EP1403637B1 - Capteur d'Ammoniac - Google Patents

Capteur d'Ammoniac Download PDF

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Publication number
EP1403637B1
EP1403637B1 EP03256022A EP03256022A EP1403637B1 EP 1403637 B1 EP1403637 B1 EP 1403637B1 EP 03256022 A EP03256022 A EP 03256022A EP 03256022 A EP03256022 A EP 03256022A EP 1403637 B1 EP1403637 B1 EP 1403637B1
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EP
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Prior art keywords
ammonia sensor
ammonia
sensor
zro
sensor according
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EP03256022A
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German (de)
English (en)
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EP1403637A1 (fr
Inventor
Hiroyuki NGK Spark Plug Co. Ltd Nishiyama
Shiro NGK Spark Plug Co. LTD Kakimoto
Ryuji NGK Spark Plug Co. LTD Inoue
Hitoshi NGK Spark Plug Co. LTD Yokoi
Noboru NGK Spark Plug Co. LTD Ishida
Takafumi NGK Spark Plug Co. LTD Oshima
Satoshi NGK Spark Plug Co. LTD Sugaya
Koichi NGK Spark Plug Co. LTD Imaeda
Tadashi NGK Spark Plug Co. LTD Hattori
Atsushi NGK Spark Plug Co. LTD Satsuma
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Niterra Co Ltd
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NGK Spark Plug Co Ltd
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/0054—Ammonia
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/406—Cells and probes with solid electrolytes
    • G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/17—Nitrogen containing
    • Y10T436/173845—Amine and quaternary ammonium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/17—Nitrogen containing
    • Y10T436/173845—Amine and quaternary ammonium
    • Y10T436/175383—Ammonia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/25—Chemistry: analytical and immunological testing including sample preparation
    • Y10T436/25875—Gaseous sample or with change of physical state

Definitions

  • the present invention relates to an ammonia sensor for detecting the concentration of ammonia contained in a sample gas.
  • This type of ammonia sensor is employed for measuring the concentration of ammonia contained in, for example, exhaust gas from an internal combustion engine, and is particularly suitable for use in a system for selectively reducing NO x (hereinafter may be referred to as an "NO x selective reduction system”), in which NO x is cleaned through addition of urea.
  • Patent Document 1 Japanese Patent Application Laid-Open ( kokai) No. 5-87760 (page 2).
  • Patent Document 2 Japanese Patent Application Laid-Open ( kokai) No. 10-19821 (page 2).
  • Patent Document 3 Specification of US Patent No. 5143696 (page 3, Fig. 4 ).
  • Patent Document 4 Specification of US Patent No. 6069013 (page 3, Fig. 2a ).
  • the ammonia sensor described in Patent Document 1 exhibits sensitivity to NO and NO 2 , and thus cannot be employed in the NO x selective reduction system for chemical reduction and cleaning of NOx contained in exhaust gas through addition of urea.
  • the ammonia sensor described in Patent Document 2 exhibits improved selectivity for ammonia.
  • MoO 3 which is incorporated into the sensitive layer for improving the ammonia selectivity of the sensor, has a melting point as low as 795°C and a boiling point as low as 1,155°C. Therefore, the sensor is not suitable for use in the aforementioned NO x selective reduction system, because of its low thermal resistance, and the sensor is difficult to employ in exhaust gas.
  • the ammonia sensor described in Patent Document 3 or 4 involves a problem in terms of thermal resistance. Specifically, zeolite having a low SiO 2 /Al 2 O 3 ratio (i.e., the A1 content is high), which is employed in the ammonia sensor, exhibits poor thermal resistance, and thus is not suitable as a material for, particularly, an exhaust gas sensor (see, for example, Society of Automotive Engineers of Japan, Inc., Academic Lecture Meeting Preprints 961 pp. 73-76 ).
  • EP-A-1 008 847 teaches an ammonia sensor based on a super-acidic composition using TiO 2 as carrier material.
  • a critical point is that the sensor must have durability (particularly, durability against heat). For example, even when the sensor is operated at a high temperature for a long period of time, the sensor must provide consistent output.
  • considerations for enhancing durability have been insufficient.
  • the present invention has been achieved to solve the aforementioned problems, and an object of the invention is to provide an ammonia sensor exhibiting high sensitivity particularly to ammonia, high ammonia selectivity, and high thermal resistance and durability.
  • Another object of the present invention is to provide an ammonia sensor which measures the concentration of ammonia contained in a gas at high accuracy, even when the temperature of the gas is varied.
  • the present inventors have performed studies, and as a result have found that a solid, super-strong acidic substance is effective as a detection material (gas-sensitive material for a sensitive section) employed in an ammonia sensor.
  • the present invention has been accomplished on the basis of this finding. The present invention will next be described in detail.
  • the term "super-strong acid” refers to an acid having an acidity of ⁇ -11.93 as determined by Hammett acidity function H 0 .
  • Hammett acidity function H 0 is used for evaluating the ability of a solvent to donate a proton to a Hammett base [B], and is represented by the following formula (2) for the relation expressed by the following formula (1).
  • H 0 pKa + log([B]/[BH + ]) (2)
  • the present invention provides an ammonia sensor including a sensitive section containing a primary component and a secondary component added thereto.
  • the form of the secondary component present in the sensitive section has not necessarily been elucidated completely.
  • the primary component and the secondary component of the sensitive section exhibiting super-strong acidity are not present in the form of a mixture, but the secondary component in molecular form is chemically bonded to the surfaces of oxide particles constituting the primary component.
  • the below-described solid, super-strong acid (super-strong acidic metal oxide) is considered to have a structure shown in Fig. 1 (the upper figure and the middle figure) or a structure similar to the structure shown therein, in view of the results of studies employing XPS (X-ray photoelectron spectroscopy) and IR (infrared spectroscopy).
  • the secondary component In order to cause the sensitive section to exhibit super-strong acidity, as described above, the secondary component must be chemically bonded to the surfaces of the primary component particles. When the specific surface area of the primary component particles is larger, larger amounts of the secondary component molecules (particles) can be bonded to the surfaces of the primary component particles. As a result, the acid content of the sensitive section is increased.
  • the amount of the secondary component which can be added to the primary component varies in accordance with the specific surface area of the primary component. As described below, when the amount of the secondary component to be added is appropriately determined, the resultant ammonia sensor can reliably and selectively detect ammonia gas contained in a sample gas.
