EP1296394B1 - Constituent part for fuel cell - Google Patents

Constituent part for fuel cell Download PDF

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Publication number
EP1296394B1
EP1296394B1 EP01932198A EP01932198A EP1296394B1 EP 1296394 B1 EP1296394 B1 EP 1296394B1 EP 01932198 A EP01932198 A EP 01932198A EP 01932198 A EP01932198 A EP 01932198A EP 1296394 B1 EP1296394 B1 EP 1296394B1
Authority
EP
European Patent Office
Prior art keywords
gas diffusion
gasket
diffusion layer
fuel battery
separator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01932198A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1296394A4 (en
EP1296394A1 (en
Inventor
Yuichi Kuroki
Yoshihiro Kurano
Tomohiro Inoue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nok Corp
Original Assignee
Nok Corp
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Filing date
Publication date
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Publication of EP1296394A1 publication Critical patent/EP1296394A1/en
Publication of EP1296394A4 publication Critical patent/EP1296394A4/en
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Publication of EP1296394B1 publication Critical patent/EP1296394B1/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023—Porous and characterised by the material
    • H01M8/0234—Carbonaceous material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0213—Gas-impermeable carbon-containing materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0276—Sealing means characterised by their form
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/028—Sealing means characterised by their material
    • H01M8/0284—Organic resins; Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0286—Processes for forming seals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a constituting part for a fuel battery forming an assembly of constituting elements for the fuel battery.
  • the fuel battery has a separator (collector electrode) 51 constituted by a carbon plate or the like, a reaction electrode portion (MEA) 52 constituted by an integrated product of an electrode with catalyst (catalyst layer) carrying a Pt catalyst and an electrolyte membrane (ion exchange membrane), for reacting a gas, a gas diffusion layer (GDL) 53 made of a carbon fiber or the like for promoting a diffusion of gas, and a gasket (seal) 54 for sealing the gas or a refrigerant, as main constituting elements.
  • a separator collector electrode
  • MEA reaction electrode portion
  • MEA reaction electrode portion
  • GDL gas diffusion layer
  • gasket gasket
  • the gas diffusion layer is a porous body made of the carbon fiber or the like, a void portion of the gas diffusion layer forms a flow passage for gas leakage from an inner gas flow passage side toward an outer side with respect to the gasket at a time of laminating the gasket on the gas diffusion layer so as to seal, so that there is a problem that the gas is leaked. Further, portions between the gas diffusion layer, and the gasket and the separator are pressurized for a sealing, however, there is a risk that a part of the gas diffusion layer is crushed or broken.
  • a peripheral edge portion of an electrolyte membrane (ion exchange membrane)62 in a reaction electrode portion (MEA) 61 in which gas diffusion layers (GDL) 64 are fixed to both surfaces is formed so as to be extended in a plane direction, and seals 65 such as packings or the like are arranged on both surfaces of the peripheral edge portion, whereby a seal portion of a fuel battery cell is constituted.
  • GDL gas diffusion layers
  • the reaction electrode portion 61 is formed by integrating the electrolyte membrane 62 with electrodes with catalyst (catalyst layers) 63 arranged on both surfaces thereof, a UEA 66 is constituted by the reaction electrode portion 61 and the gas diffusion layers 64 fixed to both surfaces thereof, and the UEA 66 is inserted and held between a pair of separators (collector electrodes) 67, whereby the fuel battery cell is constituted.
  • the gas diffusion layers 64 are a porous bodies made of a carbon fiber, a metal fiber or the like, and are mounted between a pair of separators 67 so as to be compressed in an assembled state, a permanent strain is easily generated.
  • the present invention is made by taking the above matters into consideration, and an object of the present invention is to provide a constituting part for a fuel battery which can reduce a man hour for assembling constituting elements for the fuel battery, and in addition thereto, another aim of the present invention is to provide a constituting part for a fuel battery which can improve an efficiency of power generation of the fuel battery, and can achieve an excellent sealing property.
  • another aim of the present invention is to provide a constituting part for a fuel battery which can improve a replacing property and a maintenance property of the constituting elements for the fuel battery and can restrict a parts cost.
  • another aim of the present invention is to provide a constituting part for a fuel battery which can restrict a permanent compression strain generated in the gasket to a comparatively small level, in an integrated product of the gas diffusion layer and the gasket or an integrated product of the gas diffusion layer, the gasket and the separator.
  • a constituting part for a fuel battery characterized in that a separator made of a carbon plate, a gas diffusion layer made of a carbon fiber, and a gasket made of a liquid rubber cured material are integrally formed.
  • a constituting part for a fuel battery characterized in that there is provided an integrated product of a separator made of a carbon plate and a gas diffusion layer made of a carbon fiber, and a gasket made of a liquid rubber cured material is integrally formed on one surface in the side of the gas diffusion layer of the integrated product.
  • a constituting part for a fuel battery characterized in that there is provided an integrated product of a separator made of a carbon plate and a gas diffusion layer made of a carbon fiber, a gasket made of a liquid rubber cured material is integrally formed on one surface in the side of the gas diffusion layer of the integral product, and a gasket is also integrally formed on the opposite side surface.
  • a constituting part for a fuel battery in which an adhesive agent is applied to the separator, and a rubber of the gasket permeating into the gas diffusion layer is reacted with the adhesive agent on the separator, thereby being integrally formed in such a manner as to hold the gas diffusion layer therein.
  • a constituting part for a fuel battery in which an adhesive agent is applied to one surface of the separator, a rubber of the gasket permeating into the gas diffusion layer is reacted with the adhesive agent on the separator, thereby being integrally formed in such a manner as to hold the gas diffusion layer therein, and an adhesive agent is also applied to the opposite side surface, whereby the gaskets are integrally formed.
