WO2003048455A1 - Feuille ayant un toucher rugueux - Google Patents
Feuille ayant un toucher rugueux Download PDFInfo
- Publication number
- WO2003048455A1 WO2003048455A1 PCT/FR2002/004168 FR0204168W WO03048455A1 WO 2003048455 A1 WO2003048455 A1 WO 2003048455A1 FR 0204168 W FR0204168 W FR 0204168W WO 03048455 A1 WO03048455 A1 WO 03048455A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sheet
- particles
- parts
- sheet according
- dry weight
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/253—Cellulosic [e.g., wood, paper, cork, rayon, etc.]
Definitions
- the present invention relates to a sheet having a rough feel. It also relates to the process for manufacturing the sheet and the use of this sheet.
- the Applicant is interested in particular in providing a sheet which, without being very rough or abrasive, however has a certain granular appearance which is only sensitive to touch, its surface appearing to be perfectly smooth to the naked eye.
- the Applicant aims to provide a sheet that is rough but pleasant to touch, that is to say that does not cling to the finger.
- the sheets must also be able to be printable, have whiteness characteristics, be manipulated for example.
- the Applicant has sought particles that meet these goals.
- the Applicant has highlighted two main categories of particles: those for which the abrasive role predominates, and which have an angular microscopic surface state and a rather homogeneous distribution on the surface of the sheet, such as alumina or corundum. and those for which the role of spacer and abrasion resistance is sought, and which have a more rounded microscopic surface state, a more voluminous shape, such as starch.
- the Applicant has given priority to using particles from the last category mentioned, so as to reduce as much as possible the grip on the fingers of the sheet thus covered. She found that the rough effect actually results from several causes:
- starch grains of potato starch are almost spherical or oval in shape, have an average size distribution of 28 micrometers and are made up of large particles, but few.
- the explanation is due to the fact that the particles are small, their average diameter being below 15 micrometers, and their particle size rather little differentiated.
- corn starch grains therefore spread out in a regular layer, following the relief of the leaf on which they are applied.
- the particles must be large enough to be flush with the layer so that they can be seen by the manipulator.
- the particles should be slightly angular so as to create a light, even pleasant, rough feel.
- silica or corundum grains such as those used to make abrasives are not suitable for the desired feel, the particles having a fractured geometry that is too aggressive.
- the particles will have a relatively spherical and bulky geometry, which also excludes platelet particles such as talc. Finally, the particles must be non-deformable.
- materials such as rubber or expanded microbeads are not suitable because of their compressible and elastic nature, giving a gummy and non-rough feel to the coated sheet.
- the invention relates to a sheet having on at least one of its faces a rough surface feel, said sheet being coated on the face (s) with a layer comprising incompressible, voluminous microscopic particles and having a rounded shape. .
- the invention is characterized in that the particles have an average diameter by weight greater than 25 micrometers, and preferably less than 200 micrometers.
- the invention is characterized by the fact that the particles have an almost spherical shape.
- the particles are grains of non-gelatinized starch, in particular grains of potato starch starch.
- the particles can also be glass microbeads, or ground plastic, the plastic preferably being a polyamide, a polyester, a polyolefin or a PVC.
- the invention is characterized in that the distribution of the particles on the surface is between 20 and 250 particles per mm 2 .
- This distribution can in particular be determined by topological analysis of the surface of the sheet obtained.
- the grammage of the sheet obtained will be between 50 and 500 g / m 2 .
- the weight of the layer on each coated face is between 3 and 30 g / m by dry weight, preferably between 5 and 18 g / m by dry weight.
- the invention is characterized by the fact that said layer comprises: 100 parts by dry weight of said particles, from 5 to 300 parts by dry weight of a binder, preferably from 10 to 50 parts, from 0 to 500 parts by dry weight of fillers.
- the binder is chosen from styrene butadiene latexes, acrylic latexes, vinyl latexes, solubilized starches, polyvinyl alcohol, proteins, in particular casein, gelatin or soy protein, nitrocellulose, plastisol, glycerophthalic resins, epoxy resins, polyesters.
