EP0989908A2 - Conversion d'un gaz de synthese en olefines de faible poids moleculaire a l'aide de tamis moleculaires modifies - Google Patents

Conversion d'un gaz de synthese en olefines de faible poids moleculaire a l'aide de tamis moleculaires modifies

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Publication number
EP0989908A2
EP0989908A2 EP98931364A EP98931364A EP0989908A2 EP 0989908 A2 EP0989908 A2 EP 0989908A2 EP 98931364 A EP98931364 A EP 98931364A EP 98931364 A EP98931364 A EP 98931364A EP 0989908 A2 EP0989908 A2 EP 0989908A2
Authority
EP
European Patent Office
Prior art keywords
catalyst
molecular sieves
group
sapo
synthesis gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98931364A
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German (de)
English (en)
Inventor
Hsiang-Ning Sun
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to EP01111008A priority Critical patent/EP1153660A3/fr
Publication of EP0989908A2 publication Critical patent/EP0989908A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]

Definitions

  • the invention relates to a process for incorporating catalysts for the conversion of synthesis gas, preferably synthesis gas comprising carbon dioxide and hydrogen, into molecular sieves. More particularly, the invention relates to a process for incorporating into molecular sieves a catalyst selected from the group consisting of iron, cobalt, nickel, chromium, manganese, and rhodium, in an amount sufficient to catalyze the conversion of synthesis gas to lower olefins.
  • olefins such as ethylene, propylene, and butenes
  • Olefins traditionally are produced by petroleum cracking. Because of the limited supply and/or the high cost of petroleum sources, the cost of producing olefins from petroleum sources has increased steadily.
  • a known alternative feedstock for the production of lower olefins is synthesis gas.
  • Synthesis gas is a combination of hydrogen with either carbon monoxide or carbon dioxide.
  • Synthesis gas can be made from non-petroleum organic sources, such as coal, recycled plastics, and municipal wastes.
  • the catalysts used to convert synthesis gas to olefins are known as one type of Fischer-Tropsch catalysts.
  • Fischer-Tropsch catalysts typically are supported on various solids such as molecular sieves.
  • Molecular sieves are ordered, porous crystalline materials with a definite three dimensional crystal structure within which are a large number of small channels or pores. The channels and pores in any specific molecular sieve material are precisely uniform in size.
  • the pores accept for adsorption molecules which are small enough to pass through the pores, while rejecting molecules of larger size.
  • Molecular sieves are used in various ways which take advantage of this property; for example, as catalysts or as supports for catalysts which may be incorporated into the molecular sieve as a framework.
  • the present invention provides a method for incorporating one or more Fischer Tropsch catalysts into molecular sieves comprising contacting untreated molecular sieves with a catalyst precursor in an inert atmosphere under first conditions effective to form complexes comprising said catalyst precursor and said molecular sieves; and, exposing said complexes to an inert atmosphere and to second conditions effective to dissociate volatile components from said catalyst precursor and to evaporate solvent from said complexes, forming modified molecular sieves comprising a catalytically effective amount of a catalyst selected from the group consisting of iron, cobalt, nickel, chromium, manganese, and rhodium.
  • the present invention provides catalysts which will convert a carbon dioxide rich synthesis gas to olefins, and which can be manipulated to produce varying amounts of ethylene, propylene, and butenes.
  • any molecular sieves may be used in the invention.
  • One group of suitable molecular sieves is the zeolite group.
  • the structural formula of a zeolite is best expressed for the crystallographic unit cell as
  • M a cation of valence n
  • w the number of water molecules
  • the ratio y/x usually has values of 1-5000, depending upon the structure.
  • (x+y) is the total number of SiO plus AI0 tetrahedra in the unit cell. The portion within brackets represents the framework composition.
  • zeolites Several types exist, each of which exhibit different properties and different utilities. Perhaps the best known zeolites are synthetic crystalline aluminosilicate zeolites, which have a rigid three-dimensional network of SiO 4 ' and AIO 4 " tetrahedra, which are cross-linked through shared oxygen atoms. The electronegativity of the aluminum-containing tetrahedra is balanced by the inclusion in the crystal of a cation, typically monovalent or divalent, such as an alkali metal (e.g., sodium) or an alkaline earth metal.
