EP1109834A1 - Production d' thers polysaccharidiques - Google Patents

Production d' thers polysaccharidiques

Info

Publication number
EP1109834A1
EP1109834A1 EP99940869A EP99940869A EP1109834A1 EP 1109834 A1 EP1109834 A1 EP 1109834A1 EP 99940869 A EP99940869 A EP 99940869A EP 99940869 A EP99940869 A EP 99940869A EP 1109834 A1 EP1109834 A1 EP 1109834A1
Authority
EP
European Patent Office
Prior art keywords
polysaccharide
cellulose
basic compound
neutralized liquid
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99940869A
Other languages
German (de)
English (en)
Inventor
Charles B. Mallon
John S. Vames
John Ioannis Sarlis
Benito See
David M. Trampe
Rathin Datta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of EP1109834A1 publication Critical patent/EP1109834A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B11/00—Preparation of cellulose ethers
    • C08B11/20—Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B11/00—Preparation of cellulose ethers
    • C08B11/02—Alkyl or cycloalkyl ethers
    • C08B11/04—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
    • C08B11/08—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals with hydroxylated hydrocarbon radicals; Esters, ethers, or acetals thereof

Definitions

  • the present invention relates to processes for producing polysaccharide ethers. More specifically, the present invention relates to improved processes for producing polysaccharide ethers wherein salts formed in the processes can be converted to their corresponding acids and bases, e.g., by electrodialysis.
  • Typical commercial processes for the manufacture of polysaccharide ethers require the use of acids and bases.
  • a base such as, e.g., sodium hydroxide
  • an alkylene oxide e.g., ethylene oxide.
  • the reaction mixture is typically neutralized with a mineral acid or an organic acid, e.g., nitric acid or acetic acid.
  • a salt e.g., sodium nitrate or sodium acetate
  • the salt is comprised in an aqueous waste stream which also contains organic solvents used in the process and residues of the polysaccharide.
  • the salts are recovered from the waste stream and disposed of. However, the disposal of such salts may not be environmentally desirable or feasible. Therefore, improved processes for the production of polysaccharide ethers are desired which can convert the salts formed in the processes to their corresponding acids and bases. Preferably, the acids and bases recovered from the processes can be recycled for use in the production of the polysaccharide ethers.
  • the present invention improved processes for the production of polysaccharide ethers, e.g., hydroxyethyl cellulose, are provided.
  • the improvements are directed to the conversion of salts formed during the manufacture of the polysaccharide ethers to their corresponding acids and bases.
  • the conversion of the salts to their corresponding acids and bases is achieved by subjecting the salts to an electric current effective to promote the conversion of the salts to the acids and bases.
  • a separation means e.g., a bipolar membrane, is utilized to isolate the acids and bases as they are converted from the salt.
  • Electrodialysis is a convenient means for removing such materials in accordance with the present invention because the salts are more strongly ionized than the other materials. However, these other materials, the residues of the polysaccharides in particular, can cause fouling of the membranes used in the electrodialysis process. Quite surprisingly, in accordance with the present invention, it has been found that by conducting the electrodialysis at a alkaline pH, the degree of fouling of the membrane can be reduced and the ionic mobility of the salt through the membrane can be enhanced.
  • Figure 1 is a schematic of a process for the conversion of a salt to its corresponding acid and base in accordance with the present invention.
  • the polysaccharide starting materials suitable for use in accordance with the present invention include naturally occurring, biosynthesized and derivatized carbohydrate polymers or mixtures thereof. Such materials encompass high molecular weight polymers composed of monosaccharide units joined by glycosidic bonds. These materials may include, for example, the entire starch and cellulose families; pectin, chitosan; chitin; the seaweed products such as agar and carrageenan; alginate; the natural gums such as guar, arabic and tragacanth; bio-derived gums such as xanthan; and the like.
