EP1165743B1 - Preparations tensioactives aqueuses a phases multiples - Google Patents

Preparations tensioactives aqueuses a phases multiples Download PDF

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Publication number
EP1165743B1
EP1165743B1 EP00920627A EP00920627A EP1165743B1 EP 1165743 B1 EP1165743 B1 EP 1165743B1 EP 00920627 A EP00920627 A EP 00920627A EP 00920627 A EP00920627 A EP 00920627A EP 1165743 B1 EP1165743 B1 EP 1165743B1
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EP
European Patent Office
Prior art keywords
preparations
aqueous preparations
aqueous
contain
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00920627A
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German (de)
English (en)
Other versions
EP1165743A1 (fr
Inventor
Thomas Förster
Barbara Heide
Wolfhard Scholz
Soraya Heinen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1165743A1 publication Critical patent/EP1165743A1/fr
Application granted granted Critical
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Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2017—Monohydric alcohols branched

Definitions

  • the invention relates to aqueous surfactant preparations which are in the state of rest in the form of two or more segregated, liquid, aqueous phases present by movement temporarily are dispersible in each other.
  • EP 0116 442 A1 describes a shampoo which consists of two separate aqueous Phases and whose specific heavier, lower phase has a content of at least 6 Wt .-% dissolved sodium hexametaphosphate has. Such a high content of condensed However, phosphates are neither advantageous in terms of application technology nor ecologically desirable.
  • JP 62 263 297 A1 cosmetic cleaners were known, the two denmischte, have liquid, aqueous phases and by a content of surfactants and water-soluble polymers are characterized.
  • the cleaning agents described there however, they take a relatively long time (several hours) until they mix in the mix Disconnect the idle state again.
  • the invention therefore aqueous, at rest in the form of two or more demixed aqueous, with intermittent intermittently dispersible phases present preparations with at least one dissolved surface-active compound and at least one dissolved polymer compound used to accelerate the phase separation at rest, at least one water-soluble, mono- or polyhydric alcohol with 2-9 C atoms, they are defined in the claims
  • dissolved surface-active Compounds can be ionogenic or nonionic compounds, it is crucial that they are a preferably linear lipid group having 8-22 C atoms and at least one water-solubilizing polyol or polyether group or a water-solubilizing salt-forming group, e.g. a carboxyl, sulfonate or sulfate ester group or both or an optionally quaternary ammonium group or ampholytic aminocarboxylate or Aminosulfonatrios or a betaine moiety, preferably at one end of the linear Contain lipid group.
  • water-solubilizing polyol or polyether group or a water-solubilizing salt-forming group e.g. a carboxyl, sulfonate or sulfate ester group or both or an optionally quaternary ammonium group or ampholytic aminocarboxylate or Aminosulfonatrios or a betaine moiety, preferably at one end of the
  • Suitable cosmetic cleaners are preferably those preparations which contain as surface-active compounds high-foaming anionic surfactants, preferably those with anionic sulfonate or sulfate ester groups in the form of their alkali metal, magnesium or ammonium salts.
  • Such preferably suitable surfactants are, above all, the alkylpolyglycol ether sulfate salts or the alkylpolyglycol ether sulfosuccinate salts which, for example, fulfill the general formula I or II as sodium salts: R 1 -O- (C 2 H 4 O) n -SO 3 Na
  • R 1 and R 2 is a preferably linear alkyl group having 8-22, preferably having 12-18 C atoms and n is a number from 1 to 6, preferably from 2-4.
  • Preferred preparations contain as surface-active compounds an alkylpolyglycol ether sulfate salt or an alkylpolyglycol ether-sulfosuccinate salt having an alkyl group with 12-18 C atoms and 1-6 glycol ether groups or a mixture thereof in a total amount of 5-20% by weight of the preparation, preferably from 8-12% by weight of the preparation.
  • anionic surfactants are, for example, soaps, N-acylamino acid salts, alkyl phosphate salts, alkylpolyglycate-carboxylate salts, alkyl sulfate-alkanolamine salts, alkylsulfonate salts, ⁇ -olefinsulfonate salts, acylisethionate salts and acyltaurine salts.
  • amphoteric and / or zwitterionic surfactants for example cocoamphoglycinate or cocoamidopropyl-dimethyl-ammonio-glycinate and betaine surfactants may also be present.
  • Nonionic surfactants for example the adducts of 6-30 moles of ethylene oxide with fatty acids, fatty alcohols, fatty acid monoglycerides, fatty acid alkanolamides, fatty acid sorbitan esters, alkylphenols, methylglucoside fatty acid esters and other polar lipids and alkylglucosides and their ethylene oxide adducts can also be present as surface-active substances.
  • the total amount of surfactants may be 5-40 wt .-%, but an amount of 5-20 wt .-% is preferred because otherwise the rapid separation of the phases is no longer guaranteed.
  • dissolved polymer compounds are all suitable in water or aqueous surfactant solutions at 20 ° C in amounts of at least 1% by weight soluble natural or synthetic high-molecular substances with recurring structural elements
  • natural polymers are water-soluble proteins or water-soluble polysaccharides or the water-soluble derivatives of water-insoluble proteins or polysaccharides understood.
  • Suitable natural polymers are e.g. Albumins, gelatin, glycosaminoglycans (Hyaluronic acid), chitosans, starch, guar, cellulose ethers, e.g. Methylcelluloses or Hydroxyethylcelluloses, carboxymethylcelluloses and cationic cellulose derivatives, e.g.
