EP1174524B1 - Couche superficielle pour la formation d'une surface de marche sur une paroi cylindrique, poudre à pulvériser pour cet usage et procédé de production de cette couche - Google Patents
Couche superficielle pour la formation d'une surface de marche sur une paroi cylindrique, poudre à pulvériser pour cet usage et procédé de production de cette couche Download PDFInfo
- Publication number
- EP1174524B1 EP1174524B1 EP01810455.4A EP01810455A EP1174524B1 EP 1174524 B1 EP1174524 B1 EP 1174524B1 EP 01810455 A EP01810455 A EP 01810455A EP 1174524 B1 EP1174524 B1 EP 1174524B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- surface layer
- spraying powder
- difference
- following composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/14—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying for coating elongate material
- C23C4/16—Wires; Tubes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12063—Nonparticulate metal component
Definitions
- the invention relates to a formed according to the preamble of claim 1 surface layer for forming a tread on a cylinder wall, a defined in the preamble of claim 6 spray powder for producing the surface layer and a circumscribed in the preamble of claim 11 method for producing such surface layers.
- machinability of such plasma spray coatings can be significantly increased by adding solid lubricants, for example by adding hexagonal boron nitride BN, MoS 2 or WS 2 .
- solid lubricants for example by adding hexagonal boron nitride BN, MoS 2 or WS 2 .
- Boron nitride and the abovementioned sulfides are difficult to incorporate into the layers because they react with the oxygen in the air or are decomposed by the high temperature of the plasma. They have to be protected by expensive cladding.
- Insert sleeves for cylinder surfaces known, which consist of supereutectic aluminum / silicon alloys.
- the insert bushing is subjected to mechanical machining after insertion into the engine block, by first rough and then finely working its surface. In a final processing phase, the surface is honed. After honing are those particles that are harder than the microstructure of the base alloy, namely Silicone crystals and intermetallic phases, slightly above the actual surface. These exposed particles should improve the wear resistance.
- the object of the invention is to propose a surface layer for forming a tread on a cylinder wall according to the preamble of claim 1, which can be easily applied to the cylinder wall and significantly better machinable without the other important functions of the coating material be negatively influenced.
- the wear resistance and the low coefficient of friction should be maintained or even improved with respect to the piston ring materials coming into contact with the surface layer.
- the separate phases of constituent surface layer for forming a tread on a cylinder wall by plasma spraying of an iron-containing spray powder is generated, which contains all components of the surface layer to be generated.
- the surface layer can either be applied directly to the cylinder wall or to an insert bush, which is used to form the running surface in the cylinder bore.
- preferred additives are chromium, manganese, sulfur and carbon. Suitable are e.g. but also bismuth, lead, tellurium and selenium. The substances mentioned can be added in elemental form or in the form of compounds.
- the sprayed coatings produced have the same composition as the spray powders used.
- claim 6 is also a spray powder for the production of surface layers according to claim 1 and in claim 11, a method for the production of surface layers proposed according to claim 1.
- Preferred compositions of the molding powder are defined in claims 7 to 10 while a preferred embodiment of the method of producing the surface layers is defined in claim 18.
- the wettable powders advantageously have a particle size of from 5 to 60 .mu.m, preferably from 10 to 45 .mu.m.
- the layers thus produced are corrosion resistant to sulfuric and formic acids, i. Condensates that can form in internal combustion engines.
- the proposed surface layers and the proposed powders are particularly suitable for direct application to the cylinder wall of engine blocks, in particular engine blocks made of light metal.
- the spray powder is preferably applied by means of a plasma spraying device with a rotating plasmatron.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
Claims (12)
- Couche de surface supérieure pour former une bande de roulement sur une paroi de cylindre, dans laquelle la couche de surface supérieure comprend des phases séparées de composants, qui sont séparées par la ou les phases des autres matériaux de surface supérieure, caractérisée en ce que la couche de surface supérieure est produite par projection au plasma d'une poudre de pulvérisation contenant du fer qui contient tous les composants de la couche de surface supérieure à produire, et en ce que la couche de surface supérieure présente la composition suivante :Fe = différence par rapport à 100 % en poids Cr = 0,1 à 18,0 % en poidsMn = 0,1 à 6,0 % en poidsS = 0,01 à 0,5 % en poidsC = 0,1 à 1,2 % en poids.et présente un ou plusieurs des composants suivants :As = 0,001 à 0,1 % en poidsTe = 0,001 à 0,1 % en poidsSe = 0,001 à 0,1 % en poidsSb = 0,001 à 0,1 % en poidsBi = 0,001 à 0,1 % en poidsouPb = 0,01 à 0,5 % en poids.
