EP1011957A1 - Rigid coloured article - Google Patents

Rigid coloured article

Info

Publication number
EP1011957A1
EP1011957A1 EP98900097A EP98900097A EP1011957A1 EP 1011957 A1 EP1011957 A1 EP 1011957A1 EP 98900097 A EP98900097 A EP 98900097A EP 98900097 A EP98900097 A EP 98900097A EP 1011957 A1 EP1011957 A1 EP 1011957A1
Authority
EP
European Patent Office
Prior art keywords
article
layer
sheet
mould
skin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP98900097A
Other languages
German (de)
English (en)
French (fr)
Inventor
Robert Worley Homer
Roy Stanley Pulley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TETRAFORM COMPOSITES LIMITED
Original Assignee
Pulley Bros Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pulley Bros Ltd filed Critical Pulley Bros Ltd
Publication of EP1011957A1 publication Critical patent/EP1011957A1/en
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/18Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles
    • B29C43/183Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles the preformed layer being a lining, e.g. shaped in the mould before compression moulding, or a preformed shell adapted to the shape of the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/78Moulding material on one side only of the preformed part
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/0854Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002Coloured

Definitions

  • the invention relates to a method of making coloured rigid articles and to the articles
  • the vehicles can have metal panels as an exterior covering it would
  • A-0266107 discloses an article said to be useful as an automobile body panel and comprising a cast weatherable polymer film made up of a pigmented acrylic layer
  • the invention provides a method of making a coloured rigid article
  • thermoplastic polymer to form the precursor of the skin
  • the skin should be capable of being thermoformed (i.e. under vacuum) and have a
  • the skin should be weather and impact resistant and have
  • the thermoplastic layer may be acrylonitrilebutadienestyrene (ABS); an ester of acrylonitrilestyreneacrylic(ASA); polycarbonate and derivatives thereof;
  • thermoplastic polymer is
  • ABS and the pigmented layer is a glossy pigmented layer in a plastics carrier, e.g. a
  • the sheet and layer are a coextrusion which is available under the trade mark "IRIDON".
  • the formed article will need to be secured to a frame or companion articles and it is an
  • the shell may be shaped to engage the free end
  • the sheet is preferably formed of ABS, i.e. acrylonitrilebutadienestyrene, and the polyacrylate carrier for the pigment is preferably polymethylmethacrylate.
  • ABS i.e. acrylonitrilebutadienestyrene
  • polyacrylate carrier for the pigment is preferably polymethylmethacrylate.
  • a high impact form having the following combination of properties: an Izod impact of 380-420 J/m at 23°C; a tensile strength of 30-40 MPa; a density of about 1.1
  • the coextrusion sheet is first vacuum formed, i.e. thermoformed, in a male mould to
  • the resin composition is cured in the mould.
  • the shell comprises shell halves of cured epoxy GRP (which can be made to particularly tight tolerances).
  • the shell halves are located in a mould which is then held in a pressure
  • the shaped sheet is laid in the shell half with the acrylate layer face down, so that the
  • the fibres Preferably have tensile and ductile properties.
  • fibres may be loose but preferably take the form of a mat. While the fibres may be
  • metals selected from a wide range of materials, e.g. metals, non-metals, composites such as
  • the fibre material is preferably
  • the resin composition should be selected to have mechanical properties according to
  • the composition may be selected for sound attenuation, flowability (to allow the moulding of complex shapes); and be capable of being pigmented and colour matched.
  • the resin composition may be selected from a range of curable materials such as PVC,
  • composition is a mixture of acrylic polymer, polyethylene, polyester, polyurethane and the like.
  • the composition is a mixture of acrylic polymer, polyethylene, polyester, polyurethane and the like.
  • composition is selected to form a formed
  • polyurethane in which case it comprises a polyol component, an isocyanate component
  • ingredients may be present such as fillers, blowing agents,
  • the polyol may be based on a polyester,
  • the isocyanate may be methyldiisocyanate
  • the curable resin composition is a polyurethane because
  • Such element may be a threaded bolt the head of
  • Curing is then initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation. Foaming may be initiated chemically or by temperature or other radiation.
  • the invention provides a method of making a coloured rigid article comprising the steps of placing a shaped skin having a pigmented surface in a shaped shell in a pressure and temperature resistant mould with the pigmented surface
  • the skin is a vacuum formed co-extrusion of a layer of an impact resistant
  • the invention provides a rigid shaped article comprising an outer layer
  • the article includes fibre
  • Figure 1 is a side elevation of a coextrusion
  • Figure 2 is a vertical section through a mould containing shell halves and before
  • a coextrusion 1 comprising an acrylonitrile butadiene styrene 1A and a layer of
  • pigmented impact modified polymethacrylate IB is thermo or vacuum formed in a
  • suitable vacuum mould (not shown) at about 160° to 170°C to a required profile P of the skin of the intended article.
  • the coextrusion is selected according to the properties required for the end use; in a preferred case the coextrusion has a density of about 1.1
  • the coextrusion will have a Vicat softening temperature of about
  • a rigid foam backing B is applied to the profile P in a mould shown in Figure 1.
  • mould comprises a base 2 and a lid 3; and has side walls 4.
  • the sidewalls are in
  • bottom and top halves 4A, 4B respective shaped to hold the free edges of the profile P.
  • a paste of a self setting filler composition 5, e.g. a filled plastics is placed in the lower
  • the lower shelf half HI has a shaped upper wall against which
  • the shell half is made of glass reinforced epoxy plastics or the like to tight tolerances, so that the profile is an accurate fit, and
  • uncured polyurethane composition 7 is poured on to the upper, i.e.
  • a top shell half H2 is placed at one end.
  • the panel has been made with a glossy paint finish and at low cost.
  • the shell halves are
  • the invention is not limited to the embodiment shown.
  • the coextrusion may have a shaped face to key to the foam layer.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Glass Compositions (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Graft Or Block Polymers (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
EP98900097A 1997-01-03 1998-01-05 Rigid coloured article Ceased EP1011957A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9700071A GB2320908B (en) 1997-01-03 1997-01-03 Rigid coloured article
GB9700071 1997-01-03
PCT/GB1998/000009 WO1998029233A1 (en) 1997-01-03 1998-01-05 Rigid coloured article

