EP1215276B1 - Compositions détergentes contenant des particules microdispersées en silicates - Google Patents
Compositions détergentes contenant des particules microdispersées en silicates Download PDFInfo
- Publication number
- EP1215276B1 EP1215276B1 EP01128892A EP01128892A EP1215276B1 EP 1215276 B1 EP1215276 B1 EP 1215276B1 EP 01128892 A EP01128892 A EP 01128892A EP 01128892 A EP01128892 A EP 01128892A EP 1215276 B1 EP1215276 B1 EP 1215276B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent
- cleaner
- weight
- laundry
- laundry detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000003599 detergent Substances 0.000 title claims description 53
- 239000002245 particle Substances 0.000 title claims description 42
- 239000000203 mixture Substances 0.000 title claims description 37
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 45
- -1 antifoams Substances 0.000 claims description 19
- 238000004851 dishwashing Methods 0.000 claims description 14
- 239000007844 bleaching agent Substances 0.000 claims description 10
- 239000008119 colloidal silica Substances 0.000 claims description 10
- 239000002689 soil Substances 0.000 claims description 9
- 239000004569 hydrophobicizing agent Substances 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- 108090000790 Enzymes Proteins 0.000 claims description 7
- 102000004190 Enzymes Human genes 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 4
- 239000000499 gel Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 150000004812 organic fluorine compounds Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000008139 complexing agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 238000004140 cleaning Methods 0.000 description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000012459 cleaning agent Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 238000003756 stirring Methods 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 239000002518 antifoaming agent Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 239000000344 soap Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229920004482 WACKER® Polymers 0.000 description 6
- 229960004106 citric acid Drugs 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 229940088598 enzyme Drugs 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000004667 Diesterquat Substances 0.000 description 5
- 108090001146 Nuclear Receptor Coactivator 1 Proteins 0.000 description 5
- 102100037223 Nuclear receptor coactivator 1 Human genes 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 4
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 229960002303 citric acid monohydrate Drugs 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 4
- 229910000271 hectorite Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 108010075550 termamyl Proteins 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229940071118 cumenesulfonate Drugs 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- 229940094522 laponite Drugs 0.000 description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 3
- XMMDVXFQGOEOKH-UHFFFAOYSA-N n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCNCCCN XMMDVXFQGOEOKH-UHFFFAOYSA-N 0.000 description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 235000014347 soups Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 235000021185 dessert Nutrition 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 108010020132 microbial serine proteinases Proteins 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229910052615 phyllosilicate Inorganic materials 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical class O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 240000004307 Citrus medica Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000004890 Hydrophobing Agent Substances 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
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- 239000002274 desiccant Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical class CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
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- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- ZDGGJQMSELMHLK-UHFFFAOYSA-N m-Trifluoromethylhippuric acid Chemical compound OC(=O)CNC(=O)C1=CC=CC(C(F)(F)F)=C1 ZDGGJQMSELMHLK-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- 235000013336 milk Nutrition 0.000 description 1
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- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
Definitions
- washing and cleaning compositions containing microdisperse silicate-containing particles and a hydrophobizing agent containing microdisperse silicate-containing particles and a hydrophobizing agent
- the invention relates to detergents and cleaners containing silicate-containing, microdispersed hydrophilic particles, and a hydrophobizing agent having high soil release capacity and less Resistant to soiling of the surfaces to be cleaned.
- EP 368 559 describes the use of finely divided silica as Abrasion agents.
- the aforementioned documents relate to the abrasive action of colloidal Silica and its thickening effect in one formulation.
- silicate-containing particles act as surface coating agents used in the Adhering to the surfaces displace the dirt and at the same time through the Coating the surfaces makes their re-soiling difficult. In the repeated use of detergents and cleaners, the effect occurs amplified on.
- Microdispers refers to the particle size of the silicate-containing particles. Particle, in solution or when applied to surfaces not sufficiently small or do not form particles at all, are not suitable for the invention.
