EP0912663A1 - A lubricant comprising an alkyl-substituted naphthaline and an ester - Google Patents

A lubricant comprising an alkyl-substituted naphthaline and an ester

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Publication number
EP0912663A1
EP0912663A1 EP97930667A EP97930667A EP0912663A1 EP 0912663 A1 EP0912663 A1 EP 0912663A1 EP 97930667 A EP97930667 A EP 97930667A EP 97930667 A EP97930667 A EP 97930667A EP 0912663 A1 EP0912663 A1 EP 0912663A1
Authority
EP
European Patent Office
Prior art keywords
lubricant
ester
percent
alkyl
hours
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97930667A
Other languages
German (de)
English (en)
French (fr)
Inventor
Randall Krinker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Castrol Ltd
Original Assignee
Castrol Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Castrol Ltd filed Critical Castrol Ltd
Publication of EP0912663A1 publication Critical patent/EP0912663A1/en
Withdrawn legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02Well-defined hydrocarbons
    • C10M105/06Well-defined hydrocarbons aromatic
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
    • C10M105/34Esters of monocarboxylic acids
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
    • C10M105/36Esters of polycarboxylic acids
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
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    • C10M111/00Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/02Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a non-macromolecular organic compound
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    • C10M149/00Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
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    • C10M2207/2815Esters of (cyclo)aliphatic monocarboxylic acids used as base material
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/283Esters of polyhydroxy compounds
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/283Esters of polyhydroxy compounds
    • C10M2207/2835Esters of polyhydroxy compounds used as base material
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/28Esters
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/30Refrigerators lubricants or compressors lubricants
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    • C10N2040/32Wires, ropes or cables lubricants
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    • C10N2040/34Lubricating-sealants
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    • C10N2040/38Conveyors or chain belts
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    • C10N2040/40Generators or electric motors in oil or gas winning field
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    • C10N2040/42Flashing oils or marking oils
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Definitions

  • the present invention relates to lubricant comprising an ester. More particularly, the invention relates to high temperature chain oils having improved volatility and functional life.
  • Lubricant compositions for use on drive chains, particle board presses, tenter frames and stenter frames require viscosity stability.
  • the present invention overcomes these and other disadvantages by including an alkyl-substituted naphthalene in a lubricant composition having an ester.
  • One object of the present invention is the provision of a lubricant for use with drive chains and other chain mechanisms operating in high temperature environments having improved viscosity characteristics.
  • Another object of the invention is to provide a high temperature chain oil having improved volatility characteristics and an increased functional life.
  • the lubricant composition of the present invention comprises an alkyl-substituted naphthalene and an ester.
  • an alkyl-substituted naphthalene it is contemplated that reference is made to naphthalene substituted with one or more straight or branched alkyl groups of varying lengths.
  • the present invention may comprise diesters, phthalates, trimellitates, pyromellitates, dimer acid ester, polyols and polyoleates. It is contemplated that trimellitic esters and polyols are particularly suitable.
  • an ester comprises from about 40 percent to about 90 percent by weight of the lubricant composition, alternatively from about 50 percent to about 80 percent.
  • Emkarate 9130 is a trimeilitic acid ester, available from ICI Chemical Polymers.
  • Mobil MCP 968 is a mixture of dialkyl- and trialkylnaphthalenes, available from Mobil Chemical Co.
  • Parapol 1300 and Indopol H-1900 are polybutene polymers.
  • Irgalube 349 is an antiwear additive available from
  • Emkarate 9130 and Mobil MCP 968 are combined and heated to a temperature of from about 70°C to about 85°C.
  • Parapol 1300 or Indopol H-1900
  • Irganox L06 and Vanlube SS are blended into the mixture.
  • Irganox L06 and Vanlube SS are powders which must be melted into the mixture, and the mixture must be blended until the Irganox L06 and Valube SS are thoroughly dispersed in the mixture.
  • the temperature of the composition is then lowered to about 60°C and Irgalube 349 and Nasul 707 are blended into the composition.
  • Samples of the lubricant compositions of the preceding Examples were prepared in accordance with the steps outlined in the preceding paragraph.
  • the isothermal evaporation of several samples was measured by subjecting a sample to the constant temperature in an instrument specifically designed for thermo-gravimetric analysis by TA Instruments.
  • t90 represents the time at which 10 percent by weight of the original sample had volatized (i.e., 90 percent by weight of the sample remained)
  • T50 indicates the time at which 50 percent by weight of the original sample had volatized (i.e., 50 percent by weight of the sample remained).
  • Formula B has the same ingredients in the same amounts as Example I except that in place of Mobil MCP 968 (a mixture of dialkyl- and trialkyl-naphthalenes), Formula B has additional Emkarate 9130 (a trimeilitic acid ester). Isothermal scans on 10 to 12 mg samples of Example I and Formula B were run at four different temperatures. The following results indicate the time at which 50 percent by weight of the original sample had volatized at each of the four temperatures (i.e. 50 percent by weight of the sample remained).
  • Mobil MCP 968 a mixture of dialkyl- and trialkyl-naphthalenes
  • Emkarate 9130 a trimeilitic acid ester
  • the lubricant composition of the present invention is notable for its ability to meet the demands of use of high temperature drive chain applications. However, the present invention is also suitable for use in other applications, such as gears and air compressors, as well as for any lubricant application where low volatility and increased functional life are desirable.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP97930667A 1996-07-12 1997-07-10 A lubricant comprising an alkyl-substituted naphthaline and an ester Withdrawn EP0912663A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US2169496P 1996-07-12 1996-07-12
US21694P 1996-07-12
PCT/GB1997/001857 WO1998002510A1 (en) 1996-07-12 1997-07-10 A lubricant comprising an alkyl-substituted naphthaline and an ester

