EP0806510A1 - Matériau de garnissage, procédé pour sa fabrication et son utilisation - Google Patents

Matériau de garnissage, procédé pour sa fabrication et son utilisation Download PDF

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Publication number
EP0806510A1
EP0806510A1 EP97106879A EP97106879A EP0806510A1 EP 0806510 A1 EP0806510 A1 EP 0806510A1 EP 97106879 A EP97106879 A EP 97106879A EP 97106879 A EP97106879 A EP 97106879A EP 0806510 A1 EP0806510 A1 EP 0806510A1
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EP
European Patent Office
Prior art keywords
monofilaments
carrier
carrier insert
reinforcement
elongation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97106879A
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German (de)
English (en)
Other versions
EP0806510B1 (fr
Inventor
Werner Dr. Groh
Hans-Jürgen Profé
Michael Schöps
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Johns Manville
Original Assignee
Hoechst Trevira GmbH and Co KG
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Publication of EP0806510A1 publication Critical patent/EP0806510A1/fr
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/04Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/105Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by needling
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/12Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with filaments or yarns secured together by chemical or thermo-activatable bonding agents, e.g. adhesives, applied or incorporated in liquid or solid form
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/902High modulus filament or fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/643Including parallel strand or fiber material within the nonwoven fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/643Including parallel strand or fiber material within the nonwoven fabric
    • Y10T442/644Parallel strand or fiber material is glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/643Including parallel strand or fiber material within the nonwoven fabric
    • Y10T442/645Parallel strand or fiber material is inorganic [e.g., rock wool, mineral wool, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681Spun-bonded nonwoven fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/696Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]