  • a constituting part for a fuel battery in which a through hole is provided in the separator, and a part of a rubber penetrating into the gas diffusion layer passes through the through hole so as to reach the opposite side surface, whereby the gaskets are integrally formed on both surfaces of the separator.
  • a constituting part for a fuel battery in which gaskets are provided on both surfaces of a pair of gas diffusion layers holding an independent electrolyte membrane from both sides thereof between the pair.
  • a constituting part for a fuel battery in which the gaskets have a double lip structure in side of the separator in one gas diffusion layer, and in side of the electrolyte membrane and side of the separator in another gas diffusion layer, and the gasket has a flat seal structure in the side of the electrolyte membrane in one gas diffusion layer.
  • each of the gaskets is structured such that a porous structure of the gas diffusion layer is impregnated with a liquid rubber.
  • a constituting part for a fuel battery characterized in that through holes are provided near peripheral edge portions of a pair of gas diffusion layers holding an independent electrolyte membrane from both sides thereof between the pair, and a gaskets are integrally formed on both surfaces of the gas diffusion layers via the through holes.
  • a constituting part for a fuel battery in which the gaskets cover the peripheral edge portions of the gas diffusion layers, and particularly cover end surface of the gas diffusion layers.
  • a constituting part for a fuel battery in which the constituting part is an integrated product of a gas diffusion layer made of a carbon fiber or the like and a gasket made of a liquid rubber cured material or the like, and the gas diffusion layer and seal lips of the gasket are arranged so as not to be overlapped with each other in view of a plane.
  • a constituting part for a fuel battery a rubber in a part of the gasket is impregnated into the gas diffusion layer in a bonding portion between the gas diffusion layer and the gasket.
  • the gasket is a gasket for double-face seal or a gasket for one-face seal.
  • a constituting part for a fuel battery in which a separator made of a carbon plate is further integrally formed with the gas diffusion layer and the gasket.
  • the separator, the gas diffusion layer and the gasket are integrally formed , or the gasket is integrally formed with one surface in the side of the gas diffusion layer of the integrated product constituted by the separator and the gas diffusion layer , these parts are previously integrated, so that it is possible to reduce steps of assembling these parts with each other at a time of assembling of the fuel battery.
  • the gasket is also integrally formed on the opposite surface of the integrated product constituted by the separator and the gas diffusion layer, the integrated product having gaskets on both surfaces is constructed.
  • the rubber of the gasket permeates into the gas diffusion layer and is integrally formed in such a manner as to hold the gas diffusion layer therein, the gasket and the gas diffusion layer are closely attached to each other, so that it is possible to prevent the space forming the shortcut flow passage of the gas from being formed between the both elements.
  • the gasket is integrally formed.
  • a part of the rubber passes through the through hole so as to reach the opposite surface, whereby the gasket is integrally formed, the integrated product having the gaskets on both surfaces is constructed.
  • An integrated product is disclosed of a carbon plate, a gas diffusion layer and a gasket for a fuel battery, in which the carbon plate used in a separator for the fuel battery, the gas diffusion layer made of a carbon fiber, and the gasket corresponding to a liquid rubber cured material are integrated.
  • the gas diffusion layer made of the carbon fiber can be permeated with the rubber and thereafter cured. Accordingly, the permeated rubber can reach the carbon plate by applying the adhesive agent onto the carbon plate, whereby it is possible to bond the carbon plate with the rubber. At this time, the gas diffusion layer is fixed onto the carbon plate by the adhesive agent due to the permeating rubber.
  • Fig. 2 in accordance with an embodiment described below shows a product in which the gasket is formed only in the side of the gas diffusion layer (the side of the ion exchange membrane) . In this product, the gasket is bonded by the adhesive agent applied to the surface of the carbon plate during the formation. Further, Fig.
  • FIG. 5 shows a product of a double-face gasket type in which the adhesive agent is applied to a back surface (a refrigerant surface) of the separator of the product in Fig. 2 , and the gasket is formed.
  • Fig. 7 shows a product in which a through hole is provided in the carbon plate, and the gasket in the side of the gas diffusion layer and the gasket in the side of the refrigerant on the back surface thereof are fixed with no adhesive agent.
  • the space existing in the periphery of the gas diffusion layer forms the shortcut flow passage of the gas so as to prevent the gas from being diffused, and the efficiency of power generation is deteriorated, however, since the space mentioned above does not exist, a diffusion of the gas is improved, and it is possible to improve an efficiency of power generation in the fuel battery.
  • the electrolyte membrane and the gas diffusion layer are independently formed, and the gasket is provided on both surfaces of a pair of gas diffusion layers holding the independent electrolyte membrane therein from both sides thereof, it is sufficient to replace only the gas diffusion layer provided with the gasket, with leaving the electrolyte membrane independent from the gas diffusion layer, at a time of replacing the gas diffusion layer.
  • the seal portion of the fuel battery cell is structured by a combination of the gas diffusion layer and the gasket, and the electrolyte membrane is received inside the seal portion. Accordingly, it is possible to reduce a plane area of the electrolyte membrane in comparison with the prior art.
  • the gasket is formed in the double lip structure in the side of the separator in one gas diffusion layer, and in the side of the electrolyte membrane and the side of the separator in another gas diffusion layer, and the double lip structure has a plurality of lips, a seal performance is high. Further, since the gasket is formed in the flat seal structure in the side of the electrolyte membrane in one gas diffusion layer, it is possible to prevent the electrolyte membrane with which this is pressure contacted from being deformed.
  • the gas diffusion layer has the porous structure, it is preferable that the gasket integrated therewith is formed by impregnating the liquid rubber into the porous structure of the gas diffusion layer.
