EP1298996A1 - Herbicides selectifs a base d'heteroaryloxy-acetamides - Google Patents

Herbicides selectifs a base d'heteroaryloxy-acetamides

Info

Publication number
EP1298996A1
EP1298996A1 EP01943335A EP01943335A EP1298996A1 EP 1298996 A1 EP1298996 A1 EP 1298996A1 EP 01943335 A EP01943335 A EP 01943335A EP 01943335 A EP01943335 A EP 01943335A EP 1298996 A1 EP1298996 A1 EP 1298996A1
Authority
EP
European Patent Office
Prior art keywords
methyl
ethyl
chloro
phenyl
dihydro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01943335A
Other languages
German (de)
English (en)
Inventor
Dieter Feucht
Peter Dahmen
Mark Wilhelm Drewes
Rolf Pontzen
Mathias Kremer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10041619A external-priority patent/DE10041619A1/de
Priority to EP10158924A priority Critical patent/EP2243366A3/fr
Priority to EP10158913.3A priority patent/EP2243361B1/fr
Priority to EP10158916.6A priority patent/EP2243363B1/fr
Priority to EP10158933A priority patent/EP2243370A2/fr
Priority to EP10158915.8A priority patent/EP2243362B1/fr
Priority to EP10158932A priority patent/EP2243369A3/fr
Priority to EP10158929A priority patent/EP2243368A3/fr
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP10158925A priority patent/EP2243367A3/fr
Priority to DK05005219.0T priority patent/DK1552746T3/en
Priority to EP10158918A priority patent/EP2243365A3/fr
Priority to EP10158917.4A priority patent/EP2243364B1/fr
Priority to EP05005219.0A priority patent/EP1552746B1/fr
Publication of EP1298996A1 publication Critical patent/EP1298996A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms

Definitions

  • the invention relates to new selective herbicidal, synergistic active ingredient combinations which consist of known heteroaryloxyacetamides on the one hand and known herbicidally active compounds and / or compounds which improve the tolerance of crop plants on the other hand and which are used with particularly good success for selective weed control in various crop plants can.
  • Heteroaryloxyacetamides as strong herbicides which are particularly effective against monocotyledon weeds, are the subject of a number of patent applications (cf. EP-A 5501, EP-A 18497, EP-A 29171, EP-A 94514, EP-A 100044, EP-A 100045, EP -A 161602, EP-A 195237, EP-A 348734, EP-A 348737, DE-A 4317323).
  • EP-A 5501, EP-A 18497, EP-A 29171, EP-A 94514, EP-A 100044, EP-A 100045, EP -A 161602, EP-A 195237, EP-A 348734, EP-A 348737, DE-A 4317323 are the subject of a number of patent applications.
  • active substance combinations are heteroaryloxyacetamides and other herbicidally active compounds to achieve a synergistic effect (cf. WO-A 94/02014, WO-A-96/07323, WO-A-96/11575, WO-A-96/17519 , WO-A-
  • the invention relates to selective herbicidal compositions, characterized by an effective content of an active ingredient combination consisting of
  • Ar represents phenyl which is optionally substituted by halogen, C 4 -C 4 -alkyl or C 4 -C 4 -haloalkyl,
  • Het is thiadiazolyl which is substituted by halogen or by C1-C4-alkyl or phenyl which is optionally substituted by halogen, and
  • R represents alkyl, alkenyl or alkynyl each having up to 4 carbon atoms
  • Ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazole carboxylate isoxadifen-ethyl
  • diethyl l- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole -3,5-dicarboxy-lat mefenpyr-diethyl
  • 2-dichloromethyl-2-methyl-1,3-dioxolane MG-191, 1,8-naphthalic acid anhydride, ⁇ - (1,3-dioxolane-2 -yl-methoximino) -phenylaceto-nitrile (oxabetrinil), 2,2-dichloro-N- (1,3-dioxolan-2-yl-methyl) -N- (2-propenyl) -acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyl-oxazolidine (R-2
  • Ar preferably represents phenyl optionally substituted by fluorine, chlorine, bromine, methyl, ethyl or trifluoromethyl.
  • Het preferably stands for 1,2,4-thiadiazolyl or 1,3,4-thiadiazolyl, which by fluorine, chlorine, bromine or by optionally by fluorine and / or Chlorine substituted methyl, ethyl, n- or i-propyl or phenyl is substituted.
  • R preferably represents methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, 2-propenyl, l-methyl-2-propenyl, 2-butenyl, 2-propynyl, 1- Methyl 2-propynyl, 2-butynyl.
  • Ar particularly preferably represents phenyl optionally substituted by fluorine, chlorine, bromine, methyl or trifluoromethyl.
  • Het is particularly preferably 1,2,4-thiadiazolyl or 1,3,4-thiadiazolyl, which is substituted by fluorine, chlorine, bromine or by methyl, ethyl or phenyl which are optionally substituted by fluorine and / or chlorine.
  • R particularly preferably represents methyl, ethyl, n- or i-propyl, n-, i-, s- or t-
  • Ar very particularly preferably represents phenyl optionally substituted by fluorine or chlorine.
  • Het very particularly preferably represents 1,3,4-thiadiazolyl which is substituted by chlorine, bromine or by fluorine- and / or chlorine-substituted methyl.
  • R very particularly preferably represents methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl.
  • Examples of the compounds of the formula (I) to be used as mixture partners according to the invention are: Ni-propyl-N-phenyl- ⁇ - (5-trifluoromethyl-l, 3,4-thiadiazol-2-yl-oxy) -acetamide, Ni-propyl-N- (2-chlorophenyl) - ⁇ - (5th -trifluora ⁇ ethyl-l, 3,4-thiadiazol-2-yl-oxy) -acetamide, Ni-propyl-N- (3-chlorophenyl) - ⁇ - (5-trifluoromethyl-l, 3,4-thiadiazol-2 -yl-oxy) -acetamide, Ni-propyl-N- (4-chlorophenyl) - ⁇ - (5-trifluoromethyl-l, 3,4-thiadiazol-2-yl-oxy) - acetamide, Ni Propyl-N- (2-fluoro-phenyl) - ⁇ - (5-trifluoromethyl-1, 3,
  • the active substances of group 2 can be assigned to their chemical structure according to the following active substance classes:
  • Amides e.g. beflubutamide
  • aryl heterocycles e.g. azafenidin, benzfendizone
  • Butroxydim, Clefoxydim, Cycloxydim), dinitroanilines e.g. Benfluralin, Oryzalin
  • imidazoxones e.g. Imazamoxolinone
  • Isoxachlortole e.g. Isoxachlortole
  • pyridines e.g. Thiazopyr
  • pyrimidinyl (thio) benzoates e.g. Pyribenz-oxim, Pyriftalid, Pyriminobac-methyl, Pyrithiobac-sodium
  • sulfonylureas e.g.
  • Azimsulfuron Flupyrsulfuron-methyl-sodium, Foramsulfuron-methyl- Iodosulfuron sodium, mesosul Someon, trifloxysulfuron, triflusulfuron-methyl), tetrazolinones (e.g.
  • Fentrazamides Fentrazamides
  • triazoles e.g. amitroles
  • triazolinones e.g. flucarbazone-sodium, Procarbazone-sodium
  • triazolopyrimidines e.g. cloransulam-methyl, diclosulam, florasulam
  • triketones e.g. mesotrione
  • mixture components from the active ingredients of group 2 are:
  • Azimsulfuron Beflubuta id, Butafenacil-allyl, Cinidon-ethyl, Cloransulam-methyl, Clefoxydim, Diclosulam, Fenoxaprop-P-ethyl, Florasulam, Flupyrsul possiblyon-methyl-sodium, Foramsulmron, Imazamox, Iodosulfuron-methyl-sodium, Oxox, Isox , Procarbazone-sodium, pyriftalid, pyrithiobac-sodium, quinclorac, trifloxysulfuron.
  • beflubutamide is of particular interest as a mixture component.
