EP0786355A2 - Bloc autocopiant avec adhésif repositionable - Google Patents
Bloc autocopiant avec adhésif repositionable Download PDFInfo
- Publication number
- EP0786355A2 EP0786355A2 EP97101056A EP97101056A EP0786355A2 EP 0786355 A2 EP0786355 A2 EP 0786355A2 EP 97101056 A EP97101056 A EP 97101056A EP 97101056 A EP97101056 A EP 97101056A EP 0786355 A2 EP0786355 A2 EP 0786355A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- quick
- set according
- sheet
- tear
- repositionable adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 38
- 239000000853 adhesive Substances 0.000 title claims abstract description 37
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000003112 inhibitor Substances 0.000 claims abstract description 5
- 239000003292 glue Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004831 Hot glue Substances 0.000 claims description 2
- 238000007640 computer printing Methods 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 16
- 239000010410 layer Substances 0.000 description 10
- 239000003153 chemical reaction reagent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000025 natural resin Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 241001148717 Lygeum spartum Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000221095 Simmondsia Species 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000012164 animal wax Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000012434 pretzels Nutrition 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000012176 shellac wax Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- -1 walrate Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41L—APPARATUS OR DEVICES FOR MANIFOLDING, DUPLICATING OR PRINTING FOR OFFICE OR OTHER COMMERCIAL PURPOSES; ADDRESSING MACHINES OR LIKE SERIES-PRINTING MACHINES
- B41L1/00—Devices for performing operations in connection with manifolding by means of pressure-sensitive layers or intermediaries, e.g. carbons; Accessories for manifolding purposes
- B41L1/20—Manifolding assemblies, e.g. book-like assemblies
- B41L1/22—Manifolding assemblies, e.g. book-like assemblies made up of single sheets or forms
- B41L1/24—Pads or books
Definitions
- the invention relates to self-copying high-speed separating sets which can be used in particular for computer-controlled printers and typewriters and which can be stuck and detached again and again from any object by means of a repositionable adhesive such as a sticky note.
- Self-copying papers are known.
- the back of a first paper is usually coated with a mostly encapsulated chemical reagent (so-called coated-back coating, CB coating).
- CB coating coated-back coating
- the top of the underlying sheet is then coated with a reagent that is often also microencapsulated and / or with a clay containing reagent. If pressure is now exerted on the first sheet above, also called the cover sheet, the CB reagent is released on the back by breaking open the microcapsules and pressed onto the coating of the sheet below, so that the two reagents come together and react to form a dye.
- both reagents required to form a dye are arranged together on one side of the sheet.
- the color reagents are brought together, which triggers the color reaction.
- SC systems self-contained systems
- Sticky notes are already known.
- a sheet of repositionable adhesive glue can be used be removed from a block and glued to and removed from any object, in particular on paper, as often as required.
- the production of such adhesive glues is generally known and is described, for example, in US Pat. No. 3,691,140.
- EP-B-0,261,817 describes a form block which in particular contains different forms and consists of a plurality of superimposed, self-copying sets of sheets, each sheet adhering to the underlying sheet by means of an intermediate adhesive, and in each set to at least one sheet the adhesive is a permanent adhesive.
- EP-B-0,281,344 also describes a block of self-copying sheets, in which all sheets are connected to one another with adhesive. All sheets have a repositionable pressure sensitive adhesive, so that the block can be separated on any sheet and a copy protection can be inserted.
- the aim of the invention is therefore to provide self-copying quick disconnect sets which do not have the disadvantages mentioned above and which are not only for handwritten use, but in particular also for that Labeling with typewriters and computer-controlled printers are suitable.
- a self-copying quick-release set which has an inscribable cover sheet and at least one copy or control sheet underneath, a self-copying system or an SC system being arranged between the cover sheet and control sheet and the cover and control sheet being able to be repositioned Adhesive glue are interconnected.
- both the cover sheet and the control sheet each have at least one tear line, which lie one above the other and which separate the quick release set into a removable, writable part and an edge strip, the repositionable adhesive glue between the cover sheet and control sheet preferably on both sides of the Tear-off or tear-off line, but at least on the side of the detachable part, so that even after the writable part has been torn off, the sheets of the remaining set still adhere to one another on the tear-off lines lying one above the other.
- the tear line can be designed both in the so-called cross-sectional perforation or as a microperforation.