Definitions

  • the invention relates to a carrier insert which is particularly suitable as a carrier insert for producing roofing sheets or as a tarpaulin or surface.
  • Carrier inserts for the production of roofing membranes must meet a wide range of requirements. On the one hand, sufficient mechanical stability is required, such as good perforation resistance and good tensile strength, in order, for example, to withstand the mechanical loads during further processing, such as bituminization or laying. In addition, a high level of resistance to thermal stress, for example when bituminizing or to radiant heat, and resistance to flying flames are required. There has been no shortage of attempts to improve existing core inserts.
  • nonwovens based on synthetic fiber nonwovens with reinforcing fibers for example with glass fibers.
  • sealing sheets can be found in GB-A-1,517,595, DE-Gbm-77-39,489, EP-A-160,609, EP-A-176-847, EP-A-403,403 and EP-A-530,769.
  • the connection between the nonwoven fabric and the reinforcing fibers takes place either by gluing with a binder or by needling the layers of different material.
  • DE-A-3,417,517 discloses a textile interlining material with anisotropic properties and a process for its production.
  • the interlining consists of a substrate which has a surface melting below 150 ° C and associated reinforcement filaments melting above 180 ° C, which are fixed on this surface parallel to each other.
  • the substrate can be a nonwoven fabric, on one surface of which there are hot-melt adhesive fibers or filaments which are provided for producing a bond between the reinforcing fibers arranged in parallel with the nonwoven fabric.
  • EP-A-0,281,643 discloses a combination of reinforcing fibers in the form of a network of bicomponent fibers with nonwovens based on synthetic fibers, the weight fraction of the network of bicomponent fibers being at least 15% by weight.
  • a filter material made of inorganic non-woven material and metal wires is known, which is used for exhaust air purification at high temperatures (higher than 300 ° C).
  • DE-Gbm-295 00 830 describes the reinforcement of a glass fleece with synthetic monofilaments. These reinforcing monofilaments do not contribute significantly to the reference force at low strains in the sealing membrane. However, they have a significantly higher maximum tensile strength expansion than the glass fleece; thus the areal connection of the geomembrane also becomes guaranteed in the event of deformations that can lead to breakage of the glass fleece.
  • the shrinkage of the synthetic monofilaments is higher than the shrinkage of the glass fleece and can lead to waviness in the sealing membrane.
  • DE-A-3,941,189 also discloses a combination of reinforcing fibers in the form of a thread chain with nonwovens based on synthetic fibers, which can be connected to one another in a wide variety of ways.
  • a preferred connection technique is needling. With needling there is a risk of damage or breakage of the reinforcement threads.
  • monofilaments are used, the diameter of which is larger than the notch protrusion of the needles.
  • the reinforcement by monofilaments according to the invention leads to particularly low values of the expansion reserve; due to their inherent rigidity, these monofilaments or flat structures made from them can be fed in in a particularly well-oriented manner and installed in the carrier insert. Unlike multifilaments, they always have a load-bearing effect across their entire cross-section.
  • the diameter of the monofilaments is preferably greater than the sum of the notch protrusion and the notch depth of the needles.
  • the diameter of the monofilaments used is usually at least 0.1 mm.
  • the present invention relates to a carrier insert containing a textile fabric and a reinforcement, characterized in that the Reinforcement contains monofilaments with a diameter of at least 0.1 mm, preferably between 0.1-1 mm, particularly preferably 0.1-0.5 mm, and particularly preferably 0.1-0.3 mm.
  • Such carrier inserts can absorb a force, so that in the force-elongation diagram (at 20 ° C) the reference force of the carrier insert with reinforcement compared to the carrier insert without reinforcement in the range between 0 and 1% elongation at least at one point by at least 10% , preferably by at least 20%, particularly preferably by at least 30%.
  • textile fabric is to be understood in its broadest meaning within the scope of this description. These can be all structures made of fibers from synthesized polymers that have been manufactured using a surface-forming technique.
  • notch depth and notch protrusion are defined in a brochure from Groz-Beckert from 1994 with the name "felting and structuring needles”.
  • the reference force is measured in accordance with EN 29073, Part 3, on 5 cm wide samples with a measuring length of 100 mm.
  • textile fabrics are fabrics, scrims, knitted fabrics and knitted fabrics, and preferably nonwovens.
  • spunbonded fabrics which are produced by randomly depositing freshly melt-spun filaments are preferred. They consist of endless synthetic fibers made of melt-spinnable polymer materials.
  • Suitable polymer materials are, for example, polyamides, such as polyhexamethylene diadipamide, polycaprolactam, aromatic or partially aromatic polyamides (“aramids”), aliphatic polyamides, such as nylon, partially aromatic or fully aromatic polyesters, polyphenylene sulfide (PPS), polymers with ether and keto groups, such as polyether ketones (PEK) and poly ether ketones (PEEK), or polybenzimidazoles.
  • the spunbonded fabrics preferably consist of melt-spinnable polyesters.
  • polyester material consist predominantly of building blocks which are derived from aromatic dicarboxylic acids and from aliphatic diols.
  • Common aromatic dicarboxylic acid building blocks are the divalent residues of benzenedicarboxylic acids, in particular terephthalic acid and isophthalic acid;
  • Common diols have 2 to 4 carbon atoms, with the ethylene glycol being particularly suitable.
  • Spunbonded fabrics which consist of at least 85 mol% of polyethylene terephthalate are particularly advantageous.
