EP0944696B1 - Procede et installation de regeneration d'huiles lubrifiantes a hautes performances - Google Patents
Procede et installation de regeneration d'huiles lubrifiantes a hautes performances Download PDFInfo
- Publication number
- EP0944696B1 EP0944696B1 EP97950242A EP97950242A EP0944696B1 EP 0944696 B1 EP0944696 B1 EP 0944696B1 EP 97950242 A EP97950242 A EP 97950242A EP 97950242 A EP97950242 A EP 97950242A EP 0944696 B1 EP0944696 B1 EP 0944696B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- extraction
- waste oil
- strong base
- impurities
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 23
- 239000002699 waste material Substances 0.000 title claims description 18
- 230000001172 regenerating effect Effects 0.000 title claims description 12
- 230000001050 lubricating effect Effects 0.000 title claims description 6
- 239000003921 oil Substances 0.000 claims description 51
- 238000000605 extraction Methods 0.000 claims description 29
- 239000012535 impurity Substances 0.000 claims description 15
- 239000010687 lubricating oil Substances 0.000 claims description 13
- 239000002199 base oil Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 238000011084 recovery Methods 0.000 claims description 8
- 230000000295 complement effect Effects 0.000 claims description 7
- 239000000446 fuel Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 230000008030 elimination Effects 0.000 claims description 5
- 238000003379 elimination reaction Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000005292 vacuum distillation Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 239000012141 concentrate Substances 0.000 claims 1
- 238000003809 water extraction Methods 0.000 claims 1
- 239000002585 base Substances 0.000 description 41
- 238000007792 addition Methods 0.000 description 13
- 238000009434 installation Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 239000010913 used oil Substances 0.000 description 8
- 238000004821 distillation Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 208000005156 Dehydration Diseases 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000010603 pastilles Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
- C10M175/0016—Working-up used lubricants to recover useful products ; Cleaning with the use of chemical agents
Definitions
- the present invention relates to a method and a lubricating oil regeneration plant used with high performance.
- the object of the invention is therefore to propose such a process and the corresponding installation.
- a complementary addition of a strong base in aqueous solution due to 0.1 to 1% of pure bases by mass of lubricating oils is performed after step e).
- the amount of strong bases in aqueous solution can be between 0.5 to 3% of pure bases by mass used lubricating oils. This addition can be totally or partially cold or hot.
- the heating temperature of waste oils at regenerate between 120 and 250 ° C is a temperature at which the addition of the hot base is carried out in whole or in part.
- the used oils collected may have various origins. It can be, for example, oil engine, gear oil, hydraulic oil, turbine oil, etc.
- the regeneration process of the invention aims to eliminate light components, such as petrol, diesel and water, it allows also the elimination of degradation products from oil and additives but does not remove some components as heavy as the oils themselves and having different physical properties. he could be, for example, fuel oil elimination or treatment could not be obtained only by a complete refining process.
- Waste oil collected 1 having undergone with successful all of the tests come together in a tank 2.
- a base or a mixture of bases stored by elsewhere in a tank 4a is brought and mixed by means 5a to waste oils at temperature ambient between 10 and 40 ° C.
- Heating means 3 carry the oils taken from tank 2 and possibly mixed with the base, at a temperature between 120 and 250 ° C and preferably between 140 and 160 ° C.
- a base or a mixture of bases stored by elsewhere in a tank 4b is brought and mixed by means 5b to heated waste oils.
- an amount of pure bases between 0.5 and 3% by mass is added to waste oils.
- This rate as well as its distribution between the two cold and hot injection points, can be advantageously specified according to the quality of used oils and the nature of the base used.
- the base used is a strong base, preferably sodium or potassium hydroxide. We can also consider using a mixture of these bases.
- Waste oils brought to a temperature high, added with strong base, feed a water and oil extraction unit 6 light by triggering (flash).
- a water and oil extraction unit 6 light by triggering (flash).
- water evaporation is produced by expansion brutal mixing in a balloon.
