EP1365901A2 - Procede et dispositif de preparation, notamment de deblais - Google Patents
Procede et dispositif de preparation, notamment de deblaisInfo
- Publication number
- EP1365901A2 EP1365901A2 EP02750515A EP02750515A EP1365901A2 EP 1365901 A2 EP1365901 A2 EP 1365901A2 EP 02750515 A EP02750515 A EP 02750515A EP 02750515 A EP02750515 A EP 02750515A EP 1365901 A2 EP1365901 A2 EP 1365901A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- material mixture
- homogenizing
- additive
- component
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/12—Apparatus having only parallel elements
- B07B1/14—Roller screens
- B07B1/15—Roller screens using corrugated, grooved or ribbed rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/26—Mixers with an endless belt for transport of the material, e.g. in layers or with mixing means above or at the end of the belt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/60—Mixing solids with solids
Definitions
- the invention relates to a method for processing a material mixture, in particular for processing a material mixture that contains at least one lumpy coarse component and a sticky component, and an apparatus for performing the method according to the invention.
- blade separators for material separation. These are designed in the manner of an excavator bucket, in the bottom of which at least two driven rollers are arranged. Disks and chisels are arranged on these. For material preparation, the material mixture is picked up with this shovel and the shovel is pivoted in such a way that the material contained on the rollers overloaded. The rotations of the rollers let the fine fraction fall between them downwards, while the coarse component remains in the blade separator and can then be tipped out.
- DE 199 25 502 Cl discloses a method for extracting oil from drilling mud and / or oil-containing drilling mud fractions.
- coal dust is added to the drilling mud.
- the resulting suspension is then mixed, after which the mixture is separated into a light and a heavy coal dust oil fraction.
- the coal dust-oil fraction is then separated off by desorption or extraction.
- the method according to the invention continuously prepares the material mixture.
- both the material mixture to be processed and an additive are each fed to a homogenizing and separating device as a continuous stream of material.
- a water-binding additive can be added to reduce the stickiness of the binding component.
- the uniform distribution of the aggregate in the material mixture is therefore essential for good separability of the entire coarse component from the entire fine component.
- the coarse component obtained as a usable product in this way but also the fine component provided with the additive in a sufficient degree of homogenization, so that post-treatment of the fine component can be omitted.
- a flow equilibrium is established in the homogenizing and separating device between supplied material flows and discharged material flows.
- the conditions in the homogenizing and separating device can thus be set essentially constant during the operation of the system.
- the conditions include those present in the homogenizing and separating device Amount of substance, its composition, its speed and direction of movement, the moisture content of the mixture and the composition thereof.
- the material components forming the mixture can be separated from one another in a single pass through the plant and converted into separately usable products.
- non-recyclable waste such as sludge or the like.
- the homogenizing and separating device has a homogenizing section which extends from an input to an output.
- the material mixture and the aggregate pass through the homogenizing section in the same direction. Separation outputs branch off down the entire length of the homogenization section, which e.g. are formed by gaps between rotating shafts.
- a moisture-regulating substance is preferably used as the additive, such as, for example, quicklime as powder or as granules, cement, ash, stone powder, granules, fibers (cellulose fibers or others), wood shavings, wood flour, suspensions such as lime sludge bentonite or sealing suspensions e.g. on a plastic basis.
- the additives are preferably selected such that the cohesive and the lumpy component can be separated better from one another and that the cohesive component, after it has been separated from the lumpy component, has the required or desired physical properties, such as load-bearing capacity or tightness.
- the amount of the additive supplied per unit of time is measured continuously or from time to time using the Water content of the mixture of materials to be processed.
- a moisture probe connected to a central controller can be used for this.
- the moisture can be determined by taking a sample and subsequent testing. On the basis of the physical properties of the sample (formability or directly measured moisture content) it is possible to determine the suitable amount of the additive, for example using a table, and to enter it via an input device in the central control of the processing plant.
