EP1278814A2 - Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission - Google Patents

Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission

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Publication number
EP1278814A2
EP1278814A2 EP01943321A EP01943321A EP1278814A2 EP 1278814 A2 EP1278814 A2 EP 1278814A2 EP 01943321 A EP01943321 A EP 01943321A EP 01943321 A EP01943321 A EP 01943321A EP 1278814 A2 EP1278814 A2 EP 1278814A2
Authority
EP
European Patent Office
Prior art keywords
fuel
composition according
carrier oil
fuel additive
additive composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01943321A
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German (de)
English (en)
Other versions
EP1278814B1 (fr
Inventor
Harald Schwahn
Dietmar Posselt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
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Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP1278814A2 publication Critical patent/EP1278814A2/fr
Application granted granted Critical
Publication of EP1278814B1 publication Critical patent/EP1278814B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1625—Hydrocarbons macromolecular compounds
    • C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)

Definitions

  • Fuel additive packages for petrol with improved viscosity properties and good IVD performance are provided.
  • the invention relates to gasoline fuel additive compositions and fuels for gasoline engines additized with them, the gasoline fuel additive packages according to the invention not only having very good performance in keeping the intake system clean, but also having improved viscosity properties, especially at low temperatures.
  • Carburetors and intake systems of gasoline engines are increasingly loaded by contaminants caused by dust particles from the air, unburned hydrocarbon residues from the combustion chamber and the crankcase ventilation gases passed into the carburetor.
  • the first generation of additives could only prevent the formation of deposits in the intake system, but not remove existing deposits, whereas the modern additives of the second generation can do both (keep-clean and clean-up effect), in particular due to their excellent thermal stability in zones of higher temperature, namely the inlet valves.
  • Such detergents which can originate from a large number of chemical substance classes, such as, for example, polyalkenamines, polyetheramines, polybutene-Mannich bases or Polybutensuccinimides are generally used in combination with carrier oils and some other additive components, such as corrosion inhibitors and demulsifiers.
  • the carrier oils have a solvent or washing function in combination with the detergents.
  • Carrier oils are usually high-boiling, viscous, thermostable liquids that coat the hot metal surface and thereby prevent the formation or deposition of contaminants on the metal surface.
  • Such formulations of detergents with carrier oils can in principle be classified as follows (depending on the type of carrier oils (carrier oil):
  • mineral oil-based carrier oils i.e. only mineral oil-based (mineral) carrier oils are used
  • fully synthetic carrier oils i.e. only synthetic carrier oils are used
  • semi-synthetic i.e. mixtures of mineral oil-based and synthetic carrier oils are used
  • the object was therefore to provide semi-synthetic fuel additive packages for petrol which are distinguished both by improved viscosity properties and by very good cleaning effects in the intake system.
  • Such semisynthetic additive formulations according to the invention showed that on the one hand they ensure very good performance in terms of their cleaning properties and, moreover, are distinguished by surprisingly significantly lower viscosities at lower temperatures.
  • Lower viscosities for additive formulations in turn mean advantages in processing, since fewer solvents have to be used to set the desired viscosity.
  • a) at least one detergent additive b) a carrier oil mixture comprising i) at least one synthetic carrier oil; and ii) at least one mineral carrier oil; and c) optionally further customary fuel additive components
  • Preferred fuel additive compositions are those whose mineral carrier oil component has a viscosity of approximately 250 to a maximum of approximately 410 mm 2 / s, in particular approximately 350 to a maximum of 410 mm 2 / s, determined at + 20 ° C. according to DIN 51562, part 1.
  • compositions preferred according to the invention are those whose synthetic carrier oil component has a viscosity of approximately 120 to approximately 270 mm 2 / s, in particular approximately 140 to approximately 240 mm 2 / s, determined at + 20 ° C. according to DIN 51562, part 1 ,