- the invention relates to a washing and cleaning agent, characterized characterized in that it comprises microdisperse, hydrophilic silicate-containing particles having a Particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the Particles around colloidal silica gels, colloidal silica, hectorites, saponites or Mixtures thereof and additionally at least one hydrophobicizing Agent, where the hydrophobizing agents are silicones, Silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluorine compounds is.
- the particles are preferably electrically charged on their surface.
- the washing and cleaning agent preferably contains 0.01 to 10% by weight. silicate-containing particles, 0.01 to 10 wt .-% hydrophobizing agents and 80 bis 99.8% by weight of other detergent / cleaner ingredients.
- the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.01 to 10% by weight of hydrophobing agents, 0.5 to 60 Wt .-% surfactants and 20 to 99.48 wt .-% other Detergent ingredients.
- the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.5 to 60% by weight of surfactants and 30 to 99.49 % By weight of other detergent / cleaning agent ingredients.
- the washing and cleaning agent preferably also contains builders, cobuilders, Suppliers of alkali, anionic, nonionic, zwitterionic and nonionic Surfactants, antifoaming agents, dispersants, complexing agents, bleaching agents, Bleach activators and catalysts and / or enzymes.
- the washing and cleaning agent is preferably a heavy-duty detergent, Compact heavy-duty detergent, Compact color detergent, heavy-duty detergent low bulk density, special detergents, such as laundry after-treatment, Fabric softeners, stain salts, bleach boosters, curtain washes, Wool detergents, building block detergents and industrial detergents.
- the washing and cleaning agent is also about Hard surface cleaning agents, e.g. Facade, glass, metal, window, Floor and carpet cleaner.
- Hard surface cleaning agents e.g. Facade, glass, metal, window, Floor and carpet cleaner.
- the washing and cleaning agent is also um Hand dishwashing detergents, machine dishwashing detergents, machine dishwashing detergents and Rinse aid.
- the invention also relates to the use of microdispersed, hydrophilic silicate-containing particles having a particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the particles are colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof and additionally at least a hydrophobizing agent, wherein the hydrophobizing agents are silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluoro-compounds as surface-coating agents for soil release and reducing the tendency to re-soak in detergents and cleaners.
- the particles are preferably electrically charged on their surface.
- the silicate-containing particles on the Surface ionically charged.
- the electrical charge is the dirt better detached and the re-soiling more difficult.
- the silicate-containing particles negatively charged.
- silicate-containing particles are colloidal Kleselsole that of the Clariant GmbH as ®Klebosol and from Bayer as ®Baykisol to be expelled. Also particularly suitable are the synthetic Clay mineral hectorite and saponite from Laporte (®Laponite types), Südchemie (®Optigel) and Clariant GmbH (®SKS-20 and ®SKS-21).
- the silicate-containing particles become simultaneously used with hydrophobizing agents, which enhances soiling and reduces the re-pollution propensity.
- Preferred hydrophobizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ®SE36 and ®SE39, the Antifoam ®S850 and the antifoam powders ®ASP 8, ®ASP 15, ®ASP16, ® ASP 20 and ® ASP 30 from Wacker.
- polyorganosiloxanes e.g. polydimethylsiloxanes
- Polysiloxanes, alkyl-modified siloxanes and amino-functional siloxanes particularly preferred ®Fish CT 34 E (silicone softener emulsions of the company Wacker).
- hydrophobizing agents are so-called soil release polymers, for example polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular oligomeric terephthalate esters, polymers of ethylene terephthalates and polyethylene glycol terephthalates or else anionic and / or nonionic derivatives thereof.
- cationic surfactants consisting of mono- (C 8 -C 16 ) -N-alkyl or alkenyl quaternary ammonium salts whose N-positions are occupied by methyl, hydroxymethyl or hydroxypropyl groups. Particularly preferred are distearyldimethylammonium chloride, ditallowdimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride.
- hydrophobizing agents are fluoro compounds, e.g. the company 3M.
- the detergents and cleaners preferably contain from 0.01 to 10% by weight, particularly preferably 0.1 to 5 wt .-% of silicate-containing particles.
