EP1306138A2 - Verfahren zur kontinuierlichen Beschichtung von bandförmigen Substraten mit Flüssigkeitsfilm aus vernetzbarem Polymer - Google Patents

Verfahren zur kontinuierlichen Beschichtung von bandförmigen Substraten mit Flüssigkeitsfilm aus vernetzbarem Polymer Download PDF

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Publication number
EP1306138A2
EP1306138A2 EP02292532A EP02292532A EP1306138A2 EP 1306138 A2 EP1306138 A2 EP 1306138A2 EP 02292532 A EP02292532 A EP 02292532A EP 02292532 A EP02292532 A EP 02292532A EP 1306138 A2 EP1306138 A2 EP 1306138A2
Authority
EP
European Patent Office
Prior art keywords
polymer
film
strip
temporary additive
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP02292532A
Other languages
English (en)
French (fr)
Other versions
EP1306138A3 (de
Inventor
Frédéric JENNY
Thierry Soas
Richard Verhalle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArcelorMittal France SA
Original Assignee
USINOR SA
Arcelor France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by USINOR SA, Arcelor France SA filed Critical USINOR SA
Publication of EP1306138A2 publication Critical patent/EP1306138A2/de
Publication of EP1306138A3 publication Critical patent/EP1306138A3/de
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
    • B05D1/265—Extrusion coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2252/00—Sheets
    • B05D2252/02—Sheets of indefinite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218—Pretreatment, e.g. heating the substrate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/068—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using ionising radiations (gamma, X, electrons)

