EP0865527B1 - Procede de teinture de bandes textiles realisees en fibres polyester ou dans un melange de fibres polyester et d'autres fibres et roulard correspondant - Google Patents
Procede de teinture de bandes textiles realisees en fibres polyester ou dans un melange de fibres polyester et d'autres fibres et roulard correspondant Download PDFInfo
- Publication number
- EP0865527B1 EP0865527B1 EP96934360A EP96934360A EP0865527B1 EP 0865527 B1 EP0865527 B1 EP 0865527B1 EP 96934360 A EP96934360 A EP 96934360A EP 96934360 A EP96934360 A EP 96934360A EP 0865527 B1 EP0865527 B1 EP 0865527B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dyeing
- textile web
- jigger
- colour index
- index disperse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004043 dyeing Methods 0.000 title claims description 45
- 239000004753 textile Substances 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 20
- 241001584775 Tunga penetrans Species 0.000 title claims description 16
- 229920000728 polyester Polymers 0.000 title claims description 14
- 239000000203 mixture Substances 0.000 title claims description 5
- 239000000835 fiber Substances 0.000 title description 24
- 239000004744 fabric Substances 0.000 title description 3
- 238000004804 winding Methods 0.000 claims description 16
- 238000009835 boiling Methods 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 claims description 4
- SBSBBPZTTALABX-UHFFFAOYSA-N 1,8-diamino-2-bromo-4,5-dihydroxyanthracene-9,10-dione Chemical compound O=C1C2=C(O)C=C(Br)C(N)=C2C(=O)C2=C1C(O)=CC=C2N SBSBBPZTTALABX-UHFFFAOYSA-N 0.000 claims description 4
- NPBDWXMKLFBNIW-UHFFFAOYSA-N 3-[4-[(2-chloro-4-nitrophenyl)diazenyl]-n-ethylanilino]propanenitrile Chemical compound C1=CC(N(CCC#N)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl NPBDWXMKLFBNIW-UHFFFAOYSA-N 0.000 claims description 4
- UNBOSJFEZZJZLR-UHFFFAOYSA-N 4-(4-nitrophenylazo)aniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1 UNBOSJFEZZJZLR-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- QJGOOFISESXSNF-UHFFFAOYSA-N methyl 4-[(3-methyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]benzoate Chemical compound C1=CC(C(=O)OC)=CC=C1N=NC1C(=O)N(C=2C=CC=CC=2)N=C1C QJGOOFISESXSNF-UHFFFAOYSA-N 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 3
- FOQABOMYTOFLPZ-ISLYRVAYSA-N Disperse Red 1 Chemical compound C1=CC(N(CCO)CC)=CC=C1\N=N\C1=CC=C([N+]([O-])=O)C=C1 FOQABOMYTOFLPZ-ISLYRVAYSA-N 0.000 claims description 3
- DSSYKIVIOFKYAU-UHFFFAOYSA-N camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 claims description 3
- 230000002441 reversible effect Effects 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 239000000975 dye Substances 0.000 description 31
- 230000008569 process Effects 0.000 description 8
- 239000000986 disperse dye Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 239000000969 carrier Substances 0.000 description 4
- 238000000859 sublimation Methods 0.000 description 4
- 230000008022 sublimation Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010016 exhaust dyeing Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/32—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of open-width materials backwards and forwards between beaming rollers during treatment; Jiggers
Definitions
- the invention relates to a method and a jigger for dyeing textile webs made of polyester fibers (PES fibers) or mixtures of PES fibers with other natural fibers, especially cellulosic fibers such as cotton, but also linen, wool etc., and synthetic fibers such as Viscose fibers and the like, in which a web of material from a dock unwound, passed through a dye bath and subsequently to a dock is rewound and this process repeated by reversing the direction of the path movement.