  • the with epoxypropyl-trimethylammoinum chloride modified starch, guar or Cellulose ethers are suitable polymer compounds.
  • Suitable synthetic polymer compounds are e.g. polyvinyl alcohols, Polyvinylpyrrolidone, polyacrylamides and polyalkylene glycols having molecular weights of more than 1000 D. Also water-soluble copolymers of acrylic acid, acrylamide, the Vinylpyrrolidons and other water-soluble monomers with non-water-soluble Comonomers are suitable as polymer compounds in the context of the present invention.
  • Polymer compounds selected from polypropylene glycols having molecular weights of more than 1000 D, hydroxyethylcelluloses, xanthan gum, dextran, sodium hyaluronate and cationic cellulose ethers.
  • the quantities required for separation Polymer compounds are of the type and molecular weight of the polymer compound dependent, it is general that the higher the quantities required, the lower the required quantities is the molecular weight of the polymer compound.
  • the very high molecular weight salts of Hyaluronic acid or xanthan gum are therefore amounts of 0.1 - 1 wt .-%, of Cellulose ethers such.
  • the upper limit of salary Polymer compounds should be chosen so that the preparation does not gel and the Demixing is not hindered by the toughness of the phases.
  • the dissolved surface-active compounds and polymer compounds can be individually or as combinations of two or more such surfactants or polymers in the Preparations should be included. It has been shown that it is for the segregation of Composition is advantageous if at least two different surface-active Compounds or at least two different polymer compounds in the Contain compositions of the invention.
  • the polymer compounds has this is a combination of a particularly high molecular weight polymer with a low molecular weight polymer compound proved to be particularly suitable. So, for example Combinations of sodium hyaluronate with cellulose derivatives or of Polypropylene glycols having average molecular weights of 2000 D and more with such of 1000 D and less particularly well proven.
  • Suitable water-soluble mono- or polyhydric alcohols are all aliphatic alcohols, Diols or polyols, preferably those having 2-9 carbon atoms, in quantities of at least 1 wt .-% in water at 20 ° C are clearly soluble.
  • Such mono- or polyvalent ones Alcohols are in an amount of 1-40 wt .-% in the inventive preparations contain.
  • Suitable alcohols are e.g. Ethanol, 1-propanol, 2-propanol (isopropanol), n-butanol, Isobutanol, methoxyethanol or 2-ethoxyethanol.
  • Suitable diols are e.g.
  • Ethylene glycol 1,2-propylene glycol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, Diethylene glycol, triethylene glycol, dipropylene glycol, glycerol monomethyl ether or Cyclohexanediol.
  • Suitable polyols are glycerol, erythritol, diglycerol, triglycerol, sorbitol, Methyl glucoside, butyl glucoside, pentaerythritol or trimethyl propane.
  • the multiphase preparations of the present invention of the present invention separate particularly easy if, as alcohol, ethanol or isopropanol in an amount of 2 - 20 Wt .-% is included. It could be obtained in this way preparations that after intensive mixing of the phases at rest in less than 10 minutes to separate completely and be in the form of separate, clear phases.
  • Suitable electrolyte salts are especially water-soluble inorganic salts, e.g. Alkali halides such as sodium chloride (sodium chloride), calcium or Magnesium chloride, the sulphates of the alkali metals or of magnesium, sodium bicarbonate, Sodium hydrogen phosphate and sodium pyrophosphate but are also suitable salts of organic, low molecular weight acids, e.g.
  • Sodium acetate, sodium citrate, sodium lactate, Sodium toluenesulfonate, sodium xylenesulfonate or sodium benzoate are preferred water-soluble, inorganic electrolyte salts in an amount of 1-6 wt .-%.
  • the multiphase preparations according to the invention can also other advantageous for the application or the appearance Contain components, as they are common in cosmetic cleaning and care products.
  • these are e.g. Dyes, fragrances, preservatives and pH-adjusting agents (buffer salts), Complexing agents, antioxidants and cosmetic or dermatological active substances, the give the skin a pleasant feel or give the hair a good finish or the cause specific dermatological effects on the skin.
  • dyes preferably from those which have a different solubility in the segregated, aqueous phases and in this way the preparations have a particularly appealing appearance to lend.
  • yellow dyes e.g. Quinoline yellow varnish (Food color E 104)
  • red dyes such as Cochenillerot lacquer (food color E 124) or blue dyes (Sudan blue)
  • blue dyes Sud blue
  • the surfactant preparations of the invention may e.g. as shampoos for shampooing, as Shower preparations, bath products, liquid soaps - but also as liquid cleaning agents in the Household or used as a mild detergent. That segregated two- or multi-phase appearance can be used to give the consumer the Make composition of cleansing and nourishing components vivid and to motivate him to homogenize the product before use by shaking to remove from to use all components in the same way.
  • the percentages given in the table refer to% by weight of anhydrous active substance.
  • the following raw materials were used: LES-Na Sodium C 12 / C 14 alkylpoly (2) glycol ether sulphate (Texapon®NSO, Henkel KGaA) SBE-Na Sulfosuccinic acid - alkyl (C 12/14 -poly (3) glycol ether monoester di-sodium salt (Texapon® SB3, Henkel KGaA) HEC Hydroxyethylcellulose, viscosity 25 ° C (1% by weight): 350 m Pa s Degree of substitution 2.5 Natrasol® 250 HR (Hercules) Xanthan gum Keltrol® SF (Kelco) IR 400 Polyquaternium-1 O (Polymer IR 400, Amerchol) dextran Fa. Sigma, MG: 2-82000 PPG 600 Polypropylene glycol, molecular weight about 6000