  • dicarboxylic acid units and glycol units which act as so-called modifying agents and which allow the person skilled in the art to specifically influence the physical and chemical properties of the filaments produced.
  • dicarboxylic acid units are residues of isophthalic acid or of aliphatic dicarboxylic acid such as e.g. Glutaric acid, adipic acid, sebacic acid;
  • diol residues with a modifying action are those of longer-chain diols, e.g. B. of propanediol or butanediol, of di- or triethylene glycol or, if present in small quantities, of polyglycol with a molecular weight of about 500 to 2000.
  • Polyesters which contain at least 95 mol% of polyethylene terephthalate (PET), in particular those made of unmodified PET, are particularly preferred.
  • the carrier inlays according to the invention are also to have a flame-retardant effect, it is advantageous if they have been spun from flame-retardant modified polyesters.
  • flame-retardant modified polyesters are known. They contain additions of halogen compounds, in particular bromine compounds, or, which is particularly advantageous, they contain phosphorus compounds which are condensed into the polyester chain.
  • the spunbonded fabrics particularly preferably contain flame-retardant modified polyesters which in the chain contain assemblies of the formula (I) wherein R is alkylene or polymethylene with 2 to 6 carbon atoms or phenyl and R 1 is alkyl with 1 to 6 carbon atoms, aryl or aralkyl, contained in condensed form.
  • R is preferably ethylene and R 1 is methyl, ethyl, phenyl, or o-, m- or p-methylphenyl, in particular methyl.
  • Such spunbonded fabrics are described, for example, in DE-A-39 40 713.
  • the polyesters contained in the spunbonded fabrics preferably have a molecular weight corresponding to an intrinsic viscosity (IV), measured in a solution of 1 g of polymer in 100 ml of dichloroacetic acid at 25 ° C., from 0.6 to 1.4.
  • IV intrinsic viscosity
  • the individual titer of the polyester filaments in the spunbonded fabric is between 1 and 16 dtex, preferably 2 to 8 dtex.
  • the spunbonded nonwoven can also be a nonwoven bond strengthened by melt binder, which contains carrier and hot-melt adhesive fibers.
  • the carrier and hot-melt adhesive fibers can be derived from any thermoplastic thread-forming polymers.
  • Carrier fibers can also be derived from non-melting thread-forming polymers.
  • melt-bond-strengthened spunbonded fabrics are described, for example, in EP-A-0,446,822 and EP-A-0,590,629.
  • polymers from which the carrier fibers can be derived are polyacrylonitrile, polyolefins, such as polyethylene, essentially aliphatic polyamides, such as nylon 6.6, essentially aromatic polyamides (aramids), such as poly (p-phenylene terephthalamide) or copolymers containing a proportion on aromatic m-diamine units to improve solubility or poly (m-phenylene isophthalamide), essentially aromatic polyesters, such as poly (p-hydroxybenzoate) or preferably essentially aliphatic polyesters, such as polyethylene terephthalate.
  • the proportion of the two types of fibers to one another can be selected within wide limits, it being important to ensure that the proportion of hot-melt adhesive fibers is chosen so high that the nonwoven fabric is given sufficient strength for the desired application by bonding the carrier fibers to the hot-melt adhesive fibers.
  • the proportion of hot melt adhesive originating from the hot melt adhesive fiber in the nonwoven fabric is usually less than 50% by weight, based on the weight of the nonwoven fabric.
  • Modified polyesters with a melting point which is lowered by 10 to 50 ° C., preferably 30 to 50 ° C., compared to the nonwoven raw material, are particularly suitable as hot-melt adhesives.
  • hot melt adhesives are polypropylene, polybutylene terephthalate or by condensing longer-chain diols and / or polyethylene terephthalate modified by isophthalic acid or aliphatic dicarboxylic acids.
  • the hot melt adhesives are preferably introduced into the nonwovens in fiber form.
  • Carrier and hot-melt adhesive fibers are preferably constructed from one polymer class. This means that all fibers used are selected from a class of substances so that they can be easily recycled after the fleece has been used.
  • the carrier fibers consist of polyester
  • the hot melt adhesive fibers are also made of polyester or a mixture of polyesters, e.g. B. selected as a bicomponent fiber with PET in the core and a lower melting polyethylene terephthalate copolymer as a sheath:
  • bicomponent fibers are also possible which are made up of different polymers. Examples include bicomponent fibers made of polyester and polyamide (core / shell).
  • the individual fiber titers of the carrier and hot melt adhesive fibers can be selected within wide limits. Examples of common titer ranges are 1 to 16 dtex, preferably 2 to 6 dtex.
  • the carrier inserts according to the invention with flame-retardant properties are additionally bound, they preferably contain flame-retardant hot-melt adhesives.
  • flame retardant hot melt adhesive z. B. a modified by incorporation of chain links of the formula (I) indicated polyethylene terephthalate in the laminate according to the invention.
  • the filaments or staple fibers that make up the nonwovens can have a practically round cross section or can also have other shapes, such as dumbbell, kidney-shaped, triangular or tri or multilobal cross sections. Hollow fibers can also be used. Furthermore, the hot-melt adhesive fiber can also be used in the form of bi- or multicomponent fibers.
  • the fibers forming the textile fabric can be modified by conventional additives, for example by antistatic agents such as carbon black.
  • the weight per unit area of the spunbonded fabric is between 20 and 500 g / m 2 , preferably 40 and 250 g / m 2 .
  • the reinforcement used in the carrier insert according to the invention is such that it absorbs and dissipates a force even at an elongation in the range from 0 to 1% (at an ambient temperature of 20 ° C.), so that the reference force is shown in the force-elongation diagram (KD diagram ) increases by at least 10%, preferably by at least 20%, particularly preferably by at least 30%, compared to the unreinforced carrier insert.
