EP1093936A1 - Schreibgerät - Google Patents

Schreibgerät Download PDF

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Publication number
EP1093936A1
EP1093936A1 EP99922525A EP99922525A EP1093936A1 EP 1093936 A1 EP1093936 A1 EP 1093936A1 EP 99922525 A EP99922525 A EP 99922525A EP 99922525 A EP99922525 A EP 99922525A EP 1093936 A1 EP1093936 A1 EP 1093936A1
Authority
EP
European Patent Office
Prior art keywords
ink
component
layer
writing instrument
separative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99922525A
Other languages
English (en)
French (fr)
Other versions
EP1093936A4 (de
Inventor
Takao Koyama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Pencil Co Ltd
Original Assignee
Mitsubishi Pencil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Pencil Co Ltd filed Critical Mitsubishi Pencil Co Ltd
Publication of EP1093936A1 publication Critical patent/EP1093936A1/de
Publication of EP1093936A4 publication Critical patent/EP1093936A4/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K8/00—Pens with writing-points other than nibs or balls
    • B43K8/02—Pens with writing-points other than nibs or balls with writing-points comprising fibres, felt, or similar porous or capillary material
    • B43K8/03—Ink reservoirs; Ink cartridges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K8/00—Pens with writing-points other than nibs or balls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K5/00—Pens with ink reservoirs in holders, e.g. fountain-pens
    • B43K5/005—Pen barrels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K5/00—Pens with ink reservoirs in holders, e.g. fountain-pens
    • B43K5/02—Ink reservoirs
    • B43K5/12—Ink reservoirs with ink-level inspection means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K7/00—Ball-point pens
    • B43K7/005—Pen barrels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K7/00—Ball-point pens
    • B43K7/02—Ink reservoirs; Ink cartridges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
    • B43K—IMPLEMENTS FOR WRITING OR DRAWING
    • B43K8/00—Pens with writing-points other than nibs or balls
    • B43K8/003—Pen barrels

Definitions

  • the present invention relates to a writing instrument having an ink tank part for storing ink, more specifically to a writing instrument of a free ink type in which a ink contained in an ink tank part is directly fed to a pen tip or a writing instrument equipped with an ink tank part of a cartridge type for storing ink and a liquid applicator equipped with a tank part of a cartridge type for storing coating liquid, wherein visibility of an ink-remaining amount or a coating liquid-remaining amount is excellent.
  • a writing instrument of a free ink type that an ink-remaining amount can be observed (visibility). That is, in a free ink type writing instrument, an ink is filled in an ink tank which is a holder part, and the ink freely moves in the ink tank; and when the pen tip is turned downward, the ink-remaining amount can be observed through a visible part of the holder part.
  • polypropylene which is excellent in transparency and solvent resistance and which has a good moldability is used for a holder part of a writing instrument of a free ink type since the visibility can be secured.
  • a method for improving this visibility is a method in which an ink-repellence property is improved by making a rib-like projection or by providing surface treatment such as fluorine treatment and silicone treatment on the inside of the holder part.
  • Japanese Utility Model Publication no. 53902/1991 discloses a transparent or translucent ink reservoir of a writing instrument, in which the material thereof comprises polyethylene or polypropylene and a water-based ink is used and in which a greasy back leaking preventive (ink follower) incompatible with the water-based ink is disposed on an end of the water-based ink, wherein the above back leaking preventive comprises polybutene so that the water-based ink is less liable to be wet than the back leaking preventive against the ink reservoir in order to allow the water-based ink to come into contact with the back leaking preventive convexly at a central part of a contact face between the water-based ink and the back leaking preventive; and the water-based ink has less wetting against the ink reservoir than polybutene has.
  • an object and a technical concept described in this official gazette reside in an ink reservoir of a writing instrument, wherein a greasy back leaking preventive comprising polybutene which is incompatible with a water-based ink is filled in contact with the ink so that the ink does not leak from the ink reservoir; a boundary line between the ink and the back leaking preventive moves smoothly depending on a discharge amount of the ink in writing; the boundary line can always be observed from the outside of the ink reservoir; and the ink amount contained in the ink reservoir can certainly be observed.
  • the writing instrument is different in view of object and constitution from a free ink type writing instrument having a structure in which an ink freely moves in a holder part doubling as an ink tank which is one embodiment of the present invention and in which the ink-remaining amount therein can be observed via a visible part of the holder part when turning the pen tip downward. Accordingly, the preceding greasy back leaking preventive comprising polybutene can not be applied to the ink comprising the above constitution.
  • the cause of the problem described above is inferred to originate in that complete consumption of the ink allows the air to create a space in a pen feed which serves as a pen tip and coagulation of a pigment in the space part brings about clogging and that even if a new cartridge is installed, an ink discharge amount passing through the ink feed is markedly controlled, so that the drawn line intensity is notably reduced.
  • a liquid applicator in which a cartridge type is employed for a tank part storing coating liquid such as manicure liquid has the same problem as described above.
  • the present invention is intended to solve these problems, and an object thereof is to provide a writing instrument of a free ink type or a liquid applicator which is excellent in visibility of an ink-remaining amount or a coating liquid-remaining amount, and to provide a writing instrument and a liquid applicator in which the time of exchange for an ink cartridge can surely be visually found and in which the original ink discharge amount can be maintained as it is even when exchanged with a new ink cartridge.
  • the present invention comprises the following items (1) to (7):
  • a "writing instrument of a free ink type” means a writing instrument which has an ink tank for directly storing the ink without absorbing in a sliver and in which installed is an ink reservoir (collector member) for temporarily storing the ink pressed out from the ink tank when the air contained in the ink tank is expanded by a rise in the temperature so as to prevent the ink from blobbing from the pen tip or the air hole.