  • the through hole is provided near the peripheral edge portion of a pair of gas diffusion layers holding the independent electrolyte membrane therein, and the gasket is integrally formed on both surfaces of the gas diffusion layer via the through hole, it is sufficient to replace only the gas diffusion layer provided with the gasket with leaving the electrolyte membrane independent from the gas diffusion layer, at a time of replacing the gas diffusion layer.
  • the gasket covers the peripheral edge portion of the gas diffusion layer, and particularly covers the end surface of the gas diffusion layer, it is possible to prevent the sealed fluid from permeating through the gas diffusion layer so as to leak toward the end surface.
  • the subject proposal includes the following technical matters.
  • the gas diffusion layer and the seal lip of the gasket are arranged so as not to overlap with each other in a plane, as in the constituting part for the fuel battery in accordance with the twelfth aspect of the present invention provided with the structure mentioned above, the gas diffusion layer is not positioned immediately below the seal lip of the gasket, so that it is possible to restrict the permanent compression strain generated in the gasket to a comparatively small level.
  • the gas diffusion layer is arranged in a side surface of the gasket, or the gasket is arranged in an outer side of the gas diffusion layer, and in order to integrate the gas diffusion layer with the gasket, it is preferable that the liquid rubber in a part of the gasket is impregnated into the gas diffusion layer in the bonding portion between the gas diffusion layer and the gasket.
  • the gasket includes the gasket having the seals on both surfaces provided with the seal lips in both of the upper and lower surfaces, and the gasket having the seal on one surface provided with the seal lip in any one of both of the upper and lower surfaces , and there is a case that the separator made of the carbon plate or the like is integrally formed with the gas diffusion layer and the gasket.
  • the gas diffusion layer made of the carbon fiber or the like used in the separator for the fuel battery, and the gasket corresponding to the cured material of the liquid rubber are integrally formed, or in the product in which the carbon plate, the gas diffusion layer made of the carbon fiber or the like, and the gasket corresponding to the cured material of the liquid rubber are integrally formed, when the gas diffusion layer does not exist immediately below the gasket, the gas diffusion layer is positioned in the side surface of the gasket, and the gas diffusion layer is impregnated with the rubber so as to be fixed to the gasket, it is possible to restrict the permanent compression strain generated in the gasket to a small level because the gas diffusion layer is not positioned immediately below the gasket.
  • Fig. 1 shows a schematic perspective view of a constituting part 1 for a fuel battery (separator for a fuel battery) in accordance with a first embodiment of the present invention, and a cross sectional view along a line A-A thereof is shown in Fig. 2 .
  • Fig. 3 shows a cross sectional view of an assembling state of the constituting part 1 for the fuel battery.
  • reference numeral 6 in Fig. 3 denotes a reaction electrode portion (MEA: Membrane Electrode Assembly) assembled with the constituting part 1 for the fuel battery.
  • MEA Membrane Electrode Assembly
  • the constituting part 1 for the fuel battery in accordance with the present embodiment is structured in the following manner.
  • a separator (separator main body) 2 constituted by a carbon plate having a predetermined thickness is provided, and a gas diffusion layer 3 made of a carbon fiber and a gasket 4 made of a liquid rubber cured material are integrally formed with one surface of the separator 2.
  • the gasket 4 is integrally provided with a flat base portion 4a received in a receiving groove 2a provided on one surface of the separator 2, and a lip portion 4b having a substantially trapezoidal cross sectional shape and integrally formed with the base portion 4a, and is integrated with the separator 2 so as to hold the gas diffusion layer 3 with the separator 2 in accordance that the liquid rubber of the gasket 4 impregnated into the carbon fiber of the gas diffusion layer 3 reacts with an adhesive agent 5 which is previously applied to an inner surface of the receiving groove 2a so as to be solidified, at an immediately upper position of the receiving groove 2a.
  • gas diffusion layer 3 is integrated with the separator 2 so as to be held between the gasket 4 and the separator 2 in accordance that the liquid rubber of the gasket 4 impregnated into the carbon fiber of the gas diffusion layer 3 reacts with the adhesive agent 5 within the receiving groove 2a so as to be solidified, at the immediately upper position of the receiving groove 2a.
  • the gas diffusion layer 3 is formed in a flat shape having substantially the same size and the same shape as those of the separator 2, and an upper surface of a lip portion 4b of the gasket 4 is formed so as to protrude outward from the gas diffusion layer 3.
  • the separator 2 constituted by the carbon plate, the gas diffusion layer 3 made of the carbon fiber, and the gasket 4 made of the liquid rubber cured material are integrally formed with each other as mentioned above, it is possible to reduce steps of assembling these parts with each other at a time of assembling of the fuel battery.
  • liquid rubber forming the gasket 4 is impregnated into the carbon fiber of the gas diffusion layer 3 so as to react with the adhesive agent 5 within the receiving groove 2a and solidify, thereby being integrally formed with the separator 2 so as to hold the gas diffusion layer 3, there is provided a structure in which the gasket 4 and the gas diffusion layer 3 are closely attached. Accordingly, it is possible to prevent the space forming the shortcut flow passage for the gas which is formed in the prior art mentioned above, from being formed between the gasket 4 and the gas diffusion layer 3.
  • liquid rubber forming the gasket 4 is impregnated into the carbon fiber of the gas diffusion layer 3 so as to reach the separator 2, whereby the gasket 4 and the separator 2 are directly integrally formed, it is possible to prevent the gas leakage flow passage from being formed between the both elements 2 and 4.
  • Fig. 4 shows a schematic perspective view of a constituting part 1 for a fuel battery (separator for a fuel battery) in accordance with a second embodiment of the present invention, and a cross sectional view along a line B-B thereof is shown in Fig. 5 .