- PES fibers polyester fibers
- synthetic fibers such as Viscose fibers and the like
- thermosol process mentioned under 3 is because of the comparatively low fleet absorption of about 35% for dyeing 100% polyester fibers Textile webs have disadvantages. In particular, the Uniformity of color picking left something to be desired. Furthermore is the thermosol process like all continuous processes economically only suitable for larger dyeing batches.
- FR-A-1 333 808 on which the generic term is based shows a jigger etc. for dyeing polyester, in which onto the web before winding onto one of the rolls of steam is sprayed on both sides over the surface of the web should sweep away. After applying the steam and before it hits the roll, the web passes a guide roller-spreader combination. It has shown, that the temperature-increasing and coloring-promoting effect this arrangement is in need of improvement.
- the object of the invention is the dyeing of textile webs from polyester and its To improve mixtures.
- a key factor in staining PES is the dyeing temperature.
- pressureless (atmospheric) dyeing machines can at most reach the cooking temperature of the fleet that are known to depend on the height of the location is dependent on the sea.
- At a height above sea level of about 300 m is the maximum achievable temperature in closed Dyeing vessels at about 98 ° C to 99 ° C, provided that a perfect seal of the hood space of the Jiggers.
- the textile web is after it emerges from the boiling point or immediately below the boiling temperature of the dye bath Supply of thermal energy directly into the winding nip and by using the heat of condensation to saturated steam temperature of 100 ° C brought and docked under these operating conditions - the temperature reached is "wrapped up", so to speak and benefits from the winding process.
- a temperature gain of only a few degrees leads to a noticeable increase the dye yield of several percent.
- the invention allows textile webs comprising polyester fibers with good color depth and color fastness in a comparative simple, no pressure-resistant housing required Device and with comparatively low energy consumption to color without a large number of passes of the Goods through the dye bath are required.
- these dyes are "small-molecular” Disperse dyes, ie “low energy” types with high migration capacity, i.e. Dyes that are low Need energy for penetration into the fiber, as well acceptable sublimation fastness. This applies - with certain Restrictions - also for "medium molecular” disperse dyes, the “medium energy” types with sufficient Migration ability and very good fastness to sublimation. Large molecules Disperse dyes or "high energy” types with low migration capacity and maximum sublimation fastness usually turn out to be less or not suitable.
- the disperse dyes mentioned meet the above mentioned criteria. With these dyes Trichromas are also possible to the extent necessary. Furthermore sufficient sublimation fastness is guaranteed. Especially with the mentioned types of dyes Interact with the additional heating, that is higher dyeing temperatures, better dyeing results.
- the concentration gradient affects dye diffusion in the fiber.
- An embodiment of the invention is as follows based on the drawing of a 2-tank jigger explained, which is a perspective, partially broken and schematic representation of one in its basic elements known jiggers.
- the jigger comprises two winding rollers in a housing 10 21, 22, between which a textile web 1 made of PES fibers extends and is wrapped around and between which two small ones Can be used alternately or in the same run one after the other Basin 11 and 12 and in between a height adjustable Spreader-coating tube 13 are arranged. Furthermore, with adjustable force can be pressed against the winding rollers 21 and 22 Pressure rollers 14, 15 provided a clean winding formation should support.
- the housing 10 is in suitably against the intrusion or exchange effectively sealed with outside air. It points for the Batch change on a pivotable access hatch 16.
