EP1180128A1 - Produit de lavage de voiture - Google Patents

Produit de lavage de voiture

Info

Publication number
EP1180128A1
EP1180128A1 EP00932659A EP00932659A EP1180128A1 EP 1180128 A1 EP1180128 A1 EP 1180128A1 EP 00932659 A EP00932659 A EP 00932659A EP 00932659 A EP00932659 A EP 00932659A EP 1180128 A1 EP1180128 A1 EP 1180128A1
Authority
EP
European Patent Office
Prior art keywords
vehicle
composition
cleaning
water
anionic surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00932659A
Other languages
German (de)
English (en)
Other versions
EP1180128B1 (fr
Inventor
Richard E. Rudin
Robert H. Lohr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SC Johnson and Son Inc
Original Assignee
SC Johnson and Son Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SC Johnson and Son Inc filed Critical SC Johnson and Son Inc
Publication of EP1180128A1 publication Critical patent/EP1180128A1/fr
Application granted granted Critical
Publication of EP1180128B1 publication Critical patent/EP1180128B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2072Aldehydes-ketones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/42Amino alcohols or amino ethers
    • C11D1/44Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/722Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to vehicle cleaners which do not require hand drying. More particularly, it relates to car wash cleaners which permit rinse water to readily sheet off the vehicle during the rinsing process, yet which do not adversely affect beading properties after the car has dried .
  • a rinae aid which improves sheeting during the car wash process, but also destroys the ability of car wax to cause beading is a commercially unacceptable additive (as consumers would believe that the cleaner had destroyed the wax job) .
  • the invention provides a composition for cleaning a vehicle containing a copolymer of ethylene oxide and propylene oxide, anionic surfactant and water.
  • the copolymer is selected from the group consisting of:
  • the copolymer can be selected from the group consisting of: CH 3 CH 3 H-(OCH 2 CH 2 )y"-(OCHCH 2 ) x - ⁇ ⁇ CHzCHO ⁇ — (CH 2 CH 2 0) y — H — CH 2 -CH 2 -N
  • each of x, x' , x " , x "' , y, y' , y " , and y '" is 2-500.
  • Overall molecular weights of the copolymers are preferably between 1,000 and 50,000, with total EO and total PO units each preferably under 150 (even more preferably each under 50) .
  • compositions contain at least 50% water, between 0.5% and 8% block copolymer, and 20% to 45% anionic surfactant.
  • the preferred anionic surfactants are sulfates, sulfonates, and mixtures thereof, especially sodium dodecylbenzene sulfonate, sodium laureth sulfate and mixtures thereof .
  • the compositions can also contain a preservative such as formaldehyde, and other ingredients such as dyes, fragrances, other rinse aids, and fillers.
  • the composition can be applied in concentrated form to deal with particularly soiled areas, diluted with water in a bucket and directly applied with a sponge or the like, or diluted with water and sprayed onto a vehicle.
  • the invention provides methods for cleaning the surface of a vehicle by applying the above compositions to the vehicle, followed by rinsing with water.
  • the vehicle can then air dry (either from a stationary position, or while moving) .
  • a variety of the copolymers within the block copolymer formulae of claim 2 are sold by BASF under the trade designation Pluronics * .
  • a variety of the copolymers within the "block" copolymer formulae of claim 10 are sold by BASF under the trade designation Tetronics ⁇ .
  • the most preferred surfactants are alkali metal sulfate or sulfonate surfactants such as sodium dodecylbenzene sulfonate (SDS) and sodium laureth sulfate (SLES) .
  • SDS sodium dodecylbenzene sulfonate
  • SLES sodium laureth sulfate
  • they are sold as BIO SOFT D40 and Steal CS-230 from Stepan Chemical Co. They are preferably employed with the SDS in a major amount of about 30% to about 35% by weight and the SLES in a minor amount of about 3% to about 5% by weight .
  • anionic surfactants can be used such as sodium alkyl aryl ethoxy sulfates, sodium lauryl sulfate, sodium linear alkylate sulfonates, disodium sulfosuccinate , and diammonium lauryl sulfosuccinate .
  • other types of surfactants may be used in minor amounts.
  • a preservative e.g. formaldehyde
  • preservatives include anti-microbials such as Kathon (Rohm & Haas) , Dowicil (Dow Chemical) , and Canguard (Angus Chemical) .
  • Water is preferably 50% to 70% of a concentrated form of the composition.
  • the compositions can be diluted with water (e.g. one part of the concentrated composition diluted with 60-175 parts of water, or even more) . As noted above with respect to the spot use of the concentrated formula, no such dilution is required. However, absent such dilution the cost of washing an entire vehicle using the concentrate could be quite expensive.
  • the cleaners of the present invention can be used to wash vehicles such as automobiles, vans and trucks from a bucket.
  • the cleaners can be applied by hand (e.g. via a rag, pad or sponge) and subsequently rinsed off with a hose.
  • the cleaner can be sprayed onto the vehicles in more diluted form using an automated sprayer, and then rinsed off using an automated rinsing system. In either case, the vehicles dry by evaporation.
  • the objects of the present invention therefore include providing cleaners of the above kind:
  • EXAMPLE 1 EXAMPLE 2 Ingredient % wt . % wt .
  • the present invention provides chemicals that are particularly useful for cleaning vehicle exteriors, and methods of using these cleaners.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Vehicle Cleaning, Maintenance, Repair, Refitting, And Outriggers (AREA)
EP00932659A 1999-05-24 2000-05-19 Produit de lavage de voiture Expired - Lifetime EP1180128B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US31750899A 1999-05-24 1999-05-24
US317508 1999-05-24
PCT/US2000/013925 WO2000071655A1 (fr) 1999-05-24 2000-05-19 Produit de lavage de voiture