- Couche de surface supérieure selon la revendication 1, caractérisée en ce qu'elle est appliquée directement sur la paroi de cylindre.
- Couche de surface supérieure selon la revendication 1, caractérisée en ce qu'elle est appliquée par une douille d'insertion destinée à être mise en place ou insérée dans l'alésage de cylindre.
- Couche de surface supérieure selon l'une quelconque des revendications 1 à 3, caractérisée en ce qu'elle présente la composition suivante :Fe = différence par rapport à 100 % en poidsCr = 0,1 à 3,0 % en poidsMn = 0,3 à 1,5 % en poidsS = 0,05 à 0,3 % en poidsC = 0,8 à 1,2 % en poids.
- Couche de surface supérieure selon l'une quelconque des revendications 1 à 3, caractérisée en ce que la couche de surface est résistante à la corrosion par l'acide sulfurique et l'acide formique, et présente la composition suivante :Fe = différence par rapport à 100 % en poidsCr = 12,0 à 15,0 % en poidsMn = 0,3 à 1,5 % en poidsS = 0,05 à 0,3 % en poidsC = de 0,35 à 0,6 % en poids.
- Poudre de pulvérisation pour la production de revêtements de surface selon la revendication 1, caractérisée en ce que la poudre de pulvérisation contient tous les composants de la couche à produire, et présente la composition suivante :Fe = différence par rapport à 100 % en poidsCr = 0,1 à 18,0 % en poidsMn = 0,1 à 6,0 % en poidsS = 0,01 à 0,5 % en poidsC = 0,1 à 1,2 % en poids.et présente un ou plusieurs des composants suivants :As = 0,001 à 0,1 % en poidsTe = 0,001 à 0,1 % en poidsSe = 0,001 à 0,1 % en poidsSb = 0,001 à 0,1 % en poidsBi = 0,001 à 0,1 % en poidsouPb = 0,01 à 0,5 % en poids.
- Poudre de pulvérisation selon la revendication 6, caractérisée en ce qu'elle présente la composition suivante :Fe = différence par rapport à 100 % en poidsCr = 0,1 à 3,0 % en poidsMn = 0,3 à 1,5 % en poidsS = 0,05 à 0,3 % en poidsC = 0,8 à 1,2 % en poids.
- Poudre de pulvérisation selon la revendication 6 pour la production de couches de surface supérieure, qui sont résistantes à la corrosion par l'acide sulfurique et l'acide formique, caractérisée en ce qu'elle présente la composition suivante :Fe = différence par rapport à 100 % en poidsCr = 12,0 à 15,0 % en poidsMn = 0,3 à 1,5 % en poidsS = 0,05 à 0,3 % en poidsC = de 0,35 à 0,6 % en poids.
- Poudre de pulvérisation selon la revendication 6, caractérisée en ce qu'elle présente une taille de particule de 5 à 60 microns.
- Poudre de pulvérisation selon la revendication 9, caractérisée en ce qu'elle présente une taille de particule de 10 à 45 microns.
- Procédé pour la production de couches de surface supérieure selon la revendication 1, caractérisé en ce que la poudre de pulvérisation est appliquée au moyen d'un plasmatron rotatif.
