EP1056602B1 - Verwendung eines wärmeempfindlichen aufzeichnungsmaterials als etikett - Google Patents
Verwendung eines wärmeempfindlichen aufzeichnungsmaterials als etikett Download PDFInfo
- Publication number
- EP1056602B1 EP1056602B1 EP99913163A EP99913163A EP1056602B1 EP 1056602 B1 EP1056602 B1 EP 1056602B1 EP 99913163 A EP99913163 A EP 99913163A EP 99913163 A EP99913163 A EP 99913163A EP 1056602 B1 EP1056602 B1 EP 1056602B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- heat
- sensitive recording
- recording material
- protective layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2848—Three or more layers
Definitions
- the present invention relates to the use of a heat-sensitive recording material, consisting of a layer support, one on the front of the Layer-arranged arranged heat-sensitive recording layer containing a dye precursor and a dye acceptor that are in contact with the dye precursor undergoes a color formation reaction, one between the substrate and heat sensitive Recording layer arranged intermediate layer and a die heat sensitive recording layer covering by means of actinic radiation hardened protective layer.
- a heat-sensitive recording material of the type specified above is known from DE-C-33 12 716 .
- the protective layer specified there serves to limit harmful influences which act on the recording material through water, plasticizers, oils or organic solvents and impair the stability of the image density.
- a heat-sensitive recording material with a glossy surface which has a protective layer hardened by actinic radiation which is said to show excellent adaptability to the thermal head without causing pressure drops.
- a heat-sensitive recording material which has a protective layer arranged over the heat-sensitive recording layer and a backside coating, both of which are hardened by means of electron beams.
- a protective layer arranged over the heat-sensitive recording layer and a backside coating, both of which are hardened by means of electron beams.
- an intermediate layer made of crosslinked polymers which has also been hardened by means of electron beams. This intermediate layer is intended to limit the influence of the carrier material on the color formation reaction and the contrast of the resulting image with the background of the image.
- DE-A-42 25 419 discloses a heat-sensitive recording material with a cover layer which has a resin curable by ionizable radiation, the cover layer containing a silicone surface active agent and microspheres of low molecular weight olefin polymer resin.
- the known heat-sensitive recording material is to be used as a sticker, for example in a fully automatic labeling machine, on the one hand avoiding contamination of the recording head by components of the cover layer, but on the other hand a perfect printability should be ensured.
- a process for producing a heat-sensitive layer and a protective layer to be applied to the heat-sensitive layer from the mixture of a water-soluble or water-dispersible binder which can be crosslinked with electron beams and a prepolymer or monomer which is curable by means of electron beams is known from EP-B-0 159 659. It is stated that better resistance to water or moisture is to be achieved compared to the conventional heat-sensitive recording materials. For this purpose the use of polysiloxane compounds is proposed.
- a heat-sensitive recording material is also known from EP-A-0 780 241 , the protective layer of which contains a silicone component. This proposal is intended to achieve better behavior of the recording material on the thermal head and to reduce the so-called fogging.
- a heat-sensitive recording material which has two intermediate layers applied to the heat-sensitive recording layer, namely a barrier layer and a release layer provided on the barrier layer, the release layer consisting mainly of compounds containing silicone.
- WO 97/07985 A1 discloses a heat-sensitive recording material with an adhesive layer on the back and a protective layer which covers the heat-sensitive recording layer and is crosslinked by means of ultraviolet radiation or electron beam , which forms a matrix for embedding the first component. Other than components consisting of silicone are not disclosed. If the heat-sensitive recording material is wound onto a roll, the adhesive layer on the back and the protective layer come into contact.
- the heat-sensitive recording material according to WO 97/07985 A1 should have a matt, writable surface which does not cause excessive wear of the thermal head, adheres only slightly to the adhesive layer and cleans the thermal head mechanically. Flexographic and offset printing processes are explicitly used only for printing addressed before applying the protective layer. The use according to the invention of a heat-sensitive recording material with a protective layer free of silicone-containing compounds as the label material to be printed in offset or flexographic printing is not known from WO 97/07985 A1
- US-A-4 833 116 aims to improve the recording quality and the stability of the recorded image.
- this document relates to a recording material intended for the video printing process.
- An intermediate layer to be formed on the heat-sensitive recording layer based on an aqueous resin is coated with a protective layer curable by electron beams, to which a fine silicone powder is added.
- EP-A-0764 548 provides a disposible sheet of disposable sheet made of neutral paper for covering the adhesive layer applied to the back of a heat-sensitive recording material.
- the heat-sensitive recording material is intended for use as a label.