  • Preferred starting materials include cellulosics conventionally employed for the preparation of cellulose ethers, such as, for example, chemical cotton, cotton linters, wood pulp, alkali cellulose and the like. Such materials are commercially available.
  • molecular weight means weight average molecular weight. Methods for determining weight average molecular weight of cellulose ethers are known to those skilled in the art. One preferred method for determining molecular weight is low angle laser light scattering.
  • the particular derivatizing agent, e.g., alkyl halides or alkylene oxides, used to derivatize the polysaccharides is not critical to the present invention.
  • Suitable alkylene oxides for use in accordance with the present invention comprise from about 2 to 24, preferably from about 2 to 5 carbon atoms per molecule. Examples include ethylene oxide, propylene oxide and butylene oxide.
  • the ether substituent is derivatized onto the cellulose by reacting the polysaccharide with an alkylene oxide, preferably ethylene oxide.
  • the amount of ether substitution is typically from about 1.5 to 6 and preferably from about 2 to 4 moles of ether substituent per mole of polysaccharide ether.
  • Suitable alkyl halides include, for example, ethyl chloride or methyl chloride.
  • the polysaccharide ethers may be substituted with one or more desired substituents, e.g., cationic, anionic and/or hydrophobic substituents.
  • Hydrophobic substituents are known in the art and typically comprise alkyl, alkene, aryl-alkene or aryl-alkyl groups having about 8 to 24 carbon atoms per molecule.
  • Hydrophobically - modified cellulose ethers are described, for example, in U.S. Patent Nos. 4,228,277, 5,120,328 and 5,504,123 and European Patent Publication 0 384 167 Bl.
  • Cationic, hydrophobically modified cellulose ethers are described, for example, in U.S. Patent No. 4,663,159.
  • substitution level of each such substituent on the polysaccharide ether is typically from about 0.001 to 0.1 and preferably from about 0.004 to about 0.05 moles of substituent per mole of polysaccharide ether. More than one particular substituent can be substituted onto the polysaccharide ether.
  • the polysaccharide ethers of the present invention can be water- soluble or water-insoluble.
  • water-soluble means that at least 1 gram, and preferably at least 2 grams of the polysaccharide ether are soluble in 100 grams of distilled water at 25°C and 1 atmosphere.
  • the extent of water-solubility can be varied by adjusting the extent of ether substitution on the polysaccharide ether and by adjusting the substitution level of the various substituents, when present. Techniques for varying the water solubility of polysaccharide ethers are known to those skilled in the art.
  • the viscosity of the polysaccharide ethers typically ranges from about 1 to 8000 centipoise, preferably from about 100 to 3000 centipoise. Unless otherwise indicated, as used herein the term “viscosity” refers to the viscosity of a 1.0 weight percent aqueous solution of the polymer measured at 25°C with a Brookfield viscometer. Such viscosity measuring techniques are known in the art and are described in ASTM D 2364-89.
  • the average particle size of the polysaccharide ethers is not critical, but is preferably from about 0.01 to 1000 microns and more preferably from about 50 to 400 microns.
  • Preferred polysaccharide ethers produced in accordance with the present invention are cellulose ethers, including for example, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, ethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, carboxymethyl cellulose, hydroxyethyl carboxylmethyl cellulose, and derivatives thereof.
  • typical processes for producing polysaccharide ethers comprise:
  • the basic compounds suitable for use in accordance with the present invention include any base effective to promote the swelling of the polysaccharide.
  • Typical basic compounds include, for example, sodium hydroxide, potassium hydroxide, calcium hydroxide, magnesium hydroxide, lithium hydroxide, ammonium hydroxide and mixtures thereof.
  • the acidic compounds suitable for use in accordance with the present invention include any acids which are effective to neutralize the polysaccharide ether.