  • butafenacil-allyl is of particular interest as a mixture component.
  • cinidon-ethyl is of particular interest as a mixture component.
  • Clefoxydim is also of particular interest as a mixture component.
  • cloransulam-methyl is also of particular interest as a mixture component.
  • flupyrsulfuron-methyl-sodium is of particular interest as a mixture component.
  • imazamox is also of particular interest as a mixture component.
  • iodosulfuron-methyl-sodium is of particular interest as a mixture component.
  • mesosullayson is also of particular interest as a mixture component.
  • oxaziclomefone is also of particular interest as a mixture component.
  • Procarbazone-sodium from this group is of particular interest as a mixture component.
  • agents according to the invention preferably contain one or two active substances from group 1, one to three active substances from group 2 and optionally an active substance from group 3.
  • the agents according to the invention contain an active ingredient of group 1, one or two active ingredients of group 2 and optionally an active ingredient of group 3.
  • Active ingredients of group 2 with a largely good crop tolerance have a particularly high herbicidal activity and can be used in various crops, in particular in barley, potatoes, corn, rice, soybeans and wheat, for the selective control of monocotyledonous and dicotyledonous weeds and that they can also be used for Control of monocot and dicot weeds in the semi and non-selective range can be used.
  • the herbicidal activity of the active compound combinations according to the invention consisting of compounds from groups 1 and 2 listed above is considerably higher than the sum of the effects of the individual active compounds.
  • the new active ingredient combinations are well tolerated in many crops, and the new active ingredient combinations also combat weeds that are otherwise difficult to control.
  • the new active ingredient combinations thus represent a valuable addition to the herbicides.
  • the synergistic effect of the active compound combinations according to the invention is particularly pronounced at certain concentration ratios.
  • the weight ratios of the active ingredients in the active ingredient combinations can be varied within relatively large ranges.
  • 1 part by weight of active Substance of the formula (I) 0.01 to 1000 parts by weight, preferably 0.02 to 500 parts by weight and particularly preferably 0.05 to 100 parts by weight of active ingredient or active ingredients of group 2.
  • the group 3 compounds listed above are particularly suitable, the harmful effect of active compounds of the formula ( I) and their salts, if appropriate also in combination with one or more of the active ingredients of group 2 mentioned above, to be completely removed from the crop plants without impairing the herbicidal activity against the weeds.
  • the advantageous effect of the crop plant compatibility of the active compound combinations according to the invention is also particularly pronounced at certain concentration ratios.
  • the weight ratios of the active ingredients in the active ingredient combinations can be varied within relatively large ranges. In general, 1 part by weight of active compound of the formula (I) or mixtures thereof are present
  • Active substances of group 2 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight and particularly preferably 0.1 to 10 parts by weight of active substance or active substances of group 3.
  • Plants are understood to mean all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
  • Plant parts are to be understood to mean all above-ground and underground plant parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and
  • Roots, tubers and rhiozomes are listed.
  • the plant parts also include vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offshoots and seeds.
  • the treatment according to the invention of the plants and parts of plants with the active compounds takes place directly or by acting on their surroundings, living space or storage space according to the customary treatment methods, for example by dipping, spraying, evaporating, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, by - or multi-layer wrapping.
  • the plants obtained by biotechnological and genetic engineering methods or by a combination of these methods those plants are emphasized which tolerate so-called 4-HPPD, EPSP and / or PPO materials, such as, for example, acuron plants.
  • the active compounds according to the invention can e.g. can be used in the following plants:
  • the active ingredient combinations to be used according to the invention can be used both in conventional cultivation processes (row crops with a suitable row width) in plantation crops (for example wine, fruit, citrus) and in industrial and track systems, on paths and squares, but also for stubble treatment and with the minimum tillage process become. They are also suitable as burners (herb killing e.g. in potatoes) or as defoliants (e.g. in cotton). They are also suitable for use on fallow land. Other areas of application are tree nurseries, forestry, grassland and ornamental plant growing.
