EP0806509B1 - Matériau de garnissage, procédé pour sa fabrication et son utilisation - Google Patents
Matériau de garnissage, procédé pour sa fabrication et son utilisation Download PDFInfo
- Publication number
- EP0806509B1 EP0806509B1 EP97106878A EP97106878A EP0806509B1 EP 0806509 B1 EP0806509 B1 EP 0806509B1 EP 97106878 A EP97106878 A EP 97106878A EP 97106878 A EP97106878 A EP 97106878A EP 0806509 B1 EP0806509 B1 EP 0806509B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reinforcement
- support
- sheet according
- support lining
- lining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000463 material Substances 0.000 title claims description 9
- 230000002787 reinforcement Effects 0.000 claims description 64
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- 239000004753 textile Substances 0.000 claims description 27
- 239000011230 binding agent Substances 0.000 claims description 24
- 229920000728 polyester Polymers 0.000 claims description 22
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 22
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 22
- 230000003014 reinforcing effect Effects 0.000 claims description 22
- -1 polyethylene terephthalate Polymers 0.000 claims description 21
- 239000011521 glass Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 229920003235 aromatic polyamide Polymers 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 238000009987 spinning Methods 0.000 claims description 7
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- 238000007789 sealing Methods 0.000 claims description 5
- 238000007669 thermal treatment Methods 0.000 claims description 5
- 238000010586 diagram Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000011888 foil Substances 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
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- 238000005728 strengthening Methods 0.000 claims 2
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- 239000000835 fiber Substances 0.000 description 36
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 8
- 239000012528 membrane Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- 239000012783 reinforcing fiber Substances 0.000 description 7
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 5
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- 239000012209 synthetic fiber Substances 0.000 description 5
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- 239000010426 asphalt Substances 0.000 description 4
- 238000004049 embossing Methods 0.000 description 4
- 229920001643 poly(ether ketone) Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000009958 sewing Methods 0.000 description 3
- 239000004953 Aliphatic polyamide Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
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- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920003231 aliphatic polyamide Polymers 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
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- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 1
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
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- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- D04H13/00—Other non-woven fabrics
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- Y10S428/902—High modulus filament or fiber
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/643—Including parallel strand or fiber material within the nonwoven fabric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/643—Including parallel strand or fiber material within the nonwoven fabric
- Y10T442/644—Parallel strand or fiber material is glass
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/643—Including parallel strand or fiber material within the nonwoven fabric
- Y10T442/645—Parallel strand or fiber material is inorganic [e.g., rock wool, mineral wool, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/654—Including a free metal or alloy constituent
- Y10T442/655—Metal or metal-coated strand or fiber material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/681—Spun-bonded nonwoven fabric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/682—Needled nonwoven fabric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
Definitions
- the invention relates to a carrier insert, which is particularly a carrier insert suitable for the production of roofing membranes or as a tarp or surface.
- Carrier inserts for the production of roofing membranes must be diverse Requirements met. So on the one hand there is sufficient mechanical Stability required, such as good perforation strength and good tensile strength for example the mechanical loads during further processing, such as Bituminizing or laying to withstand. It will also be high Resistance to thermal stress, for example when bituminizing or against radiant heat, and resistance to flight fire required. There has therefore been no shortage of attempts at existing carrier inserts to improve.
- nonwovens based on synthetic fiber nonwovens Reinforcing fibers for example to combine with glass fibers.
- sealing sheets can be found in GB-A-1,517,595, DE-Gbm-77-39,489, EP-A-160,609, EP-A-176-847, EP-A-403,403 and EP-A-530.769.
- the connection between nonwoven and reinforcing fibers takes place according to this prior art either by gluing using a Binder or by needling the layers of different material.
- the Interlining consists of a substrate that melts below 150 ° C Has surface, and associated melting over 180 ° C. Reinforcement filaments that are fixed on this surface parallel to each other are.
- the substrate can be a Trade non-woven fabric, on one surface of which there are hot melt adhesive fibers or threads are used to produce a bond of the parallel arranged Reinforcing fibers are provided with the nonwoven.
- a filter material made of inorganic non-woven material and metal wires known for cleaning exhaust air at high temperatures (higher than 300 ° C) is used.
- DE-Gbm-295 00 830 describes the reinforcement of a glass fleece synthetic monofilaments. These reinforcing monofilaments carry in the Sealing membrane does not contribute significantly to the reference force at low strains. However, they have a significantly higher maximum tensile force extension than that Glass mat; thus the areal connection of the geomembrane also becomes guaranteed in the event of deformations that can lead to breakage of the glass fleece.
- the shrinkage of synthetic monofilaments is higher than the shrinkage of Glass fleece and can lead to waviness in the sealing membrane.
- DE-A-3,941,189 also discloses a combination of reinforcing fibers in Form of a thread chain with nonwovens based on synthetic fibers known that can be connected to each other in various ways. In this application it is emphasized that the Young module of the reinforced The carrier insert does not change compared to an unreinforced base fleece.
- the Reference force of the reinforced carrier insert at low stretches in different proportions on the textile fabric or on the Reinforcements can be distributed.
- the quotient is a suitable measure for the distribution of the reference forces of these reference forces at a measuring temperature of 20 ° C divided by the Reference force at 180 ° C.
