EP0937452B1 - Utilisation des composés d' ammonium polyquaternaire dans des produits pour le traitement du cheveux - Google Patents

Utilisation des composés d' ammonium polyquaternaire dans des produits pour le traitement du cheveux Download PDF

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EP0937452B1
EP0937452B1 EP98124166A EP98124166A EP0937452B1 EP 0937452 B1 EP0937452 B1 EP 0937452B1 EP 98124166 A EP98124166 A EP 98124166A EP 98124166 A EP98124166 A EP 98124166A EP 0937452 B1 EP0937452 B1 EP 0937452B1
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Prior art keywords
group
anionic
hair
weight
alkyl
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EP0937452A3 (fr
EP0937452A2 (fr
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Mustafa Dr. Grit
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Kao Germany GmbH
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Goldwell AG
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/415—Aminophenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/418—Amines containing nitro groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes

Definitions

  • the present invention relates to the use of anionic UV absorbers and / or substantive anionic dyes in a hair treatment product with improved Performance characteristics, in particular improved light protection or an improved Color intensity and color stability.
  • hair treatment agents in particular hair aftertreatment agents as defined in the monograph by K. Schrader, Fundamentals and Recipes of Cosmetics, 2nd edition (1989, Wilsonhig Buch Verlag), pp. 722-724, UV absorber, for example with anionic groups, in order to protect the hair against the harmful effects of light.
  • this is often not optimal since, for example, various components of hair treatment agents prevent or at least impede the absorption of these UV absorbers.
  • anionic direct hair dyes which is why generally only cationic direct hair dyes are used in hair tinting agents.
  • compositions that contain both substance groups namely both UV absorbers and anionic direct hair dyes
  • the invention is therefore based on the task of creating a hair treatment composition which contains anionic UV absorbers and / or anionic direct hair dyes which does not have the disadvantages mentioned, but rather ensures stable light protection and permanent hair coloring.
  • an aqueous-based hair treatment composition which contains at least 0.05 to 5% by weight of an anionic UV absorber and / or 0.01 to 2.5% by weight of at least one anionic hair dye , 5 to 20 wt .-% of at least one compound of general formula I.
  • R 1 and R 2 each represent an optionally hydroxy-substituted C 8 -C 22 alkyl or alkenyl group
  • R 3 and R 4 represent a C 1 -C 3 alkyl group or a group -CH 2 -CH 2 -O- [ EO] z -H
  • x, y and z for 0 to 5
  • Y - for an anion
  • Preferred radicals R 1 and R 2 are C 12 -C 18 alkyl and oleyl radicals, the radical R 3 is a methyl group and the radical R 4 is a hydroxyethyl group, x, y and z are preferably 0 or 1; Y - is preferably a methosulfate, chloride or phosphate anion.
  • the amount of this compound of the formula I is in particular about 0.5 to 15, especially 1 to 10 wt .-%, calculated on the hair treatment agent.
  • the hair treatment compositions used according to the invention are either Tinting shampoos based on anionic direct hair dyes or after-treatment agents, which contain these dyes and / or anionic UV absorbers.
  • the latter are used in an amount of 0.05 to 5, in particular 0.1 to 2.5% by weight, calculated on the total composition of the agent. A stable light protection is achieved by using this composition.
  • water-soluble UV absorbers with anionic groups are 5-Benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid (Benzophenone-4), whose Sodium salt (Benzophenone-5) and 2,2'-dihydroxy-4,4'-dimethoxy-3,3'-disulfobenzophenone or its disodium salt (Benzophenone-9) and phenylbenzimidazole sulfonic acid (Eusolex® 232); however, other anionic UV absorbers can also be used.
  • anionic UV absorber containing agents used according to the invention can are also colorants which additionally contain cationic direct dyes and Contain compounds of formula I; these lead to due to the better sun protection permanent stains.
  • compositions used according to the invention contain, especially if they are is hair after-treatment agent in the sense of the definition mentioned, preferably at least one cationic surfactant, in particular in an amount of 0.1 to 7.5, preferably 0.25 to 5, particularly preferably 0.5 to 2.5% by weight of the total composition.