  • Typical acidic compounds include, for example, nitric acid, acetic acid, hydrochloric acid, sulfuric acid, phosphoric acid and mixture thereof.
  • the liquid medium in which the etherification is conducted comprises from about 5 to 25 wt %, preferably from about 10 to 20 wt % water, from about 75 to 95 wt %, preferably from about 80 to 90 wt % of at least one organic solvent.
  • organic solvents used in the processes of the present invention are not critical and may include, for example, t- butyl alcohol, acetone, isopropyl alcohol, ethanol, dioxane , glycol ethers and mixtures thereof.
  • the etherification of polysaccharides is conducted in a batch mode, although semi-batch and continuous processes may be employed.
  • the process conditions typically include a reaction temperature of about 50 to 100 °C, preferably from about 70 to 90 °C, a pressure of from about 1 to 5 atmospheres, and the reaction time of from about 30 to 400 minutes.
  • Further details concerning the etherification of cellulose are known in the art and disclosed, for example, in U.S. Patent Nos. 2,010,818, 4,228,277 and 4,663,159.
  • Typical salts which are formed when the acidic compound is added to neutralize the reaction product include, for example, sodium nitrate, sodium acetate and other salts produced by combination of the acids and bases listed above.
  • concentration of the salts in the neutralized reaction product, i.e., the neutralized liquid is typically from about 2 to 20 moles per kilogram of polysaccharide ether and prefer_ ⁇ bly from about 5 to 10 moles per kilogram of polysaccharide ether.
  • the neutralized liquid which comprises the salt
  • an electric current and suitable means effective to promote the conversion of the salt to the acidic compound and the basic compound e.g., a suitable separation means and a source of hydrogen ions and hydroxyl ions.
  • a suitable separation means to isolate the acidic compound and the basic compound as they are converted from the salt. Any suitable means can be used to effect the isolation.
  • a preferred separation means is by semi-permeable membranes, i.e., electrodialyis.
  • Electrodialysis is a well known separation process wherein ionized compounds are separated from non-ionized or weakly ionized compounds in aqueous solutions based on transport through ionic exchange membranes in an electric field. Details concerning suitable apparatus and process conditions for conducting electrodialysis are known to those skilled in the art.
  • bipolar membranes for use in accordance with the present invention to isolate the acids and bases from the salts are bipolar membranes.
  • the use of bipolar membranes in conjunction with an electric current to perform a separation is referred to in the art as "water-splitting electrodialysis". Further details concerning suitable apparatus and process conditions for conducting water-splitting electrodialysis are known to those skilled in the art. See, for example, U.S. Patent Nos. 4,885,247 and 5,143,839.
  • the particular composition of the bipolar membranes is not critical. Examples of materials which comprise such membranes include cationic and anionic polymers, e.g., sulfonated polystyrene, polystyrene with amine functionality and polysulfone.
  • Bipolar membranes are described for example, in U.S. Patent Nos. 4,116,889 and 4,766,161.
  • Preferred by commercially available bipolar membranes for use in accordance with the present invention include the following: BP1 from Tokuyama Corporation Tokyo, Japan and AQPS and BA06 from Aqualytics Corporation, Warren, NJ.
  • Other suitable bipolar membranes are commercially available.
  • the electric current used to facilitate the conversion of the salt to its corresponding acid and base has a current density of from about 500 to 2000 amps/square meter ("A/sq. m.") and preferably from about 800 to 1200 amps per square meter.
  • Current density is the current per unit area of available membrane through which the current passes measured when the current is initially applied to the membrane. The higher the applied current density, the lower the cell area required to achieve a specific degree of ion transfer.
  • the neutralized liquid is subjected to a separation prior to the water- splitting electrodialysis to separate the salt from the organic solvents and any residue of the polysaccharide remaining from the etherification.