  • Fig. 1 and Fig. 2 are the embodiments of the writing instrument of a free ink type
  • Fig. 3 is the embodiment of the writing instrument equipped with an ink tank part of a cartridge type
  • Fig. 4 and Fig. 5 are the embodiments of the liquid applicator equipped with a coating liquid tank part of a cartridge type.
  • Fig. 1 is one example of an embodiment in which the writing instrument of a free ink type is applied to a marking pen.
  • the free ink type writing instrument A of the embodiment of the present invention is characterized in that an ink 11 contained in an ink tank part 10 which is a holder part comprises an ink component 12 and a layer-separative component 13 which separates to be a layer from the above ink component 12 and both of a specific gravity and a surface tension of the layer-separative component 13 are smaller than those of the ink component 12 and that the ink 11 can freely move in the ink tank part 10.
  • the numeral 14 in Fig. 1 is a collector member; 15 is a holder member; 16 is a feed; and 17 is a pen feed which serves as a pen tip.
  • the ink is fed from the ink tank 10 into the pen feed 17 via the feed 16 having an ink passage disposed in a central hole 14a of the collector member 14.
  • the layer-separative component 13 is used for elevating visibility of a visible part in the holder part 10 doubling as the ink tank and shall not specifically be restricted as long as it satisfies conditions that the layer-separative component 13 has a smaller surface tension than that of the ink component 12 contained in the ink 11 and separate to be a layer without mixing with the ink component 12 and that it has a specific gravity smaller than that of the ink component 12.
  • This layer-separative component 13 separates to be a layer without mixing with the ink component 12 and exerts no adverse effects on the physical properties of the ink component 12.
  • the layer-separative component 13 has a surface tension larger than that of the visible part (in the present embodiment, the whole holder part serves as the visible part) in the holder part 10 doubling as the ink tank, it becomes easy to observe the ink remaining amount which is the object of the present invention, but the layer-separative component 13 has preferably a surface tension than smaller that of the visible part (the whole holder part becomes the visible part) for observing the ink-remaining amount in the holder part 10 doubling as the ink tank. This layer-separative component makes it easier to observe the ink-remaining amount.
  • the layer-separative component 13 used in the present invention includes, for example, linear silicone oil having a dimethylsiloxane bond as a principal skeleton, cyclic silicone oil, modified silicone oil in which a part of the methyl group is modified with other functional groups (organic groups such as an amino group, an epoxy group, a carboxyl group, a carbinol group, a methacryl group, a mercapto group, an alkyl group, a higher fatty acid ester group, a higher alkoxy group, a fluorine group and a methylstyryl group) or a mixture obtained by mixing two or more kinds of hydrocarbon base liquid substances.
  • functional groups such as an amino group, an epoxy group, a carboxyl group, a carbinol group, a methacryl group, a mercapto group, an alkyl group, a higher fatty acid ester group, a higher alkoxy group, a fluorine group and a methylstyryl group
  • linear silicone oil represented by the following formula (I) capable of being used are linear silicone oil represented by the following formula (I), cyclic silicone oil represented by the following formula (II), modified silicone oil in which organic groups are introduced into side chains or both ends, or single end, side chains and both ends of polysiloxanes represented by the following formulas (III) to (VI) [amino-modified silicone oil, epoxy-modified silicone oil, carboxyl-modified silicone oil, carbinol-modified silicone oil, methacryl-modified silicone oil, mercapto-modified silicone oil, phenol-modified silicone oil, silicone oil modified with a reactive group at single end (single end carbinol-modified silicone oil, single end epoxy-modified silicone oil and single end methacryl-modified silicone oil), different functional groups-modified silicone oil (epoxy group/polyether group-modified silicone oil, amino group/polyether group-modified silicone oil and amino group/alkoxy group-modified silicone oil), polyether-modified silicone oil,
  • n and n described in the preceding formulas (III) to (VI) are integers of 0 or more, and m and n which are suitably settled are used respectively but restricted to those falling in a range where they function as the layer-separative component.
  • the preferred layer-separative component 13 are volatile ones considering that when the above layer-separative component 13 is discharged from the pen feed 17 of the free ink type writing instrument A (when it is lastly discharged after having consumed the ink component 12 contained in the ink tank 10 by writing), it does not stain a paper surface and not remain there.
  • It includes, for example, volatile linear silicone oil [in the case where n is 5 to 30 in the formula (I)] and volatile cyclic silicone oil (in the case where n is 3 to 4 in the formula (II)].
  • the layer-separative component 13 when the layer-separative component 13 has a surface tension larger than that of the ink component 12 contained in the ink 11, the layer-separative component can not be present between the ink tank member surface and the ink component, so that clear drain can not be carried out. Also, when the layer-separative component 13 has a specific gravity larger than that of the ink component 12, the layer-separative component 13 passes the pen feed through the feed and stays at the pen tip or is discharged on a writing surface in writing (normal writing with the pen tip turned downward), so that normal drawn lines can not be obtained in a certain case. Accordingly, it is not preferred.
  • the layer-separative component 13 has a viscosity of 10000 mPa ⁇ s or less, preferably 1000 mPa ⁇ s or less and more preferably 30 mPa ⁇ s or less at 25°C.
  • a use amount of the layer-separative component is 0.01 to 50 %, preferably 0.1 to 20 % and more preferably 1 to 10 % based on the content volume of the ink tank.