  • the constituting part 1 for the fuel battery in accordance with the present embodiment is structured in the following manner.
  • a separator (separator main body) 2 constituted by a carbon plate having a predetermined thickness is provided, a gas diffusion layer 3 made of a carbon fiber and a gasket 4 made of a liquid rubber cured material are integrally formed with one surface of the separator 2, and a gasket 7 made of a liquid rubber cured material is integrally formed with an opposite surface of the separator 2.
  • One gasket 4 provided on one surface of the separator 2 is integrally provided with a flat base portion 4a received in a receiving groove 2a provided on one surface of the separator 2, and a lip portion 4b having a substantially trapezoidal cross sectional shape and integrally formed with the base portion 4a, and is integrated with the separator 2 so as to hold the gas diffusion layer 3 with the separator 2 in accordance that the liquid rubber of the gasket 4 impregnated into the carbon fiber of the gas diffusion layer 3 reacts with an adhesive agent 5 which is previously applied to an inner surface of the receiving groove 2a so as to solidify, at an immediately upper position of the receiving groove 2a.
  • gas diffusion layer 3 is integrated with the separator 2 so as to be held between the gasket 4 and the separator 2 in accordance that the liquid rubber of the gasket 4 impregnated into the carbon fiber of the gas diffusion layer 3 reacts with the adhesive agent 5 within the receiving groove 2a so as to solidify, at the immediately upper position of the receiving groove 2a.
  • the gas diffusion layer 3 is formed in a flat shape having substantially the same size and the same shape as those of the separator 2, and an upper surface of a lip portion 4b of the gasket 4 is formed so as to protrude outward from the gas diffusion layer 3.
  • another gasket 7 provided on the opposite surface of the separator 2 is integrally provided with a flat base portion 7a, and a lip portion 4b having a substantially triangular cross sectional shape and integrally formed with the base portion 7a, and is integrated with the separator 2 by an adhesive agent 8 applied to the opposite surface of the separator 2.
  • the separator 2 constituted by the carbon plate, the gas diffusion layer 3 made of the carbon fiber, and a pair of gaskets 4 and 7 made of the liquid rubber cured material are integrally formed with each other as mentioned above, it is possible to reduce steps of assembling these parts with each other at a time of assembling of the fuel battery.
  • liquid rubber forming one gasket 4 is impregnated into the carbon fiber of the gas diffusion layer 3 so as to react with the adhesive agent 5 within the receiving groove 2a and solidify, thereby being integrally formed with the separator 2 so as to hold the gas diffusion layer 3, there is provided a structure in which the gasket 4 and the gas diffusion layer 3 are closely attached. Accordingly, it is possible to prevent the space forming the shortcut flow passage for the gas, which is formed in the prior art mentioned above, from being formed between the gasket 4 and the gas diffusion layer 3.
  • liquid rubber forming one gasket 4 is impregnated into the carbon fiber of the gas diffusion layer 3 so as to reach the separator 2, whereby the gasket 4 and the separator 2 are directly integrally formed, it is possible to prevent the gas leakage flow passage from being formed between the both elements 2 and 4.
  • Fig. 6 shows a schematic perspective view of a constituting part 1 for a fuel battery (separator for a fuel battery) in accordance with a third embodiment of the present invention, and a cross sectional view along a line C-C thereof is shown in Fig. 7 .
  • the constituting part 1 for the fuel battery in accordance with the present embodiment is structured in the following manner.
  • a separator (separator main body) 2 constituted by a carbon plate having a predetermined thickness is provided, a gas diffusion layer 3 made of a carbon fiber and a gasket 4 made of a liquid rubber cured material are integrally formed with one surface of the separator 2, and a gasket 7 made of a liquid rubber cured material is integrally formed with an opposite surface of the separator 2.
  • One gasket 4 provided on one surface of the separator 2 is integrally provided with a flat base portion 4a received in a receiving groove 2a provided on one surface of the separator 2, and a lip portion 4b having a substantially trapezoidal cross sectional shape and integrally formed with the base portion 4a, and another gasket 7 provided on the opposite surface of the separator 2 is integrally provided with a flat base portion 7a, and a lip portion 7b having a substantially triangular cross sectional shape and integrally formed with the base portion 7a.
  • a pair of gaskets 4 and 7 are integrated with the separator 2 without any adhesive agent in accordance that a part of the liquid rubber impregnated into the carbon fiber of the gas diffusion layer 3 at an immediately upper position of the receiving groove 2a passes through a through hole 2b which is previously provided in a bottom surface portion of the receiving groove 2a, and reaches the opposite surface so as to be formed as a double-face gasket.
  • a desired number of through holes 2b are provided so as to be arranged in one line along an extending direction of the gaskets 4 and 7.
  • gas diffusion layer 3 is integrated with the separator 2 so as to be held between one gasket 4 and the separator 2 in accordance that a part of the liquid rubber impregnated into the carbon fiber of the gas diffusion layer 3 passes through the through holes 2b and reaches the opposite surface so as to be formed as a double-face gasket.
  • the gas diffusion layer 3 is formed in a flat shape having substantially the same size and the same shape as those of the separator 2, and an upper surface of a lip portion 4b of one gasket 4 is formed so as to protrude outward from the gas diffusion layer 3.
  • the separator 2 constituted by the carbon plate, the gas diffusion layer 3 made of the carbon fiber, and a pair of gaskets 4 and 7 made of the liquid rubber cured material are integrally formed with each other as mentioned above, it is possible to reduce steps of assembling these parts with each other at a time of assembling of the fuel battery.
