2004-09-22
EP1459005B1 true EP1459005B1 (en) 2005-11-09

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EP02798574A Expired - Fee Related EP1459005B1 (en) 2001-12-21 2002-12-20 Method of preparing aerogel-containing insulation article
EP05020333A Expired - Fee Related EP1614954B1 (en) 2001-12-21 2002-12-20 Aerogel-containing insulation article

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Country Status (9)

Country Link
US (1) US6598283B2 (ja)
EP (2) EP1459005B1 (ja)
JP (2) JP4523279B2 (ja)
CN (1) CN1312426C (ja)
AU (1) AU2002364103B2 (ja)
DE (2) DE60219088T2 (ja)
HK (1) HK1072285A1 (ja)
RU (1) RU2293906C2 (ja)
WO (1) WO2003056230A1 (ja)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101118583B1 (ko) * 2003-06-24 2012-02-27 아스펜 에어로겔, 인코퍼레이티드 겔 시트의 제조방법
US7621299B2 (en) * 2003-10-03 2009-11-24 Cabot Corporation Method and apparatus for filling a vessel with particulate matter
US20060035054A1 (en) * 2004-01-05 2006-02-16 Aspen Aerogels, Inc. High performance vacuum-sealed insulations
CA2578623C (en) * 2004-09-01 2013-08-06 Aspen Aerogels, Inc. High performance vacuum-sealed insulations
US20060272727A1 (en) * 2005-06-06 2006-12-07 Dinon John L Insulated pipe and method for preparing same
US7618608B1 (en) 2005-12-13 2009-11-17 Keller Companies, Inc. Aerogel and method of manufacturing same
US7562534B2 (en) * 2006-03-23 2009-07-21 Praxair Technology, Inc. Cryogenic aerogel insulation system
GB2438210B (en) * 2006-05-18 2011-02-16 Corus Uk Ltd Insulation of pipe-in-pipe systems
US7750056B1 (en) 2006-10-03 2010-07-06 Sami Daoud Low-density, high r-value translucent nanocrystallites
CN101679657B (zh) * 2007-03-16 2012-11-14 卡伯特公司 气凝胶颗粒及其制造方法
WO2008118776A2 (en) * 2007-03-23 2008-10-02 Birdair, Inc. Architectural membrane structures and methods for producing them
WO2008144634A2 (en) * 2007-05-18 2008-11-27 Cabot Corporation Filling fenestration units
US7794805B2 (en) * 2007-06-29 2010-09-14 Schlumberger Technology Corporation Thermal insulation barriers
EP2176488B1 (en) * 2007-08-07 2018-11-21 Hunter Douglas Inc. Method for manufacturing a translucent insulated glass panel
DE102008056987A1 (de) * 2008-11-12 2010-05-20 Rwe Power Ag Isolierkassette
WO2010068254A2 (en) 2008-12-10 2010-06-17 Cabot Corporation Insulation for storage or transport of cryogenic fluids
US7930892B1 (en) 2010-02-26 2011-04-26 Whirlpool Corporation Refrigerator with continuous vacuum insulation
US8899000B2 (en) 2010-07-09 2014-12-02 Birdair, Inc. Architectural membrane and method of making same
US10093437B2 (en) 2015-05-20 2018-10-09 David Charles LODA High performance insulation packaging and disbursement system
KR102525551B1 (ko) 2015-08-03 2023-04-25 엘지전자 주식회사 진공단열체 및 냉장고
KR102466469B1 (ko) 2015-08-03 2022-11-11 엘지전자 주식회사 진공단열체 및 냉장고
KR102447245B1 (ko) 2015-08-03 2022-09-27 엘지전자 주식회사 진공단열체 및 냉장고
KR102497139B1 (ko) 2015-08-03 2023-02-07 엘지전자 주식회사 진공단열체
KR102456642B1 (ko) 2015-08-03 2022-10-19 엘지전자 주식회사 진공단열체 및 냉장고
KR20170016188A (ko) 2015-08-03 2017-02-13 엘지전자 주식회사 진공단열체 및 냉장고
KR102529853B1 (ko) 2015-08-03 2023-05-08 엘지전자 주식회사 진공단열체, 진공단열체의 제조방법, 다공성물질패키지, 및 냉장고
KR102529852B1 (ko) 2015-08-03 2023-05-08 엘지전자 주식회사 진공단열체 및 냉장고
KR102502160B1 (ko) 2015-08-03 2023-02-21 엘지전자 주식회사 진공단열체 및 냉장고
KR102442973B1 (ko) 2015-08-03 2022-09-14 엘지전자 주식회사 진공단열체 및 냉장고
CN111412715B (zh) 2015-08-03 2022-11-11 Lg电子株式会社 真空绝热体及冰箱
KR102498210B1 (ko) 2015-08-03 2023-02-09 엘지전자 주식회사 진공단열체 및 냉장고
KR102525550B1 (ko) 2015-08-03 2023-04-25 엘지전자 주식회사 진공단열체 및 냉장고
KR102466470B1 (ko) 2015-08-04 2022-11-11 엘지전자 주식회사 진공단열체 및 냉장고
JP2018178372A (ja) * 2017-04-03 2018-11-15 株式会社竹中工務店 エアロゲルを利用した透光部材
US11047517B2 (en) 2018-10-31 2021-06-29 Praxair Technology, Inc. Modular vacuum insulated piping