Definitions

  • the present invention relates to a continuous coating process at least one face of at least one strip by a mono fluid film or multilayer of crosslinkable polymer free of solvent or diluent and the softening temperature is above 50 ° C.
  • crosslinkable polymers to be hardened by heat treatment, by irradiation (UV radiation, electron beam %), after their application on the strip or by any other suitable process.
  • crosslinkable organic coatings such as paints or varnishes for example
  • paints or varnishes for example
  • a technique particularly used to deposit coatings with base of crosslinkable polymers free of solvent or diluent on a strip running is dusting. This technique consists in applying on tape a layer of polymer in powder form and then melt the polymer to re-spread it, and cook it for a few minutes at a temperature conventionally between 180 and 200 ° C so as to form a film.
  • This process consists in forming a crosslinkable polymer film melted by forced flow through a nozzle supplied with crosslinkable polymer melted either in an extruder or in a barrel void, on a cylinder preferably deformable surface applicator in contact with the surface of the strip to be coated. Transfer of the film formed by forced flow on the strip in scrolling is achieved by friction of the applicator cylinder and the strip, the scrolling of the two surfaces taking place in opposite directions, we then speak of reverse transfer (reverse in French). Cooking these polymers is carried out under conditions different from those of powder polymers standard; The cooking temperature is higher, around 230 to 270 ° C, and the cooking time much shorter, of the order of 10 to 60 s.
  • This reverse transfer coating process does not allow use standard powder polymers whose viscosity is too high high so that they can be extruded without risk of crosslinking in good conditions, i.e. with sufficient flow and pressure drop acceptable.
  • Solvent-free crosslinkable polymer formulations or diluent and whose particularity is to present a temperature at the start of higher crosslinking than that of powder polymers, as well as a viscosity have therefore been developed for this type of process.
  • the transfer process reverse remains difficult to implement, because we are still forced to heat the polymer to decrease its viscosity before forming a film by forced flow through the nozzle.
  • This process has the disadvantage of requiring very precise adjustment of the temperatures at the barrel or extruder, and at the nozzle. In addition, it does not make it possible to obtain coatings having a state always satisfactory surface area.
  • the present invention therefore aims to remedy the drawbacks prior art methods by providing a method of continuous coating of strips with a crosslinkable polymer free of solvent or diluent and whose softening temperature is higher at 50 ° C., which makes it possible to avoid any risk of the start of crosslinking of the polymer untimely before film formation, and to obtain a thin film of polymer cross-linked of uniform thickness and having a surface state free of craters.
  • the inventors have demonstrated that the addition of this temporary additive strongly reduces the viscosity of the polymer. From then on, it becomes possible increase the difference between the polymer film formation temperature crosslinkable and the temperature at which the polymer begins to crosslink by decreasing the polymer film formation temperature, which reduces the risk of crosslinking before film formation. So completely unexpected, the inventors have also found that by adding to the polymer crosslinkable a temporary additive with a boiling point included between the polymer film formation temperature minus 30 ° C and the temperature at the start of crosslinking of the polymer, the formation of craters in the crosslinked polymer film.
  • the temporary additive not only acts as a temporary plasticizer of the polymer, but also improves the surface appearance of the film.
  • the invention applies not only to metal strips, as for example steel, aluminum or an aluminum alloy, but also glass, plastic, plywood, or other suitable material, and the tape may have been previously painted or covered with a coating on one or two faces.
  • the solvent or diluent-free crosslinkable polymer can be crosslinkable thermally, or even by irradiation (UV or beam electrons).
  • irradiation UV or beam electrons
  • the compositions thermosets based on hydroxylated polyesters and blocked isocyanates and reference will be made to application WO95 / 21706 for a general description of products of this type, well known to those skilled in the art.
  • Polymers crosslinkable by irradiation can be radical systems or cationic, even hybrid systems.
  • the polymer can usually contain fillers, pigments, additives such as catalysts, plasticizers, stabilizers or any other known additive.
  • additive is understood to mean temporary, an additive that is added to the crosslinkable polymer, before formation of polymer film, and that we do not find, or almost not, in the composition of the crosslinked polymer film. This temporary additive is neither a solvent or diluent of the crosslinkable polymer.
  • the polymers used in this process have temperatures of softening, start of flow and start of different crosslinking.
  • the temperature at the start of crosslinking is the temperature from which an increase in viscosity is observed more than 10% in less than 15 min.
  • the polymers used in the context of the present invention are such that their softening temperature is higher than 50 ° C, which means that they are solid or very viscous at ambient temperature.
  • the strip is continuously scrolled on at least one support, and a fluid film of the said strip is deposited on the strip.
  • a temporary additive is added to the crosslinkable polymer before the film is formed, the boiling point T e of which is between the formation temperature T F of the polymer film mixed with the temporary additive minus 30 ° C, and the start temperature of crosslinking of the polymer T r . Since the crosslinkable polymer does not dissolve in the temporary additive, a homogeneous mixture is not formed.