  • liquid rubber forming one gasket 4 is impregnated into the carbon fiber of the gas diffusion layer 3 so as to solidify, thereby being integrally formed with the separator 2 so as to hold the gas diffusion layer 3, there is provided a structure in which the gasket 4 and the gas diffusion layer 3 are closely attached. Accordingly, it is possible to prevent the space forming the shortcut flow passage for the gas, which is formed in the prior art mentioned above, from being formed between the gasket 4 and the gas diffusion layer 3.
  • liquid rubber forming one gasket 4 is impregnated into the carbon fiber of the gas diffusion layer 3 so as to reach the separator 2, whereby the gasket 4 and the separator 2 are directly integrally formed, it is possible to prevent the gas leakage flow passage from being formed between the both elements 2 and 4.
  • a pair of gaskets 4 and 7 are integrally formed with the separator 2 without any adhesive agent, it is possible to omit an adhesive agent application step from the steps of manufacturing the constituting part 1 for the fuel battery, so that it is possible to make the manufacturing easy and it is possible to provide a product which is advantageous in view of cost.
  • Fig. 8 shows a cross section of a constituting part for a fuel battery (gasket for a fuel battery) in accordance with a fourth example which is not claimed , and the constituting part for the fuel battery is structured as follows.
  • a reaction electrode portion (MEA) 11 in which an electrolyte membrane (ion exchange membrane) 12 and electrodes with catalyst (catalyst layers) 13 and 14 are integrated is provided in the middle in the vertical direction of the drawing, and gas diffusion layers (GDL) 15 and 16 made of a carbon fiber, a metal fiber or the like are respectively layered on both upper and lower sides of the reaction electrode portion 11 in a non-adhesive manner as separate bodies, and separators (collector electrodes) 17 and 18 are respectively layered on both upper and lower sides of the gas diffusion layers 15 and 16, whereby a laminated body corresponding to one cell is constituted.
  • GDL gas diffusion layers
  • the gasket 19 in the side of the separator 17 of the upper gas diffusion layer 15 in the drawing has an outer lip 19a and an inner lip 19b so as to constitute a double-lip structure, and both of the lips 19a and 19b are closely attached to the separator 17.
  • the gasket 20 in the side of the reaction electrode portion 11 of the upper gas diffusion layer 15 in the drawing is formed in a flat shape so as to form a flat seal structure, and is closely attached to the electrolyte membrane 12 by a part of an inner side thereof. Since the gas diffusion layer 15 has a porous structure, both of the gaskets 19 and 20 are formed by being impregnated with a liquid silicone rubber, and accordingly are integrally formed with each other.
  • the gasket 21 in the side of the reaction electrode portion 11 of the lower gas diffusion layer 16 in the drawing has an outer lip 21a and an inner lip 21b so as to constitute a double-lip structure, and the outer lip 21a is closely attached to the flat seal of the gasket 20, and the inner lip 21b is closely attached to the electrolyte membrane 12.
  • the inner lip 21b is formed so that a height thereof is smaller than that of the outer lip 21a at a thickness of the electrolyte membrane 12.
  • the gasket 22 in the side of the separator 18 of the lower gas diffusion layer 16 in the drawing has an outer lip 22a and an inner lip 22b so as to constitute a double-lip structure, and both of the lips 22a and 22b are closely attached to the separator 18. Since the gas diffusion layer 16 has a porous structure, both of the gaskets 21 and 22 are formed by being impregnated with a liquid silicone rubber, and accordingly are integrally formed with each other.
  • a dimension of each of the portions is set as follows.
  • An assembled structure having the structure mentioned above constructs a fuel battery cell as an finished assembly product, and has a feature that the following function and effects can be achieved by the structure mentioned above.
  • the reaction electrode portion 11 provided with the electrolyte membrane 12 and the gas diffusion layers 15 and 16 arranged in both surfaces thereof are formed as independent bodies as described above, and the gaskets 19, 20, 21 and 22 are respectively provided on both surfaces of a pair of gas diffusion layers 15 and 16 holding the independent reaction electrode portion 11 from both sides between the pair, it is possible to replace only the gas diffusion layers 15 and 16 provided with the gaskets 19, 20, 21 and 22 by a substitute with leaving the independent reaction electrode portion 11, when there occurs a necessity of replacing the gas diffusion layers 15 and 16 due to generation of permanent strain or the like. Accordingly, since it is not necessary to replace the reaction electrode portion 12 corresponding to a comparatively expensive part each time, it is possible to reduce a cost for parts and a cost for maintenance. A replacing operation can be significantly easily executed.
  • a seal portion of the cell is structured by a combination of the gas diffusion layers 15 and 16 and the gaskets 19, 20, 21 and 22, and the electrolyte membrane 12 is received in side the seal portion. Accordingly, since a plane area of the electrolyte membrane 12 corresponding to the comparatively expensive part can be made smaller in comparison with the conventional one, it is possible to reduce the cost for parts at this degree.
  • Fig. 9 shows a cross section of a constituting part for a fuel battery (gasket for a fuel battery) in accordance with a fifth embodiment of the present invention, and the constituting part for the fuel battery is structured as follows.
  • a reaction electrode portion (MEA) 11 in which an electrolyte membrane (ion exchange membrane) 12 and electrodes with catalyst (catalyst layers) 13 and 14 are integrated is provided in the middle in a vertical direction of the drawing, and gas diffusion layers (GDL) 15 and 16 made of a carbon fiber, a metal fiber or the like are respectively layered on both upper and lower sides of the reaction electrode portion 11 in a non-adhesive manner, and separators (collector electrodes) 17 and 18 are respectively layered on both upper and lower sides of the gas diffusion layers 15 and 16, whereby a laminated body corresponding to one cell is constituted.