  • the invention provides an ammonia sensor comprising an element section, the element section including a pair of electrodes and a sensitive section contacting the paired electrodes,
  • the sensitive section contains a solid, super-strong acidic substance other than zeolite, the acidic substance having an acidity of ⁇ -11.93 as determined by Hammett acidity function H 0 , wherein the solid, super-strong acidic substance comprises at least one species selected from among the following combinations of secondary components and primary components: WO 3 /ZrO 2 , SO 4 2 -/ZrO 2 , PO 4 3- /ZrO 2 , MoO 3 /ZrO 2 , and B 2 O 3 /ZrO 2
  • the sensitive section contains a solid, super-strong acidic substance other than zeolite, the acidic substance having an acidity of ⁇ -11.93 as determined by Hammett acidity function H 0 . Therefore, the ammonia sensor exhibits high sensitivity to ammonia, high ammonia selectivity, and high thermal resistance.
  • a solid, super-strong acidic substance other than zeolite is employed in the sensitive section.
  • the sensitive section predominantly contains the aforementioned solid, super-strong acidic substance (preferably, the entirety of the sensitive section is formed of the solid, super-strong acidic substance), the aforementioned characteristics of the ammonia sensor are further enhanced, which is more preferable.
  • the sensitive portion is operable when it contained at least 80 % by weight of the super-strong acid substance.
  • the solid, super-strong acidic substance contains an oxide serving as a primary component and an oxide or an oxide ion serving as a secondary component, the primary and secondary components being chemically bonded to each other.
  • the sensitive section contains a solid, super-strong acidic substance having an acidity of ⁇ -11.93 as determined by Hammett acidity function H 0 , and the primary component (an oxide) and the secondary component (an oxide or an oxide ion) of the solid, super-strong acidic substance are chemically bonded to each other. Therefore, the ammonia sensor exhibits high sensitivity to ammonia and high ammonia selectivity. In addition, since the primary component is an oxide and the secondary component is an oxide (or an oxide ion), the ammonia sensor exhibits high thermal resistance.
  • Chemical bonding between the primary component (an oxide) and the secondary component (an oxide or an oxide ion) can be confirmed through, for example, the following procedure: the sensitive section of the ammonia sensor is subjected to XPS measurement, to thereby obtain a specific electron orbital spectrum of the primary component (or the secondary component); and the thus-obtained spectrum is confirmed to have a peak that is shown in neither an electron orbital spectrum of merely the primary component (or merely the secondary component) nor an electron orbital spectrum of a mixture of the primary and secondary components.
  • the solid, super-strong acidic substance employed in this invention in which the secondary component is bonded to the primary component, preferably has a specific surface area of about 35 to about 80 m 2 /g.
  • the sensitive section predominantly contains the aforementioned solid, super-strong acidic substance (preferably, the entirety of the sensitive section is formed of the solid, super-strong acidic substance), the aforementioned characteristics of the ammonia sensor are further enhanced, which is more preferable.
  • the aforementioned solid, super-strong acidic substance (super-strong acidic metal oxide) is employed as the material of the sensitive section. Therefore, the ammonia sensor can accurately and selectively detect ammonia gas with high responsiveness and high sensitivity.
  • the sensitive section predominantly contains the aforementioned solid, super-strong acidic substance (preferably, the entirety of the sensitive section is formed of the solid, super-strong acidic substance), the aforementioned characteristics of the ammonia sensor are further enhanced, which is more preferable.
  • the solid, super-strong acidic substance becomes a sulfated super-strong acidic metal oxide
  • the secondary component is PO 4 3-
  • the solid, super-strong acidic substance becomes a phosphorylated super-strong acidic metal oxide
  • the invention is further characterized in that the solid, super-strong acidic substance is a composite oxide containing a ZrO 2 carrier serving as a primary component, and at least one species selected from among WO 3 , MoO 3 , B 2 O 3 , SO 4 2- , and PO 4 3- , serving as a secondary component, the secondary component being bonded to the surface of the carrier; and the carrier contains an agent for stabilizing the crystal structure of ZrO 2 .
  • the ZrO 2 carrier serving as the primary component contains an agent for stabilizing the ZrO 2 crystal structure. Therefore, the ammonia sensor exhibits excellent thermal resistance and durability against heat. Even when the ammonia sensor is employed at a high temperature (e.g., 400°C or higher) over a long period of time, the sensor exhibits a remarkable effect; i.e., the sensor provides consistent output.
  • a high temperature e.g. 400°C or higher
  • a predetermined amount of a crystal-structure-stabilizing agent is incorporated into the ZrO 2 carrier (specifically to form a solid solution) so as to stabilize a ZrO 2 crystal phase, whereby change in the crystal structure of ZrO 2 by heat can be suppressed, Therefore, since the secondary component is reliably bonded to the surface of the carrier, even when the ammonia sensor is employed at a high temperature over a long period of time, the sensitivity of the sensor is not lowered, and the sensor provides consistent output.
  • the present inventors have performed studies on durability of an ammonia sensor, and have found that the sensitivity of the ammonia sensor is gradually lowered as the service time progresses, and, in accordance with lowering of the sensitivity, the proportion of monoclinic crystals is increased in the ZrO 2 crystal phase.
  • the present inventors have also found that when a stabilizing agent (e.g., Y 2 O 3 ) is added to ZrO 2 serving as the primary component, to thereby cause ZrO 2 to have a crystal phase containing tetragonal crystals and cubic crystals and not containing monoclinic crystals, the durability of the ammonia sensor is enhanced, and lowering of the sensitivity of the sensor is significantly retarded.
  • a stabilizing agent e.g., Y 2 O 3
  • the invention is further characterized in that the crystal-structure-stabilizing agent is at least one species selected from among CaO, MgO, Y 2 O 3 , Yb 2 O 3 , and Ga 2 O 3 .
  • the invention is further characterized in that the Y 2 O 3 content is at least 4 mol%.
  • the invention is further characterized in that the Y 2 O 3 content is at least 6 mol%.
  • the Y 2 O 3 content of the Y 2 O 3 -containing ZrO 2 carrier serving as the primary component is 6 mol% or more (preferably 8 mol% or more) on the basis of the entire amount (100 mol%) of the carrier, even when the ammonia sensor is employed at a high temperature, change in the ZrO 2 crystal phase is suppressed considerably, thereby further preventing lowering of the sensitivity of the sensor.
  • the invention is further characterized in that the solid, super-strong acidic substance has an acid content of at least 0.05 mmol/g.
  • a preferred acid content of the solid, super-strong acidic substance is specified.
  • the ammonia sensor adsorbs a sufficient amount of ammonia, and the sensor exhibits satisfactory performance.
  • the acid content more preferably falls within a range of 0.07 to 0.25 mmol/g.
  • the ammonia sensor When the acid content is higher, the ammonia sensor exhibits more enhanced sensitivity to ammonia gas. Therefore, the operation temperature of the sensor element can be increased.
  • an ammonia sensor When the operation temperature of an ammonia sensor is increased, the sensitivity of the sensor tends to be lowered.
  • An ammonia sensor employing a solid, super-strong acidic substance having a high acid content maintains sufficient sensitivity even when operated at a high temperature.
