EP1454015B1 - Feuille ayant un toucher rugueux - Google Patents

Feuille ayant un toucher rugueux Download PDF

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Publication number
EP1454015B1
EP1454015B1 EP02799771A EP02799771A EP1454015B1 EP 1454015 B1 EP1454015 B1 EP 1454015B1 EP 02799771 A EP02799771 A EP 02799771A EP 02799771 A EP02799771 A EP 02799771A EP 1454015 B1 EP1454015 B1 EP 1454015B1
Authority
EP
European Patent Office
Prior art keywords
sheet
particles
parts
dry weight
plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02799771A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1454015A1 (fr
Inventor
Thierry Mayade
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArjoWiggins Rives
Original Assignee
ArjoWiggins Rives
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ArjoWiggins Rives filed Critical ArjoWiggins Rives
Publication of EP1454015A1 publication Critical patent/EP1454015A1/fr
Application granted granted Critical
Publication of EP1454015B1 publication Critical patent/EP1454015B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/253—Cellulosic [e.g., wood, paper, cork, rayon, etc.]

Definitions

  • the present invention relates to a sheet having a rough feel.
  • the Applicant was particularly interested in providing a sheet which, without being very rough or abrasive, however, has a certain granular appearance only sensitive to touch, its surface appearing perfectly smooth with the naked eye.
  • the Applicant has protected a sheet having a touch making it possible to recall a specific characteristic of the contents of a package, in particular for the packaging of cosmetic products and, in this case, in the patent FR 2 791 368 .
  • WO-A-0157315 discloses a wear-resistant paper for decorative purposes, the paper having abrasion-resistant particles and microspheres larger than those of the particles and having the function of separating and spacing the particles.
  • US Patent 4,849,265 discloses a flexible sheet substrate, one side of which is covered with balls, which are held on this face by an adhesive, these beads making it possible to improve the resistance of the water side, the abrasion, etc., and to confer on this face an ornamental aspect.
  • GB-A-1401533 discloses a package comprising a sheet material provided with a surface finishing composition consisting of microspheres or balls incorporated in a substance, such as a varnish or a lacquer.
  • a substance such as a varnish or a lacquer.
  • the Applicant aims to provide a rough but pleasant touch sheet, that is to say, not hanging on the finger.
  • Sheets must also be printable, have whiteness characteristics, be manipulable for example.
  • the Applicant has sought particles that meet these goals.
  • starch grains of potato starch are of quasi-spherical or oval shape, have an average size distribution of 28 micrometers and consist of large particles, but few.
  • the Applicant has also been able to observe that the "rough" feel is not obtained with all types of starch, in particular that a coating of corn starch grains does not give the desired rough feeling.
  • the explanation is that the particles are small, their average diameter being below 15 micrometers, and their particle size rather undifferentiated.
  • corn starch grains are spread out in an even layer, matching the relief of the leaf on which they apply.
  • the particles must be large enough to be flush with the layer to be perceived by the manipulator.
  • the particles should be slightly angular so as to create a sensation of rough touch light, even pleasant.
  • silica or corundum grains such as those used to make abrasives are not suitable for the desired touch, the particles having a fractured geometry too aggressive.
  • the particles will have a relatively spherical and voluminous geometry, which also excludes platelet particles such as talc.
  • the particles must be non-deformable.
  • materials such as rubber or expanded microbeads are unsuitable because of their compressible and elastic nature, imparting a gummy and non-rough feel to the coated sheet.
  • the invention relates to a sheet according to claim 1.
  • the invention is characterized in that the particles have an average diameter greater than 25 micrometers, and preferably less than 200 micrometers.
  • the invention is characterized in that the particles have an almost spherical shape.
  • the particles are starch grains of potato starch.
  • the particles may also be crushed plastic, the plastic preferably being a polyamide, a polyester, a polyolefin or a PVC.
  • the invention is characterized in that the distribution of particles on the surface is between 20 and 250 particles per mm 2 .
  • this distribution can be determined by topological analysis of the surface of the sheet obtained.
  • the grammage of the sheet obtained will be between 50 and 500 g / m 2 .
  • the weight of the layer on each coated face is between 3 and 30 g / m 2 dry weight, preferably between 5 and 18 g / m 2 dry weight.
  • the binder is chosen from styrene butadiene latices, acrylic latices, vinyl latices, solubilized starches, polyvinyl alcohol, proteins, especially casein, gelatin or soy protein, nitrocellulose, plastisol, glycerophthalic resins, epoxy resins, polyesters.
  • the fillers are chosen from calcium carbonate, kaolin, talc, titanium dioxide, barium sulfate, precipitated or fumed silica, and plastic pigments.
  • compositions such as waxes, rheology modifiers, defoamers, leveling agents, bactericides or fungicides, etc. may also take place in the coating composition.