  • the active substance combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension emulsion concentrates, active substance-impregnated natural and synthetic substances and very fine encapsulations in polymeric substances.
  • formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, optionally using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents.
  • extenders that is to say liquid solvents and / or solid carriers
  • surface-active agents that is to say emulsifiers and / or dispersants and / or foam-generating agents.
  • water is used as an extender, e.g. also organic
  • Solvents are used as auxiliary solvents.
  • the following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable
  • Oils Oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • ketones such as Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide
  • e.g. Ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders such as highly disperse silica, aluminum oxide and silicates are suitable as solid carriers for granules: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems; as emulsifying and / or foaming agents are possible: e.g. nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkyl sulfonates,
  • Alkyl sulfates, aryl sulfonates and protein hydrolyzates Possible dispersants are: e.g. Lignin sulfate leachate and methyl cellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations.
  • Other additives can be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarinv, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are used.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarinv, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are used.
  • the formulations generally contain between 0.1 and 95 percent by weight of active ingredients, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention are generally used in the form of finished formulations.
  • the active substances contained in the active substance combinations can, however, also be mixed in individual formulations when used, that is to say applied in the form of tank mixtures.
  • the new combinations of active ingredients can furthermore also be used in a mixture with other known herbicides, ready-to-use formulations or tank mixes being possible.
  • a mixture with other known active compounds such as fungicides, insecticides, acaricides, nematicides, bird repellants, growth agents, plant nutrients and agents which improve soil structure, is also possible.
  • mineral or vegetable oils which are compatible with plants (e.g. the commercial preparation "Oleo DuPont 11E") or ammonium salts such as e.g. Include ammonium sulfate or ammonium rhodanide.
  • the new combinations of active substances can be used as such, in the form of their formulations or in the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. They are used in the usual way, e.g. by pouring, spraying, spraying, dusting or scattering.
  • the active ingredient combinations according to the invention can be applied before and after emergence of the plants, that is to say in the pre-emergence and post-emergence process. They can also be worked into the soil before sowing.
  • X % damage by herbicide A (active ingredient of the formula I) at p kg / ha
  • Y % damage by herbicide B (active ingredient of the formula II) at q kg / ha
  • the effect of the combination is super-additive, that is, it shows a synergistic effect.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne de nouvelles combinaisons de principes actifs, herbicides et synergiques, constituées d'hétéroaryloxy-acétamides d'une part et de composés à action herbicide ou de phytoprotecteurs connus d'autre part, énumérés dans la description. Les combinaisons selon l'invention peuvent être utilisées avec de très bons résultats pour la lutte sélective contre les mauvaises herbes dans différentes cultures de plantes utiles.
EP01943335A 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides Withdrawn EP1298996A1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
EP05005219.0A EP1552746B1 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acétamides
EP10158929A EP2243368A3 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acetamides
EP10158916.6A EP2243363B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs à base d'heteroaryloxy-acetamides
EP10158933A EP2243370A2 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acetamides
EP10158915.8A EP2243362B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides
EP10158932A EP2243369A3 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acetamides
EP10158925A EP2243367A3 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acetamides
EP10158924A EP2243366A3 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acetamides
EP10158913.3A EP2243361B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides
DK05005219.0T DK1552746T3 (en) 2000-05-22 2001-05-09 Selective herbicides based on heteroaryloxy-acetamides
EP10158918A EP2243365A3 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acétamides
EP10158917.4A EP2243364B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10025306 2000-05-22
DE10025306 2000-05-22
DE10041619A DE10041619A1 (de) 2000-05-22 2000-08-24 Selektive Herbizide auf Basis von Heteroaryloxyacetamiden
DE10041619 2000-08-24
PCT/EP2001/005242 WO2001089301A1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides

Related Child Applications (5)

Application Number Title Priority Date Filing Date
EP10158913.3A Division EP2243361B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides
EP10158916.6A Division EP2243363B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs à base d'heteroaryloxy-acetamides
EP10158915.8A Division EP2243362B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides
EP05005219.0A Division EP1552746B1 (fr) 2000-05-22 2001-05-09 Herbicides sélectifs à base d'hétéroaryloxy-acétamides
EP10158917.4A Division EP2243364B1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides

Publications (1)

Publication Number Publication Date
EP1298996A1 true EP1298996A1 (fr) 2003-04-09

Family

ID=26005781

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01943335A Withdrawn EP1298996A1 (fr) 2000-05-22 2001-05-09 Herbicides selectifs a base d'heteroaryloxy-acetamides

Country Status (15)

Country Link
US (2) US6967188B2 (fr)
EP (1) EP1298996A1 (fr)
JP (1) JP2003533545A (fr)
KR (1) KR100781758B1 (fr)
CN (1) CN1430471A (fr)
AU (2) AU6593601A (fr)
BR (1) BRPI0111008B1 (fr)
CA (1) CA2409215A1 (fr)
CZ (1) CZ301614B6 (fr)
HR (1) HRP20021022A2 (fr)
HU (1) HU230428B1 (fr)
MX (1) MXPA02011468A (fr)
PL (1) PL218432B1 (fr)
SK (1) SK287461B6 (fr)
WO (1) WO2001089301A1 (fr)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1209975B1 (fr) * 1999-09-07 2003-11-12 Syngenta Participations AG Composition herbicide
GB0022833D0 (en) 2000-09-18 2000-11-01 Aventis Cropscience Sa New herbicidal composition
AR036047A1 (es) * 2001-06-13 2004-08-04 Syngenta Participations Ag Composicion herbicida selectiva y metodo para controlar selectivamente malezas y pastos en cultivos de plantas utiles
DE10135642A1 (de) * 2001-07-21 2003-02-27 Bayer Cropscience Gmbh Herbizid-Kombinationen mit speziellen Sulfonylharnstoffen
DE10209478A1 (de) * 2002-03-05 2003-09-18 Bayer Cropscience Gmbh Herbizid-Kombinationen mit speziellen Sulfonylharnstoffen
PL371445A1 (en) * 2002-03-21 2005-06-13 Syngenta Participations Ag Herbicidal composition
MY141982A (en) * 2004-12-21 2010-08-16 Syngenta Participations Ag Herbicidal composition
MX2008012995A (es) * 2006-04-10 2008-10-17 Du Pont Mezclas herbicidas.
EP1974609A1 (fr) * 2007-03-29 2008-10-01 Bayer CropScience GmbH Procédé de fabrication de granulés dispersibles dans l'eau
AR069022A1 (es) * 2007-10-26 2009-12-23 Kumiai Chemical Industry Co Agente para incrementar el contenido de azucar de la caña de azucar asi como metodo para acelerar la maduracion de la caña de azucar utilizando el mismo
EP2057898A1 (fr) * 2007-11-06 2009-05-13 Bayer CropScience AG Mélanges homogènes et stables de différentes particules granulaires d'agents phytosanitaires
US20090215625A1 (en) * 2008-01-07 2009-08-27 Auburn University Combinations of Herbicides and Safeners
AU2009214972A1 (en) * 2008-02-12 2009-08-20 Arysta Lifescience North America, Llc Method of controlling unwanted vegetation
JP5563773B2 (ja) * 2008-12-17 2014-07-30 バイエル・クロップサイエンス・アーゲー 除草剤組成物
DE102008062905A1 (de) * 2008-12-23 2010-06-24 Saltigo Gmbh Verfahren zur Herstellung von Acylamid-Verbindungen
WO2011082968A2 (fr) * 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
PL2512249T3 (pl) * 2009-12-17 2016-12-30 Środki chwastobójcze zawierające flufenacet
WO2011082959A2 (fr) 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
WO2011082955A2 (fr) * 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
HUE030350T2 (en) * 2009-12-17 2017-05-29 Bayer Ip Gmbh Herbicidal preparations containing flufenacet
WO2011082964A1 (fr) 2009-12-17 2011-07-14 Bayer Cropscience Ag Produits herbicides contenant du flufénacet
WO2011082956A2 (fr) 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
WO2011082957A2 (fr) * 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
WO2011082953A2 (fr) * 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
EP2515658B1 (fr) * 2009-12-17 2016-06-08 Bayer Intellectual Property GmbH Agents herbicides contenant du flufénacet
WO2011082954A2 (fr) * 2009-12-17 2011-07-14 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
CN102239854A (zh) * 2011-05-18 2011-11-16 利尔化学股份有限公司 除草农药组合物
WO2014001357A1 (fr) 2012-06-27 2014-01-03 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
WO2014001248A1 (fr) 2012-06-27 2014-01-03 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
WO2014001361A1 (fr) 2012-06-27 2014-01-03 Bayer Cropscience Ag Agents herbicides contenant du flufénacet
HUE042995T2 (hu) 2012-06-27 2019-07-29 Bayer Cropscience Ag Flufenacetot tartalmazó herbicid készítmények
UA116642C2 (uk) 2012-12-21 2018-04-25 ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі Термостабільні водні композиції клоквінтосет-мексилу
WO2014130661A1 (fr) 2013-02-25 2014-08-28 Dow Agrosciences Llc Procédés de lutte contre les mauvaises herbes dans des ananas
PL2967051T3 (pl) 2013-03-15 2019-01-31 Dow Agrosciences Llc Synergistyczne zwalczanie chwastów przez nanoszenie penoksulamu i petoksamidu
EP2936983A1 (fr) 2014-04-25 2015-10-28 Bayer CropScience AG Agents actifs destinés à l'augmentation du rendement des cultures de coton
CN104365628A (zh) * 2014-11-06 2015-02-25 江苏省农用激素工程技术研究中心有限公司 用于防治大豆田杂草的除草组合物
GB2532217B (en) * 2014-11-11 2019-05-15 Rotam Agrochem Int Co Ltd Herbicidal composition and method for controlling plant growth
CN105454266A (zh) * 2015-12-23 2016-04-06 汤云鹤 一种含氟噻草胺、异丙隆和双氟磺草胺的农药组合物及其在防治小麦田杂草中的应用
CN106689141A (zh) * 2017-03-10 2017-05-24 合肥星宇化学有限责任公司 丙酯草醚和喹禾糠酯复配除草组合物及其制剂和应用
CN107751226B (zh) * 2017-11-27 2020-11-13 浙江永太药业有限公司 一种含哒草特和氟噻草胺的除草剂组合物
CN114208833B (zh) * 2021-12-30 2024-03-29 青岛润农化工有限公司 含氟草烟异辛酯和双氯磺草胺的农药组合物及其制备方法和应用