  • the reinforcement is such that the reference force of the carrier insert at room temperature (20 ° C.) divided by the reference force of the carrier insert at 180 °, measured at at least one point in the range between 0 and 1% elongation, has a quotient of at most 3 ( three), preferably at most 2.5, particularly preferably less than 2.
  • the above properties are obtained by monofilaments whose Young's modulus is at least 5 Gpa, preferably at least 10 Gpa, particularly preferably at least 20 Gpa.
  • the abovementioned monofilaments have a diameter between 0.1 and 1 mm, preferably 0.1 and 0.5 mm, in particular 0.1 and 0.3 mm and have an elongation at break of 0.5 to 100%, preferably 1 to 60 %.
  • the carrier inlays according to the invention particularly advantageously have an expansion reserve of less than 1%.
  • the stretch reserve is the stretch that acts on the carrier insert before the force acting on the monofilaments is dissipated, ie a stretch reserve of 0% would mean that tensile forces acting on the carrier insert would be dissipated immediately on the monofilaments. This means that forces acting on the spunbonded fabric do not first bring about an alignment or orientation of the monofilaments, but rather are derived directly on the monofilaments, so that damage to the textile fabric can be avoided. This is particularly evident in a steep increase in the force to be applied with small strains (force-strain diagram at room temperature).
  • suitable monofilaments that have a high elongation at break the maximum tensile strength elongation of the carrier insert can be considerably improved. For example, high-strength monofilaments made of polyester or wires made of metals or metallic alloys with an elongation at break of at least 10% are suitable.
  • Monofilaments based on aramids preferably so-called high-module aramids, high-strength polyester monofilaments and particularly preferably monofilament wires made of metals or metallic alloys, are preferably used.
  • preferred reinforcements consist of metal monofilaments in the form of parallel thread sheets, scrims or fabrics, which may also contain other monofilaments or multifilaments.
  • the nonwovens are only reinforced in the longitudinal direction by thread sheets running in parallel.
  • the reinforcement by monofilaments according to the invention leads to particularly low values of the expansion reserve; due to their inherent rigidity, these monofilaments or flat structures made from them can be fed in in a particularly well-oriented manner and installed in the carrier insert. Unlike multifilaments, they always have a load-bearing effect across their entire cross-section.
  • the monofilaments are preferably fed in during spunbond formation and thus embedded in the spunbonded fabric.
  • the thread density can vary within wide limits depending on the desired property profile.
  • the thread density is preferably between 20 and 200 threads per Meter.
  • the thread density is measured perpendicular to the thread running direction.
  • the spunbonded nonwovens are usually subjected to chemical or thermal and / or mechanical consolidation in a known manner.
  • the spunbonded fabrics are preferably mechanically consolidated by needling.
  • the spunbonded fabric which advantageously already contains the monofilaments, is usually needled with a needle density of 20 to 100 stitches / cm 2 .
  • the needling is carried out according to the invention by needles whose notch protrusion, preferably the sum of notch protrusion and notch depth, is smaller than the diameter of the monofilaments. This will not damage the monofilaments.
  • the spunbonded webs are then subjected to further consolidation steps, for example a thermal treatment.
  • the spunbonded nonwovens which can be bonded with melt binders and which also contain binder fibers in addition to carrier fibers, are thermally bonded in a manner known per se with a calender or in an oven. If the spunbonded fabrics do not contain any binding fibers capable of thermal consolidation, these spunbonded fabrics are impregnated with a chemical binder. Acrylic binders are particularly suitable for this. The proportion of binder is expediently up to 30% by weight, preferably 2 to 25% by weight. The exact choice of the binder is based on the special interests of the processor. Hard binders allow high processing speeds with impregnation, especially bituminization, while a soft binder gives particularly high values of tear and nail tear resistance.
  • flame-retardant modified binders can also be used.
  • the carrier web according to the invention has an embossing pattern of statistically distributed or repeat arranged, small-area embossments, preferably a canvas embossing, in which the pressing surface, ie the totality of all thin, compacted areas of the spunbonded fabric makes up 30 to 60%, preferably 40 to 45% of its total area, and the thickness of the compacted areas of the nonwoven fabric is at least 20%, preferably 25 to 50%, the thickness of the non-compacted areas of the nonwoven.
  • this embossing pattern can advantageously be applied during calender bonding.
  • the embossing pattern can also be embossed using a calender.
  • This embossing pattern which is applied to both surfaces of the spunbonded fabric, but preferably only to one surface of the spunbonded fabric, when it passes through the spunbonded fabric, has a large number of small embossments which have a size of 0.2 to 40 mm 2 , preferably 0 , 2 to 10 mm 2 , and are separated from one another by interposed, approximately the same size, non-embossed surface elements of the fleece.
  • the area of the compacted areas of the nonwoven and the non-compacted areas of the nonwoven can be determined, for example, by means of microscopic cross-sectional images.
  • the carrier inlays according to the invention can be combined with other textile fabrics, so that their properties are variable.
  • Such composites, which contain the carrier insert according to the invention, are also the subject of the invention.
  • the reinforcement from monofilaments can be supplied before, during and / or after the formation of the textile surface.