Publications (1)

Publication Number Publication Date
EP0912663A1 true EP0912663A1 (en) 1999-05-06

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EP97930667A Withdrawn EP0912663A1 (en) 1996-07-12 1997-07-10 A lubricant comprising an alkyl-substituted naphthaline and an ester

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EP (1) EP0912663A1 (ko)
JP (1) JP2000514853A (ko)
KR (1) KR20000023606A (ko)
CN (1) CN1230212A (ko)
AU (1) AU3454397A (ko)
BR (1) BR9710296A (ko)
CA (1) CA2260046A1 (ko)
CZ (1) CZ6799A3 (ko)
NO (1) NO990104L (ko)
PL (1) PL331096A1 (ko)
TR (1) TR199900054T2 (ko)
WO (1) WO1998002510A1 (ko)

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Publication number Priority date Publication date Assignee Title
US6436882B1 (en) 2001-06-29 2002-08-20 King Industries, Inc. Functional fluids
JP2005330328A (ja) * 2004-05-18 2005-12-02 Osamu Ogata オイル性能の改善方法
US20090186789A1 (en) * 2006-05-15 2009-07-23 Mitsuhiro Nagakari Lubricating oil composition
DE202006019075U1 (de) * 2006-09-13 2007-04-12 Addinol Lube Oil Gmbh Hochtemperaturschmierstoff für Ketten
DE102014018718A1 (de) * 2014-12-17 2016-06-23 Klüber Lubrication München Se & Co. Kg Hochtemperaturschmierstoffe
DE102014018719A1 (de) * 2014-12-17 2016-06-23 Klüber Lubrication München Se & Co. Kg Hochtemperaturschmierstoff für die Lebensmittelindustrie
CN106833825A (zh) * 2016-12-08 2017-06-13 天长市天龙泵阀成套设备厂 可改善润滑性能的链条润滑油
WO2019189834A1 (ja) * 2018-03-30 2019-10-03 出光興産株式会社 潤滑油組成物
CN108865360A (zh) * 2018-07-26 2018-11-23 郑州市欧普士科技有限公司 一种环保型合成酯类高温链条油及其制备方法

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NL73008C (ko) * 1948-10-25
GB2168378B (en) * 1984-11-28 1988-06-29 Nippon Oil Co Ltd Synthetic oils
JPH02286792A (ja) * 1989-04-28 1990-11-26 Nippon Oil Co Ltd 潤滑油組成物
DK0496486T3 (da) * 1991-01-11 1994-03-28 Mobil Oil Corp Smøremiddelsammensætninger
US5236610A (en) * 1992-02-03 1993-08-17 The United States Of America As Represented By The Secretary Of The Commerce Stable high temperature liquid lubricant blends and antioxidant additives for use therewith

Non-Patent Citations (1)

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Title
See references of WO9802510A1 *

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CA2260046A1 (en) 1998-01-22
CZ6799A3 (cs) 1999-08-11
AU3454397A (en) 1998-02-09
NO990104D0 (no) 1999-01-11
KR20000023606A (ko) 2000-04-25
JP2000514853A (ja) 2000-11-07
BR9710296A (pt) 1999-08-17
WO1998002510A1 (en) 1998-01-22
NO990104L (no) 1999-01-11
PL331096A1 (en) 1999-06-21
CN1230212A (zh) 1999-09-29
TR199900054T2 (xx) 1999-03-22

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