  • the sheet has a dynamic coefficient of friction measured according to standard NF Q 03-082 on blotting paper less than 0.5.
  • the invention also relates to the method of coating a sheet.
  • step a) is carried out using a coating device chosen from the gravure roll coaters, or gravity rollers, which correspond to the co-operating roller coaters.
  • a coating device chosen from the gravure roll coaters, or gravity rollers, which correspond to the co-operating roller coaters.
  • step a) is carried out using a spraying device.
  • the invention also relates to the use of a sheet as described above for manufacturing a printing medium of paper or plastic, a paper or plastic packaging, a cover for binding, a cardboard or plastic box.
  • the Figure 1A and 1B represent scanning electron microscope observations of a sheet of coated paper with starch grains of potato starch respectively at 50 and 750-fold magnification.
  • the figure 1C represents the same leaf but seen in section at a magnification of 1000 times.
  • the Figures 2A and 2B represent a sheet of paper coated with corn starch grains respectively at a magnification of 50 and 750 times.
  • the Figure 2C represents the same leaf seen in section at a magnification of 1000 times.
  • the Figures 3A and 3B represent a sheet of coated paper with starch grains of potato starch and calcium carbonate as filler respectively at a magnification of 50 and 750 times.
  • the figure 3C represents the same leaf seen in section at a magnification of 1000 times.
  • the Figures 4A and 4B represent a sheet of paper coated with silica particles respectively at a magnification of 50 and 750 times.
  • the figure 4C represents the same leaf seen in section at a magnification of 1000 times.
  • the figure 5 represents a sheet of coated paper with expanded thermoplastic microspheres, type EXPANCEL 820 ® marketed by Expancel at a magnification of 500 times.
  • the figure 6 represents a sheet of coated paper with glass microbeads at a magnification of 500 times.
  • the figure 7 represents a sheet of coated paper with alumina particles at a magnification of 500 times.
  • the figure 8 represents a sheet of paper coated with wheat starch grains at a magnification of 500 times.
  • the starch has a rather heterogeneous distribution on the leaf, small grains coming either to agglutinate around larger grains or to settle in isolation and at random on the paper.
  • the finger will go from a hollow to a bump quite frequently, the height separating them being at least 25 micrometers.
  • the finger will go from one grain peak to another grain peak, the distance separating them being at most 10 micrometers.
  • the Applicant has also been able to observe a feeling of increased roughness when adding fillers, in particular calcium carbonate.
  • calcium carbonate a particle of size close to a micrometer, covers the surface of starch grains, which lose their surface smoothness and become more eye-catching.
  • FIGS. 4A, 4B and 4C identify another case that the plaintiff voluntarily excluded, that of a paper coated with angular particles of silica.
  • the figure 4C shows in particular the very angular and uneven nature of the silica particles, incompatible with a pleasant rough feel.
  • the sheet obtained nevertheless has a degree of roughness that is not very aggressive, it is due only to the small proportion of silica particles added and the low relief thus created.
  • the figure 5 shows, for its part, the surface of a sheet covered with expanded thermoplastic microbeads of EXPANCEL type.
  • the figure 6 shows, on the contrary, the surface of a sheet covered with glass microbeads.
  • the Figures 7 and 8 confirm that a pleasant "rough" feel can not be achieved by using alumina, or wheat starch.
  • alumina particles too angular, give a roughness to the surface, not pleasant to the touch.
  • wheat starch produces a surface quite similar to that of corn starch; as a result, the rough character will be almost imperceptible.
  • the thus treated sheet is dried at about 150 ° C.
  • a coating composition containing starch grains of potato starch and calcium carbonate as fillers is applied by means of a laboratory gluing press. at a rate of 22.5 g / m 2 .
  • the thus treated sheet is dried at about 150 ° C.
  • a coating composition containing glass microbeads On one side of a sheet of paper is deposited, using a laboratory gluing press, a coating composition containing glass microbeads, at a rate of 47 g / m 2 .
  • the Applicant has also endeavored to characterize the pleasant surface roughness of the sheets obtained, other than by a tactile assessment performed by a manipulator taken at random, a method that can be considered too subjective.
  • the Applicant has measured the coefficient of dynamic friction according to the French standard NF Q 03-082.
  • the standard based on the measurement of the tensile force required to initiate and then maintain the displacement from one surface to another can be applied to the evaluation of the slippage of one sheet of the material to be measured on another reference material.
  • the Applicant has therefore chosen as a reference material a blotting paper, weight of 275 g / m 2 , which meets the requirements of the ISO 5269-1 in its paragraph 4.4.
  • Table 1 shows the measurements made for different coating compositions, by varying the particles introduced.
  • thermoexpansed microspheres such as EXPANCEL-type thermoexpansed microspheres, alumina particles, wheat starch granules or rubber powder are therefore excluded.