- the quick release set according to the invention is further characterized in that the bottom control or copy sheet does not contain any pressure sensitive adhesive on its underside, but at least on the separated side of the tear line. It preferably contains no glue at the bottom.
- adhesive glue or another adhesive for example glue which can be activated by moistening, such as stamp glue
- label adhesive such as Raflatac RR 22 Non Permanent, available from Raflatac, 33101 Tampbere, Finland.
- the glue or adhesive is covered with a protective film that is peeled off in use.
- the quick disconnect sets according to the invention can be available both as a single set or as a book or block form.
- the quick disconnect sets are arranged one below the other on the sidebar by means of clips or by means of a side glue applied to the stack or book spine, e.g. B. a hot melt or PUR adhesive.
- a side glue applied to the stack or book spine e.g. B. a hot melt or PUR adhesive.
- Such methods are known to the person skilled in the art and are referred to, for example, as Eurobind or Otabind. Another method is described for example in DE-A-35,38,897.
- a stack of individual separating sets with front and rear cover sides is formed.
- One side of the stack forms the spine of the book, which is glued to a fold comprising the edges of the covers by means of hot-melt glue.
- the hot melt glue is preferably applied thinly.
- Such a book has good flat lying properties, so that it is also suitable for handwritten use.
- a write-through protection usually a piece of cardboard, between the individual separating sets or to put cardboard.
- the rear cover is extended and has one or more folding lines lying on the stacking edge, so that the outer side of the rear book cover can be folded back into the book and at the desired location as Write protection can be inserted.
- Such a copy protection can be seen, for example, from the form book "Delivery Notes SD 12" from Sigel.
- the back cover is provided with a flap that can be used as a desk pad. The flap is inserted behind the quick disconnect set to be labeled and in this way prevents unwanted copying on other sheets.
- the sheets are designed as forms so that the copies below can be filed or pinned as control and registration documents at any point until further processing or use.
- the quick disconnect set according to the invention has tear lines on two opposite sides, so that an edge strip is formed on both sides. These edge strips preferably have holes that are used for transport in computer-controlled printers. In this way it is possible to form so-called endless forms from the quick disconnect sets according to the invention.
- the quick disconnect sets are to be separated from one another at transverse dividing lines, in particular at perforation lines.
- Such quick-release sets connected to continuous forms make it possible to print computer-controlled forms, in which case a sheet provided with the repositionable adhesive, in particular the cover sheet, can be detachably stuck on at any desired position and the control copy underneath can be kept elsewhere as evidence .
- the adhesive glue is applied at least on the two inner sides of the two tear lines.
- the repositionable adhesive glue which can be used in the quick release sets according to the invention is known to the person skilled in the art and is described, for example, in US Pat. No. 3,691,140 by Silver or in US Pat. No. 4,495,318 and US Pat. No. 4,598,112 by Howard.
- the adhesive with the CF layer optionally also reacts with the CB layer to form a dye and / or possibly also the Detaching dye-forming reagents from the coating and thus leading to an early undesirable color formation.
- the contact of a repositionable adhesive glue with the CF layer to a mostly blue discoloration.
- release layer which facilitates the detachment of the overlying sheet, is not possible with such systems, since the silicones used here do not bond well to the CF layer and are often also undesirable Lead color reactions.
- any resins can be used for the inhibitor mixture according to the invention, as long as they do not themselves react with the SD coatings.
- the resins can be both synthetic resins and natural resins and can be in modified or unmodified form.
- the resins to be used according to the invention can be alkyl, epoxy, melamine, phenol or urethane resins, as long as they can be applied in the form of a layer.
- Preferred resins are film-forming resins, namely natural resins in native and modified form, e.g. B. as a resin ester or resin soaps. Rosin and its derivatives are also particularly suitable. It is also possible to use synthetic resins. However, the resins should not be soluble in the adhesive glue itself.
- both natural and chemically modified or synthetic waxes can be used as waxes.
- natural waxes are vegetable waxes such as carnauba wax, candelilla wax, Japanese wax, esparto grass wax, montan wax and guaruma wax, animal waxes such as beeswax, shellac wax, walrate, lanolin, pretzel fat, mineral waxes such as ceresin and ozokerite, petrochemical waxes such as petrolatum, paraffin waxes, microfaxes.