- the fillers are chosen from calcium carbonate, kaolin, talc, titanium dioxide, barium sulphate, precipitated or pyrogenic silica, plastic pigments.
- compositions such as waxes, rheology modifiers, defoamers, spreading agents, bactericides or fungicides, ... can also take place in the coating composition.
- the sheet has a dynamic coefficient of friction measured according to standard NF Q 03-082 on blotting paper less than 0.5.
- the invention also relates to the process for coating a sheet.
- the sheet coating process is characterized in that it comprises the following stages: a) at least one of the faces of the sheet is treated with a composition in an aqueous medium comprising: 100 parts of incompressible microscopic particles , bulky and having a rounded shape, from 5 to 200 parts by dry weight of binder, preferably from 10 to 50 parts by dry weight, from 0 to 500 parts by dry weight of fillers, b) the sheet obtained is dried,
- step a) is carried out using a coating device chosen from coating rollers, rotogravure type, or reverse roU, which correspond to roller coaters running in opposite directions. reverse, coarse blade coater, air knife coater, film transfer sizing presses, curtain coater. According to another particular case, step a) is carried out using a spraying device.
- a coating device chosen from coating rollers, rotogravure type, or reverse roU, which correspond to roller coaters running in opposite directions. reverse, coarse blade coater, air knife coater, film transfer sizing presses, curtain coater.
- step a) is carried out using a spraying device.
- the sheet coating process is characterized in that it comprises the following stages: a) at least one of the faces of the sheet is treated with a varnish comprising:
- the invention also relates to the use of a sheet as described above for manufacturing a printing medium made of paper or plastic, a paper or plastic packaging, a cover intended for binding, a cardboard or plastic box.
- FIGS. 1A and 1B represent the observations with the scanning electron microscope of a sheet of paper coated with grains of starch from potato starch at 50 and 750 times magnification respectively.
- FIG. 1C represents the same sheet but seen in section at a magnification of 1000 times.
- Figures 2A and 2B show a sheet of paper coated with corn starch grains at 50 and 750 times magnification, respectively.
- FIG. 2C represents the same sheet seen in section at a magnification of 1000 times.
- Figs. 3A and 3B show a sheet of paper coated with grains of potato starch starch and calcium carbonate as a filler at 50 and 750 times magnification, respectively.
- FIG. 3C represents the same sheet seen in section at a magnification of 1000 times.
- Figures 4A and 4B show a sheet of paper coated with silica particles at 50 and 750 times magnification, respectively.
- FIG. 4C represents the same sheet seen in section at a magnification of 1000 times.
- FIG. 5 represents a sheet of paper coated with expanded thermoplastic microspheres, type EXPANCEL 820® sold by the company EXPANCEL at a magnification of 500 times.
- Figure 6 shows a sheet of paper coated with glass microbeads at 500 times magnification.
- Figure 7 shows a sheet of paper coated with alumina particles at 500 times magnification.
- Figure 8 shows a sheet of paper coated with grains of wheat starch at 500 times magnification.
- FIGS. 1A, 1B and 2A, 2B corresponding respectively to the two types of starch previously mentioned, it appears that the distribution, the shape and the size of the grains make it possible to explain this difference.
- the starch has a rather heterogeneous distribution on the leaf, small grains coming either, to agglomerate around larger grains, or, to be deposited in an isolated manner and at random on the paper.
- this distribution is completely homogeneous on the sheet, the grains having relatively close sizes and forming a thin, fine-grained layer on the paper.
- FIGS. 1C and 2C make it possible to appreciate what the finger of the manipulator will perceive during a tactile passage over the surface of the coated paper.
- the finger will pass from a hollow to a bump quite frequently, the height separating them being at least 25 micrometers.
- the finger will pass from one top of grains to another top of grains, the distance between them being at most 10 micrometers. Below ten micrometers, it is difficult for a manipulator to appreciate the graininess of the surface and to feel any sensation of roughness.