  • GDL gas diffusion layers
  • a peripheral edge portion of the electrolyte membrane 12 protrudes outward in the plane direction beyond the electrodes with catalyst 13 and 14, and are set to be the same length (plane area) as that of the upper and lower gas diffusion layers 15 and 16, a desired number of through holes 23 and 24 extending through in the thickness direction are respectively provided in the peripheral edge portions of the upper and lower gas diffusion layers 15 and 16, and the gaskets 19, 20, 21 and 22 are integrally formed with both surfaces of the gas diffusion layers 15 and 16 via the through holes 23 and 24 in a non-adhesive manner.
  • the gaskets 19 and 20 integrally formed with the upper gas diffusion layer 15 in the drawing are structured such that the upper gasket 19 closely attached to the upper separator 17, and the lower gasket 20 closely attached to the electrolyte membrane 12 are integrally formed with each other via a rubber 25 charged into the through hole 23, and a membrane-like covering portion 26 covering an end surface 15a of the gas diffusion layer 15 is integrally formed so as to cover a whole of the peripheral edge portion of the gas diffusion layer 15.
  • gaskets 21 and 22 integrally formed with the lower gas diffusion layer 16 in the drawing are structured such that the upper gasket 21 closely attached to the electrolyte membrane 12, and the lower gasket 22 closely attached to the lower separator 18 are integrally formed with each other via a rubber 27 charged into the through hole 24, and a membrane-like covering portion 28 covering an end surface 16a of the gas diffusion layer 16 is integrally formed so as to cover a whole of the peripheral edge portion of the gas diffusion layer 16.
  • These gaskets 19, 20, 21 and 22 are formed by a liquid rubber capable of executing an injection molding at a low pressure, and a hardness of the rubber is set to about Hs 20 to 60.
  • An assembled structure having the structure mentioned above constructs a fuel battery cell as an finished assembly product, and has a feature that the following functions and effects can be achieved by the structure mentioned above.
  • the reaction electrode portion 11 provided with the electrolyte membrane 12 and the gas diffusion layers 15 and 16 arranged in both surfaces thereof are formed as independent bodies as described above, the through holes 23 and 24 are provided near the peripheral edge portions of a pair of gas diffusion layers 15 and 16 holding the independent reaction electrode portion 11 from both sides thereof, and the gaskets 19, 20, 21 and 22 are integrally formed with both surfaces of the gas diffusion layers 15 and 16 via the through holes 23 and 24, it is possible to replace only the gas diffusion layers 15 and 16 with which the gaskets 19, 20, 21 and 22 are integrally formed by a substitute with leaving the independent reaction electrode portion 11, when there occurs a necessity of replacing the gas diffusion layers 15 and 16 due to generation of permanent strain or the like. Accordingly, since it is not necessary to replace the electrolyte membrane 12 corresponding to a comparatively expensive part each time, it is possible to reduce a cost for parts and a cost for maintenance. A replacing operation can be significantly easily executed.
  • the gaskets 19, 20, 21 and 22 are formed so as to cover the peripheral edge portions of the gas diffusion layers 15 and 16 by the covering portions 26 and 28 integrally formed therewith, particularly cover the end surfaces 15a and 16a of the gas diffusion layers 15 and 16, it is possible to prevent the sealed fluid from permeating through the gas diffusion layers 15 and 16 so as to leak in the direction to the end surfaces 15a and 16a thereof. Accordingly, it is possible to provide the constituting part for the fuel battery which can achieve an excellent seal property in the direction to the end surface.
  • a LIM molding machine is used in forming the constituting part for the fuel battery.
  • recess portions 31 and 32 are provided in parting portions of mold plates 29 and 30, and the mold is clamped only in portions near the peripheral edge portions of the gas diffusion layers 15 and 16 at a time of forming.
  • Fig. 11 shows a plan view of a constituting part 41 for a fuel battery in accordance with a sixth example which is not claimed, and an enlarged cross sectional view along a line D-D thereof is shown in Fig. 12 .
  • the constituting part 41 for the fuel battery in accordance with the present embodiment is an integrated product of a gas diffusion layer 42 and a gasket 43, and is structured as follows.
  • the flat gas diffusion layer 42 provided with a predetermined plane shape is provided, and the gasket 43 is arranged in an outer side (left side in Fig. 12 ) of an outer peripheral edge portion 42a in the gas diffusion layer 42 all around the periphery.
  • the gas diffusion layer 42 is formed by a carbon fiber
  • the gasket 43 is formed by a liquid rubber cured material
  • a part of the liquid rubber forming the gasket 43 is impregnated in the outer peripheral edge portion 42a of the gas diffusion layer 42, whereby the gas diffusion layer 42 and the gasket 43 are integrated.
  • dots are attached to the impregnated portions.
  • the gasket 43 is formed as a double-face seal type gasket respectively provided with seal lips 43a and 43b on both upper and lower surfaces thereof, a height position of a seal surface 43c of the upper seal lip 43a is set to be above a height position of an upper surface 42b of the gas diffusion layer 42, and a height position of a seal surface 43d of the lower seal lip 43b is set to be below a height position of a lower surface 42c of the gas diffusion layer 42. Accordingly, the gas diffusion layer 42 is arranged within a height area of the gasket 43 and is arranged inside and on the side surface of the gasket 43, whereby the gas diffusion layer 42 and the seal lips 43a and 43b of the gasket 43 are arranged so as not to vertically overlap on the plane.
  • the gas diffusion layer 42 and the seal lips 43a and 43b of the gasket 43 are arranged so as not to vertically overlap on the plane as mentioned above, the gas diffusion layer 42 is not positioned immediately below or immediately above the seal lips 43a and 43b of the gasket 43, whereby it is possible to restrict the permanent compression strain generated in the gasket 43 to a smaller level than the prior art.