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005501B1 (fr) * 1978-05-20 1981-11-25 Bayer Ag Heteroaryloxy-acetamides, procédé pour leur préparation et leur utilisation comme herbicides
DE3060330D1 (en) * 1979-04-06 1982-06-09 Bayer Ag Azolyloxy-acetamides, process for their preparation and their use as herbicides
DE2946524A1 (de) * 1979-11-17 1981-06-11 Bayer Ag, 5090 Leverkusen Azolyloxy-carbonsaeure-n-oxy-amide, verfahren zu ihrer herstellung und ihre verwendung als herbizide
DE3218482A1 (de) * 1982-05-15 1983-11-17 Bayer Ag, 5090 Leverkusen Substituierte 5-trifluormethyl-1,3,4-thiadiazol-2-yloxyessigsaeureamide, verfahren zu ihrer herstellung und ihre verwendung als herbizide
DE3228147A1 (de) * 1982-07-28 1984-02-09 Bayer Ag, 5090 Leverkusen Substituierte 3-trihalogenmethyl-1,2,4-thiadiazol-5-yl-oxyessigsaeureamide, verfahren zu ihrer herstellung und ihre verwendung als herbizide
DE3228131A1 (de) * 1982-07-28 1984-02-02 Bayer Ag, 5090 Leverkusen Substituierte 3-trichlormethyl-1,2,4-thiadiazol-5-yl-oxyessigsaeureamide, verfahren zu ihrer herstellung und ihre verwendung als herbizide
DE3418168A1 (de) * 1984-05-16 1985-11-21 Bayer Ag, 5090 Leverkusen 6-chlorbenzazolyloxyacetamide
DE3418167A1 (de) 1984-05-16 1985-11-21 Bayer Ag, 5090 Leverkusen Verwendung von amiden zur verbesserung der kulturpflanzen-vertraeglichkeit von herbizid wirksamen heteroaryloxyacetamiden
US4585899A (en) * 1985-01-22 1986-04-29 Chem Systems Inc. Hydrogenation of carboxylic acid compounds to aldehydes using MnO2 on gamma alumina as catalyst
DE3505902A1 (de) * 1985-02-21 1986-08-21 Bayer Ag, 5090 Leverkusen 4,5-disubstituierte 1,3-thiazol-2-yloxyacetamide
DE3811446A1 (de) * 1988-04-06 1989-10-19 Bodenseewerk Perkin Elmer Co Einrichtung zur erzeugung eines magnetfeldes in einem atomabsorptions-spektrometer
DE3821597A1 (de) * 1988-06-27 1989-12-28 Bayer Ag 5-difluormethyl-1,3,4-thiadiazol-2-yl- oxyessigsaeureamide, verfahren und 5-difluormethyl-2- methylsulfonyl- bzw. 2- methylthio-1,3,4-thiadiazol als zwischenprodukte zu ihrer herstellung und ihre verwendung als selektivherbizide
DE3821600A1 (de) * 1988-06-27 1989-12-28 Bayer Ag Heteroaryloxyessigsaeure-n-isopropylanilide
US5529976A (en) * 1990-01-10 1996-06-25 Hoechst Aktiengesellschaft Pyridyl sulphonyl ureas as herbicides and plant growth regulators
DE4223465A1 (de) * 1992-07-16 1994-01-20 Bayer Ag Herbizide Mittel auf Basis von Heteroaryloxyacetamiden
DE4431219A1 (de) * 1994-09-02 1996-03-07 Bayer Ag Selektive Herbizide auf Basis von Aryluracilen
DE4437049A1 (de) * 1994-10-17 1996-04-18 Bayer Ag Selektive Herbizide auf Basis von Carbamoyltriazolinonen und Heteroaryloxyacetamiden
US5912206A (en) * 1994-12-09 1999-06-15 Rhone-Poulenc Agrochimie Herbicidal compositions
DE19546751B4 (de) * 1994-12-23 2005-02-17 Bayer Cropscience Ag Selektive Herbizide auf Basis von Heteroaryloxy-acetamiden
ES2128984B1 (es) * 1996-05-24 2000-02-01 Bayer Ag Herbicidas a base de heteroariloxi-acetamidas para el empleo en el cultivo de arroz.
DE19728568B4 (de) * 1996-07-17 2007-06-14 Bayer Cropscience Ag Herbizide Mittel auf Basis von (5-Trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-essigsäure-N-isopropyl-N-(4fluorphenyl)-amid
US5985797A (en) * 1996-07-17 1999-11-16 Bayer Aktiengesellschaft Herbicidal compositions based on N-isopropyl-N-(4-fluorophenyl) (5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy)acetamide
DE19634701A1 (de) * 1996-08-28 1998-03-05 Bayer Ag Herbizide Mittel auf Basis von 4-Brom-l-methyl-5-trifluormethyl-3-(2-fluor-4-chlor-5-isopropoxycarbonsylphenyl)pyrazol
AR012651A1 (es) * 1997-05-06 2000-11-08 Sumitomo Chemical Co COMPOSICIoN HERBICIDA Y METODO DE DESMALEZADO UTILIZANDO LA MISMA.
JPH10306007A (ja) * 1997-05-06 1998-11-17 Sumitomo Chem Co Ltd 除草剤組成物
DE19832017A1 (de) * 1998-07-16 2000-01-27 Hoechst Schering Agrevo Gmbh Herbizide Mittel mit substituierten Phenylsulfonylharnstoffen zur Unkrautbekämpfung in Reis
AU4782099A (en) * 1998-07-16 2000-02-07 Aventis Cropscience Gmbh Herbicides
JP4480890B2 (ja) * 1998-08-13 2010-06-16 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト アシル化アミノフェニルスルホニル尿素を有する除草剤組成物
JP4200559B2 (ja) * 1998-10-23 2008-12-24 住友化学株式会社 除草剤組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0189301A1 *