- the system can be designed such that the determined moisture content of the material mixture is entered, after which the central control device determines the required amount of aggregate on the basis of internal calculation rules or tables.
- the size of the material mixture material flow fed in is regulated, for example, by means of the layer height on a feeding conveyor belt.
- the layer height is made approximately as large as the largest diameter of the chunks forming the lumpy material component. This represents the lowest possible layer thickness for an undisturbed process.
- a material mixture feed is preferably used in which the layer height of the material mixture lying, for example, on a conveyor belt and fed in this way is set as low as possible.
- the width of the conveyor belt can be significantly larger. It is possible to apply the aggregate only as a narrow strip on the material mixture. However, it is preferred to apply it over the entire width, so that within the limits of the accuracy of this technical process, the same uniform layer height of the material mixture with uniform coverage (layer height) of the additive is obtained over the entire width of the feeding conveyor belt. This gives the best prerequisites for good homogenization and thus also for a good separation effect of the homogenization and separation device.
- a device for carrying out the method according to the invention is specified in claim 12.
- the device has at least one homogenizing and separating device, a material feed device and an additive metering device.
- the devices are designed in such a way that they each work continuously, ie continuously feed material and aggregate to the homogenizing and separating device, the homogenizing and separating device working continuously, ie in a continuous process.
- it is considered advantageous to arrange a roller grate in the storage container. This enables a more even material feed as well as the rejection of too large material components,
- the material feed device is formed, for example, by a belt conveyor device and optionally an upstream separating device.
- the material feed device continuously conveys a material mixture flow even with discontinuous material feed.
- a constant material height can be set on the conveyor belt using a slider or an aperture.
- the belt conveyor can also be designed as a weighing conveyor.
- a feed hopper is preferably arranged above the conveyor belt. If it is to be expected that the material mixture contains components that are too coarse, it is considered advantageous to arrange a roller grate in or above the feed hopper for the lateral discharge of excessively coarse components. This prevents very coarse components from interfering with the conveying process when feeding the material mixture.
- the roller grate arranged above the belt conveyor acts as a material buffer. Discontinuous and abundant material is fed onto the roller grate from the roller grate in a relatively uniform manner to the belt conveyor of the material feeder.
- roller grate of the material feed device it is considered to be particularly advantageous to design the roller grate of the material feed device to be adjustable in inclination. This enables performance to be adjusted to different flow rates and material qualities.
- the axes of rotation of the rollers are preferably arranged horizontally, while the conveying direction (horizontal, ascending or descending) should be adjustable.
- the roller distances are preferably fixed; but they can also be set adjustable.
- the roller spacing can be determined in accordance with each other.
- a splitting or breaking device with at least two mutually parallel shafts can also be provided, which carry wedge elements.
- the wedge elements are oriented obliquely to the radial direction and obliquely to the circumferential direction and serve to split up the very large components (coarse components, ie stones or boulders, the diameter of which is greater than the maximum layer thickness on the conveyor belt of the feed device).
- Such a splitting device is preferably set up to limit the maximum grain size to approximately 200 mm, ie to split larger parts accordingly, and to convey smaller material unaffected.
- a roller grate, a disc separator or a similar arrangement can be used as a homogenizing and separating device. These have in common that they have several shafts arranged parallel to one another, which are preferably driven rotating in the same direction.
- the waves carry separator elements, for example disks, disks provided with chisels, or non-round, for example elliptical elements. Due to the rotation in the same direction, the shafts and the separator elements define a conveying direction.
- the material mixture and the aggregate are added.
- the coarse component is removed at the opposite end of the conveyor track. This can be done continuously or discontinuously.
- a discharge device is used to control this process.
- the separator elements can be provided with projections such as chisels, pins, fingers or the like. be provided. This improves both the separator effect and the homogenization effect.
- the device according to the invention can have a sensor device which controls the size of the additive flow in relation to the material flow of the material mixture to be processed via a control device. This then enables a fully automatic mode of operation insofar as the quantity of aggregate required to achieve an optimal separation of the material components is automatically dosed.
