EP1032357A1 - Utilisation de solvants fluores pour la formulation de lotions pour soins capillaires - Google Patents
Utilisation de solvants fluores pour la formulation de lotions pour soins capillairesInfo
- Publication number
- EP1032357A1 EP1032357A1 EP98956964A EP98956964A EP1032357A1 EP 1032357 A1 EP1032357 A1 EP 1032357A1 EP 98956964 A EP98956964 A EP 98956964A EP 98956964 A EP98956964 A EP 98956964A EP 1032357 A1 EP1032357 A1 EP 1032357A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- lotions
- hair
- fluorinated
- formulation
- fluorinated solvents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000006210 lotion Substances 0.000 title claims abstract description 31
- 239000002904 solvent Substances 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 title description 21
- 238000009472 formulation Methods 0.000 title description 9
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 claims description 5
- 229940104873 methyl perfluorobutyl ether Drugs 0.000 claims description 5
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical class CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical class CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 208000032484 Accidental exposure to product Diseases 0.000 description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 2
- 235000007866 Chamaemelum nobile Nutrition 0.000 description 2
- 241000218691 Cupressaceae Species 0.000 description 2
- 208000001840 Dandruff Diseases 0.000 description 2
- 244000178870 Lavandula angustifolia Species 0.000 description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 2
- 240000003553 Leptospermum scoparium Species 0.000 description 2
- 235000015459 Lycium barbarum Nutrition 0.000 description 2
- 244000042664 Matricaria chamomilla Species 0.000 description 2
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 2
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical class CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- -1 for example Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001102 lavandula vera Substances 0.000 description 2
- 235000018219 lavender Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MRAMPOPITCOOIN-VIFPVBQESA-N (2r)-n-(3-ethoxypropyl)-2,4-dihydroxy-3,3-dimethylbutanamide Chemical compound CCOCCCNC(=O)[C@H](O)C(C)(C)CO MRAMPOPITCOOIN-VIFPVBQESA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 201000004384 Alopecia Diseases 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000021513 Cinchona Nutrition 0.000 description 1
- 241000157855 Cinchona Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- 206010041349 Somnolence Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 231100001133 acute intoxication condition Toxicity 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 210000004381 amniotic fluid Anatomy 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 210000002808 connective tissue Anatomy 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000035475 disorder Diseases 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002489 hematologic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 150000002634 lipophilic molecules Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000003533 narcotic effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 230000003169 placental effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004393 prognosis Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 231100000041 toxicology testing Toxicity 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 229940124549 vasodilator Drugs 0.000 description 1
- 239000003071 vasodilator agent Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
- A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
- A61K8/315—Halogenated hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Definitions
- the invention relates to the field of the cosmetic and pharmaceutical industry. More specifically, the invention relates to hair care lotions for cosmetic or pharmaceutical use.
- Hair care lotions are generally used to tone the hair, remove dandruff and other impurities from the scalp, and remove excess sebum secreted by the scalp. Certain hair lotions can also be used for therapeutic purposes. These lotions are generally for specific actions.
- a vehicle which most often consists of ethanol titrating 30 to 50 °, chosen for its antiseptic properties and its ability to evaporate quickly;
- - emollients such as, for example, castor oil and its derivatives, which compensate for the drying action of ethanol;
- Hair loss lotions can also contain:
- vasodilator compounds such as, for example, extracts of capsicum, cinchona or nicotinic esters;
- panthenol or ethers derived pantothenyl-ethyl-ether which would be factors of growth of the hair;
- Fragrance substances such as camphor or oils essential, dyes as well as stabilizers (antioxidants, pH correctors) can complete the basic composition of such lotions for hair use.
- These lotions are generally presented in the form of a monophasic or biphasic liquid system.
- monophasic systems the various constituents of the lotion are dissolved or dispersed in water or in a hydroalcoholic mixture.
- two-phase liquid lotions it is added to the formulation of deodorized light petroleum. This feature makes it possible to add to the lotion various lipophilic constituents which are poorly soluble in the hydroalcoholic phase. The immiscibility of light oil and water or hydroalcoholic solutions leads to the formation of the two liquid phases.
- Ethanol which, as already mentioned above, is very generally used as a vehicle in hair lotions, involves a certain number of drawbacks.
- Light oils also frequently used in hair lotion formulations, also have recognized toxicity. By frequent or prolonged contact with the skin, light oils destroy the lipo-acid skin coating and can cause dermatoses of varying severity, with risk of secondary allergy. The vapors are irritating to the mucous membranes. At high concentration, they exert a narcotic action on the central nervous system (headache, dizziness, drowsiness). Certain light oils, officially called petrol A, petrol B and petrol C, have vapors rich in hexane and have been at the origin of serious polyneurites, notably in Japan and in certain European countries including France.
- the objective of the present invention is to provide hair lotions which do not contain ethanol.
- Another object of the present invention is to allow the manufacture of such lotions which also do not contain light petroleum.
- a hair care lotion characterized in that it contains a solvent consisting of at least one fully or partially fluorinated hydrocarbon.
- said fluorinated solvent is chosen from the group consisting of: - linear saturated C j , C 2Q totally or partially fluorinated hydrocarbons;
- fluorinated solvents have decisive advantages over conventional organic solvents, such as ethanol, which form part of the formulation of prior art hair lotions.