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Claims (7)

  1. Préparations aqueuses, se présentant au repos sous forme de deux ou plusieurs phases aqueuses dissociées, dispersibles temporairement les unes dans les autres sous agitation, avec au moins un composé tensio-actif dissous, choisi parmi un sel sulfate d'alkylpolygtycoléther ou un sel sulfosuccinate d'alkylpolyglycoléther avec un groupe alkyle ayant 1,2 à 18 atomes de C et 1 à 6 groupes glycoléther ou un mélange de ceux-ci et au moins un composé polymère dissous, caractérisées en ce que, au moins un alcool mono- ou polyvalent, hydrosoluble, ayant 2 à 9 atomes de C y est contenu pour accélérer la séparation des phases au repos.
  2. Préparations aqueuses selon la revendication 1, caractérisées en ce que l'éthanol ou l'isopropanol y est contenu à titre d'alcool en une quantité de 2 à 20% en poids.
  3. Préparations aqueuses selon l'une quelconque des revendications 1 ou 2, caractérisées en ce que le composé tensio-actif y est contenu en une quantité de 5 à 20% en poids au total.
  4. Préparations aqueuses selon l'une quelconque des revendications 1 à 3, caractérisées en ce qu'en tant que composé polymère, un composé choisi parmi les polypropylèneglycols ayant des masses moléculaires supérieures à 1000 daltons, une hydroxyéthylcellulose, une gomme xanthane, le dextrane, l'hyaluronate de sodium, ou des éthers de cellulose cationique, y est contenu.
  5. Préparations aqueuses selon l'une quelconque des revendications 1 à 4, caractérisées en ce qu'au moins deux composés tensioactifs différents ou au moins deux composés polymères différents, y sont contenus.
  6. Préparations aqueuses selon l'une quelconque des revendications 1 à 5, caractérisées en ce que des sels électrolytes inorganiques hydrosolubles y sont contenus en une quantité de 1 à 6% en poids pour favoriser la séparation des phases.
  7. Préparations aqueuses selon l'une quelconque des revendications 1 à 6, caractérisées en ce que des colorants ayant une solubilité différente dans les phases aqueuses dissociées, y sont contenus.
EP00920627A 1999-04-08 2000-03-30 Preparations tensioactives aqueuses a phases multiples Expired - Lifetime EP1165743B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19915837A DE19915837A1 (de) 1999-04-08 1999-04-08 Wässrige mehrphasige Tensidzubereitungen
DE19915837 1999-04-08
PCT/EP2000/002806 WO2000061716A1 (fr) 1999-04-08 2000-03-30 Preparations tensioactives aqueuses a phases multiples