- Carrier deposits with a quotient of 3.3 as defined in DE-A-3,941,189 show no detectable improvement in the Reference force at room temperature.
- German utility model 92 07 367 describes only a laminate that consists of at least two layers of spunbonded nonwovens and at least one layer of scrim Reinforcement yarns is built. Indications that the carrier insert is a Should have an expansion reserve of less than 1% or to a corresponding one Manufacturing processes as taught in the application are these Not to be cited. This is also resolved by the applicant Problem not mentioned in this document either.
- the object of the invention is to provide a carrier insert in which the Reinforcements already in the initial area of elongation, i.e. between 0 and 1%, take effect and ensure that the carrier insert with loads in these lower areas already maintain their excellent properties and not too Damage that occurs both inside and outside the Carrier insert can make noticeable.
- the object of the invention is also to provide a carrier insert available in a significantly improved reference force with low elongation throughout the temperature range having.
- the invention further relates to a method according to claim 19.
- Advantageous Embodiments are described in claims 20 to 23.
- the invention further relates to the use of the carrier insert according to claim 24 or 25.
- the carrier insert thus contains a textile fabric and a reinforcement absorbs a force so that in the force-elongation diagram (at 20 ° C) the reference force of the carrier insert with reinforcement compared to the carrier insert without reinforcement in the range between 0 and 1% elongation at least at one point by at least 10%, preferably around differs at least 20%, particularly preferably by at least 30%.
- the reinforcement is such that the reference force of the carrier insert at room temperature (20 ° C) divided by the reference force of the carrier insert at 180 °, measured at at least one point in the range between 0 and 1% elongation, a quotient of at most 3 (three), preferably at most 2.5, particularly preferably less than 2, results.
- textile fabric is used in the context of this description to understand the broadest meaning. It can be made up of all structures Fibers made from synthesized polymers act on a surface-forming Technology have been produced.
- notch depth and notch protrusion are in a brochure with the Description "felting and structuring needles” from Groz-Beckert from the Year 1994 defined.
- the reference force is measured according to EN 29073, part 3, on 5 cm wide Samples at 100 mm measuring length.
- the numerical value of the preload, specified in Centinewton corresponds to the numerical value of the mass per unit area of the sample, stated in grams per square meter.
- textile fabrics are woven, laid, knitted and Knitted fabrics, and preferably nonwovens.
- spunbonds which are created by a tangle of freshly melt-spun Filaments are generated, preferred. They consist of endless synthetic fibers made of melt-spinnable polymer materials.
- Suitable polymer materials are for example polyamides, e.g. Polyhexamethylene diadipamide, Polycaprolactam, aromatic or partially aromatic polyamides ("aramids"), aliphatic polyamides, e.g. Nylon, partially aromatic or fully aromatic Polyester, polyphenylene sulfide (PPS), polymers with ether and keto groups, such as e.g. Polyether ketones (PEK) and poly ether ketones (PEEK), or Polybenzimidazoles.
- PEK Polyether ketones
- PEEK poly ether ketones
- the spunbonded fabrics preferably consist of melt-spinnable polyesters.
- polyester materials are all suitable for fiber production known types into consideration.
- Such polyesters mainly consist of Building blocks that differ from aromatic dicarboxylic acids and from aliphatic Derive diols.
- Common aromatic dicarboxylic acid building blocks are divalent residues of benzenedicarboxylic acids, especially the Terephthalic acid and isophthalic acid; common diols have 2 to 4 carbon atoms, the ethylene glycol being particularly suitable.
- Spunbonded fabrics which consist of at least 85 mol% of polyethylene terephthalate.
- dicarboxylic acid units and Glycol units which act as so-called modifiers and which allow the person skilled in the art to control the physical and chemical properties of the to influence the filaments produced.
- Dicarboxylic acid units are residues of isophthalic acid or aliphatic Dicarboxylic acid such as e.g. Glutaric acid, adipic acid, sebacic acid;
- examples for modifying diol residues are those of longer-chain diols, e.g. B. of propanediol or butanediol, of di- or triethylene glycol or, if in small amount available, of polyglycol with a molecular weight of approx. 500 until 2000.
- Polyesters which contain at least 95 mol% are particularly preferred. Contain polyethylene terephthalate (PET), especially those made of unmodified PET.
- PET polyethylene terephthalate
- flame retardant modified polyesters are known. They contain additions from Halogen compounds, especially bromine compounds, or what particularly is advantageous, they contain phosphorus compounds that are in the polyester chain are condensed.
- the spunbonded fabrics particularly preferably contain flame-retardant modified polyesters which in the chain contain assemblies of the formula (I) wherein R is alkylene or polymethylene with 2 to 6 C atoms or phenyl and R 1 is alkyl with 1 to 6 C atoms, aryl or aralkyl, contained in condensed form.
- R is preferably ethylene and R 1 is methyl, ethyl, phenyl, or o-, m- or p-methylphenyl, in particular methyl.
- Such spunbonded fabrics are described, for example, in DE-A-39 40 713.
- the polyesters contained in the spunbonded fabrics preferably have a Molecular weight corresponding to an intrinsic viscosity (IV), measured in a solution of 1 g polymer in 100 ml dichloroacetic acid at 25 ° C, of 0.6 to 1.4.
