EP0899325B1 - Composition adoucissante pour textiles - Google Patents
Composition adoucissante pour textiles Download PDFInfo
- Publication number
- EP0899325B1 EP0899325B1 EP98810753A EP98810753A EP0899325B1 EP 0899325 B1 EP0899325 B1 EP 0899325B1 EP 98810753 A EP98810753 A EP 98810753A EP 98810753 A EP98810753 A EP 98810753A EP 0899325 B1 EP0899325 B1 EP 0899325B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- formula
- alkoxy
- independently
- phthalocyanine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 68
- 239000002979 fabric softener Substances 0.000 title claims description 31
- -1 alkoxide carboxylate Chemical class 0.000 claims description 52
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 31
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 30
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 20
- 229910052736 halogen Inorganic materials 0.000 claims description 20
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 19
- 150000002367 halogens Chemical group 0.000 claims description 16
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 16
- 150000001450 anions Chemical class 0.000 claims description 15
- 239000004753 textile Substances 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 9
- 229910002651 NO3 Inorganic materials 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 238000004061 bleaching Methods 0.000 claims description 8
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- CKHJYUSOUQDYEN-UHFFFAOYSA-N gallium(3+) Chemical compound [Ga+3] CKHJYUSOUQDYEN-UHFFFAOYSA-N 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 5
- NFGODEMQGQNUKK-UHFFFAOYSA-M [6-(diethylamino)-9-(2-octadecoxycarbonylphenyl)xanthen-3-ylidene]-diethylazanium;chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C1=C2C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C21 NFGODEMQGQNUKK-UHFFFAOYSA-M 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000003760 tallow Substances 0.000 claims description 5
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 2
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 2
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 2
- 150000001449 anionic compounds Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 150000002891 organic anions Chemical class 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 3
- ORTFAQDWJHRMNX-UHFFFAOYSA-M oxidooxomethyl Chemical compound [O-][C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-M 0.000 claims 2
- JYNZIOFUHBJABQ-UHFFFAOYSA-N allyl-{6-[3-(4-bromo-phenyl)-benzofuran-6-yloxy]-hexyl-}-methyl-amin Chemical group C=1OC2=CC(OCCCCCCN(C)CC=C)=CC=C2C=1C1=CC=C(Br)C=C1 JYNZIOFUHBJABQ-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000004744 fabric Substances 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
- 229920000742 Cotton Polymers 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000003599 detergent Substances 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 125000003342 alkenyl group Chemical group 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 125000001424 substituent group Chemical group 0.000 description 7
- 0 CC1*CCC1 Chemical compound CC1*CCC1 0.000 description 6
- 244000269722 Thea sinensis Species 0.000 description 6
- 229940077464 ammonium ion Drugs 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000020095 red wine Nutrition 0.000 description 4