- FIGS. 3A, 3B and 3C represent this aspect of the invention well, since one can see an unchanged distribution of the starch grains of potato starch, but an aspect of these grains themselves completely different.
- calcium carbonate a particle close to a micrometer in size, covers the surface of the starch grains, which thus lose their surface smoothness and become more catchy to the touch.
- FIGS. 4A, 4B and 4C identify another case which the applicant has voluntarily excluded, that of a paper coated with angular particles of silica.
- FIG. 4C shows in particular the very angular and uneven nature of the silica particles, incompatible with a pleasant rough feel. If the sheet obtained nevertheless has a slightly aggressive degree of roughness, it does so only with the small proportion of added silica particles and the low relief thus created.
- FIG. 5 shows, for its part, the surface of a sheet covered with expanded thermoplastic microbeads of the EXPANCEL type.
- Figure 6 shows, on the contrary, the surface of a sheet covered with glass microbeads.
- Figures 7 and 8 confirm the fact that a pleasant "rough" feel cannot be obtained using alumina, or wheat starch.
- the alumina particles which are too angular, confer a rough character on the surface, which is not very pleasant to the touch.
- the wheat starch produces a surface quite similar to that of corn starch; therefore, the rough character will be practically imperceptible. Examples of coating compositions in accordance with the invention are described below.
- a coating composition containing 10.7 grains of potato starch is applied using a laboratory press. g / m 2 .
- the sheet thus treated is dried at around 150 ° C.
- composition containing the starch grains is produced in an aqueous medium and contains, dry: 100 parts of HIC AT 110 marketed by ROQUETTE (potato starch starch)
- a coating composition containing potato starch starch grains and calcium carbonate as fillers is applied using a laboratory size press. , at a rate of 22.5 g / m 2 .
- the sheet thus treated is dried at around 150 ° C.
- composition containing the starch grains and the calcium carbonate is produced in an aqueous medium and contains in dry: 100 parts of HIC AT 110 marketed by ROQUETTE (potato starch starch)
- HYDROCARB 90 60 parts of HYDROCARB 90 marketed by OMYA (calcium carbonate)
- a coating composition containing glass microbeads is deposited using a laboratory size press, at a rate of 47 g / m 2 .
- the composition containing the glass microbeads is produced in an aqueous medium and contains in dry:
- the Applicant has also endeavored to characterize the pleasant rough surface condition of the sheets obtained, other than by a tactile appraisal carried out by a handler taken at random, a method which can be considered too subjective.
- the Applicant has measured the dynamic friction coefficient according to French standard NF Q 03-082.
- the standard based on the measurement of the tensile force necessary to initiate and then maintain the displacement of one surface on another can be applied to the evaluation of the sliding of a sheet of the material to be measured on another reference material.
- thermo-expanded microspheres such as EXPANCEL type thermo-expanded microspheres, alumina particles, wheat starch grains or rubber powder are therefore to be excluded.
