EP1361074B1 - Verfahren zum Verbessern der Metalleffekte, der Weiterverarbeitungskriterien sowie der Flexibilität von harzbeschichteten Dekorpapieren - Google Patents
Verfahren zum Verbessern der Metalleffekte, der Weiterverarbeitungskriterien sowie der Flexibilität von harzbeschichteten Dekorpapieren Download PDFInfo
- Publication number
- EP1361074B1 EP1361074B1 EP02009270A EP02009270A EP1361074B1 EP 1361074 B1 EP1361074 B1 EP 1361074B1 EP 02009270 A EP02009270 A EP 02009270A EP 02009270 A EP02009270 A EP 02009270A EP 1361074 B1 EP1361074 B1 EP 1361074B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sodium aluminate
- fond
- water
- gravure printing
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 229920005989 resin Polymers 0.000 title claims abstract description 17
- 239000011347 resin Substances 0.000 title claims abstract description 17
- 230000000694 effects Effects 0.000 claims abstract description 32
- 238000007639 printing Methods 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 19
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 12
- 238000007646 gravure printing Methods 0.000 claims description 11
- 239000000976 ink Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000004606 Fillers/Extenders Substances 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 239000003086 colorant Substances 0.000 abstract description 10
- 229910052728 basic metal Inorganic materials 0.000 abstract description 4
- -1 basic metal salts Chemical class 0.000 abstract description 4
- 239000000123 paper Substances 0.000 description 33
- 239000003973 paint Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 239000002023 wood Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010037867 Rash macular Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 238000010073 coating (rubber) Methods 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002983 wood substitute Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/18—Particular kinds of wallpapers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
Definitions
- the present invention relates to methods for improving the metallic effects and further processing criteria as well as the flexibility of resin-coated Decorative papers.
- Printed decorative papers are used in the coating industry Coating of laminates, or they are directly on wood substitute panels applied for surface improvement and -beautification.
- the further processing is done by impregnation with melamine resins, phenolic resins, urea resins as well as other mixed resin systems and other resin solutions as well by painting with chemically or physically curing paint systems.
- Highly absorbent resin-impregnable decorative papers having a weight per unit area of 45 g / m 2 to 200 g / m 2 , preferably 70 g / m 2 to 90 g / m 2 , are used as materials for the substrates for the printed image and for the resin.
- Water-dispersible decorative printing inks used are paints without organic solvents or with limited solvent content with exclusively organic color pigments and casein-based binder systems, as well as overpressure blends for mother-of-pearl based on polyurethanes.
- RWO decorative printing inks are known, for example, under the trade names Hartmann / 761 series or Arcolor 1010/1012/3008/3017/5000/7000 and others, metallic effect colors T1332 / 761, T2630 / 761, Arcolor Ardeco brilliant silver, Ardeco brilliant mother among others, iridescent or iriondin ink.
- Coated wood materials are made by pulling the high-pressure laminate panels (HPL) by mechanically / thermally imageable edges, in pre-milled Wood material, achieved during the bending process. This procedure is called Postforming called.
- Conventionally produced standard base papers can be in the high pressure laminate area (HPL) not or only insufficiently around these tight Deforming radii, for example in the manufacture of countertops or Furniture fronts with rounded edges.
- Base papers so-called postforming papers used, this after the State of the art.
- the sandwich panels themselves receive at the critical narrow radii on the opposite side of the coating differently shaped notches or milling, as described for example in DE19830778C1. The At the outer edge of the sheet applied paper layer is here, however, considerably stretched.
- optical and physical properties as well as the achieved metallic effect of the Finished wood-based materials are further decisive quality criteria.
- the maximum optical effects are achieved by applying the highest possible quantities of paint scored in decor printing. These are rear cylinder with the largest possible used theoretical ink transfer volume. The maximum possible Ink transfer is limited by the drying capacity of the printing presses.