- the use of a recording material wound on a roll in offset or flexographic printing - without a paper sheet covering the adhesive layer - is not known from this document
- Heat-sensitive recording papers the protective layer of which is a silicone component contains, are already without additional use of release paper for the production of labels that can be unwound from rolls.
- Through the silicone additive should avoid sticking of the back adhesive layer with the protective layer become. This creates the disadvantage that the printability in the silicone additive Flexo and offset printing is affected.
- the roll form a thermal printer is supplied, with the use of a release paper or a silicone additive is dispensed with in the protective layer, so that a satisfactory printability in the FIexo and offset printing is guaranteed.
- actinic radiation used in claims and description are to be understood as UV or ionizing radiation, such as electron beams.
- the surface layer is to be hardened by means of UV rays the monomers or prepolymers used in the top layer in a known manner of initiators included.
- By electron beam hardening one could over her Cross-section formed particularly evenly, d. H. cured, top layer achieved become.
- the formation of the cover layer with a basis weight in the range from 0.5 to 3.5 g / m 2 is preferred
- the one present in the protective layer and by means of actinic Radiation-cured resin component from the monomers or prepolymers of Acrylate and / or methacrylate is formed.
- Photoinitiators can be found in a minor amount of pigments and cross-linking agents in the top layer available; in any case, however, the top layer is free of silicone Links.
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
Claims (2)
- Verwendung eines wärmeempfindlichen Aufzeichnungsmaterials, bestehend aus:a) einem Schichtträger, auf dessen Vorderseite eine wärmeempfindliche Aufzeichnungsschicht angeordnet ist, die einen Farbstoffvorläufer und einen Farbakzeptor enthält, der bei Kontakt mit dem Farbstoffvorläufer einer Farbbildungsreaktion unterliegt,b) einer zwischen Schichtträger und wärmeempfindlicher Aufzeichnungsschicht angeordneten Zwischenschicht,c) einer die wärmeempfindliche Aufzeichnungsschicht abdeckenden und mittels aktinischer Strahlung gehärteten von silikonhaltigen Verbindungen freien Schutzschicht, sowied) einer auf der Rückseite des Schichtträgers angeordneten Selbstklebeschicht,e) als auf Rolle aufwickelbares und im Offset-oder Flexodruckverfahren zu bedruckendes Etikettenmaterial, bei dem in der Rolle die Selbstkiebeschicht mit der Schutzschicht in Kontakt steht.
- Verwendung eines wärmeempfindlichen Aufzeichnungsmaterials nach Anspruch 1 mit einer Schutzschicht, deren mittels aktinischer Strahlung ausgehärtete Harzkomponente aus den Monomeren oder Prepolymeren von Acrylat und/oder Methacrylat gebildet ist.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19806433 | 1998-02-17 | ||
DE19806433A DE19806433B4 (de) | 1998-02-17 | 1998-02-17 | Verwendung eines wärmeempfindlichen Aufzeichnungsmaterials als Etikett |
PCT/EP1999/000964 WO1999042298A1 (de) | 1998-02-17 | 1999-02-13 | Verwendung eines wärmeempfindlichen aufzeichnungsmaterials als etikett |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1056602A1 EP1056602A1 (de) | 2000-12-06 |
EP1056602B1 true EP1056602B1 (de) | 2002-05-15 |
Family
ID=7857943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99913163A Expired - Lifetime EP1056602B1 (de) | 1998-02-17 | 1999-02-13 | Verwendung eines wärmeempfindlichen aufzeichnungsmaterials als etikett |
Country Status (8)
Country | Link |
---|---|
US (1) | US6623852B1 (de) |
EP (1) | EP1056602B1 (de) |
JP (1) | JP2002503573A (de) |
AT (1) | ATE217583T1 (de) |
DE (2) | DE19806433B4 (de) |
ES (1) | ES2177266T3 (de) |
NO (1) | NO20000768L (de) |