  • the process is characterized by the feeding of the monofilaments and any thermal treatment in the manufacturing process of the carrier insert under tension, in particular under longitudinal tension.
  • a thermal treatment under tension is present if the layer is retained as monofilaments in the carrier insert during a thermal step; the preservation of the longitudinal threads by applying a longitudinal tension is of particular interest.
  • the formation of the textile fabric can take place on a tapered monofilament or the monofilaments can during the surface formation process, for. B. in the production of nonwovens, or it can be finished a textile fabric and connected by subsequent assembly with a reinforcement in the form of monofilaments.
  • the combination of the textile fabric with the reinforcement can be carried out by measures known per se, for example by needling or gluing, including hot melt gluing. The advantages of the process are particularly evident in the production of needled carrier inserts.
  • the production of a textile fabric as described can be carried out by spunbonding by means of spinning apparatus known per se.
  • the molten polymer is carried through several series of spinnerets or groups of spinneret series Polymers. If a melt-bond-strengthened spunbonded nonwoven is to be produced, polymers are alternately loaded, which form the carrier fiber and the hot-melt adhesive fibers. The spun polymer streams are stretched in a conventional manner, and z. B. deposited using a rotating baffle in scattering texture on a conveyor belt.
  • nonwoven layer on the reinforcement or a subsequent layer formation from reinforcement and nonwoven fabric by assembly is preferred.
  • the carrier inserts according to the invention can also be combined with other components to form multilayer composites.
  • other components are glass fleeces, thermoplastic or metallic foils, insulation materials, etc.
  • the carrier inserts according to the invention can be used for the production of bituminized roofing and waterproofing membranes.
  • the carrier material is treated with bitumen in a manner known per se and then optionally sprinkled with a granular material, for example with sand.
  • the roofing and waterproofing membranes produced in this way are easy to process.
  • the bituminized webs contain at least one carrier web embedded in a bitumen matrix - described above - the weight fraction of the bitumen in the basis weight of the bituminized roofing web preferably being 40 to 90% by weight and that of the spunbonded fabric 10 to 60% by weight.
  • These membranes can also be a so-called roof membrane.
  • bitumen another material, for example polyethylene or polyvinyl chloride, can also be used to coat the carrier insert according to the invention be used.
  • PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 2 m width.
  • steel wires are continuously fed at a distance of 2 cm (50 wires / m) in the longitudinal direction.
  • the wires manufactured by Bekaert
  • the wires are supplied on spools and have a diameter of 0.18 mm, a strength of 2300 N / mm 2 and an elongation at break of 1.5%.
  • the nonwoven / wire bond is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylate binder, the weight proportion of which in the finished nonwoven is 20%.
  • the binder is cured in a screen drum oven at 210 ° C. This gives a reinforced fleece of 190 g / m 2 basis weight.
  • PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 1 m in width.
  • steel wires material no. 1.4301
  • the wires are supplied on spools and have a diameter of 0.15 mm, a strength of 14 N and an elongation at break of 34%.
  • the nonwoven / wire bond is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylate binder, the weight proportion of which in the finished nonwoven is 20%.
  • the binder is cured in a screen drum oven at 210 ° C.
  • a reinforced fleece of 165 g / m 2 basis weight is obtained in this way.
  • PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 2 m width.
  • wires consisting of an alloy of the CuZn37 type are continuously fed in at a distance of 2 cm (50 wires / m).
  • the wires (manufacturer JG Dahmen) are supplied on spools and have a diameter of 0.25 mm, a strength of 47 N and an elongation at break of 1.4%.
  • the composite fleece / wires is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylic binder, the weight proportion of which in the finished fleece is 20%.
  • the binder is cured in a screen drum oven at 210 ° C.
  • a reinforced fleece of 192 g / m 2 basis weight is obtained in this way.
  • PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 2 m width.
  • wires consisting of an alloy of the CuSn6 type are continuously fed in at a distance of 1.2 cm (83 wires / m).
  • the wires (manufacturer JG Dahmen) are supplied on spools and have a diameter of 0.25 mm, a strength of 21 N and an elongation at break of 54%.
  • the composite fleece / wires is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylic binder, the weight proportion of which in the finished fleece is 20%.
  • the binder is cured in a screen drum oven at 210 ° C.
  • a reinforced fleece of 165 g / m 2 basis weight is obtained in this way.
  • PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 2 m width.
  • wires consisting of a type CUZn37 alloy are continuously fed in at a distance of 2 cm (50 wires / m).
  • the wires (manufacturer JG Dahmen) are supplied on spools and have a diameter of 0.25 mm, a strength of 25 N and an elongation at break of 15%.
  • the composite fleece / wires is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylic binder, the weight proportion of which in the finished fleece is 20%.
  • the binder is cured in a screen drum oven at 210 ° C.
  • a reinforced fleece of 160 g / m 2 basis weight is obtained in this way.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Laminated Bodies (AREA)
  • Artificial Filaments (AREA)
EP97106879A 1996-05-10 1997-04-25 Matériau de garnissage, procédé pour sa fabrication et son utilisation Expired - Lifetime EP0806510B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19620361 1996-05-10
DE19620361A DE19620361C5 (de) 1996-05-10 1996-05-10 Trägereinlage und deren Verwendung