  • Particularly preferred fuel additive compositions contain mineral carrier oil component and synthetic carrier oil component in a weight ratio of approximately 10: 1 to approximately 1:10, in particular approximately 5: 1 to approximately 1: 5, preferably approximately 4: 1 to approximately 1: 4.
  • the weight ratio of detergent additive component to carrier oil component is in the range from approximately 1:20 to 20: 1, in particular approximately 1:10 to 10: 1, preferably approximately 1: 5 to approximately 5: 1 or about 2: 3 to about 4: 1.
  • carrier oil component sum of mineral and synthetic carrier oil
  • Preferred fuel additive compositions according to the invention comprise as detergent additive component (component a) a detergent component.
  • polyalkene mono- and polyamines selected from polyalkene mono- and polyamines, polyether amines and mixtures thereof.
  • useful polyether amines are poly-C 2 -C 6 -alkylene oxide amines
  • polyalkenamines are poly-C 2 -C 6 -alkeneamines, and functional derivatives thereof, each with a preferred Mn of about 150 to
  • amines include both mono- and polyamines, preferably with up to 6 nitrogen atoms.
  • Polyalkene mono- or polyalkene polyamines 25 or functional derivatives thereof which can be used according to the invention are, in particular, poly-C 2 -C 6 -alkenamines or functional derivatives thereof, such as, for example, based on polypropene, polybutene or polyisobutene.
  • Examples of functional derivatives of the above additives are compounds which carry, for example in the amine part, one or more polar substituents, in particular hydroxyl groups.
  • Preferred additives which can be used according to the invention are polyalkene mono- or polyalkene polyamines based on polypropene or
  • Such additives based on highly reactive polyisobutene which consists of polyisobutene, which can contain up to 20% by weight of n-butene units, by hydroformylation and reductive amination with ammonia, monoamines or polyamines, such as dimethylaminopropyl
  • additives containing monoamino groups are the compounds obtainable from polyisobutene epoxides by reaction with amines and subsequent dehydration and reduction of the amino alcohols, as are described in particular in DE-A 196 20 262.
  • Particularly useful detergent additives of the polyalkenamine type are sold by BASF AG, Ludwigshafen, under the trade name Kerocom PIBA. These contain polyisobutenamines dissolved in aliphatic C ⁇ -C ⁇ hydrocarbons and can be used as such in the additive packages according to the invention.
  • Examples of usable carrier oils or carrier oil liquids are combinations of mineral carrier oil (s) and synthetic carrier oil (s) which are compatible with the additive (s) and the fuel used.
  • Suitable mineral carrier oils which meet the above-mentioned viscosity criterion according to the invention are fractions obtained in petroleum processing, such as kerosene or naphtha, brightstock or base oils with viscosities such as from the SN 500-2000 class; but also aromatic hydrocarbons, paraffinic hydrocarbons, and alkoxyalkanols. Also useful is one known as "hydrocrack oil” and used in refining mineral oil fraction (vacuum distillate cut with a boiling range of around 360 to 500 ° C, obtainable from high-pressure natural mineral oil catalytically hydrogenated and isomerized and dewaxed). Mixtures of the mineral carrier oils mentioned above are also suitable.
  • Examples of synthetic carrier oils which can be used according to the invention and which meet the above viscosity criterion according to the invention are selected from: polyolefins, (poly) esters, (poly) alkoxylates, polyethers, aliphatic polyetheramines, alkylphenol-started polyethers, alkylphenol-started polyetheramines and carboxylic acid esters of long-chain alkanols.
  • suitable polyethers or polyetheramines are preferably compounds containing polyoxy-C 2 -C -alkylene groups, which are obtained by reacting C -C 6 -alkanols, C 6 -C 30 -alkanols, mono- or di-C 2 -C 3 o-alkylamines, Cx-Cso-alkylcyclohexanols or C ⁇ -C 3 o-alkylphenols with 1 to 30 mol ethylene oxide and / or propylene oxide and / or butylene oxide per hydroxyl group or amino group and, in the case of the polyether amines, by subsequent reductive Amination with ammonia, monoamines or polyamines are available.
  • poly-C 2 -C 6 -alkylene oxide amines or functional derivatives thereof can be used as polyether amines.
  • Typical examples of this are tridecanol or isotridecanol butoxylates, isononylphenol butoxylates and polyisobutenol butoxylates and propoxylates as well as the corresponding reaction products with ammonia.
  • carboxylic acid esters of long-chain alkanols are in particular esters of mono-, di- or tricarboxylic acids with long-chain alkanols or polyols, in particular those with a minimum viscosity of 2 mm 2 / s at 100 ° C., as described in particular in DE-A-38 38 918 are described.