  • the sensor when the sensor is operated at a high temperature, the sensor advantageously exhibits quick responsiveness.
  • the acid content can be calculated from the integral (area) of the peak obtained by means of the below-described NH 3 -TPD (animonia-temperature programmed desorption).
  • the invention is further characterized in that when the total amount of the aforementioned primary and secondary components is taken as 100 mol%, the amount of the secondary component is 1 to 25 mol%; i.e., the amount of the primary component is 99 to 75 mol%.
  • the amount of the secondary component to be added is specified.
  • the ammonia sensor can reliably and selectively detect ammonia gas contained in a sample gas, which is preferable.
  • the ammonia sensor exhibits enhanced sensitivity to ammonia, which is more preferable.
  • the specific surface area of particles of the primary component is preferably about 100 m 2 /g.
  • the invention is further characterized in that, when the sensitive section predominantly contains ZrO 2 and contains at least W, the W content of the sensitive section is 1.5 to 30 wt.% as converted to WO 3 .
  • the sensitive section predominantly contains ZrO 2 , and therefore exhibits high thermal resistance. Since the sensitive section predominantly contains ZrO 2 and contains at least W, the ammonia sensor exhibits high sensitivity to ammonia and low sensitivity to gases other than ammonia (i.e., interference gases such as NO and NO 2 ); i.e., the sensor exhibits high selectivity for ammonia.
  • the ammonia sensor when the amount of W contained in the sensitive section is 1.5 to 30 wt.% as converted to WO 3 , the ammonia sensor exhibits high sensitivity to ammonia.
  • the amount of W contained in the raw material of the sensitive section (the amount of W incorporated into the raw material) is 2 to 40 wt.% as reduced to WO 3 .
  • the invention is further characterized in that the ammonia sensor comprises a protective layer which covers the sensitive section.
  • the surface of the sensitive section is covered with a protective layer which NH 3 can permeate (e.g., a porous protective layer). Therefore, there can be prevented adhesion of a deposit (e.g., carbon) contained in exhaust gas or a poisoning substance (e.g., phosphorus or silicon) contained in exhaust gas to the sensitive section, and thus impairment of the sensitive section can be suppressed.
  • a protective layer which NH 3 can permeate e.g., a porous protective layer. Therefore, there can be prevented adhesion of a deposit (e.g., carbon) contained in exhaust gas or a poisoning substance (e.g., phosphorus or silicon) contained in exhaust gas to the sensitive section, and thus impairment of the sensitive section can be suppressed.
  • Examples of the dominant material constituting the protective layer include magnesia-alumina spinel, alumina, zirconia, and titania.
  • the invention is further characterized in that the ammonia sensor further comprises a heater for heating the element section.
  • the element section is heated by the heater, to thereby regulate the temperature of the element section (particularly, the temperature of the sensitive section) to an optimal temperature for detection of ammonia.
  • This regulation of the temperature of the element section advantageously enhances sensor performance, including responsiveness and accuracy in measurement of ammonia concentration.
  • the invention is further characterized in that the ammonia sensor comprises an insulating substrate in which the heater is embedded, wherein the paired electrodes are formed on the insulating substrate, and the sensitive section is formed so as to cover the paired electrodes.
  • the ammonia sensor having the aforementioned configuration is preferred, since the sensor is readily produced and is suitable for mass-production, and exhibits high mechanical strength.
  • the paired electrodes may be parallel electrodes or comb-shaped electrodes.
  • the ammonia sensor comprises an insulating substrate in which the heater is embedded, a lower electrode, and an upper electrode, the lower and upper electrodes being formed of the paired electrodes, wherein the lower electrode is formed on the insulating substrate, the sensitive section is formed so as to cover the lower electrode, and the upper electrode is formed on the sensitive section.
  • the ammonia sensor having the aforementioned configuration is preferred, since the sensor is readily produced and is suitable for mass-production, and exhibits high mechanical strength.
  • the upper electrode may serve as a protective layer for the sensitive section.
  • the invention is further characterized in that the ammonia sensor further comprises element temperature detection means for detecting the temperature of the element, and temperature regulation means for controlling the heater such that the element temperature falls within a predetermined temperature range.
  • the element temperature detection means detects the element temperature (the temperature of the element section), to thereby regulate, for example, voltage applied to the heater such that the element temperature falls within a predetermined temperature range (a temperature range suitable for measurement of the concentration of ammonia). Therefore, the ammonia sensor can consistently measure the concentration of ammonia with high accuracy.
  • the sensitivity of the ammonia sensor to ammonia varies depending on the element temperature. Therefore, when the element temperature is regulated to a predetermined temperature, the concentration of ammonia can be accurately measured.
  • the element temperature can be regulated in accordance with the environment in which ammonia is measured. For example, in order to accurately measure the concentration of ammonia contained in exhaust gas from a diesel engine, preferably, the ammonia sensor is operated such that the element section is maintained at a predetermined temperature of about 350 to about 450°C, in consideration of the temperature of the exhaust gas, which varies in accordance with the operation conditions of the diesel engine.
  • the responsiveness (response speed) of the ammonia sensor to ammonia depends on the operation temperature of the sensor (the heating temperature of the element section). The higher the operation temperature, the higher the rate at which ammonia gas molecules are adsorbed onto or desorbed from the sensor, and thus the more enhanced the responsiveness of the sensor to ammonia. Meanwhile, when the operation temperature of the ammonia sensor is increased, the sensitivity of the sensor to ammonia gas is lowered.
  • the temperature of the element section is regulated to a predetermined temperature falling within a range represented by the following relation: T-100 ⁇ t ⁇ T + 100 (wherein T represents the peak end temperature (°C) as measured by means of NH 3 -TPD).
  • the element temperature detection means may be a temperature sensor formed of a platinum resistor or a thermistor.
  • the ammonia sensor 1 of the present embodiment employs a gas-sensitive material whose impedance (Z) varies in accordance with the concentration of ammonia.
  • the impedance (Z) of the gas-sensitive material varies in accordance with the concentration of ammonia. Therefore, the ammonia concentration is determined on the basis of variation in the impedance.
  • An element section 3 constituting the essential portion of the ammonia sensor 1 includes an insulating substrate 5 and the below-described components successively laminated thereon.
  • the insulating substrate 5 having the laminated components may be referred to as "sensor element member 6.”
  • Fig. 2 shows merely the front-end portion of the sensor element member 6.
  • a pair of lead portions 7 and 9 which predominantly contain platinum are provided on the insulating substrate 5 formed of alumina; a pair of comb-shaped electrodes 11 and 13 are connected to the lead portions 7 and 9, respectively; a sensitive layer 15 (sensitive section) formed of the aforementioned gas-sensitive material is provided on the comb-shaped electrodes 11 and 13 so as to cover the entirety of the electrodes 11 and 13; and a protective layer 17 is provided on the sensitive layer 15 so as to cover the entirety of the layer 15.