  • the amount of the layer-separative component is less than 0.01 %, there is a spot where it can not be present between the ink tank member surface and the ink component, so that fine clear drain can not be carried out.
  • the amount of the layer-separative component exceeds 50 %, the layer-separative component comes out to a pen feed side through the feed in writing with the pen tip turned horizontal, and normal drawn lines can not be obtained in a certain case.
  • the ink component 12 of the present invention shall not specifically be restricted as long as it allows the layer-separative component 13 to separate to be a layer and functions as an ink component for a writing instrument.
  • Capable of being used are, for example, so-called normal water-based inks and oil-based inks used for writing instruments prepared by dissolving or dispersing colorants comprising dyes and/or pigments, resins, dispersants, preservatives and other additives for a writing instrument in liquid obtained by mixing at least one of water, (purified water and ion-exchanged water) and organic solvents (1-methoxy-2-propanol, 1-ethoxy-2-propanol, benzyl alcohol, ethanol, ethylene glycol, carbitol, cellosolve, glycerin, diethylene glycol stearate, propylene glycol, 1-propanol, 2-propanol, 1-butanol, 2-butanol and t-butyl alcohol).
  • the ink component has a viscosity of 100 mPa ⁇ s or less, preferably 50 mPa ⁇ s or less and more preferably 10 mPa ⁇ s or less at 25°C.
  • the ink component has a viscosity exceeding 100 mPa ⁇ s, brought about are the problems that not only movement thereof in the ink tank is deteriorated and it is difficult to observe the ink-remaining amount but also the ink followability in writing is notably degraded.
  • thermoplastic plastics which are transparent and can be injection-molded.
  • thermoplastic plastics which are transparent and can be injection-molded.
  • polypropylene polyethylene, polyethylene terephthalate, polystyrene, polyetherimide, polycarbonate, polysulfone, acrylonitrile-acrylate-styrene copolymers, acrylonitrile-styrene copolymers, butadiene-styrene-methacrylate terpolymers, ethylene-vinyl chloride copolymers, ethylene- vinyl alcohol copolymers, polymethylpentene and polyethersulfone.
  • thermoplastic plastics which have a large surface tension against the ink component contained in the ink and the layer-separative component and which are not dissolved in the ink.
  • An inner surface of the visible part of the holder part which is the ink tank doubling as the visible part may be subjected to surface treatment with a fluororesin or a silicone resin to further improve the visibility.
  • the layer-separative component 13 having the characteristics described above allows the ink to be repelled in short time without remaining the ink component 12 in the ink tank 10 which is the visible part, and makes the visibility of the ink-remaining amount excellent very much.
  • the free ink type writing instrument having excellent visibility of an ink-remaining amount is obtained just by charging the ink tank 10 with the ink 11 comprising the ink component 12 and the layer-separative component 13 having the characteristics described above, and the intended free ink type writing instrument can be produced without going through a conventional step of making a rib-like projection for improving visibility of an ink-remaining amount in an ink tank. Accordingly, the free ink type writing instrument which is excellent in productivity as well as in cost can be provided.
  • Fig. 2 (a) and (b) are explanatory drawings showing an embodiment in which the free ink type writing instrument is applied to a ball point pen.
  • the free ink type writing instrument B of the present invention is characterized in that an ink 21 contained in an ink tank part 20 which is a holder part comprises an ink component 22 and a layer-separative component 23 which separates to be a layer from the ink component 22 and both of a specific gravity and a surface tension of the above layer-separative component 23 are smaller than those of the ink component 22 and that the ink component 22 can freely move in the holder part 20 doubling as the ink tank.
  • the layer-separative component 23 has a surface tension smaller than that of a visible part 20a for observing an ink-remaining amount in the holder part 20 doubling as the ink tank.
  • a coated film such as a coating film and a metal-deposited film is provided on the surface of the ink tank 20 excluding the visible part 20a described above to make the part opaque and invisible.
  • the ink tank 20 which is the holder part, the ink component 22 and the layer-separative component 23.
  • the numeral 24 in Fig. 2 is a collector member; 25 is a holder member; 26 is a feed comprising a leading feed 26a and an inner feed 26b; and 27 is a pen tip comprising a ball point tip.
  • the ink 21 is derived from the ink tank 20 into the pen tip 27 via the feed 26 which comprises the leading feed 26a and the inner feed 26b and which is disposed in a central hole 24a of the collector member 24 and provided an ink passage.
  • the visible part 20a (another visible part having the same structure on a reverse side or an opposite side) is formed in a part of the ink tank 20. Even if this visible part 20a is a part of the ink tank 20, the layer-separative component 23 having the characteristics described above allows the ink to be repelled in short time without allowing the ink component to remain on the surface of the visible part 20a, and therefore it improves a clear drain property and makes the visibility of the ink-remaining amount excellent very much.
  • a conventional free ink type writing instrument filled with an ink having a dark color such as black and blue is inferior in the ink-repellence property, and had a problem on the visibility thereof.
  • the free ink type writing instrument filled with an ink having a dark color such as black and blue the ink is repelled in short time without allowing the ink component to remain on the surface of the visible part 20a, and the visibility of the ink-remaining amount becomes excellent very much.
  • the free ink type writing instrument in the present invention shall not be restricted to the marking pen and the ball point pen of the embodiments described above and can be applied to a brush pen, a fountain pen, a felt type pen and an applicator for cosmetics.
  • the free ink type writing instruments of the embodiments described above are characterized by the ink filled into the ink tank which comprises the ink component and the layer-separative component having the characteristics described above, and therefore a structure of a free ink type writing instrument shall not specifically be restricted excluding this constitution.