- IV intrinsic viscosity
- the individual titer of the polyester filaments in the spunbonded fabric is between 1 and 16 dtex, preferably 2 to 8 dtex.
- the spunbond can also be a be melt-bond-bonded nonwoven, which carrier and Contains hot melt adhesive fibers.
- the carrier and hot melt adhesive fibers can be derived from any thermoplastic thread-forming polymer.
- Carrier fibers can also differ from non-melting ones derive thread-forming polymers.
- Such solidified melt binders Spunbonded fabrics are described, for example, in EP-A-0,446,822 and EP-A-0,590,629 described.
- polymers from which the carrier fibers can be derived are Polyacrylonitrile, polyolefins such as polyethylene, essentially aliphatic Polyamides, such as nylon 6.6, essentially aromatic polyamides (aramids), such as poly (p-phenylene terephthalamide) or copolymers containing a portion on aromatic m-diamine units to improve solubility or poly (m-phenylene isophthalamide), essentially aromatic polyesters, such as poly (phydroxybenzoate) or preferably essentially aliphatic polyesters such as Polyethylene terephthalate.
- polyolefins such as polyethylene
- essentially aliphatic Polyamides such as nylon 6.6
- aromatic polyamides such as poly (p-phenylene terephthalamide) or copolymers containing a portion on aromatic m-diamine units to improve solubility
- poly (m-phenylene isophthalamide) essentially aromatic polyesters, such as poly (phydroxybenzoate) or preferably essentially
- the proportion of the two types of fibers to one another can be chosen within wide limits be, taking care that the proportion of hot melt adhesive fibers so is chosen high that the nonwoven fabric by gluing the carrier fibers with the hot melt adhesive fibers are sufficient for the desired application Maintains firmness.
- the proportion of that comes from the hot melt adhesive fiber Hot melt adhesive in the nonwoven fabric is usually less than 50% by weight, based on the weight of the nonwoven.
- Modified polyesters come with a hot melt adhesive compared to the nonwoven raw material by 10 to 50 ° C, preferably 30 to 50 ° C lowered melting point into consideration.
- Hot melt adhesives are polypropylene, polybutylene terephthalate or through Condensing longer-chain diols and / or isophthalic acid or aliphatic dicarboxylic acids modified polyethylene terephthalate.
- the hot melt adhesives are preferably introduced into the nonwovens in fiber form.
- Carrier and hot-melt adhesive fibers from one polymer class are preferred built up. This means that all fibers used are made from one Substance class should be selected so that after using the fleece can be easily recycled.
- the carrier fibers for example made of polyester
- the hot melt adhesive fibers are also made of polyester or from a mixture of polyesters, e.g. B. as bicomponent fiber with PET in Core and a lower melting polyethylene terephthalate copolymer selected as a sheath:
- bicomponent fibers are also included possible, which are made up of different polymers. Examples of this are bicomponent fibers made of polyester and polyamide (core / shell).
- the single fiber titers of the carrier and hot melt adhesive fibers can be within further limits can be chosen. Examples of common titer ranges are 1 to 16 dtex, preferably 2 to 6 dtex.
- the carrier inserts according to the invention with flame retardant Properties additionally bound they preferably contain flame retardant hot melt adhesive.
- the filaments or staple fibers that make up the nonwovens can be one have practically round cross-section or have other shapes, such as dumbbell, kidney-shaped, triangular, tri or multilobal cross-sections. It hollow fibers can also be used. Furthermore, the hot melt adhesive fiber can also be used in Use the form of bicomponent or multicomponent fibers.
- the fibers forming the textile fabric can be made using conventional additives be modified, for example by antistatic agents such as carbon black.
- the surface area of the spunbonded fabric is between 20 and 500 g / m 2 , preferably 40 and 250 g / m 2 .
- the above properties are, for example, by threads and / or Obtain yarns whose Young's modulus is at least 5 Gpa, preferably at least 10 Gpa, particularly preferably at least 20 Gpa.
- the above reinforcing threads mentioned have a diameter between 0.1 and 1 mm, preferably 0.1 and 0.5 mm, in particular 0.1 and 0.3 mm and have an elongation at break of 0.5 to 100%, preferably 1 to 60%.
- the carrier inserts according to the invention have a Expansion reserve of less than 1%.
- the stretch reserve is the stretch that is applied to the carrier insert acts before the force acting on the reinforcing threads is dissipated, i.e. an expansion reserve of 0% would mean that on the carrier insert tensile forces acting on the reinforcement threads are immediately derived would. This means that the forces acting on the spunbonded fabric are not the first bring about an alignment or orientation of the reinforcing threads rather be derived directly on the reinforcing threads, so that a Damage to the textile fabric can be avoided. this shows especially in a steep increase in the force to be applied small strains (force-strain diagram at room temperature).
- Suitable reinforcing threads are, for example, high tenacity Monofilaments made of polyester or wires made of metal or metallic Alloys with an elongation at break of at least 10%.
- Multifilaments and / or are preferred as reinforcing threads Monofilaments based on aramids, preferably so-called high-modulus aramids, Carbon, glass, high tenacity polyester monofilaments, as well So - called hybrid multifilament yarns (yarns containing reinforcing fibers and deep melting binding fibers) or wires (monofilaments) made of metals or metallic alloys used.