  • distillation can be used to remove any volatile organics from the salt solution and to concentrate the salt to the appropriate concentration for further processing, typically about 5 to 20 wt %.
  • Any suitable means can be used to effect the separation of the salt from the high boiling organic solvents and the residue of the polysaccharide, e.g. membrane separation, filtration, ultra-filtration, electrolysis, electrodialysis.
  • Electrodialysis is a preferred means of separating the salts from the organic solvents and the residues of the polysaccharide.
  • Typical membranes comprise films of crosslin od polymers comprising either positively or negatively charged groups. Examples include polystyrene divinylbenzene copolymers containing sulfonic acid groups (negatively charged, allowing transport of positive ions) or quaternary amine groups (positively charged, allowing transport of negative ions).
  • Preferred commercially available semi-permeable membranes for the desalting electrodialysis step include, for example, cation membranes CM-2, CMX and CMB and anion membranes AM-1, AM-2 and AM-3 from Tokuyama Corporation. Other suitable membranes are commercially available. Further details concerning the apparatus and process for conducting desalting electrodialysis are known to those skilled in the art.
  • the efficiency of the salt recovery in the desalting electrodialysis step can be surprisingly enhanced by conducting the separation under alkaline conditions.
  • the alkaline conditions are effective to inhibit the deposition of the residue of the polysaccharide on the membrane.
  • the alkaline conditions are effective to enhance the ionic mobility of the salt through the membrane.
  • the pH is greater than about 10, more preferably from about 10.5 to 14, even more preferably from about 10.5 to 13 and most preferably from about 10.5 to 11.5. At a pH below about 10, it has been found that significant fouling of the membranes can occur.
  • the polysaccharide ethers of the present invention can have a variety of end-use applications, such as, for example, industrial applications and personal care applications.
  • Typical industrial applications for polysaccharide ethers include, for example, use as viscosity adjusters, suspension aids, oil field drilling and fracturing materials, adhesion promoters for siliceous substrates, e.g., glass panels and ceramics, coating materials for plastic and metal substrates, protective colloids and building materials, e.g., wallboard compound and latex grout additive.
  • Typical personal care applications include, for example, pharmaceutical and cosmetic compositions, e.g., ointments, skin creams, lotions, soaps, shampoos, conditioners and the like.
  • a preferred end-use application for polysaccharide ethers of the present invention, especially cellulose ethers such as hydroxyethyl cellulose and its derivatives, is as an additive in latex compositions.
  • Typical latex compositions comprise as essential components: water; latex polymer; and the cellulose ether.
  • the kind and amount of latex polymer is not critical, and may be provided based on well established procedures.
  • Typical latex polymers include, but are not limited to, various types such as the following: acrylics: alkyds; celluloses; coumarone-indenes; epoxys, esters; hydrocarbons; maleics; melamines; natural resins; oleo resins; phenolics; polyamides; polyesters; rosins; silicones; styrenes; terpenes; ureas; urethanes; vinyls; vinyl acrylics; and the like.
  • Illustrative latex polymers include, but are not limited to, one or more homo- or copolymers containing one or more of the following monomers: (meth)acrylates; vinyl acetate; styrene; ethylene; vinyl chloride; butadiene; vinylidene chloride; vinyl versatate; vinyl propionate; t-butyl acrylate; acrylonitrile; neoprene; maleates; fumarates; and the like, including plasticized or other derivatives thereof.
  • the amount of cellulose ether which may be used in the latex composition is not narrowly critical. In the broadest sense, the amount of cellulose ether is that which is an effective amount in providing the desired thickening and rheological properties to the latex composition. Typically, the amount of cellulose ether is at least about 0.05, preferably from about 0.15 to about 3, and more preferably from about 0.25 to about 1.5 weight percent of the latex composition.