  • the free ink type writing instrument of the embodiment in the present invention is constituted as described above.
  • the ink contained in the ink tank part comprises the ink component and the layer-separative component which separates to be a layer from the above ink component; both of a specific gravity and a surface tension of the above layer-separative component are smaller than those of the ink component; and the ink can freely move in the ink tank, so that the ink is repelled in short time without allowing the ink component to remain on the surface of the holder part, and the visibility of the ink-remaining amount becomes excellent very much.
  • the layer-separative component has a surface tension smaller than that of the holder part (visible part) doubling as the ink tank, the visibility of the ink-remaining amount becomes excellent very much.
  • the free ink type writing instrument having the excellent visibility of an ink remaining amount is obtained just by charging the ink tank with the ink comprising the ink component and the layer-separative component having the characteristics described above, and the free ink type writing instrument which is excellent in an aspect of productivity as well as cost is provided.
  • Fig. 3 is a schematic explanatory drawing for schematically explaining a writing instrument equipped with an ink tank of a cartridge type.
  • the cartridge type writing instrument C of the embodiment of the present invention is characterized, as shown in Fig. 3 (a), in that a writing instrument body 30 which is a holder is equipped with an ink tank part 31 of a detachable cartridge type and an ink 32 contained in the ink tank part 31 comprises an ink component 33 and a layer-separative component 34 which separate to be a layer from the ink component 33 and that both of a specific gravity and a surface tension of the layer-separative component 34 are smaller than those of the ink component 33 and the ink 32 can freely move in the ink tank 31.
  • a pen tip 35 comprising a pen feed is installed on a tip part of the writing instrument body 30.
  • the ink component 33 stored in the ink tank 31 described above shall not specifically be restricted and includes various components shown in the embodiment of the marking pen described above.
  • the examples thereof include water-based inks comprising colorants comprising dyes and/or pigments, water, organic solvents and the like.
  • Conventionally known additives such as a pH controlling agent, a dispersant, a preservative, a rust preventive and an auxiliary aye can suitably be added, if necessary, to these ink components.
  • Both of a specific gravity and a surface tension of the layer-separative component 34 stored in the ink tank part 31 together with the ink component 33 have to be smaller than those of the ink component 33, and the ink 32 has to freely move in the ink tank part 31. Even if the ink component 33 is completely consumed by writing and the drawn line intensity is notably reduced, some amounts of the layer-separative component 34 has to still remain in the ink tank part 31.
  • the layer-separative component 34 requiring such as amount shall not specifically be restricted as long as it has the characteristics that both of a specific gravity and a surface tension thereof are smaller than those of the ink component 33 and that the ink can freely move in the ink tank part and includes, for example, various layer-separative components having the characteristics shown in the embodiment of the marking pen described above.
  • materials to be used, sizes and forms of the pen tip part 35 and the ink tank part 31 of a cartridge type storing the ink 32 which comprises the ink component 33 and the layer-separative component 34 having the characteristics described above shall not specifically be restricted, and those shown in the embodiment of the marking pen described above can be used therefor.
  • a fiber bundle which is integrated with a pen tip, a synthetic resin-made pen tip having continuous pores and a small tube pen tip can suitably be used for the pen tip 35.
  • the writing instrument C of this embodiment thus constructed is so constituted that the ink 32 contained in the ink tank part 31 comprises the ink component 33 and the layer-separative component 34 which separates to be a layer from the ink component 33, and both of a specific gravity and a surface tension of the layer-separative component 34 are smaller than those of the ink component 33 and that the ink 32 can freely move in the ink tank 31, and therefore even if the ink component 33 contained in the ink tank part 31 is completely consumed by writing and the drawn line intensity is markedly reduced, the layer-separative component 34 is still contained, as shown in Fig. 3 (b), in the ink tank part 31, and the pen tip 35 is filled with the layer-separative component 34.
  • the layer-separative component 34 is discharged from the pen tip 35, that is, when the drawn lines are written with the layer-separative component 34 in place of the ink component 33, the ink contained in the ink tank part 31 is completely consumed, which notifies (sign) the time to exchange the ink tank 31.
  • the ink tank part 31 can repeatedly be exchanged until the pen tip part 35 itself is damaged to thereby bring about inferior writing. If the pen tip part 35 is a cartridge type, it can be exchanged together with the ink tank part 31 and used.
  • Fig. 4 and Fig. 5 are cross sections showing one example of the embodiment of the liquid applicator.
  • the liquid applicator D of this embodiment is composed of an applicator body 40 having an opened rear end, a tank part 50 of a cartridge type and a cylindrical plug 60.
  • a coating liquid (not illustrated) stored in the tank part 50 described above comprises a coating liquid component such as a manicure liquid and a layer-separative component which separates to be a layer from the coating liquid component. Both of a specific gravity and a surface tension of the layer-separative component are smaller than those of the coating liquid component, and the coating liquid can freely move in the tank part 50.
  • the numeral 45 is a cap.
  • the plug 60 is inserted, as shown in Fig. 4 and Fig. 5, to the rear end side of the tank part 50 of a cartridge type.
  • a front end aperture part 67 of the plug 60 comes into contact with a stage part 54 of the tank part 50 of a cartridge type, and insertion of the plug 60 is stopped.
  • the plug 60 is inserted into the inside of the applicator body 40 from the rear end aperture side thereof.
  • This allows a concave engaging part 65 of the plug 60 to be engaged and fixed with a convex engaging part 42 of the applicator body 40 with narrowing a width of slits 64 while keeping a suitable gap between the peripheral face part having each slit 64 and the convex engaging part 42.