  • Aliphatic or aromatic acids can be used as mono-, di- or tricarboxylic acids, and long-chain representatives with, for example, 6 to 24 carbon atoms are particularly suitable as ester alcohols or polyols.
  • esters are adipates, phthalates, isophthalates, terephthalates and trimellitates of isooctanol, isononanol, isodecanol and isotridecanol, such as di- (n- or isotridecyl) phthalate.
  • suitable carrier oil systems are described, for example, in DE-A-38 26 608, DE-A-41 42 241, DE-A-43 09 074, EP-A-0 452 328 and EP-A-0 548 617, whereupon hereby explicit reference is made.
  • suitable synthetic carrier oils are alcohol-initiated polyethers with about 5 to 35, for example about 5 to 30, C 3 -C 6 alkylene oxide units, such as, for example, selected from propylene oxide, n-butylene oxide and i-butylene oxide units, or mix of them.
  • suitable starter alcohols are long-chain alkanols or phenols substituted with long-chain alkyl, the long-chain alkyl radical in particular representing a straight-chain or branched C 6 -C 8 - in particular Cs-Cis-alkyl radical.
  • Preferred examples are tridecanol and nonylphenol.
  • composition preferred according to the invention typical of a semi-synthetic gasoline additive package, comprises:
  • a synthetic carrier liquid such as a polyether, for example composed of about 10 to 35, such as 15 to 30, C 3 -C 6 alkylene oxide units, such as propylene oxide, n- and i-butylene oxide units or mixtures thereof, and at least one mineral oil-based carrier oil
  • main detergent additive component (a) polyetheramine and / or polyalkenamine
  • further detergent additives may be present, provided that the advantageous effects observed according to the invention are not adversely affected thereby.
  • further useful detergent additives are those which have at least one hydrophobic hydrocarbon radical with a number average molecular weight (Mn) of 85 to
  • additives containing nitro groups, optionally in combination with hydroxyl groups (ab) additives containing nitro groups, optionally in combination with hydroxyl groups; (ac) hydroxyl groups in combination with additives containing mono- or polyamino groups, at least one nitrogen atom having basic properties;
  • the hydrophobic hydrocarbon residue in these detergent additives which ensures sufficient solubility in the fuel, has a number average molecular weight (Mn) from 85 to 20,000, in particular from 113 to 10,000, especially from 300 to 5,000.
  • Mn number average molecular weight
  • These reaction products are usually mixtures of pure nitropolyisobutanes (e.g. ⁇ , ß-dinitropolyisobutane) and mixed hydroxynitropolyisobutanes (e.g. ⁇ -nitro-ß-hydroxypolyisobutane).
  • Additives (ad) containing carboxyl groups or their alkali metal or alkaline earth metal salts are preferably copolymers of C 2 -C 0 -olefins with maleic anhydride with a total molecular weight of 500 to 20,000, the carboxyl groups of which are wholly or partly to the alkali metal or alkaline earth metal salts and a remainder implemented the carboxyl groups with alcohols or amines are.
  • Such additives are known in particular from EP-A 307 815.
  • Such additives mainly serve to prevent valve seat wear and, as described in WO-A 87/01126, can advantageously be used in combination with conventional fuel detergents such as poly (iso) butenamines or polyetheramines.
  • Sulfonic acid groups or additives (ae) containing alkali metal or alkaline earth metal salts thereof are preferably alkali metal or alkaline earth metal salts of an alkyl sulfosuccinic acid ester, as described in particular in EP-A-639 632.
  • Such additives mainly serve to prevent valve seat wear and can advantageously be used in combination with conventional fuel detergents such as poly (iso) butenamines or polyetheramines.
  • Derivatives with aliphatic polyamines such as ethylene diamine, diethylene triamine, triethylene tetramine or tetraethylene pentamine are of particular interest.
  • Such gasoline fuel additives are described in particular in US Pat. No. 4,849,572.
  • Additives (ag) produced by the Mannich reaction of substituted phenols with aldehydes and mono- or polyamines are preferably reaction products of polyisobutene-substituted phenols with formaldehyde and mono- or polyamines such as ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine or dimethylamino -propylamine.
  • Such "polyisobutene Mannich bases” are described in particular in EP-A 831 141.
  • component (c) are corrosion inhibitors, for example based on ammonium salts of organic carboxylic acids which tend to form films, or of heterocyclic aromatics for non-ferrous metal corrosion protection, dyes, antioxidants or stabilizers, for example based on amines such as p-phenylenediamine, dicyclohexylamine or derivatives thereof or of phenols such as 2, 4-di-tert.