  • the heater 19 predominantly contains platinum, and the temperature sensor 21 also predominantly contains platinum.
  • the sensitive layer 15 (thickness: about 30 ⁇ m) formed through thick-film printing contains a porous gas-sensitive material (i.e., a solid, super-strong acidic substance).
  • a porous gas-sensitive material i.e., a solid, super-strong acidic substance.
  • the impedance (or resistance) of the solid, super-strong acidic substance varies in accordance with variation in the concentration of ammonia contained in an atmosphere surrounding the substance.
  • the sensitive layer 15 contains, as a primary component, ZrO 2 in an amount of 99 to 75 mol%, and contains, as a secondary component, at least a species selected from among SO 4 2- , PO 4 3- , WO 3 , MoO 3 , B 2 O 3 , etc. in an amount of 1 to 25 mol%.
  • the amount of the primary and secondary components of the sensitive layer 15 can be obtained through, for example, the following procedure: the amount of the elements constituting the components is determined by use of an inductively coupled argon plasma emission spectrophotometer (IRIS Advantage ICAP, product of Nippon Jarrell-Ash Co., Ltd.); and, on the basis of the thus-determined amount of the elements, the amount of the corresponding oxides is calculated, to thereby obtain the amount of the primary and secondary components.
  • IRIS Advantage ICAP inductively coupled argon plasma emission spectrophotometer
  • the protective layer 17 (thickness: about 30 ⁇ m) formed through thick-film printing is provided for preventing adhesion of a deposit (e.g., carbon) to the comb-shaped electrodes 11 and 13 or the sensitive layer 15.
  • the protective layer 17 is formed of a porous protective film predominantly containing magnesia-alumina spinel (MgAl 2 O 4 ) ⁇
  • ammonia sensor 1 which is an assembly incorporating the aforementioned sensor element member 6, will now be described briefly.
  • the sensor element member 6- which, at its front-end portion (the lower portion as viewed in Fig. 4 ), includes the element section 3-is connected to lead wires 31 at the rear-end portion (the upper portion as viewed in Fig. 4 ).
  • the lead wires 31 are welded to first ends of electrode leads 33.
  • a second end of each of the electrode leads 33 is connected via a connection terminal 35 to a lead wire 37.
  • the rear-end portion of the sensor element member 6 is accommodated in an alumina tubular insulator 39, and the front-end portion of the member 6 projects from the insulator 39.
  • the sensor element member 6 is fitted into an alumina insulating porcelain bushing 41 which is provided in the interior of the insulator 39, and is connected to the insulating porcelain bushing 41 by use of cement 43.
  • the insulator 39 and the sensor element member 6 are fixed together via a first filler layer 45 and a second filler layer 47, the layers 45 and 47 being formed through melting and solidification of a powder mixture of talc and glass.
  • a portion at which the lead wires 31 are connected to the electrode leads 33 is encapsulated with a glass layer 49 formed through melting and solidification of glass powder.
  • the front-end portion of the sensor element member 6 is protected by a porous protector 53 which is supported by a main fitting 51.
  • the insulator 39 is fitted in the main fitting 51 via a packing plate 55 and a talc layer 57.
  • a crimping ring 59 for sealing the talc layer 57 is provided around the insulator 39, an outer tube 61 is provided around the crimping ring 59, and a ring 63 is provided around a first end of the outer tube 61.
  • the upper end portion of the main fitting 51 is crimped so as to cover the ring 63.
  • a protective outer tube 65 is joined to a second end of the outer tube 61 through crimping, and the connection terminal 35 and the lead wire 37 are supported by a rubber cap 67 fitted in the protective outer tube 65.
  • a Pt-containing paste is applied through printing onto the substrate 5, dried at 120°C for one hour, and fired at 1,400°C for one hour.
  • zirconium oxynitrate is dissolved in H 2 O, and aqueous ammonia is added to the resultant solution, to thereby adjust the pH of the solution to 8.
  • the thus-obtained zirconium hydroxide is subjected to suction filtration, followed by washing. Thereafter, the resultant zirconium hydroxide is dried in a drying machine at 110°C for 24 hours, and then fired in an electric furnace at 400°C for 24 hours, to thereby yield a ZrO 2 powder having a large surface area.
  • ammonium tungstate is dissolved in H 2 O, and aqueous ammonia is added to the resultant solution, to thereby prepare a solution (W solution) having a pH of 10 to 11.
  • the above-obtained ZrO 2 powder is mixed with the W solution such that the amount of W as reduced to WO 3 becomes a predetermined value of 2 to 40 wt.% on the basis of the total amount (100 wt.%) of WO 3 and ZrO 2 , and the resultant mixture is placed in a crucible. Thereafter, the mixture is dried in a drying machine at 120°C for 24 hours, and then fired in an electric furnace at 800°C for five hours, to thereby yield a W-containing ZrO 2 powder (the target material).
  • the above-obtained W-containing ZrO 2 powder i.e., powder containing a primary component and a secondary component
  • an organic solvent i.e., ethanol
  • a dispersant is placed in a mortar, and disperse-mixed by use of a smash-mixing machine for four hours.
  • a binder is added to the resultant mixture, and wet-mixed for four hours, to thereby prepare a slurry.
  • the viscosity of the resultant slurry is regulated, to thereby yield a paste.
  • the thus-obtained paste containing the gas-sensitive material is applied through screen printing onto the insulating substrate 5 having the printed comb-shaped electrodes 11 and 13, so as to form a thick film. Thereafter, the paste is dried at 60°C, and then baked on the insulating substrate 5 by means of one-hour firing at 600°C.
  • a spinel (MgAl 2 O 4 ) paste is applied onto the sensitive layer 15 through printing.
  • the sensor element member 6 of the ammonia sensor 1 of the present embodiment is produced.
  • the ammonia sensor 1 of the present embodiment is employed in a system for reducing the amount of NO x contained in exhaust gas from a vehicle (diesel vehicle).
  • urea serving as a reducing agent is supplied to a known SCR catalytic system 75 provided on the upstream side of an oxidation catalyst 73 mounted on an exhaust pipe 71 of a vehicle, to thereby generate ammonia, and NO x contained in exhaust gas is chemically reduced to nitrogen by the thus-generated ammonia, to thereby clean the exhaust gas.
  • the amount of urea to be supplied i.e., the concentration of ammonia to be generated
  • the ammonia sensor 1 is provided on the downstream side of the SCR catalytic system 75, to thereby determine the concentration of ammonia discharged from the SCR catalytic system 75.
  • the supply amount of urea is increased, whereas when ammonia is detected by the ammonia sensor 1, the supply amount of urea is decreased in accordance with the thus-determined ammonia concentration.
  • the exhaust gas can be chemically reduced and cleaned at high efficiency.