- Perfluorinated N-methylmorpholine produces, at doses of 0.1 ml, a slight reversible irritation of the ocular connective tissues but without corneal alteration.
- fluorinated alkanes do not produce eye irritation. Furthermore, no skin irritation is observed for local applications of 0.5 ml of fluorinated solvent.
- the fluorinated compounds proposed by the invention are also completely odorless or not very odorous. They can therefore be incorporated into hair lotion formulations without the risk of masking any perfumes.
- these fluorinated solvents are lipophilic compounds. They therefore make it possible, on the one hand, to dissolve the lipophilic constituents of the formulations and, on the other hand, to contribute to elimination of sebum.
- fluorinated solvents also have the advantage of being chemically inert and of not being able to react with any of the usual constituents of cosmetic formulations. These are volatile compounds which, after evaporation, leave no trace.
- said solvent is chosen from the group consisting of methylperfluorobutylether, perfluorinated octane and perfluorinated nonane.
- said solvent may include a fluorinated compound as described above or a mixture of such fluorinated compounds.
- the light deodorized petroleum of a commercial hair lotion is replaced by a mixture of 50% (v / v) of methylperfluorobutylether (CH 3 -O-
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9715118 | 1997-11-26 | ||
| FR9715118A FR2771287B1 (fr) | 1997-11-26 | 1997-11-26 | Utilisation de solvants fluores pour la formulation de lotions pour soins capillaires |
| PCT/FR1998/002545 WO1999026594A1 (fr) | 1997-11-26 | 1998-11-26 | Utilisation de solvants fluores pour la formulation de lotions pour soins capillaires |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1032357A1 true EP1032357A1 (fr) | 2000-09-06 |
Family
ID=9514025
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98956964A Withdrawn EP1032357A1 (fr) | 1997-11-26 | 1998-11-26 | Utilisation de solvants fluores pour la formulation de lotions pour soins capillaires |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1032357A1 (enExample) |
| JP (1) | JP2001523698A (enExample) |
| AU (1) | AU748913B2 (enExample) |
| CA (1) | CA2311784A1 (enExample) |
| FR (1) | FR2771287B1 (enExample) |
| WO (1) | WO1999026594A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2795641A1 (fr) * | 1999-07-01 | 2001-01-05 | Oreal | Utilisation d'huile fluoree volatile pour estomper les imperfections et matifier la peau, et procede de traitement cosmetique employant ladite huile fluoree volatile |
| FR2811891A1 (fr) * | 2000-07-21 | 2002-01-25 | Oreal | Composition aerosol cosmetique |
| DE10302190A1 (de) * | 2003-01-20 | 2004-07-29 | Hans Schwarzkopf & Henkel Gmbh & Co. Kg | 3-Phasen-Stylingmittel |
| WO2011035034A1 (en) | 2009-09-16 | 2011-03-24 | Living Proof, Inc. | Cationic alcohols and uses thereof |
| KR101368829B1 (ko) * | 2011-03-08 | 2014-03-03 | 소망화장품주식회사 | 일욕식 퍼머넌트 웨이브용 및 스트레이트너용 용제 조성물 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1029527A1 (en) | 1997-08-28 | 2000-08-23 | Daikin Industries, Limited | Cosmetic preparation |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9109693D0 (en) * | 1991-05-03 | 1991-06-26 | Unilever Plc | Hair treatment composition |
| FR2688006A1 (fr) * | 1992-02-27 | 1993-09-03 | Oreal | Dispersion d'un hydrocarbure fluore dans une solution aqueuse d'un polymere filmogene et son utilisation pour la formation de films composites notamment en cosmetique. |
| GB9204509D0 (en) * | 1992-03-02 | 1992-04-15 | Unilever Plc | Hair care composition |
| US5667772A (en) * | 1992-10-29 | 1997-09-16 | Lancaster Group Ag | Preparation containing a fluorocarbon emulsion and usable as cosmetics or dermatics |
-
1997
- 1997-11-26 FR FR9715118A patent/FR2771287B1/fr not_active Expired - Fee Related
-
1998
- 1998-11-26 AU AU13411/99A patent/AU748913B2/en not_active Ceased
- 1998-11-26 CA CA002311784A patent/CA2311784A1/en not_active Abandoned
- 1998-11-26 WO PCT/FR1998/002545 patent/WO1999026594A1/fr not_active Ceased
- 1998-11-26 EP EP98956964A patent/EP1032357A1/fr not_active Withdrawn
- 1998-11-26 JP JP2000521797A patent/JP2001523698A/ja active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1029527A1 (en) | 1997-08-28 | 2000-08-23 | Daikin Industries, Limited | Cosmetic preparation |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO9926594A1 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1341199A (en) | 1999-06-15 |
| CA2311784A1 (en) | 1999-06-03 |
| AU748913B2 (en) | 2002-06-13 |
| JP2001523698A (ja) | 2001-11-27 |
| FR2771287A1 (fr) | 1999-05-28 |
| FR2771287B1 (fr) | 2000-11-03 |
| WO1999026594A1 (fr) | 1999-06-03 |
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