Landscapes

  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Materials For Medical Uses (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Wrappers (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)
  • Push-Button Switches (AREA)
  • Steering Devices For Bicycles And Motorcycles (AREA)
  • Cartons (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP02799771A 2001-12-04 2002-12-04 Feuille ayant un toucher rugueux Expired - Lifetime EP1454015B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0115661 2001-12-04
FR0115661A FR2833022B1 (fr) 2001-12-04 2001-12-04 Feuille ayant un toucher rugueux
PCT/FR2002/004168 WO2003048455A1 (fr) 2001-12-04 2002-12-04 Feuille ayant un toucher rugueux

Publications (2)

Publication Number Publication Date
EP1454015A1 EP1454015A1 (fr) 2004-09-08
EP1454015B1 true EP1454015B1 (fr) 2010-09-29

Family

ID=8870092

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02799771A Expired - Lifetime EP1454015B1 (fr) 2001-12-04 2002-12-04 Feuille ayant un toucher rugueux

Country Status (21)

Country Link
US (1) US8361596B2 (ru)
EP (1) EP1454015B1 (ru)
JP (1) JP4643908B2 (ru)
KR (1) KR100872912B1 (ru)
CN (1) CN100395407C (ru)
AT (1) ATE483064T1 (ru)
AU (1) AU2002364415B8 (ru)
BR (1) BR0206875B1 (ru)
CA (1) CA2468261C (ru)
DE (1) DE60237843D1 (ru)
ES (1) ES2351437T3 (ru)
FR (1) FR2833022B1 (ru)
HK (1) HK1076497A1 (ru)
HU (1) HUP0600860A2 (ru)
MX (1) MXPA04005486A (ru)
NO (1) NO333896B1 (ru)
NZ (1) NZ533809A (ru)
PT (1) PT1454015E (ru)
RU (1) RU2310028C2 (ru)
WO (1) WO2003048455A1 (ru)
ZA (1) ZA200305497B (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008005228A2 (en) 2006-06-30 2008-01-10 Omnova Solutions Inc. Coating compositions and related products and methods
AU2008304584B2 (en) 2007-09-25 2013-02-14 Aetrex Worldwide, Inc. Articles prepared using recycled materials and methods of preparation thereof
NL2009904C2 (nl) * 2012-10-10 2014-04-14 Climate Invest B V Werkwijze voor het vervaardigen van een antislip-folie en een door het uitvoeren van de werkwijze verkregen antislip-folie.
FR3018085A1 (fr) * 2014-02-28 2015-09-04 Arjowiggins Security Element de securite tactile
EP3571349B1 (en) * 2017-01-17 2024-05-22 Neenah, Inc. Texturized printable coating and methods of making and using the same