  • the ammonia sensor 1 of the present embodiment When the ammonia sensor 1 of the present embodiment is not employed for measuring the concentration of ammonia, the ammonia sensor 1 can be cleaned under heating, to thereby maintain the performance of the ammonia sensor 1 at high level.
  • the element section 3 is heated at, for example, a temperature of 500 to 700°C (i.e., a temperature higher than the element temperature when the ammonia sensor 1 is employed in a routine manner and a temperature lower than the calcining temperature required for obtaining the powdery material of the sensitive layer 15); for example, the element section 3 is heated at 600°C for five minutes.
  • a substance adsorbed onto the ammonia sensor 1 particularly, the sensitive layer 15
  • moisture or miscellaneous gas can be completely removed.
  • a non-illustrated electronic control apparatus e.g., a microcomputer.
  • Test Examples 1 through 4 in which the effects of the ammonia sensor of the present embodiment were confirmed.
  • Samples, a test apparatus, etc. employed in the Test Examples will now be described.
  • ammonia sensors (sample Nos. 1 through 10), each including the corresponding sensitive layer shown in Table 1, the sensitive layer being formed from a material produced through any of the below-described production methods.
  • ammonia sensors (sample Nos. 1 through 4), each including a sensitive layer formed from a material produced through the production method described in the first embodiment (synthesis method A).
  • ammonia sensor (sample No. 5) including a sensitive layer formed from a material produced through the below-described synthesis method B.
  • synthesis method B firstly, a zirconium nitrate aqueous solution is added dropwise to aqueous ammonia, and the thus-prepared zirconium hydroxide precipitate is washed with water and then stirred in an ammonium tungstate aqueous solution. Subsequently, the resultant precipitate is subjected to filtration, and dried in a drying machine at 110°C for 12 hours. The thus-dried precipitate is fired at 700°C for five hours, to thereby yield a W-containing ZrO 2 powder (the target material). In a manner similar to that of the first embodiment, an ammonia sensor including a sensitive layer formed from the W-containing ZrO 2 powder was produced.
  • ammonia sensors (sample Nos. 7 through 9), each including a sensitive layer formed from a material produced through the below-described synthesis method C.
  • an ammonia sensor (sample No. 8)
  • a zirconium nitrate aqueous solution is added dropwise to aqueous ammonia, and the thus-prepared zirconium hydroxide precipitate is washed with water and then stirred in a 0.5 M sulfuric acid aqueous solution.
  • the resultant precipitate is subjected to filtration, and dried in a drying machine at 100°C for 12 hours.
  • the thus-dried precipitate is fired at 650°C for five hours, to thereby yield an S-containing ZrO 2 powder (the target material).
  • an ammonia sensor including a sensitive layer formed from the S-containing ZrO 2 powder was produced.
  • a comparative ammonia sensor (sample No. 6) including a sensitive layer containing merely a primary component
  • a comparative ammonia sensor (sample No. 10) including a sensitive layer containing merely a secondary component.
  • Each of the sensitive layers was formed as follows: a paste was prepared from a powder containing a single component (primary component or secondary component), and the paste was baked on the substrate, to thereby form the sensitive layer.
  • the ammonia sensor to be tested was placed in the evaluation apparatus and exposed to the gas flowing through the apparatus, an AC voltage (2 V) of a predetermined frequency (400 Hz) was applied between the electrode leads of the ammonia sensor, and the impedance of the ammonia sensor (i.e., the sensitive layer) was determined from the value of current flowing between the electrode leads.
  • NH 3 sensitivity (Z base - Z NH3 )/Z base ⁇ 100[%], wherein Z base is an impedance of the sensor as measured when the gas contains 0 ppm of NH 3 and Z NH3 is an impedance of the sensor as measured when the gas contains NH 3 .
  • the equation is similarly applied to the sensitivity to any other gas component.
  • the "Analytical value” shown in Table 1 refers to a value obtained through analysis of the sensitive layer of the above-produced ammonia sensor by use of the aforementioned inductively coupled argon plasma emission spectrophotometer.
  • ammonia sensors (sample Nos. 1 through 10), each including a sensitive layer formed from a material produced through any of the above-described production methods (synthesis methods A, B, and C).
  • the specific surface area of the raw material powder for the sensitive layer of each of the samples was measured by means of the BET method; i.e., the specific surface area of the ZrO 2 powder (primary component) for the sensitive layer of each of sample Nos. 1 through 9, and the specific surface area of the WO 3 powder (secondary component) for the sensitive layer of sample No. 10 were measured.
  • the specific surface area was measured by means of the N 2 gas adsorption BET method by use of Multisorb 12 (product of Yuasa Ionics Inc.), in which each of the above powders was exposed to flow of a gas mixture of He and N 2 at 200°C for 60 minutes. The results are shown in Table 2.
  • Each of the ammonia sensors was mounted in the evaluation apparatus, a gas containing NH 3 (concentration of NH 3 : 0, 5, 20, 50, 100, or 150 ppm) was supplied to the evaluation apparatus, and the impedance (Z) of the ammonia sensor was obtained under the following conditions: gas temperature: 280°C, element temperature: 350°C, 400°C, or 450°C. The results are shown in Figs. 6 through 16 . Each of the figures shows Sample No. and the element operation temperature.
  • ammonia sensors of the present invention exhibit good concentration-dependent sensitivity to ammonia of different concentrations.
  • the comparative ammonia sensor (sample No. 6), which includes the sensitive layer containing merely the primary component, exhibits no change in sensitivity to ammonia of different concentrations.
  • the results of evaluation of the comparative ammonia sensor (sample No. 10), which includes the sensitive layer containing merely the secondary component, will be described in Test Example 2.
  • Figs. 17 and 18 are comparative graphs showing the sensitivity to each of the above gases when the sensitivity to NH 3 is taken as 100.
  • the ammonia sensor of the present invention exhibits high sensitivity to NH 3 and very low sensitivity to other interference gases; i.e., the ammonia sensor exhibits excellent ammonia selectivity.
  • test results of the comparative ammonia sensor (sample No. 10), which includes the sensitive layer containing merely WO 3 (secondary component), are shown in Fig. 18 .
  • the ammonia sensor (sample No. 10), which includes the sensitive layer containing merely WO 3 (secondary component), exhibits sensitivity to different gases, and does not selectively detect NH 3 .
  • the element temperature is regulated by use of a Pt resistor (i.e., a temperature sensor, which is a temperature measuring resistor).
  • a Pt resistor i.e., a temperature sensor, which is a temperature measuring resistor
  • a gas (temperature: 300°C or 400°C, NH 3 concentration: 0, 5, 20, 50, 100, or 200 ppm) was supplied to the evaluation apparatus, and the impedance (Z) of the ammonia sensor was measured. The above procedure was repeated, except that the element temperature was not regulated.
  • the results are shown in Figs. 19 and 20.