- concentrates containing up to 80 wt .-% of silicate-containing particles contain.
- the weight ratio of Water to silicate-containing particles between 10000 to 1 and 1: 4.
- Nonionic surfactants are alkyl alkoxylates, gluconamides and alkylpolyglycosides particularly preferred.
- alkyl alkoxylates are preferably ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol used, wherein the alcohol radical is linear or preferably methyl-branched in the 2-position or linear and methyl branched Contains radicals in the mixture, as is usually the case in Oxoalkoholresten.
- the preferred ethoxylated alcohols include, for example, C 11 alcohols having 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols having 3, 6, 7, 8, 10 and 13 EO units, respectively , (C 14 -C 15 ) -alcohols having 4, 7 or 8 EO units, (C 16 -C 18 ) -alcohols having 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same.
- the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
- it is also possible to use fatty alcohol EO / PO adducts for example the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
- Suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
- alkyl glycosides of the general formula RO (G) x in which R is a primary straight-chain or methyl-branched, in particular 2-methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G is a glycose unit having 5 or 6 carbon atoms, preferably glucose.
- the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
- Suitable anionic surfactants of the sulfonate type are preferably the known (C 9 -C 13 ) -alkylbenzenesulfonates, alpha-olefinsulfonates and alkanesulfonates. Also suitable are esters of sulfo fatty acids or the disalts of the alpha-sulfo fatty acids. Other suitable anionic surfactants are sulfated Fettklareglycerinester which mono-, di- and triesters and mixtures thereof, as in the preparation by esterification by 1 mole of monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Mole of glycerol can be obtained.
- alkyl sulfates are the sulfuric acid monoesters of (C 12 -C 18 ) -fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain portions of unsaturated alcohols, For example, oleyl alcohol may contain.
- anionic surfactants are particularly soaps into consideration. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures.
- the anionic surfactants can be used in Form their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine.
- the anionic surfactants are in the form of their sodium or potassium salts, especially in the form of the sodium salts.
- the buildem are preferably crystalline aluminosilicates, Alkali metal carbonates, alkali ortho, alkali pyro and alkali polyphosphates, crystalline Phyllosilicates, crystalline alkali metal silicates without layer structure and / or X-ray amorphous alkali silicates.
- the co-builders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.
- the bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g., TAED), Bleach catalysts, removal of discoloration, perborates and / or Percarbonates.
- bleach activators e.g., TAED
- Bleach catalysts removal of discoloration, perborates and / or Percarbonates.
- the pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.
- detergents and cleaners may also contain enzymes, such as. Proteases, amylases, lipases and cellulases.
- the detergents and cleaners can be used to treat fiber and fiber Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.
- Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic use in car washes.
- compositions of the agents according to the invention are specified in percent by weight.
- the Gardnertest is a cleaning test for hard surfaces, mainly floors etc ..
- test strips maximal 45cm long and 5-6 cm wide
- the cleaning solution add 10 g of the cleaning solution to the strip and attach a piece of wipe to a holder.
- the cloth is driven by tensioning cables, driven by an eccentric, back and forth on the prepared sample strip.
- the number of swipes is read on a counter.
- the number of wiping movements is evaluated up to the absolute cleanliness, or after a maximum of 50 wiping movements the rating of the cleaning result on the scale of 1 (clean) to 5.
- the rating 50/3 means here that after the maximum number of 50 wipes the matching gave the grade 3 on the scale of 1 to 5.
- the rating 5/1 means here that after only 5 wipes the matching gave the grade 1 (clean) on the scale from 1 to 5.
- Ceramic wall tiles and PVC floor tiles were used as surfaces. As stains were Edding permanent pen, marking pencil and pencil (Graphite) used.
- the stains were:
- the measurements were arithmetically averaged and averaged Scale spread from 0 to 100%.
- Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved.
- Table 1 The Composition and results are shown in Table 1.
- Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water hectorite SKS-21 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.
- Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 and with the cumenesulfonate TexCare SRC-1 dispersion added. This can be in the Gardner test compared to Examples 1 to 3 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
- a tile / bathroom cleaner was made by adding isopropanol and water mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The detergency was tested using the Gardner test. The composition and the results are shown in Table 1.
- Example 5 As in Example 5, a tile / bathroom cleaner was made. It was also with Klebosol 20 H 12 was added to the water. This can be seen in the Gardner test in the Compared to Example 5 an improvement of the cleaning effect can be achieved.
- the composition and the results are shown in Table 1.
- Example 5 As in Example 5, a tile / bathroom cleaner was made. It was also with Add to the water Klebosol 20 H 12 and with the Citric Acid Finish CT 34 E. This can be in the Gardner test compared to Examples 5 and 6 a Improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
- a hand dishwashing detergent was prepared by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed with slow stirring. The Composition is listed in Table 2.
- a window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed with stirring. The composition is in Table 2 listed.
- a window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E while stirring. The composition is in table 2 listed.
- An all-purpose cleaner was made by using Genapol UD 080 with Hostapur SAS 60 was mixed. Then water, Klebosol 30 R 12 and propylene glycol n-butyl ether mixed with stirring. The composition is in Table 2 listed.
- a flow / bath cleaner was made by adding isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed with stirring. The Composition is listed in Table 2.
- a cleaner for car washes was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then, Klebosol became 30 R 12 mixed. The composition is listed in Table 2.
- a desiccant for car washes was made by successively butyldiglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added.
- the Composition is listed in Table 2.
- a machine dishwashing rinse was made by successively Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing tests were dishes with a commercial Rinsed tablet-dishwashing detergent. The rinse aid was the above formulation used. This procedure of cleaning and rinsing was repeated repeated and the dishes are then scrapped. The composition and the Results are listed in Table 3.
- Example 16 As in Example 16, a machine dishwashing rinse aid is prepared. additionally Klebosol 30 H 25 is mixed in. According to the general rule implementation The machine dishwashing tests were dishes twice with a rinsed with commercially available tablet-dishwashing detergent and with the rinse aid treated. The use of silica sol gives clear advantages for the Cleaning effect. The composition and the results are in Table 3 listed.
- Example 19 The composition is listed in Table 4.
- a liquid detergent is prepared by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes.
- the composition is listed in Table 4.
- a powder detergent is prepared by adding in a Ploughshare mixer Fa. Lödige Antifoam, phyllosilicate, soda, Sokalan CP5 and Zeolite A and Genapol 3070 sprayed on. The remaining components are mixed in for a short time. The composition is listed in Table 4.
- a fabric softener is prepared by stirring at 50 to 60 ° C First Lapnite RD and then Praepagen WK are dissolved in water.
- the Composition is listed in Table 4.
- a fabric softener is prepared by dissolving molten triethanolamine diesterquat (85%) in preheated water at 50 ° C, then stirring Genapol UD 088 and cooling the solution. Finally, TexCare SRC-1 dispersion and Klebosol 30 V 50 are stirred in.
- Genagen CAB 818 10 Genamin LAP 100 D 2 Genapol LRO liquid 0.5 0.5 Genapol O 020 5 Genapol DU 080 3 9 0.5 Genapol DU 110 10 Genapol DU 50 3 Genapol X 080 2 Genapol ZRO liquid 22.9 Hoechst wax KST 4 Hordaphos CC MS 1 Hostapur SAS 60 42.7 8.3 3 isopropanol 29 29 3 Praepagen 4317 10 Praepagen WKT 11 Propylene glycol n-butyl ether 3 spindle oil 6 water 19.4 69 68 75.7 88.5 86 59.2 57 Klebosol 30 R 12 2 2 1 5 Klebosol 30 H 25 1 5 Klebosol 30 N 12 1 1 Finish CT 34 E 1 dosage 1: 1000 1: 1000 1: 500 example 16 17 Components [%] See citric acid 3 3 Cumene sulphonate, 40% 8th 8th Genapol 2908 14 14 water 75 74 Klebosol 30 H 25
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Claims (12)
- Produit de lavage et de nettoyage contenant des particules silicatées hydrophiles microdispersées, ayant une granulométrie de 1 à 500 nm, de préférence de 9 à 50 nm, les particules étant des gels de silice colloïdaie, des sols de silice colloïdale, des hectorites, des saponites ou des mélanges de ceux-ci, et contenant en plus au moins un agent d'hydrophobisation, les agents d'hydrophobisation étant des silicones, des huiles de silicone, des huiles de fluorosilicone, des polymères anti-tache, des tensio-actifs cationiques et/ou des composés organiques du fluor.