- preferred reinforcements consist of glass multifilaments in the form of parallel thread sheets or scrims. Most of time there is only a reinforcement in the longitudinal direction of the nonwovens by parallel running thread groups.
- the reinforcing threads can be used as such or in the form of a textile Fabric, for example as a fabric, scrim, knitted fabric, knitted fabric or as Fleece can be used.
- Reinforcements with one another are preferred reinforcement yarns running in parallel, i.e. warp thread sheets, as well as scrims or tissue.
- the thread density can be in depending on the desired property profile wide limits fluctuate.
- the thread density is preferably between 20 and 200 threads per meter.
- the thread density becomes perpendicular to Thread running direction measured.
- the reinforcing threads are preferred fed during spunbond formation and thus into the spunbond embedded.
- the spunbonded nonwovens are usually subjected to chemical or thermal and / or mechanical consolidation in a known manner.
- the spunbonded fabrics are preferably mechanically consolidated by needling.
- the spunbonded fabric which advantageously already contains the reinforcing threads, is usually needled with a needle density of 20 to 100 stitches / cm 2 .
- the needling is advantageously carried out by needles whose notch protrusion, preferably the sum of notch protrusion and notch depth, is smaller than the diameter of the reinforcing threads. As a result, the reinforcing threads are not damaged.
- the spunbonded webs, which already contain reinforcing threads are then subjected to further consolidation steps, for example a thermal treatment.
- the spunbonded nonwovens which can be bonded together, are next to Carrier fibers also contain binding fibers, in a manner known per se with a Calendered or thermally solidified in an oven. If the spunbonded fabrics do not contain any materials capable of thermal bonding Binding fibers, so these spunbonded with a chemical binder impregnated. Acrylic binders are particularly suitable for this.
- the Binder content is advantageously up to 30 wt .-%, preferably 2 to 25% by weight.
- Hard binders allow high ones Processing speeds with impregnation, in particular Bituminization, while a soft binder particularly high values of Tear and nail tear resistance results.
- flame-retardant modified can also Binder can be used.
- the carrier web according to the invention has an embossed pattern of statistically distributed or repeat-arranged, small-area embossments, preferably a canvas embossing, in which the pressing surface, that is to say the totality of all thin, compacted areas of the spunbonded nonwoven, is 30 to 60%, preferably 40 to 45 makes up% of its total area, and the thickness of the compacted areas of the nonwoven is at least 20%, preferably 25 to 50%, of the thickness of the non-compacted areas of the nonwoven.
- this embossing pattern can advantageously be applied during the calendering process.
- the embossing pattern can also be embossed using a calender.
- This embossing pattern which is applied to both surfaces of the spunbonded fabric, but preferably only to one surface of the spunbonded fabric as it passes through the spunbonded fabric, has a large number of small embossments which have a size of 0.2 to 40 mm 2 , preferably 0 , 2 to 10 mm 2 , and are separated from one another by interposed, approximately the same size, non-embossed surface elements of the fleece.
- the area of the compacted areas of the nonwoven and the non-compacted areas of the nonwoven can be determined, for example, by means of microscopic cross-sectional images.
- the carrier inlays according to the invention can be combined with other textiles Fabrics are combined so that their properties are variable.
- Composites of this type, which contain the carrier insert according to the invention, are also the subject of the invention.
- the reinforcement can be applied before, during and / or after formation the textile surface.
- the process is characterized by the addition of the reinforcement and each thermal treatment in the manufacturing process of the carrier insert under tension, especially under longitudinal tension.
- a thermal treatment under Tension is present when the position of the reinforcement in the carrier insert a thermal step remains unchanged; in particular is the preservation the longitudinal threads of interest by applying a longitudinal tension.
- the education of the textile fabric can on a taut reinforcement or the reinforcement can take place during the area formation process, e.g. B. in the manufacture of fleece, or it can be a textile fabric be completed and by subsequent assembly with a Reinforcement.
- the combination of the textile fabric with the reinforcement can take place by measures known per se, for example by needling or gluing including hot melt gluing.
- the Advantages of the process are particularly evident in the production of needled carrier inserts.
- the formation of a fabric as described in a) can be carried out by Spunbond formation takes place by means of spinning apparatus known per se.
- the molten polymer is replaced by several in a row switched rows of spinnerets or groups of spinneret rows cleverly. If a spunbond bond strengthened by melt binder is to be produced, then is alternately loaded with polymers that the carrier fiber and Form hot melt adhesive fibers.
- the spun polymer streams are in stretched in a known manner, and z. B. using a rotating Baffle plate in scattered texture deposited on a conveyor belt.
- Carrier inserts with other components to multilayer Composites can be combined.
- other components are Glass fleeces, thermoplastic or metallic foils, insulation materials, etc.
- the carrier inserts according to the invention can be used to produce Use bituminized roofing and waterproofing membranes.
- This is also a Subject of the present invention.
- the carrier material in itself treated in a known manner with bitumen and then optionally with a granular material, such as sand, sprinkled. That way roofing and waterproofing membranes are characterized by good Processability.
- the bituminized sheets contain at least one in a bitumen matrix embedded - described above - carrier web, wherein the weight fraction of the bitumen in the basis weight of the bituminized roofing membrane preferably 40 to 90% by weight and that of the spunbond nonwoven 10 to 60 % By weight.