  • This temporary additive acts as a temporary plasticizer for the polymer, making it less viscous, which makes it possible to melt the polymer / temporary additive mixture in the extruder or in the barrel-void, at a temperature T F of at least 10 °. C lower than the formation temperature T fo of the polymer film not mixed with a temporary additive.
  • the temporary additive produces significant foaming of the polymer.
  • the degassing of the polymer is thus facilitated before the crosslinking of the polymer, and a crosslinked polymer film free of craters is obtained.
  • the inventors have demonstrated that when the boiling point T e of the temporary additive is equal to or greater than the temperature at which the crosslinking begins to cross-link with the polymer, the additive does not have time to act and it generates numerous craters by rupture of the already crosslinked polymer film.
  • the boiling point T e of the temporary additive is preferably equal to the forming temperature T F of the polymer film mixed with the temporary additive more or less 20 ° C. In fact, when the boiling point T e of the temporary additive is lower than the formation temperature T F of the polymer film mixed with the temporary additive minus 20 ° C., the additive tends to vaporize in the 'extruder or in the barrel emptier. The temporary additive still acts as a temporary plasticizer for the polymer, but loses its effect on the surface appearance of the polymer film.
  • the boiling point T e of the temporary additive is chosen as a function of the crosslinkable polymer according to the invention of which it is desired to form a film by forced flow. It is between 70 and 155 ° C, preferably between 90 and 120 ° C.
  • the temporary additive retained is water.
  • the temporary additive is preferably added in liquid form in a proportion between 1 and 5% by weight of the crosslinkable polymer, preferably between 2 and 4%.
  • Figure 1 there is shown a coating installation, by reverse transfer, of a moving band B, by a fluid polymer film crosslinkable, comprising means for melting the polymer, means for formation of the polymer film, and means for reverse transfer of the film to band B.
  • the polymer melting means consist of an extruder 1 comprising a hopper 1a into which the polymer is introduced in the form solid particles, and means for heating and kneading the polymer consisting of a worm 1b which pushes the molten polymer to through a die.
  • the extruder may also include a flow control of the molten polymer (not shown) like a pump that we have between the exit of the extruder and the means of forming the polymer film. Feeding the molten polymer to the means of film formation takes place, for example, through a hose heater 2.
  • the heater hose 2 can advantageously be equipped with a heating homogenization system 10 of the molten polymer, as for example a static mixer.
  • the means for forming the polymer film comprise a nozzle 3 provided with a slot bearing against the deformable surface of a cylinder applicator 4.
  • the molten polymer film forcibly flows through of the slot of the nozzle 3 on the applicator cylinder 4.
  • the slot of the nozzle 3 is provided with means for adjusting the position of the edges of the nozzle slot relative to the surface of the applicator cylinder 4. Due to the parallelism of the nozzle 3 and applicator cylinder 4, a film is formed thereon of uniform thickness.
  • the means for reverse transfer of the polymer film consist of the applicator cylinder 4 and a support cylinder 5 of the band B, which are rotated in the opposite direction.
  • the applicator cylinder 4 is in contact with the surface of strip B, which is in contact with the cylinder support 5 and is driven in scrolling according to arrow F by means drive (not shown).
  • the applicator cylinder 4 is generally deformable and is formed of a steel core coated with a layer elastomer, while the support cylinder 5 is most often dimensionally stable.
  • the coating installation according to the invention may also include preheating means 6, such as an induction furnace, which make it possible to bring the strip B to a temperature between the formation temperature T F of the film of polymer mixed with the temporary additive and the temperature T r at the start of crosslinking of the polymer, so as to improve the quality of the adhesion between the polymer and the strip B.
  • preheating means 6 such as an induction furnace, which make it possible to bring the strip B to a temperature between the formation temperature T F of the film of polymer mixed with the temporary additive and the temperature T r at the start of crosslinking of the polymer, so as to improve the quality of the adhesion between the polymer and the strip B.
  • a mixture of the polymer in the form of solid particles with the temporary additive in liquid form in a first step, a mixture of the polymer in the form of solid particles with the temporary additive in liquid form, and in a second step, introduces this mixture into the hopper 1a of the extruder 1.
  • the additive is added temporary by injection into one of the zones of the extruder 1, preferably at a mixing zone of the extrusion screw 1b so as to obtain a better dispersion of the additive in the polymer.
  • the temporary additive is added by injection into the heating homogenization system 10 of the molten polymer, preferably at the inlet of the system 10 to promote the dispersion of the temporary additive in the polymer.
  • the film of the temporary polymer / additive mixture is formed by forced flow through the nozzle 3 at a temperature T F of at least 10 ° C lower than the formation temperature T fo of the polymer film not mixed with an additive. temporary.
  • the coated strip BR then passes through means of crosslinking 7 which can be constituted, for example, by an induction furnace or convection when the polymer is crosslinkable thermally, or else again by UV lamps or by electron beams when it's photocrosslinkable. In the latter case, the effect of the radiation to that of temperature to accelerate the hardening of the polymer.