- Procédé selon la revendication 11, caractérisé en ce que la poudre de pulvérisation est vaporisée à l'état gazeux.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH11742000 | 2000-06-14 | ||
CH01174/00A CH694664A5 (de) | 2000-06-14 | 2000-06-14 | Durch Plasmaspritzen eines Spritzpulvers aufgebrachte eisenhaltige Schicht auf einer Zylinderlauffläche. |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1174524A2 EP1174524A2 (fr) | 2002-01-23 |
EP1174524A3 EP1174524A3 (fr) | 2009-03-11 |
EP1174524B1 true EP1174524B1 (fr) | 2016-12-21 |
Family
ID=4561420
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01810455.4A Expired - Lifetime EP1174524B1 (fr) | 2000-06-14 | 2001-05-10 | Couche superficielle pour la formation d'une surface de marche sur une paroi cylindrique, poudre à pulvériser pour cet usage et procédé de production de cette couche |
Country Status (8)
Country | Link |
---|---|
US (1) | US6578539B2 (fr) |
EP (1) | EP1174524B1 (fr) |
JP (2) | JP2002047550A (fr) |
KR (1) | KR100596124B1 (fr) |
CA (1) | CA2347980C (fr) |
CH (1) | CH694664A5 (fr) |
ES (1) | ES2619929T3 (fr) |
PT (1) | PT1174524T (fr) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH695339A5 (de) | 2002-02-27 | 2006-04-13 | Sulzer Metco Ag | Zylinderlaufflächenschicht für Verbrennungsmotoren sowie Verfahren zu deren Herstellung. |
DE10324279B4 (de) * | 2003-05-28 | 2006-04-06 | Daimlerchrysler Ag | Verwendung von FeC-Legierung zur Erneuerung der Oberfläche von Zylinderlaufbuchsen |
JP2005307857A (ja) * | 2004-04-21 | 2005-11-04 | Toyota Motor Corp | シリンダブロック及びその製造方法 |
US7487840B2 (en) * | 2004-11-12 | 2009-02-10 | Wear Sox, L.P. | Wear resistant layer for downhole well equipment |
WO2007135683A2 (fr) * | 2006-05-23 | 2007-11-29 | Perspective D.S.S Ltd. | Système et procédé de gestion de crédit |
KR100878878B1 (ko) * | 2007-06-14 | 2009-01-15 | 주식회사뉴테크 | 용사기술을 이용한 엔진블록 라이너외벽 코팅 방법 |
JP2012509406A (ja) * | 2008-11-20 | 2012-04-19 | ボルボ エアロ コーポレイション | 排気口をコーティングする方法、並びに該方法を実施する装置 |
US8863834B2 (en) | 2009-04-07 | 2014-10-21 | Antelope Oil Tool & Mfg. Co., Llc | Friction reducing wear band and method of coupling a wear band to a tubular |
DE102010021300B4 (de) * | 2010-05-22 | 2012-03-22 | Daimler Ag | Drahtförmiger Spritzwerkstoff, damit erzeugbare Funktionsschicht und Verfahren zum Beschichten eines Substrats mit einem Spritzwerkstoff |
FR2974610B1 (fr) * | 2011-04-26 | 2013-05-17 | Peugeot Citroen Automobiles Sa | Procede de realisation des surfaces de chambres a combustion d'un bloc moteur en alliage d'aluminium |
DE102012015405B4 (de) * | 2012-08-03 | 2014-07-03 | Federal-Mogul Burscheid Gmbh | Zylinderlaufbuchse und Verfahren zu deren Herstellung |
EP2829713B1 (fr) | 2013-07-26 | 2018-11-07 | Sulzer Metco AG | Pièce usinée dotée d'un évidement pour la réception d'un piston |
EP3039168B1 (fr) | 2013-08-28 | 2018-10-24 | Antelope Oil Tool & Mfg. Co., LLC | Composition de projection thermique exempt de chrome, procédé et appareil |
JP7437607B2 (ja) | 2020-03-26 | 2024-02-26 | 日産自動車株式会社 | 溶射被膜及び溶射材 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4251599A (en) * | 1979-08-23 | 1981-02-17 | Ramsey Corporation | Ferrous metal body coated with an alloy formed by an iron/silicon extended molybdenum plasma spray powder |
JPS59180989A (ja) * | 1983-03-30 | 1984-10-15 | 新日本製鐵株式会社 | プラズマア−ク加熱装置 |
JPS6257755A (ja) * | 1985-08-07 | 1987-03-13 | Honda Motor Co Ltd | 軽合金製シリンダブロツク素材の鋳造方法 |