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- CTYRPMDGLDAWRQ-UHFFFAOYSA-N phenyl hydrogen sulfate Chemical compound OS(=O)(=O)OC1=CC=CC=C1 CTYRPMDGLDAWRQ-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- RHQQHZQUAMFINJ-GKWSUJDHSA-N 1-[(3s,5s,8s,9s,10s,11s,13s,14s,17s)-3,11-dihydroxy-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-17-yl]-2-hydroxyethanone Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@H](CC4)C(=O)CO)[C@@H]4[C@@H]3CC[C@H]21 RHQQHZQUAMFINJ-GKWSUJDHSA-N 0.000 description 1
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 1
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GESFNQOJVBMNHY-UHFFFAOYSA-N C1C2N(C3)C3CC12 Chemical compound C1C2N(C3)C3CC12 GESFNQOJVBMNHY-UHFFFAOYSA-N 0.000 description 1
- NZZNMDNKJVUJAL-UHFFFAOYSA-N CCC1NCC1 Chemical compound CCC1NCC1 NZZNMDNKJVUJAL-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000727 Decyl polyglucose Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- YITMLDIGEJSENC-UHFFFAOYSA-N Hexadecen Natural products CCCCCCCCCCCCCC=CC YITMLDIGEJSENC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000007920 enema Substances 0.000 description 1
- 229940095399 enema Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C11D2111/12—
-
- C11D2111/46—
Claims (14)
- Composition d'adoucissant contenantoù(a) une phtalocyanine hydrosoluble de Zn, Fe(II), Ca, Mg, Na, K, Al, Si(IV), P(V), Ti(IV), Ge(IV), Cr(VI), Ga(III), Zr(IV), In(III), Sn(IV) ou Hf(VI) ; et(b) un composé d'ammonium quaternaire de formule
- R1 et R2
- représentent, indépendamment l'un de l'autre, des groupes alkyle en C1-C5 ; ou hydroxyalkyle en C1 - C5 ;
- A et B
- représentent chacun, indépendamment l'un de
l'autre, le reste de formule
ou le reste de formule
- R3, R4 et R5
- représentent, indépendamment l'un de l'autre, un reste acide gras en C8-C20 ;
- X1 -
- représente un anion compatible avec l'adoucissant ;
m, n et p sont un nombre de 0 à 5. - Composition selon la revendication 1, caractérisée en ce qu'elle contient une phtalocyanine de formuleou
où
- PC
- représente le système cyclique phtalocyanine ;
- Me
- représente un atome de Zn, Fe(II), Ca, Mg, Na, K, Al-Z1, Si(IV), P(V), Ti(IV), Ge(IV), Cr(VI), Ga(III), Zr(IV), In(III), Sn(IV) ou Hf(VI) ;
- Z1
- représente un ion halogénure, sulfate, nitrate, acétate, alcoolate, carboxylate ou hydroxy ;
- q
- vaut 0, 1 ou 2 ;
- r
- va de 1 à 4 ;
- Q1
- représente un groupe sulfo ou carboxyle ; ou un
reste de formule
-SO2X2-R6-X3 +, -O-R6-X3 +; ou -(CH2)t-Y1 + ;
- R6
- représente des groupes alkylène en C1-C8 linéaire ou ramifié ; ou 1,3- ou 1,4-phénylène ;
- X2
- représente des groupes -NH- ; ou -N-alkyle en C1-C5- ;
- X3 +
- représente un groupe de formule
pour le cas, où R6 = alkylène en C1-C8, également un groupe de formule
- Y1 +
- représente un groupe de formule
- t
- vaut 0 ou 1 ;
- R7 et R8
- représentent, indépendamment l'un de l'autre, un groupe alkyle en C1-C6 ;
- R9
- représente un groupe alkyle en C1-C6 ; cyclo-alkyle en C5-C7 ; ou NR11R12 ;
- R10 et R11
- représentent, indépendamment l'un de l'autre, un groupe alkyle en C1-C5 ;
- R12 et R13
- représentent, indépendamment l'un de l'autre, un atome d'hydrogène ou un groupe alkyle en C1-C5 ;
- R14 et R15
- représentent, indépendamment l'un de l'autre, un groupe alkyle en C1-C6 non substitué ou substitué par des substituants hydroxy, cyano, carboxy, carbalkoxy en C1-C6, alkoxy en C1-C6, phényle, naphtyle ou pyridyle ;
- u
- va de 1 à 6 ;
- A1
- représente un complément d'un hétérocycle azoté de 5 à 7 chaínons qui peut éventuellement contenir encore un ou deux atomes d'azote en tant que termes cycliques, et