  • corrosion inhibitors for example based on ammonium salts of organic carboxylic acids which tend to form films, or of heterocyclic aromatics for non-ferrous metal corrosion protection, dyes, antioxidants or stabilizers, for example based on amines such as p-phenylenediamine, dicyclohexylamine or derivatives thereof or of phenols such as 2, 4-di-tert.
  • demulsifiers such as ferrocene or methylcyclopentadienylmanganese tricarbonate
  • metallocenes such as ferrocene or methylcyclopentadienylmanganese tricarbonate
  • further lubricity improvers such as certain fatty acids, alkenylsuccinic acid esters, bis ( xyalkyl) fatty amines or hydroxyacetamides and dyes (markers). If necessary, amines are also added to lower the pH of the fuel.
  • the fuel additive combinations according to the invention optionally in combination with one or more of the above-mentioned further fuel additives with the polar groups, and the other components mentioned, are metered into the fuel and develop their effect there.
  • the components or additives can be added to the fuel individually or as a previously prepared concentrate (“additive package”).
  • solvents or diluents there are aliphatic and aromatic hydrocarbons, e.g. Solvent naphtha or kerosene.
  • the fuel additive mixtures according to the invention are added to the fuel, for example in an amount in the range from 10 to 5000 ppm (mg / kg fuel), preferably 20 to 1500 ppm (mg / kg fuel).
  • the optionally used further fuel additives with the polar groupings are usually added to the fuel in an amount of 10 to 5000 ppm, in particular 50 to 1000 ppm, and the other components and additives mentioned, if desired, in amounts customary for this.
  • the fuel to which the fuel additive mixtures according to the invention are added is not subject to any particular restrictions. It can be, for example, a gasoline according to DIN EN 228.
  • the fuel can be, for example, a petrol with an aromatic content of at most 42 vol.%, Such as 20 to 42 vol.% And a sulfur content of at most 150 ppm, such as 0.5 to 150 ppm.
  • the petrol can also have a maximum olefin content of 10 21% by volume, e.g. have from 6 to 21 vol .-%.
  • the benzene content can be a maximum of 1.0% by volume, e.g. 0.5 to
  • the oxygen content can e.g. are in the range from 0.1 to 2.7% by weight.
  • the alcohol and ether content in petrol is usually relatively low. Typical maximum contents are 3% by volume for methanol, 5% by volume for ethanol, 10% by volume for isopropanol, 7% by volume for ter-butanol, 10% by volume for isobutanol and for
  • the summer vapor pressure of petrol is usually a maximum of 70 kPa, especially 60 kPa (each at 37 ° C).
  • the research octane number ("RON") of petrol is usually 90 to 100.
  • a typical range for the corresponding engine octane number (“MOZ”) is 80 to 90.
  • Base oil (viscosity at + 20 ° C: 407 mm 2 / s) and 10% of a synthetic butylene oxide carrier (tridecanol etherified with butylene oxide units) (viscosity at + 20 ° C: 157 mm / s).
  • Production example B (comparison): A mixture is prepared analogously to Example A, only the mineral carrier oil being replaced by a base oil not according to the invention with a viscosity at + 20 ° C. of 432 mm 2 / s.
  • Test example 2 Comparison of IVD performance
  • composition according to the invention surprisingly shows a clearly advantageous IVD performance.
  • a base oil viscosity at + 20 ° C: 407 mm 2 / s
  • Preparation example C is repeated, the mineral carrier oil being replaced by a base oil which is not according to the invention and has a viscosity at + 20 ° C. of 432 mm 2 / s.
  • 20% by weight of a base oil viscosity at + 20 ° C: 407 mm 2 /
  • Preparation example E is repeated, the mineral carrier oil being replaced by a base oil which is not according to the invention and has a viscosity at + 20 ° C. of 432 mm 2 / s.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L'invention concerne des compositions d'additifs pour essence de moteurs ainsi que des carburants contenant ces additifs, destinés à des moteurs à étincelles. Ces compositions d'additifs pour essence de moteurs présentent non seulement de bonnes propriétés détergentes pour le système d'admission mais aussi des propriétés de viscosité améliorées, en particulier à basse température.
EP01943321A 2000-05-05 2001-05-04 Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission Expired - Lifetime EP1278814B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10021936 2000-05-05
DE10021936A DE10021936A1 (de) 2000-05-05 2000-05-05 Kraftstoffadditivpakete für Ottokraftstoffe mit verbesserten Viskositätseigenschaften und guter IVD Performance
PCT/EP2001/005039 WO2001085874A2 (fr) 2000-05-05 2001-05-04 Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission

Publications (2)

Publication Number Publication Date
EP1278814A2 true EP1278814A2 (fr) 2003-01-29
EP1278814B1 EP1278814B1 (fr) 2006-05-31

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EP01943321A Expired - Lifetime EP1278814B1 (fr) 2000-05-05 2001-05-04 Compositions d'additifs pour essence de moteurs, presentant des proprietes de viscosite ameliorees et de bonnes proprietes detergentes pour le systeme d'admission

Country Status (22)

Country Link
US (1) US6840970B2 (fr)
EP (1) EP1278814B1 (fr)
JP (1) JP5192627B2 (fr)
KR (1) KR100727363B1 (fr)
AR (1) AR033821A1 (fr)
AT (1) ATE328053T1 (fr)
AU (2) AU6592501A (fr)
BR (1) BR0110543A (fr)
CA (1) CA2406762C (fr)
CZ (1) CZ20023608A3 (fr)
DE (2) DE10021936A1 (fr)
EE (1) EE200200624A (fr)
HR (1) HRP20020957A2 (fr)
HU (1) HUP0301874A2 (fr)
IL (1) IL152357A (fr)
MX (1) MXPA02010048A (fr)
MY (1) MY127143A (fr)
NO (1) NO20025285D0 (fr)
NZ (1) NZ521875A (fr)
PL (1) PL198793B1 (fr)
SK (1) SK15502002A3 (fr)
WO (1) WO2001085874A2 (fr)

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DE10256161A1 (de) 2002-12-02 2004-06-09 Basf Ag Verwendung von Aminen und/oder Mannich-Addukten in Kraft- und Schmierstoffzusammensetzungen für direkteinspritzende Ottomotoren
DE10314809A1 (de) * 2003-04-01 2004-10-14 Basf Ag Polyalkenamine mit verbesserten Anwendungseigenschaften
DE10316871A1 (de) * 2003-04-11 2004-10-21 Basf Ag Kraftstoffzusammensetzung
EP1705234A1 (fr) * 2005-03-24 2006-09-27 Basf Aktiengesellschaft Utilisation d'additifs détergents afin d'empêcher ou de réduire la formation des dépôts dans les systèmes d'injection pour moteurs diesel à injection directe
US20060277820A1 (en) * 2005-06-13 2006-12-14 Puri Suresh K Synergistic deposit control additive composition for gasoline fuel and process thereof
US20060277819A1 (en) * 2005-06-13 2006-12-14 Puri Suresh K Synergistic deposit control additive composition for diesel fuel and process thereof
US8222180B2 (en) * 2005-08-01 2012-07-17 Indian Oil Corporation Limited Adsorbent composition for removal of refractory sulphur compounds from refinery streams and process thereof
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GB201001920D0 (en) * 2010-02-05 2010-03-24 Innospec Ltd Fuel compostions
GB201007756D0 (en) 2010-05-10 2010-06-23 Innospec Ltd Composition, method and use
KR101241387B1 (ko) * 2010-11-08 2013-03-11 석종호 연료 첨가제 조성물 및 이를 포함하는 연료 조성물
KR101287026B1 (ko) * 2011-01-11 2013-07-17 주식회사 재윤 연료 첨가제 조성물 및 이를 포함하는 연료 조성물
US8641788B2 (en) 2011-12-07 2014-02-04 Igp Energy, Inc. Fuels and fuel additives comprising butanol and pentanol
CN112410131B (zh) * 2020-11-09 2022-04-12 3M中国有限公司 发动机进气阀沉积物清洗组合物及其制备方法，以及清洗发动机进气阀沉积物的方法

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Also Published As

Publication number Publication date
US6840970B2 (en) 2005-01-11
HUP0301874A2 (hu) 2003-08-28
NO20025285L (no) 2002-11-04
PL198793B1 (pl) 2008-07-31
KR20020093128A (ko) 2002-12-12
JP5192627B2 (ja) 2013-05-08
NO20025285D0 (no) 2002-11-04
EP1278814B1 (fr) 2006-05-31
SK15502002A3 (sk) 2003-05-02
EE200200624A (et) 2004-06-15
CA2406762A1 (fr) 2002-10-17
BR0110543A (pt) 2003-04-01
WO2001085874A2 (fr) 2001-11-15
WO2001085874A3 (fr) 2002-04-04
AU2001265925B2 (en) 2006-02-16
MY127143A (en) 2006-11-30
HRP20020957A2 (en) 2005-02-28
AR033821A1 (es) 2004-01-07
CZ20023608A3 (cs) 2003-06-18
AU6592501A (en) 2001-11-20
ATE328053T1 (de) 2006-06-15
DE50109967D1 (de) 2006-07-06
IL152357A0 (en) 2003-05-29
PL358461A1 (en) 2004-08-09
US20030140552A1 (en) 2003-07-31
KR100727363B1 (ko) 2007-06-13
MXPA02010048A (es) 2003-03-10
NZ521875A (en) 2004-05-28
IL152357A (en) 2005-07-25
JP2003532783A (ja) 2003-11-05
CA2406762C (fr) 2009-11-03
DE10021936A1 (de) 2001-11-08

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