- Produit de lavage et de nettoyage selon la revendication 1, caractérisé en ce que les particules sont chargées électriquement sur leur surface.
- Produit de lavage et de nettoyage selon la revendication 1 et/ou 2, caractérisé en ce que le rapport pondéral des particules silicatées aux agents d'hydrophabisation va de 100 sur 1 à 1 sur 100 par rapport à la substance active.
- Produit de lavage et de nettoyage selon l'une ou plusieurs des revendications 1 à 3, caractérisé en ce qu'il contient 0,01% à 10% en poids de particules silicatées, 0,01% à 10% en poids d'agents d'hydrophobisation et 80% à 99,8% en poids d'autres ingrédients de produits de lavage et de nettoyage.
- Produit de lavage et de nettoyage selon l'une ou plusieurs des revendications 1 à 3, caractérisé en ce qu'il contient 0,01% à 10% en poids de particules silicatées, 0,01% à 10% en poids d'agents d'hydrophobisation, 0,5% à 60% en poids de tensio-actifs et 20% à 99,48% en poids d'autres ingrédients de produits de lavage et de nettoyage.
- Produit de lavage et de nettoyage selon l'une ou plusieurs des revendications 1 à 3, caractérisé en ce qu'il contient 0,01% à 10% en poids de particules silicatées, 0,5% à 60% en poids de tensio-actifs et 30% à 99,49% en poids d'autres ingrédients de produits de lavage et de nettoyage.
- Produit de lavage et de nettoyage selon l'une ou plusieurs des revendications 1 à 6, caractérisé en ce qu'il contient en outre des adjuvants, des co-adjuvants, des agents basifiants, des tensio-actifs anioniques, non ioniques, zwitterioniques et non ioniques, des agents antimousse, des agents dispersants, des agents complexants, des agents de blanchiment, des activateurs de blanchiment et des catalyseurs de blanchiment et/ou des enzymes.
- Produit de lavage et de nettoyage selon l'une ou plusieurs des revendications 1 à 7, caractérisé en ce qu'il s'agit d'un détergent toute température, d'un détergent toute température compact, d'un détergent compact pour textiles de couleur, d'un détergent toute température de faible masse volumique apparente, d'un détergent spécial tel qu'un détergent de finissage, un assouplissant, un sel détachant, un blanchisseur, un détergent pour rideaux, un détergent pour laine, un détergent modulaire et un détergent industriel.
- Produit de lavage et de nettoyage selon l'une ou plusieurs des revendications 1 à 7, caractérisé en ce qu'il s'agit d'un produit de nettoyage de surfaces dures, par exemple d'un produit nettoyant pour façades, verre, métal, fenêtres, sols et tapis.
- Produit de lavage et de nettoyage selon la revendication 9, caractérisé en ce qu'il s'agit d'un liquide pour vaisselle à la main, d'un produit pour vaisselle en machine, d'un liquide pour vaisselle en machine et d'un liquide de rinçage.
- Utilisation de particules silicatées hydrophiles microdispersées ayant une granulométrie de 1 à 500 nm, de préférence de 9 à 50 nm, les particules étant des gels de silice colloïdale, des sols de silice colloïdale, des hectorites, des saponites ou des mélanges de ceux-ci, et contenant en plus au moins un agent d'hydrophobisation, les agents d'hydrophobisation étant des silicones, des huiles de silicone, des huiles de fluorosilicone, des polymères anti-tache, des tensio-actifs cationiques et/ou des composés organiques du fluor, en tant que revêtement de surface pour le détachage et pour diminuer la tendance au salissement, dans des produits de lavage et de nettoyage.