  • Synthetic crystalline aluminosilicate zeolites include MFI zeolites and ZSM-5, which is described, for example, in US-A- 3,702,886 to Argauer et al.
  • ferrisilicate molecular sieves such as ZSM-12.
  • ZSM-12 type molecular sieves consist structurally of a three-dimensional network of SiO 4 , FeO 4 , and optionally AIO 4 , GaO 4 , GeO 4 tetrahedra which are interlinked by oxygen atoms.
  • Suitable zeolites for use in the invention include, but are not necessarily limited to ZSM-34, erionite, chabazite, and offretite. Zeolites with a relatively high silica-to-alumina atomic ratio are preferred.
  • the silica-to- alumina atomic ratio may be in the range of from about 20 to about 4000, preferably from about 40 to about 2000, and most preferably from about 100 to about 800.
  • the most effective silica-to-alumina ratio appears to be in the range of from about 200 to about 300.
  • SAPO's Silicoaluminophosphates
  • the chemical composition is: mR:(Si ⁇ Al y P z )O 2 wherein "R” represents at least one organic templating agent present in the intracrystalline pore system: "m” represents the moles of “R” present per mole of (Si x Al y P z )O 2 and has a value of from zero to 0.3, the maximum value in each case depending upon the molecular dimensions of the templating agent and the available void volume in the pore system of the particular SAPO species involved, and "x", "y”, and “z” represent the mole fractions of silicon, aluminum and phosphorus, respectively. "R” may be removed at elevated temperatures.
  • SAPO's for use in the invention include, but are not necessarily limited to SAPO-34, SAPO-18, SAPO-17, SAPO-11 , and SAPO-5.
  • SAPO's and zeolites may be synthesized according to US-A-4,440,871 , incorporated herein by reference, and Zeolites, Vol. 17, pp. 512-522 (1996), incorporated herein by reference.
  • Aluminophospho catalysts are another type of molecular sieves useful in the present invention.
  • Suitable ALPO's for use in the invention include, but are not necessarily limited to ALPO-17, ALPO-5, ALPO-11 , ALPO-20, and ALPO-25.
  • US-A- 4,310,440 incorporated herein by reference, gives a good general description of ALPO's.
  • MeAPSO's Crystalline metal silico- aluminophosphates
  • MeAPO's crystalline metal aluminophospho oxides
  • Suitable MeAPSO's and MeAPO'S include, but are not necessarily limited to SAPO's and alumino phospho oxides comprising preferably in the range of from about 0.005 to about 0.05 moles of a metal selected from the group consisting of magnesium, zinc, iron, cobalt, nickel, manganese, chromium, and mixtures thereof.
  • US-A-4, 567,029 is a good general description of MeAPSO's.
  • Preferred molecular sieves for use in the invention are (a) intermediate pore zeolites with a silicon to aluminum ratio in the range of from about 100 to about 800, preferably in the range of from about 200 to about 300, and (b) small pore SAPO's.
  • the preparation of the framework for molecular sieves is well known in the art and is described in U.S. Patent Nos.: 4,554,143; 4,440,871; 4,853,197; 4,793,984, 4,732,651; and 4,310,440, all of which are incorporated herein by reference.
  • the molecular sieves of the present invention should be treated to incorporate a catalyst selected from the group consisting of iron, cobalt, nickel, chromium, manganese, and rhodium.
  • the catalyst may be incorporated into the molecular sieves by many different methods, such as the techniques of incipient wetness, wet impregnation, solid state mixing, soxhlet impregnation, vapor deposition, and other techniques.
  • the catalyst typically is contacted with the molecular sieves in the form of a catalyst precursor.
  • Suitable catalyst precursors include, but are not necessarily limited to compounds comprising the catalyst and a volatile material which relatively easily disassociates from the catalyst, especially at high temperatures.
  • Suitable catalyst precursors are selected from the group consisting of metal carbonyls, metal alkoxides, metal carboxylates, organometallics, and combinations thereof.
  • Preferred catalyst precursors are carbonyls, including but not limited to iron carbonyls, other metal carbonyls, and mixed metal carbonyl cluster compounds.
  • Suitable carbonyl precursors may be anionic, cationic, non- ionic, or radical.