- FIG. 1 shows a device for processing a material mixture in a schematic representation
- FIG. 2 shows the separation process as a flow picture
- FIG. 3 shows the device according to FIG. 1 in a detailed detail view
- FIG. 4 shows a disk separator as part of a homogenizing and separating device in a schematic sectional view
- FIG. 5 shows a separating device with non-circular separator elements in a schematic side view
- Figure 6 shows a splitting device for pretreatment of the
- FIG. 1 ' A processing device 1 is illustrated in FIG. 1 ' , which is used in particular for processing material mixtures 2 which contain a coarse component 3 and a fine component 4.
- the coarse component 3 is formed, for example, by stones, boulders or other solid components of the material mixture 2.
- the material mixture 2 is, for example, excavated soil, which as a fine component 4 has a non-piece portion, which contains clay or clay. The clay or clay portion leads to a cohesion or a certain stickiness of the material mixture 2 or the fine component 4 in accordance with the moisture present.
- the material mixture 2 is processed by the processing device 1 in that the coarse component 3, as indicated on the right in FIG. 1, is separated from the fine component 4 and output separately.
- the fine component 4, however, is also mixed separately with an additive 5 as a prepared fine component 6.
- the processing device 1 has a material feed device 7, which in the exemplary embodiment is formed by a belt conveyor device 8 in connection with a drive device 9.
- This material feed device 7 is used to introduce the material mixture 2 into a homogenizing and separating device 12 in a continuous material flow 11.
- the homogenizing and separating device 12 has a number of shafts 14 arranged horizontally parallel to one another, which are connected to the drive device 9 or a separate drive device. The shafts rotate evenly or with increasing speed in the direction of passage and, as illustrated in FIG.
- a homogenization chamber 16 is formed above the shafts 14 and separator elements 15, through which the material mixture 2 is conveyed in accordance with the rotation of the shafts 14 from a feed position 17 to a starting position 18 in the conveying direction F.
- the material mixture 2 is circulated, whereby the fine component 4 largely falls down between the shafts 14.
- a collecting device 19 Arranged below the path formed by the shafts 14 is a collecting device 19 which directs the mixture 6 onto a conveying device 21, for example in the form of a belt conveying device.
- a metering device 22 for the additive 5 is arranged above the material feed device 7.
- the metering device 22 is designed such that it emits a continuous stream of material 23, which is illustrated, for example, in FIG. 3.
- the metering device 22 can be designed as a cellular wheel sluice. This has a cellular wheel 24, which is driven in rotation, for example, under the control of a central control device 25 (FIG. 5).
- the metering device 22 is preferably designed so as to apply the aggregate 5 over the entire width of the belt conveyor 8 to the lying on the belt conveyor 8 material mixture. 2
- a discharge device 26 is provided, which is used for the controlled discharge of the coarse component 3 arriving here.
- the discharge device 26 can be formed, for example, by a motor-operated slide 27 or a flap, which from time to time releases and closes an output under the control of the control device 25. Instead of the slide 27, if necessary, a free exit can also be provided, through which the coarse components 3 arriving here are continuously released.
- a slide 28 is provided above the belt conveyor 8, which is fixed or can be adjusted separately by a motor under the control of the control device 25 or by hand , As illustrated in FIG.
- the slider 28 produces a layer of material mixture of height H, the height H being determined by the distance between the lower edge of the slider 28 and the conveyor belt.
- the height H is dimensioned such that it just slightly exceeds the largest diameter D of the coarse component 3. It is notess- "tens as large as the distance between the rollers 31st
- the slide 28 preferably has a rotatably mounted roller 28a or a corresponding roller on its underside. He or she delimits a feed space 29 above the belt conveyor 8 which is filled with material mixture 2 and into which the material mixture 2 is constantly refilled.