- B1
- représente le complément d'un hétérocycle azoté de 5 à 7 chaínons, qui peut éventuellement contenir encore 1 à 2 atomes d'azote, d'oxygène et/ou de soufre en tant que termes cycliques ;
- Q2
- représente un groupe hydroxy ; un groupe alkyle
en C1-C22 ; un groupe alkyle en C4-C22 ramifié ;
un groupe alcényle en C2-C22 ; un groupe alcényle
en C4-C22 ramifié et ses mélanges ; un groupe
alkoxy en C1-C22 ; un reste sulfo ou carboxyle ;
un reste de formule
-SO2(CH2)v-OSO3M; -SO2(CH2)v-SO3M;
un motif alkyloxyéthyléne de formule
-(T1)d-(CH2)b(OCH2CH2)a-B3 ou un ester de formule COOR23 où- B2
- représente un atome d'hydrogène ; des groupes hydroxy ; alkyle en C1-C30 ; alkoxy en C1-C30 ; -CO2H ; -CH2COOH ; -SO3 -M1 + ; -OSO3 -M1 + ; -PO3 2- ; M1 ; -PO3 2-M1 ; et leurs mélanges ;
- B3
- représente un atome d'hydrogène ; des groupes hydroxy ; -COOH ; -SO3 -M1 + ; -OSO3 -M1 + ; alkoxy en C1-C6 ;
- M1
- représente un cation hydrosoluble ;
- T1
- représente des groupes -O- ; -NH- ;
- X1 et X4
- représentent, indépendamment l'un de l'autre, un atome de -O- ; des groupes -NH- ; ou N-alkyle en C1-C5 ;
- R16 et R17
- représentent, indépendamment l'un de l'autre, un atome d'hydrogène, le groupe sulfo et ses sels, le groupe carboxyle et ses sels, ou le groupe hydroxyle, au moins l'un des restes R16 et R17 représente un grupe sulfo ou carboxyle ou leurs sels,
- Y2
- représente des groupes de -O-, -S-, -NH- ou N-alkyle en C1-C5 ;
- R18 et R19
- représentent, indépendamment l'un de l'autre, un atome d'hydrogène, des groupes alkyle en C1-C6, hydroxyalkyle en C1-C6, cyanoalkyle en C1-C6, sulfoalkyle en C1-C6, carboxy ou haloalkyle en C1-C6 ; un groupe phényle non substitué ou substitué par des substituants halogène, alkyle en C1-C4 ou alkoxy en C1-C4, sulfo ou carboxy ; ou R18 et R19 forment conjointement avec l'atome d'azote auquel ils sont liés, un cycle hétérocyclique saturé de 5 ou 6 chaínons, qui peut contenir de plus un atome d'azote ou d'oxygène en tant que terme cyclique ;
- R20 et R21
- représentent, indépendamment l'un de l'autre, un reste alkyle en C1-C6 ou arylalkyle en C1-C6 ;
- R22
- représente un atome d'hydrogène ; ou un groupe alkyle en C1-C6 non substitué ou substitué par des substituants halogène, hydroxy, cyano, phényle, carboxy, carbalkoxy en C1-C6 ou alkoxy en C1-C6 ;
- R23
- représente des groupes alkyle en C1-C22, alkyle en C4-C22 ramifié, alcényle en C2-C22 ou alcényle en C4-C22 ramifié ; glycol en C3-C22 ; alkoxy en C1-C22 ; alkoxy en C4-C22 ramifié ; et leurs mélanges ;
- M
- représente un atome d'hydrogène ; ou un ion métal alcalin ou ammonium,
- Z2
- représente un ion chlore, brome, alkyl- ou aralkylsulfate ;
- a
- vaut 0 ou 1 ;
- b
- va de 0 à 6 ;
- c
- va de 0 à 100 ;
- d
- vaut 0 ou 1 ;
- e
- va de 0 à 22 ;
- v
- est un entier de 2 à 12 ;
- w
- vaut 0 ou 1 ; et
- A
- représente un anion organique ou inorganique, et
- s
- en cas d'anions monovalents A- est égal à r et en cas d'anions multivalents est ≤r, As - devant compenser la charge positive ; où lorsque r ≠ 1, les restes Q1 peuvent être identiques ou différents,
- Composition selon la revendication 1 ou 2, caractérisée en ce qu'elle contient une phtalocyanine de formuleoù
- PC,
- X2, X3, R6 possèdent la signification donnée à la revendication 2 ;
- M
- représente un atome d'hydrogène, un ion sel de métal alcalin, d'ammonium ou d'amine ;
- As
- compense précisément la charge positive de la molécule du reste.