  • an aperture of an inner front axis 53 of the tank part 50 of a cartridge type is inserted into a pipe member 43 of the applicator body 40, and setting is completed.
  • the tank part 50 of a cartridge type freely slides, as shown in Fig. 5, in an axis direction to the pipe part 43, and when the rear end of the tank part 50 is pressed forward, a valve part 52 of the tank part 50 is opened, and the coating liquid contained in the tank part 50 flows into the pipe member 43 through the valve part 52 and is fed into a brush member 41a.
  • the tank part 50 When the rear end of the tank part 50 is released from pressing, the tank part 50 goes back against the pipe member 43 by virtue of a valve spring 52a built in the valve body 52 to shut the valve body 52. At the same time, in order to prevent the valve part 52 from falling from the pipe member 43 with the tank part 50 sliding to a plug 60 side at the time of pressing (knocking) the tank part 50 or applying careless force to it, the tank part 50 touches with the front end aperture part 67 of the plug 60 at the stage part 54 and stops.
  • liquid applicator D of this embodiment a prescribed amount of the coating liquid is fed into the brush member 41a and used by repeating the pressing operation described above.
  • the coating liquid component stored in the tank described above shall not specifically be restricted and includes, for example, a liquid cosmetic such as a manicure liquid, a liquid detergent and a liquid chemical.
  • Both of a specific gravity and a surface tension of the layer-separative component stored in the tank part 50 together with the coating liquid component have to be smaller than those of the coating liquid component, and the coating liquid has to freely move in the tank. Further, even if the coating liquid component is completely consumed by coating and the coating density is notably reduced, some amounts of the layer-separative component has to still remain in the ink tank part 50.
  • the layer-separative component requiring such an amount shall not specifically be restricted as long as it has the characteristics that both of a specific gravity and a surface tension thereof are smaller than those of the coating liquid component and that the coating liquid can freely move in the ink tank part and includes, for example, various layer-separative components having the characteristics shown in the embodiment of the marking pen described above.
  • the liquid applicator D of this embodiment thus constituted has the same working effects as those of the writing instrument C.
  • the preceding tank part 50 of a cartridge type can easily be exchanged by detaching the plug 60 from the applicator body 40 with releasing engagement thereof, then detaching the tank part 50 and setting a new tank according to the setting way described above.
  • the ink or the coating liquid stored in the tank part comprises the ink component or the coating liquid component such as a manicure liquid and the layer-separative component which separates to be a layer from the above ink component or coating liquid component.
  • the layer-separative component Both of a specific gravity and a surface tension of the layer-separative component are smaller than those of the ink component or the coating liquid component, and the ink or the coating liquid can freely move in the tank part, whereby the intended observation of the remaining amount of the ink or the coating liquid can simply and easily be achieved.
  • Constitution other than that of the layer-separative component having the characteristic described above which is stored in the ink tank part shall not specifically be restricted.
  • the writing instrument of the embodiment described above which is equipped with the ink tank part of a cartridge type includes, for example, a felt tip pen, a ball point pen, a marking pen such as a marker for underlining and a fountain pen which are equipped with the ink tank parts of a cartridge type, and the embodiment can further be applied to a liquid applicator for various uses which is equipped with a tank part of a cartridge type storing a coating liquid.
  • Examples 1 to 7 and Comparative Examples 1 to 5 are examples and comparative examples for free ink type writing instruments
  • Example 8 and Comparative Example 6 are an example and a comparative example for writing instruments equipped with an ink tank of a cartridge type.
  • Ink component composition (% by weight) Purified water 55.0 Propylene glycol 17.0 Glycerin 5.0 Preservative (1,2-benzisothiazoline-3-one) 0.3 Resin (acryl base emulsion) 7.0 Dispersant (styrene-acryl base dispersion resin) 0.7 Carbon black 15.0 Surface tension 35 dyn/cm (at 25°C) Specific gravity 1.07 (at 25°C) Viscosity 4.5 mPa ⁇ s (at 25°C) (2) Decamethylcyclopentasiloxane (KF995: manufactured by Shin-Etsu Chemical Co., Ltd.) was used for a layer-separative component. Surface tension 17.8 dyn/cm (at 25°C) Specific gravity 0.956 (at 25°C) Viscosity 3.8 mPa ⁇ s (at 25°C)
  • the ink tank was charged with 1.5 cc of the ink component described above and 0.1 cc of the layer-separative component so that the visible part was completely covered with the ink component. This was assembled into such a writing instrument as shown in Fig. 1 to carry out a test of visibility according to the following method (test of visibility).
  • the pen tip is turned downward to cover the visible part with the ink component. Then, the pen tip is turned upward so that the ink component stays in a lower position than the visible part.
  • Ink component composition (% by weight) Propylene glycol monomethyl ether 80.0 Resin (alkylphenol resin) 7.0 Dye (black) 13.0 Surface tension 24 dyn/cm (at 25°C) Specific gravity 0.950 (at 25°C) Viscosity 4.7 mPa ⁇ s (at 25°C) (2) Dimethylsilicone oil (KF96-10: manufactured by Shin-Etsu Chemical Co., Ltd.) was used for a layer-separative component. Surface tension 20.0 dyn/cm (at 25°C) Specific gravity 0.940 (at 25°C) Viscosity 9.4 mPa ⁇ s (at 25°C)
  • the ink tank was charged with 1.5 cc of the ink component described above and 0.1 cc of the layer-separative component so that the visible part was completely covered with the ink component.