  • suitable catalyst precursors include, but are not necessarily limited to: Fe(CO) 4 ; Fe(CO) 5 ; Fe 2 (CO) 9 ; Fe 3 (CO) ⁇ 2 ; Na 2 Fe(CO) 4 ; NaHFe 3 (CO)n; Na 2 Fe 4 (CO) ⁇ 3 ; C 5 H 5 Fe(CO) 2 CH 3 ; C 4 H 4 Fe(CO) 3 ; C 4 H 8 Fe(CO) 3 ; C 4 H 6 Fe(CO) 3 ; C 4 H 5 OHFe(CO) 3 ; [C 5 H 5 Fe(CO) 2]2 ; (C 5 H 5 ) 4 Fe 4 (CO) 4 ; HFe 4 (CO) 12 (CH); Co 2 (CO) 8 ; Ni(CO) 4
  • the catalyst precursor should be dissolved in a suitable solvent.
  • suitable solvents include, but are not necessarily limited to lower alcohols and ketones, such as methanol, ethanol, ethylene glycol, acetone, etc.
  • Preferred solvents are methanol and ethanol.
  • the solvent should be used in an amount large enough to dissolve and complex the catalyst precursor with the molecular sieves but small enough to evaporate off the resulting complexes in a reasonably short period of time, preferably no longer than about 8-16 hours.
  • the molecular sieves preferably should be placed in an inert environment, such as a nitrogen purged box, at a pressure in the range of from about 1.01 kPa (1 x 10 '2 atm) to about 1.01 x 10 5 kPa (1 x 10 3 atm), preferably from about 10.1 kPa (0.1 atm) to about 5.07 x 10 4 kPa (5 x 10 2 atm), most preferably from about 50.67 kPa (0.5 atm) to about 3.04 x 10 4 kPa (3 x 10 2 atm).
  • the precursor solution should be added, and the mixture should be stirred for an amount of time sufficient to complex the precursor with the molecular sieves.
  • the stirring time may range from about 10 minutes to about 16 hours, depending upon the size of the catalyst precursor molecules and temperature. Larger precursor molecules require a longer period of stirring in order to be incorporated into the molecular sieves.
  • Another aliquot of the precursor solution should be added and the resulting complexes should be allowed to dry at ambient temperature, typically around 25 °C, in an inert atmosphere for at least about 4 hours or until the solvent evaporates.
  • the mixture then should be subjected to vacuum for at least about 2 hours, preferably in the range of from about 8 -16 hours.
  • the procedure may be repeated, as necessary, until a desired amount of catalyst is incorporated into the molecular sieves.
  • the complexes then should be heated to a temperature sufficient to disassociate volatile components of said catalyst precursor from said catalyst.
  • the complexes then should be calcined.
  • Preferred temperatures for calcination are in the range of from about 300 °C to about 800 °C, preferably in the range of from about 350 °C to about 650 °C, most preferably about 480 °C.
  • the amount of catalyst incorporated into the molecular sieve may vary over a wide range depending, at least in part, on the selected catalyst and the incorporation method.
  • the total weight percent of catalyst on the molecular sieves should be the following where the listed metal is the catalyst: for iron based catalysts, in the range of from about 1.0 wt% to about 40 wt%; for nickel based catalysts, in the range of from about 0.5 wt% to about 30 wt%; for cobalt based catalysts, in the range of from about 0.5 wt% to about 30 wt%; for chromium based catalysts, in the range of from about 0.5 wt% to about 25 wt%; for osmium based catalysts, in the range of from about 0.5 wt% to about 25 wt%; and for catalysts comprising 2 or more metals, in the range of from about 0.5 wt% to about 40 wt%.
  • a preferred total weight percent of catalyst will be in the range of from about 0.01 wt% to about 80 wt%, preferably in the range of from about 0.1 wt% to about 60 wt%, most preferably in the range of from about 0.5 wt% to about 40 wt%
  • the conversion process employs a feed of synthesis gas comprising hydrogen and either carbon monoxide or carbon dioxide.
  • synthesis gas comprising hydrogen and either carbon monoxide or carbon dioxide.
  • the catalysts of the present invention also are effective to convert synthesis gas which is rich in carbon monoxide.
  • gas consists essentially of hydrogen and carbon dioxide at a molar ratio in the range of from about 1:1 to about 10:1 , preferably from about 2:1 to about 6:1 , most preferably of about 3:1.
  • a preferred ratio of CO:hydrogen is in the range of from about 0.01:10, preferably from about 0.1 :5, most preferably from about 0.2:2.
  • the conversion of feed to olefins preferably should be carried out in the vapor phase.
  • the feedstock should be contacted in the vapor phase in a reaction zone with the defined molecular sieves at effective process conditions so as to produce the desired olefins, i.e., an effective temperature, pressure, GHSV (Gas Hourly Space Velocity) and, optionally, an effective amount of diluent, correlated to produce olefins.