Landscapes
- Laminated Bodies (AREA)
- Paper (AREA)
- Materials For Medical Uses (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Wrappers (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Steering Devices For Bicycles And Motorcycles (AREA)
- Cartons (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Push-Button Switches (AREA)
Abstract
Description
Claims
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020047008584A KR100872912B1 (ko) | 2001-12-04 | 2002-12-04 | 거친 촉감을 갖는 시트 |
BRPI0206875-3A BR0206875B1 (pt) | 2001-12-04 | 2002-12-04 | folha tendo uma superfìcie áspera ao tato em pelo menos um de seus lados e processo para revestir uma folha. |
AU2002364415A AU2002364415B8 (en) | 2001-12-04 | 2002-12-04 | Sheet having a rough feel |
CA2468261A CA2468261C (fr) | 2001-12-04 | 2002-12-04 | Feuille ayant un toucher rugueux |
US10/497,529 US8361596B2 (en) | 2001-12-04 | 2002-12-04 | Sheet having a rough feel |
NZ533809A NZ533809A (en) | 2001-12-04 | 2002-12-04 | Sheet having a rough feel |
AT02799771T ATE483064T1 (de) | 2001-12-04 | 2002-12-04 | Blatt mit einem rauhen anfühlen |
MXPA04005486A MXPA04005486A (es) | 2001-12-04 | 2002-12-04 | Hoja que presenta una sensacion al tacto rugosa. |
EP02799771A EP1454015B1 (fr) | 2001-12-04 | 2002-12-04 | Feuille ayant un toucher rugueux |
HU0600860A HUP0600860A2 (en) | 2001-12-04 | 2002-12-04 | Sheet having a rough feel and process for preparing the coating layer of rough fiel sheat |
DE60237843T DE60237843D1 (de) | 2001-12-04 | 2002-12-04 | Blatt mit einem rauhen anfühlen |
JP2003549629A JP4643908B2 (ja) | 2001-12-04 | 2002-12-04 | 粗い触感を有する用紙 |
NO20033245A NO333896B1 (no) | 2001-12-04 | 2003-07-17 | Papir med et grovt eller ru grep |
HK05108366.4A HK1076497A1 (en) | 2001-12-04 | 2005-09-22 | Sheet having a rough feel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0115661A FR2833022B1 (fr) | 2001-12-04 | 2001-12-04 | Feuille ayant un toucher rugueux |
FR01/15661 | 2001-12-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003048455A1 true WO2003048455A1 (fr) | 2003-06-12 |
Family
ID=8870092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2002/004168 WO2003048455A1 (fr) | 2001-12-04 | 2002-12-04 | Feuille ayant un toucher rugueux |
Country Status (21)
Country | Link |
---|---|
US (1) | US8361596B2 (fr) |
EP (1) | EP1454015B1 (fr) |
JP (1) | JP4643908B2 (fr) |
KR (1) | KR100872912B1 (fr) |
CN (1) | CN100395407C (fr) |
AT (1) | ATE483064T1 (fr) |
AU (1) | AU2002364415B8 (fr) |
BR (1) | BR0206875B1 (fr) |
CA (1) | CA2468261C (fr) |
DE (1) | DE60237843D1 (fr) |
ES (1) | ES2351437T3 (fr) |
FR (1) | FR2833022B1 (fr) |
HK (1) | HK1076497A1 (fr) |
HU (1) | HUP0600860A2 (fr) |
MX (1) | MXPA04005486A (fr) |
NO (1) | NO333896B1 (fr) |
NZ (1) | NZ533809A (fr) |
PT (1) | PT1454015E (fr) |
RU (1) | RU2310028C2 (fr) |
WO (1) | WO2003048455A1 (fr) |
ZA (1) | ZA200305497B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015128806A1 (fr) | 2014-02-28 | 2015-09-03 | Arjowiggins Security | Element de securite tactile |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008005228A2 (fr) * | 2006-06-30 | 2008-01-10 | Omnova Solutions Inc. | Compositions de revêtement et produits et procédés correspondants |