  • Ink component composition (% by weight) Purified water 55.0 Propylene glycol 17.0 Glycerin 5.0 Preservative (1,2-benzisothiazoline-3-one) 0.3 Resin (acryl base emulsion) 7.0 Dispersant (styrene-acryl base dispersion resin) 0.7 Carbon black 15.0 Surface tension 35 dyn/cm (at 25°C) Specific gravity 1.07 (at 25°C) Viscosity 4.5 mPa ⁇ s (at 25°C) (2) ⁇ -Olefin oligomer (hydrocarbon oil, SHF-20: manufactured by Mobil Sekiyu K.K.) was used for a layer-separative component. Surface tension 27.2 dyn/cm (at 25°C) Specific gravity 0.80 (at 25°C) Viscosity 6.5 mPa ⁇ s (at 25°C)
  • the ink tank was charged with 1.5 cc of the ink component described above and 0.1 cc of the layer-separative component so that the visible part was completely covered with the color component.
  • Ink component composition (% by weight) Purified water 55.0 Propylene glycol 17.0 Glycerin 5.0 Preservative (1,2-benzisothiazoline-3-one) 0.3 Resin (acryl base emulsion) 7.0 Dispersant (styrene-acryl base dispersion resin) 0.7 Carbon black 15.0 Surface tension 35 dyn/cm (at 25°C) Specific gravity 1.07 (at 25°C) Viscosity 4.5 mPa ⁇ s (at 25°C) (2) Layer-separative component composition (% by weight) ⁇ -Olefin oligomer (hydrocarbon oil, SHF-20: manufactured by Mobil Sekiyu K.K.) 98.0 Dimethylsilicone oil (KF96-10000: manufactured by Shin-Etsu Chemical Co., Ltd.) 2.0 Surface tension 22.0 dyn/cm (at 25°C) Specific gravity 0.805 (at 25°C) Viscosity 6.0 mPa ⁇ s (at 25°C)
  • the ink tank was charged with 1.5 cc of the ink component described above and 0.1 cc of the layer-separative component comprising the two components described above so that the visible part was completely covered with the ink component.
  • Ink component composition (% by weight) Propylene glycol monomethyl ether 80.0 Resin (alkylphenol resin) 7.0 Dye (black) 13.0 Surface tension 24 dyn/cm (at 25°C) Specific gravity 0.950 (at 25°C) Viscosity 4.7 mPa ⁇ s (at 25°C)
  • Layer-separative component composition (% by weight) Liquid paraffin (first class reagent, manufactured by Wako Pure Chemical Industries, Ltd.) 99.0 Dimethylsilicone oil (KF96-50000: manufactured by Shin-Etsu Chemical Co., Ltd.) 1.0 Surface tension 21.9 dyn/cm (at 25°C) Specific gravity 0.900 (at 25°C) Viscosity 110 mPa ⁇ s (at 25°C)
  • the ink tank was charged with 1.5 cc of the ink component described above and 0.1 cc of the layer-separative component comprising the two components described above so that the visible part was completely covered with the ink component.
  • Polypropylene (PP) which did not contain an antioxidant, a light degradation preventive and an antistatic agent and which had a surface tension of 28 dyn/cm (at 25°C) was used for the material thereof.
  • Ink component composition (% by weight) Purified water 55.0 Propylene glycol 17.0 Glycerin 5.0 Preservative (1,2-benzisothiazoline-3-one) 0.3 Resin (acryl base emulsion) 7.0 Dispersant (styrene-acryl base dispersion resin) 0.7 Carbon black 15.0 Surface tension 35 dyn/cm (at 25°C) Specific gravity 1.07 (at 25°C) Viscosity 4.5 mPa ⁇ s (at 25°C) (2) Liquid paraffin 100 % by weight (first class reagent, manufactured by Wako Pure Chemical Industries, Ltd.) was used for a layer-separative component. Surface tension 30.5 dyn/cm (at 25°C) Specific gravity 0.870 (at 25°C) Viscosity 105 mPa ⁇ s (at 25°C)
  • the ink tank was charged with 1.5 cc of the ink component described above and 0.1 cc of the layer-separative component so that the visible part was completely covered with the color component.
  • Example 1 a writing instrument excluding the layer-separative component was assembled to carry out the test of visibility according to the same method as in Example 1 described above. The result thereof is shown in the following Table 1.
  • Example 2 a writing instrument excluding the layer-separative component was assembled to carry out the test of visibility according to the same method as in Example 1 described above. The result thereof is shown in the following Table 1.
  • Example 3 a writing instrument excluding the layer-separative component was assembled to carry out the test of visibility according to the same method as in Example 1 described above. The result thereof is shown in the following Table 1.
  • PP polypropylene
  • fluororesin fluorine base coating agent: Fluorad FC-722, manufactured by Sumitomo 3M Limited
  • Example 3 The same ink composition as in Example 3 was used. That is, the surface tension was 35 dyn/cm (at 25°C); the specific gravity was 1.07 (at 25°C); and the viscosity was 4.5 mPa ⁇ s (at 25°C).
  • the ink tank was charged with 1.5 cc of the ink component described above so that the visible part was completely covered with the color component.
  • PP polypropylene
  • fluororesin fluorine base coating agent: Fluorad FC-722, manufactured by Sumitomo 3M Limited
  • Example 2 The same ink composition as in Example 2 was used. That is, the surface tension was 24 dyn/cm (at 25°C); the specific gravity was 0.950 (at 25°C); and the viscosity was 4.7 mPa ⁇ s (at 25°C).