  • the process may be carried out in the liquid phase in the presence of solvent. When the process is carried out in the liquid phase, different conversion rates and selectivities of feedstock-to-product may result depending upon the composition of the liquid.
  • the temperature employed in the conversion process may vary over a wide range depending, at least in part, on the selected catalyst. Although not limited to a particular temperature, best results will be obtained if the process is conducted at temperatures in the range of from about 130 °C to about 600 °C, preferably in the range of from about 180 °C to about 450 °C, most preferably in the range of from about 220 °C to about 350 °C. Lower temperatures generally result in lower rates of reaction. However, at higher temperatures, the process may not form an optimum amount of lower olefin products, and the coking rate may become too high.
  • Lower olefin products will form-although not necessarily in optimum amounts-at a wide range of pressures, including but not limited to autogenous pressures and pressures in the range of from about 0.1 kPa (9.8 x 10 "4 atm) to about 100 MPa (98 atm).
  • a preferred pressure is in the range of from about 6.9 kPa (6.76 x 10 '2 atm) to about 34 MPa (3.33 X 10 2 atm), most preferably from about 48 kPa (0.47 atm) to about 0.34 MPa (3.33 atm).
  • the foregoing pressures are exclusive of diluent, if any, and refer to the partial pressure of the feedstock as it relates to synthesis gas. Pressures outside of the stated ranges may operate and are not excluded from the scope of the invention. Lower and upper extremes of pressure may adversely affect selectivity, conversion, coking rate, and/or reaction rate; however, lower olefins still may form.
  • the process should be continued for a period of time sufficient to produce the desired lower olefins.
  • the reaction time may vary from tenths of seconds to a number of hours.
  • the reaction time is largely determined by the reaction temperature, the pressure, the catalyst selected, the weight hourly space velocity, the phase (liquid or vapor), and the selected process design characteristics.
  • GHSV gas hourly space velocity
  • the GHSV generally should be in the range of from about 10 - 100,000 hr "1 , preferably in the range of from about 100 - 10,000 hr '1 , and most preferably in the range of from about 500 - 5000 hr '1 .
  • the catalyst may contain other materials which act as inerts, fillers, or binders; therefore, the GHSV is calculated on the volume basis of synthesis gas feed and catalyst.
  • the feed may contain one or more diluents in an amount in the range of from about 1-99 vol%, preferably in the range of from about 5-90 vol%, most preferably in the range of from about 10-50 vol%, based on the total number of moles of all feed and diluent components fed to the reaction zone (or catalyst).
  • Diluents which may be employed in the process include, but are not necessarily limited to, helium, argon, nitrogen, water, and mixtures thereof. Preferred diluents are argon and nitrogen.
  • the process may be carried out in a batch, semi-continuous, or continuous fashion.
  • the process may use a single reaction zone or a number of reaction zones arranged in series or in parallel.
  • the process may be intermittent or continuous in an elongated tubular zone or a number of such zones.
  • one or more of the catalysts advantageously may be used in series to provide for a desired product mixture.
  • a dynamic bed system or any system that includes a variety of transport beds rather than fixed beds, may be desirable. If regeneration of the catalyst is required, such a system would permit introduction of the catalyst as a moving bed to a regeneration zone where, e.g., carbonaceous material could be removed or oxidized. Preferably, the catalyst should be regenerated by burning off carbonaceous deposits that accumulate during the process.
  • Example I The procedures of Example I were repeated using 7.007 g of a ZSM-5 molecular sieve with a Si:AI ratio of 180.
  • Example I The procedures of Example I were repeated using 7.003 g of a ZSM-5 molecular sieve with a Si:AI ratio of 1000.
  • Example IV The procedures of Example IV were repeated using 7.002 g of SAPO-17 powder.
  • Example VI 5.0 cc of the ZSM-5 supported catalyst prepared in Example II was evaluated as in Example VI. Gas chromatographic analysis revealed 20% C0 2 conversion and 65 wt% total selectivity of ethylene and propylene.
  • Example VIII 5.0 cc of the ZSM-5 supported catalyst in Example III was evaluated as in Example VI. Gas chromatographic analysis revealed 8% CO 2 conversion and 35 wt% total selectivity of ethylene and propylene.
  • Example IX