  • Fig. 19 is a graph showing the gas temperature dependency of the NH 3 sensitivity in the case where element temperature is not regulated; and
  • Fig. 20 is a graph showing the gas temperature dependency of the NH 3 sensitivity in the case where element temperature is regulated.
  • Fig. 21 shows data obtained through the TPD measurement.
  • the peak end temperature i.e., T
  • the peak end temperature T was estimated to be 450°C from the mountain-shaped ammonia-temperature programmed desorption curve.
  • the peak end temperature T represents acid strength (NH 3 adsorption strength).
  • a temperature programmed desorption curve as shown in Fig. 21 , acid characteristics of a substance (sample) can be evaluated. Specifically, the acid content and the acid strength of the substance can be readily estimated from the integral area and the peak end temperature, respectively. However, these values vary in accordance with test conditions (e.g., the amount of the sample), and thus are not necessarily specific to the substance.
  • the acid contents of sample Nos. 2, 3, and 5 can be estimated to be 0.071 mmol/g, 0.107 mmol/g, and 0.224 mmol/g, respectively.
  • the impedance (Z) of the ammonia sensor (sample No. 5) was measured in a gas containing NH 3 whose concentration was varied in a stepwise manner from 0 to 5, 20, 100, 150, and 0 ppm at a predetermined interval (200 seconds) under the following conditions: gas temperature: 280°C, element temperature: 350°C or 450°C.
  • gas temperature: 280°C gas temperature: 280°C
  • element temperature 350°C or 450°C.
  • Figs. 22 and 23 are graphs showing the responsiveness of the sensor to NH 3 gas at the respective element temperatures.
  • Figs. 8 and 9 showing the relation between the sensitivity and the element temperature regarding the ammonia sensor (sample No. 3), in which the incorporation amount of the secondary component is small and the acid content is low; Figs. 11 and 12 showing the relation between the sensitivity and the element temperature regarding the ammonia sensor (sample No. 5), in which the incorporation amount of the secondary component is high and the acid content is high; and Figs. 22 and 23 showing the relation between the responsiveness and the element temperature regarding the ammonia sensor (sample No. 5), the ammonia sensor in which the acid content is high detects the NH 3 concentration at high accuracy even at a high regulation temperature.
  • the NH 3 sensitivity is enhanced.
  • the operation temperature of the ammonia sensor the element temperature
  • the sensor exhibits sufficient NH 3 sensitivity, and thus the sensor operation temperature can be increased. Therefore, the responsiveness of the sensor can be enhanced.
  • the optimum operation temperature of the ammonia sensor can be increased by increasing the incorporation amount of the secondary component; i.e., by increasing the acid content. Therefore, the temperature required for operation of the sensor is determined in accordance with the environment in which the sensor is employed (preferably, the sensor is operated at a temperature higher than that of the environment in order to avoid the effect of the environmental temperature on the sensor), and the composition of the primary and secondary components is determined such that the sensor can be operated at the above-determined temperature, to thereby optimize the design of the sensor.
  • the base impedance of the ammonia sensor as measured when NH 3 is 0 ppm decreases. Small base impedance is advantageous in designing a sensor control circuit.
  • ZrO 2 was employed as the primary component of the super-strong acidic metal oxide
  • WO 3 , SO 4 2- , or PO 4 3- was employed as the secondary component of the metal oxide.
  • the secondary component may also be selected from among MoO 3 and B 2 O 3 . This is because these oxides are considered to exhibit characteristics similar to those of the components of the super-strong acidic metal oxide employed in the Test Examples.
  • ammonia sensor of the second embodiment will next be described. Repeated description of components which are common between the ammonia sensors of the first and second embodiments is omitted.
  • the ammonia sensor of the second embodiment differs from that of the first embodiment in the configuration of a sensor element member.
  • an element section 103 of a sensor element member 102 constituting the essential portion of the ammonia sensor 101 of the present embodiment includes an insulating substrate 105 on which the below-described components are successively laminated.
  • a pair of lead portions 107 and 109 which predominantly contain platinum are provided on the insulating substrate 105 formed of alumina; a lower electrode 111 is provided on the substrate 105 so as to be connected to the lead portion 107; a sensitive layer 113 is provided on the lower electrode 111 so as to cover the entirety of the electrode 111; an upper electrode 115 is provided on the sensitive layer 113 so as to be connected to the lead portion 109; and a protective layer 117 is provided on the upper electrode 115 so as to cover the entirety of the electrode 115 and the entirety of a portion of the sensitive layer 113 that is exposed at the periphery of the electrode 115.
  • the sensitive layer 113 (thickness: about 30 ⁇ m) formed through thick-film printing contains a porous gas-sensitive material (i.e., a solid, super-strong acidic substance).
  • the lower electrode 111 and the upper electrode 115 are formed from a porous electrode material having a porosity larger than that of the material of the sensitive layer 113, such that the electrodes 111 and 115 do not impede diffusion of a sample gas to the sensitive layer 113.
  • a heater 119 for heating the element section 103 and a temperature sensor 120, which is a temperature-measuring resistor, are provided in the interior of the insulating substrate 105.
  • the ammonia sensor 101 of the present embodiment exhibits effects similar to those obtained from the ammonia sensor of the first embodiment.
  • the upper electrode 115 may serve as a protective layer for the sensitive layer 113.
  • ammonia sensor of the third embodiment will next be described. Repeated description of components which are common among the ammonia sensors of the first, second, and third embodiments is omitted.
  • the ammonia sensor of the present embodiment differs from that of the first or second embodiment in the configuration of a sensitive layer.
  • a sensitive layer (not illustrated) is formed of a composite oxide containing a ZrO 2 carrier (primary component) and WO 3 (secondary component) which is bonded to the surface of the carrier.
  • the ZrO 2 carrier contains a predetermined amount of Y 2 O 3 serving as an agent for stabilizing the crystal structure of ZrO 2 , and ZrO 2 and Y 2 O 3 together form a solid solution.
  • WO 3 is employed as the secondary component, but the secondary component may be at least one species selected from among WO 3 , MoO 3 , B 2 O 3 , SO 4 2- , and PO 4 3- .
  • the stabilizing agent is not necessarily limited to Y 2 O 3 , and may be at least one species selected from among CaO, MgO, Y 2 O 3 , Yb 2 O 3 , and Ga 2 O 3 .
  • the composite oxide employed in the present embodiment has a structure in which ZrO 2 and Y 2 O 3 form a solid solution in the crystal phase of ZrO 2 serving as the primary component, the stability of the crystal phase is high, and the composite oxide exhibits excellent thermal resistance and durability. Therefore, even when the ammonia sensor is employed at a high temperature (e.g., 400°C or higher) over a long period of time, the sensitivity of the sensor is not lowered, and the sensor provides consistent output.