  • the ink tank was charged with 1.5 cc of the ink component described above so that the visible part was completely covered with the color component.
  • Example 6 a writing instrument excluding the layer-separative component was assembled to carry out the test of visibility according to the same method as in Example 1 described above. The result thereof is shown in the following Table 1. Time spent until ink-remaining amount can be observed Example 1 one second or shorter Example 2 one second or shorter Example 3 one second or shorter Example 4 one second or shorter Example 5 3 seconds or shorter Example 6 5 seconds or shorter Comparative Example 1 5 minutes or longer Comparative Example 2 20 minutes or longer Comparative Example 3 5 minutes or longer Comparative Example 4 5 minutes or longer Comparative Example 5 20 minutes or longer Comparative Example 6 one minute or longer
  • the ink contained in the ink tank comprises the ink component and the layer-separative component which separates to be a layer from the ink component; both of a specific gravity and a surface tension of the layer-separative component are smaller than those of the ink component; and the ink can freely move in the ink tank. Accordingly, it can be found that the ink is excellent very much in visibility of an ink-remaining amount.
  • the layer-separative components have a surface tension smaller than that of the visible part for observing the ink-remaining amount of the holder part doubling as the ink tank
  • the layer-separative component has a surface tension larger than that of the visible part for observing the ink-remaining amount of the holder part doubling as the ink tank. It can be found that the object of the present invention has been achieved in all these cases.
  • Comparative Examples 1 to 6 relate to the free ink type writing instruments containing no layer-separative components.
  • the fluororesin was coated on the surface of the visible part of the inside of the ink tank.
  • the time until the ink-remaining amount can be observed was 5 seconds or shorter in the beginning, but the coating film was peeled off from the inner wall surface of the ink tank with the passage of time (after left standing for 5 days), and the effect was lost. After all, required were 5 minutes or longer in the case of Comparative Example 4 and 20 minutes or longer in the case of Comparative Example 5.
  • a water-based ink (specific gravity: 1.07/25°C) having the following composition was used as an ink component in Example 7.
  • Color resin emulsion toner (yellow) (color emulsion particle size: 0.5 ⁇ m) 50.0 % by weight Purified water 29.5 % by weight Glycerin 20.0 % by weight Preservative 0.5 % by weight Surface tension 35 dyn/cm (at 25°C) Specific gravity 1.07 (at 25°C) Viscosity 5 mPa ⁇ s (at 25°C)
  • Decamethylcyclopentasiloxane (KF995: manufactured by Shin-Etsu Chemical Co., Ltd.) was used. Surface tension 17.8 dyn/cm (at 25°C) Specific gravity 0.956 (at 25°C) Viscosity 3.8 mPa ⁇ s (at 25°C)
  • Comparative Example 7 the same ink as in Example 7 was used, except that silicone oil was not added, and a test was carried out according to the following method.
  • the writing instrument E is equipped with an ink tank 70 doubling as a holder which is a cartridge part, and the ink tank 70 is detachably installed to a main body 71 via a connecting part 72.
  • An ink 73 stored in the ink tank 70 is derived into a pen feed 75 via a feed 74.
  • the numeral 76 is a collector member.
  • the ink tank part 70 of a cartridge type was charged with 2.0 cc of the ink component and 0.2 cc of the layer-separative component each having the composition described above, respectively, and writing was carried out until the ink contained in the ink tank part 70 was completely consumed and the drawn line was blurred. Then, the cartridge was exchanged with a new ink tank cartridge filled with the ink component and the layer-separative component having the compositions described above, and writing was carried out again to visually observe the drawn line intensity and compare it with the original intensity. This operation was repeated 5 times.
  • a free ink type writing instrument and a writing instrument equipped with an ink tank part of a cartridge type which are excellent in visibility of an ink-remaining amount.
  • layer-separative component in which both of a specific gravity and a surface tension are smaller than those of the ink component and which separates to be a layer from the ink component is just stored in the ink tank part together with a conventional ink component, and therefore the writing instrument which is excellent in productivity and profitability is provided.
  • the writing instrument equipped with an ink tank part of a cartridge type it has become possible to exchange any number of times a cartridge in the ink tank part, and even after the ink component is completely consumed, the state that the layer-separative component is filled in the inside of the pen tip such as the pen feed can be maintained. Further, when the ink component is completely consumed, the drawn line is written with the liquid of the layer-separative component in place of the ink component, and therefore the time for exchange of the ink tank part can surely be visually observed.