- These railways can also be a so-called Act roofing membrane.
- bitumen instead of bitumen, another material, e.g. Polyethylene or Polyvinyl chloride for coating the carrier insert according to the invention be used.
- PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 2 m width.
- steel wires are continuously fed at a distance of 2 cm (50 wires / m) in the longitudinal direction.
- the wires manufactured by Bekaert
- the wires are supplied on spools and have a diameter of 0.18 mm, a strength of 2300 N / mm 2 and an elongation at break of 1.5%.
- the nonwoven / wire bond is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylate binder, the weight proportion of which in the finished nonwoven is 20%.
- the binder is cured in a sieve drum oven at 210 ° C. This gives a reinforced fleece of 190 g / m 2 basis weight.
- PET threads with a filament titer of 4 dtex manufactured and deposited to a tangled fleece of 1 m width.
- steel wires are continuously in the longitudinal direction (Material no. 1.4301) at a distance of 6.7 mm (150 wires / m).
- the Wires manufactured on spools and have one Diameter of 0.15 mm, a strength of 14 N and an elongation at break of 34%.
- the bonded fleece / wire is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylate binder, the weight percentage of which in the finished fleece is 20%.
- the binder is cured in a sieve drum oven at 210 ° C.
- a reinforced fleece of 165 g / m 2 basis weight is obtained in this way.
- PET threads with a filament titer of 4 dtex manufactured and filed to a tangled fleece of 2 m width.
- the wires are delivered on spools and have a diameter of 0.25 mm, a strength of 47 N and a Elongation at break of 1.4%.
- the nonwoven / wire bond is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylic binder, the weight proportion of which in the finished nonwoven is 20%.
- the binder is cured in a sieve drum oven at 210 ° C.
- a reinforced fleece of 192 g / m 2 basis weight is obtained in this way.
- PET threads with a filament titer of 4 dtex manufactured and filed to a tangled fleece of 2 m width.
- the wires are delivered on spools and have a diameter of 0.25 mm, a strength of 21 N and a Elongation at break of 54%.
- the nonwoven / wire bond is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylic binder, the weight proportion of which in the finished nonwoven is 20%.
- the binder is cured in a sieve drum oven at 210 ° C. A reinforced fleece of 165 g / m 2 basis weight is obtained in this way.
- PET threads with a filament titer of 4 dtex manufactured and filed to a tangled fleece of 2 m width.
- wires are continuously consisting of an alloy of the type CUZn37, at a distance of 2 cm (50 Wires / m) supplied.
- the wires (manufactured by J.G. Dahmen) are opened Coils supplied and have a diameter of 0.25 mm, a strength of 25 N and an elongation at break of 15%.
- the nonwoven / wire bond is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylic binder, the weight proportion of which in the finished nonwoven is 20%.
- the binder is cured in a sieve drum oven at 210 ° C. A reinforced fleece of 160 g / m 2 basis weight is obtained in this way.
- PET threads with a filament titer of 4 dtex are produced and laid down to a tangled fleece of 1 m in width.
- glass multifilaments of the type EC 934T6Z28 from Vetrotex are fed in at a distance of 6.25 mm (160 threads per meter).
- the glass threads are supplied on spools and have a strength of 20 N and an elongation at break of 2.5%.
- the composite of fleece and threads is needled with 40 stitches / cm 2 at a penetration depth of 12.5 mm (needle type from Foster, 15x18x38x3 CB) and then impregnated with an acrylate binder, the weight proportion of which in the finished fleece is 20%.
- the binder is cured in a sieve drum oven at 210 ° C.
- a reinforced fleece of 110 g / m 2 basis weight is obtained in this way.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Nonwoven Fabrics (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Claims (25)
- Pièce rapportée de support contenant un produit plat textile et un renforcement, caractérisée en ce que la pièce rapportée de support présente une réserve d'allongement inférieure à 1 % et la force de référence de la pièce rapportée de support avec renforcement comparée à celle de la pièce rapportée de support sans renforcement, dans le diagramme de forces-allongement (à 20 °C), dans la plage d'un allongement entre 0 et 1 %, se distingue d'une valeur de référence d'au moins 10 %, le renforcement de la pièce rapportée de support ayant été amené sous tension et chaque traitement thermique, lors de la fabrication de la pièce rapportée de support, ayant été réalisé sous tension.
- Pièce rapportée de support selon la revendication 1, caractérisée en ce que le renforcement de la pièce rapportée de support a été amené sous tension longitudinale.
- Pièce rapportée de support selon la revendication 2, caractérisée en ce que la force de référence de la pièce rapportée de support avec renforcement comparée à celle de la pièce rapportée de support sans renforcement, dans le diagramme de forces-allongement (à 20 °C), dans la plage d'un allongement entre 0 et 1 %, se distingue, à au moins un endroit, d'au moins 30 %.
- Pièce rapportée de support selon la revendication 3, caractérisée en ce que la force de référence de la pièce rapportée de support à la température ambiante (20 °C) divisée par la force de référence de la pièce rapportée de support à 180 °C, mesurée à au moins un endroit dans la plage d'un allongement entre 0 et 1 %, présente un quotient maximal égal à 3.