  • a high temperature e.g. 400°C or higher
  • Y 2 O 3 is incorporated into the crystal phase of ZrO 2 such that ZrO 2 and Y 2 O 3 form a solid solution, thereby stabilizing the crystal phase of ZrO 2 .
  • This structure enables suppression of change in the crystal structure, whereby the secondary component is reliably bonded to the surface of the carrier. Therefore, even when the ammonia sensor is employed at a high temperature over a long period of time, the sensitivity of the sensor is not lowered, and the sensor provides consistent output.
  • Zirconium oxynitrate and yttrium nitrate were dissolved in H 2 O, and aqueous ammonia was added to the resultant solution, to thereby adjust the pH of the solution to 8.
  • the amount of yttrium nitrate was regulated such that the Y content of the target product (i.e., ZrO 2 -Y 2 O 3 powder) was 1) 2.7 mol%, 2) 4 mol%, or 3) 8 mol% as reduced to Y 2 O 3 .
  • the thus-obtained precipitate was subjected to suction-filtration and washing, and then dried in a drying machine at 110°C for 24 hours.
  • the thus-dried product was fired in a muffle furnace at 400°C for 24 hours, to thereby yield a ZrO 2 -Y 2 O 3 powder (which was to serve as a carrier) having a large specific surface area.
  • ammonium tungstate was weighed such that the W content of the target product (i.e., WO 3 /ZrO 2 -Y 2 O 3 powder) was 10 wt.% as reduced to WO 3 , and the thus-weighed ammonium tungstate was dissolved in H 2 O.
  • Aqueous ammonia was added to the resultant solution, to thereby adjust the pH of the solution to 10 to 11.
  • a predetermined amount of the above-obtained ZrO 2 -Y 2 O 3 powder was added to the resultant solution, and sufficiently stirred, to thereby prepare a suspension.
  • the suspension was subjected to evaporation to dryness by use of a rotary evaporator.
  • the thus-obtained solid was dried in a drying machine at 120°C for 24 hours, followed by firing in a muffle furnace at 800°C for five hours.
  • the target product i.e., WO 3 /ZrO 2 -Y 2 O 3 powder having a WO 3 content of 10 wt.% was obtained.
  • the powder was employed in the below-described Test Examples.
  • the specific surface area of the thus-obtained powder was measured by means of the BET method. The results are shown in Table 3.
  • the WO 3 content is 10 wt.% on the basis of the total amount (100 wt.%) of ZrO 2 -Y 2 O 3 (or ZrO 2 ) and WO 3 .
  • each of the powders synthesized as described above, an organic solvent, and a dispersant were placed in a mortar, and disperse-mixed by use of a smash-mixing machine for four hours. Thereafter, a binder was added to the resultant mixture, and wet-mixed for four hours, to thereby prepare a slurry. The viscosity of the resultant slurry is regulated, to thereby yield a paste.
  • the thus-obtained paste is applied through screen printing onto an insulating substrate having; on its surface, a pair of comb-shaped electrodes, so as to form a thick film.
  • the material of the comb-shaped electrodes may be, for example, Au, a noble metal other than Au, a noble metal alloy, or a mixture of noble metals.
  • the paste was dried at 60°C, and then baked on the insulating substrate at 600°C for one hour, to thereby produce a sensor element member of an ammonia sensor.
  • a sample gas generation apparatus similar to that employed in Test Example 1 was employed for evaluation of the ammonia sensor.
  • the ammonia sensor was subjected to evaluation under the following measurement conditions.
  • the ammonia sensor to be tested was placed in the evaluation apparatus and exposed to the gas flowing through the apparatus, a predetermined alternating voltage (2 V) at a predetermined frequency (400 Hz) was applied to the electrode leads of the ammonia sensor, and the impedance of the ammonia sensor (i.e., the sensitive layer) was obtained from a current flowing between the electrode leads.
  • NH 3 sensitivity was obtained by measuring the impedance of the sensor as measured in a gas containing 0 ppm NH 3 and the impedance of the sensor as measured in a gas containing NH 3 of different concentrations.
  • ammonia sensor incorporating a sensor element member including a sensitive layer formed of each of samples (1) through (4) shown in Table 3.
  • the thus-prepared ammonia sensor (hereinafter called an "untreated ammonia sensor") was employed as a test sample.
  • an ammonia sensor was prepared through the following procedure: a sensor element member including a sensitive layer formed of each of samples (1) through (4) shown in Table 3 was thermally treated (specifically, the sensor element member was heated in a small-sized heating furnace at 600°C for 100 hours); and the thus-treated sensor element member was assembled into an ammonia sensor.
  • the thus-prepared ammonia sensor (hereinafter called an "endured ammonia sensor") was employed as a test sample.
  • the above-prepared untreated and endured ammonia sensors were mounted in the aforementioned evaluation apparatus, to thereby evaluate performances of the sensors. Specifically, the concentration of ammonia in the gas was varied, and the sensitivity, measured based on variation in the impedance, was obtained for each of the ammonia sensors. The results are shown in Fig. 26 .
  • ammonia sensors including the sensitive layers formed of samples (1) through (3) i.e., the ammonia sensors including the sensitive layers formed of ZrO 2 stabilized by Y 2 O 3
  • variation in ammonia sensitivity between untreated and endured sensors is small, and even the endured ammonia sensor maintains sensitivity at a high level (comparable with the untreated ammonia sensor) and exhibits excellent thermal resistance and durability.
  • ammonia sensors including the sensitive layers formed of sample (4) (sample for comparison); i.e., the ammonia sensors including the sensitive layers formed of ZrO 2 which is not stabilized by Y 2 O 3 , the endured ammonia sensor exhibits considerably lowered sensitivity as compared with the untreated ammonia sensor.
  • a paste was prepared from each of samples (1) through (4) shown in Table 3, and the paste was applied through printing onto an alumina plate (size: 5 cm ⁇ 5 cm) and fired at 600°C for one hour, to thereby prepare a thick film sample (hereinafter may be called an "untreated sample").
  • thick film samples were formed in a manner similar to that described above, and each of the samples was heated in a small-sized heating furnace at 600°C for 100 hours, to thereby prepare a thermally treated thick film sample (hereafter may be called an "endured sample").
  • peaks at 28° and 31.5° correspond to monoclinic ZrO 2
  • a peak at 30° corresponds to tetragonal ZrO 2 or cubic ZrO 2 .
  • the thick film samples formed of sample (3) containing completely stabilized ZrO 2 in which Y 2 O 3 is incorporated in an amount of 8 mol% such that ZrO 2 and Y 2 O 3 form a solid solution, have a crystal structure of very high stability (substantially no peak corresponding to monoclinic ZrO 2 is observed for the endured sample).
  • sample for comparison i.e., the samples formed of ZrO 2 which is not stabilized by Y 2 O 3
  • the amount of tetragonal crystals is considerably reduced, and crystal phase transition from tetragonal crystals to more stable monoclinic crystals occurs at ambient temperature.