- Composition selon la revendication 1 ou 2, caractérisée en ce qu'elle contient une phtalocyanine de formule
- PC
- est défini comme à la revendication 2,
- R6 '
- représente un groupe alkylène en C2-C6 ;
- r1
- est un nombre de 1 à 4 ;
- X3'+
- représente un groupe de formule
- R7 et R8
- représentent, indépendamment l'un de l'autre, un groupe alkyle en C1-C4 non substitué ou substitué par des substituants hydroxy, cyano, halogène ou phényle ;
- R9
- représente R7 ; des groupes cyclohexyle ou amino ;
- R11
- représente un groupe alkyle en C1-C4 ;
- R21
- représente des groupes alkyle en C1-C4 ; alkoxy en C1-C4 ; halogène, carboxy, carbalkoxy en C1-C4 ou hydroxy ; et
- A'
- représente un ion halogénure, alkylsulfate ou arylsulfate ;
- Composition selon la revendication 1 ou 2, caractérisée en ce qu'elle contient une phtalocyanine de formuleoù
- PC
- représente le système cyclique phtalocyanine ;
- Me
- représente Zn, Fe(II), Ca, Mg, Na, K, Al-Z1, Si(IV), P(V), Ti(IV), Ge(IV), Cr(VI), Ga(III), Zr(IV), In(III), Sn(IV) ou Hf(VI) ;
- Z1
- représente un ion halogénure, sulfate, nitrate, acétate, alcoolate, carboxylate ou hydroxy ;
- q
- vaut 0, 1 ou 2 ;
- Y3
- représente un atome d'hydrogène ; un ion métal alcalin ou ammonium ; et
- r
- est un nombre arbitraire de 1 à 4.
- Composition selon la revendication 5, caractérisée en ce que à la formule (5)
- Me
- représente un atome de Zn ou un groupe Al-Z1 ; et
- Z1
- représente un ion halogénure, sulfate, nitrate, acétate, alcoolate, carboxylate ou hydroxy.
- Composition selon la revendication 1, 2 ou 5, caractérisé en ce que la composition contient une phtalocyanine de formuleoù
- R24
- représente des groupes hydroxy ; alkyle en
C1-C22 ; alkyle en C4-C22 ramifié ; alcényle en
C2-C22 ; alcényle en C4-C22 ramifié et ses
mélanges ; alkoxy en C1-C22 ; un reste sulfo ou
carboxyle ; un reste de formule
un reste alkoxy ramifié de formule
un motif allyloxyéthylène de formule -(T1)d-(CH2)b(OCH2CH2)a-B3
ou un reste ester de formule COOR23 ; et- U
- représente [Q1]r +AS - ; ou Q2.
- Composition selon l'une des revendications 1 à 7, caractérisée en ce que le composé quaternaire d'ammonium répond à la formule (1), où
- X1
- représente un atome d'halogène, des groupes -CH3SO4 - ; -C2H5SO4 - ; ou -NO3 -.
- Composition selon l'une des revendications 1 à 8, caractérisée en ce que à la formule (1) A et B représentent le reste de formule (1b).
- Composition selon l'une des revendications 1 à 7, caractérisée en ce que le composé d'ammonium quaternaire répond à la formuleR1, R2 et B représentent un groupe alkyle en C1-C5 ;
- R3
- représente le reste aliphatique de l'acide gras de suif et
- X3 -
- représente un atome d'halogène.
- Composition selon la revendication 1, contenant(a) une phtalocyanine hydrosoluble de formule (5) selon la revendication 5 et(b) un composé d'ammonium quaternaire de formule (8) selon la revendication 10.
- Composition selon la revendication 1, contenant(a) une phtalocyanine hydrosoluble de formule (10) selon la revendication 7 et(b) un composé d'ammonium quaternaire de formule (8) selon la revendication 10.