  • crosslinking 7 can be constituted, for example, by an induction furnace or convection when the polymer is crosslinkable thermally, or else again by UV lamps or by electron beams when it's photocrosslinkable. In the latter case, the effect of the radiation to that of temperature to accelerate the hardening of the polymer.
  • the means of conditioning the polymer film are formed by an internal cylinder heating system applicator and / or by an external heating system such as for example infrared lamps.
  • the applicator cylinder 4 is rotated in the direction of travel of the band B, and in this case the polymer film formed is transferred to the applicator cylinder 4 by forced flow from the applicator cylinder 4 onto the strip B by compressing it between the support cylinder 5 of the strip B and the applicator cylinder 4. This is of the direct transfer coating process.
  • the installation can include a taker cylinder (not shown) located upstream of the cylinder applicator 4, and in this case the slot of the nozzle 3 is in abutment against the surface of the taker cylinder.
  • the fluid polymer film is formed in the molten state on the take-up cylinder.
  • the film is transferred to the applicator cylinder 4, the surface of the gripping cylinder moving in contact with the surface of the cylinder applicator 4 either in the opposite direction or in the same direction. Then, we transfers the film from the applicator cylinder 4 to the strip B, either by transfer direct, either by reverse transfer.
  • the installation does not does not include an applicator cylinder 4.
  • the slot of the nozzle 3 is then in direct support against the surface of strip B, and the film formed by flow forced through the nozzle is deposited directly on the strip B.
  • Figure 2 differs from the previous one in that the means for melting the polymer consist of a barrel void 8 comprising a barrel 8a and a heating plate 8b equipped with a pump 9 allowing control the flow of molten polymer.
  • the supply of the polymer melted to nozzle 3 takes place, for example, through a hose heater 2.
  • the heater hose 2 can advantageously be equipped with a heating homogenization system 10 of the molten polymer, as for example a static mixer.
  • the temporary additive is added by injection into an area of the drum-caster where the polymer is melted.
  • the polymer / temporary additive mixture is melted in the barrel 8 at a temperature T F of at least 10 ° C lower than the formation temperature T fo of the polymer film not mixed with a temporary additive.
  • the temporary additive is added by injection into the heating homogenization system 10 of the molten polymer, preferably at the inlet of the system 10 to promote the dispersion of the temporary additive in the polymer.
  • the film of the temporary polymer / additive mixture is formed by forced flow through a nozzle 3 at a temperature T F of at least 10 ° C lower than the formation temperature T fo of the polymer film not mixed with an additive. temporary.
  • the crosslinkable polymer is used in the form of solid particles, into which the additive has been previously incorporated temporary.
  • a mixture containing the polymer is prepared solid particles with the additive in liquid form, we melt this mix for example in an extruder, and we form a sheet that we let cool.
  • the tablecloth After the tablecloth has completely cooled, it is ground so as to obtain the polymer in the form of solid particles and incorporating the temporary additive.
  • This polymer incorporating the temporary additive is then implemented, i.e. it is melted either in the extruder 1 or in the drum emptier 8 so as to form a film by forced flow through the nozzle 3.
  • the temporary additive is injected under pressure.
  • an injection needle supplied by a high pressure piston pump.
  • the purpose of this example is to illustrate the plasticizing effect of a temporary additive according to the invention when added to a crosslinkable polymer thermosetting.
  • thermosetting crosslinkable polymer is as follows: Hydroxylated polyester resin 55% Uretdione hardener 10% TiO 2 pigment (for a white appearance of the final coating) 33% Additives (spreading agent, catalysts ...) 2%
  • This composition was developed to be applied on a strip running according to the reverse transfer coating process.
  • One side of a steel strip was coated with a layer of this crosslinkable thermosetting polymer, using the reverse transfer coating method as illustrated in FIG. 1.
  • the polymer was extruded, and a fluid film of the polymer was formed on the applicator cylinder by forced flow of the molten polymer through the nozzle at a temperature T fo of 130 ° C (measured in the nozzle).
  • polymers can be extruded standard powder, i.e. polymers with higher viscosity and the crosslinking start temperature is lower than that of the polymer previously described.
  • composition of a standard powder polymer is as follows: Carboxylated polyester resin 60% TGIC hardener (Triglycidylisocyanurate) 5% TiO 2 pigment (for a white appearance of the final coating) 33% Additives (spreading agent, catalysts ...) 2%
  • the viscosity of this polymer is too high to be able to be extruded at a temperature below its crosslinking start temperature minus 10 ° C.
  • the viscosity drops sufficiently so that the polymer / temporary additive mixture can be extruded under good flow conditions, so as to form a film by forced flow through the nozzle. at a temperature T F of 115 ° C.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
EP02292532A 2001-10-29 2002-10-15 Verfahren zur kontinuierlichen Beschichtung von bandförmigen Substraten mit Flüssigkeitsfilm aus vernetzbarem Polymer Ceased EP1306138A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0114086A FR2831470A1 (fr) 2001-10-29 2001-10-29 Procede de revetement en continu d'une bande par un film fluide en polymere reticulable
FR0114086 2001-10-29