Publications (2)

Publication Number Publication Date
EP0806510A1 true EP0806510A1 (fr) 1997-11-12
EP0806510B1 EP0806510B1 (fr) 2001-12-05

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EP97106879A Expired - Lifetime EP0806510B1 (fr) 1996-05-10 1997-04-25 Matériau de garnissage, procédé pour sa fabrication et son utilisation

Country Status (6)

Country Link
US (2) US6110572A (fr)
EP (1) EP0806510B1 (fr)
JP (1) JPH1053949A (fr)
KR (1) KR970075018A (fr)
CA (1) CA2204968A1 (fr)
DE (2) DE19620361C5 (fr)

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DE102006060241A1 (de) * 2006-12-20 2008-06-26 Johns Manville Europe Gmbh Trägereinlage, Verfahren zu deren Herstellung und deren Verwendung
DE202008010258U1 (de) 2008-07-30 2008-10-30 Johns Manville, Denver Trägereinlage und beschichtete Dachbahnen
DE102009005587A1 (de) 2009-01-21 2010-07-22 Johns Manville Europe Gmbh Verfahren zur Qualitätssicherung von verstärkten flächigen Gebilden
DE102010007939A1 (de) 2010-02-12 2011-08-18 Johns Manville Europe GmbH, 86399 Vorkonfektionierte Trägereinlage und beschichtete Dachbahnen
DE202006021073U1 (de) 2006-12-20 2012-04-30 Johns Manville Europe Gmbh Trägereinlage und deren Verwendung