- Composition selon la revendication 1, caractérisée en ce qu'elle contient
de 0,0001 à 0,05 % en masse du composant (a) et de 1 à 20 % en masse du composant (b). - Procédé de blanchiment de matières fibreuses textiles à l'aide d'un agent de blanchiment photoactif, caractérisé en ce qu'on traite sous irradiation des matières textiles souillées dans un bain qui contient la composition d'adoucissant, contenantsous irradiation par la lumière dans le domaine du visible et/ou infrarouge ou la lumière du jour et en présence de l'oxygène, en irradiant soit le bain adoucissant directement, soit les matières textiles humides en dehors du bain adoucissant.(a) une phtalocyanine hydrosoluble de Zn, Fe(II), Ca, Mg, Na, K, Al, Si(IV), P(V), Ti(IV), Ge(IV), Cr(VI), Ga(III), Zr(IV), In(III), Sn(IV) ou Hf(VI) ; et(b) un composé d'ammonium quaternaire de formule (1),
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98810753A EP0899325B1 (fr) | 1997-08-15 | 1998-08-06 | Composition adoucissante pour textiles |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97810573 | 1997-08-15 | ||
| EP97810573 | 1997-08-15 | ||
| EP98810753A EP0899325B1 (fr) | 1997-08-15 | 1998-08-06 | Composition adoucissante pour textiles |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0899325A2 EP0899325A2 (fr) | 1999-03-03 |
| EP0899325A3 EP0899325A3 (fr) | 1999-07-21 |
| EP0899325B1 true EP0899325B1 (fr) | 2001-12-19 |
Family
ID=8230344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98810753A Expired - Lifetime EP0899325B1 (fr) | 1997-08-15 | 1998-08-06 | Composition adoucissante pour textiles |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6583105B1 (fr) |
| EP (1) | EP0899325B1 (fr) |
| JP (1) | JPH11172575A (fr) |
| KR (1) | KR100505528B1 (fr) |
| AU (1) | AU747856B2 (fr) |
| BR (1) | BR9803753A (fr) |
| DE (1) | DE59802506D1 (fr) |
| ES (1) | ES2169492T3 (fr) |
| ID (1) | ID20699A (fr) |
| NZ (1) | NZ331196A (fr) |
| ZA (1) | ZA987302B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1320090C (zh) * | 2002-09-04 | 2007-06-06 | 西巴特殊化学品控股有限公司 | 包含水溶性颗粒的制剂 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0959123B1 (fr) * | 1998-05-18 | 2004-07-28 | Ciba SC Holding AG | Granules de composés de phthalocyanine solubles dans l'eau |
| ATE272104T1 (de) | 1998-05-18 | 2004-08-15 | Ciba Sc Holding Ag | Wasserlösliche granulate von phthalocyaninverbindungen |
| BR0009241A (pt) * | 1999-03-05 | 2006-10-03 | Procter & Gamble | fotobranqueadores lìquidos hidrofóbicos |
| KR100554479B1 (ko) * | 2002-09-11 | 2006-03-03 | 씨제이라이온 주식회사 | 염착 얼룩 방지 세탁용 착염 |
| KR100502955B1 (ko) * | 2002-10-11 | 2005-07-21 | 씨제이라이온 주식회사 | 염착얼룩방지 세탁용 과립조성물 |
| US7345016B2 (en) * | 2003-06-27 | 2008-03-18 | The Procter & Gamble Company | Photo bleach lipophilic fluid cleaning compositions |
| EP1806392B1 (fr) * | 2005-09-06 | 2008-12-24 | Clariant (Brazil) S.A. | Composés quaternaires d'esters aqueuses stables |
| DE602008006099D1 (de) * | 2007-09-08 | 2011-05-19 | Unilever Nv | Verbesserungen im zusammenhang mit wäscheweichmachern |
| GB0717485D0 (en) * | 2007-09-08 | 2007-10-17 | Unilever Plc | Improvements relating to fabric conditioners |
| CN103147267B (zh) * | 2013-03-06 | 2015-07-15 | 浙江传化股份有限公司 | 一种低温练漂剂及其制备方法 |