- Binder household reduces the fixation of the pigments on the decor paper and causes during the impregnation a bleeding of the decor pressure, which in Flooding of larger amounts of metallic effect pigments in the resin liquor shows.
- the binder content is too low, the abrasion resistance of the non-resinated material is negligible printed decorative paper so down that a run of the printed paper web as Web through the steering rollers in the impregnating without damaging the Print image is hardly possible.
- the possibilities, higher metal effects by increasing to achieve the color order are thus limited.
- the problems are as follows: Unhomogeneous dark and blotchy surfaces, possibly "pearlescent". Through a Increased metallic paint application are not improved mother of pearl or Metallic effects achieved more.
- the general solution according to the invention is to delay the curing Solutions of basic metal salts during gravure printing applied. This can improve the postforming properties of the inexpensive plain papers are used, and a costly chemical Pre-treatment of special papers is eliminated. Metallic salts in the basic range are used to improve postforming properties. Continue this method improves the gloss and the metallic effects as well the reduction of pressing errors, as described above achieved. Other features, Details and embodiments will become apparent from the dependent claims.
- HPL high-pressure laminate sector
- the fund of homogeneous color funds on decorative papers with basis weights of 70 g / m 2 to 90 g / m 2
- planar coating methods such as flexographic printing, Haschurwalzen Lucas or similar methods should be possible.
- the transfer of surface ink quantities should take place wet with high ink coverage on printed or unprinted decorative papers.
- the ink transfer in rotogravure should be done with a rear cylinder.
- a gravure printing unit of a Dekor briefly horrinskymaschine is with a pressure cylinder printed with a homogeneously engraved grid, which is always used here as a "rear cylinder” referred to as.
- the color transfer to the rear cylinder takes place from storage containers by means of electric pumps or pneumatic diaphragm pumps.
- the metal effect color is constantly stirred to prevent sedimentation and over the Pumps kept in circulation. From the storage containers, the color is in the color pans conveyed under the rear cylinder into the printing unit of Dekortiefdruckmaschine.
- the application of the metallic effect color takes place by means of An Hugheswalzen, which with a lasered and slightly compressible rubber coating are coated. By means of this will be picked up the paint from the paint tray and applied to the printing cylinder.
- the rear cylinder is dipped directly into the color stand of the paint tray and picks up a color film on the surface and in the wells.
- the rear cylinder is further passed by a squeegee, which the excess Metal effect color from the cylinder surface scratches and only a defined Quantity of paint left in a so-called cup.
- the cylinder comes into the pressure zone.
- the paper web that over Drives and guide rollers of the pressure zone of the printing unit is supplied by means of a Pressed with mechanical pressure roller pressed on the cylinder.
- the force with which this press called roller presses the paper is usually 18 N / cm, depending on the application also a higher force.
- a sodium aluminate solution (Water or water / waste mixture) in the gravure printing method by means of a Rear cylinder applied to the surface of Metallic horre.
- This is a significantly increased pearlescent or metallic effect with simultaneous improvement Surface homogeneity HPL / LPM achieved.
- Nacreous pigments are compounds in the form of feldspar or silicic acid (silicon dioxide), which are coated with titanium dioxide.