- Utilisation selon la revendication 11, caractérisée en ce que les particules sont chargées électriquement sur leur surface.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10061897 | 2000-12-12 | ||
DE10061897A DE10061897A1 (de) | 2000-12-12 | 2000-12-12 | Wasch- und Reinigungsmittel, enthaltend mikrodisperse silikathaltige Partikel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1215276A1 EP1215276A1 (fr) | 2002-06-19 |
EP1215276B1 true EP1215276B1 (fr) | 2005-08-03 |
Family
ID=7666852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01128892A Revoked EP1215276B1 (fr) | 2000-12-12 | 2001-12-05 | Compositions détergentes contenant des particules microdispersées en silicates |
Country Status (4)
Country | Link |
---|---|
US (1) | US6784149B2 (fr) |
EP (1) | EP1215276B1 (fr) |
JP (1) | JP2002285194A (fr) |
DE (2) | DE10061897A1 (fr) |
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CA2431925C (fr) | 2001-01-30 | 2009-01-27 | The Procter & Gamble Company | Compositions de revetement de surfaces facilitant le rincage et servant a modifier la surface d'articles de vaisselle |
US6764988B2 (en) | 2001-04-18 | 2004-07-20 | Kimberly-Clark Worldwide, Inc. | Skin cleansing composition incorporating anionic particles |
US6596682B1 (en) * | 2002-04-16 | 2003-07-22 | Colgate-Palmolive Company | Cleaning compositions in the form of a tablet |
DE50210858D1 (de) * | 2002-11-02 | 2007-10-18 | Dalli Werke Gmbh & Co Kg | Wasserlösliche Builder von bestimmter Korngrösse in Wasch-und Reinigungsmitteln |
DE10258831A1 (de) * | 2002-12-17 | 2004-07-08 | Henkel Kgaa | Reinigungsmittel für harte Oberflächen |
ATE471365T1 (de) * | 2004-04-08 | 2010-07-15 | Akzo Nobel Nv | Waschmittel |
US8361946B2 (en) * | 2004-04-08 | 2013-01-29 | Akzo Nobel N.V. | Detergent composition |
DE102004019022A1 (de) * | 2004-04-16 | 2005-11-17 | Henkel Kgaa | Hydrophillierender Reiniger für harte Oberflächen |
DE102004046495B4 (de) * | 2004-09-23 | 2009-04-09 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Aerogel-enthaltener Verbundwerkstoff und Verfahren zu dessen Herstellung |
EP1866401B1 (fr) * | 2005-03-30 | 2010-09-29 | Basf Se | Utilisation d'hydrophobines pour le traitement antisalissant de surfaces dures |
WO2006103230A1 (fr) * | 2005-03-30 | 2006-10-05 | Basf Aktiengesellschaft | Utilisation d'hydrophobines pour traiter la surface de materiaux de construction mineraux durcis, de pierre naturelle, de pierre artificielle et de ceramiques |
US20060269441A1 (en) * | 2005-05-25 | 2006-11-30 | Ochomogo Maria G | Nanosilica-based food contact sanitizer |
US20060281807A1 (en) * | 2005-06-13 | 2006-12-14 | Tapestry Pharmaceuticals, Inc. | Quassinoid compositions for the treatment of cancer and other proliferative diseases |
WO2007054126A1 (fr) | 2005-11-09 | 2007-05-18 | Ecolab Inc. | Composition ayant des proprietes de modification de surface |
US7655609B2 (en) * | 2005-12-12 | 2010-02-02 | Milliken & Company | Soil release agent |
US20070131892A1 (en) * | 2005-12-12 | 2007-06-14 | Valenti Dominick J | Stain repellant and release fabric conditioner |
US20070130694A1 (en) * | 2005-12-12 | 2007-06-14 | Michaels Emily W | Textile surface modification composition |