Also Published As

Publication number Publication date
BR0111008A (pt) 2003-04-08
MXPA02011468A (es) 2004-08-12
HUP0302069A3 (en) 2005-11-28
HRP20021022A2 (en) 2005-02-28
US20040102321A1 (en) 2004-05-27
US6967188B2 (en) 2005-11-22
KR20030027890A (ko) 2003-04-07
AU2001265936B2 (en) 2006-04-06
WO2001089301A1 (fr) 2001-11-29
SK16262002A3 (sk) 2003-09-11
AU6593601A (en) 2001-12-03
KR100781758B1 (ko) 2007-12-04
JP2003533545A (ja) 2003-11-11
CZ301614B6 (cs) 2010-05-05
PL218432B1 (pl) 2014-12-31
HUP0302069A2 (hu) 2003-09-29
CN1430471A (zh) 2003-07-16
SK287461B6 (sk) 2010-10-07
CA2409215A1 (fr) 2002-11-19
BRPI0111008B1 (pt) 2015-12-15
US20060009359A1 (en) 2006-01-12
PL359033A1 (en) 2004-08-23
CZ20023822A3 (cs) 2003-04-16
HU230428B1 (hu) 2016-06-28

Similar Documents

Publication Publication Date Title
WO2001089301A1 (fr) Herbicides selectifs a base d'heteroaryloxy-acetamides
EP2272353B1 (fr) Herbicides à base de thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)ones substitués et de dicamba
WO2001037652A2 (fr) Herbicides a base de carbamoyl-triazolinones
DE10031825A1 (de) Selektive Herbizide auf Basis von Arylsulfonylaminocarbonyltriazolinonen
EP2243364A2 (fr) Herbicides sélectifs à base d'hétéroaryloxy-acétamides

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20021223

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

17Q First examination report despatched

Effective date: 20031001

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RTI1 Title (correction)

Free format text: SELECTIVE FLUFENACET-BASED HERBICIDES

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20050621