  • the selection and amount of latex polymer used in the latex composition can be determined by those skilled in the art is not critical. Typically, the amount of dry latex polymer is at least about 1, preferably from about 2 to about 50, and most preferably from about 3 to about 40 weight percent of the total latex composition.
  • the latex composition may optionally contain other components such as those generally used in latex compositions.
  • Typical components include, but are not limited to, one or more of the following: solvents such as aliphatic or aromatic hydrocarbons, alcohols, esters, ketones, glycols, glycol ethers, nitroparaffins or the like; pigments; fillers, dryers, flatting agents; plasticizers; stabilizers; dispersants; surfactants; viscosifiers including other polymeric additives, cellulose ether based thickeners and so on; suspension agents; flow control agents; defoamers; anti-skinning agents; preseratives; extenders; filming aids; other crosslinkers; surface improvers; corrosion inhibitors; and other ingredients useful in latex compositions.
  • solvents such as aliphatic or aromatic hydrocarbons, alcohols, esters, ketones, glycols, glycol ethers, nitroparaffins or the like
  • pigments fillers, dryers, flatting agents
  • plasticizers
  • a hazy, dark brown feedstream 10 (neutralized liquid) containing about 8-10 wt % sodium acetate, about 0.5 wt % sodium hydroxide, about 4-5 wt % of a mixture of ethylene glycol, diethylene glycol and triethylene glycol, l-2wt % of partially soluble cellulosic material and the remainder water is passed to an ultrafiltration unit 100 wherein suspended materials and soluble materials with molecular weights above about 100,000 grams/gram mole are removed.
  • Ultrafiltration unit 100 is comprised of a metal housing containing tubular membranes which are permeable to materials with molecular weights below 100,000 grams/gram mole.
  • Suitable membranes include ceramic membranes and polymeric membranes, e.g., polyamide, cellulose acetate, polyethersulfone, poly aery lonitrite, polyvirfylidene fluoride and poly vinylchlo ride.
  • a waste stream 11 comprising material which does not pass through the ultrafiltration unit is withdrawn by a stream 11.
  • a clear brown filtrate stream 12 comprising essentially the same components as stream 10 but with the suspended matter and possibly some high molecular weight dissolved material removed is withdrawn from ultrafiltration unit 100, combined with sodium hydroxide via line 13, the source of which is hereinafter described, and introduced via line 14 to a desalting electrodialysis unit 101 which is comprised of a TS-2 ED stack from Tokuyama Corporation containing 6 ED cells comprised of AMI anion exchange membranes and CM2 and CMX cation exchange membranes.
  • the desalting electrodialysis unit 101 is operated at a pH of from about 11 to 11.5.
  • the amount of sodium hydroxide introduced via line 13 is controlled in order to provide the desired pH in the desalting electrodialysis unit 101.
  • a stream 15 comprising material which does not pass through the membranes in the desalting electrodialysis unit 101 is combined with stream 11 as described previously and withdrawn from the process via line 16.
  • a permeate stream 17 comprising about 18-20 wt % sodium acetate, about 1 wt % sodium hydroxide, about 0.5 wt % glycols and the remainder water is withdrawn from the desalting electrodialysis unit 101.
  • the desalting electrodialysis unit 101 operates in a batch mode under the following conditions: a temperature of about 45°C, a feed flowrate (line 14) of about 3-4 liters/minute, an initial current density of about 500 A/sq. m., with a 3 wt % sodium sulfate electrode rinse solution.
  • Stream 17 is passed to a chelation unit 102 which is a 2-liter column with an internal diameter of 2 inches containing Duolite C-467 sodium form ion exchange resin available from Rohm and Haas, Philadelphia, PA.
  • the purpose of the chelation unit is to reduce multivalent cation (Ca++, Mg++, Fe+++,etc.) concentrations to ⁇ lppmw.
  • An effluent stream 18 is withdrawn from chelation unit 102 and passed to a water-splitting electrodialysis unit 103 which comprises a 2-compartment ED stack (TS-2, Tokuyama Corporation) equipped with cation exchange membrane CM-1 and bipolar membrane BP1(4 cell pairs), both from Tokuyama Corporation.