  • Fig. 13 shows a plan view of a constituting part 41 for a fuel battery in accordance with a seventh embodiment of the present invention, and an enlarged cross sectional view along a line E-E thereof is shown in Fig. 14 .
  • the constituting part 41 for the fuel battery in accordance with the present embodiment is an integrated product of a gas diffusion layer 42, a gasket 43 and a separator 44, and is structured as follows.
  • the flat gas diffusion layer 42 provided with a predetermined plane shape is provided, and the gasket 43 is arranged in an outer side (left side in Fig. 14 ) of an outer peripheral edge portion 42a in the gas diffusion layer 42 all around the periphery, and the gas diffusion layer 42 and the gasket 43 are layered on one surface side (upper surface side in Fig 14 ) of the separator 44.
  • the gas diffusion layer 42 is formed by a carbon fiber
  • the gasket 43 is formed by a liquid rubber cured material
  • the separator 44 is formed by a carbon plate.
  • a part of the liquid rubber forming the gasket 43 is impregnated in the outer peripheral edge portion 42a of the gas diffusion layer 42, whereby the gas diffusion layer 42 and the gasket 43 are integrated (in the drawing, as a matter of convenience for explanation, dots are attached to the impregnated portions), and a part of the liquid rubber reacts with an adhesive agent 45 applied to the separator 44, whereby the gasket 43 and the separator 44 are integrated.
  • the gasket 43 is formed as a one-face seal type gasket provided with a seal lip 43a on an upper surface thereof, and a mounting portion 43e to the separator 44 is provided on a lower surface thereof.
  • a height position of a seal surface 43c of the seal lip 43a is set to be above a height position of an upper surface 42b of the gas diffusion layer 42, and a height position of a mounting surface 43f of the mounting portion 43e is set to be below a height position of a lower surface 42c of the gas diffusion layer 42.
  • the gas diffusion layer 42 is arranged within a height area of the gasket 43 and is arranged inside and on the side surface of the gasket 43, whereby the gas diffusion layer 42 and the seal lip 43a of the gasket 43 are arranged so as not to vertically overlap on the plane.
  • a groove-like recess portion 44a for fixing the gasket 43 by applying the adhesive agent 45 is provided on one surface of the separator 44, and a step portion 44b for facilitating to position the gas diffusion layer 42 is provided inside the recess portion 44a.
  • the gas diffusion layer 42 and the seal lip 43a of the gasket 43 are arranged so as not to vertically overlap on the plane as mentioned above, the gas diffusion layer 42 is not positioned immediately below the seal lip 43a of the gasket 43. Accordingly, it is possible to restrict the permanent compression strain generated in the gasket 43 to a smaller level than the prior art.
  • the present invention achieves the following effects.
  • the separator made of the carbon plate or the like, the gas diffusion layer made of the carbon fiber or the like, and the gasket made of the liquid rubber cured material or the like are integrally formed, it is possible to reduce the number of steps of assembling the parts with each other at a time of assembling of the fuel battery. Accordingly, it is possible to make the assembling operation of the fuel battery easy. Further, since they are integrated, it is possible to significantly improve the seal property of the gasket portion mounted to the gas diffusion layer.
  • the gasket made of the liquid rubber cured material or the like is integrally formed with one surface in the side of the gas diffusion layer of the integrated product of the separator made of the carbon plate or the like and the gas diffusion layer made of the carbon fiber or the like, it is possible to reduce the number of steps of assembling the parts with each other at a time of assembling of the fuel battery. Accordingly, it is possible to make the assembling operation of the fuel battery easy. Further, since they are integrated, it is possible to significantly improve the seal property of the gasket portion mounted to the gas diffusion layer.
  • the gasket made of the liquid rubber cured material or the like is integrally formed with one surface in the side of the gas diffusion layer of the integral product of the separator made of the carbon plate or the like and the gas diffusion layer made of the carbon fiber or the like, and the gasket is integrally formed with the opposite surface, it is possible to reduce the number of steps of assembling the parts with each other at a time of assembling of the fuel battery. Accordingly, it is possible to make the assembling operation of the fuel battery easy. Further, since they are integrated, it is possible to significantly improve the seal property of the gasket portion mounted to the gas diffusion layer.
  • the invention in accordance with the present aspect provides the integrated product of the double-face gasket.
  • the adhesive agent is applied to the separator, and the rubber of the gasket permeating into the gas diffusion layer is reacted with the adhesive agent on the separator, thereby being integrally formed in such a manner as to hold the gas diffusion layer therein, the structure in which the gasket and the gas diffusion layer are closely attached is provided, and it is possible to prevent the space forming the shortcut flow passage for the gas from being formed between the gasket and the gas diffusion layer. Accordingly, it is possible to improve a diffusion property of the gas, whereby it is possible to improve an efficiency of power generation of the fuel battery.
  • the adhesive agent is also applied to the separator, and the rubber of the gasket permeating into the gas diffusion layer is reacted with the adhesive agent on the separator, thereby being integrally formed in such a manner as to hold the gas diffusion layer therein, the structure in which the gasket and the gas diffusion layer are closely attached is provided, and it is possible to prevent the space forming the shortcut flow passage for the gas from being formed between the gasket and the gas diffusion layer. Accordingly, it is possible to improve a diffusion property of the gas, whereby it is possible to improve an efficiency of power generation of the fuel battery.
  • the rubber of the gasket permeates into the gas diffusion layer so as to reach the separator, whereby the gasket and the separator are integrated, it is possible to prevent the gas leakage flow passage form being formed, whereby it is possible to improve a seal property.