- a moisture sensor 32 which is connected to the control device 25, projects into this feed space, at least in a preferred embodiment. This uses the data obtained about the moisture or the water content of the material mixture to dose the appropriate amount of aggregate.
- a rough separation device for example in the form of a roller grate 30 with driven rollers 31, is provided in the feed space 29 or above it.
- the roller grate 30 is set or constructed in such a way that oversized material components do not get onto the conveyor belt but are sorted out.
- the rollers 31 are arranged at appropriate distances from one another. This affects material components, the size of which corresponds to the height of the slide 28 exceed the slot defined by the conveyor belt.
- the roller grate 30 serves to discharge the coarse components before further processing.
- An outlet flap is provided on the side next to the roller grate to allow the collection of coarse parts.
- a splitting or breaking device 36 can also be provided.
- the coarse component is then not rejected, but shredded.
- the splitting device 36 has at least two mutually parallel, oppositely driven shafts 37, 38 which carry wedge elements 41 on corresponding arms 39.
- the wedge elements 41 run in groups on different diameters and are oriented obliquely to the radial direction and obliquely to the circumferential direction.
- the distances between the shafts 37, 38 and their wedge elements 41 are set such that fine and medium-coarse components of up to approximately 200 mm in diameter are conveyed downwards without being crushed between the shafts 37, 38.
- the wedge elements 41 each have a tip 42 for the selective introduction of force into the crushed material and serve to split up the very large components (coarse component, i.e. stones or boulders, the diameter of which is greater than the maximum layer thickness on the conveyor belt of the feed device).
- a splitting device 36 is preferably set up to limit the maximum grain size to about 200 mm, i.e. to split larger parts accordingly and to convey smaller material unaffected.
- blades 43 can be provided on the shafts for improved conveyance of fine particles between the shafts 37, 38.
- Such a splitting device 36 can also be provided after the roller grate 30, if only from time to time split the coarse components separated by the roller grate and process them separately,
- the processing device 1 described so far operates as follows:
- the belt conveyor 8 conveys the material mixture 2 as a material flow 11 (FIG. 3) into the homogenization space 16 while forming a constant layer thickness.
- the control device 25 determines the speed of the cellular wheel 24 on the basis of the water content of the material mixture 2 measured by the moisture sensor 32 or a corresponding specification. This creates a uniform layer of thickness Z, consisting of aggregate 5, on the material stream 11. For example, quick lime (CaO) is used as the aggregate. Depending on the water content of the material mixture, about 2 to a maximum of about 15% additive to the material mixture 2 is used. In this way, the material flow 11 and the material flow 23 as illustrated in FIG.
- the separation is to be improved, or if this is difficult for other reasons, it can sometimes be carried out discontinuously by reversing the direction of rotation of the shafts 14 periodically or from time to time.
- the belt conveyor 8 can be stopped briefly or continue to run. The reversal can under certain circumstances further support the material separation, especially if the fine component 4 is very cohesive.
- the process mentioned produces two usable products at the same time, namely the coarse components 3 (stones, pebbles, rocks or the like) separated from the material mixture and the fine fraction 4 mixed with aggregate 5, such as cement, lime, fibers or other aggregate materials, as a mixture 6
- coarse components 3a are already sorted out of the feed bunker by the roller grate 30 and discharged separately. They can be used without being shredded or fed to a shredding plant (e.g. rock crushing plant).
- the mixture 6 of corresponding additives 5 can be reusable, for example as a filling material for trenches or the like.
- the shafts 14 are connected to elliptical separator elements 15 '.
- separator elements 15'a and 15'b are each offset on a shaft 14 by 90 °, as can be seen on the left in FIG. 5 on the basis of the separator elements 15'a and 15'b.
- separator elements of adjacent shafts 14, which are adjacent to one another in the conveying direction F are offset from one another, again by 90 °.
- the separator elements 15 ' can be provided with chisels 33, 34 which can promote both the homogenization of the material mixture and the separation into its coarse and fine components.