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615751A (en) * 1968-02-14 1971-10-26 Salvat Editores Process and composition for preventing offsetting of drying printing ink
GB1401533A (en) * 1972-08-02 1975-07-16 British American Tobacco Co Surface finishes
JP2546853B2 (ja) * 1987-09-03 1996-10-23 オーツタイヤ株式会社 装飾性ビーズコートシートおよびその製造方法
JPH026682A (ja) * 1987-12-01 1990-01-10 Honshu Paper Co Ltd 剥離紙用原紙
US5314753A (en) * 1988-12-07 1994-05-24 Stora Feldmuhle Aktiengesellschaft Printing paper and a process for its manufacture
JPH04502350A (ja) * 1988-12-07 1992-04-23 シユトーラ　フエルトミユーレ　アクチエンゲゼルシヤフト 印刷用紙、該印刷用紙の製造法および使用法
US5093159A (en) * 1989-11-06 1992-03-03 National Starch And Chemical Investment Holding Corporation Process for rapidly immobilizing paper coating compositions
DE4322179C2 (de) * 1993-07-03 1997-02-13 Schoeller Felix Jun Papier Aufzeichnungsmaterial für Ink-Jet-Druckverfahren
US5902453A (en) * 1995-09-29 1999-05-11 Mohawk Paper Mills, Inc. Text and cover printing paper and process for making the same
JPH09268495A (ja) * 1996-03-29 1997-10-14 Oji Paper Co Ltd 非塗工紙風合いを有する艶消し塗工紙
US5759346A (en) * 1996-09-27 1998-06-02 The Procter & Gamble Company Process for making smooth uncreped tissue paper containing fine particulate fillers
DE69908472T2 (de) * 1998-03-31 2004-05-06 Oji Paper Co., Ltd. Aufzeichnungsmaterial für das Tintenstrahldruckverfahren
JP2000054291A (ja) * 1998-08-06 2000-02-22 Nippon Zeon Co Ltd 印刷用塗工紙および塗工用組成物
JP3023104B1 (ja) * 1999-01-21 2000-03-21 恵和株式会社 防湿紙
FR2791368B1 (fr) * 1999-03-26 2001-06-01 Arjo Wiggins Sa Feuille avec un toucher "peau" imprimable a des cadences elevees et son procede de fabrication et emballage la comportant
JP3581599B2 (ja) * 1999-04-22 2004-10-27 東亞合成株式会社 防湿性被覆剤組成物および防湿性紙
US6517674B1 (en) * 2000-02-02 2003-02-11 The Mead Corporation Process for manufacturing wear resistant paper
US6572951B2 (en) 2000-03-31 2003-06-03 Nippon Paper Industries Co., Ltd. Printing sheet
JP3872309B2 (ja) * 2000-03-31 2007-01-24 日本製紙株式会社 印刷用受像シート
JP2002003801A (ja) * 2000-06-19 2002-01-09 Oji Paper Co Ltd 段ボール用接着剤

Also Published As

Publication number Publication date
EP1454015A1 (fr) 2004-09-08
MXPA04005486A (es) 2005-04-19
RU2310028C2 (ru) 2007-11-10
RU2004120297A (ru) 2005-06-10
ES2351437T3 (es) 2011-02-04
CN100395407C (zh) 2008-06-18
FR2833022A1 (fr) 2003-06-06
HUP0600860A2 (en) 2008-05-28
NZ533809A (en) 2007-01-26
AU2002364415B2 (en) 2008-03-20
JP2005511912A (ja) 2005-04-28
AU2002364415A1 (en) 2003-06-17
JP4643908B2 (ja) 2011-03-02
HK1076497A1 (en) 2006-01-20
BR0206875A (pt) 2005-04-12
PT1454015E (pt) 2010-11-22
FR2833022B1 (fr) 2004-07-02
CA2468261A1 (fr) 2003-06-12
DE60237843D1 (de) 2010-11-11
BR0206875B1 (pt) 2012-10-30
ZA200305497B (en) 2004-02-11
CN1599825A (zh) 2005-03-23
US8361596B2 (en) 2013-01-29
NO20033245L (no) 2003-09-09
NO333896B1 (no) 2013-10-14
KR100872912B1 (ko) 2008-12-08
WO2003048455A1 (fr) 2003-06-12
CA2468261C (fr) 2010-10-19
ATE483064T1 (de) 2010-10-15
KR20040071173A (ko) 2004-08-11
AU2002364415B8 (en) 2008-05-15
US20050106357A1 (en) 2005-05-19
NO20033245D0 (no) 2003-07-17

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