Publications (2)

Publication Number Publication Date
EP1165743A1 EP1165743A1 (fr) 2002-01-02
EP1165743B1 true EP1165743B1 (fr) 2005-01-12

Family

ID=7903882

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00920627A Expired - Lifetime EP1165743B1 (fr) 1999-04-08 2000-03-30 Preparations tensioactives aqueuses a phases multiples

Country Status (5)

Country Link
EP (1) EP1165743B1 (fr)
AT (1) ATE286966T1 (fr)
AU (1) AU4113600A (fr)
DE (2) DE19915837A1 (fr)
WO (1) WO2000061716A1 (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU1152601A (en) * 1999-10-22 2001-05-08 Reckitt Benckiser France Compositions and their use
DE19951635A1 (de) * 1999-10-26 2001-05-17 Henkel Kgaa Wäßriges mehrphasiges Reinigungsmittel
US6429177B1 (en) * 2000-08-22 2002-08-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Separating multi-phase personal wash composition in a transparent or translucent package
DE10062045A1 (de) * 2000-12-13 2002-06-27 Henkel Kgaa Verschiedenfarbiges wässriges mehrphasiges Reinigungsmittel
DE10206795A1 (de) * 2002-02-19 2003-08-28 Beiersdorf Ag Zweiphasige kosmetische oder dermatologische Zubereitungen mit einer Mikroemulsion
US6787511B2 (en) * 2002-08-14 2004-09-07 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Biphasic composition induced by polydextrose
WO2005023975A1 (fr) * 2003-09-03 2005-03-17 Henkel Kommanditgesellschaft Auf Aktien Agent cosmetique a phases multiples pour laver les cheveux et nettoyer la peau
DE10341024A1 (de) * 2003-09-03 2005-03-31 Hans Schwarzkopf & Henkel Gmbh & Co. Kg Mehrphasiges Tensidprodukt
FR2859626B1 (fr) * 2003-09-12 2006-01-27 Oreal Composition biphase et ses utilisations dans le domaine cosmetique
FR2871373B1 (fr) * 2004-06-11 2006-12-01 Oreal Procede de lavage des cheveux frises ou crepus
DE102004054278A1 (de) * 2004-11-10 2006-06-01 Wella Ag Klares, zweiphasiges, schaumbildendes Aerosol-Haarstylingprodukt
US20060140897A1 (en) * 2004-12-28 2006-06-29 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Biphasic inducing agent for aqueous cleansing compositions
DE102005051864A1 (de) 2005-10-25 2007-04-26 Beiersdorf Ag Kosmetische O/W-Emulsion mit 1,2-Hexandiol
DE102005051860A1 (de) * 2005-10-25 2007-04-26 Beiersdorf Ag Langzeitstabile Gesichtswässer mit 1,2 Hexandiol
EP1894994B1 (fr) 2006-08-31 2013-10-16 Henkel AG & Co. KGaA Produit de nettoyage du visage à deux phases ou plus doté d'un procédé de mélange et de ségrégation réversible amélioré
DE102014205475A1 (de) * 2014-03-25 2015-10-01 Beiersdorf Ag Polypropylenglykole mit antimikrobieller Wirkung in kosmetischen oder dermatologischen Zubereitungen
CN111328341B (zh) * 2017-11-30 2021-12-17 高露洁-棕榄公司 清洁组合物及其用途

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1188460A (fr) * 1955-09-06 1959-09-23 Colgate Palmolive Co Composition détersive sous forme de suspension
GB8421196D0 (en) * 1984-08-21 1984-09-26 Reckitt & Colmann Prod Ltd Cleansing compositions
JPS62263297A (ja) * 1986-05-09 1987-11-16 ライオン株式会社 ２相分離型液体洗浄剤組成物
DE19811386A1 (de) * 1998-03-16 1999-09-23 Henkel Kgaa Wäßriges mehrphasiges Reinigungsmittel

Also Published As

Publication number Publication date
DE50009223D1 (de) 2005-02-17
WO2000061716A1 (fr) 2000-10-19
ATE286966T1 (de) 2005-01-15
EP1165743A1 (fr) 2002-01-02
AU4113600A (en) 2000-11-14
DE19915837A1 (de) 2000-10-12

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