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DE10052431B4 (de) * 2000-10-23 2004-07-15 Elsayed Elsaftawi Verfahren zur Abdichtung von Natursteinmauerwerksfugen gegen Feuchtigkeit
US7662252B2 (en) 2005-02-04 2010-02-16 Johns Manville Method for producing a reinforced polyester non-woven material
US7786028B2 (en) 2005-04-08 2010-08-31 Johns Manville Nonwoven polymeric fiber mat composites and method
US20080233825A1 (en) * 2007-03-21 2008-09-25 Mohamed Walid Gamaleldin Articles Including High Modulus Fibrous Material
US8906275B2 (en) 2012-05-29 2014-12-09 Nike, Inc. Textured elements incorporating non-woven textile materials and methods for manufacturing the textured elements
US8850719B2 (en) 2009-02-06 2014-10-07 Nike, Inc. Layered thermoplastic non-woven textile elements
US20100199406A1 (en) * 2009-02-06 2010-08-12 Nike, Inc. Thermoplastic Non-Woven Textile Elements
US9682512B2 (en) 2009-02-06 2017-06-20 Nike, Inc. Methods of joining textiles and other elements incorporating a thermoplastic polymer material
US20130255103A1 (en) 2012-04-03 2013-10-03 Nike, Inc. Apparel And Other Products Incorporating A Thermoplastic Polymer Material
EP2679713A1 (fr) * 2012-06-26 2014-01-01 O.R.V. Ovattificio Resinatura Valpadana S.p.a. Support en textile non tissé renforcé avec des fils et procédé de fabrication d'un tel support
ITMI20131114A1 (it) * 2013-07-03 2015-01-04 Politex S A S Di Freudenberg Polit Ex S R L Substrato di supporto per membrana bituminosa e suo procedimento di preparazione.
US11618997B2 (en) 2020-10-30 2023-04-04 Johns Manville Reinforced polymeric nonwoven mat for carpet tiles

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006060241A1 (de) * 2006-12-20 2008-06-26 Johns Manville Europe Gmbh Trägereinlage, Verfahren zu deren Herstellung und deren Verwendung
EP1939342A2 (fr) 2006-12-20 2008-07-02 Johns Manville Europe GmbH Garniture de support, son procédé de fabrication et d'utilisation
EP1939342A3 (fr) * 2006-12-20 2008-09-03 Johns Manville Europe GmbH Garniture de support, son procédé de fabrication et d'utilisation
DE202006021073U1 (de) 2006-12-20 2012-04-30 Johns Manville Europe Gmbh Trägereinlage und deren Verwendung
DE202008010258U1 (de) 2008-07-30 2008-10-30 Johns Manville, Denver Trägereinlage und beschichtete Dachbahnen
EP2154281A2 (fr) 2008-07-30 2010-02-17 Johns Manville Europe GmbH Base interlining and coated roofing membranes
EP2154281A3 (fr) * 2008-07-30 2010-03-17 Johns Manville Europe GmbH Base interlining and coated roofing membranes
DE102009005587A1 (de) 2009-01-21 2010-07-22 Johns Manville Europe Gmbh Verfahren zur Qualitätssicherung von verstärkten flächigen Gebilden
DE102010007939A1 (de) 2010-02-12 2011-08-18 Johns Manville Europe GmbH, 86399 Vorkonfektionierte Trägereinlage und beschichtete Dachbahnen
EP2360304A1 (fr) 2010-02-12 2011-08-24 Johns Manville Europe GmbH Garniture de support préfabriquée et bandes de toit revêtues

Also Published As

Publication number Publication date
JPH1053949A (ja) 1998-02-24
DE19620361C2 (de) 1998-09-10
DE19620361C5 (de) 2004-01-15
CA2204968A1 (fr) 1997-11-10
DE59705614D1 (de) 2002-01-17
US6045645A (en) 2000-04-04
KR970075018A (ko) 1997-12-10
US6110572A (en) 2000-08-29
DE19620361A1 (de) 1997-11-13
EP0806510B1 (fr) 2001-12-05

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