WO2009042599A1 (fr) | 2007-09-25 | 2009-04-02 | Aetrex Worldwide, Inc. | Objets préparés à l'aide de matériaux recyclés et leurs procédés de préparation |
NL2009904C2 (nl) * | 2012-10-10 | 2014-04-14 | Climate Invest B V | Werkwijze voor het vervaardigen van een antislip-folie en een door het uitvoeren van de werkwijze verkregen antislip-folie. |
WO2018136178A1 (fr) * | 2017-01-17 | 2018-07-26 | Neenah Paper, Inc. | Revêtement imprimable texturé et procédés de fabrication et d'utilisation d'un tel revêtement imprimable texturé |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1401533A (en) * | 1972-08-02 | 1975-07-16 | British American Tobacco Co | Surface finishes |
US4849265A (en) * | 1987-09-03 | 1989-07-18 | The Ohtsu Tire & Rubber Co., Ltd. | Sheet coated with beads and process for preparing same |
FR2791368A1 (fr) * | 1999-03-26 | 2000-09-29 | Arjo Wiggins Sa | Feuille avec un toucher "peau" imprimable a des cadences elevees et son procede de fabrication et emballage la comportant |
WO2001057315A2 (fr) * | 2000-02-02 | 2001-08-09 | The Mead Corporation | Papier resistant a l'usure et procede de fabrication associe |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3615751A (en) * | 1968-02-14 | 1971-10-26 | Salvat Editores | Process and composition for preventing offsetting of drying printing ink |
JPH026682A (ja) * | 1987-12-01 | 1990-01-10 | Honshu Paper Co Ltd | 剥離紙用原紙 |
JPH04502350A (ja) * | 1988-12-07 | 1992-04-23 | シユトーラ フエルトミユーレ アクチエンゲゼルシヤフト | 印刷用紙、該印刷用紙の製造法および使用法 |
US5314753A (en) * | 1988-12-07 | 1994-05-24 | Stora Feldmuhle Aktiengesellschaft | Printing paper and a process for its manufacture |
US5093159A (en) * | 1989-11-06 | 1992-03-03 | National Starch And Chemical Investment Holding Corporation | Process for rapidly immobilizing paper coating compositions |
DE4322179C2 (de) * | 1993-07-03 | 1997-02-13 | Schoeller Felix Jun Papier | Aufzeichnungsmaterial für Ink-Jet-Druckverfahren |
US5902453A (en) * | 1995-09-29 | 1999-05-11 | Mohawk Paper Mills, Inc. | Text and cover printing paper and process for making the same |
JPH09268495A (ja) * | 1996-03-29 | 1997-10-14 | Oji Paper Co Ltd | 非塗工紙風合いを有する艶消し塗工紙 |
US5759346A (en) * | 1996-09-27 | 1998-06-02 | The Procter & Gamble Company | Process for making smooth uncreped tissue paper containing fine particulate fillers |
US6277498B1 (en) * | 1998-03-31 | 2001-08-21 | Oji Paper Co., Ltd. | Ink jet recording material process for producing the same and ink jet recording method using the same |
JP2000054291A (ja) * | 1998-08-06 | 2000-02-22 | Nippon Zeon Co Ltd | 印刷用塗工紙および塗工用組成物 |
JP3023104B1 (ja) * | 1999-01-21 | 2000-03-21 | 恵和株式会社 | 防湿紙 |
JP3581599B2 (ja) * | 1999-04-22 | 2004-10-27 | 東亞合成株式会社 | 防湿性被覆剤組成物および防湿性紙 |
JP3872309B2 (ja) * | 2000-03-31 | 2007-01-24 | 日本製紙株式会社 | 印刷用受像シート |
US6572951B2 (en) | 2000-03-31 | 2003-06-03 | Nippon Paper Industries Co., Ltd. | Printing sheet |
JP2002003801A (ja) * | 2000-06-19 | 2002-01-09 | Oji Paper Co Ltd | 段ボール用接着剤 |
-
2001
- 2001-12-04 FR FR0115661A patent/FR2833022B1/fr not_active Expired - Lifetime
-
2002
- 2002-12-04 BR BRPI0206875-3A patent/BR0206875B1/pt not_active IP Right Cessation
- 2002-12-04 WO PCT/FR2002/004168 patent/WO2003048455A1/fr active Application Filing
- 2002-12-04 CA CA2468261A patent/CA2468261C/fr not_active Expired - Fee Related