- the diesel 9 is then discharged and the remaining mixture is led to a distillation column 10 allowing the fractionation of the mixture into sections lubricating base oils 11, 12 and separation of residue 15 where all the impurities are concentrated.
- Base oils can be separated at different levels depending on the number of cuts sought.
- the distillation column 10 is a column traditional vacuum which allows dissociation and the extraction of residues which are directed to a accumulation tank 14.
- the residues 15 are then removed and are likely to be used, for example, as tar or bitumen for road construction. They can also be used as fuel.
- the vacuum distillation column 10 is preferably associated with a depletion evaporator column bottom 13 to improve sound efficiency. Part of the energy needed to the rise in the temperature of used oils before the flash preferably comes from recovery of energy carried out on the cuts of base oils lubricants 11, 12 of the column outlet 10.
- Used oils are advantageously filtered during their recovery and when they leave the storage tank 2, so as to eliminate the solid particles they may contain.
- An additional basic solution is added made at lower proportions than additions initials, before the flash, the additional addition being in proportions of the order of 0.1 to 1% by mass of pure bases compared to oils used lubricants. It can be done in different points of the corresponding installation in each case has an embodiment.
- This process ensures better stability of regenerated base oils and fluidize the impurities, which allows a easier operation of the process.
- the oil temperature is then advantageously between 270 and 310 ° C.
- the additional basic addition is carried out under the same concentration conditions and than in the first embodiment, but after the extraction operation of diesel (stripping).
- a base stored in a tank 18 is brought and mixed by means 19 with oil stripped reheated directed towards the column of splitting.
- an evaporator 13 preferably thin-film, coupled to a vacuum column 10 eliminates most of the impurities.
- the oil obtained is then subjected to oxidation accelerated in a bin 22, before a quantity complementary to pure bases is added to it.
- a base stored in a tank 23b is brought and mixed with the oil by means of mixture 24.
- the oil is then fractionated in the column of distillation 20.
- the oil temperature when adding the base is advantageously between 200 and 300 ° C. for injection from reservoir 23b just before column 20 and is between 120 and 200 ° C for addition from a tank 23a directly in the oxidation tank 22.
- the evaporator 13 is advantageously a thin film evaporator. It is also possible to use several evaporators successively.
- the residues 21 of column 20 are, according to the efficiency of this column and the requirements imposed regenerated oils, either recirculated and injected at the entry in column 10, either routed to the storage of residues such as residues 15 from the distillation column 10 and the evaporator 13.
- sample 2 was obtained by a process according to the invention implemented according to one of Figures 2 and 3.
- Sample 3 was obtained by a process according to the invention implemented according to Figure 4. These samples are compared to sample 1 obtained with a single basic injection according to the prior art.