| CN107406808B (zh) | 2015-01-19 | 2020-06-12 | 泰华施公司 | 洗衣用助干剂 |
| EP3805346A1 (fr) * | 2019-10-08 | 2021-04-14 | The Procter & Gamble Company | Procédé de lavage de tissu |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1408144A (en) | 1972-06-02 | 1975-10-01 | Procter & Gamble Ltd | Bleaching process |
| US4033718A (en) * | 1973-11-27 | 1977-07-05 | The Procter & Gamble Company | Photoactivated bleaching process |
| CA1064797A (fr) | 1975-04-03 | 1979-10-23 | Brandon H. Wiers | Produit de blanchissage photoactive et procede de fabrication |
| CH630127A5 (de) | 1977-03-25 | 1982-05-28 | Ciba Geigy Ag | Verfahren zum bleichen von textilien. |
| GR66580B (fr) | 1978-01-11 | 1981-03-27 | Procter & Gamble | |
| CA1104451A (fr) * | 1978-02-28 | 1981-07-07 | Manuel Juan De Luque | Traduction non-disponible |
| MX155643A (es) * | 1980-02-29 | 1988-04-11 | Ciba Geigy Ag | Composicion blanqueadora de telas |
| ATE12254T1 (de) * | 1980-12-22 | 1985-04-15 | Unilever Nv | Einen photoaktivator enthaltende zusammensetzung mit verbesserter bleichwirkung. |
| JP2855287B2 (ja) | 1990-08-22 | 1999-02-10 | ライオン株式会社 | 柔軟剤組成物 |
| DE69123704T2 (de) * | 1990-11-02 | 1997-04-30 | Zeneca Ltd | Polysubstituierte Phthalocyanine |
| JP3330200B2 (ja) | 1993-09-14 | 2002-09-30 | 花王株式会社 | 液体漂白剤組成物 |
| MX9700498A (es) * | 1994-07-19 | 1997-04-30 | Procter & Gamble | Perfumes para composiciones de lavanderia y limpieza. |
| IL116638A0 (en) | 1995-01-12 | 1996-05-14 | Procter & Gamble | Method and compositions for laundering fabrics |
| US5916481A (en) * | 1995-07-25 | 1999-06-29 | The Procter & Gamble Company | Low hue photobleaches |
| US5679661A (en) | 1995-07-25 | 1997-10-21 | The Procter & Gamble Company | Low hue photodisinfectants |
-
1998
- 1998-07-31 NZ NZ331196A patent/NZ331196A/xx unknown
- 1998-08-06 ES ES98810753T patent/ES2169492T3/es not_active Expired - Lifetime
- 1998-08-06 EP EP98810753A patent/EP0899325B1/fr not_active Expired - Lifetime
- 1998-08-06 DE DE59802506T patent/DE59802506D1/de not_active Expired - Lifetime
- 1998-08-10 ID IDP981114A patent/ID20699A/id unknown
- 1998-08-13 KR KR10-1998-0032821A patent/KR100505528B1/ko not_active IP Right Cessation
- 1998-08-14 ZA ZA987302A patent/ZA987302B/xx unknown
- 1998-08-14 AU AU80006/98A patent/AU747856B2/en not_active Ceased
- 1998-08-14 BR BR9803753-6A patent/BR9803753A/pt not_active IP Right Cessation
- 1998-08-17 JP JP10230444A patent/JPH11172575A/ja active Pending
-
2000
- 2000-07-19 US US09/618,870 patent/US6583105B1/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1320090C (zh) * | 2002-09-04 | 2007-06-06 | 西巴特殊化学品控股有限公司 | 包含水溶性颗粒的制剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0899325A3 (fr) | 1999-07-21 |
| DE59802506D1 (de) | 2002-01-31 |
| AU8000698A (en) | 1999-02-25 |
| JPH11172575A (ja) | 1999-06-29 |
| EP0899325A2 (fr) | 1999-03-03 |
| NZ331196A (en) | 2000-01-28 |
| ES2169492T3 (es) | 2002-07-01 |
| ID20699A (id) | 1999-02-18 |
| KR19990023559A (ko) | 1999-03-25 |
| ZA987302B (en) | 1999-02-15 |
| US6583105B1 (en) | 2003-06-24 |
| AU747856B2 (en) | 2002-05-23 |
| KR100505528B1 (ko) | 2005-11-09 |
| BR9803753A (pt) | 1999-12-07 |
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