- 2002-12-04 MX MXPA04005486A patent/MXPA04005486A/es unknown
- 2002-12-04 RU RU2004120297/12A patent/RU2310028C2/ru not_active IP Right Cessation
- 2002-12-04 ES ES02799771T patent/ES2351437T3/es not_active Expired - Lifetime
- 2002-12-04 PT PT02799771T patent/PT1454015E/pt unknown
- 2002-12-04 AT AT02799771T patent/ATE483064T1/de not_active IP Right Cessation
- 2002-12-04 DE DE60237843T patent/DE60237843D1/de not_active Expired - Lifetime
- 2002-12-04 US US10/497,529 patent/US8361596B2/en active Active
- 2002-12-04 JP JP2003549629A patent/JP4643908B2/ja not_active Expired - Fee Related
- 2002-12-04 KR KR1020047008584A patent/KR100872912B1/ko active IP Right Grant
- 2002-12-04 NZ NZ533809A patent/NZ533809A/en not_active IP Right Cessation
- 2002-12-04 HU HU0600860A patent/HUP0600860A2/hu unknown
- 2002-12-04 EP EP02799771A patent/EP1454015B1/fr not_active Expired - Lifetime
- 2002-12-04 AU AU2002364415A patent/AU2002364415B8/en not_active Ceased
- 2002-12-04 CN CNB028242963A patent/CN100395407C/zh not_active Expired - Lifetime
-
2003
- 2003-07-16 ZA ZA200305497A patent/ZA200305497B/en unknown
- 2003-07-17 NO NO20033245A patent/NO333896B1/no not_active IP Right Cessation
-
2005
- 2005-09-22 HK HK05108366.4A patent/HK1076497A1/xx not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1401533A (en) * | 1972-08-02 | 1975-07-16 | British American Tobacco Co | Surface finishes |
US4849265A (en) * | 1987-09-03 | 1989-07-18 | The Ohtsu Tire & Rubber Co., Ltd. | Sheet coated with beads and process for preparing same |
FR2791368A1 (fr) * | 1999-03-26 | 2000-09-29 | Arjo Wiggins Sa | Feuille avec un toucher "peau" imprimable a des cadences elevees et son procede de fabrication et emballage la comportant |
WO2001057315A2 (fr) * | 2000-02-02 | 2001-08-09 | The Mead Corporation | Papier resistant a l'usure et procede de fabrication associe |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015128806A1 (fr) | 2014-02-28 | 2015-09-03 | Arjowiggins Security | Element de securite tactile |
FR3018085A1 (fr) * | 2014-02-28 | 2015-09-04 | Arjowiggins Security | Element de securite tactile |
Also Published As
Publication number | Publication date |
---|---|
RU2004120297A (ru) | 2005-06-10 |
NO333896B1 (no) | 2013-10-14 |
NO20033245D0 (no) | 2003-07-17 |
JP4643908B2 (ja) | 2011-03-02 |
EP1454015B1 (fr) | 2010-09-29 |
CA2468261A1 (fr) | 2003-06-12 |
KR100872912B1 (ko) | 2008-12-08 |
ATE483064T1 (de) | 2010-10-15 |
HUP0600860A2 (en) | 2008-05-28 |
CA2468261C (fr) | 2010-10-19 |
PT1454015E (pt) | 2010-11-22 |
ES2351437T3 (es) | 2011-02-04 |
MXPA04005486A (es) | 2005-04-19 |
RU2310028C2 (ru) | 2007-11-10 |
EP1454015A1 (fr) | 2004-09-08 |
NO20033245L (no) | 2003-09-09 |
FR2833022B1 (fr) | 2004-07-02 |
AU2002364415B2 (en) | 2008-03-20 |
AU2002364415A1 (en) | 2003-06-17 |
US8361596B2 (en) | 2013-01-29 |
HK1076497A1 (en) | 2006-01-20 |
KR20040071173A (ko) | 2004-08-11 |
BR0206875A (pt) | 2005-04-12 |
US20050106357A1 (en) | 2005-05-19 |
CN1599825A (zh) | 2005-03-23 |
NZ533809A (en) | 2007-01-26 |
CN100395407C (zh) | 2008-06-18 |
FR2833022A1 (fr) | 2003-06-06 |
ZA200305497B (en) | 2004-02-11 |
JP2005511912A (ja) | 2005-04-28 |
BR0206875B1 (pt) | 2012-10-30 |
AU2002364415B8 (en) | 2008-05-15 |
DE60237843D1 (de) | 2010-11-11 |
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