- samples 5 and 6 obtained according to the invention are to be compared with sample 4 obtained according to the prior art.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9615380A FR2757175B1 (fr) | 1996-12-13 | 1996-12-13 | Procede et installation de regeneration d'huiles lubrifiantes a hautes performances |
| FR9615380 | 1996-12-13 | ||
| PCT/FR1997/002224 WO1998026031A1 (fr) | 1996-12-13 | 1997-12-05 | Procede et installation de regeneration d'huiles lubrifiantes a hautes performances |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0944696A1 EP0944696A1 (fr) | 1999-09-29 |
| EP0944696B1 true EP0944696B1 (fr) | 2001-04-04 |
Family
ID=9498674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP97950242A Expired - Lifetime EP0944696B1 (fr) | 1996-12-13 | 1997-12-05 | Procede et installation de regeneration d'huiles lubrifiantes a hautes performances |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP0944696B1 (cs) |
| AR (1) | AR010353A1 (cs) |
| AT (1) | ATE200302T1 (cs) |
| AU (1) | AU5326998A (cs) |
| BG (1) | BG64486B1 (cs) |
| CA (1) | CA2274831C (cs) |
| CZ (1) | CZ300297B6 (cs) |
| DE (1) | DE69704500T2 (cs) |
| DK (1) | DK0944696T3 (cs) |
| DZ (1) | DZ2369A1 (cs) |
| ES (1) | ES2156008T3 (cs) |
| FR (1) | FR2757175B1 (cs) |
| GR (1) | GR3036074T3 (cs) |
| HU (1) | HU222544B1 (cs) |
| MA (1) | MA24424A1 (cs) |
| OA (1) | OA11060A (cs) |
| PL (1) | PL186318B1 (cs) |
| PT (1) | PT944696E (cs) |
| RU (1) | RU2187544C2 (cs) |
| TN (1) | TNSN97189A1 (cs) |
| UA (1) | UA59382C2 (cs) |
| WO (1) | WO1998026031A1 (cs) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6238551B1 (en) * | 1999-02-16 | 2001-05-29 | Miami University | Method of removing contaminants from petroleum distillates |
| ATE324421T1 (de) | 2002-07-15 | 2006-05-15 | Sener Grupo De Ingenieria Sa | Verfahren zur regeneration von altölen mittels lösungsmittelextraktion |
| ES2199697B1 (es) | 2003-09-23 | 2005-02-01 | Sener Grupo De Ingenieria, S.A. | Procedimiento para regenerar aceites usados por desmetalizacion y destilacion. |
| CN101104832B (zh) * | 2006-07-11 | 2012-04-25 | 北京百慧生化制药有限责任公司 | 废润滑油再炼制的方法及其设备 |
| EP3078730A4 (en) | 2013-11-08 | 2017-07-19 | Sener Ingenieria Y Sistemas, S.A. | Method for increasing the yield of lubricating bases in the regeneration of used oils |
| CN106906040B (zh) * | 2017-02-28 | 2020-01-10 | 中石化炼化工程(集团)股份有限公司 | 一种废润滑油的再生方法 |
| CN107551657A (zh) * | 2017-10-18 | 2018-01-09 | 杭州正进能源技术有限公司 | 润滑油净化再生装置 |
| TN2017000484A1 (fr) | 2017-11-20 | 2019-04-12 | Soc Tunisienne De Lubrifiants Sotulub | Amélioration du procédé de regénération des huiles usagées avec respect de différents aspects environnementaux. |
| CN110628455A (zh) * | 2019-09-26 | 2019-12-31 | 南通市泓正再生资源有限公司 | 一种废矿物油再生回收处理系统 |
| RU2712025C1 (ru) * | 2019-10-23 | 2020-01-24 | Акционерное общество "Интер РАО - Электрогенерация" | Установка для регенерации использованных смазочных масел с высокими рабочими параметрами |
| RU2713904C1 (ru) * | 2019-10-23 | 2020-02-11 | Акционерное общество "Интер РАО - Электрогенерация" | Способ регенерации использованных смазочных масел с высокими рабочими параметрами |
| RU2745628C1 (ru) * | 2020-08-25 | 2021-03-29 | Открытое акционерное общество "Всероссийский дважды ордена Трудового Красного Знамени теплотехнический научно-исследовательский институт" (ОАО "ВТИ") | Установка для регенерации отработавших смазочных масел |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2818521A1 (de) * | 1978-04-27 | 1979-11-08 | Degussa | Verfahren zur wiederaufbereitung von gebrauchten schmieroelen (ii) |