- the dye liquors 2, 3 in the basins are temperature sensors 11, 12 with the help of heating registers 4 Temperature adjusted, the same or only slightly, e.g. B. 1 ° C, less than the boiling temperature of the dye liquors under the prevailing atmospheric pressure conditions.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
Claims (7)
- Procédé de teinture de bandes textiles réalisées en fibres polyester (fibres PES) ou par des mélanges de fibres PES avec d'autres fibres dans un bain de teinture dans un jigger, dans lequelcaractérisé en ce quela bande textile est déroulée à partir de l'une des bobines du jigger, puis dirigée dans le bain de teinture, et enfin, aussitôt enroulée à nouveau sur l'autre bobine du jigger, le sens de l'enroulement étant inversé après le passage de la longueur de la bande textile,la teinture a lieu à la pression atmosphérique sans entrée d'air ou sans échange avec l'atmosphère environnante, d'une manière telle que, dans le bain de teinture, on maintient la température d'ébullition de ce bain ou une température se situant directement en dessous de la température d'ébullition,la bande textile est en outre chauffée avant son passage sur la bobine à enrouler,
le chauffage a lieu en soufflant de la vapeur saturée sur la bande textile directement dans la fente d'enroulement. - Procédé de teinture selon la revendication 1,
caractérisé en ce que
dans le bain de teinture sont présents un ou plusieurs types de colorants :indice de couleur jaune dispersable 3indice de couleur jaune dispersable 60indice de couleur jaune dispersable 68indice de couleur orange dispersable 3indice de couleur rouge dispersable 1indice de couleur rouge dispersable 50indice de couleur violet dispersable 1indice de couleur bleu dispersable 81 - Procédé de teinture selon la revendication 1 ou la revendication 2,
caractérisé en ce que
le rapport de bain atteint 1 : 1,3 à 1 : 2, 5. - Procédé de teinture selon l'une des revendications 1 à 3,
caractérisé en ce qu'
on fournit au bain de teinture un agent formateur de pellicule qui accroít son pouvoir de portance sur la bande textile réalisée en fibres PES. - Procédé de teinture selon l'une des revendications 1 à 4
caractérisé en ce que
l'agent formateur de pellicule est à base de polymères d'amide acrylique. - Jigger large pour la mise en oeuvre du procédé selon l'une des revendications 1 à 5,caractérisé paravec un carter étanche (10) par ailleurs accessible au changement des lots,avec deux rouleaux d'enroulement (21, 22) montés de façon à pouvoir tourner dans le carter (10), et qui peuvent être entraínés de façon alternée, rouleaux entre lesquels on peut faire aller et venir la bande textile (1) en l'enroulant dans un sens et dans l'autre,avec au moins un bain de teinture à travers lequel on peut faire passer la bande textile (1) en l'enroulant, etavec un dispositif de chauffage (17, 4) qui sert à maintenir le bain de teinture à la température d'ébullition du bain de teinture (2, 3) ou à une température qui se situe immédiatement en dessous de sa température d'ébullition, à la pression sensiblement atmosphérique, à l'intérieur du boítier (10),
des tuyaux additionnels d'injection de vapeur (18, 19) qui sont opérationnels dans le sens perpendiculaire sur toute la largeur de la bande textile (1) qui sont disposés sur le côté de l'enroulement de la bande textile (1) et exposent la bande textile (1) à l'action de la vapeur saturée immédiatement dans la fente d'enroulement avant son passage sur la bobine à d'enroulement. - Jigger large selon la revendication 6,
caractérisé en ce qu'
il est du type à deux cuves.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19543314A DE19543314C1 (de) | 1995-11-21 | 1995-11-21 | Verfahren zum Färben von Textilbahnen aus Polyesterfasern oder Gemischen aus Polyesterfasern mit anderen Fasern und entsprechender Jigger |
| DE19543314 | 1995-11-21 | ||