US4741974A (en) * | 1986-05-20 | 1988-05-03 | The Perkin-Elmer Corporation | Composite wire for wear resistant coatings |
US5334235A (en) * | 1993-01-22 | 1994-08-02 | The Perkin-Elmer Corporation | Thermal spray method for coating cylinder bores for internal combustion engines |
US5332422A (en) * | 1993-07-06 | 1994-07-26 | Ford Motor Company | Solid lubricant and hardenable steel coating system |
JPH07243528A (ja) * | 1994-03-02 | 1995-09-19 | Teikoku Piston Ring Co Ltd | 摺動部材の組合せ |
US5466906A (en) * | 1994-04-08 | 1995-11-14 | Ford Motor Company | Process for coating automotive engine cylinders |
GB2297053B (en) * | 1994-10-28 | 1996-11-06 | Daimler Benz Ag | Cylinder liner for a reciprocating piston engine and method of producing such a cylinder liner |
US5671532A (en) * | 1994-12-09 | 1997-09-30 | Ford Global Technologies, Inc. | Method of making an engine block using coated cylinder bore liners |
US5766693A (en) * | 1995-10-06 | 1998-06-16 | Ford Global Technologies, Inc. | Method of depositing composite metal coatings containing low friction oxides |
US5736200A (en) * | 1996-05-31 | 1998-04-07 | Caterpillar Inc. | Process for reducing oxygen content in thermally sprayed metal coatings |
US5958521A (en) * | 1996-06-21 | 1999-09-28 | Ford Global Technologies, Inc. | Method of depositing a thermally sprayed coating that is graded between being machinable and being wear resistant |
GB2320033B (en) * | 1996-12-05 | 2001-06-06 | Fmc Corp | Improvements in strength and wear resistance of mechanical components |
JP3173452B2 (ja) * | 1997-02-28 | 2001-06-04 | 株式会社豊田中央研究所 | 耐摩耗性被覆部材及びその製造方法 |
JPH11247712A (ja) * | 1998-02-27 | 1999-09-14 | Aisin Seiki Co Ltd | エンジン用ピストン |
EP1133580B1 (fr) * | 1998-11-25 | 2003-05-02 | Joma Chemical AS | Procede pour produire une couche anticorrosion et anti-usure par metallisation a chaud |
EP1507020B1 (fr) | 1999-01-19 | 2007-06-27 | Sulzer Metco AG | Couche déposée par jet de plasma sur des alésages de cylindres de blocs moteur |
-
2000
- 2000-06-14 CH CH01174/00A patent/CH694664A5/de not_active IP Right Cessation
-
2001
- 2001-05-10 ES ES01810455.4T patent/ES2619929T3/es not_active Expired - Lifetime
- 2001-05-10 EP EP01810455.4A patent/EP1174524B1/fr not_active Expired - Lifetime
- 2001-05-10 PT PT1810455T patent/PT1174524T/pt unknown
- 2001-05-15 US US09/855,471 patent/US6578539B2/en not_active Expired - Lifetime
- 2001-05-17 CA CA002347980A patent/CA2347980C/fr not_active Expired - Lifetime
- 2001-06-07 JP JP2001172095A patent/JP2002047550A/ja active Pending
- 2001-06-13 KR KR1020010033134A patent/KR100596124B1/ko active IP Right Grant
-
2005
- 2005-06-21 JP JP2005180905A patent/JP2005325452A/ja active Pending
Non-Patent Citations (1)
Title |
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None * |
Also Published As
Publication number | Publication date |
---|---|
PT1174524T (pt) | 2017-01-23 |
CH694664A5 (de) | 2005-05-31 |
CA2347980C (fr) | 2004-12-07 |
KR100596124B1 (ko) | 2006-07-05 |
JP2005325452A (ja) | 2005-11-24 |
US20020011243A1 (en) | 2002-01-31 |
EP1174524A2 (fr) | 2002-01-23 |
ES2619929T3 (es) | 2017-06-27 |
CA2347980A1 (fr) | 2001-12-14 |
JP2002047550A (ja) | 2002-02-15 |
EP1174524A3 (fr) | 2009-03-11 |
KR20010112649A (ko) | 2001-12-20 |
US6578539B2 (en) | 2003-06-17 |
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