WO (1) | WO1999042298A1 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10051294C1 (de) * | 2000-10-16 | 2002-04-18 | Mitsubishi Hitec Paper Flensbu | Wärmeempfindlicher Aufzeichnungsbogen und seine Verwendung |
DE20117479U1 (de) * | 2001-10-25 | 2003-03-06 | Hummel Gmbh & Co | Veredeltes Thermopapier |
DE10341168A1 (de) | 2003-09-06 | 2005-04-07 | Mitsubishi Hitec Paper Flensburg Gmbh | Wärmeempfindliches Aufzeichnungsmaterial und seine Verwendung |
ES2684629T3 (es) * | 2015-06-24 | 2018-10-03 | Mitsubishi Hitec Paper Europe Gmbh | Material de registro termosensible |
WO2021011939A1 (en) * | 2019-07-18 | 2021-01-21 | Isp Investments Llc | Flexible self-adhesive label comprising a radiation-sensitive indicator for a syringe |
EP3885152B1 (de) | 2020-03-23 | 2022-06-08 | Koehler Innovation & Technology GmbH | Verwendung von n-(p-toluolsulfonyl)-n'-(3-p-toluolsulfonylfonyloxyphenyl) harnstoff als farbentwickler in einem wärmeempfindlichen aufzeichnungsmaterial |
WO2024078971A1 (de) | 2022-10-11 | 2024-04-18 | Koehler Innovation & Technology Gmbh | Wärmeempfindliches aufzeichnungsmaterial |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4484204A (en) | 1982-04-10 | 1984-11-20 | Kanzaki Paper Manufacturing Co., Ltd. | Heat-sensitive record material |
JPS60220786A (ja) * | 1984-04-17 | 1985-11-05 | Kanzaki Paper Mfg Co Ltd | 感熱記録体の製造方法 |
US4711874A (en) * | 1984-08-20 | 1987-12-08 | Ricoh Company, Ltd. | Thermosensitive recording adhesive sheet |
US4717709A (en) | 1984-11-02 | 1988-01-05 | Tomoegawa Paper Manufacturing Co., Ltd. | Thermosensitive recording material |
US4833116A (en) * | 1986-10-16 | 1989-05-23 | Kanzaki Paper Mfg. Co., Ltd. | Heat-sensitive recording material |
DE3935070A1 (de) | 1988-10-21 | 1990-04-26 | Dainippon Ink & Chemicals | Waermeempfindliches wiedergabemedium und harzzusammensetzung fuer einen deckueberzug dafuer |
EP0373903B1 (de) | 1988-12-12 | 1995-02-15 | Tomoegawa Paper Co. Ltd. | Wärmeempfindliches Aufzeichnungspapier für Etiketten |
DE4012185C1 (de) * | 1990-04-14 | 1991-05-23 | Renker Gmbh & Co Kg, 5160 Dueren, De | |
JPH0532051A (ja) | 1991-07-31 | 1993-02-09 | Kanzaki Paper Mfg Co Ltd | 感熱記録体 |
US5840657A (en) * | 1994-02-18 | 1998-11-24 | The Standard Register Company | Imagable linerless pressure sensitive adhesive |
JP3071130B2 (ja) * | 1994-09-13 | 2000-07-31 | 株式会社巴川製紙所 | 可逆性感熱記録媒体 |
US5658661C1 (en) | 1995-08-29 | 2002-06-11 | Media Solutions Inc | Matted release coat for self-wound thermal printable facestock |
JPH09183270A (ja) * | 1995-09-21 | 1997-07-15 | Ricoh Co Ltd | 感熱記録型剥離ラベル |
US5866508A (en) | 1995-12-21 | 1999-02-02 | Ricoh Company, Ltd. | Thermosensitive recording material |
US5977021A (en) * | 1996-12-24 | 1999-11-02 | Oji Paper Co., Ltd | Heat-sensitive recording adhesive sheet |
-
1998
- 1998-02-17 DE DE19806433A patent/DE19806433B4/de not_active Expired - Fee Related
-
1999
- 1999-02-13 JP JP2000532280A patent/JP2002503573A/ja active Pending
- 1999-02-13 EP EP99913163A patent/EP1056602B1/de not_active Expired - Lifetime
- 1999-02-13 WO PCT/EP1999/000964 patent/WO1999042298A1/de active IP Right Grant
- 1999-02-13 DE DE59901445T patent/DE59901445D1/de not_active Expired - Lifetime
- 1999-02-13 AT AT99913163T patent/ATE217583T1/de not_active IP Right Cessation
- 1999-02-13 US US09/622,494 patent/US6623852B1/en not_active Expired - Lifetime
- 1999-02-13 ES ES99913163T patent/ES2177266T3/es not_active Expired - Lifetime
-
2000
- 2000-02-16 NO NO20000768A patent/NO20000768L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
ES2177266T3 (es) | 2002-12-01 |
WO1999042298A1 (de) | 1999-08-26 |
DE19806433B4 (de) | 2004-11-11 |
DE19806433A1 (de) | 1999-08-19 |
NO20000768D0 (no) | 2000-02-16 |
US6623852B1 (en) | 2003-09-23 |
JP2002503573A (ja) | 2002-02-05 |
NO20000768L (no) | 2000-03-24 |
ATE217583T1 (de) | 2002-06-15 |
EP1056602A1 (de) | 2000-12-06 |
DE59901445D1 (de) | 2002-06-20 |
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