- Bande de support selon revendication 1 ou 4, caractérisée en ce que le produit plat textile est un non-tissé, de préférence en polyester.
- Bande de support selon la revendication 5, caractérisée en ce que le non-tissé a été renforcé par voie mécanique, par voie thermique et/ou par voie chimique.
- Bande de support selon la revendication 6, caractérisée en ce que le renforcement est présent sous la forme de fils de renforcement et le non-tissé a été renforcé par voie mécanique par aiguilletage, dans laquelle, de préférence, la résistance des entailles, respectivement la somme de la résistance des entailles et de la profondeur des entailles des aiguilles est inférieure au diamètre des fils de renforcement.
- Bande de support selon la revendication 5, caractérisée en ce que le polyester est constitué de polyéthylène téréphtalate jusqu'à concurrence d'au moins 85 moles %.
- Bande de support selon la revendication 6, caractérisée en ce que le non-tissé est un non-tissé renforcé avec un liant fusible.
- Bande de support selon la revendication 6, caractérisée en ce que le non-tissé a été renforcé avec un liant chimique.
- Bande de support selon la revendication 1 ou 4, caractérisée en ce que le poids surfacique du produit plat textile se situe entre 20 et 500 g/m2.
- Bande de support selon la revendication 1 ou 4, caractérisée en ce que le renforcement est présent sous la forme de fils de renforcement dont le diamètre s'élève de 0,1 à 1 mm et dont le module de Young s'élève à au moins 5 GPa.
- Bande de support selon la revendication 12, caractérisée en ce que les fils de renforcement possèdent un diamètre s'élevant de 0,1 à 5 mm.
- Bande de support selon la revendication 12, caractérisée en ce que les fils de renforcement présentent un allongement de rupture de 0,5 à 100 %.
- Bande de support selon la revendication 1 ou 4, caractérisée en ce que le renforcement est présent sous la forme de fils de renforcement constitués par des monofilaments ou par des multifilaments.
- Bande de support selon la revendication 15, caractérisée en ce que les fils de renforcement sont constitués d'aramide, de carbone, de verre, par des monofilaments en polyester très résistants, par des multifilaments hybrides, par des métaux ou encore par des alliages métalliques.
- Bande de support selon la revendication 1 ou 4, caractérisée en ce que le renforcement est présent sous la forme d'un tissu, d'un tissu non tissé, d'un produit tricoté, d'un tissu à mailles, d'une feuille ou d'un non-tissé.
- Bande de support selon la revendication 5, caractérisée en ce que le non-tissé en polyester présente un dessin gaufré.
- Procédé pour la fabrication d'une pièce rapportée de support telle que définie à la revendication 1, comprenant les mesures connues en soi :a) formation d'un produit plat textile,b) amenée du renforcement,c) le cas échéant amenée d'un produit plat textile supplémentaire de telle sorte que le renforcement est entouré de produits plats textiles à la manière d'un sandwich,d) renforcement de la pièce rapportée de support obtenue conformément à la mesure c),e) le cas échéant imprégnation de la pièce rapportée renforcée, avec un liant, etf) le cas échéant renforcement du produit intermédiaire obtenu conformément à d) via une température et/ou une pression élevées, la succession des étapes a) et b) pouvant également être inversée, caractérisé en ce que l'amenée du renforcement et chaque traitement thermique, dans le procédé de fabrication de la pièce rapportée de support, ont lieu sous tension, de préférence sous tension longitudinale.
- Procédé selon la revendication 19, caractérisé en ce que la formation du produit pas textile a lieu sur un renforcement amené sous tension.
- Procédé selon la revendication 19, caractérisée en ce que l'amenée du renforcement a lieu au cours du processus de formation du produit plat textile.
- Procédé selon la revendication 19, caractérisé en ce qu'on assemble au moins un produit plat textile prêt à l'emploi et au moins un renforcement et en ce qu'on les relie par aiguilletage et/ou par collage.
- Procédé selon la revendication 19, caractérisé en ce que le renforcement, conformément à la mesure d), a lieu par aiguilletage, de préférence, la résistance des entailles, respectivement la somme de la résistance des entailles et de la profondeur des entailles des aiguilles est inférieure au diamètre des fils de renforcement, ou par collage.
- Utilisation de la pièce rapportée de support définie à la revendication 1 pour la fabrication de matières composites, en particulier de bandes de couvertures et d'étanchéisation.