- This type of homogenizing and separating device 12 provides an increased transport effect and a good separating effect for separating coarse components 3 and fine components 4 from one another.
- both the material mixture 2 and an additive 5 are fed to a homogenizing and separating device 12 in continuous streams 11, 23.
- the homogenizing and separating device 12 serves to uniformly mix the aggregate 5 and the material mixture 2 with one another in order to convert the fine component 4 of the material mixture 2 into such a state that the fine component 4 can be separated from the coarse component 3.
- an intimate mixing of additive 5 and fine component 4 ' is achieved, so that the coarse component and fine component can be separated directly in the same device.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processing Of Solid Wastes (AREA)
- Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
Abstract
L'invention concerne un procédé de préparation de mélanges de matières qui contiennent une composante grossière (3) et une composante fine (4) principalement cohésive, le mélange de matières (2) tout comme un granulat (5) étant cédés à un dispositif d'homogénéisation et de séparation (12) sous forme de flux continus (11, 23). Le dispositif d'homogénéisation et de séparation (12) sert à mélanger de façon uniforme le granulat (5) et le mélange de matières (2) pour transformer la composante fine (4) du mélange (2) de telle manière qu'elle puisse être séparée de la composante grossière (3). L'alimentation continue du dispositif d'homogénéisation et de séparation (12) en mélange (2) et en granulat (5) permet d'obtenir un mélange intime du granulat (5) et de la composante fine (4), de telle façon que la composante grossière et la composante fine puissent être séparées immédiatement dans le même équipement. Ce procédé permet de préparer des mélanges de matières (2) sans déchet en une seule opération et d'obtenir deux produits utilisables.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10111300A DE10111300B4 (de) | 2001-03-09 | 2001-03-09 | Aufbereitungsvorrichtung insbesondere für Aushub |
DE10111300 | 2001-03-09 | ||
PCT/DE2002/000826 WO2002072329A2 (fr) | 2001-03-09 | 2002-03-08 | Procede et dispositif de preparation, notamment de deblais |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1365901A2 true EP1365901A2 (fr) | 2003-12-03 |
Family
ID=7676817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02750515A Withdrawn EP1365901A2 (fr) | 2001-03-09 | 2002-03-08 | Procede et dispositif de preparation, notamment de deblais |
Country Status (6)
Country | Link |
---|---|
US (1) | US7182204B2 (fr) |
EP (1) | EP1365901A2 (fr) |
AU (1) | AU2002308359A1 (fr) |
CA (1) | CA2439069A1 (fr) |
DE (1) | DE10111300B4 (fr) |
WO (1) | WO2002072329A2 (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070272776A1 (en) * | 2003-05-14 | 2007-11-29 | Jurgen Schenk | Method and Apparatus for Processing Excavated Earth |
FR2882377B1 (fr) * | 2005-02-22 | 2008-10-24 | Fibac Sa | Procede de traitement de sols, en particulier de sols secs sensibles a l'eau |
US8360249B1 (en) * | 2006-11-22 | 2013-01-29 | Albert Ben Currey | Crusher and mechanical bucket for use therewith |
DE102009004619A1 (de) * | 2009-01-15 | 2011-02-17 | Mérai, Josef, Dipl.-Ing. | Verfahren und Anlage zur Schaffung einer alternativen Kläranlage zur Aufbereitung von kommunalen, industriellen und landwirtschaftlichen Abwässern und Schlämmen |