  • the water-splitting electrodialysis unit 103 operates in a batch mode under the following conditions: a temperature of pbout 45°C, a feed flowrate (line 18) of about 2-3 liters/minute, an initial current density of about 1000 A sq. m., with a normal sodium hydroxide electrode rinse solution.
  • Water is introduced to the water-splitting electrodialysis unit 103 via line 19.
  • a base product stream 20 comprising from about 5 to 15 weight percent sodium hydroxide is produced.
  • a portion of the sodium hydroxide product stream is recycled to the desalting electrodialysis unit 101 via line 13 as described previously. The remainder of the stream is withdrawn from the process via line 21.
  • An acid product stream 22 comprising from about 10 to 20 weight percent acetic acid, is also produced.
  • This stream also contains some residual sodium acetate e.g., about 0.5 to 2 wt % and glycols present in the feed e.g., about 0.5 to 1 wt %.
  • Wood pulp Improved Ethenier-F wood pulp sheets available from ITT Rayonier, Stamford, CT, and flocked in the laboratory by techniques known in the art.
  • Ethylene oxide Obtained from Praxair, Inc., Danbury, CT, distilled under nitrogen before use.
  • Duolite C-467 Ion A chelating resin comprised of a polystyrene
  • a three pint, glass ChemcoTM pressure reactor was charged with Improved Ethenier-F wood pulp (32.4 g contained), 317 g of acetone, 41 g of ethanol and 47 g of water. The mixture was stirred for one hour while purging the headspace of the reactor with nitrogen at a rate of 400 ml min to remove any entrained oxygen. The reactor was fitted with an ice water condenser to prevent evaporative losses of the diluent during the nitrogen purge.
  • the slurry was heated to 35°C and held for 15 minutes. 47 g of 22 wt. % (by weight) aqueous sodium hydroxide solution were added to the slurry by syringe. The slurry was stirred for one hour at 35°C, while continuing the nitrogen headspace purge.
  • Ethylene oxide 34 g was added to the reactor by syringe, and with continuous stirring, the reactor was sealed.
  • the slurry was heated with a water bath to 75°C (typical heat-up time is 60 minutes). The temperature was held at 75°C for 1.5 hours to react out the ethylene oxide.
  • the slurry was cooled to room temperature and 16.2 g of glacial acetic acid were added by syringe. After stirring for 15 minutes, the polymer was collected by vacuum filtration through a fritted metal Buchner funnel. The polymer was washed four times with 500 ml of 7:1 (by volume) acetone/water, twice with 500 ml of 5:1 acetone/water, and twice with 500 ml of pure acetone. In the second pure acetone wash, 1.00 g of 40% aqueous glyoxal and 2.00 g of glacial acetic acid was included in the acetone wash to surface-treat the polymer.
  • the polymer was dried overnight in ⁇ acuo at 50°C, affording 50-55 g of a white granular solid.
  • the ash content was found to be 4-8% (as sodium acetate), and the mass gain EO MS was found to be 2-2.5.
  • EXAMPLE 3 A stream identical to the one used in Control Example 2 was processed as described above except that the pH of the feed was raised to ⁇ 11.5 by addition of 40wt % sodium hydroxide whenever the pH dropped to ⁇ 11. As a result of this pH control, ⁇ 91wt % of the acetate was transferred and cell resistance was kept under control. Sodium acetate concentration in the concentrate was about 20 wt % by weight.
  • the product from the ED step was then processed through a column containing Duolite C-467 to remove multivalent cations. Ca++ and Mg++ were below 1 pp in the resulting stream.
  • This product stream was then subjected to water splitting electrodialy , _''.s using a 2- compartment TS-2 stack equipped with BP1, CM-1, and CMX ion exchange membranes.
  • a stream from the distillation of the diluent and wash solutions from example 1 containing about 12wt % sodium acetate was ultrafiltered and passed through a chelation column as described in example 3.
  • the resulting solution was processed using the water splitting electrodialysis process described in example 3.
  • Cell voltage was about 1.5 volts/cell pair within a half hour. After 6-8 hours of operation the system began to plug up, pressure increased and cell voltage increased to over 2 volts/cell pair (constant current operating mode) .
  • An oily, tarry material was seen floating on the top of the feed tank. The base was brown in color. The entire system, including tanks and pipes, had to be cleaned after this test