Landscapes
- Printing Methods (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PT02009270T PT1361074E (pt) | 2002-04-26 | 2002-04-26 | Processo para melhorar os efeitos metalicos, os criterios de acabamento e a flexibilidade de papeis decorativos revestidos com resina |
| DE50203499T DE50203499D1 (de) | 2002-04-26 | 2002-04-26 | Verfahren zum Verbessern der Metalleffekte, der Weiterverarbeitungskriterien sowie der Flexibilität von harzbeschichteten Dekorpapieren |
| AT02009270T ATE298671T1 (de) | 2002-04-26 | 2002-04-26 | Verfahren zum verbessern der metalleffekte, der weiterverarbeitungskriterien sowie der flexibilität von harzbeschichteten dekorpapieren |
| EP02009270A EP1361074B1 (de) | 2002-04-26 | 2002-04-26 | Verfahren zum Verbessern der Metalleffekte, der Weiterverarbeitungskriterien sowie der Flexibilität von harzbeschichteten Dekorpapieren |
| ES02009270T ES2241919T3 (es) | 2002-04-26 | 2002-04-26 | Procedimiento para mejorar los efectos metalicos y los criterios del procesamiento. |
| DK02009270T DK1361074T3 (da) | 2002-04-26 | 2002-04-26 | Fremgangsmåde til forbedring af metaleffekterne, videreforarbejdningskriterierne samt fleksibiliteten af harpikscoatede dekorpapirer |
| TR2004/03486T TR200403486T2 (tr) | 2002-04-26 | 2003-04-24 | Reçine kaplı dekoratif kağıtların metal effektlerini iyileştirme yöntemi |
| PL373297A PL201674B1 (pl) | 2002-04-26 | 2003-04-24 | Sposób podwyższania efektów metalicznych i kryteriów dalszej obróbki oraz elastyczności papierów dekoracyjnych pokrytych żywicą |
| US10/512,036 US7348040B2 (en) | 2002-04-26 | 2003-04-24 | Method for improving characteristics of resin coated papers comprising applying a solution of one or more alkaline metal salts |
| BRPI0309565-7A BR0309565B1 (pt) | 2002-04-26 | 2003-04-24 | Método para aprimorar os efeitos metálicos e critérios de processamento posterior, bem como a flexibilidade de papéis de decoração revestidos com resina |
| AU2003242523A AU2003242523A1 (en) | 2002-04-26 | 2003-04-24 | Method for improving the metallic effects and further processing criteria and flexibility of decorative paper coated with resin |
| RU2004134585/12A RU2304049C2 (ru) | 2002-04-26 | 2003-04-24 | Способ улучшения эффекта внешнего вида металла и показателей технологичности, а также повышения гибкости декоративной бумаги с полимерным покрытием |
| PCT/EP2003/004247 WO2003091470A2 (de) | 2002-04-26 | 2003-04-24 | Verfahren zum verbessern der metalleffekte und weiterverarbeitungskriterien sowie flexibilität von harzbeschichteten dekorpapieren |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02009270A EP1361074B1 (de) | 2002-04-26 | 2002-04-26 | Verfahren zum Verbessern der Metalleffekte, der Weiterverarbeitungskriterien sowie der Flexibilität von harzbeschichteten Dekorpapieren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1361074A1 EP1361074A1 (de) | 2003-11-12 |
| EP1361074B1 true EP1361074B1 (de) | 2005-06-29 |
Family
ID=29225597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02009270A Expired - Lifetime EP1361074B1 (de) | 2002-04-26 | 2002-04-26 | Verfahren zum Verbessern der Metalleffekte, der Weiterverarbeitungskriterien sowie der Flexibilität von harzbeschichteten Dekorpapieren |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7348040B2 (pl) |
| EP (1) | EP1361074B1 (pl) |
| AT (1) | ATE298671T1 (pl) |
| AU (1) | AU2003242523A1 (pl) |
| BR (1) | BR0309565B1 (pl) |
| DE (1) | DE50203499D1 (pl) |
| DK (1) | DK1361074T3 (pl) |
| ES (1) | ES2241919T3 (pl) |