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US95256A (en) * 1869-09-28 F n o r m a lv ill i n
US3122520A (en) 1959-10-05 1964-02-25 Dow Corning Method of making silicone rubber fillers
GB1350661A (en) * 1970-06-10 1974-04-18 Micropore International Ltd Thermal insulating materials
US3869334A (en) * 1971-06-10 1975-03-04 Micropore Insulation Limited Insulating materials
JPS5728837B2 (ja) 1973-10-09 1982-06-18
US4273161A (en) 1974-10-09 1981-06-16 Ameron, Inc. Insulated plastic pipe product and method
US4581804A (en) 1975-09-12 1986-04-15 Ameron, Inc. Method for making insulated pipe
FR2360536A1 (fr) 1976-08-05 1978-03-03 Air Liquide Materiau isolant a faible conductibilite thermique constitue d'une structure granulaire compactee
US4251252A (en) 1978-06-23 1981-02-17 Aladdin Industries, Incorporated Method for making vacuum insulated container
JPS55150217A (en) 1979-05-11 1980-11-22 Fuji Electric Co Ltd Method of insulating coil
DE2928695C2 (de) * 1979-07-16 1984-05-30 Grünzweig + Hartmann und Glasfaser AG, 6700 Ludwigshafen Wärmeisolierkörper sowie Verfahren zu seiner Herstellung
JPH02130111A (ja) 1988-11-10 1990-05-18 Kubota Ltd 真空断熱容器の成形方法
US5091233A (en) 1989-12-18 1992-02-25 Whirlpool Corporation Getter structure for vacuum insulation panels
US5500305A (en) 1990-09-24 1996-03-19 Aladdin Industries, Inc. Vacuum insulated panel and method of making a vacuum insulated panel
US5252408A (en) 1990-09-24 1993-10-12 Aladdin Industries, Inc. Vacuum insulated panel and method of forming a vacuum insulated panel
US5376424A (en) 1991-10-02 1994-12-27 Fujimori Kogyo Co., Ltd. Vacuum thermal insulating panel and method for preparing same
US5273801A (en) 1991-12-31 1993-12-28 Whirlpool Corporation Thermoformed vacuum insulation container
JPH07269779A (ja) 1994-03-28 1995-10-20 Toshiba Corp 断熱筐体及び真空断熱パネルの製造方法
US5527411A (en) 1995-03-31 1996-06-18 Owens-Corning Fiberglas Technology, Inc. Insulating modular panels incorporating vacuum insulation panels and methods for manufacturing
US6143400A (en) 1995-09-11 2000-11-07 Hoechst Research & Technology Deutchland Gmbh & Co. Kg Aerogel and adhesive-containing composite, process for its production and its use
DE19624066A1 (de) 1996-06-17 1997-12-18 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen
KR0161824B1 (ko) 1996-07-05 1999-01-15 김광호 진공단열패널의 제조장치 및 그 제조방법
JPH10146910A (ja) 1996-11-20 1998-06-02 C I Kasei Co Ltd エアロゲル断熱パネル
JPH10209040A (ja) 1996-11-25 1998-08-07 Nikon Corp 露光装置
US5928723A (en) 1997-04-09 1999-07-27 Cabot Corporation Progress for producing surface modified metal oxide compositions
JP3935556B2 (ja) 1997-05-20 2007-06-27 大日本印刷株式会社 断熱材及びその製造方法
JP3149817B2 (ja) 1997-05-30 2001-03-26 日本電気株式会社 半導体装置およびその製造方法
US6148519A (en) 1998-09-18 2000-11-21 Donaldson Company, Inc. Apparatus for installing a packing material in a muffler assembly; and methods thereof
US6132837A (en) 1998-09-30 2000-10-17 Cabot Corporation Vacuum insulation panel and method of preparing the same
JP3921580B2 (ja) 1998-10-26 2007-05-30 三菱電機株式会社 断熱箱体の製造方法
JP2000160721A (ja) * 1998-11-26 2000-06-13 Matsushita Electric Works Ltd シリカエアロゲルパネルの製造方法
US20020114937A1 (en) * 2000-04-06 2002-08-22 Albert Donald F. Insulated barriers and methods for producing same

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CN1312426C (zh) 2007-04-25
WO2003056230A1 (en) 2003-07-10
DE60207300D1 (de) 2005-12-15
DE60219088T2 (de) 2007-12-13
US6598283B2 (en) 2003-07-29
JP4523279B2 (ja) 2010-08-11
JP2010107046A (ja) 2010-05-13
US20030115838A1 (en) 2003-06-26
RU2293906C2 (ru) 2007-02-20
JP2005514562A (ja) 2005-05-19
EP1614954B1 (en) 2007-03-21
CN1620574A (zh) 2005-05-25
AU2002364103B2 (en) 2008-05-08
EP1459005A1 (en) 2004-09-22
EP1614954A1 (en) 2006-01-11
DE60207300T2 (de) 2006-08-03
AU2002364103A1 (en) 2003-07-15
JP5390358B2 (ja) 2014-01-15
DE60219088D1 (de) 2007-05-03
RU2004122424A (ru) 2005-04-10
HK1072285A1 (en) 2005-08-19

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