- Utilisation de la pièce rapportée de support définie à la revendication 1 pour la fabrication de bandes de couvertures et d'étanchéisation bitumées.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19618775 | 1996-05-10 | ||
| DE19618775A DE19618775A1 (de) | 1996-05-10 | 1996-05-10 | Trägereinlage, Verfahren zu deren Herstellung und deren Verwendung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0806509A1 EP0806509A1 (fr) | 1997-11-12 |
| EP0806509B1 true EP0806509B1 (fr) | 2003-07-02 |
| EP0806509B2 EP0806509B2 (fr) | 2011-08-31 |
Family
ID=7793897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP97106878A Expired - Lifetime EP0806509B2 (fr) | 1996-05-10 | 1997-04-25 | Matériau de garnissage, procédé pour sa fabrication et son utilisation |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6114262A (fr) |
| EP (1) | EP0806509B2 (fr) |
| JP (1) | JPH10131019A (fr) |
| KR (1) | KR100490187B1 (fr) |
| CN (1) | CN1122736C (fr) |
| CA (1) | CA2204967C (fr) |
| DE (2) | DE19618775A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2679713A1 (fr) | 2012-06-26 | 2014-01-01 | O.R.V. Ovattificio Resinatura Valpadana S.p.a. | Support en textile non tissé renforcé avec des fils et procédé de fabrication d'un tel support |
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| US6489805B1 (en) * | 1998-12-09 | 2002-12-03 | Cypress Semiconductor Corp. | Circuits, architectures, and methods for generating a periodic signal in a memory |
| DE19935408B4 (de) * | 1999-07-30 | 2004-04-22 | Johns Manville International, Inc., Denver | Mehrlagenschichtstoff |
| US7351673B1 (en) | 1999-07-30 | 2008-04-01 | Johns Manville | Laminates including two or more layers of organic synthetic filament non-wovens and glass fiber webs and scrims |
| DE19950057B4 (de) * | 1999-10-16 | 2005-10-13 | Johns Manville International, Inc., Denver | Zwei- oder Mehrlagenschichtstoffe aus Polyesterfilamentvliesen und Glasfasergeweben oder -gelegen |
| FR2804677B1 (fr) * | 2000-02-09 | 2002-08-30 | Vetrotex France Sa | Voile de verre et son utilisation pour des revetements d'etancheite |
| US7125601B1 (en) | 2000-10-18 | 2006-10-24 | 3M Innovative Properties Company | Integrated granule product |
| US6796115B1 (en) * | 2001-12-19 | 2004-09-28 | Gilbert Patrick | Needle punched yarns |
| US7166671B2 (en) | 2002-12-10 | 2007-01-23 | Cellresin Technologies, Llc | Grafted cyclodextrin |
| US8129450B2 (en) * | 2002-12-10 | 2012-03-06 | Cellresin Technologies, Llc | Articles having a polymer grafted cyclodextrin |
| EP1447213A1 (fr) * | 2003-02-11 | 2004-08-18 | Saint-Gobain Vetrotex France S.A. | Structure comprenant un voile de fibres de verre obtenu par voie sèche et un voile de fibres organiques |
| AU2005304879B2 (en) | 2004-11-05 | 2010-02-04 | Donaldson Company, Inc. | Filter medium and structure |
| US8057567B2 (en) | 2004-11-05 | 2011-11-15 | Donaldson Company, Inc. | Filter medium and breather filter structure |
| US12172111B2 (en) | 2004-11-05 | 2024-12-24 | Donaldson Company, Inc. | Filter medium and breather filter structure |
| CN101151084B (zh) | 2005-02-04 | 2013-02-13 | 唐纳森公司 | 气溶胶分离器 |
| EP1858618B1 (fr) | 2005-02-22 | 2009-09-16 | Donaldson Company, Inc. | Separateur d aerosol |
| US7325262B2 (en) * | 2005-03-02 | 2008-02-05 | Standard Textile Co., Inc. | Bedding hem with associated interlining |
| DE202006021073U1 (de) | 2006-12-20 | 2012-04-30 | Johns Manville Europe Gmbh | Trägereinlage und deren Verwendung |
| DE102006060241A1 (de) | 2006-12-20 | 2008-06-26 | Johns Manville Europe Gmbh | Trägereinlage, Verfahren zu deren Herstellung und deren Verwendung |
| US20080233825A1 (en) * | 2007-03-21 | 2008-09-25 | Mohamed Walid Gamaleldin | Articles Including High Modulus Fibrous Material |
| US10260197B2 (en) | 2007-12-14 | 2019-04-16 | Johns Manville | Base interlining, methods for their manufacture and application thereof |
| DE102007060494A1 (de) | 2007-12-14 | 2009-06-18 | Johns Manville Europe Gmbh | Trägereinlage, Verfahren zu deren Herstellung und deren Verwendung |
| DE202008010258U1 (de) * | 2008-07-30 | 2008-10-30 | Johns Manville, Denver | Trägereinlage und beschichtete Dachbahnen |
| DE102009005587A1 (de) | 2009-01-21 | 2010-07-22 | Johns Manville Europe Gmbh | Verfahren zur Qualitätssicherung von verstärkten flächigen Gebilden |
| US20100212272A1 (en) * | 2009-02-24 | 2010-08-26 | Hollingsworth & Vose Company | Filter media suitable for ashrae applications |
| DE102010007939A1 (de) | 2010-02-12 | 2011-08-18 | Johns Manville Europe GmbH, 86399 | Vorkonfektionierte Trägereinlage und beschichtete Dachbahnen |