Publications (2)

Publication Number Publication Date
EP1306138A2 true EP1306138A2 (de) 2003-05-02
EP1306138A3 EP1306138A3 (de) 2006-08-02

Family

ID=8868922

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Application Number Title Priority Date Filing Date
EP02292532A Ceased EP1306138A3 (de) 2001-10-29 2002-10-15 Verfahren zur kontinuierlichen Beschichtung von bandförmigen Substraten mit Flüssigkeitsfilm aus vernetzbarem Polymer

Country Status (4)

Country Link
EP (1) EP1306138A3 (de)
JP (1) JP2003164796A (de)
AU (1) AU2002301628B2 (de)
FR (1) FR2831470A1 (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008071638A1 (en) * 2006-12-14 2008-06-19 W.R. Grace & Co.-Conn. Metal substrate coating process
WO2014031987A3 (en) * 2012-08-23 2014-08-07 Selwyn Gary S Chemical stick finishing method and apparatus
CN114302773A (zh) * 2020-08-04 2022-04-08 株式会社东芝 涂敷装置以及涂敷方法
CN115315318A (zh) * 2021-03-04 2022-11-08 株式会社东芝 涂敷装置及涂敷方法

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
DE4013319A1 (de) * 1990-04-26 1991-10-31 Pagendarm Gmbh Vorrichtung zum auftragen einer schicht auf eine substratbahn
ATE250469T1 (de) * 1992-07-08 2003-10-15 Ppg Ind Ohio Inc Beschichtungsverfahren und zusammensetzungen
CA2122075A1 (en) * 1993-04-30 1994-10-31 Glen H. Bayer, Jr. Coating process and apparatus
DE19542097C2 (de) * 1995-11-11 1997-10-16 Hans Josef May Vorrichtung zum Beschichten von Metallbändern
FR2767074B1 (fr) * 1997-08-08 1999-10-22 Lorraine Laminage Procede et dispositif de revetement en continu d'au moins une bande metallique par un film en polymere reticulable fluide
ES2207309T3 (es) * 1998-12-16 2004-05-16 Sollac Procedimiento y dispositivo de revestimiento en continuo de al menos una banda metalica por una pelicula fluida de polimero reticulable.
FR2787353B1 (fr) * 1998-12-16 2001-03-09 Lorraine Laminage Procede et dispositif de revetement en continu d'au moins une bande metallique par un film fluide en polymere reticulable
FR2814688B1 (fr) * 2000-09-29 2003-06-27 Usinor Procede et dispositif de revetement en continu d'au moins une face d'une bande metalique par un film fluide monocouche ou multicouches en polymeres reticulable
FR2814689A1 (fr) * 2000-09-29 2002-04-05 Usinor Procede et dispositif de revetement en continu d'au moins une face d'une bande metallique par un film fluide multicouches en polymere reticulable

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008071638A1 (en) * 2006-12-14 2008-06-19 W.R. Grace & Co.-Conn. Metal substrate coating process
WO2014031987A3 (en) * 2012-08-23 2014-08-07 Selwyn Gary S Chemical stick finishing method and apparatus
CN114302773A (zh) * 2020-08-04 2022-04-08 株式会社东芝 涂敷装置以及涂敷方法
CN114302773B (zh) * 2020-08-04 2023-10-20 株式会社东芝 涂敷装置以及涂敷方法
EP4194104A4 (de) * 2020-08-04 2024-05-29 Kabushiki Kaisha Toshiba Anwendungsvorrichtung und anwendungsverfahren
US12233432B2 (en) 2020-08-04 2025-02-25 Kabushiki Kaisha Toshiba Coating apparatus and coating method
CN115315318A (zh) * 2021-03-04 2022-11-08 株式会社东芝 涂敷装置及涂敷方法

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Publication number Publication date
JP2003164796A (ja) 2003-06-10
FR2831470A1 (fr) 2003-05-02
EP1306138A3 (de) 2006-08-02
AU2002301628B2 (en) 2007-08-16

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