  • Suitable long-chain quaternary ammonium compounds which can be used as cationic surfactants alone or in admixture with each other are in particular cetyl trimethyl ammonium chloride, Dimethyldicetylammoniumchlorid, trimethylcetylammonium bromide, stearyltrimethylammonium chloride, dimethylstearylbenzylammonium chloride Benzyltetradecyldimethylammoniumchlorid, Dimethyldihydrators-tallow ammonium chloride, lauryl pyridinium chloride, lauryldimethylbenzylammonium chloride, lauryl trimethyl ammonium chloride, tris (oligooxyethyl) alkyl ammonium phosphate, cetyl pyridinium chloride, Behentrimonium chloride, etc.
  • composition can of course additionally contain the constituents customary in such agents contain; in order to avoid repetitions, it is on K.Schrader, p.722 - 771, directed.
  • Nonionic surfactants can also be used, especially when mixed with cationic surfactants.
  • Such amine oxides have long been state of the art, for example C 12 -C 18 alkyldimethylamine oxides such as lauryldimethylamine oxide, C 12 -C 18 alkylamidopropyl or ethylamine oxides, C 12 -C 18 alkyldi (hydroxyethyl) or - (hydroxypropyl) amine oxides , or also amine oxides with ethylene oxide and / or propylene oxide groups in the alkyl chain.
  • C 12 -C 18 alkyldimethylamine oxides such as lauryldimethylamine oxide, C 12 -C 18 alkylamidopropyl or ethylamine oxides, C 12 -C 18 alkyldi (hydroxyethyl) or - (hydroxypropyl) amine oxides , or also amine oxides with ethylene oxide and / or propylene oxide groups in the alkyl chain.
  • Suitable surfactants are also the known C 8 -C 18 alkyl polyglucosides, in particular with a degree of polycondensation of 1.2 to 3.
  • compositions used according to the invention are toning shampoos is also anionic surfactants, preferably in a mixture with nonionic, amphoteric and / or zwitterionic surfactants can be used.
  • Suitable anionic surfactants are of course those which are usually used in shampoos, for example the known C 10 -C 18 alkyl sulfates and in particular the corresponding ether sulfates, for example C 12 -C 14 alkyl ether sulfate, lauryl ether sulfate, in particular with 1 to 4 ethylene oxide groups in the molecule , furthermore monoglyceride (ether) sulfates, fatty acid amide sulfates, which are obtained by ethoxylation and subsequent sulfation of fatty acid alkanolamides, and their alkali salts and salts of long-chain mono- and dialkyl phosphates, which are mild, skin-compatible detergents.
  • ether monoglyceride
  • Anionic surfactants which are also suitable in the context of the invention are isethionates and ⁇ -olefin sulfonates or their salts and in particular alkali metal salts of sulfosuccinic acid semiesters, for example the disodium salt of monooctyl sulfosuccinate and alkali salts long chain monoalkyl ethoxy sulfosuccinates.
  • Suitable surfactants of the carboxylate type are alkyl polyether carboxylic acids and their salts of the formula R - (C 2 H 4 O) n - O - CH 2 COOX, wherein R is a C 8 -C 20 alkyl group, preferably a C 12 -C 14 alkyl group, n is a number from 1 to 20, preferably 2 to 17, and XH or preferably a cation of the group sodium, potassium, magnesium and ammonium, which may optionally be hydroxyalkyl-substituted, and alkylamido polyether carboxylic acids of the general formula wherein R and X have the meaning given above and n is in particular a number from 1 to 10, preferably 2.5 to 5.
  • mixtures of several anionic surfactants for example a mixture of an ⁇ -olefin sulfonate and a sulfosuccinate, preferably in a ratio of 1: 3 to 3: 1, or an ether sulfate and one Polyether carboxylic acid or alkylamido ether carboxylic acid.
  • Protein-fatty acid condensation products can also be used in a mixture with other anionic surfactants structure known per se, especially in quantities between 0.5 and 5, preferably 1 to 3 wt .-% of the total composition of the liquid Shampoo.
  • the preferred range of amounts of anionic surfactants used in the invention liquid hair treatment agents is between 2.5 and 2.5% by weight, in particular at 5 to 20% by weight, particularly preferably at 7.5 to 15 % By weight, calculated on the total composition of the agent.
  • Non-ionic surfactants are preferably mixed with tinting shampoos anionic surfactants.