CN103124600A (zh) * | 2010-07-23 | 2013-05-29 | 第一太阳能有限公司 | 粉体共混物 |
KR102028632B1 (ko) * | 2018-07-10 | 2019-10-04 | 기형도 | 적하 충격을 최소화할 수 있는 버력 선별장치 |
AT521538B1 (de) * | 2018-07-25 | 2020-04-15 | Rohrdorfer Transp Gmbh | Künettenfüllmaterial sowie Verfahren zu dessen Wiederaufbereitung |
CN110202696B (zh) * | 2019-06-27 | 2024-05-28 | 广西路桥工程集团有限公司 | 一种纤维分散装置 |
CN111570045B (zh) * | 2020-05-14 | 2021-11-05 | 刘津君 | 一种矿石肥料土制造装置 |
CN111532805B (zh) * | 2020-05-26 | 2024-09-10 | 中冶赛迪工程技术股份有限公司 | 一种短流程混矿加工工艺及系统 |
DE102021107719B3 (de) * | 2021-03-26 | 2022-04-28 | Soil2Sand UG (haftungsbeschränkt) | Verfahren zur Gewinnung eines sandartigen Bodenbaustoffs und dessen Verwendung zur Herstellung von Beton |
CN113019639A (zh) * | 2021-03-27 | 2021-06-25 | 刘绪多 | 一种智能一体化多功能西药用研磨装置 |
DE102022106905B3 (de) * | 2022-03-23 | 2023-01-05 | Jörg K. Müller | Verfahren zur Gewinnung eines feinkrümeligen Kultursubstrats und dessen Verwendung |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1400721A (en) * | 1971-04-15 | 1975-07-23 | Redland Roadstone Ltd | Method of and apparatus for production of coated roadstone |
US4297311A (en) * | 1978-12-07 | 1981-10-27 | Conwed Corporation | Method of manufacturing improved mineral board |
DE3244898C2 (de) * | 1982-12-04 | 1985-04-11 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verfahren zur Abtrennung von mineralischem ultrafeinen Korn aus Waschwässern der Kohleaufbereitung bzw. aus Kohleschlämmen |
DE4409507A1 (de) * | 1994-03-19 | 1995-09-21 | Walter Schoelkopf | Vorrichtung zur Aufbereitung von Erdreich zu einem standfesten Baumaterial |
CH690758A5 (de) | 1995-03-28 | 2001-01-15 | Mbt Holding Ag | Vorrichtung, Anlage und Verfahren zum Beimischen eines flüssigen Zusatzstoffes zu einer fliessfähigen Grundmasse. |
DE19627465C2 (de) * | 1996-07-08 | 1997-08-07 | Uhrig Strasen Und Tiefbau Gmbh | Verfahren zum Aufbereiten von Aushubmaterial |
DE19925502C1 (de) * | 1999-06-04 | 2001-03-01 | Geesthacht Gkss Forschung | Verfahren zur Gewinnung von Öl aus Bohrschlamm und/oder ölhaltigen Bohrschlammfraktionen |
US6444731B1 (en) * | 1999-08-06 | 2002-09-03 | G. Mohammed Memon | Modified asphalt |
ITBO20020100A1 (it) * | 2002-02-28 | 2003-08-28 | Tecnomeccanica Srl | Apparato per alimentare una macchina utilizzatrice con prodotti particolari |
-
2001
- 2001-03-09 DE DE10111300A patent/DE10111300B4/de not_active Expired - Fee Related
-
2002
- 2002-03-08 CA CA002439069A patent/CA2439069A1/fr not_active Abandoned
- 2002-03-08 US US10/471,008 patent/US7182204B2/en not_active Expired - Fee Related
- 2002-03-08 AU AU2002308359A patent/AU2002308359A1/en not_active Abandoned
- 2002-03-08 WO PCT/DE2002/000826 patent/WO2002072329A2/fr not_active Application Discontinuation
- 2002-03-08 EP EP02750515A patent/EP1365901A2/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO02072329A2 * |
Also Published As
Publication number | Publication date |
---|---|
WO2002072329A3 (fr) | 2002-12-27 |
CA2439069A1 (fr) | 2002-09-19 |
DE10111300A1 (de) | 2002-09-26 |
US7182204B2 (en) | 2007-02-27 |
WO2002072329A2 (fr) | 2002-09-19 |
DE10111300B4 (de) | 2007-12-13 |
AU2002308359A1 (en) | 2002-09-24 |
US20040091319A1 (en) | 2004-05-13 |
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