Publications (1)

Publication Number Publication Date
EP1011957A1 true EP1011957A1 (en) 2000-06-28

Family

ID=10805524

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98900097A Ceased EP1011957A1 (en) 1997-01-03 1998-01-05 Rigid coloured article

Country Status (14)

Country Link
EP (1) EP1011957A1 (pt)
JP (1) JP2001507298A (pt)
CN (1) CN1243472A (pt)
AU (1) AU721660B2 (pt)
BR (1) BR9806830A (pt)
CA (1) CA2276663A1 (pt)
CZ (1) CZ238599A3 (pt)
GB (1) GB2320908B (pt)
HU (1) HUP0000864A2 (pt)
IL (1) IL130699A0 (pt)
PL (1) PL334441A1 (pt)
SK (1) SK91299A3 (pt)
TR (1) TR199901970T2 (pt)
WO (1) WO1998029233A1 (pt)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102371683A (zh) * 2010-08-19 2012-03-14 李启文 聚胺酯复合材料及其制备方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10120912A1 (de) 2001-04-27 2002-10-31 Basf Ag Verbundbauteile aus Polyurethan und deren Verwendung in Karosserieaussenteilen
DE10161155B4 (de) * 2001-12-12 2007-08-09 Basf Ag Einleger enthaltende Polyurethan-Verbundbauteile

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2708288A (en) * 1950-05-26 1955-05-17 Frank W Fuller Method and apparatus for molding plastic
US4065337A (en) * 1973-04-18 1977-12-27 Coast Catamaran Corporation Molding process
DE2548318A1 (de) * 1975-10-29 1977-05-05 Theysohn Friedrich Fa Verfahren und vorrichtung zum beschichten von folienmaterial
DE3127253A1 (de) * 1980-07-16 1982-06-16 Comind S.p.A. Azienda Stars, Villastellone, Torino Selbsttragendes element fuer die ausruestung der innenraeume von kraftfahrzeugen, insbesondere instrumentendeck, und verfahren zu dessen herstellung
JPS60176740A (ja) * 1984-02-22 1985-09-10 Hitachi Chem Co Ltd 真空成形品の模様形成方法
JPS6131214A (ja) * 1984-07-23 1986-02-13 Toyota Motor Corp 車輛用装飾モ−ルの製造方法
JPS62181114A (ja) * 1986-02-06 1987-08-08 Meiwa Sangyo Kk 複合成形体の製造方法
CA1292603C (en) * 1986-10-28 1991-12-03 Thomas M. Ellison Injection molded plastic article with integral weatherable pigmented film surface
US4698277A (en) * 1986-11-12 1987-10-06 General Electric Company High-temperature laminated insulating member
ES2081829T3 (es) * 1988-12-22 1996-03-16 Basf Corp Procedimiento para la fabricacion de piezas de automoviles o vehiculos laminadas y recubiertas.
US4983247A (en) * 1989-08-07 1991-01-08 General Electric Company Method for producing resin rich surface layer on composite thermoplastic material
EP0549809A1 (en) * 1991-07-18 1993-07-07 Sumitomo Chemical Company Limited Method of manufacturing laminated molding
JPH05147170A (ja) * 1991-12-02 1993-06-15 Toppan Printing Co Ltd 多層プラスチツク成形品およびその製造方法
TW224443B (pt) * 1992-07-31 1994-06-01 Minnesota Mining & Mfg
JPH06144123A (ja) * 1992-11-10 1994-05-24 Kasai Kogyo Co Ltd 自動車用内装部品およびその製造方法
JPH06287323A (ja) * 1993-04-05 1994-10-11 Mitsui Petrochem Ind Ltd 高耐突き刺し性表皮シートおよびこの表皮シートを用いた積層体
TW300227B (pt) * 1993-12-20 1997-03-11 Sumitomo Chemical Co
US5514320A (en) * 1995-04-25 1996-05-07 Akemi, Inc. Method of making a hollow tool

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9829233A1 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102371683A (zh) * 2010-08-19 2012-03-14 李启文 聚胺酯复合材料及其制备方法

Also Published As

Publication number Publication date
TR199901970T2 (xx) 2000-08-21
GB2320908B (en) 1999-04-28
GB2320908A (en) 1998-07-08
IL130699A0 (en) 2000-06-01
CN1243472A (zh) 2000-02-02
SK91299A3 (en) 2000-03-13
CA2276663A1 (en) 1998-07-09
AU5334798A (en) 1998-07-31
BR9806830A (pt) 2002-01-02
GB9700071D0 (en) 1997-02-19
JP2001507298A (ja) 2001-06-05
HUP0000864A2 (hu) 2000-08-28
WO1998029233A1 (en) 1998-07-09
CZ238599A3 (cs) 1999-12-15
PL334441A1 (en) 2000-02-28
AU721660B2 (en) 2000-07-13

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