Publications (2)

Publication Number Publication Date
EP1180128A1 true EP1180128A1 (fr) 2002-02-20
EP1180128B1 EP1180128B1 (fr) 2005-12-07

Family

ID=23233978

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00932659A Expired - Lifetime EP1180128B1 (fr) 1999-05-24 2000-05-19 Produit de lavage de voiture

Country Status (10)

Country Link
EP (1) EP1180128B1 (fr)
JP (1) JP2003500524A (fr)
AT (1) ATE312153T1 (fr)
BR (1) BR0010894A (fr)
CA (1) CA2374488A1 (fr)
DE (1) DE60024614T2 (fr)
ES (1) ES2252007T3 (fr)
MX (1) MXPA01012081A (fr)
WO (1) WO2000071655A1 (fr)
ZA (1) ZA200109697B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7318871B2 (en) 2004-06-16 2008-01-15 The Clorox Company Vehicular cleaning concentrate
US10907118B2 (en) * 2018-12-21 2021-02-02 Henkel IP & Holding GmbH Use of ethyleneoxy and propyleneoxy copolymer to control rheology of unit dose detergent pack

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4595526A (en) * 1984-09-28 1986-06-17 Colgate-Palmolive Company High foaming nonionic surfacant based liquid detergent
JPH07119440B2 (ja) * 1991-02-25 1995-12-20 日華化学株式会社 自動車用洗浄剤組成物
US5250230A (en) * 1991-12-20 1993-10-05 Henkel Corporation Composition and process for cleaning metals
US5871590A (en) * 1997-02-25 1999-02-16 Ecolab Inc. Vehicle cleaning and drying compositions
PL336844A1 (en) * 1997-05-16 2000-07-17 Procter & Gamble Liquid or jelly washing compositions of adjustable ph and desirable foam-forming and food residue removing properties for washing up dishes under low-load conditions
US6133217A (en) * 1998-08-28 2000-10-17 Huntsman Petrochemical Corporation Solubilization of low 2-phenyl alkylbenzene sulfonates

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0071655A1 *

Also Published As

Publication number Publication date
ZA200109697B (en) 2002-11-26
CA2374488A1 (fr) 2000-11-30
JP2003500524A (ja) 2003-01-07
WO2000071655A1 (fr) 2000-11-30
ES2252007T3 (es) 2006-05-16
EP1180128B1 (fr) 2005-12-07
ATE312153T1 (de) 2005-12-15
BR0010894A (pt) 2002-03-05
DE60024614D1 (de) 2006-01-12
MXPA01012081A (es) 2002-06-04
DE60024614T2 (de) 2006-07-20

Similar Documents

Publication Publication Date Title
AU756776B2 (en) Compositions and process for cleaning and finishing hard surfaces
US5759980A (en) Car wash
EP1565543B1 (fr) Composition de nettoyage agissant sur la durete de l'eau et procedes de fabrication et d'utilisation de cette composition
EP0804536B1 (fr) Compositions pour nettoyer le verre
US5534167A (en) Carpet cleaning and restoring composition
US4343725A (en) Cleansers for windows, mirrors and reflecting surfaces containing a high molecular weight polyoxyethylene glycol polymer
KR100221768B1 (ko) 중합체를 포함하는 경질 표면 세정 조성물
US7119053B2 (en) Wheel and tire cleaner composition comprising an ethoxylated quaternary ammonium surfactant
AU724432B2 (en) Rinseable hard surface cleaner
US6867174B2 (en) Non-foaming cleaning compositions and a method for their use
US20050250661A1 (en) Cleaning composition and cleaning of vehicles
JPH11116988A (ja) 自動車用洗浄剤組成物
EP1180128B1 (fr) Produit de lavage de voiture
US20070129275A1 (en) Bucketless Carwash Composition
JP3255637B1 (ja) 液体洗浄剤組成物
CN106635470A (zh) 车身表面免水清洁去污防污保护喷剂及其制备方法
JPH07119440B2 (ja) 自動車用洗浄剤組成物
JPH03232000A (ja) 自動車用洗浄剤
JP2002531687A (ja) 硬質表面洗浄用組成物
JPH11264000A (ja) 自動車タイヤ用クリーナー兼つや出し剤
JPS63309596A (ja) 液体硬表面洗浄剤組成物
CA2888770C (fr) Composition de nettoyage
CN112342091A (zh) 一种汽车清洁剂及其制备方法
JPH10265768A (ja) プラスチックコンテナ用ホコリ付着防止剤組成物およびこれを使用したプラスチックコンテナのすすぎ処理方法
JPH03139600A (ja) 塗装面用の洗浄剤

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20011205

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

17Q First examination report despatched

Effective date: 20030929

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

Ref country code: CH

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 60024614

Country of ref document: DE

Date of ref document: 20060112

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060307

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060307

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060307

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060508

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2252007

Country of ref document: ES

Kind code of ref document: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060519

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20060525

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20060526

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060531

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20060531

Year of fee payment: 7

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20060630

Year of fee payment: 7

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20060908

EN Fr: translation not filed
REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20070519

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070126

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070519

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060519

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20070521

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070521

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

Ref country code: FR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20051207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070519