  • the time for exchange of the tank part of a cartridge type can surely be visually observed, and the original discharge amount of the coating liquid can be maintained as it is even after exchanged with a new tank part.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pens And Brushes (AREA)
EP99922525A 1998-05-27 1999-05-27 Schreibgerät Withdrawn EP1093936A4 (de)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP14625298 1998-05-27
JP14625298 1998-05-27
JP30286298 1998-10-23
JP30286298 1998-10-23
JP33797298 1998-11-27
JP33797298 1998-11-27
PCT/JP1999/002804 WO1999061258A1 (fr) 1998-05-27 1999-05-27 Instrument d'ecriture

Publications (2)

Publication Number Publication Date
EP1093936A1 true EP1093936A1 (de) 2001-04-25
EP1093936A4 EP1093936A4 (de) 2004-03-31

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EP (1) EP1093936A4 (de)
KR (1) KR20010043725A (de)
AU (1) AU3954699A (de)
WO (1) WO1999061258A1 (de)

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DE10105006B4 (de) * 2000-02-04 2005-01-27 Mitsubishi Pencil K.K. Schreibgerät
JP2018187831A (ja) * 2017-05-02 2018-11-29 株式会社パイロットコーポレーション 筆記具用水性インキ収容体
WO2020061492A1 (en) * 2018-09-20 2020-03-26 Porex Technologies Corporation Heterogeneous fiber fluid reservoirs
US10638792B2 (en) 2013-03-15 2020-05-05 Juul Labs, Inc. Securely attaching cartridges for vaporizer devices
US10667560B2 (en) 2013-12-23 2020-06-02 Juul Labs, Inc. Vaporizer apparatus
US10701975B2 (en) 2013-12-23 2020-07-07 Juul Labs, Inc. Vaporization device systems and methods
US10709173B2 (en) 2014-02-06 2020-07-14 Juul Labs, Inc. Vaporizer apparatus
US10865001B2 (en) 2016-02-11 2020-12-15 Juul Labs, Inc. Fillable vaporizer cartridge and method of filling
US10912331B2 (en) 2013-12-23 2021-02-09 Juul Labs, Inc. Vaporization device systems and methods
US10912333B2 (en) 2016-02-25 2021-02-09 Juul Labs, Inc. Vaporization device control systems and methods
US11019685B2 (en) 2014-02-06 2021-05-25 Juul Labs, Inc. Vaporization device systems and methods
US11369756B2 (en) 2016-09-22 2022-06-28 Juul Labs, Inc. Leak-resistant vaporizer device
US11612702B2 (en) 2007-12-18 2023-03-28 Juul Labs, Inc. Aerosol devices and methods for inhaling a substance and uses thereof

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KR102522600B1 (ko) * 2022-04-15 2023-04-17 주식회사 모아이앤씨 구조물 안전점검용 균열 표시 장치

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Cited By (28)

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Publication number Priority date Publication date Assignee Title
DE10105006B4 (de) * 2000-02-04 2005-01-27 Mitsubishi Pencil K.K. Schreibgerät
US11612702B2 (en) 2007-12-18 2023-03-28 Juul Labs, Inc. Aerosol devices and methods for inhaling a substance and uses thereof
US10638792B2 (en) 2013-03-15 2020-05-05 Juul Labs, Inc. Securely attaching cartridges for vaporizer devices
US10667560B2 (en) 2013-12-23 2020-06-02 Juul Labs, Inc. Vaporizer apparatus
US10701975B2 (en) 2013-12-23 2020-07-07 Juul Labs, Inc. Vaporization device systems and methods
US11752283B2 (en) 2013-12-23 2023-09-12 Juul Labs, Inc. Vaporization device systems and methods
US10912331B2 (en) 2013-12-23 2021-02-09 Juul Labs, Inc. Vaporization device systems and methods
US11992044B2 (en) 2013-12-23 2024-05-28 Juul Labs, Inc. Vaporization device systems and methods
US10986867B2 (en) 2013-12-23 2021-04-27 Juul Labs, Inc. Vaporization device systems and methods
US10993471B2 (en) 2013-12-23 2021-05-04 Juul Labs, Inc. Vaporization device systems and methods
US11452177B2 (en) 2014-02-06 2022-09-20 Juul Labs, Inc. Vaporization device systems and methods
US10709173B2 (en) 2014-02-06 2020-07-14 Juul Labs, Inc. Vaporizer apparatus
US11019685B2 (en) 2014-02-06 2021-05-25 Juul Labs, Inc. Vaporization device systems and methods
US10865001B2 (en) 2016-02-11 2020-12-15 Juul Labs, Inc. Fillable vaporizer cartridge and method of filling
US11751605B2 (en) 2016-02-11 2023-09-12 Juul Labs, Inc. Securely attaching cartridges for vaporizer devices
US10912333B2 (en) 2016-02-25 2021-02-09 Juul Labs, Inc. Vaporization device control systems and methods
US12063973B2 (en) 2016-02-25 2024-08-20 Juul Labs, Inc. Vaporization device control systems and methods
US11766527B2 (en) 2016-09-22 2023-09-26 Juul Labs, Inc. Leak-resistant vaporizer device
US11660403B2 (en) 2016-09-22 2023-05-30 Juul Labs, Inc. Leak-resistant vaporizer device
US11369755B2 (en) 2016-09-22 2022-06-28 Juul Labs, Inc. Leak-resistant vaporizer device
US11759580B2 (en) 2016-09-22 2023-09-19 Juul Labs, Inc. Leak-resistant vaporizer device
US11369756B2 (en) 2016-09-22 2022-06-28 Juul Labs, Inc. Leak-resistant vaporizer device
US12023434B2 (en) 2016-09-22 2024-07-02 Pax Labs, Inc. Leak-resistant vaporizer device
US11369757B2 (en) 2016-09-22 2022-06-28 Juul Labs, Inc. Leak-resistant vaporizer device
JP2018187831A (ja) * 2017-05-02 2018-11-29 株式会社パイロットコーポレーション 筆記具用水性インキ収容体
CN112888576A (zh) * 2018-09-20 2021-06-01 波雷克斯科技公司 非均质纤维流体储存器
WO2020061492A1 (en) * 2018-09-20 2020-03-26 Porex Technologies Corporation Heterogeneous fiber fluid reservoirs
US11865857B2 (en) 2018-09-20 2024-01-09 Porex Technologies Corporation Heterogeneous fiber fluid reservoirs

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KR20010043725A (ko) 2001-05-25
WO1999061258A1 (fr) 1999-12-02
EP1093936A4 (de) 2004-03-31
AU3954699A (en) 1999-12-13

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