| PL (1) | PL201674B1 (pl) |
| PT (1) | PT1361074E (pl) |
| RU (1) | RU2304049C2 (pl) |
| TR (1) | TR200403486T2 (pl) |
| WO (1) | WO2003091470A2 (pl) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010089086A1 (de) | 2009-02-04 | 2010-08-12 | Okt Germany Gmbh | Verfahren zur herstellung von dekorpapier sowie dekorpapier |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3730828A (en) * | 1971-03-23 | 1973-05-01 | Plastics Manuf Co | Postformable laminate comprising a barrier sheet of wood fiber impregnated with fully cured unplasticized melamine-formaldehyde resin |
| DE2537409A1 (de) * | 1975-08-22 | 1977-03-03 | Roemmler H Resopal Werk Gmbh | Dekorative schichtstoffplatte bzw. verbundelement |
| DE2658784C3 (de) * | 1976-12-24 | 1983-12-08 | E. Holtzmann & Cie. Ag, 7566 Weisenbach | Verwendung eines thermoplastischen Faservlieses |
| DE3004060A1 (de) * | 1979-02-07 | 1980-08-21 | Toyo Soda Mfg Co Ltd | Verfahren zum herstellen von y-zeolith |
| CH649773A5 (de) * | 1979-09-24 | 1985-06-14 | Sandoz Ag | Asymmetrische 1:2-chromkomplexe aromatischer azoverbindungen, verfahren zu ihrer herstellung und diese enthaltende praeparate. |
| SU1052601A1 (ru) * | 1982-10-27 | 1983-11-07 | Центральный научно-исследовательский институт бумаги | Бумага дл глубокой печати |
| US5006451A (en) * | 1989-08-10 | 1991-04-09 | Eastman Kodak Company | Photographic support material comprising an antistatic layer and a barrier layer |
| US5302441A (en) * | 1991-11-15 | 1994-04-12 | The Mead Corporation | Postformable decorative laminating paper |
-
2002
- 2002-04-26 ES ES02009270T patent/ES2241919T3/es not_active Expired - Lifetime
- 2002-04-26 DK DK02009270T patent/DK1361074T3/da active
- 2002-04-26 PT PT02009270T patent/PT1361074E/pt unknown
- 2002-04-26 EP EP02009270A patent/EP1361074B1/de not_active Expired - Lifetime
- 2002-04-26 DE DE50203499T patent/DE50203499D1/de not_active Expired - Lifetime
- 2002-04-26 AT AT02009270T patent/ATE298671T1/de not_active IP Right Cessation
-
2003
- 2003-04-24 TR TR2004/03486T patent/TR200403486T2/xx unknown
- 2003-04-24 RU RU2004134585/12A patent/RU2304049C2/ru not_active IP Right Cessation
- 2003-04-24 AU AU2003242523A patent/AU2003242523A1/en not_active Abandoned
- 2003-04-24 US US10/512,036 patent/US7348040B2/en not_active Expired - Fee Related
- 2003-04-24 WO PCT/EP2003/004247 patent/WO2003091470A2/de not_active Ceased
- 2003-04-24 BR BRPI0309565-7A patent/BR0309565B1/pt not_active IP Right Cessation
- 2003-04-24 PL PL373297A patent/PL201674B1/pl unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010089086A1 (de) | 2009-02-04 | 2010-08-12 | Okt Germany Gmbh | Verfahren zur herstellung von dekorpapier sowie dekorpapier |
Also Published As
| Publication number | Publication date |
|---|---|
| US7348040B2 (en) | 2008-03-25 |
| PT1361074E (pt) | 2005-11-30 |
| PL201674B1 (pl) | 2009-04-30 |
| US20060008586A1 (en) | 2006-01-12 |
| TR200403486T2 (tr) | 2005-05-23 |
| ATE298671T1 (de) | 2005-07-15 |
| BR0309565B1 (pt) | 2014-04-01 |
| AU2003242523A1 (en) | 2003-11-10 |
| DK1361074T3 (da) | 2005-08-29 |
| AU2003242523A8 (en) | 2003-11-10 |
| RU2004134585A (ru) | 2005-05-10 |
| DE50203499D1 (de) | 2005-08-04 |
| PL373297A1 (pl) | 2005-08-22 |
| BR0309565A (pt) | 2005-04-05 |
| WO2003091470A2 (de) | 2003-11-06 |
| RU2304049C2 (ru) | 2007-08-10 |
| ES2241919T3 (es) | 2005-11-01 |
| EP1361074A1 (de) | 2003-11-12 |
| WO2003091470A3 (de) | 2004-04-01 |
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