| PCT/DE1996/001543 WO1997019214A1 (fr) | 1995-11-21 | 1996-08-20 | Procede de teinture de bandes textiles realisees en fibres polyester ou dans un melange de fibres polyester et d'autres fibres et roulard correspondant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0865527A1 EP0865527A1 (fr) | 1998-09-23 |
| EP0865527B1 true EP0865527B1 (fr) | 1999-12-08 |
Family
ID=7777976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP96934360A Expired - Lifetime EP0865527B1 (fr) | 1995-11-21 | 1996-08-20 | Procede de teinture de bandes textiles realisees en fibres polyester ou dans un melange de fibres polyester et d'autres fibres et roulard correspondant |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6036728A (fr) |
| EP (1) | EP0865527B1 (fr) |
| BR (1) | BR9611604A (fr) |
| DE (2) | DE19543314C1 (fr) |
| ES (1) | ES2140139T3 (fr) |
| WO (1) | WO1997019214A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1010795A3 (fr) | 1998-12-14 | 2001-06-13 | Tve-Escale Europe, S.A. | Machine pour le lavage et le blanchiment des étoffes textiles et analogues |
| US20050065757A1 (en) * | 2003-09-19 | 2005-03-24 | White Samer R. | System and method for estimating displacement of a seat-belted occupant |
| US20050202241A1 (en) * | 2004-03-10 | 2005-09-15 | Jian-Ku Shang | High surface area ceramic coated fibers |
| ES2301389B1 (es) * | 2006-10-19 | 2009-06-08 | La Superquimica, S.A. | Procedimiento para la impregnacion de fibras celulosicas. |
| CN106483902B (zh) * | 2016-11-23 | 2019-07-05 | 北华大学 | 一种基于互联网的高温高压卷染机电控控制系统 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2405669A (en) * | 1938-06-14 | 1946-08-13 | Celanese Corp | Coloration of textile materials |
| US3067602A (en) * | 1960-09-24 | 1962-12-11 | British Nylon Spinners Ltd | Apparatus for the treatment of textile materials |
| FR1333808A (fr) * | 1962-05-28 | 1963-08-02 | Teintureries Laval S A | Perfectionnement apporté à la teinture des tissus composés de fibres synthétiques hydrophobes sur appareils conventionnels |
| GB1045857A (en) * | 1963-05-22 | 1966-10-19 | Kyoto Kikai Kabushiki Kaisha | Method and apparatus for continuously winding and unwinding textiles in textile treating machines |
| GB1135288A (en) * | 1966-03-02 | 1968-12-04 | Smith F & Co Whitworth Ltd | Dyeing of textile materials |
| JPS5338784A (en) * | 1976-09-16 | 1978-04-10 | Akaza Textile Ind | Ombre dyeing method of woven cloth by special heating method |
| JPS59125992U (ja) * | 1983-02-16 | 1984-08-24 | 株式会社小野森鉄工所 | ジツガ−染色装置 |
| DE3341915C1 (de) * | 1983-11-19 | 1985-06-13 | Küsters, Eduard, 4150 Krefeld | Jigger |
| DE3705390A1 (de) * | 1987-02-20 | 1988-09-01 | Kuesters Eduard Maschf | Jigger |
| DE4429058C2 (de) * | 1994-08-16 | 1997-07-31 | Kuesters Eduard Maschf | Kleinveredlungsanlage |
| FR2725219B1 (fr) * | 1994-09-29 | 1996-12-20 | Inst Textile De France | Procede et appareil d'ennoblissement textile, du type jigger, mettant en oeuvre des ondes electromagnetiques |
-
1995
- 1995-11-21 DE DE19543314A patent/DE19543314C1/de not_active Expired - Fee Related
-
1996
- 1996-08-20 DE DE59603888T patent/DE59603888D1/de not_active Expired - Fee Related
- 1996-08-20 ES ES96934360T patent/ES2140139T3/es not_active Expired - Lifetime
- 1996-08-20 BR BR9611604A patent/BR9611604A/pt not_active Application Discontinuation
- 1996-08-20 EP EP96934360A patent/EP0865527B1/fr not_active Expired - Lifetime
- 1996-08-20 WO PCT/DE1996/001543 patent/WO1997019214A1/fr active IP Right Grant
- 1996-08-20 US US09/077,153 patent/US6036728A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO1997019214A1 (fr) | 1997-05-29 |
| DE19543314C1 (de) | 1996-10-02 |
| US6036728A (en) | 2000-03-14 |
| ES2140139T3 (es) | 2000-02-16 |
| DE59603888D1 (de) | 2000-01-13 |
| BR9611604A (pt) | 1999-04-06 |
| EP0865527A1 (fr) | 1998-09-23 |
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