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

L'invention concerne des processus de production d'éthers polysaccharidiques, par exemple des éthers de cellulose, les sels formés au cours de ces processus, notamment le nitrate de sodium ou l'acétate de sodium, étant convertis en leurs acides et bases correspondants au moyen d'un courant électrique, de préférence en association avec une membrane bipolaire et des membranes cationique et/ou anionique adéquates. Les acides et les bases récupérés au cours des processus susmentionnés peuvent être recyclés, ce qui évite ainsi d'avoir à jeter lesdits sels.
EP99940869A 1998-08-04 1999-08-03 Production d' thers polysaccharidiques Withdrawn EP1109834A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US9526398P 1998-08-04 1998-08-04
US95263P 1998-08-04
PCT/US1999/017597 WO2000008059A1 (fr) 1998-08-04 1999-08-03 Production d'éthers polysaccharidiques

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EP1109834A1 true EP1109834A1 (fr) 2001-06-27

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EP (1) EP1109834A1 (fr)
CN (1) CN1173994C (fr)
AU (1) AU5464399A (fr)
BR (1) BR9912637A (fr)
CA (1) CA2339374A1 (fr)
WO (1) WO2000008059A1 (fr)

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WO2010091099A2 (fr) * 2009-02-03 2010-08-12 Hercules Incorporated Procédé de traitement de biomasse destiné à dériver des polysaccharides contenus dedans afin d'augmenter leur accessibilité à l'hydrolyse, et fermentation subséquente
US20110129880A1 (en) * 2009-11-02 2011-06-02 Hercules Incorporated Process for treating biomass to increase accessibility of polysaccarides contained therein to hydrolysis and subsequent fermentation, and polysaccharides with increased accessibility
CN107226869A (zh) * 2017-06-29 2017-10-03 华南理工大学 一种酸碱协同预处理制备高取代度羟丁基淀粉的方法

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DE1668347A1 (de) * 1967-12-20 1971-09-16 Kalle Ag Verfahren zum Reinigen roher Hydroxyaethylcellulose
DE3446695A1 (de) * 1984-12-21 1986-06-26 Basf Ag, 6700 Ludwigshafen Verfahren zur aufkonzentrierung waessriger loesungen von organischen verbindungen, die salze enthalten, unter gleichzeitiger verringerung des salzgehaltes
JPS61271296A (ja) * 1985-05-28 1986-12-01 Kyogyo Kumiai N F I Ｎ−アセチルキトオリゴ糖の製造方法
JPH0195101A (ja) * 1987-10-05 1989-04-13 Dai Ichi Kogyo Seiyaku Co Ltd 高純度酸型セルロース誘導体の製造方法
JP2514389B2 (ja) * 1987-12-07 1996-07-10 第一工業製薬株式会社 変性セルロ―スエ―テルの製造方法
JPH03229621A (ja) * 1989-10-20 1991-10-11 Asahi Glass Co Ltd 電気透析法による水スプリッタシステム
US5294316A (en) * 1989-10-31 1994-03-15 Lenzing Aktiengesellschaft Process and apparatus for electrodialysis of an alkali sulfate containing aqueous solution
FR2729305A1 (fr) * 1995-01-18 1996-07-19 Atochem Elf Sa Regeneration d'acides organiques forts par des membranes bipolaires

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CA2339374A1 (fr) 2000-02-17
WO2000008059A1 (fr) 2000-02-17
CN1173994C (zh) 2004-11-03
CN1322215A (zh) 2001-11-14
AU5464399A (en) 2000-02-28
BR9912637A (pt) 2001-10-09

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