| RU2031919C1 (ru) * | 1992-01-22 | 1995-03-27 | Петров Анатолий Николаевич | Способ переработки отработанных смазочно-охлаждающих эмульсий от прокатки алюминия |
| IT1255534B (it) * | 1992-09-30 | 1995-11-09 | Processo di riraffinazione di oli usati | |
| FR2703067B1 (fr) * | 1993-03-22 | 1995-08-04 | Sotulub | Procédé et installation de régénération d'huiles lubrifiantes. |
-
1996
- 1996-12-13 FR FR9615380A patent/FR2757175B1/fr not_active Expired - Fee Related
-
1997
- 1997-05-12 UA UA99063267A patent/UA59382C2/uk unknown
- 1997-11-24 TN TNTNSN97189A patent/TNSN97189A1/fr unknown
- 1997-12-05 AU AU53269/98A patent/AU5326998A/en not_active Abandoned
- 1997-12-05 PL PL97334068A patent/PL186318B1/pl unknown
- 1997-12-05 HU HU0001433A patent/HU222544B1/hu active IP Right Grant
- 1997-12-05 CA CA002274831A patent/CA2274831C/fr not_active Expired - Lifetime
- 1997-12-05 PT PT97950242T patent/PT944696E/pt unknown
- 1997-12-05 DK DK97950242T patent/DK0944696T3/da active
- 1997-12-05 CZ CZ0211899A patent/CZ300297B6/cs not_active IP Right Cessation
- 1997-12-05 DE DE69704500T patent/DE69704500T2/de not_active Expired - Lifetime
- 1997-12-05 RU RU99115454/04A patent/RU2187544C2/ru active
- 1997-12-05 ES ES97950242T patent/ES2156008T3/es not_active Expired - Lifetime
- 1997-12-05 AT AT97950242T patent/ATE200302T1/de active
- 1997-12-05 EP EP97950242A patent/EP0944696B1/fr not_active Expired - Lifetime
- 1997-12-05 WO PCT/FR1997/002224 patent/WO1998026031A1/fr not_active Ceased
- 1997-12-10 DZ DZ970219A patent/DZ2369A1/xx active
- 1997-12-12 MA MA24900A patent/MA24424A1/fr unknown
- 1997-12-12 AR ARP970105867A patent/AR010353A1/es unknown
-
1999
- 1999-07-11 OA OA9900121A patent/OA11060A/fr unknown
- 1999-07-13 BG BG103577A patent/BG64486B1/bg unknown
-
2001
- 2001-06-19 GR GR20010400918T patent/GR3036074T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| OA11060A (fr) | 2003-03-07 |
| BG64486B1 (bg) | 2005-04-30 |
| WO1998026031A1 (fr) | 1998-06-18 |
| UA59382C2 (uk) | 2003-09-15 |
| FR2757175A1 (fr) | 1998-06-19 |
| ES2156008T3 (es) | 2001-06-01 |
| HUP0001433A3 (en) | 2001-02-28 |
| CZ300297B6 (cs) | 2009-04-15 |
| DZ2369A1 (fr) | 2002-12-28 |
| PT944696E (pt) | 2001-09-28 |
| ATE200302T1 (de) | 2001-04-15 |
| HUP0001433A2 (hu) | 2000-08-28 |
| TNSN97189A1 (fr) | 1999-12-31 |
| DK0944696T3 (da) | 2001-05-14 |
| RU2187544C2 (ru) | 2002-08-20 |
| PL186318B1 (pl) | 2003-12-31 |
| MA24424A1 (fr) | 1998-07-01 |
| DE69704500D1 (de) | 2001-05-10 |
| FR2757175B1 (fr) | 1999-03-05 |
| BG103577A (en) | 2000-05-31 |
| EP0944696A1 (fr) | 1999-09-29 |
| CA2274831A1 (fr) | 1998-06-18 |
| AU5326998A (en) | 1998-07-03 |
| HU222544B1 (hu) | 2003-08-28 |
| CZ211899A3 (cs) | 2000-03-15 |
| GR3036074T3 (en) | 2001-09-28 |
| CA2274831C (fr) | 2005-07-12 |
| AR010353A1 (es) | 2000-06-07 |
| HK1022928A1 (en) | 2000-08-25 |
| PL334068A1 (en) | 2000-01-31 |
| DE69704500T2 (de) | 2002-03-28 |
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| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| 17P | Request for examination filed |
Effective date: 19990713 |
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| AK | Designated contracting states |
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| AX | Request for extension of the european patent |
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| 17Q | First examination report despatched |
Effective date: 19990921 |
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