  • a preferred nonionic surfactant belongs to the class of alkyl polyglucosides of the general formula R - O - (R 1 O) n - Z x , wherein R is an alkyl group with 8 to 18 carbon atoms, R 1 is an ethylene or propylene group, Z is a saccharide residue with 5 to 6 carbon atoms, n is a number from 0 to 10 and x is a number from 1 to 2.5.
  • R is an alkyl group with 8 to 18 carbon atoms
  • R 1 is an ethylene or propylene group
  • Z is a saccharide residue with 5 to 6 carbon atoms
  • n is a number from 0 to 10
  • x is a number from 1 to 2.5.
  • These alkyl polyglucosides have recently become known in particular as excellent skin-compatible foam-improving agents in liquid detergents and body cleaning agents and are preferably present in an amount of 1 to 20, in particular 2.5 to 15,% by weight of the total composition.
  • nonionic surfactant components in tint shampoos are, for example, long-chain ones Fatty acid mono- and dialkanolamides, for example coconut fatty acid monoethanolamide and myristic fatty acid monoethanolamide, which are also used as foam enhancers can.
  • nonionic surfactants are, for example, the various sorbitan esters, such as Polyethylene glycol sorbitan stearic acid esters, fatty acid polyglycol esters or mixed condensates from ethylene oxide and propylene oxide, such as, for example, under the trade name "Pluronics" are in circulation.
  • sorbitan esters such as Polyethylene glycol sorbitan stearic acid esters, fatty acid polyglycol esters or mixed condensates from ethylene oxide and propylene oxide, such as, for example, under the trade name "Pluronics" are in circulation.
  • surfactants that can be used in a mixture with anionic surfactants are already Amine oxides mentioned in an amount of 0.25 to 5, preferably 0.5 to 3.5% by weight, calculated on the total composition of the agent.
  • betaines, sulfobetaines and / or alkylaminocarboxylic acids such as alkylaminoglycinates, alkylaminopropionates, alkylglycinates, etc. can be used as amphoteric or zwitterionic surfactants.
  • Alkyl amido betaines of the general formula are particularly suitable where R is a C 8 -C 18 alkyl group, e.g. B.
  • R 1 and R 2 are a lower C 1 -C 4 alkyl or hydroxyalkyl radical, in particular a methyl, ethyl and / or hydroxyethyl group; R 3 is a COO - or -SO 3 - group; and n is 1 to 3.
  • Tegobetaine® Commercial products such as “Tegobetaine®” are particularly suitable, “Dehytone®” like “AB 30", “G” and “K”, “Lonzaine®”, “Varion®” like “ADG” and “CAS”, “Lexaine®”, “Chembetaine®”, “Mirataine®”, “Rewoteric®”, “Schercotaine®”, “Monteine LCQ® ";” “Alkateric®”, “Amonyl®”, “Amphosol®”, “Cycloteric BET®”, “Emcol®”, “Empigen®”, “Mackam®”, “Monateric®”, “Unibetaine®” and “Velvetex®”.
  • amphoteric or zwitterionic surfactants are preferably in an amount of 0.25 up to 7.5% by weight, in particular 0.5 to 5% by weight, calculated on the total composition, contain.
  • the hair treatment agents used according to the invention can be those in such aqueous Preparations contain common substances.
  • synthetic or natural hair-conditioning polymers preferably in an amount of 0.1 to 2.5, in particular 0.25 to 1.5% by weight of the total composition.
  • suitable cationic polymers are of the "Polymer JR” type, in particular quaternized homo- and copolymers of dimethyldiallylammonium chloride, as they trade under the trade name "Merquat” are quaternary vinylpyrrolidone copolymers, in particular with dialkylaminoalkyl (meth) acrylates, as they are known under the name “Gafquat”, copolymers of Vinyl pyrrolidone and vinyl imidazolinium methochloride sold under the trade name “Luviquat” are offered, polyamino-polyamide derivatives, for example copolymers of Adipic acid-dimethylaminohydroxypropyldiethylenetriamine, as they are called “Cartaretine F" are sold, as well as bisquaternary long-chain ammonium compounds the urea structure described in U.S. Patent No. 4,157,388 sold under the trade name "Mira
  • nonionic polymers can be used instead of or in combination with the cationic polymers.
  • Suitable as nonionic polymers are before all vinylpyrrolidone homopolymers and copolymers, in particular polyvinylpyrrolidone itself, Copolymers of vinyl pyrrolidone and vinyl acetate or terpolymers of vinyl pyrrolidone, Vinyl acetate and vinyl propionate, such as those from BASF under the Trade names "Luviskol" are used.
  • amphoteric polymers e.g. B. under the name "Amphomer” sold copolymers of N-octylacrylamide, N-butylaminoethyl methacrylate and acrylic acid, as well as the known anionic products known in the prior art are sufficiently described.