| IT1402753B1 (it) | 2010-11-15 | 2013-09-18 | Politex S A S Di Freudenberg Politex S R L | Supporto tessile rinforzato con filamenti longitudinali di fibre cellulosiche, particolarmente per membrane bituminose. |
| IT1402882B1 (it) | 2010-11-22 | 2013-09-27 | Politex S A S Di Freudenberg Politex S R L | Supporto tessile consolidato per via chimica e termica, particolarmente per membrane bituminose. |
| US8651286B2 (en) * | 2010-12-15 | 2014-02-18 | Johns Manville | Spunbond polyester mat with binder comprising salt of inorganic acid |
| DE102012025023A1 (de) * | 2012-12-20 | 2014-06-26 | Johns Manville Europe Gmbh | Filtermedium |
| ITMI20131114A1 (it) | 2013-07-03 | 2015-01-04 | Politex S A S Di Freudenberg Polit Ex S R L | Substrato di supporto per membrana bituminosa e suo procedimento di preparazione. |
| GB2524063B (en) | 2014-03-13 | 2020-07-01 | Advanced Risc Mach Ltd | Data processing apparatus for executing an access instruction for N threads |
| TWI663311B (zh) | 2014-04-29 | 2019-06-21 | Low & Bonar B. V. | 乙烯地板覆蓋物用之載體材料及包含其之複合材料產品 |
| CN105972813A (zh) * | 2016-05-15 | 2016-09-28 | 夏维月 | 电热锅炉 |
| US11618997B2 (en) | 2020-10-30 | 2023-04-04 | Johns Manville | Reinforced polymeric nonwoven mat for carpet tiles |
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| GB1517595A (en) * | 1977-03-31 | 1978-07-12 | Bp Aquaseal Ltd | Bituminous material |
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| DE3435643A1 (de) * | 1984-09-28 | 1986-04-10 | Hoechst Ag, 6230 Frankfurt | Schichtstoff |
| EP0222610A3 (fr) * | 1985-11-13 | 1988-11-30 | Teijin Limited | Feuille laminée pour voiles et son procédé de fabrication |
| FI89189C (fi) * | 1986-02-22 | 1994-07-12 | Hoechst Ag | Laminat foer anvaendning som stoedskikt foer taeck och isoleringsmaterial foer tak |
| EP0281643B1 (fr) * | 1987-03-09 | 1991-11-27 | Chisso Corporation | Etoffe non tissée renforcée |
| FR2628448B1 (fr) * | 1988-03-14 | 1990-11-16 | Chomarat & Cie | Armature textile utilisable pour la realisation de complexes stratifies et complexes stratifies en forme comportant une telle armature |
| DE3831271A1 (de) * | 1988-09-14 | 1990-03-15 | Hoechst Ag | Traegerbahn fuer dachunterspannbahnen |
| FR2640288B1 (fr) † | 1988-12-13 | 1993-06-18 | Rhone Poulenc Fibres | Support a base de nappe non tissee en textile chimique et son procede de fabrication |
| FR2646442B1 (fr) * | 1989-04-28 | 1993-04-02 | Chomarat & Cie | Armature textile utilisable pour la realisation de materiaux composites et articles en forme comportant une telle armature |
| FR2648482B1 (fr) * | 1989-06-16 | 1992-05-15 | Chomarat & Cie | Complexes textiles multicouches a base de nappes fibreuses ayant des caracteristiques differentes et procede pour leur obtention |
| DE4008043A1 (de) * | 1990-03-14 | 1991-09-19 | Hoechst Ag | Traegerbahn fuer dachunterspannbahnen |
| WO1992005949A1 (fr) * | 1990-10-03 | 1992-04-16 | Milliken Research Corporation | Composite fibreux rigide |
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| DE9207367U1 (de) * | 1992-05-30 | 1992-09-10 | Johns Manville International, Inc., Denver, Col. | Schichtstoff aus Vlies und Gelege |
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| KR100295418B1 (ko) * | 1996-07-11 | 2001-10-24 | 김기진 | 유리섬유 파사를 이용한 보강섬유 제조방법 및 구성 |
-
1996
- 1996-05-10 DE DE19618775A patent/DE19618775A1/de not_active Withdrawn
-
1997
- 1997-04-25 EP EP97106878A patent/EP0806509B2/fr not_active Expired - Lifetime
- 1997-04-25 DE DE59710363T patent/DE59710363D1/de not_active Expired - Lifetime
- 1997-05-07 CN CN97111113A patent/CN1122736C/zh not_active Expired - Lifetime
- 1997-05-08 US US08/853,061 patent/US6114262A/en not_active Expired - Lifetime
- 1997-05-08 KR KR1019970017582A patent/KR100490187B1/ko not_active Expired - Fee Related
- 1997-05-09 CA CA002204967A patent/CA2204967C/fr not_active Expired - Fee Related
- 1997-05-12 JP JP9120768A patent/JPH10131019A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2679713A1 (fr) | 2012-06-26 | 2014-01-01 | O.R.V. Ovattificio Resinatura Valpadana S.p.a. | Support en textile non tissé renforcé avec des fils et procédé de fabrication d'un tel support |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2204967A1 (fr) | 1997-11-10 |
| EP0806509A1 (fr) | 1997-11-12 |
| DE59710363D1 (de) | 2003-08-07 |
| DE19618775A1 (de) | 1997-11-13 |
| CA2204967C (fr) | 2006-08-01 |
| EP0806509B2 (fr) | 2011-08-31 |
| CN1122736C (zh) | 2003-10-01 |
| KR970075017A (ko) | 1997-12-10 |
| JPH10131019A (ja) | 1998-05-19 |
| US6114262A (en) | 2000-09-05 |
| KR100490187B1 (ko) | 2005-09-28 |
| CN1174910A (zh) | 1998-03-04 |
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