- Chemically modified waxes are for example hard waxes such as hydrogenated jojoba waxes and montan ester waxes, synthetic waxes are for example polyalkylene waxes and polyethylene glycol waxes.
- the mixture according to the invention preferably contains at least one resin together with at least one, preferably two different waxes.
- the inhibitor according to the invention is in particular in the form of a 30% isopropanol solution the desired areas are applied and the solvent evaporates.
- the inhibitor according to the invention can prevent undesirable color reactions between and within the CF (coated front) and the CB (coated back) layer of the self-copying systems.
Landscapes
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1996102808 DE19602808A1 (de) | 1996-01-26 | 1996-01-26 | Mit repositionierbarem Haftleim versehener selbstdurchschreibender Schnelltrennsatz |
| DE19602808 | 1996-01-26 | ||
| DE19630326 | 1996-07-26 | ||
| DE1996130326 DE19630326A1 (de) | 1996-01-26 | 1996-07-26 | Mit repositionierbarem Haftleim versehener selbstdurchschreibender Schnelltrennsatz |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0786355A2 true EP0786355A2 (fr) | 1997-07-30 |
| EP0786355A3 EP0786355A3 (fr) | 1998-06-10 |
Family
ID=26022394
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP97101056A Withdrawn EP0786355A3 (fr) | 1996-01-26 | 1997-01-23 | Bloc autocopiant avec adhésif repositionable |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0786355A3 (fr) |
| DE (1) | DE29624384U1 (fr) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3691140A (en) | 1970-03-09 | 1972-09-12 | Spencer Ferguson Silver | Acrylate copolymer microspheres |
| US4495318A (en) | 1984-03-21 | 1985-01-22 | International Cube Corporation | Low tack microsphere glue |
| US4598112A (en) | 1984-09-14 | 1986-07-01 | International Cube Corp. | Low tack cationic microsphere glue |
| DE3538897A1 (de) | 1985-11-02 | 1987-05-07 | Henkel Kgaa | Klebstoffauftragsverfahren |
| EP0261817B1 (fr) | 1986-09-25 | 1993-03-31 | Moore Business Forms, Inc. | Bloc de formulaires préimprimés |
| EP0281344B1 (fr) | 1987-03-05 | 1993-03-31 | Moore Business Forms, Inc. | Blocs-notes pour copies multiples |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2369101A1 (fr) * | 1976-10-26 | 1978-05-26 | Burroughs Corp | Formulaire a feuilles multiples |
| EP0486127B1 (fr) * | 1990-11-16 | 1994-12-07 | Moore Business Forms, Inc. | Bloc-notes |
| GB2260294B (en) * | 1991-10-08 | 1995-01-18 | Drakes Office Systems Ltd | A record book or pad |
| US5209698A (en) * | 1992-01-30 | 1993-05-11 | Moore Business Forms, Inc. | Piggyback label with CF or self-contained coating |
-
1996
- 1996-07-26 DE DE29624384U patent/DE29624384U1/de not_active Expired - Lifetime
-
1997
- 1997-01-23 EP EP97101056A patent/EP0786355A3/fr not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3691140A (en) | 1970-03-09 | 1972-09-12 | Spencer Ferguson Silver | Acrylate copolymer microspheres |
| US4495318A (en) | 1984-03-21 | 1985-01-22 | International Cube Corporation | Low tack microsphere glue |
| US4598112A (en) | 1984-09-14 | 1986-07-01 | International Cube Corp. | Low tack cationic microsphere glue |
| DE3538897A1 (de) | 1985-11-02 | 1987-05-07 | Henkel Kgaa | Klebstoffauftragsverfahren |
| EP0261817B1 (fr) | 1986-09-25 | 1993-03-31 | Moore Business Forms, Inc. | Bloc de formulaires préimprimés |
| EP0281344B1 (fr) | 1987-03-05 | 1993-03-31 | Moore Business Forms, Inc. | Blocs-notes pour copies multiples |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0786355A3 (fr) | 1998-06-10 |
| DE29624384U1 (de) | 2003-02-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| PUAL | Search report despatched |
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| 17P | Request for examination filed |
Effective date: 19981209 |
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| 17Q | First examination report despatched |
Effective date: 19991203 |
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| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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| 18D | Application deemed to be withdrawn |
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