  • the hair treatment agents used according to the invention can, if they are used as emulsions, Dispersions, solutions, gels or aerosols are used as aftertreatment agents, contain the usual additives in such compositions, the nature and character of the application form of the agent is dependent. These are fats, fatty alcohols, emulsifiers, pH regulators, solvents and diluents, solubilizers, preservatives, Perfumes, etc.
  • Suitable fats and oils which also include waxes, are in particular natural oils such as Avocado oil, coconut oil, palm oil, sesame oil, peanut oil, sperm oil, sunflower oil, almond oil, peach seed oil, Wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, castor oil, or also Olive or soybean oil, lanolin and its derivatives, as well as mineral oils such as paraffin oil and Vaseline.
  • natural oils such as avocado oil, coconut oil, palm oil, sesame oil, peanut oil, sperm oil, sunflower oil, almond oil, peach seed oil, Wheat germ oil, macadamia nut oil, evening primrose oil, jojoba oil, castor oil, or also Olive or soybean oil, lanolin and its derivatives, as well as mineral oils such as paraffin oil and Vaseline.
  • Synthetic oils and waxes are, for example, silicone oils and polyethylene glycols.
  • Suitable hydrophobic components are, in particular, fatty alcohols, preferably those having 8 to 22 carbon atoms in the molecule, such as myristyl, cetyl, stearyl alcohol, wax alcohols and fatty acid esters such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dibutyl adipate , Myristyl myristate, olerlerucate, polyethylene glycol and polyglyceryl fatty acid esters such as PEG-7 glyceryl cocoate and cetyl palmitate.
  • These hydrophobic components are preferably present in the compositions used according to the invention in a total amount of 0.5 to 10, in particular 1 to 7.5, in particular 1.5 to 5% by weight, calculated on the total composition.
  • a preferred group of active ingredients are C 10 -C 24 fatty acids, in particular behenic acid and stearic acid, preferably between 0.1 and 10% by weight of the total composition.
  • C 10 -C 24 fatty acids in particular behenic acid and stearic acid, preferably between 0.1 and 10% by weight of the total composition.
  • compositions used according to the invention are in the form of an emulsion or dispersion or (optionally thickened, i.e. as a gel) solution and can also be used as aerosol foam be assembled.
  • emulsion or dispersion or (optionally thickened, i.e. as a gel) solution can also be used as aerosol foam be assembled.
  • the pH of the hair colorants used according to the invention is preferably 3 to 8, especially between 4 and 6.
  • JP 08 027669 A describes storage-stable textile treatment agents that are 3 to 30 % By weight of fabric softener (ester quat or amidoquat), 1 to 100 ppm Acid Yellow 3 and / or Acid Yellow 141 and 0.1 to 1000 ppm contain 2,6-di-tert-butyl-4-methylphenol.
  • compositions of the agents according to the invention are compositions of the agents according to the invention.
  • Post-treatment agents or tint shampoos of the following compositions were used by mixing the ingredients, optionally in the form of premixes.
  • composition 1 according to Example 1 was applied to locks of hair and in Compared to other strands of hair that have an otherwise identical composition 1A, which instead of the compound of formula I the same proportion of cetyltrimethylammonium chloride contained, had been treated, the content of UV absorber in hair samples after determined several washes.
  • composition 3 according to Example 3 was applied to human hair, wherein a shiny, intense, distinctive brown color was achieved, which can also be seen after 3 Hair washing was still stable.
  • composition 3A which instead of a Compound of formula I contained the same amount of cetylstearyltrimethylammonium chloride, was noticeably duller and largely faded after three shampoos.
  • the composition has excellent light protection properties on the hair.
  • Toner shampoo Example No. 10 11 12 13 14 Sodium C 12 -C 14 alkyl ether sulfate ( ⁇ 2-3EO groups) 10.00 - 8.00 10.00 - C 12 -C 14 alkyl polyglucoside - 10.00 - - '10.00 cocoamidopropyl 2.00 2.00 5.00 2.00 2.00 PEG-3 distearate 2.00 2.00 2.00 - - Compound of formula I. 1.00 1.00 2.00 0.50 0.50 Perfume 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Citric acid, preservative q.s. q.s. q.s. q.s. D.C.