US20070199157A1 (en) * | 2006-02-28 | 2007-08-30 | Eduardo Torres | Fabric conditioner enhancing agent and emulsion and dispersant stabilizer |
EP2045315A1 (fr) * | 2007-09-24 | 2009-04-08 | The Procter and Gamble Company | Procédé pour laver la vaisselle |
EP2045316A1 (fr) * | 2007-09-24 | 2009-04-08 | The Procter and Gamble Company | Particule détergente |
JP2009191128A (ja) * | 2008-02-13 | 2009-08-27 | Lion Corp | 液体洗浄剤組成物 |
EP2326436A2 (fr) * | 2008-05-06 | 2011-06-01 | Andrew Armstrong | Méthode pour nettoyage et vitrification d' une surface dure pour améliorer sa qualité |
KR101891228B1 (ko) * | 2010-12-16 | 2018-09-28 | 아크조 노벨 케미칼즈 인터내셔널 비.브이. | 낮은 스트리크 탈지 조성물 |
WO2013004302A1 (fr) * | 2011-07-05 | 2013-01-10 | Ecolab Inc. | Nettoyant acide pour le marbre |
US20140023814A1 (en) * | 2011-12-28 | 2014-01-23 | Frank M. Fosco, JR. | Potable water containers having surfaces including heat labile component/carrier combinations and methods for their preparation |
ITMI20130782A1 (it) | 2013-05-13 | 2014-11-14 | Fra Ber S R L | Prodotti per autolavaggi a base enzimatica |
DE102014213311A1 (de) * | 2014-07-09 | 2016-01-14 | Henkel Ag & Co. Kgaa | Neuartiges Waschverfahren mit elektrochemisch aktivierbarer Mediatorverbindung |
DE102015203041B4 (de) * | 2015-02-20 | 2022-02-10 | Thomas Lutgen | Verfahren sowie Gel zum Herauslösen von Schmutzpartikeln aus Poren einer Oberfläche |
CN106047507A (zh) * | 2016-05-31 | 2016-10-26 | 太仓协大申泰羊毛衫有限公司 | 一种含有植物凝胶的羊毛衫洗涤液 |
GB2581142A (en) * | 2019-01-23 | 2020-08-12 | Linkage Tech Switzerland Sa | Compositions and their use |
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GB9414572D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Soap composition |
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DE19726814A1 (de) | 1997-06-25 | 1999-01-07 | Murjahn Amphibolin Werke | Beschichtungsmittel zur Verringerung der Anschmutzneigung von Fassaden |
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DE19854960A1 (de) * | 1998-11-29 | 2000-05-31 | Clariant Gmbh | Maschinengeschirrspülmittel |
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DE19952383A1 (de) * | 1999-10-30 | 2001-05-17 | Henkel Kgaa | Wasch- und Reinigungsmittel |
DE10021726A1 (de) * | 2000-05-04 | 2001-11-15 | Henkel Kgaa | Verwendung von nanoskaligen Teilchen zur Verbesserung der Schmutzablösung |
US20020028288A1 (en) * | 2000-06-14 | 2002-03-07 | The Procter & Gamble Company | Long lasting coatings for modifying hard surfaces and processes for applying the same |
-
2000
- 2000-12-12 DE DE10061897A patent/DE10061897A1/de not_active Withdrawn
-
2001
- 2001-09-28 JP JP2001301439A patent/JP2002285194A/ja not_active Withdrawn
- 2001-12-05 EP EP01128892A patent/EP1215276B1/fr not_active Revoked
- 2001-12-05 DE DE50106965T patent/DE50106965D1/de not_active Revoked
- 2001-12-12 US US10/021,596 patent/US6784149B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2002285194A (ja) | 2002-10-03 |
EP1215276A1 (fr) | 2002-06-19 |
DE50106965D1 (de) | 2005-09-08 |
US20020111287A1 (en) | 2002-08-15 |
US6784149B2 (en) | 2004-08-31 |
DE10061897A1 (de) | 2002-06-13 |
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