  • the adhesive agent is applied also to the opposite surface and the gasket is integrally formed, in accordance with the invention of the present aspect, the integrated product of the double-face gasket can be provided.
  • the through hole is provided in the separator, and a part of the rubber penetrating into the gas diffusion layer passes through the through hole so as to reach the opposite surface, whereby the gasket is integrally formed on both surfaces of the separator, the structure in which the gasket and the gas diffusion layer are closely attached is provided, and it is possible to prevent the space forming the shortcut flow passage for the gas from being formed between the gasket and the gas diffusion layer. Accordingly, it is possible to improve a diffusion property of the gas, whereby it is possible to improve an efficiency of power generation of the fuel battery.
  • the rubber of the gasket permeates into the gas diffusion layer so as to reach the separator, whereby the gasket and the separator are integrated, it is possible to prevent the gas leakage flow passage form being formed, whereby it is possible to improve a seal property.
  • the gasket is integrally formed with both surfaces of the separator, in accordance with the invention of the present aspect, the integrated product of the double-face gasket can be provided.
  • the electrolyte membrane and the gas diffusion layer are formed as the independent bodies, and the gaskets are respectively provided on both surfaces of a pair of gas diffusion layers holding the independent electrolyte membrane from both sides thereof between the pair, it is possible to replace only the gas diffusion layer provided with the gasket by a substitute with leaving the electrolyte membrane independent from the gas diffusion layer. Accordingly, since it is not necessary to replace the electrolyte membrane corresponding to the comparatively expensive part each time, it is possible to reduce the cost for parts and the cost for maintenance.
  • the seal portion of the fuel battery cell is constituted by the combination of the gas diffusion layer and the gasket, and the electrolyte membrane is received inside the seal portion. Accordingly, since the plane area of the electrolyte membrane corresponding to the comparatively expensive part can be made smaller in comparison with the conventional one, it is possible to reduce the cost for parts at that degree.
  • the gasket is formed in the double lip structure in the side of the separator in one gas diffusion layer, and in the side of the electrolyte membrane and the side of the separator in another gas diffusion layer, it is possible to achieve an excellent seal performance, and since the gasket is formed in the flat seal structure in the side of the electrolyte membrane in one gas diffusion layer, it is possible to restrict the deformation of the electrolyte membrane pressed and contacted thereby to a small level.
  • the gasket is formed by being impregnated with the liquid rubber into the porous structure of the gas diffusion layer, it is possible to firmly and easily integrate the gasket with the gas diffusion layer.
  • the through hole is provided near the peripheral edge portion of a pair of gas diffusion layers holding the independent electrolyte membrane therein from both sides thereof, and the gasket is integrally formed on both surfaces of the gas diffusion layer via the through hole, it is possible to replace only the gas diffusion layer provided with the gasket by a substitute with leaving the electrolyte membrane independent from the gas diffusion layer. Accordingly, since it is not necessary to replace the electrolyte membrane corresponding to the comparatively expensive part each time, it is possible to reduce the cost for parts and the cost for maintenance.
  • the gasket covers the peripheral edge portion of the gas diffusion layer, and particularly covers the end surface of the gas diffusion layer, it is possible to prevent the sealed fluid from permeating through the gas diffusion layer so as to leak in the direction to the end surface thereof. Accordingly, it is possible to provide the constituting part for the fuel battery which achieves an excellent seal property with respect to the direction to the end surface.
  • the gas diffusion layer and the seal lip of the gasket are arranged so as not to be overlapped with each other in view of a plane, the gas diffusion layer is not positioned immediately below the seal lip of the gasket, whereby it is possible to restrict the permanent compression strain generated in the gasket to be smaller than the conventional one. Accordingly, it is possible to provide the constituting part for the fuel battery in which the number of steps of assembling of the fuel battery can be reduced, due to the integrated product of the gas diffusion layer and the gasket, or the integrated product of the gas diffusion layer, the gasket and the separator, and in addition, the permanent compression strain generated in the gasket can be restricted to be small.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Inert Electrodes (AREA)
EP01932198A 2000-06-29 2001-05-22 Constituent part for fuel cell Expired - Lifetime EP1296394B1 (en)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
JP2000195535 2000-06-29
JP2000195535 2000-06-29
JP2000307152 2000-10-06
JP2000307152 2000-10-06
JP2000328136 2000-10-27
JP2000328136 2000-10-27
JP2001026295 2001-02-02
JP2001026295 2001-02-02
PCT/JP2001/004273 WO2002001658A1 (fr) 2000-06-29 2001-05-22 Composant destine a une pile a combustible

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EP1296394A1 EP1296394A1 (en) 2003-03-26
EP1296394A4 EP1296394A4 (en) 2009-04-29
EP1296394B1 true EP1296394B1 (en) 2011-08-17

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EP (1) EP1296394B1 (zh)
JP (1) JP3894314B2 (zh)
KR (1) KR100750021B1 (zh)
CN (1) CN100487966C (zh)
AT (1) ATE521099T1 (zh)
AU (1) AU2001258800A1 (zh)
CA (1) CA2412869C (zh)
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KR20030011876A (ko) 2003-02-11
US20030104262A1 (en) 2003-06-05
CA2412869C (en) 2010-10-05
KR100750021B1 (ko) 2007-08-16
EP1296394A4 (en) 2009-04-29
AU2001258800A1 (en) 2002-01-08
JP3894314B2 (ja) 2007-03-22
CN100487966C (zh) 2009-05-13
EP1296394A1 (en) 2003-03-26
CA2412869A1 (en) 2002-12-12
CN1557034A (zh) 2004-12-22
WO2002001658A1 (fr) 2002-01-03
ATE521099T1 (de) 2011-09-15
US7504173B2 (en) 2009-03-17

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