  • an ammonia sensor incorporates a selective layer formed of a material prepared by adding a stabilizing agent (e.g., Y 2 O 3 ) to ZrO 2 , the ammonia sensor exhibits excellent long-term stability even at a high temperature.
  • a stabilizing agent e.g., Y 2 O 3
  • ammonia sensor of the fourth embodiment will next be described. Repeated description of components which are common among the ammonia sensors of the first, second, third, and fourth embodiments is omitted.
  • the ammonia sensor of the present embodiment differs from that of the first, second, or third embodiment in a casing of the ammonia sensor into which a sensor element member is to be incorporated and the internal configuration of the sensor.
  • ammonia sensor of the present embodiment which is an assembly incorporating a sensor element member, will now be described.
  • a sensor element member 123 which, at its front-end portion (the lower portion as viewed in Fig. 28 ), includes an element section (not illustrated).
  • the rear-end portion (the upper portion as viewed in Fig. 28 ) of the sensor element member 123 is connected to a first end portion of each of metallic plates 125.
  • a second end portion of each of the metallic plates 125 is connected via a connection terminal 127 to a lead wire 129.
  • a ceramic holder 131, a talc powder 133, and an insulating protector 135 are provided around the sensor element member 123 from the front-end portion toward the rear-end portion of the member 123, and the ceramic holder 131, the talc powder 133, and the insulating protector 135 are accommodated in a main fitting 137.
  • the front-end portion of the sensor element member 123 is protected by a porous protector 139 supported by the main fitting 137.
  • the first end portion of the metallic plate 125 which has a wavy form, is sandwiched between the rear-end portion of the sensor element member 123 and the insulating protector 135, whereby the metallic plate 125 is in contact with the sensor element member 123.
  • an outer tube 141 is fitted around the main fitting 137 so as to cover the periphery of the rear-end portion of the ammonia sensor 121, and a ceramic separator 143 in which the lead wire 129 is inserted and a grommet 145 are fitted in the rear-end portion of the outer tube 141.
  • the connection terminal 127 is provided in the ceramic separator 143, and the rear-end of the outer tube 141 is sealed with the grommet 145.
  • the ammonia sensor 121 of the present embodiment having the above-described configuration, exhibits effects similar to those obtained from the ammonia sensor of the first embodiment.
  • the heater is not necessarily combined with the element section, and may be provided separately from the element section.
  • the platinum resistor and the heater may be vertically inverted.

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Claims (15)

  1. Capteur d'ammoniac (1) comprenant une section élémentaire (3), la section élémentaire comprenant une paire d'électrodes (11, 13) et une section sensible (15) venant en contact avec les électrodes appariées (11, 13),
    dans lequel la section sensible (15) contient une substance acide super-forte solide autre que la zéolite, la substance acide ayant une acidité ≤ -11,93 selon la fonction d'acidité H0 de Hammett, la substance acide super-forte solide comprenant au moins un élément sélectionné parmi les combinaisons suivantes de composants secondaires et de composants primaires :

            WO3/ZrO2, SO4 2-/ZrO2, PO4 3-/ZrO2, MoO3/ZrO2 et B2O3/ZrO2.

  2. Capteur d'ammoniac selon la revendication 1, dans lequel la substance acide super-forte solide est un oxyde composite contenant un porteur en ZrO2 jouant le rôle de composant primaire, et au moins l'une des espèces sélectionnées parmi WO3, MoO3, B2O3, SO4 2- et PO4 3-, jouant le rôle de composant secondaire, le composant secondaire étant lié à la surface du porteur, et le porteur contenant un agent pour stabiliser la structure cristalline du ZrO2.
  3. Capteur d'ammoniac selon la revendication 2, dans lequel l'agent de stabilisation de structure cristalline comprend au moins un élément sélectionné parmi CaO, MgO, Y2O3, Yb2O3 et Ga2O3.
  4. Capteur d'ammoniac selon la revendication 2, dans lequel au moins 4% en moles de Y2O3 sont inclus dans le porteur en ZrO2.
  5. Capteur d'ammoniac selon la revendication 2, dans lequel au moins 6% en moles de Y2O3 sont inclus dans le porteur en ZrO2.
  6. Capteur d'ammoniac selon l'une quelconque des revendications 1 à 5, dans lequel la substance acide super-forte solide a une teneur en acide d'au moins 0,05 mmole/g.
  7. Capteur d'ammoniac selon l'une quelconque des revendications précédentes, dans lequel, lorsque la quantité totale des composants primaires et secondaires précédemment mentionnés est considérée comme étant de 100% en moles, la quantité du composant secondaire est comprise entre 1 et 25% en moles.
  8. Capteur d'ammoniac selon l'une quelconque des revendications 1 à 7, dans lequel, lorsque la section sensible contient de façon prédominante du ZrO2 et contient de plus au moins W, la teneur en W de la section sensible est comprise entre 1,5 et 30% en poids, converti en WO3.
  9. Capteur d'ammoniac selon l'une quelconque des revendications 1 à 8, comprenant de plus une couche protectrice (17) recouvrant la section sensible (15).
  10. Capteur d'ammoniac selon l'une quelconque des revendications 1 à 9, comprenant de plus un élément chauffant (19) incorporé dans le substrat isolant (5) pour chauffer la section élémentaire.
  11. Capteur d'ammoniac selon la revendication 10, dans lequel le capteur d'ammoniac comprend un substrat isolant et l'élément chauffant incorporé dans le substrat isolant, les électrodes appariées étant formées sur le substrat isolant, et la section sensible étant formée de façon à recouvrir les électrodes appariées.
  12. Capteur d'ammoniac selon la revendication 10, dans lequel le capteur d'ammoniac comprend un substrat isolant dans lequel est incorporé l'élément chauffant, une électrode inférieure et une électrode supérieure, les électrodes inférieure et supérieure constituant les électrodes appariées, l'électrode inférieure étant formée sur le substrat isolant, la section sensible étant formée de façon à recouvrir l'électrode inférieure, et l'électrode supérieure étant formée sur la section sensible.
  13. Capteur d'ammoniac selon l'une quelconque des revendications 10 à 12, comprenant de plus des moyens de détection de température d'élément pour détecter la température de l'élément, et des moyens de régulation de température pour commander l'élément chauffant de telle sorte que la température de l'élément rentre à l'intérieur d'une plage de température prédéterminée.
  14. Capteur d'ammoniac selon l'une quelconque des revendications précédentes, dans lequel la section sensible est essentiellement constituée par la substance acide super-forte solide.
  15. Capteur d'ammoniac selon l'une quelconque des revendications précédentes, dans lequel la section sensible est constituée par la substance acide super-forte solide.
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US7341694B2 (en) 2008-03-11
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