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Claims (7)

  1. Utilisation de 0,5 à 20 % en poids d'au moins un composé de formule générale I
    Figure 00260001
    dans laquelle R1 et R2 représentent chacun un groupe alkyle ou alcénylé en C8 à C22 éventuellement hydroxylé, R3 et R4 représentent un groupe alkyle en C1 à C3 ou un groupe -CH2-CH2-O-[EO]z-H, dans lequel x, y et z représentent 0 à 5 et Y- représente un anion, pour la préparation de produits actifs anioniques, sélectionnés parmi des agents anioniques d'absorption des UV à une teneur de 0,05 à 5 % en poids et/ou des colorants anioniques directs des cheveux à une teneur comprise entre 0,01 et 2,5 % en poids, dans des agents de traitement des cheveux à base aqueuse pour les cheveux humains, les pourcentages étant tous calculés par rapport à la composition totale de l'agent.
  2. Utilisation d'un mélange à 0,5 à 20 % en poids par rapport à la composition totale,
    a) d'au moins un composé de formule générale I
    Figure 00260002
    dans laquelle R1 et R2 représentent chacun un groupe alkyle ou alcényle en C8 à C22 éventuellement hydroxylé, R3 et R4 représentent un groupe alkyle en C1 à C3 ou un groupe -CH2-CH2-O-[EO]z-H, dans lequel x, y et z représentent 0 à 5 et Y- représente un anion, et
    b) d'au moins un agent anionique d'absorption des UV, dans des agents de traitement des cheveux à base aqueuse, pour obtenir une protection stable contre la lumière.
  3. Utilisation d'un mélange constitué de 0,5 à 20 % en poids par rapport à la composition totale,
    a) d'au moins un composé de formule générale I
    Figure 00270001
    dans laquelle R1 et R2 représentent chacun un groupe alkyle ou alcényle en C8 à C22 éventuellement hydroxylé, R3 et R4 représentent un groupe alkyle en C1 à C3 ou un groupe -CH2-CH2-O-[EO]z-H, dans lequel x, y et z représentent 0 à 5 et Y- représente un anion, et
    b) de 0,01 à 2,5 % en poids d'un colorant anionique direct des cheveux, dans des agents de traitement des cheveux à base aqueuse, pour obtenir une coloration durable des cheveux.
  4. Utilisation selon l'une des revendications 1 à 3, caractérisée en ce que les radicaux R1 et R2 représentent chacun un radical oléyle, le radical R3 un groupe méthyle, le radical R4 un groupe -CH2-CH2-OH, et x et y représentent 0.
  5. Utilisation selon l'une des revendications 1 à 3, caractérisée en ce que les radicaux R1 et R2 représentent chacun un groupe alkyle en C12 à C18, le radical R3 un groupe méthyle et le radical R4 un groupe -CH2-CH2-O-[EO]zH, et x et y représentent 0.
  6. Utilisation selon l'une ou plusieurs des revendications 2 à 5, dans laquelle on utilise, comme agent anionique d'absorption des UV, au moins une substance sélectionnée parmi l'acide 5-benzoyl-4-hydroxy-2-méthoxybenzènsulfonique, la 2,2'-dihydroxy-4,4'-diméthoxy-3,3'-disulfobenzophénone et/ou l'acide phénylbenzimidazole sulfonique ou leurs sels de sodium.
  7. Utilisation selon l'une ou plusieurs des revendications 1 à 6, dans laquelle l'agent de traitement des cheveux contient de 0,1 à 10 % en poids d'au moins un acide gras en C10 à C24, le pourcentage étant calculé par rapport à la composition totale.
EP98124166A 1997-12-31 1998-12-19 Utilisation des composés d' ammonium polyquaternaire dans des produits pour le traitement du cheveux Expired - Lifetime EP0937452B1 (fr)