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract

Cette invention concerne un procédé permettant d'incorporer un ou plusieurs catalyseurs Fischer Tropsch dans des tamis moléculaires. Le procédé consiste à mettre en contact des tamis moléculaires non traités avec un précurseur de catalyseur dans une atmosphère inerte dans des premières conditions efficaces pour former des complexes comprenant ledit précurseur de catalyseur et lesdits tamis moléculaires; puis à exposer lesdits complexes à une atmosphère inerte et à des deuxièmes conditions efficaces pour dissocier les constituants volatiles dudit précurseur de catalyseur et pour évaporer le solvant contenu dans lesdits complexes, ceci formant des tamis moléculaires modifiés comprenant une quantité efficace du point de vue catalytique d'un catalyseur sélectionné dans le groupe formé par fer, cobalt, nickel, chrome, manganèse et rhodium.
EP98931364A 1997-06-18 1998-06-18 Conversion d'un gaz de synthese en olefines de faible poids moleculaire a l'aide de tamis moleculaires modifies Withdrawn EP0989908A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP01111008A EP1153660A3 (fr) 1997-06-18 1998-06-18 Procédé de conversion du gaz de synthèse en oléfines légères en utilisant des tamis moléculaires modifiés

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US5014497P 1997-06-18 1997-06-18
US50144P 1997-06-18
PCT/US1998/012703 WO1998057743A2 (fr) 1997-06-18 1998-06-18 Conversion d'un gaz de synthese en olefines de faible poids moleculaire a l'aide de tamis moleculaires modifies

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP01111008A Division EP1153660A3 (fr) 1997-06-18 1998-06-18 Procédé de conversion du gaz de synthèse en oléfines légères en utilisant des tamis moléculaires modifiés

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EP0989908A2 true EP0989908A2 (fr) 2000-04-05

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EP (1) EP0989908A2 (fr)
CN (1) CN1260823A (fr)
AR (1) AR013002A1 (fr)
AU (1) AU8151298A (fr)
CA (1) CA2289993A1 (fr)
NO (1) NO996308L (fr)
TW (1) TW482750B (fr)
WO (1) WO1998057743A2 (fr)

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US6331574B1 (en) 1999-10-08 2001-12-18 Exxonmobil Research And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
BG109246A (bg) * 2005-07-29 2005-11-30 АНГЕЛОВ Чавдар Метод за получаване на въглеводороди от въглероден диоксид
EP1887071A1 (fr) * 2006-07-31 2008-02-13 Edmund Dr.-Ing. Wagner Procédé de production d'hydrocarbures synthétiques et leurs dérivés à partir de dioxide de carbone et de dihydrogène utilisés comme gaz de synthèse
KR100903439B1 (ko) 2007-10-15 2009-06-18 한국화학연구원 천연가스로부터 경질탄화수소의 직접 제조방법
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ES2655323T3 (es) 2009-12-18 2018-02-19 Basf Se Zeolita que contiene hierro, procedimiento para la preparación de zeolitas que contienen hierro y procedimiento para la reducción catalítica de óxidos de nitrógeno
WO2015001004A1 (fr) 2013-07-04 2015-01-08 Total Research & Technology Feluy Compositions de catalyseur comprenant des cristaux de tamis moléculaire de petite dimension déposés sur une matière poreuse
CN107774302B (zh) * 2016-08-26 2020-08-14 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法
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CN109701628A (zh) 2017-10-26 2019-05-03 中国石油化工股份有限公司 含磷铝分子筛的复合催化剂及其在合成气一步法制烯烃的应用
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CN111111763B (zh) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 二氧化碳加氢直接制低碳烯烃的催化剂及其用途方法
CN111111760B (zh) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 二氧化碳加氢制取低碳烯烃的催化剂及其用途
CN111111766A (zh) * 2018-10-30 2020-05-08 中国石油化工股份有限公司 二氧化碳的利用方法
CN111346671B (zh) * 2018-12-21 2023-03-24 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制低芳烃液体燃料的方法
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WO1998057743A2 (fr) 1998-12-23
NO996308D0 (no) 1999-12-17
AU8151298A (en) 1999-01-04
WO1998057743A3 (fr) 1999-05-27
CA2289993A1 (fr) 1998-12-23
NO996308L (no) 2000-02-07

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