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DE19758272A DE19758272C5 (de) 1997-12-31 1997-12-31 Verwendung eines Haarbehandlungsmittels
DE19758272 1997-12-31

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EP0937452A2 EP0937452A2 (fr) 1999-08-25
EP0937452A3 EP0937452A3 (fr) 2000-06-21
EP0937452B1 true EP0937452B1 (fr) 2002-03-27

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EP98124166A Expired - Lifetime EP0937452B1 (fr) 1997-12-31 1998-12-19 Utilisation des composés d' ammonium polyquaternaire dans des produits pour le traitement du cheveux

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EP (1) EP0937452B1 (fr)
AT (1) ATE214909T1 (fr)
DE (2) DE19758272C5 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9915095D0 (en) * 1999-06-28 1999-09-01 Procter & Gamble Cosmetic compositions
EP1469813B1 (fr) * 2002-01-31 2016-12-21 Croda, Inc. Additifs et produits contenant des oligoesters
DE10300762A1 (de) * 2003-01-11 2004-07-22 Wella Ag Zum Abspülen bestimmtes kosmetisches Mittel mit UV-Schutz
JP5902616B2 (ja) * 2010-04-28 2016-04-13 協和発酵キリン株式会社 カチオン性脂質

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2168082B (en) * 1984-07-31 1988-09-14 Beecham Group Plc Dye compositions
FR2712895B1 (fr) * 1993-11-26 1996-05-03 Oreal Composition fondante contenant des sels d'ammonium quaternaire à fonction ester, son utilisation comme produit capillaire.
JP3309102B2 (ja) * 1994-07-08 2002-07-29 ライオン株式会社 液体柔軟剤組成物
DE4441359C2 (de) * 1994-11-21 1998-07-16 Kao Corp Flüssiges Tönungsshampoo
BR9611374A (pt) * 1995-11-03 1999-02-23 Procter & Gamble Composições de amaciante de pano de baixa ação de alto teor de perfume estáveis
DE19622815A1 (de) * 1996-06-07 1997-12-11 Wella Ag Haarbehandlungsmittel
DE19652302C1 (de) * 1996-12-16 1998-03-26 Henkel Kgaa Verwendung von Mitteln enthaltend Esterquats und Sterole
DE19738303A1 (de) * 1997-09-02 1999-03-04 Schwarzkopf Gmbh Hans Verwendung einer Wirkstoffkombination und Mittel
GB2328954B (en) * 1997-09-04 2002-01-09 Henkel Kommandigesellschaft Au The use of esterquats as emulsifiers for the production of formulations for coloring keratin fibers
DE19738641C1 (de) * 1997-09-04 1999-07-01 Henkel Kgaa Esterquats auf Zimtsäurebasis

Also Published As

Publication number Publication date
DE19758272C5 (de) 2004-10-07
DE19758272C1 (de) 1999-04-15
ATE214909T1 (de) 2002-04-15
DE59803504D1 (de) 2002-05-02
EP0937452A3 (fr) 2000-06-21
EP0937452A2 (fr) 1999-08-25

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